CN112245333A - Solid-state paper-support-free extension adhesive and preparation method and use method thereof - Google Patents
Solid-state paper-support-free extension adhesive and preparation method and use method thereof Download PDFInfo
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- CN112245333A CN112245333A CN202011211089.8A CN202011211089A CN112245333A CN 112245333 A CN112245333 A CN 112245333A CN 202011211089 A CN202011211089 A CN 202011211089A CN 112245333 A CN112245333 A CN 112245333A
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- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000000853 adhesive Substances 0.000 title claims abstract description 12
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 39
- 239000000843 powder Substances 0.000 claims abstract description 29
- 238000003756 stirring Methods 0.000 claims abstract description 23
- 239000000178 monomer Substances 0.000 claims abstract description 19
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims abstract description 13
- 229920013730 reactive polymer Polymers 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 210000000282 nail Anatomy 0.000 claims description 34
- 239000003292 glue Substances 0.000 claims description 30
- 229920002635 polyurethane Polymers 0.000 claims description 27
- 239000004814 polyurethane Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 24
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 17
- 239000002981 blocking agent Substances 0.000 claims description 14
- 125000001931 aliphatic group Chemical group 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims description 9
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 claims description 6
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 3
- 244000028419 Styrax benzoin Species 0.000 claims description 3
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 3
- 229960002130 benzoin Drugs 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 3
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 235000019382 gum benzoic Nutrition 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 210000004905 finger nail Anatomy 0.000 claims description 2
- QFXCGXNPCMKTJQ-UHFFFAOYSA-N prop-2-enoic acid;1,1,3-trimethylcyclohexane Chemical compound OC(=O)C=C.CC1CCCC(C)(C)C1 QFXCGXNPCMKTJQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000009966 trimming Methods 0.000 claims description 2
- 239000004809 Teflon Substances 0.000 claims 1
- 229920006362 Teflon® Polymers 0.000 claims 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical class [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 206010006784 Burning sensation Diseases 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Paper (AREA)
Abstract
A solid-state paper support-free extension adhesive, a preparation method and a use method thereof are disclosed, and the adhesive is composed of the following raw materials in parts by mass: firstly, stirring and mixing the acrylate resin, the acrylate active monomer and the photoinitiator, then sequentially adding the reactive polymer micro powder, the acrylic micro powder and the cellulose acetate butyrate, uniformly stirring, adding the thickener and the anti-adhesion agent, and stirring for 2-30 min until all components are uniformly mixed; finally, removing air bubbles to obtain a finished product. The invention has high viscosity, no flow, no paper support operation, high transparency after curing, low smell, good toughness, high hardness, no easy fracture, simple operation, no sticking to pens, easy operation for individual users, and good curing performance, and can be added with high proportion of color paste, and the color is colorful and rich.
Description
Technical Field
The invention belongs to the technical field of chemical industry adhesion product cosmetics, and particularly relates to a solid-state paper-support-free extension glue, and a preparation method and a use method thereof.
Background
Definition of extension glue: a high-consistency, high-transparency gel with artificial nail effect after photocuring.
Through the development of years, the light-cured gel replaces the traditional nail polish, the types of the light-cured gel are more and more abundant, the patterns and styles are more and more diversified, and ornaments such as diamond ornaments are also more and more diversified.
The original extension glue is made by using monomer stained crystal powder, the extension effect can be achieved by brushing and adding powder for multiple times, but the operation process is complicated, the consumed time is long, the made artificial nail has granular feel, the color selectivity is low, the artificial nail can not be mixed with color generally, the color only depends on the color of the crystal powder, the made artificial nail is thick, and the proper thickness can be achieved by polishing for multiple times. Later, with the development of light-cured gel, light-cured extension gel is provided, and compared with the extension by utilizing crystal powder, the light-cured extension gel has high efficiency, rich color and controllable thickness, but the defects also exist, firstly, bubbles are easy to generate in the operation process, and the technical requirements on operators are higher; secondly, the colloid is easy to flow, the coating and curing are required to be completed in a short time by using a paper support for extension, otherwise, the colloid is easy to flow to two parts, so that the thickness of the whole nail surface is different, and the appearance is influenced; thirdly, the heat release is large when the colloid is solidified, and the burning sensation is serious; and fourthly, the workpiece is not easy to detach, and the workpiece needs to be repeatedly polished in the detaching process.
Disclosure of Invention
In order to solve the technical problems, the invention provides a solid-state paper-support-free extension adhesive, and a preparation method and a use method thereof.
In order to solve the technical problems, the invention adopts the following technical scheme:
the solid paper support-free extension glue is composed of the following raw materials in parts by mass:
30-60% of acrylate resin, 10-20% of acrylate active monomer, 1-5% of photoinitiator, 10-20% of reactive polymer micro powder, 10-20% of acrylic micro powder, 1-5% of cellulose acetate butyrate, 1-5% of thickener and 1-5% of anti-blocking agent.
The acrylate resin is composed of aliphatic polyurethane acrylate, polyester acrylate, polyurethane modified acrylate or hyperbranched polyurethane modified acrylate; wherein the mass fraction of the aliphatic polyurethane acrylate is 15-25%, the mass fraction of the polyester acrylate is 5-15%, the mass fraction of the polyurethane modified acrylate is 5-15%, and the mass fraction of the hyperbranched polyurethane modified acrylate is 5-15%.
The acrylate active monomer is one or more of hydroxyethyl methacrylate, dodecyl acrylate, 3,3, 5-trimethylcyclohexane acrylate and 1, 6-ethylene glycol dimethacrylate in any combination.
The acrylate active monomer is a mixture of dodecyl acrylate and 1, 6-hexanediol dimethacrylate, wherein the mass fraction of the dodecyl acrylate is 10%, and the mass fraction of the 1, 6-hexanediol dimethacrylate is 6%.
The photoinitiator is one or more of 1-hydroxy-cyclohexyl-phenyl ketone, benzoin dimethyl ether, 2,4, 6-trimethylbenzoyl-diphenyl phosphine oxide and benzophenone in any combination.
The mass fraction of the reactive polymer micro powder is 12%, the mass fraction of the acrylic micro powder is 15%, and the mass fraction of the cellulose acetate butyrate is 3%.
The thickening agent is one or two of modified silicon powder and polyamide wax.
The anti-blocking agent is one or a plurality of random combinations of PP wax, PE wax and polytetrafluoroethylene wax.
A preparation method of a solid-state paper-support-free extension adhesive comprises the following steps:
s101, firstly, stirring and mixing acrylate resin, an acrylate active monomer and a photoinitiator, heating to 40-50 ℃, and stirring for 40-50 min at 1000-1500 r/min to obtain a mixture;
s102, adding the reactive polymer micro powder, the acrylic micro powder and the cellulose acetate butyrate into the mixture obtained in the step S101 in sequence, and stirring for 80-90 min;
s103, sequentially adding a thickening agent and an anti-blocking agent into the mixture obtained in the step S102, and stirring for 2-30 min until all the components are uniformly mixed;
and S104, finally, removing bubbles from the uniformly mixed mixture in the step S103 to obtain a finished product.
A method of using a solid form of a paper-free extension gel for use as a nail polish gel, comprising the steps of:
s201, removing dead skin around the nail, and polishing the surface of the nail by using a rubbing strip until the surface of the nail is rough and dull;
s202, cleaning grease on the surface of the fingernail and polished dust;
s203, coating a layer of primer on the surface of the nail, and drying for 60S by using a UV lamp;
s204, uniformly coating a layer of solid-state paper-support-free extension glue with uniform thickness on the transparent nail model, selecting a color drawing pen to dip gel water according to needs, then flattening and molding the extension glue, inversely buckling the processed nail model on the nail coated with primer, and then drying for 60S by using a UV lamp;
s205, removing the transparent nail model, trimming and polishing the cured solid paper-support-free extension glue and cleaning dust;
and S206, finally coating a sealing layer, and drying for 60S by using a UV lamp to finish.
Compared with the traditional extension adhesive, the extension adhesive prepared by the invention has the advantages of high viscosity, no flowing, no paper support operation, high transparency after curing, low smell, good toughness, high hardness, difficult fracture, simple operation, no sticking to a pen, easy operation for an individual user, good curing performance, capability of adding high-proportion color paste and colorful and rich color.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to further understand the features and technical means of the invention and achieve specific objects and functions.
Example one
The solid paper support-free extension glue is composed of the following raw materials in parts by mass:
30% of acrylate resin, 20% of acrylate active monomer, 5% of photoinitiator, 15% of reactive polymer micro powder, 15% of acrylic micro powder, 5% of cellulose acetate butyrate, 5% of thickening agent and 5% of anti-blocking agent, wherein the total amount is 100%, namely the proportion of each component in the whole mass.
The acrylate resin is composed of aliphatic polyurethane acrylate, polyester acrylate, polyurethane modified acrylate or hyperbranched polyurethane modified acrylate; wherein the mass fraction of the aliphatic polyurethane acrylate is 15%, the mass fraction of the polyester acrylate is 5%, the mass fraction of the polyurethane modified acrylate is 5%, the mass fraction of the hyperbranched polyurethane modified acrylate is 5%, and the total mass fraction is 30%, which is the mass ratio of the acrylate resin, namely the mass ratio of the components in the whole extension glue.
The acrylate active monomer is hydroxyethyl methacrylate. The photoinitiator is 1-hydroxy-cyclohexyl-phenyl ketone. The thickening agent is modified silicon micropowder. The anti-blocking agent is PP wax.
In the specific preparation, the method comprises the following steps:
s101, firstly, stirring and mixing the acrylate resin, the acrylate active monomer and the photoinitiator, heating to 40 ℃, and stirring for 50min at 1500r/min to obtain a mixture.
S102, adding the reactive polymer micro powder, the acrylic micro powder and the cellulose acetate butyrate into the mixture obtained in the step S101 in sequence, and stirring for 90 min.
And S103, sequentially adding the thickening agent and the anti-blocking agent into the mixture obtained in the step S102, and stirring for 20min until all the components are uniformly mixed.
And S104, finally, removing bubbles from the uniformly mixed mixture in the step S103 to obtain a finished product.
The components are added and stirred in sequence and mixed uniformly, so that the extension glue can be obtained.
The paper support-free extension adhesive prepared by the invention is mainly used as nail glue, and the specific use method comprises the following steps:
s201, removing dead skin around the nail, and polishing the surface of the nail by using a rubbing strip until the surface of the nail is rough and dull.
S202, cleaning grease on the surface of the nail and the polished dust.
S203, coating a layer of primer on the surface of the nail, and drying for 60S by using a UV lamp.
S204, uniformly coating a layer of solid-state paper-support-free extension glue with uniform thickness on the transparent nail model, dipping gel water by a color drawing pen according to needs, then flattening and molding the extension glue, inversely buckling the processed nail model on the nail coated with the primer, and then drying for 60S by using a UV lamp.
S205, the transparent nail model is removed, the solidified solid paper-free extension glue is trimmed and polished, and dust is cleaned.
And S206, finally coating a sealing layer, and drying for 60S by using a UV lamp to finish.
Example two
The solid paper support-free extension glue is composed of the following raw materials in parts by mass:
34% of acrylate resin, 16% of acrylate active monomer, 5% of photoinitiator, 15% of reactive polymer micro powder, 15% of acrylic micro powder, 5% of cellulose acetate butyrate, 5% of thickening agent and 5% of anti-blocking agent, wherein the total amount is 100%, namely the proportion of each component in the whole mass.
The acrylate resin is composed of aliphatic polyurethane acrylate, polyester acrylate, polyurethane modified acrylate or hyperbranched polyurethane modified acrylate; wherein the mass fraction of the aliphatic polyurethane acrylate is 16%, the mass fraction of the polyester acrylate is 6%, the mass fraction of the polyurethane modified acrylate is 6%, the mass fraction of the hyperbranched polyurethane modified acrylate is 6%, and the total mass fraction is 34%, which is the mass ratio of the acrylate resin, namely the mass ratio of the components in the whole extension glue.
The acrylate active monomer is a mixture of dodecyl acrylate and 1, 6-hexanediol dimethacrylate, wherein the mass fraction of the dodecyl acrylate is 10%, the mass fraction of the 1, 6-hexanediol dimethacrylate is 6%, and the mass fraction is the proportion of the total mass of the whole extension adhesive composition. The photoinitiator is benzoin dimethyl ether. The thickening agent is polyamide wax. The anti-blocking agent is PE wax.
In the specific preparation, the method comprises the following steps:
s101, firstly, stirring and mixing the acrylate resin, the acrylate active monomer and the photoinitiator, heating to 45 ℃, and stirring for 45min at 1100r/min to obtain a mixture.
S102, adding the reactive polymer micro powder, the acrylic micro powder and the cellulose acetate butyrate into the mixture obtained in the step S101 in sequence, and stirring for 85 min.
And S103, sequentially adding the thickening agent and the anti-blocking agent into the mixture obtained in the step S102, and stirring for 30min until all the components are uniformly mixed.
And S104, finally, removing bubbles from the uniformly mixed mixture in the step S103 to obtain a finished product.
The components are added and stirred in sequence and mixed uniformly, so that the extension glue can be obtained, and the specific use method is consistent with that of the embodiment.
EXAMPLE III
The solid paper support-free extension glue is composed of the following raw materials in parts by mass:
50% of acrylate resin, 10% of acrylate active monomer, 5% of photoinitiator, 12% of reactive polymer micro powder, 15% of acrylic micro powder, 3% of cellulose acetate butyrate, 2% of thickening agent and 3% of anti-blocking agent, wherein the total amount is 100%, namely the proportion of each component in the whole mass.
The acrylate resin is composed of aliphatic polyurethane acrylate, polyester acrylate, polyurethane modified acrylate or hyperbranched polyurethane modified acrylate; wherein the mass fraction of the aliphatic polyurethane acrylate is 20%, the mass fraction of the polyester acrylate is 10%, the mass fraction of the polyurethane modified acrylate is 10%, the mass fraction of the hyperbranched polyurethane modified acrylate is 10%, and the total mass fraction is 50%, which is the mass ratio of the acrylate resin, namely the mass ratio of the components in the whole extension glue.
The acrylate active monomer is hydroxyethyl methacrylate, dodecyl acrylate, 3, 5-trimethylcyclohexane acrylate, 1, 6-ethylene glycol dimethacrylate and a combination thereof. The photoinitiator is a combination of 2,4, 6-trimethylbenzoyl-diphenylphosphine oxide and benzophenone. The thickening agent is the combination of modified silicon powder and polyamide wax. The anti-adhesion agent is a combination of PP wax, PE wax and polytetrafluoroethylene wax.
In the specific preparation, the method comprises the following steps:
s101, firstly, stirring and mixing the acrylate resin, the acrylate active monomer and the photoinitiator, heating to 50 ℃, and stirring for 40min at 1500r/min to obtain a mixture.
S102, adding the reactive polymer micro powder, the acrylic micro powder and the cellulose acetate butyrate into the mixture obtained in the step S101 in sequence, and stirring for 80 min.
And S103, sequentially adding the thickening agent and the anti-blocking agent into the mixture obtained in the step S102, and stirring for 25min until all the components are uniformly mixed.
And S104, finally, removing bubbles from the uniformly mixed mixture in the step S103 to obtain a finished product.
The components are added and stirred in sequence and mixed uniformly, so that the extension glue can be obtained, and the specific use method is consistent with that of the embodiment.
Although the present invention has been described in detail with reference to the embodiments, it will be apparent to those skilled in the art that modifications, equivalents, improvements, and the like can be made in the technical solutions of the foregoing embodiments or in some of the technical features of the foregoing embodiments, but those modifications, equivalents, improvements, and the like are all within the spirit and principle of the present invention.
Claims (10)
1. The solid paper-support-free extension adhesive is characterized by comprising the following raw materials in parts by mass:
30-60% of acrylate resin, 10-20% of acrylate active monomer, 1-5% of photoinitiator, 10-20% of reactive polymer micro powder, 10-20% of acrylic micro powder, 1-5% of cellulose acetate butyrate, 1-5% of thickener and 1-5% of anti-blocking agent.
2. The solid form paperless holdout extension glue of claim 1, wherein the acrylate-based resin is comprised of aliphatic urethane acrylate, polyester acrylate, urethane-modified acrylate, or hyperbranched urethane-modified acrylate; wherein the mass fraction of the aliphatic polyurethane acrylate is 15-25%, the mass fraction of the polyester acrylate is 5-15%, the mass fraction of the polyurethane modified acrylate is 5-15%, and the mass fraction of the hyperbranched polyurethane modified acrylate is 5-15%.
3. The solid-state paper-free extension glue of claim 1, wherein the acrylate reactive monomer is one or more of hydroxyethyl methacrylate, dodecyl acrylate, 3,3, 5-trimethylcyclohexane acrylate and 1, 6-ethylene glycol dimethacrylate.
4. The solid form paper-free extension glue of claim 3, wherein the acrylate reactive monomer is a mixture of dodecyl acrylate and 1, 6-hexanediol dimethacrylate, wherein the mass fraction of dodecyl acrylate is 10% and the mass fraction of 1, 6-hexanediol dimethacrylate is 6%.
5. The solid form paper-free extension adhesive according to claim 1, wherein the photoinitiator is one or more of 1-hydroxy-cyclohexyl-phenyl ketone, benzoin dimethyl ether, 2,4, 6-trimethylbenzoyl-diphenyl phosphine oxide and benzophenone in any combination.
6. The solid form paper-free extension glue of claim 1, wherein the mass fraction of the reactive polymer micropowder is 12%, the mass fraction of the acrylic micropowder is 15%, and the mass fraction of the cellulose acetate butyrate is 3%.
7. The solid form release paper extension glue of claim 1, wherein the thickener is one or a combination of modified silica powder and polyamide wax.
8. The solid form release paper stock extension glue of claim 1, wherein the anti-blocking agent is one or more of PP wax, PE wax and teflon wax in any combination.
9. A method of preparing a solid form paperless holdout extending glue according to any of claims 1-8, comprising the steps of:
s101, firstly, stirring and mixing acrylate resin, an acrylate active monomer and a photoinitiator, heating to 40-50 ℃, and stirring for 40-50 min at 1000-1500 r/min to obtain a mixture;
s102, adding the reactive polymer micro powder, the acrylic micro powder and the cellulose acetate butyrate into the mixture obtained in the step S101 in sequence, and stirring for 80-90 min;
s103, sequentially adding a thickening agent and an anti-blocking agent into the mixture obtained in the step S102, and stirring for 2-30 min until all the components are uniformly mixed;
and S104, finally, removing bubbles from the uniformly mixed mixture in the step S103 to obtain a finished product.
10. A method of using the solid form paper-free extension gel of any of claims 1-8 as a nail polish gel, comprising the steps of:
s201, removing dead skin around the nail, and polishing the surface of the nail by using a rubbing strip until the surface of the nail is rough and dull;
s202, cleaning grease on the surface of the fingernail and polished dust;
s203, coating a layer of primer on the surface of the nail, and drying for 60S by using a UV lamp;
s204, uniformly coating a layer of solid-state paper-support-free extension glue with uniform thickness on the transparent nail model, selecting a color drawing pen to dip gel water according to needs, then flattening and molding the extension glue, inversely buckling the processed nail model on the nail coated with primer, and then drying for 60S by using a UV lamp;
s205, removing the transparent nail model, trimming and polishing the cured solid paper-support-free extension glue and cleaning dust;
and S206, finally coating a sealing layer, and drying for 60S by using a UV lamp to finish.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011211089.8A CN112245333A (en) | 2020-11-03 | 2020-11-03 | Solid-state paper-support-free extension adhesive and preparation method and use method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011211089.8A CN112245333A (en) | 2020-11-03 | 2020-11-03 | Solid-state paper-support-free extension adhesive and preparation method and use method thereof |
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| CN112245333A true CN112245333A (en) | 2021-01-22 |
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| CN202011211089.8A Pending CN112245333A (en) | 2020-11-03 | 2020-11-03 | Solid-state paper-support-free extension adhesive and preparation method and use method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113520917A (en) * | 2021-07-29 | 2021-10-22 | 广州高丽蔻生物科技有限公司 | Solid color oil glue and preparation method thereof |
| CN113749956A (en) * | 2021-08-02 | 2021-12-07 | 肇庆市宝骏化工有限公司 | Quick nail lengthening glue |
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| CN110384638A (en) * | 2019-08-07 | 2019-10-29 | 河源然生新材料有限公司 | A kind of Japanese color factice of high-performance and its production, application method |
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| CN109528553A (en) * | 2018-11-08 | 2019-03-29 | 安徽省明睿合成材料有限公司 | Nail lengthening glue and preparation method thereof and solidification demoulding application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113520917A (en) * | 2021-07-29 | 2021-10-22 | 广州高丽蔻生物科技有限公司 | Solid color oil glue and preparation method thereof |
| CN113749956A (en) * | 2021-08-02 | 2021-12-07 | 肇庆市宝骏化工有限公司 | Quick nail lengthening glue |
| CN113749956B (en) * | 2021-08-02 | 2023-10-17 | 肇庆市宝骏化工有限公司 | Quick nail extension adhesive |
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Application publication date: 20210122 |