CN112300650B - Batch scraping type stone-like paint and application thereof - Google Patents

Batch scraping type stone-like paint and application thereof Download PDF

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CN112300650B
CN112300650B CN202011294228.8A CN202011294228A CN112300650B CN 112300650 B CN112300650 B CN 112300650B CN 202011294228 A CN202011294228 A CN 202011294228A CN 112300650 B CN112300650 B CN 112300650B
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parts
batch
paint
preservative
stone
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CN112300650A (en
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陈中
翁金城
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Fujian Jiayi Material Technology Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a batch-scraping type stone-like paint, which belongs to the technical field of coatings and comprises 5% of protective glue, a disperse phase and a continuous phase; the 5% protective glue comprises ST532S protective glue powder; the dispersed phase comprises hydroxyethyl cellulose, defoamer, film forming auxiliary agent, ethylene glycol, titanium dioxide, kaolin, ST-1F gel, anionic styrene-acrylic emulsion, AMP95, preservative, white snow and water; the continuous phase comprises a film forming aid, ethylene glycol, AMP95, a defoaming agent, a silicone-acrylic emulsion with nano particle size, a KZ125 thickening emulsion, a thixotropic agent, a preservative and water. This batch-scraping type stone-like paint adopts 5% protective adhesive, the usable batch scraping process of stone-like paint that disperse phase and continuous phase were made to be under construction, even the batch scraping operation can not appear the problem of breaking the paste yet, has effectively avoided the problem that easily receives the atmospheric pressure stability influence in the spraying construction to and the noise problem that the spraying construction produced.

Description

Scraping type stone-like paint and application thereof
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a batch scraping type artistic wall surface and application thereof.
Background
The batch scraping is a construction method for coating, compared with spraying, rolling and brushing, tools required by batch scraping are simple, the tools do not need to be electrified, the construction efficiency is high, the obtained wall surface is smooth, and meanwhile, the friction between the batch knife and the wall surface is lower than 40 decibels, so that noise is not generated. However, the existing stone-like paint has small particle toughness, and can be broken and pasted after being coated by adopting a batch scraping mode, the original stone-like effect cannot be achieved, further the batch scraping mode cannot be used for construction, a spraying method is adopted for construction, the construction is easily influenced by the stability of air pressure, tools with special functions are required for spraying construction, and in the spraying construction, the noise generated by spraying equipment such as an air compressor reaches 140 decibels.
Disclosure of Invention
In order to overcome the defects of the prior art, the technical problems to be solved by the invention are as follows: provides a batch-scraping type stone-like paint which can be used for batch-scraping construction.
In order to solve the technical problems, the invention adopts the technical scheme that: the batch-scraping type stone-like paint comprises 5% of protective glue, a dispersion phase and a continuous phase;
the 5% protective glue comprises ST532S protective glue powder;
the dispersed phase comprises hydroxyethyl cellulose, a defoaming agent, a film-forming auxiliary agent, ethylene glycol, titanium dioxide, kaolin, ST-1F gel, anionic styrene-acrylic emulsion, AMP95, a preservative, snow white and water;
the continuous phase comprises a film forming aid, ethylene glycol, AMP95, a defoaming agent, a silicone-acrylate emulsion with a nano particle size, a KZ125 thickening emulsion, a thixotropic agent, a preservative and water.
The other technical scheme adopted by the invention is as follows: the batch scraping type stone-like paint is applied to preparing batch scraping type artistic wall surfaces.
The invention has the beneficial effects that: according to the batch-scraping type stone-like paint provided by the invention, the stone-like paint prepared from 5% of the protective glue, the dispersed phase and the continuous phase can be constructed by using a batch-scraping process, and as the hydroxyethyl cellulose and the ST-1F gel are specifically added in the dispersed phase and the continuous phase, and the color dots in the paint can be wrapped in a high-toughness structure formed by the protective glue after the protective glue reacts with the protective glue, the problem of paste breaking can not occur even in batch scraping operation, and the problems that the spraying construction is easily influenced by air pressure stability and the noise generated by the spraying construction can be effectively avoided.
Drawings
FIG. 1 is a view showing a batch-scraped artistic wall surface prepared by a batch-scraped process of the batch-scraped stone-like paint according to the embodiment of the present invention;
FIG. 2 is a view showing a batch-scraped artistic wall surface prepared by a batch-scraped process of the batch-scraped stone-like paint according to the embodiment of the present invention;
FIG. 3 is a view showing a batch-scraped artistic wall surface prepared by a batch-scraped process of the batch-scraped stone-like paint according to the embodiment of the present invention;
FIG. 4 is a view showing a batch-scraped artistic wall surface prepared by a batch-scraped process of the batch-scraped stone-like paint according to the embodiment of the present invention;
FIG. 5 is a view showing a batch-scraped artistic wall surface prepared by a batch-scraped process of the batch-scraped stone-like paint according to the embodiment of the present invention;
FIG. 6 is a view showing a batch-scraped artistic wall surface prepared by a batch-scraped process of the batch-scraped stone-like paint according to the embodiment of the present invention;
fig. 7 shows a batch-scraping type artistic wall surface prepared by batch-scraping process of the batch-scraping type stone-like paint according to the embodiment of the invention.
Detailed Description
In order to explain technical contents, achieved objects, and effects of the present invention in detail, the following description is made with reference to the accompanying drawings in combination with the embodiments.
The invention provides a batch scraping type stone-like paint which comprises 5% of protective glue, a dispersion phase and a continuous phase;
the 5% protective glue comprises ST532S protective glue powder;
the dispersed phase comprises hydroxyethyl cellulose, a defoaming agent, a film-forming auxiliary agent, ethylene glycol, titanium dioxide, kaolin, ST-1F gel, anionic styrene-acrylic emulsion, AMP95, a preservative, snow white and water;
the continuous phase comprises a film forming aid, ethylene glycol, AMP95, a defoaming agent, a silicone-acrylate emulsion with a nano particle size, a KZ125 thickening emulsion, a thixotropic agent, a preservative and water.
As can be seen from the above description, the beneficial effects of the present invention are: according to the batch-scraping type stone-like paint provided by the invention, the hydroxyethyl cellulose and the ST-1F gel are added into the dispersed phase together, and the hydroxyethyl cellulose and the ST-1F gel act with the protective glue to wrap colored particles (color dots) in the dispersed phase when the batch-scraping type stone-like paint is used, the formed structure has higher toughness, the problem of paste breaking cannot occur in the batch-scraping construction process, the stone-like effect after batch scraping is ensured, and meanwhile, an emulsion system formed by the silicone-acrylic emulsion with the nanometer particle size, the KZ125 thickening emulsion and the anionic styrene-acrylic emulsion also has good wrapping property, so that the stability of the whole system in the batch scraping process is further ensured. Meanwhile, 5% of protective glue prepared from ST532S protective glue powder is selected specifically, and ST532S and the gel agent can provide excellent wrapping and isolating functions.
Further, the 5% protective glue consists of 5% of ST532S protective glue powder, 0.2% of preservative and 94.8% of water in percentage by weight.
Further, the dispersed phase comprises, by weight, 4-8 parts of hydroxyethyl cellulose, 1-2 parts of a defoaming agent, 8-12 parts of a film-forming aid, 5-8 parts of ethylene glycol, 25-35 parts of titanium dioxide, 50-70 parts of kaolin, 15-25 parts of ST-1F gel, 150-200 parts of anionic styrene-acrylic emulsion, 1-3 parts of AMP95, 2-4 parts of a preservative, 450-550 parts of snow white and 650-700 parts of water.
Further, the continuous phase comprises, by weight, 30-38 parts of a film-forming aid, 10-15 parts of ethylene glycol, 1-3 parts of AMP95, 2-4 parts of an antifoaming agent, 480 parts of a silicone-acrylic emulsion with a nano particle size, 160 parts of KZ125 thickened emulsion, 20-25 parts of a thixotropic agent, 1-3 parts of a preservative and 380 parts of water 320.
Further, in the continuous phase, the hydroxyethyl cellulose is HS100000 cellulose, the film-forming aid is alcohol ester twelve, the defoamer is ST2410, the titanium dioxide is R251 titanium dioxide, the kaolin is 4000-mesh calcined kaolin, the snowflake white is 100-mesh snowflake white, and the preservative is an LXE preservative.
Further, in the dispersed phase, the film-forming aid is alcohol ester twelve, the defoamer is ST2410, the preservative is an LXE preservative, and the thixotropic agent is a real stone paint thixotropic agent of a new sea vast material.
Example (b):
1. 5% of protective adhesive:
5% of protective glue A, which consists of 5% of ST532S protective glue powder, 0.2% of preservative and 94.8% of water.
5% of protective glue B, which consists of 5% of S482 protective glue powder, 0.2% of preservative and 94.8% of water.
2. The composition of the dispersed phase is shown in table 1.
TABLE 1
Components Disperse phase A Disperse phase B Disperse phase C Disperse phase D
Kelaien HS100000(kg) 4 6 8 4
ST2410(kg) 1 1 2 1
Islam ester twelve (kg) 10 8 12 10
Ethylene glycol (kg) 5 6 8 5
R251 titanium white powder (kg) 25 30 35 25
4000 mesh calcined Kaolin (kg) 60 50 70 60
Shandonghai vast New material ST-1F gel (kg) 20 15 25 /
Carbomer (kg) / / / 20
Wanhua chemical 8017 emulsion (kg) 200 150 180 200
German basf AMP95(kg) 2 1 3 2
Dow chemical LXE (kg) 3 2 4 3
100 mesh snowflake white (kg) 500 450 550 500
Water (kg) 669 650 700 669
In the preparation process of the dispersion phase, all the raw materials in table 1 are mixed and then uniformly dispersed again, so that the dispersion phase is obtained.
3. The composition of the continuous phase is shown in table 2.
TABLE 2
Figure BDA0002784877770000041
Figure BDA0002784877770000051
The continuous phase comprises, by weight, 30-38 parts of a film-forming aid, 10-15 parts of ethylene glycol, 1-3 parts of AMP95, 2-4 parts of an antifoaming agent, 480 parts of a nano-particle size silicone-acrylic emulsion, 140-160 parts of a KZ125 thickening emulsion, 20-25 parts of a thixotropic agent, 1-3 parts of a preservative and 320-380 parts of water.
Example 1:
the batch scraping type stone-like paint consists of 5 percent of protective glue A, a dispersion phase A and a continuous phase A, and black and gray color paste is added into the dispersion phase A for color mixing.
Example 2:
the batch scraping type stone-like paint consists of 5 percent of protective glue A, a dispersion phase B and a continuous phase B, and black and gray color paste is added into the dispersion phase B for color mixing.
Example 3:
the batch scraping type stone-like paint consists of 5 percent of protective glue A, a dispersion phase C and a continuous phase C, and black and yellow soil paste is added into the dispersion phase C for toning.
Example 4:
the batch scraping type stone-like paint consists of 5 percent of protective glue A, a dispersion phase A and a continuous phase B, and black and reddish brown color paste is added into the dispersion phase A for color mixing.
Example 5:
the batch scraping type stone-like paint consists of 5 percent of protective glue A, a dispersion phase B and a continuous phase C, and black and gray color paste is added into the dispersion phase B for color mixing.
Example 6:
the batch scraping type stone-like paint consists of 5 percent of protective glue A, a disperse phase C and a continuous phase A, and black and brown color paste is added into the disperse phase C for color mixing.
Example 7:
the batch scraping type stone-like paint consists of 5 percent of protective glue A, a dispersion phase A and a continuous phase C, and green color paste is added into the dispersion phase A for color mixing.
Comparative example 1:
the stone-like paint consists of 5% of protective glue B, a dispersed phase A and a continuous phase A.
Comparative example 2:
the stone-like paint consists of 5% of protective adhesive A, a disperse phase D and a continuous phase A.
Comparative example 3:
the stone-like paint consists of 5% of protective adhesive A, a dispersed phase A and a continuous phase D.
Comparative example 4:
the stone-like paint consists of 5% of protective adhesive A, a dispersed phase A and a continuous phase E.
The batch-scraping type stone-like paint and the stone-like paint of the examples 1-7 and the comparative examples 1-4 are respectively taken, 5% of protective glue, the dispersed phase and the continuous phase are mixed according to the mass ratio of 3:13:4, batch scraping can be carried out after uniform mixing, and the coating type artistic wall surface is prepared. The wall art of hanging type prepared in examples 1 to 7 is shown in FIGS. 1 to 7. Whether the batch scraping process generates paste breaking or not and the amount of paste breaking are recorded, and the results are shown in Table 3. Wherein, a small amount of paste breaking still can show the original stone-like effect, but the effect is not good, and a large amount of paste breaking basically can not show the stone-like effect.
TABLE 3
No broken paste Small amount of broken paste Breaking into paste in large amount
Example 1 √ × ×
Example 2 √ × ×
Example 3 √ × ×
Example 4 √ × ×
Example 5 √ × ×
Examples6 √ × ×
Example 7 √ × ×
Comparative example 1 × √ ×
Comparative example 2 × × √
Comparative example 3 × √ ×
Comparative example 4 × √ ×
In conclusion, the batch-scraping type stone-like paint provided by the invention can be constructed by using a batch-scraping process, wherein the stone-like paint is prepared by adopting 5% of protective glue, a dispersion phase and a continuous phase, and color points in the paint can be wrapped in a high-toughness structure formed by the dispersion phase and the continuous phase after the hydroxyethyl cellulose and the ST-1F gel are specifically added in the dispersion phase and the continuous phase and the protective glue, so that the problem of paste breaking can not occur even in batch scraping operation, and the problems of easiness in influence of air pressure stability in spraying construction and noise generated in spraying construction can be effectively avoided.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all equivalent changes made by using the contents of the present specification and the drawings, or applied directly or indirectly to the related technical fields, are included in the scope of the present invention.

Claims (5)

1. The batch-scraping type stone-like paint is characterized by comprising 5% of protective glue, a dispersion phase and a continuous phase;
the 5% protective glue consists of 5% of ST532S protective glue powder, 0.2% of preservative and 94.8% of water in percentage by weight;
the dispersed phase comprises, by weight, 4-8 parts of hydroxyethyl cellulose, 1-2 parts of a defoaming agent, 8-12 parts of a film-forming aid, 5-8 parts of ethylene glycol, 25-35 parts of titanium dioxide, 50-70 parts of kaolin, 15-25 parts of ST-1F gel, 150-200 parts of anionic styrene-acrylic emulsion, 1-3 parts of AMP95, 2-4 parts of a preservative, 550 parts of 100-mesh snow white and 650-700 parts of water;
the continuous phase comprises a film forming aid, ethylene glycol, AMP95, a defoaming agent, a silicone-acrylate emulsion with a nano particle size, a KZ125 thickening emulsion, a thixotropic agent, a preservative and water.
2. The stone-like paint as claimed in claim 1, wherein the continuous phase comprises, by weight, 30-38 parts of a film-forming aid, 10-15 parts of ethylene glycol, 1-3 parts of AMP95, 2-4 parts of a defoaming agent, 480 parts of a silicone-acrylic emulsion with a nano particle size, 160 parts of KZ125 thickening emulsion with 140-25 parts of a thixotropic agent, 1-3 parts of a preservative, and 380 parts of water with 320-380 parts of a surfactant.
3. The batch-scraped stone-like paint according to claim 1, wherein the film-forming additive is twelve alcohol esters in the continuous phase, the defoamer is ST2410, the preservative is LXE preservative, and the thixotropic agent is a real stone paint thixotropic agent of a new sea vast material.
4. The batch-scraping stone-like paint as claimed in claim 1, wherein in the dispersed phase, the hydroxyethyl cellulose is HS100000 cellulose, the film-forming aid is alcohol ester twelve, the defoamer is ST2410, the titanium pigment is R251 titanium pigment, the kaolin is 4000-mesh calcined kaolin, the snow white is 100-mesh snow white, and the preservative is LXE preservative.
5. A batch-scraping type stone-like paint as claimed in any one of claims 1 to 4, which is applied to the preparation of batch-scraping type artistic wall surface.
CN202011294228.8A 2020-11-18 2020-11-18 Batch scraping type stone-like paint and application thereof Active CN112300650B (en)

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TW200621534A (en) * 2004-12-24 2006-07-01 Chuang-Yung Chiou Method for making desired stone painting source material
CN103254710B (en) * 2013-04-11 2016-12-28 三棵树涂料股份有限公司 A kind of batch of scratch-type water-in-water multicolor coating and preparation method thereof
CN107162486A (en) * 2017-06-06 2017-09-15 厦门富思特新材料科技有限公司 A kind of true mineral varnish of reflective insulation trowelling and preparation method thereof
CN109777223A (en) * 2018-12-26 2019-05-21 中华制漆（深圳）有限公司 Colorful stone-like coating and preparation method thereof
CN110903721A (en) * 2019-06-29 2020-03-24 江苏七点建材有限公司 Colorful sand-in-water coating and preparation method thereof

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