CN112300871A - Wiping-free cleaning agent, preparation method thereof and application thereof in vehicle cleaning - Google Patents
Wiping-free cleaning agent, preparation method thereof and application thereof in vehicle cleaning Download PDFInfo
- Publication number
- CN112300871A CN112300871A CN202011110381.0A CN202011110381A CN112300871A CN 112300871 A CN112300871 A CN 112300871A CN 202011110381 A CN202011110381 A CN 202011110381A CN 112300871 A CN112300871 A CN 112300871A
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- cleaning
- surfactant
- ethoxylated fatty
- wiping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 50
- 238000004140 cleaning Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 150000002466 imines Chemical class 0.000 claims abstract description 19
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 16
- 239000010685 fatty oil Substances 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 239000003981 vehicle Substances 0.000 claims abstract description 13
- 239000002738 chelating agent Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 45
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 26
- -1 alkyl glycosides Chemical class 0.000 claims description 26
- 239000003599 detergent Substances 0.000 claims description 25
- 229930182470 glycoside Natural products 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229920000151 polyglycol Polymers 0.000 claims description 12
- 239000010695 polyglycol Substances 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 239000002280 amphoteric surfactant Substances 0.000 claims description 7
- 239000003755 preservative agent Substances 0.000 claims description 7
- 230000002335 preservative effect Effects 0.000 claims description 7
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 claims description 7
- OHOTVSOGTVKXEL-WJXVXWFNSA-K trisodium;(2s)-2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)[C@H](C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-WJXVXWFNSA-K 0.000 claims description 7
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 5
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 150000002338 glycosides Chemical class 0.000 claims description 2
- 229940117986 sulfobetaine Drugs 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 1
- YKQQUNWUCHTADP-UHFFFAOYSA-K trisodium 2-[2-[[carboxy(hydroxy)methyl]-(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound C(CN(CC(=O)[O-])C(C(=O)O)O)N(CC(=O)[O-])CC(=O)[O-].[Na+].[Na+].[Na+] YKQQUNWUCHTADP-UHFFFAOYSA-K 0.000 claims 1
- 239000012528 membrane Substances 0.000 abstract description 9
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003973 paint Substances 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 5
- 150000002739 metals Chemical class 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000004209 oxidized polyethylene wax Substances 0.000 description 8
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical group OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 5
- 229960005323 phenoxyethanol Drugs 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- BDDLHHRCDSJVKV-UHFFFAOYSA-N 7028-40-2 Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O BDDLHHRCDSJVKV-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- VYTBPJNGNGMRFH-UHFFFAOYSA-N acetic acid;azane Chemical compound N.N.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O VYTBPJNGNGMRFH-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- KSDGSKVLUHKDAL-UHFFFAOYSA-L disodium;3-[2-carboxylatoethyl(dodecyl)amino]propanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCN(CCC([O-])=O)CCC([O-])=O KSDGSKVLUHKDAL-UHFFFAOYSA-L 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- AEGBILXJAUTWNU-UHFFFAOYSA-M sodium (1-dodecanoyloxy-3-hydroxypropan-2-yl) sulfate Chemical compound S(=O)(=O)([O-])OC(COC(CCCCCCCCCCC)=O)CO.[Na+] AEGBILXJAUTWNU-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of cleaning agents, and discloses a wiping-free cleaning agent, a preparation method thereof and application thereof in vehicle cleaning. The cleaning agent comprises a solvent, a chelating agent and a surfactant; the surfactant comprises a cationic surfactant; cationic surfactants include quaternized ethoxylated fatty oils, ethoxylated fatty imines, and polyethyleneimines. The cleaning agent simultaneously contains the quaternized ethoxylated fatty oil, the ethoxylated fatty imine and the polyethyleneimine, so that the cleaning agent has a good cleaning effect on automobiles, particularly a good cleaning effect on traffic membranes on the surfaces of the automobiles, does not need to manually wipe the traffic membranes in the cleaning process, is very environment-friendly, can be biodegraded, has no damage to automobile paint, and has no corrosion to metals.
Description
Technical Field
The invention belongs to the technical field of cleaning agents, and particularly relates to a wiping-free cleaning agent, a preparation method thereof and application thereof in vehicle cleaning.
Background
The content of harmful gases in the atmosphere, such as sulfur dioxide, carbon dioxide, nitrogen dioxide and the like, is increasingly increased along with the pollution of the global atmosphere. When the automobile runs at high speed, the automobile body rubs with air to form a layer of strong static electricity on the surface of the automobile body. The static further adsorbs dust and harmful gas molecular attachments, the generated stains are gradually thickened on the surface of the vehicle body, and a stubborn traffic film can be formed after a long time (the vehicle paint is rubbed with air in the using process to generate static electricity, and adsorbs dust, harmful gas and the like, so that the vehicle paint is oxidized to form an oxide film layer which is the traffic film), and the paint surface is continuously damaged. Due to the generation of the traffic film, the original bright car body becomes dull, the color is not bright, and the quality of waxing later is seriously influenced.
The automobile cleaning agent in the current market is required to be green and environment-friendly, biodegradable and free of corrosion damage to automobile paint and the like. However, most of the cleaning agents have almost no effect on cleaning the traffic film, and the traffic film formed on the automobile body can be cleaned only by manually wiping, so that the cleaning time and the personnel cost are increased when the automobile is beautified or a cleaning shop cleans one automobile, and the cost for cleaning one automobile is higher.
Therefore, there is a need to provide a new car cleaner which has a good cleaning effect on cars, particularly on traffic membranes, without manually wiping the traffic membranes.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art described above. Therefore, the invention provides a wiping-free cleaning agent, a preparation method thereof and application thereof in vehicle cleaning, the cleaning agent has good cleaning effect on automobiles, particularly traffic membranes, does not need manual wiping of the traffic membranes, and is very environment-friendly.
In a first aspect of the invention, a wipe-free cleanser is provided.
Specifically, the wiping-free cleaning agent comprises a solvent, a chelating agent and a surfactant; the surfactant comprises a cationic surfactant; the cationic surfactant comprises quaternized ethoxylated fatty oil, ethoxylated fatty imine and polyethyleneimine.
Preferably, the quaternized ethoxylated fatty oils and ethoxylated fatty imines are available from BASF corporation under the designation
AU-39/Bio.
Preferably, the polyethyleneimine may be obtained from BASF corporation under the designation
Product supply of G35.
Preferably, the surfactant further comprises a nonionic surfactant and/or an amphoteric surfactant.
The quaternized ethoxylated fatty oil, the ethoxylated fatty imine and the polyethyleneimine all contain ether segments, are very easy to combine with water in the air through hydrogen bonds to form a conductive channel, and achieve a better antistatic effect.
Further preferably, the nonionic surfactant is selected from alkyl glycoside, C10-C18Or at least one of alkyl polyglycol ether (abbreviated as 7EO) and polyoxyethylene alkylamine.
Preferably, the alkyl glycoside is C8-C14The alkyl glycoside of (a); further preferably, the alkyl glycoside is C12-C14Alkyl glycoside of (A) and (C)8-C10The ratio of alkyl glycoside (b) is 2.5-3.5:1 by mass, more preferably 3: 1.
Preferably, the alkyl glycoside and C in the detergent10-C18The mass ratio of the alkyl polyglycol ether is 1.5-4.5: 1; further preferably, the alkyl glycoside and C in the detergent10-C18The mass ratio of the alkyl polyglycol ether is 2-4: 1.
further preferably, the amphoteric surfactant is at least one selected from the group consisting of sodium lauryliminodipropionate, carboxybetaine, and sulfobetaine.
Preferably, the sodium lauryl imino dipropionate is sold under the trade name Solvay
H2C HA as amphoteric surfactant with excellent washing, dispersing, emulsifying and antistatic performanceThe cleaning solution has fine foam, can quickly remove stubborn stains under the synergistic compatibility of the alkaline salt compounds, and can not damage vehicle paint and solution, so that the cleaning solution has high stability and is not easy to layer.
Preferably, the chelating agent is at least one selected from nitrilotriacetic acid trisodium salt, ethylenediaminetetraacetic acid disodium salt, hydroxyethyldiaminetetraacetic acid trisodium salt or methylglycinediacetic acid trisodium salt.
Preferably, the solvent is water; further preferably, the water is deionized water.
Preferably, the cleaning agent further comprises an auxiliary agent.
Preferably, the adjuvant comprises a dispersant and/or a preservative.
Preferably, the dispersing agent is oxidized polyethylene wax; further preferably, the dispersant is available from BASF corporation under the designation
WE 7. The oxidized polyethylene wax is added into the cleaning agent, so that the water on the surface of the vehicle body can be effectively prevented from evaporating, the time for the foam of the cleaning agent to stay on the vehicle body is prolonged, and the cleaning force is improved.
Preferably, the preservative is phenoxyethanol and/or 4, 4' -dichloro-2-hydroxydiphenyl ether.
Preferably, the cleaning agent comprises the following components in parts by weight: 40-80 parts of solvent, 10-20 parts of chelating agent and 5-30 parts of surfactant.
Preferably, the content of the cationic surfactant is 4-20 parts; further preferably, the content of the cationic surfactant is 5 to 10 parts.
Preferably, the content of the nonionic surfactant is 3-15 parts; further preferably, the content of the nonionic surfactant is 5 to 12 parts.
Preferably, the content of the amphoteric surfactant is 3-10 parts; more preferably, the content of the amphoteric surfactant is 5 to 8 parts.
Preferably, the content of the dispersant is 1-10 parts; more preferably, the content of the dispersant is 2 to 6 parts.
Preferably, the content of the preservative is 0.01-1 part; more preferably, the content of the preservative is 0.1-0.5 part.
In another aspect of the invention, a method for preparing a wipe-free cleanser is provided.
Specifically, the first aspect of the invention provides a preparation method of a wiping-free detergent, which comprises the following steps:
and stirring and mixing the components to prepare the wiping-free cleaning agent.
Preferably, the preparation method of the wiping-free cleaning agent comprises the following steps:
and mixing the chelating agent with the solvent, then adding the surfactant, and stirring and mixing to prepare the wiping-free cleaning agent.
Preferably, during the addition of the surfactant, a dispersant is also added.
Preferably, the surfactant is added, and after stirring and mixing, the preservative is also added.
Specifically, the preparation method of the wiping-free cleaning agent comprises the following steps:
at normal temperature, at the rotating speed of 450-one-material 600 rpm, adding the chelating agent and the deionized water into the reaction kettle in sequence, mixing, stirring and dissolving for 10-20 minutes, and then adding the alkyl glycoside and the C in sequence10-C18Stirring the alkyl polyglycol ether and the sodium lauryl imino dipropionate for 10-20 minutes, adding the quaternized ethoxylated fatty oil, the ethoxylated fatty imine, the polyethyleneimine and the dispersant, stirring for 15-25 minutes, adding the preservative after the solution is clarified, stirring for 5-15 minutes, uniformly dispersing, stopping stirring, and standing to obtain the wiping-free detergent.
In another aspect, the invention also provides the use of a wipe-free cleanser.
The application of the wiping-free cleaning agent in the field of equipment cleaning.
Preferably, the apparatus comprises a vehicle, an aircraft or a boat; further preferably, the vehicle is an automobile.
Compared with the prior art, the invention has the following beneficial effects:
the cleaning agent simultaneously contains the quaternized ethoxylated fatty oil, the ethoxylated fatty imine and the polyethyleneimine, so that the cleaning agent has a good cleaning effect on automobiles, particularly on traffic membranes, does not need to manually wipe the traffic membranes in the cleaning process, saves labor cost, is very environment-friendly, can be biodegraded, does not damage car paint, and does not corrode metal.
Detailed Description
In order to make the technical solutions of the present invention more apparent to those skilled in the art, the following examples are given for illustration. It should be noted that the following examples are not intended to limit the scope of the claimed invention.
The starting materials, reagents or apparatuses used in the following examples are conventionally commercially available or can be obtained by conventionally known methods, unless otherwise specified.
Example 1: preparation of detergents
The wiping-free cleaning agent comprises the following components in parts by weight:
wherein the mixture of quaternized ethoxylated tallow oil and ethoxylated fatty imine is available from BASF corporation under the designation
AU-39/Bio; polyethyleneimine is manufactured by BASF corporation under the trademark
Product supply of G35.
The preparation method of the wiping-free cleaning agent comprises the following steps:
sequentially adding trisodium methylglycinediacetate into the reaction kettle at the normal temperature and at the rotating speed of 550 revolutions per minuteSalt, hydroxyethyl diamine tetraacetic acid trisodium salt, ethylene diamine tetraacetic acid disodium salt and deionized water are mixed, stirred and dissolved for 15 minutes, and then alkyl glycoside and C are sequentially added10-C18Stirring the alkyl polyglycol ether and the sodium lauryl imino dipropionate for 15 minutes, adding the mixture of the quaternized ethoxylated fatty oil and the ethoxylated fatty imine, the polyethyleneimine and the oxidized polyethylene wax, stirring for 20 minutes, adding the phenoxyethanol after the solution is clarified, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the wiping-free detergent.
Example 2: preparation of detergents
The wiping-free cleaning agent comprises the following components in parts by weight:
wherein the mixture of quaternized ethoxylated tallow oil and ethoxylated fatty imine is available from BASF corporation under the designation
AU-39/Bio.
The preparation method of the wiping-free cleaning agent comprises the following steps:
at normal temperature, at the rotating speed of 550 revolutions per minute, sequentially adding methylglycine diacetic acid trisodium salt, nitrilotriacetic acid trisodium salt and deionized water into a reaction kettle, mixing, stirring and dissolving for 15 minutes, and then sequentially adding alkyl glycoside and C10-C18Stirring the alkyl polyglycol ether and the sodium lauryl imino dipropionate for 15 minutes, adding the mixture of the quaternized ethoxylated fatty oil and the ethoxylated fatty imine, the polyethyleneimine and the oxidized polyethylene wax, stirring for 20 minutes, adding the phenoxyethanol after the solution is clarified, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the wiping-free detergent.
Example 3: preparation of detergents
The wiping-free cleaning agent comprises the following components in parts by weight:
wherein the mixture of quaternized ethoxylated tallow oil and ethoxylated fatty imine is available from BASF corporation under the designation
AU-39/Bio.
The preparation method of the wiping-free cleaning agent comprises the following steps:
at normal temperature, at the rotating speed of 550 revolutions per minute, sequentially adding methylglycine diacetic acid trisodium salt, hydroxyethyldiamine tetraacetic acid trisodium salt, nitrilotriacetic acid trisodium salt and deionized water into a reaction kettle, mixing, stirring and dissolving for 15 minutes, and sequentially adding alkyl glycoside and C10-C18And stirring the alkyl polyglycol ether and the sodium lauryl imino dipropionate for 15 minutes, adding a mixture of quaternized ethoxylated fatty oil and ethoxylated fatty imine, polyethyleneimine and oxidized polyethylene wax, stirring for 20 minutes, adding 4, 4' -dichloro-2-hydroxy diphenyl ether after the solution is clarified, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the wiping-free detergent.
Example 4: preparation of detergents
The wiping-free cleaning agent comprises the following components in parts by weight:
wherein, quaternizing BMixtures of oxyliphatic oils and ethoxylated fatty imines are available from BASF corporation under the trade designation
AU-39/Bio.
The preparation method of the wiping-free cleaning agent comprises the following steps:
at normal temperature, at the rotating speed of 550 revolutions per minute, sequentially adding methylglycine diacetic acid trisodium salt, hydroxyethyldiamine tetraacetic acid trisodium salt, nitrilotriacetic acid trisodium salt and deionized water into a reaction kettle, mixing, stirring and dissolving for 15 minutes, and sequentially adding alkyl glycoside and C10-C18And stirring the alkyl polyglycol ether and the sodium lauryl imino dipropionate for 15 minutes, adding a mixture of quaternized ethoxylated fatty oil and ethoxylated fatty imine, polyethyleneimine and oxidized polyethylene wax, stirring for 20 minutes, adding 4, 4' -dichloro-2-hydroxy diphenyl ether after the solution is clarified, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the wiping-free detergent.
Example 5: preparation of detergents
The wiping-free cleaning agent comprises the following components in parts by weight:
wherein the mixture of quaternized ethoxylated tallow oil and ethoxylated fatty imine is available from BASF corporation under the designation
AU-39/Bio.
The preparation method of the wiping-free cleaning agent comprises the following steps:
at normal temperature, at the rotating speed of 550 revolutions per minute, sequentially adding methylglycine diacetic acid trisodium salt, hydroxyethyldiamine tetraacetic acid trisodium salt, nitrilotriacetic acid trisodium salt and deionized water into a reaction kettle, mixing, stirring and dissolving for 15 minutes, and sequentially adding alkyl glycoside and C10-C18And stirring the alkyl polyglycol ether and the sodium lauryl imino dipropionate for 15 minutes, adding a mixture of quaternized ethoxylated fatty oil and ethoxylated fatty imine, polyethyleneimine and oxidized polyethylene wax, stirring for 20 minutes, adding 4, 4' -dichloro-2-hydroxy diphenyl ether after the solution is clarified, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the wiping-free detergent.
Comparative example 1
Compared with example 1, the detergent of comparative example 1 was prepared without adding polyethyleneimine, and the remaining components and preparation method were the same as example 1.
Comparative example 2
In comparison with example 1, the detergent of comparative example 2 was prepared without adding the mixture of quaternized ethoxylated tallow oil and ethoxylated fatty imine, and the remaining ingredients and preparation method were the same as in example 1.
Comparative example 3
The wiping-free cleaning agent comprises the following components in parts by weight:
the preparation method of the wiping-free cleaning agent comprises the following steps:
at normal temperature, at the rotating speed of 550 revolutions per minute, sequentially adding methylglycine diacetic acid trisodium salt, hydroxyethyl diamine tetraacetic acid trisodium salt, ethylene diamine tetraacetic acid disodium salt and deionized water into a reaction kettle, mixing, stirring and dissolving for 15 minutes, and sequentially adding alkyl glycoside and C10-C18Stirring the alkyl polyglycol ether and the sodium lauryl imino dipropionate for 15 minutes, adding the polyethyleneimine and the oxidized polyethylene wax, stirring for 20 minutes, adding the phenoxyethanol after the solution is clear, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the wiping-free detergent.
Comparative example 4 (a prior art automobile cleaner)
The automobile cleaning agent comprises the following components in parts by weight:
the preparation method of the automobile detergent comprises the following steps:
adding deionized water into a reaction kettle at the rotating speed of 550 revolutions per minute, heating to 40-50 ℃, adding sodium fatty acid methyl ester sulfonate and alpha-alkenyl sulfonate, dissolving for 15 minutes, adding alkyl glycoside and coco dimethyl betaine after complete dissolution, stirring for 15 minutes, adding sodium carbonate, stirring for 15 minutes, adding isopropanol, nitrilotriacetic acid trisodium salt and phenoxyethanol after complete dissolution, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the automobile detergent.
Comparative example 5 (a prior art automobile cleaner)
The automobile cleaning agent comprises the following components in parts by weight:
the preparation method of the automobile detergent comprises the following steps:
mixing and heating ethylene diamine tetraacetic acid disodium salt, sodium phosphate, sodium dodecyl benzene sulfonate, sodium bicarbonate, sodium lauryl sulfate, sodium glycerol monolaurate sulfate and deionized water to 50-60 ℃ at the rotating speed of 550 revolutions per minute to obtain a component A; mixing the silicone emulsion and polyglycerol fatty acid ester, and heating to 50-60 deg.C to obtain component B; and (3) mixing the component A and the component B, stirring for 15 minutes, adding 4, 4' -dichloro-2-hydroxy diphenyl ether, stirring for 10 minutes, dispersing uniformly, stopping stirring, and standing to obtain the automobile cleaner.
Product effectiveness testing
The following performance tests were performed on the detergent products prepared in examples 1 to 5 and comparative examples 1 to 5, and the test results are shown in Table 1:
cleaning test (determination of cleaning rate): automobile cosmetic metal nose cover models (28.5 × 25.5cm, thickness 0.1cm) of the same size were purchased in the automobile appliance market. Smearing the same dirt (automobile engine oil) on the head cover, putting the head cover into an oven with the temperature of 80 ℃ for keeping the temperature for 24 hours, then taking out the head cover, putting the head cover outdoors for 1 month, and adsorbing the generated traffic membrane on the head cover, thereby manufacturing the pollution panel. Diluting a test sample by 100 times, carrying out an actual cleaning test on the polluted panel for 3 minutes, then fully rinsing the polluted panel with water, drying the polluted panel with nitrogen, and calculating the cleaning rate by using a differential interference microscope (manufactured by Leica, Inc., with the magnification of 400 times), thereby evaluating the cleaning property of the surface of the panel;
the high temperature (55 ℃) stability test method comprises the following steps: according to a high-temperature detection method in QB/T2117-1995, Universal Water-based Metal detergent;
the low temperature (5 ℃) stability test method comprises the following steps: according to the low-temperature detection method in QB/T2117-1995, general water-based metal detergent;
the metal corrosion test method comprises the following steps: the test specimen 5g was diluted 100-fold, and a 45# steel specimen (5 cm in size, 2.5m in thickness, 0.1cm in thickness) was immersed in the sample taken out of a polypropylene container. And sealing the container, placing the container in a room with the temperature adjusted to 25 ℃ for 5 days, taking out the container, soaking and flushing, and observing whether the surface of the test piece is corroded by naked eyes to evaluate the corrosion of the cleaning agent to metal.
Table 1: detergent performance test results
As can be seen from Table 1, the cleaning rates of the cleaners prepared in examples 1 to 5 according to the present invention were significantly higher than those of the products prepared in comparative examples 1 to 5, and the high-temperature stability and the low-temperature stability of the cleaners prepared in examples 1 to 5 according to the present invention were also significantly better than those of the cleaners prepared in comparative examples 4 to 5. In addition, the cleaning agents prepared in the embodiments 1 to 5 of the invention have no corrosion to metals, and the traffic film does not need to be manually wiped in the cleaning process.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (10)
1. A cleaning agent, comprising a solvent, a chelating agent, and a surfactant; the surfactant comprises a cationic surfactant; the cationic surfactant comprises quaternized ethoxylated fatty oil, ethoxylated fatty imine and polyethyleneimine.
2. The cleaning agent according to claim 1, wherein the surfactant further comprises a nonionic surfactant and/or an amphoteric surfactant.
3. The cleaning agent according to claim 2, wherein the nonionic surfactant is selected from alkyl glycosides, C10-C18At least one of an alkyl polyglycol ether or a polyoxyethylene alkylamine; preferably, the alkyl glycoside is C12-C14Alkyl glycoside of (A) and (C)8-C10The alkyl glycoside of (a) is a mixture of 2.5-3.5:1 by mass; preferably, the alkyl glycoside and C in the detergent10-C18The mass ratio of the alkyl polyglycol ether is 1.5-4.5: 1.
4. the cleaning agent according to claim 2, wherein the amphoteric surfactant is at least one selected from the group consisting of sodium lauryiiminodipropionate, carboxybetaine, and sulfobetaine.
5. The cleaning agent as claimed in claim 1, wherein the chelating agent is at least one selected from nitrilotriacetic acid trisodium salt, ethylenediaminetetraacetic acid disodium salt, hydroxyethylenediaminetetraacetic acid trisodium salt, or methylglycinediacetic acid trisodium salt.
6. The cleaning agent of claim 1, further comprising an adjunct; the auxiliary agent comprises a dispersing agent and/or a preservative.
7. The cleaning agent according to claim 1, which comprises the following components in parts by weight: 40-80 parts of solvent, 10-20 parts of chelating agent and 5-30 parts of surfactant.
8. A process for the preparation of a cleaning formulation as claimed in any one of claims 1 to 7, comprising the steps of:
and stirring and mixing the components to prepare the cleaning agent.
9. Use of the cleaning agent according to any one of claims 1 to 7 in the field of cleaning of equipment.
10. Use according to claim 9, wherein the device comprises a vehicle, an aircraft or a ship.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011110381.0A CN112300871A (en) | 2020-10-16 | 2020-10-16 | Wiping-free cleaning agent, preparation method thereof and application thereof in vehicle cleaning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011110381.0A CN112300871A (en) | 2020-10-16 | 2020-10-16 | Wiping-free cleaning agent, preparation method thereof and application thereof in vehicle cleaning |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112300871A true CN112300871A (en) | 2021-02-02 |
Family
ID=74328032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011110381.0A Withdrawn CN112300871A (en) | 2020-10-16 | 2020-10-16 | Wiping-free cleaning agent, preparation method thereof and application thereof in vehicle cleaning |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112300871A (en) |
-
2020
- 2020-10-16 CN CN202011110381.0A patent/CN112300871A/en not_active Withdrawn
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6984269B2 (en) | Cleaning surfaces | |
| US20050187119A1 (en) | Water-based paint-removing solution | |
| WO2002081610A1 (en) | Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds | |
| AU2002257654A1 (en) | Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds | |
| CN103451666A (en) | Metal cleaning agent | |
| CN110629234B (en) | Non-ferrous metal cleaning agent and method for cleaning non-ferrous metal parts | |
| US7384902B2 (en) | Metal brightener and surface cleaner | |
| CN110724605B (en) | Environment-friendly water-based cleaning agent and preparation method thereof | |
| CN112300871A (en) | Wiping-free cleaning agent, preparation method thereof and application thereof in vehicle cleaning | |
| JP2018035209A (en) | Cleaning agent for optical glass and cleaning method of optical glass | |
| CN114214126B (en) | Water-based cleaning composition, preparation method and application thereof | |
| JPH11513731A (en) | Metal finishing method and composition | |
| EP1287099B1 (en) | Cleaning surfaces | |
| JPH0959677A (en) | Detergent composition | |
| JP4425731B2 (en) | Cleaning composition for CIP | |
| JPH11302693A (en) | Concentrated detergent composition | |
| US20040009884A1 (en) | Flushing solutions for coatings removal | |
| CN110453232B (en) | Phosphorus-free normal-temperature composite metal surface degreasing agent | |
| JP3747554B2 (en) | Detergent composition for light metals | |
| JPH07109493A (en) | Detergent composition | |
| JP2000008080A (en) | Industrial detergent composition and cleaning using the same | |
| JP2005514493A6 (en) | Cleaning agent for the outer surface of the vehicle | |
| JP2005514493A (en) | Cleaning agent for the outer surface of the vehicle | |
| JP6780172B1 (en) | Water-based cleaning agent and cleaning method using the water-based cleaning agent | |
| JP3366718B2 (en) | Hard surface cleaning composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20210202 |
|
| WW01 | Invention patent application withdrawn after publication |