CN115522392A - Aromatic fiber containing rose essential oil and preparation method thereof - Google Patents
Aromatic fiber containing rose essential oil and preparation method thereof Download PDFInfo
- Publication number
- CN115522392A CN115522392A CN202210686931.6A CN202210686931A CN115522392A CN 115522392 A CN115522392 A CN 115522392A CN 202210686931 A CN202210686931 A CN 202210686931A CN 115522392 A CN115522392 A CN 115522392A
- Authority
- CN
- China
- Prior art keywords
- essential oil
- rose essential
- aromatic
- fiber containing
- aromatic fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000341 volatile oil Substances 0.000 title claims abstract description 100
- 241000220317 Rosa Species 0.000 title claims abstract description 97
- 239000000835 fiber Substances 0.000 title claims abstract description 44
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims description 16
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 26
- 239000004627 regenerated cellulose Substances 0.000 claims abstract description 23
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 15
- 229920000858 Cyclodextrin Polymers 0.000 claims description 27
- 239000001116 FEMA 4028 Substances 0.000 claims description 27
- 235000010489 acacia gum Nutrition 0.000 claims description 27
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 27
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 27
- 229960004853 betadex Drugs 0.000 claims description 27
- 229920001661 Chitosan Polymers 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 23
- 239000003094 microcapsule Substances 0.000 claims description 23
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 229920000084 Gum arabic Polymers 0.000 claims description 7
- 239000000205 acacia gum Substances 0.000 claims description 7
- 238000005354 coacervation Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000007598 dipping method Methods 0.000 claims description 6
- 230000000149 penetrating effect Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229920000433 Lyocell Polymers 0.000 claims description 3
- 229920000297 Rayon Polymers 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- -1 modal Polymers 0.000 claims description 3
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 239000004640 Melamine resin Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 229920002674 hyaluronan Polymers 0.000 claims description 2
- 229960003160 hyaluronic acid Drugs 0.000 claims description 2
- 238000001338 self-assembly Methods 0.000 claims description 2
- 241000978776 Senegalia senegal Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 239000003205 fragrance Substances 0.000 abstract description 10
- 241000894006 Bacteria Species 0.000 abstract description 8
- 230000003796 beauty Effects 0.000 abstract description 6
- 210000005036 nerve Anatomy 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 244000215068 Acacia senegal Species 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 241001330002 Bambuseae Species 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 210000003056 antler Anatomy 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000002124 endocrine Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229920000591 gum Polymers 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 210000004291 uterus Anatomy 0.000 description 2
- FWVCSXWHVOOTFJ-UHFFFAOYSA-N 1-(2-chloroethylsulfanyl)-2-[2-(2-chloroethylsulfanyl)ethoxy]ethane Chemical compound ClCCSCCOCCSCCCl FWVCSXWHVOOTFJ-UHFFFAOYSA-N 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001123946 Gaga Species 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 235000011449 Rosa Nutrition 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses aromatic fiber containing rose essential oil, which comprises the following components in percentage by weight: 15-20 parts of rose essential oil, 40-50 parts of regenerated cellulose fiber and 15-18 parts of an auxiliary agent. The aromatic fiber prepared by the invention has the effects of resisting bacteria, soothing the nerves and maintaining beauty while maintaining the faint scent and elegant fragrance for a long time.
Description
Technical Field
The invention relates to the technical field of fiber materials, in particular to aromatic fiber containing rose essential oil and a preparation method thereof.
Background
With the current great increase of the social development speed, people pursue quality of life more and more. Especially, most people can pay attention to the external appearance of wearing clothes and matching and also can give out fragrance or not when people come in or go out of the environment of some formal occasions.
At present, most people also choose to make themselves emit unique fragrance by spraying perfume, so as to attract the attention of people. The perfumes often contain various perfumes, the rose essential oil is one of the perfumes, is called as "essential oil queen", not only plays a good role in nourishing the uterus, regulating endocrine and the like of the internal physical environment of women, but also has the functions of maintaining beauty and keeping young and lightening melanin spots on the skin, and plays an important role in improving the elasticity of the skin.
The method of spraying perfume increases personal charm and quality, and often has the defect of not being capable of lasting fragrance. The rose essential oil is applied to the fiber, the fiber is processed into the fabric, and the fiber in the fabric is used as a diffusion carrier of the rose essential oil, so that the diffusion area of the fragrance can be increased, and the lasting existence of the fragrance is facilitated. The patent CN106087250A discloses a bamboo filament fiber non-woven fabric containing rose essential oil and capable of continuously releasing negative oxygen ions and a preparation method thereof, wherein the rose essential oil is adsorbed on activated carbon particles, and then the activated carbon particles adsorbed with the rose essential oil are attached to the fiber surface to obtain the bamboo filament fiber non-woven fabric with fragrance, but the defect of low utilization rate of the rose essential oil exists; patent CN103741448B discloses an anti-shrinkage and anti-bacterial cotton-padded clothes treatment liquid and a preparation method thereof, wherein components such as zinc oxide and rose essential oil are mixed to prepare the treatment liquid, and the treatment liquid is used for treating cotton-padded clothes, so that the cotton-padded clothes has an anti-shrinkage and anti-bacterial effect and the defect of low utilization rate of the rose essential oil still exists. The aromatic fiber has faint scent and elegant fragrance, also has the effects of resisting bacteria, soothing nerves and beautifying, and improves the utilization rate of the rose essential oil by slowly releasing the rose essential oil.
Disclosure of Invention
The aromatic fiber containing the rose essential oil and the preparation method thereof have the effects of resisting bacteria, soothing nerves and maintaining beauty while maintaining the faint scent and elegant fragrance for a long time.
The invention provides aromatic fiber containing rose essential oil, which comprises the following components in percentage by weight: 15-20 parts of rose essential oil, 40-50 parts of regenerated cellulose fiber and 15-18 parts of an auxiliary agent.
The Latin science of the rose essential oil is named as 'Rosa damascona', has the name of 'essential oil queen', has special fragrance, can play a role in moisturizing, beautifying chest, eliminating dark eye circles, adjusting female endocrine and nourishing uterus, and also has the effects of calming, sleeping, soothing, pressure reducing, diminishing inflammation, inhibiting bacteria and the like.
As a preferable technical scheme, the rose essential oil is subjected to pretreatment, and the pretreatment is to mix the rose essential oil with wall materials to prepare the rose essential oil microcapsule.
In the invention, the rose essential oil microcapsule is prepared by pretreating rose essential oil, and the rose essential oil microcapsule can play a role of slowly releasing the internal rose essential oil, thereby more durably playing the roles of improving sleep, resisting bacteria, maintaining beauty, keeping young and the like of the rose essential oil.
Preferably, the wall material comprises at least one of beta-cyclodextrin, gelatin, gum arabic, chitosan, hyaluronic acid, melamine resin and cellulose.
Preferably, the wall material comprises beta-cyclodextrin, arabic gum and chitosan, and the weight ratio of the beta-cyclodextrin to the Arabic gum is (1-1.5): (0.6-0.8): (1.2-1.7).
Beta-cyclodextrin has a hollow cylindrical three-dimensional annular structure close to a cone, and the special molecular structure causes the inside of the beta-cyclodextrin to have extremely strong hydrophobicity and causes the outside of the beta-cyclodextrin to have hydrophilicity. The unique internal cavity hydrophobic structure can well coat essential oil molecules; the chitosan belongs to a natural polycation compound, has excellent emulsification and film-forming properties, is one of ideal wall materials for preparing microcapsules, contains a large amount of amino groups in chitosan molecules, can inhibit the growth of some fungi and bacteria, and has a synergistic effect with rose essential oil, so that the antibacterial property of the aromatic fiber is better. The beta-cyclodextrin, the Arabic gum and the chitosan are selected as wall materials in the system, and the weight ratio of the beta-cyclodextrin to the Arabic gum to the chitosan is (1-1.5): (0.6-0.8): (1.2-1.7), the three components cooperate with each other to act with the rose essential oil, a multilayer composite microcapsule structure can be formed, the coating rate is high, the structure can play a role of slowly releasing the rose essential oil in multiple layers, the effect durability of the aromatic fiber is kept to the maximum extent, and the aromatic fiber can be firmly combined with the cellulose fiber in a hydrogen bond mode; the addition of the Arabic gum in the system can well participate in promoting the emulsification effect of the rose essential oil, and the Arabic gum and the chitosan polycation compound generate electrostatic interaction, so that the complex coacervation reaction is facilitated to obtain the rose essential oil microcapsule. When the proportion of the three ingredients in the system is not in the range, the prepared rose essential oil microcapsule has low coating rate and poor slow release effect.
Preferably, the wall material comprises beta-cyclodextrin, arabic gum and chitosan, and the weight ratio of the beta-cyclodextrin to the Arabic gum is 1.2:0.7: (1.3-1.6).
Preferably, the wall material comprises beta-cyclodextrin, arabic gum and chitosan, and the weight ratio of the beta-cyclodextrin to the Arabic gum is 1.2:0.7:1.4.
when the weight ratio of the beta-cyclodextrin to the Arabic gum to the chitosan is 1.2:0.7:1.4, the synergistic effect of the three in the system is the best, the microcapsule prepared by reacting with the rose essential oil has more stable structure, high coating rate and better generated sustained-release effect.
Preferably, the molecular weight of the chitosan is 10000-50000; preferably, the chitosan has a molecular weight of 30000, and is purchased from Shanghai Aiyan Biotech, inc.
As a preferable technical scheme, the weight ratio of the rose essential oil to the wall material is 1: (2-2.7).
Preferably, the weight ratio of the rose essential oil to the wall material is 1:2.3.
as a preferable technical scheme, the preparation method of the rose essential oil microcapsule is one of a complex coacervation method, a crosslinking method and a self-assembly method.
Preferably, the preparation method of the rose essential oil microcapsule is a complex coacervation method.
As a preferable technical scheme, an emulsifier is also added in the pretreatment process.
Preferably, the emulsifier is a tween emulsifier; preferably, the emulsifier is tween 80.
Preferably, the preparation method of the rose essential oil microcapsule adopts a complex coacervation method, and comprises the following steps: 1) Uniformly mixing gum arabic with rose essential oil and water, wherein the addition amount of the water is 2.5-3 times of the mass of the gum arabic, and stirring for 1-2h at 40-50 ℃ to obtain a mixture A; 2) Mixing beta-cyclodextrin, chitosan and water, wherein the addition amount of the water is 0.6-1.2 times of the total mass of the beta-cyclodextrin and the chitosan, and stirring for 1-2 hours at the temperature of 30-40 ℃ to adjust the pH value to 4-6 to obtain a mixture B; 3) Slowly adding the mixture A into the mixture B, adding an emulsifier, wherein the addition amount of the emulsifier is 0.5 time of the total mass of the wall materials, adjusting the pH value to 4.5, stirring for 1-1.5h, and depositing to obtain the rose essential oil microcapsule.
As a preferred technical solution, the regenerated cellulose fiber is at least one of viscose, modal, and lyocell.
As a preferred technical scheme, the auxiliary agent comprises a binding agent and a penetrating agent.
Preferably, the weight ratio of the adhesive to the penetrant in the auxiliary agent is (3-5): 1.
Preferably, the weight ratio of the adhesive to the penetrant in the auxiliary agent is 4.
Preferably, the adhesive is waterborne polyurethane or adhesive Goon720.
Preferably, the adhesive is the adhesive Goon720, available from gaga macro silicone technologies, ltd.
Preferably, the penetrating agent is one of penetrating agent JFC and rapid penetrating agent T; preferably, the penetrant is a rapid penetrant T.
The auxiliary agent in the system is added with the adhesive and the penetrating agent, so that the prepared rose essential oil microcapsule can be combined with the surface of a cellulose fiber molecule more easily, the coverage rate of the rose essential oil microcapsule on the surface of the cellulose fiber molecule is improved, the content of rose essential oil is improved, and the prepared aromatic fiber has more lasting effects of sleeping and resisting bacteria, maintaining beauty and keeping young and the like.
In another aspect, the present invention provides a method for preparing aromatic fibers containing rose essential oil, comprising the following steps: 1) Mixing the pretreated rose essential oil and the auxiliary agent, and uniformly stirring to obtain a mixture; 2) Placing the regenerated cellulose fiber in the mixture for dipping treatment for 2h, taking out the regenerated cellulose fiber, controlling the liquid carrying rate of the regenerated cellulose fiber to be 60-70%, and performing drying treatment, wherein the drying temperature is 130-150 ℃, and the drying time is 5-10min; 3) And then placing the dried regenerated cellulose fiber in the mixture for dipping treatment for 2h, taking out, controlling the liquid carrying rate to be 40-50%, and drying at the drying temperature of 120-130 ℃ for 5-8min to obtain the aromatic fiber.
The invention has the following beneficial effects: 1) The rose essential oil microcapsule is prepared by pretreating the rose essential oil, so that the effect of slowly releasing the internal rose essential oil is achieved, and the effects of improving sleep, resisting bacteria, maintaining beauty and keeping young and the like of the rose essential oil are exerted for a longer time; 2) Selecting beta-cyclodextrin, arabic gum and chitosan as wall materials, wherein the weight ratio of the beta-cyclodextrin to the Arabic gum to the chitosan is (1-1.5): (0.6-0.8): (1.2-1.7), the three components cooperate with each other to act with the rose essential oil, a multi-layer composite microcapsule structure can be formed, the coating rate is high, the structure can play a role in multi-layer slow release of the rose essential oil, the effect durability of the aromatic fiber is kept to the maximum extent, and the antibacterial effect is excellent; 3) The aromatic fiber is obtained by a preparation method of controlling different liquid carrying rates of two times and drying for the second time, and the coating rate of the prepared rose essential oil microcapsule on the surface of the fiber can be improved, so that the content of the rose essential oil is improved.
Detailed Description
Example 1
The embodiment 1 of the invention specifically provides aromatic fiber containing rose essential oil, which comprises the following components in percentage by weight: 18 parts of rose essential oil, 45 parts of regenerated cellulose fiber and 16 parts of auxiliary agent.
The rose essential oil was purchased from sienna bai biotechnology limited.
The rose essential oil is subjected to pretreatment, and the pretreatment is to mix the rose essential oil and wall materials to prepare the rose essential oil microcapsule.
The wall material comprises beta-cyclodextrin, arabic gum and chitosan, and the weight ratio of the beta-cyclodextrin to the Arabic gum to the chitosan is 1.2:0.7:1.4.
the beta-cyclodextrin was purchased from Qingdao Wanyuan mountain Biotech, inc.
The gum arabic was purchased from shanghai mclin biochemical science ltd.
The chitosan has a molecular weight of 30000 and is purchased from Shanghai Aiyan Biotech, inc.
The weight ratio of the rose essential oil to the wall material is 1:2.3.
the preparation method of the rose essential oil microcapsule is a complex coacervation method.
An emulsifier is also added in the pretreatment process; the emulsifier is tween 80, purchased from shanghai alading biochem-tech ltd.
The preparation method of the rose essential oil microcapsule adopts a complex coacervation method, and comprises the following steps: 1) Uniformly mixing gum arabic with rose essential oil and water, wherein the addition amount of the water is 2.7 times of the mass of the gum arabic, and stirring for 1.5 hours at 45 ℃ to obtain a mixture A; 2) Mixing beta-cyclodextrin, chitosan and water, wherein the addition amount of the water is 0.9 time of the total mass of the beta-cyclodextrin and the chitosan, and adjusting the pH value to be 4.5 at the temperature of 35 ℃ and stirring for 1.4 hours to obtain a mixture B; 3) Slowly adding the mixture A into the mixture B, adding an emulsifier, wherein the adding amount of the emulsifier is 0.5 time of the total mass of the wall materials, adjusting the pH value to 4.5, stirring for 1.5h, and depositing to obtain the rose essential oil microcapsules.
The regenerated cellulose fiber is viscose.
The weight ratio of the adhesive to the penetrant in the auxiliary agent is 4.
The adhesive was adhesive Goon720, purchased from Kagaku silicone technologies, inc.
The penetrant is a rapid penetrant T, purchased from Nanjing Doulele Biotechnology GmbH.
A preparation method of aromatic fiber containing rose essential oil comprises the following steps: 1) Mixing the pretreated rose essential oil and the auxiliary agent and stirring uniformly to obtain a mixture; 2) Placing the regenerated cellulose fiber in the mixture for dipping treatment for 2h, taking out the regenerated cellulose fiber, controlling the liquid carrying rate of the regenerated cellulose fiber to be 65%, and performing drying treatment, wherein the drying temperature is 140 ℃, and the drying time is 7min; 3) And then placing the dried regenerated cellulose fiber in the mixture for dipping treatment for 2h, taking out, controlling the liquid carrying rate to be 48%, and drying at 125 ℃ for 6min to obtain the aromatic fiber.
Example 2
The embodiment 2 of the invention specifically provides aromatic fiber containing rose essential oil, which comprises the following components in percentage by weight: 15 parts of rose essential oil, 40 parts of regenerated cellulose fiber and 15 parts of auxiliary agent.
The components were the same as in example 1 except that the regenerated cellulose fiber was modal, and the preparation method was the same as in example 1.
Example 3
The embodiment 3 of the invention specifically provides aromatic fiber containing rose essential oil, which comprises the following components in percentage by weight: 20 parts of rose essential oil, 50 parts of regenerated cellulose fiber and 18 parts of auxiliary agent.
The preparation method is the same as that of example 1 except that the regenerated cellulose fiber is lyocell and the components are the same as that of example 1.
Comparative example 1
The comparative example 1 of the present invention specifically provides an aromatic fiber containing rose essential oil, and the specific implementation manner is the same as that of example 1, except that chitosan is not added to the wall material.
Comparative example 2
The invention provides a comparative example 2 specifically providing aromatic fiber containing rose essential oil, which is the same as the embodiment 1, and is characterized in that the wall material comprises beta-cyclodextrin, arabic gum and chitosan, and the weight ratio of the beta-cyclodextrin to the Arabic gum to the chitosan is 0.8:1:2.5.
comparative example 3
The invention provides a comparative example 3, which specifically provides an aromatic fiber containing rose essential oil, and the specific implementation manner is the same as that of example 1, except that arabic gum in the wall material is replaced by antler gum, and the antler gum is obtained from the Yangyi Biotech limited.
Comparative example 4
The comparative example 4 of the present invention specifically provides an aromatic fiber containing rose essential oil, and the specific implementation manner is the same as that in example 1, except that the weight ratio of the rose essential oil to the wall material is 1:4.
comparative example 5
Comparative example 5 of the present invention specifically provides an aromatic fiber containing rose essential oil, and the specific embodiment is the same as example 1, except that the weight ratio of the binder to the penetrant in the auxiliary is 1.
Performance testing
1. And (3) antibacterial property test: antibacterial property test was performed according to FZ/T73023-2006, and mainly for Staphylococcus aureus, escherichia coli and Candida albicans.
2. Testing the content of the rose essential oil: the prepared examples and comparative examples were each left to stand for 3 months and tested for rose essential oil content using UV1901 model UV-vis spectrophotometer.
The test results are shown in Table 1.
TABLE 1
Claims (10)
1. The aromatic fiber containing the rose essential oil is characterized by comprising the following components in parts by weight: 15-20 parts of rose essential oil, 40-50 parts of regenerated cellulose fiber and 15-18 parts of an auxiliary agent.
2. The aromatic fiber containing rose essential oil according to claim 1, wherein the rose essential oil is subjected to a pretreatment, and the pretreatment is to mix the rose essential oil with wall materials to prepare a rose essential oil microcapsule.
3. The aromatic fiber containing rose essential oil according to claim 2, wherein the wall material comprises at least one of beta-cyclodextrin, gelatin, gum arabic, chitosan, hyaluronic acid, melamine resin, and cellulose.
4. The aromatic fiber containing rose essential oil of claim 3, wherein the wall material comprises beta-cyclodextrin, arabic gum and chitosan, and the weight ratio of the beta-cyclodextrin to the arabic gum is (1-1.5): (0.6-0.8): (1.2-1.7).
5. The aromatic fiber containing rose essential oil according to claim 2, wherein the weight ratio of the rose essential oil to the wall material is 1: (2-2.7).
6. The aromatic fiber containing rose essential oil according to claim 2, wherein the preparation method of the rose essential oil microcapsule is one of complex coacervation, crosslinking and self-assembly.
7. The aromatic fiber containing rose essential oil according to claim 2, wherein an emulsifier is further added during the pretreatment.
8. The aromatic fiber containing rose essential oil according to claim 1, wherein the regenerated cellulose fiber is at least one of viscose, modal, lyocell.
9. The aromatic fiber containing rose essential oil according to claim 1, wherein the auxiliary agent comprises a binder and a penetrating agent.
10. A method for preparing the rose essential oil-containing aromatic fiber according to any one of claims 1 to 9, comprising the steps of: 1) Mixing the pretreated rose essential oil and the auxiliary agent, and uniformly stirring to obtain a mixture; 2) Placing the regenerated cellulose fiber in the mixture for dipping treatment for 2h, taking out the regenerated cellulose fiber, controlling the liquid carrying rate of the regenerated cellulose fiber to be 60-70%, and performing drying treatment, wherein the drying temperature is 130-150 ℃, and the drying time is 5-10min; 3) And then placing the dried regenerated cellulose fiber in the mixture for dipping treatment for 2h, taking out, controlling the liquid carrying rate to be 40-50%, and drying at the temperature of 120-130 ℃ for 5-8min to obtain the aromatic fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210686931.6A CN115522392B (en) | 2022-06-16 | 2022-06-16 | Aromatic fiber containing rose essential oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210686931.6A CN115522392B (en) | 2022-06-16 | 2022-06-16 | Aromatic fiber containing rose essential oil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115522392A true CN115522392A (en) | 2022-12-27 |
| CN115522392B CN115522392B (en) | 2024-03-01 |
Family
ID=84695893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210686931.6A Active CN115522392B (en) | 2022-06-16 | 2022-06-16 | Aromatic fiber containing rose essential oil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115522392B (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493207A (en) * | 2011-12-06 | 2012-06-13 | 东华大学 | Method for preparing regenerated cellulose fabric with calming healthcare effect |
| CN107929100A (en) * | 2017-11-28 | 2018-04-20 | 戴凤 | A kind of rose essential-oil microcapsule and preparation method thereof |
| CN107956132A (en) * | 2017-12-12 | 2018-04-24 | 芜湖环瑞汽车内饰件有限公司 | A kind of preparation method of microcapsule aromatic type automotive trim coir fibre material |
| CN108118536A (en) * | 2016-11-28 | 2018-06-05 | 丹阳市丹祈纺织有限公司 | Ms's fragrance skin makeup fabric |
| CN110511603A (en) * | 2019-09-02 | 2019-11-29 | 上海工程技术大学 | A kind of rose essential-oil microcapsule lotion and its preparation method and application |
| CN111286979A (en) * | 2020-03-02 | 2020-06-16 | 周祎杨 | Manufacturing process for implanting natural aroma into fiber |
| CN112301738A (en) * | 2020-11-10 | 2021-02-02 | 深圳千维生态纺织有限公司 | Rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin and preparation method of rose fiber |
| CN113151978A (en) * | 2021-03-15 | 2021-07-23 | 杭州诚品实业有限公司 | Antibacterial wood pulp viscose composite non-woven fabric and preparation method thereof |
| CN113981555A (en) * | 2021-12-07 | 2022-01-28 | 罗莱生活科技股份有限公司 | Aromatic regenerated cellulose fiber, fabric and preparation method |
| CN114150500A (en) * | 2021-12-07 | 2022-03-08 | 罗莱生活科技股份有限公司 | Preparation method of aromatic cotton fiber and textile thereof |
-
2022
- 2022-06-16 CN CN202210686931.6A patent/CN115522392B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493207A (en) * | 2011-12-06 | 2012-06-13 | 东华大学 | Method for preparing regenerated cellulose fabric with calming healthcare effect |
| CN108118536A (en) * | 2016-11-28 | 2018-06-05 | 丹阳市丹祈纺织有限公司 | Ms's fragrance skin makeup fabric |
| CN107929100A (en) * | 2017-11-28 | 2018-04-20 | 戴凤 | A kind of rose essential-oil microcapsule and preparation method thereof |
| CN107956132A (en) * | 2017-12-12 | 2018-04-24 | 芜湖环瑞汽车内饰件有限公司 | A kind of preparation method of microcapsule aromatic type automotive trim coir fibre material |
| CN110511603A (en) * | 2019-09-02 | 2019-11-29 | 上海工程技术大学 | A kind of rose essential-oil microcapsule lotion and its preparation method and application |
| CN111286979A (en) * | 2020-03-02 | 2020-06-16 | 周祎杨 | Manufacturing process for implanting natural aroma into fiber |
| CN112301738A (en) * | 2020-11-10 | 2021-02-02 | 深圳千维生态纺织有限公司 | Rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin and preparation method of rose fiber |
| CN113151978A (en) * | 2021-03-15 | 2021-07-23 | 杭州诚品实业有限公司 | Antibacterial wood pulp viscose composite non-woven fabric and preparation method thereof |
| CN113981555A (en) * | 2021-12-07 | 2022-01-28 | 罗莱生活科技股份有限公司 | Aromatic regenerated cellulose fiber, fabric and preparation method |
| CN114150500A (en) * | 2021-12-07 | 2022-03-08 | 罗莱生活科技股份有限公司 | Preparation method of aromatic cotton fiber and textile thereof |
Non-Patent Citations (2)
| Title |
|---|
| 卢亚会;张维;皇甫志杰;: "壳聚糖聚氨酯双层壳香味微胶囊的研发", 针织工业, no. 04, pages 44 - 47 * |
| 杨陈;: "驱蚊微胶囊的制备及对粘胶面料的功能整理", 纤维素科学与技术, no. 01, pages 46 - 50 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115522392B (en) | 2024-03-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102936835B (en) | Preparation method of nano-silver antibacterial real silk | |
| CN102061625B (en) | Mugwort leaf oil microcapsule antibacterial crease-resistant fabric and preparation method thereof | |
| CN100529246C (en) | Process for preparing poly modified chitosan anti-bacteria wet keeping finishing agent | |
| CN113134879B (en) | Fragrance-releasing decorative artificial board and preparation method thereof | |
| CN113062025B (en) | Jade zinc ice health-care fabric and preparation method thereof | |
| CN105054328A (en) | Manufacturing method for antibacterial material | |
| CN110791828B (en) | Multifunctional regenerated cellulose fiber and preparation method thereof | |
| CN101368219B (en) | Fragrant sustained-release type leather compound tanning agent and method of producing the same | |
| CN103343455A (en) | Aromatic fabric production method | |
| CN105332086B (en) | A kind of preparation method of Mesoporous zirconium phosphate loading nano silvery antibacterial polylactic acid fiber | |
| Xiao et al. | Application of microencapsulation technology in silk fibers | |
| CN115522392A (en) | Aromatic fiber containing rose essential oil and preparation method thereof | |
| CN111228302A (en) | Antibacterial hydrogel and preparation method and application thereof | |
| CN105506767B (en) | A kind of Mesoporous zirconium phosphate loading nano silvery antibacterial polypropylene fiber and preparation method thereof | |
| CN112971485B (en) | Antiviral cow leather mat and preparation method thereof | |
| CN101781849B (en) | Method for curing chitosan on fabrics | |
| CN110433741A (en) | Aromatic antibacterial microcapsule with carbon skeleton and preparation method thereof | |
| CN114150500A (en) | Preparation method of aromatic cotton fiber and textile thereof | |
| Gu et al. | Osmanthus fragrance polyurethane/silk fibroin‐based double‐shell microcapsules for aromatic leather with sustained release fragrance | |
| CN113047036B (en) | Jade-zinc ice health-care fiber and preparation method thereof | |
| CN115958854A (en) | Antibacterial mildew-resistant cotton | |
| CN104642301B (en) | A kind of preparation method of the preserved flower that refreshes the mind | |
| CN116807938B (en) | Composite mask cloth with color-changing function and preparation method thereof | |
| CN102851992A (en) | Fragrant fabric and its production method | |
| CN109056354A (en) | A kind of slow-release fragrance polyurethane coating and preparation method for automotive seat leather |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |