CN112226133A - Antiskid marble-imitated coating for colored pavement - Google Patents
Antiskid marble-imitated coating for colored pavement Download PDFInfo
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- CN112226133A CN112226133A CN202011016264.8A CN202011016264A CN112226133A CN 112226133 A CN112226133 A CN 112226133A CN 202011016264 A CN202011016264 A CN 202011016264A CN 112226133 A CN112226133 A CN 112226133A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an antiskid marble-imitated coating for a colored pavement, which belongs to the technical field of coatings and comprises the following components in parts by weight: 50-60 parts of methyl methacrylate resin, 0.1-0.2 part of wetting agent, 15-20 parts of colored sintered sand, 20-30 parts of triple superphosphate, 0.2-0.4 part of dispersing agent, 0.3-0.7 part of anti-settling agent, 5-8 parts of colored pigment and 0.5-1.5 parts of BPO curing agent. The invention has the advantages of oxidation resistance, water resistance, oil resistance, good durability, low temperature resistance of minus 40 ℃ and high temperature resistance of 90 ℃, long service life, no VOC solvent and low volatility, and belongs to an environment-friendly material.
Description
Technical Field
The invention relates to a colored sintered sand coating and a preparation method thereof, in particular to a colored pavement anti-skid marble-imitated coating, belonging to the technical field of coatings.
Background
The existing outdoor color pavement material mostly adopts outdoor weather-resistant MMA (methyl methacrylate) antiskid paint, weather-resistant resin methacrylic resin and BPO (bis-phenol-butyl-phenol) curing agent are adopted to achieve anaerobic reaction through polymerization reaction free radicals to form a film-forming surface material, the pigment color of the material is well protected to enable the color of the material to be kept for a long time due to the weather-resistant resin methacrylic resin, and after the weather-resistant resin methacrylic resin reacts, the surface is matt, and a color sintered sand material added in the paint enables the material to have good antiskid property and attractive appearance, so that the paint can be used in occasions such as outdoor squares instead of attractive epoxy color sintered sand and PVC glue floors.
The existing anti-skid marble-imitated coating for the colored pavement has the following defects: (1) the existing anti-skid marble-imitated coating for the colored pavement wastes materials in the using process and increases the cost; (2) the existing antiskid marble-imitated coating for the colored pavement has poor permeability and high decolorization rate in the actual production process.
Disclosure of Invention
The invention mainly aims to solve the defects of the prior art and provide the colored anti-skid marble-imitated coating for the road surface.
The purpose of the invention can be achieved by adopting the following technical scheme:
the anti-skid marble-imitated coating for the colored pavement comprises the following components in parts by weight: 50-60 parts of methyl methacrylate resin, 0.1-0.2 part of wetting agent, 15-20 parts of colored sintered sand, 20-30 parts of triple superphosphate, 0.2-0.4 part of dispersing agent, 0.3-0.7 part of anti-settling agent, 5-8 parts of colored pigment and 0.5-1.5 parts of BPO curing agent.
Preferably, the composition comprises the following components in parts by weight: 52-60 parts of methyl methacrylate resin, 0.1-0.2 part of wetting agent, 16-20 parts of color sintering sand, 23-30 parts of heavy calcium carbonate, 0.2-0.4 part of dispersing agent, 0.3-0.6 part of anti-settling agent, 5-8 parts of color pigment and 0.5-1.3 parts of BPO curing agent.
Preferably, the composition comprises the following components in parts by weight: 55 parts of methyl methacrylate resin, 0.1 part of wetting agent, 17 parts of colored sintered sand, 25 parts of triple superphosphate, 0.3 part of dispersing agent, 0.5 part of anti-settling agent, 5 parts of colored pigment and 0.7 part of BPO curing agent.
Preferably, the wetting agent is a mixture of sodium dodecyl benzene sulfonate and tween 60.
Preferably, the granularity of the colored sintering sand after being crushed and screened by a crusher is 100-150 meshes.
Preferably, the dispersant is a mixture of guar gum, polyaspartic acid and petroleum sulfonic acid.
Preferably, the anti-settling agent is a mixture of isomeric tridecanol polyoxyethylene ether, behenyl alcohol polyoxyethylene ether, glycerin and water.
Preferably, the concentration of the BPO curing agent is 30-40%.
A preparation method of the anti-skid marble-imitated coating for the colored pavement comprises the following steps:
step 1: adding 50 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 min;
step 2: adding 0.1 part of wetting agent;
and step 3: adding 5 parts of color pigment, and stirring for 5 min;
and 4, step 4: adding 0.3 part of dispersant into the mixture and stirring the mixture;
and 5: adding 17 parts of colored sintered sand and 25 parts of heavy calcium into the mixture respectively, quickly stirring the mixture for 20min, and adding 0.5 part of anti-settling agent into the mixture during stirring.
The invention has the beneficial technical effects that: according to the colored road surface anti-skid marble-imitated coating, by combining the components and the component proportions, the attractiveness, weather resistance and skid resistance of the outdoor weather-resistant MMA anti-skid coating in the use of outdoor road surfaces are effectively enhanced, the coating is not easy to fall off, resistant to pressure and wear resistant, the main component methyl methacrylate resin is high in weather resistance and bright and durable in color, colored sintered sand can effectively float to the surface of the coating, the color of particles is obvious and attractive, meanwhile, the wear resistance and skid resistance are enhanced, the curing agent can be rapidly cured at normal temperature, a wear-resistant and flexible solid material is obtained, the road surface coating has oxidation resistance, is waterproof, oil-proof, good in durability, resistant to low temperature of minus 40 ℃ and high temperature of 90 ℃, long in service life, free of VOC solvents and low in volatility, and belongs to an environment-friendly material.
Detailed Description
In order to make the technical solutions of the present invention more clear and definite for those skilled in the art, the present invention is further described in detail with reference to the following examples, but the embodiments of the present invention are not limited thereto.
The colored pavement anti-skid marble-imitated coating provided by the embodiment comprises the following components in parts by weight: 50-60 parts of methyl methacrylate resin, 0.1-0.2 part of wetting agent, 15-20 parts of colored sintered sand, 20-30 parts of triple superphosphate, 0.2-0.4 part of dispersing agent, 0.3-0.7 part of anti-settling agent, 5-8 parts of colored pigment and 0.5-1.5 parts of BPO curing agent.
Comprises the following components in parts by weight: 52-60 parts of methyl methacrylate resin, 0.1-0.2 part of wetting agent, 16-20 parts of color sintering sand, 23-30 parts of heavy calcium carbonate, 0.2-0.4 part of dispersing agent, 0.3-0.6 part of anti-settling agent, 5-8 parts of color pigment and 0.5-1.3 parts of BPO curing agent.
Comprises the following components in parts by weight: 55 parts of methyl methacrylate resin, 0.1 part of wetting agent, 17 parts of colored sintered sand, 25 parts of triple superphosphate, 0.3 part of dispersing agent, 0.5 part of anti-settling agent, 5 parts of colored pigment and 0.7 part of BPO curing agent.
The wetting agent is prepared by mixing sodium dodecyl benzene sulfonate and tween 60. The granularity of the colored sintering sand after being crushed and screened by a crusher is 100-150 meshes. The dispersant is a mixture of gulch gum, polyaspartic acid and petroleum sulfonic acid. The anti-settling agent is a mixture of isomeric tridecanol polyoxyethylene ether, behenyl alcohol polyoxyethylene ether, glycerin and water. The concentration of the BPO curing agent is 30-40%.
A preparation method of the anti-skid marble-imitated coating for the colored pavement comprises the following steps:
step 1: adding 50 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 minutes;
step 2: adding 0.1 part of wetting agent;
and step 3: adding 5 parts of color pigment, and stirring for 5 minutes;
and 4, step 4: adding 0.3 part of dispersant into the mixture and stirring the mixture;
and 5: adding 17 parts of colored sintered sand and 25 parts of heavy calcium carbonate respectively, quickly stirring for 20 minutes, and adding 0.5 part of anti-settling agent during stirring.
Example 1:
the anti-skid marble-imitated coating for the colored pavement comprises the following components in parts by weight: 50 parts of methyl methacrylate resin, 0.1 part of wetting agent, 15 parts of colored sintered sand, 20 parts of heavy calcium carbonate, 0.2 part of dispersing agent, 0.3 part of anti-settling agent, 5 parts of colored pigment and 0.5 part of BPO curing agent.
A preparation method of the anti-skid marble-imitated coating for the colored pavement comprises the following steps:
step 1: adding 50 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 minutes;
step 2: adding 0.1 part of wetting agent;
and step 3: adding 5 parts of color pigment, and stirring for 5 minutes;
and 4, step 4: adding 0.2 part of dispersant into the mixture and stirring the mixture;
and 5: respectively adding 15 parts of colored sintered sand and 20 parts of heavy calcium carbonate, quickly stirring for 20 minutes, and adding 0.3 part of anti-settling agent during stirring.
Example 2:
the anti-skid marble-imitated coating for the colored pavement comprises the following components in parts by weight: 52 parts of methyl methacrylate resin, 0.1 part of wetting agent, 16 parts of colored sintered sand, 22 parts of heavy calcium carbonate, 0.3 part of dispersing agent, 0.4 part of anti-settling agent, 6 parts of colored pigment and 0.7 part of BPO curing agent.
A preparation method of the anti-skid marble-imitated coating for the colored pavement comprises the following steps:
step 1: adding 52 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 minutes;
step 2: adding 0.1 part of wetting agent;
and step 3: adding 6 parts of color pigment, and stirring for 5 minutes;
and 4, step 4: adding 0.3 part of dispersant into the mixture and stirring the mixture;
and 5: respectively adding 16 parts of colored sintered sand and 22 parts of heavy calcium carbonate, quickly stirring for 20 minutes, and adding 0.4 part of anti-settling agent during stirring.
Example 3:
the anti-skid marble-imitated coating for the colored pavement comprises the following components in parts by weight: 55 parts of methyl methacrylate resin, 0.1 part of wetting agent, 17 parts of colored sintered sand, 25 parts of triple superphosphate, 0.3 part of dispersing agent, 0.5 part of anti-settling agent, 5 parts of colored pigment and 0.7 part of BPO curing agent.
A preparation method of the anti-skid marble-imitated coating for the colored pavement comprises the following steps:
step 1: adding 50 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 minutes;
step 2: adding 0.1 part of wetting agent;
and step 3: adding 5 parts of color pigment, and stirring for 5 minutes;
and 4, step 4: adding 0.3 part of dispersant into the mixture and stirring the mixture;
and 5: adding 17 parts of colored sintered sand and 25 parts of heavy calcium carbonate respectively, quickly stirring for 20 minutes, and adding 0.5 part of anti-settling agent during stirring.
Example 4:
the anti-skid marble-imitated coating for the colored pavement comprises the following components in parts by weight: 58 parts of methyl methacrylate resin, 0.18 part of wetting agent, 19 parts of colored sintered sand, 28 parts of heavy calcium carbonate, 0.3 part of dispersing agent, 0.6 part of anti-settling agent, 7 parts of colored pigment and 1.4 parts of BPO curing agent.
A preparation method of the anti-skid marble-imitated coating for the colored pavement comprises the following steps:
step 1: adding 58 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 minutes;
step 2: adding 0.18 part of wetting agent;
and step 3: adding 7 parts of color pigment, and stirring for 5 minutes;
and 4, step 4: adding 0.3 part of dispersant into the mixture and stirring the mixture;
and 5: adding 17 parts of colored sintered sand and 25 parts of heavy calcium carbonate respectively, quickly stirring for 20 minutes, and adding 0.5 part of anti-settling agent during stirring.
Example 5:
the anti-skid marble-imitated coating for the colored pavement comprises the following components in parts by weight: 60 parts of methyl methacrylate resin, 0.2 part of wetting agent, 20 parts of colored sintered sand, 30 parts of triple superphosphate, 0.4 part of dispersing agent, 0.7 part of anti-settling agent, 8 parts of colored pigment and 1.5 parts of BPO curing agent.
A preparation method of the anti-skid marble-imitated coating for the colored pavement comprises the following steps:
step 1: adding 60 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 minutes;
step 2: adding 0.2 part of wetting agent;
and step 3: adding 8 parts of color pigment, and stirring for 5 minutes;
and 4, step 4: adding 0.4 part of dispersant into the mixture and stirring the mixture;
and 5: and respectively adding 20 parts of colored sintered sand and 30 parts of heavy calcium, quickly stirring for 20 minutes, and adding 0.7 part of anti-settling agent during stirring.
In summary, in this embodiment, according to the color road surface anti-skid marble-imitated coating of this embodiment, the color road surface anti-skid marble-imitated coating provided in this embodiment, and the application of the coating, the BPO curing agent is proportionally added into the outdoor weather-resistant MMA anti-skid coating, and the mixture is quickly stirred for 1 minute, and the stirred material is poured onto the cleaned base asphalt or concrete surface and quickly leveled with a spatula or a roller. It can be seen from examples 1 to 5 that the colored road surface anti-skid marble-imitated coating prepared in example 4 has a long service life, and through the combination of the above components and the component ratios, the aesthetic property, weather resistance, skid resistance, difficult shedding, compression resistance and wear resistance of the outdoor weather-resistant MMA anti-skid coating in the use of outdoor road surfaces are effectively enhanced, the main component of methyl methacrylate resin has strong weather resistance and bright and durable color, the colored sintered sand can effectively float on the surface of the coating, the color of the particles is obvious and beautiful, and the wear resistance and skid resistance are enhanced, and the curing agent can be rapidly cured at normal temperature to obtain a wear-resistant and flexible solid material. The pavement coating disclosed by the invention has the advantages of oxidation resistance, water resistance, oil resistance, good durability, low temperature resistance of minus 40 ℃ and high temperature resistance of 90 ℃, long service life, no VOC solvent and low volatility, and belongs to an environment-friendly material.
The above description is only for the purpose of illustrating the present invention and is not intended to limit the scope of the present invention, and any person skilled in the art can substitute or change the technical solution of the present invention and its conception within the scope of the present invention.
Claims (9)
1. The colored anti-skid marble-imitated coating for the pavement is characterized by comprising the following components in parts by weight: 50-60 parts of methyl methacrylate resin, 0.1-0.2 part of wetting agent, 15-20 parts of colored sintered sand, 20-30 parts of triple superphosphate, 0.2-0.4 part of dispersing agent, 0.3-0.7 part of anti-settling agent, 5-8 parts of colored pigment and 0.5-1.5 parts of BPO curing agent.
2. The colored pavement anti-skid marble-imitated coating according to claim 1, which is characterized by comprising the following components in parts by weight: 52-60 parts of methyl methacrylate resin, 0.1-0.2 part of wetting agent, 16-20 parts of color sintering sand, 23-30 parts of heavy calcium carbonate, 0.2-0.4 part of dispersing agent, 0.3-0.6 part of anti-settling agent, 5-8 parts of color pigment and 0.5-1.3 parts of BPO curing agent.
3. The colored pavement anti-skid marble-imitated coating according to claim 1, which is characterized by comprising the following components in parts by weight: 55 parts of methyl methacrylate resin, 0.1 part of wetting agent, 17 parts of colored sintered sand, 25 parts of triple superphosphate, 0.3 part of dispersing agent, 0.5 part of anti-settling agent, 5 parts of colored pigment and 0.7 part of BPO curing agent.
4. The colored pavement anti-skid marble coating of claim 1, wherein the wetting agent is a mixture of sodium dodecylbenzenesulfonate and tween 60.
5. The colored pavement anti-skid marble-imitated coating as claimed in claim 1, wherein the granularity of the colored sintered sand after being crushed and screened by a crusher is 100-150 meshes.
6. The colored pavement anti-skid marble coating of claim 1, wherein said dispersant is a mixture of guar gum, polyaspartic acid and petroleum sulfonic acid.
7. The colored pavement anti-skid marble coating of claim 1, wherein said anti-settling agent is a mixture of isotridecanol polyoxyethylene ether, behenyl alcohol polyoxyethylene ether, glycerin and water.
8. The colored pavement anti-skid faux stone coating of claim 1, wherein the concentration of the BPO curing agent is 30-40%.
9. The colored pavement anti-skid artificial marble coating as claimed in claim 1, wherein the preparation process of the colored pavement anti-skid artificial marble coating comprises the following steps:
step 1: adding 50 parts of methyl methacrylate resin into a stainless steel tank in proportion, mixing and stirring for 10 min;
step 2: adding 0.1 part of wetting agent;
and step 3: adding 5 parts of color pigment, and stirring for 5 min;
and 4, step 4: adding 0.3 part of dispersant into the mixture and stirring the mixture;
and 5: adding 17 parts of colored sintered sand and 25 parts of heavy calcium into the mixture respectively, quickly stirring the mixture for 20min, and adding 0.5 part of anti-settling agent into the mixture during stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011016264.8A CN112226133A (en) | 2020-09-24 | 2020-09-24 | Antiskid marble-imitated coating for colored pavement |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011016264.8A CN112226133A (en) | 2020-09-24 | 2020-09-24 | Antiskid marble-imitated coating for colored pavement |
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| CN112226133A true CN112226133A (en) | 2021-01-15 |
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| KR100920165B1 (en) * | 2009-02-26 | 2009-10-06 | 주식회사 포이닉스 | A non-slip type paved material composition |
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| CN103274618A (en) * | 2013-06-08 | 2013-09-04 | 合肥万博制漆有限公司 | Real mineral varnish sintered sand manufacturing method |
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- 2020-09-24 CN CN202011016264.8A patent/CN112226133A/en active Pending
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| KR100920165B1 (en) * | 2009-02-26 | 2009-10-06 | 주식회사 포이닉스 | A non-slip type paved material composition |
| KR101059135B1 (en) * | 2011-05-19 | 2011-08-25 | 한토산업 (주) | Permeative paint composition including ceramic and polymer resin against water, corrosion and salt damage of concrete structures and water pollution by elution of concrete material |
| CN103274618A (en) * | 2013-06-08 | 2013-09-04 | 合肥万博制漆有限公司 | Real mineral varnish sintered sand manufacturing method |
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| CN108546383A (en) * | 2018-04-28 | 2018-09-18 | 天津佰思特新材料科技有限公司 | A kind of anti-skidding colored pavement material of road, preparation method and construction technology |
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| Title |
|---|
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