CN112175532A - Adhesive film and application method thereof - Google Patents

Adhesive film and application method thereof Download PDF

Info

Publication number
CN112175532A
CN112175532A CN202011066117.1A CN202011066117A CN112175532A CN 112175532 A CN112175532 A CN 112175532A CN 202011066117 A CN202011066117 A CN 202011066117A CN 112175532 A CN112175532 A CN 112175532A
Authority
CN
China
Prior art keywords
layer
film
semi
glue
glue layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011066117.1A
Other languages
Chinese (zh)
Inventor
邓志军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Lifengda Zhanmao Technology Co ltd
Original Assignee
Shenzhen Lifengda Zhanmao Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Lifengda Zhanmao Technology Co ltd filed Critical Shenzhen Lifengda Zhanmao Technology Co ltd
Priority to CN202011066117.1A priority Critical patent/CN112175532A/en
Publication of CN112175532A publication Critical patent/CN112175532A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255Polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/0017Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor characterised by the choice of the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/0047Preventing air-inclusions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/0073Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor of non-flat surfaces, e.g. curved, profiled
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/24Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/245Vinyl resins, e.g. polyvinyl chloride [PVC]
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/50Adhesives in the form of films or foils characterised by a primer layer between the carrier and the adhesive
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00Presence of polysiloxane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a film and a pasting method thereof, wherein the film is of a composite layer structure and comprises a substrate layer, a silica gel layer, a semi-cured adhesive layer, a polyethylene terephthalate layer, a glue layer and a self-exhaust adhesive layer; the pasting method of the pasting film comprises the following steps: preparing the liquid semi-cured adhesive into the semi-cured adhesive by a UV curing method, a temperature curing method or a moisture curing method, attaching a glue layer and a self-exhausting glue layer, pressing and exhausting, exhausting air between the film body and the screen to enable the film body and the screen to be tightly attached, and performing secondary curing by the UV curing method, the temperature curing method or the moisture curing method and the like. The film and the pasting method can enable the 3D film to be tightly pasted with the screen, fill tolerance, solve the problem that the curved screen is not tightly pasted with the 3D film, exhaust air, avoid bubbles, enable the glue layer not to rebound and deform, comprehensively realize full pasting, and have the advantage of being difficult to leave marks compared with a flexible film.

Description

Adhesive film and application method thereof
Technical Field
The invention relates to a film and a pasting method thereof, belonging to the technical field of films, sheets and adhesives on carriers.
Background
The mobile phone is more in the present curved surface screen, and the pad pasting of prior art is the rigid film (glass membrane, ya keli membrane, pet membrane) material, adopts the fashioned technology of mould hot bending, because of there is the tolerance in cell-phone and the membrane body, and there is stress rebound phenomenon in the membrane material, causes the laminating of cell-phone and membrane body not in place, and the membrane body has the phenomenon such as stick up the limit, peel off, and the problem that the trace was easily left in the flexible membrane of prior art. The above technical problems have not been satisfactory, and improvement is urgently needed.
Disclosure of Invention
The invention aims to provide a film and a pasting method thereof, which solve the defects in the prior art.
The invention is realized by adopting the following technical scheme:
the utility model provides a pad pasting, includes the substrate layer and from the exhaust glue film, its characterized in that is provided with composite bed structure between the substrate layer and from the exhaust glue film, including the semi-solid glue film among the composite bed structure.
Furthermore, the composite layer structure is a glue layer and a semi-solidified glue layer which are sequentially arranged from top to bottom.
Furthermore, the composite layer structure is a glue layer, a polyethylene terephthalate layer, a semi-cured glue layer and a polyethylene terephthalate layer which are sequentially arranged from top to bottom.
Furthermore, the composite layer structure is a glue layer, a semi-cured glue layer and a polyethylene terephthalate layer which are sequentially arranged from top to bottom.
Furthermore, the composite layer structure is a semi-solidified glue layer and a glue layer which are sequentially arranged from top to bottom.
Furthermore, the material of substrate layer is for polyethylene glycol terephthalate, organic glass, polyimide, glass or polycarbonate.
A method of applying a film, comprising the steps of:
step 1): preparing the liquid semi-cured adhesive into a semi-cured adhesive by a UV curing method, a temperature curing method or a moisture curing method;
step 2): coating the semi-cured adhesive on the substrate layer;
step 3): an adhesive glue layer and a self-venting glue layer;
step 4): pressing and exhausting, namely pressing and exhausting air between the film body and the screen by utilizing mechanical force to enable the film body and the screen to be tightly attached;
step 5) secondary curing molding, wherein the secondary curing molding adopts a process method comprising the following steps: and curing and forming the semi-cured adhesive by a UV curing method, a temperature curing method or a moisture curing method to finish the application.
By adopting the film and the pasting method, the 3D film can be tightly pasted with the screen, the tolerance is filled, the problem that the curved screen is not tightly pasted with the 3D film is solved, the air is discharged by the exhaust glue, and the bubbles are avoided. The glue layer does not rebound and deform, the full lamination is comprehensively realized, and compared with a flexible film, the adhesive film has the advantage of difficult mark retention.
Drawings
Fig. 1 is a schematic structural diagram of a first embodiment of the present invention.
Fig. 2 is a schematic structural diagram of a second embodiment of the present invention.
Fig. 3 is a schematic structural diagram of a third embodiment of the present invention.
Fig. 4 is a schematic structural diagram of a fourth embodiment of the present invention.
Fig. 5 is a schematic structural diagram of a fifth embodiment of the present invention.
Fig. 6 is a schematic structural diagram of a sixth embodiment of the present invention.
Fig. 7 is a schematic structural diagram of a seventh embodiment of the present invention.
Fig. 8 is a schematic structural diagram of an eighth embodiment of the present invention.
Fig. 9 is a schematic structural diagram of a ninth embodiment of the present invention.
Detailed Description
The invention will be better understood by the following description of embodiments thereof, but the applicant's specific embodiments are not intended to limit the invention to the particular embodiments shown, and any changes in the definition of parts or features and/or in the overall structure, not essential changes, are intended to define the scope of the invention.
The core idea of the invention is that a composite layer structure is arranged between a substrate layer and a silica gel layer of the film, and the composite layer structure comprises a semi-cured glue layer. The surface of the base material layer has the following functions: scratch resistance, fingerprint resistance, blue light resistance and bacteria resistance.
The silica gel has the characteristics of high cleanliness, no white point, white fog, sand hole, no wiredrawing, no scratch and the like, also has the characteristics of low adhesion, high adsorptivity, quick automatic bubble removal, high temperature resistance, good chemical solvent resistance, easy shearing and punching, easy tearing, no residual glue and the like, has no light transmission on the surface of the silica gel layer, can well protect a display screen, improves the hardness of a protective film, ensures that the protective film is not easy to scratch, and prolongs the service life.
The semi-cured glue layer is a synthetic resin material, and the material can be cured for multiple times, and has the characteristic of delayed curing among multiple times of curing. In any of the embodiments the material has the following characteristics: the main component or all components are epoxy resin; the semi-cured glue layer is cured to a certain degree, has a certain crosslinking degree, is insoluble in a solvent, has good ductility or elasticity and certain viscosity, is not easy to tear and can rebound after being deformed by external force; when in use, the material needs to be cured by moisture, and is completely hardened after being cured, the hardness can reach more than 80D, the Tg is about 90 ℃, but the material can slowly react at normal temperature.
Polyethylene terephthalate, abbreviated as PET in English, is prepared by the exchange of dimethyl terephthalate and ethylene glycol or by the esterification of terephthalic acid and ethylene glycol to synthesize dihydroxyethyl terephthalate, and then by polycondensation. The polyester resin is a milky white or light yellow polymer with high crystallinity, has smooth and glossy surface, good creep resistance, fatigue resistance, abrasion resistance and dimensional stability, small abrasion and high hardness, and has the maximum toughness in thermoplastic plastics; the electric insulation performance is good, the temperature influence is small, but the corona resistance is poor. The paint has the advantages of no toxicity, good weather resistance, good chemical resistance stability, low water absorption, weak acid and organic solvent resistance, but no hot water soaking resistance and alkali resistance. The main application is accessories of switches, instruments and machines, currency counting machines and the like in the aspects of electronic and electric appliances; flow control valves, foot transmissions, etc. in the automotive industry; in addition, there are parts such as wheelchair bodies, wheels, clock parts, and sprayers.
Acrylic, also called PMMA or perspex, is derived from acrylic (acrylic plastic) english, and is known by the chemical name polymethylmethacrylate. The high-molecular-weight polyester resin is an important plastic high-molecular material which is developed earlier, has better transparency, chemical stability and weather resistance, is easy to dye and process, has beautiful appearance and is widely applied to the building industry. Organic glass products can be generally classified into cast sheets, extruded sheets and molding compounds. PMMA is dissolved in an organic solvent, such as phenol, anisole and the like, can form a good film through spin coating, has good dielectric property, and can be used as a dielectric layer of an Organic Field Effect Transistor (OFET), also known as an Organic Thin Film Transistor (OTFT).
The polyimide material is abbreviated as PI in English, and has the characteristics of low temperature resistance (-269-400 ℃), high friction resistance, self lubrication, high strength, high insulation, radiation resistance, corrosion resistance, small thermal expansion coefficient, organic solvent resistance, self extinguishment, no toxicity and other comprehensive properties. The class of PI (polyimide) is that the long-term working temperature is above 300 ℃, the short-term working temperature can reach 400 ℃, the PI (polyimide) is the engineering plastic with the best temperature resistance in the existing engineering plastics, the comprehensive performance of the PI (polyimide) is incomparable with other special engineering plastics, and the PI (polyimide) is praised by the world people as the solution to the problems. Polyimide (various products of machining and injection molding) is widely applied to the fields of compressors, tobacco machinery, food packaging machinery, office machinery, electronic products, mold industry and the like as a high-temperature-resistant, wear-resistant, self-lubricating or sealing part, and gains high praise from users.
Polycarbonate (PC) was first synthesized in 1898 by AlfredEinhorn, a german scientist. Polycarbonate is a transparent material, and has good mechanical property, flame retardant property and high temperature resistance. As one of five engineering plastics, the polycarbonate is applied to the fields of building industry plates, automobile parts, medical appliances, aerospace, electronic and electric appliances, optical lenses, optical disk base materials and LED illumination … …, and has wide market prospect. Polycarbonate is a novel thermoplastic, with a transparency of up to 90%, and is known as transparent metal. It is rigid and tough, has high impact strength, high size stability, wide use temperature range, excellent electric insulating performance, high heat resistance and no toxicity, and may be injection molded and extrusion molded.
The PC has excellent thermal performance, can be used for a long time at the temperature of-100-130 ℃, and has the brittle temperature below-100 ℃. Although polycarbonate has poor resistance to cracking and chemicals, is easily hydrolyzed at high temperatures, has poor compatibility with other resins, and has poor lubricating properties, it can be modified by adding other resins or inorganic fillers to obtain very excellent properties. The polycarbonate can be applied to a plurality of technical fields such as optical illumination, electronic and electric appliances, mechanical equipment, medical equipment and the like, and can be used as a hollow rib double-wall plate, greenhouse glass and the like in buildings; the product can be used as textile bobbin, textile machine bush, milk bottle, tableware, toy, model, etc. in textile industry. Polycarbonate (PC) advantages: high strength, elastic coefficient, high impact strength and wide application temperature range; high transparency, ability to dye any color; the heat resistance is good, and the H.D.T. is high; the food is tasteless and odorless, is harmless to human bodies, meets the requirements of sanitation and safety and food grade; the molding shrinkage is low, the dimensional stability is good, and the processing is convenient; the electrical property is excellent, and the flame retardant grade is high; ultraviolet resistance and good weather resistance; good fatigue resistance and good toughness.
Example 1: the substrate layer 1 and be provided with composite layer structure from between the exhaust glue film 3, the silica gel layer 3 is from exhaust silica gel in this embodiment.
Example 2: the composite layer structure is arranged between the substrate layer 1 and the self-venting glue layer 3, and the composite layer structure is the substrate layer 1, the glue layer 4, the semi-curing glue layer 2 and the self-venting glue layer 3 which are sequentially arranged in the embodiment.
Example 3: the curved surface pre-bending adhesive film is provided with a composite layer structure between the substrate layer 1 and the self-exhaust adhesive layer 3.
Example 4: the curved surface pre-bending film has a composite layer structure between the substrate layer 1 and the self-venting glue layer 3, wherein the composite layer structure is a glue layer 4 and a semi-curing glue layer 2 arranged in sequence in the embodiment.
Example 5: the substrate layer 1 and be provided with composite layer structure from between the exhaust glue film 3, composite layer structure is glue layer 4, polyethylene terephthalate layer 5, semi-solid glue film 2, polyethylene terephthalate layer 5 that arrange in proper order in this embodiment.
Example 6: a composite layer structure is arranged between the substrate layer 1 and the self-venting glue layer 3, and the composite layer structure is a glue layer 4, a semi-curing glue layer 2, a polyethylene terephthalate layer 5 and the self-venting glue layer 3 which are sequentially arranged in the embodiment
Example 7: the composite layer structure is arranged between the substrate layer 1 and the self-venting glue layer 3, and in the embodiment, the composite layer structure is a semi-solidified glue layer 2, a glue layer 4 and a polyethylene terephthalate layer 5 which are sequentially arranged.
Example 8: a composite layer structure is arranged between the substrate layer 1 and the self-venting glue layer 3, and in this embodiment, the composite layer structure is a semi-curing glue layer 2 and a glue layer 4 which are arranged in sequence.
Example 9: the composite layer structure is arranged between the substrate layer 1 and the self-venting glue layer 3, and in the embodiment, the composite layer structure is a glue layer 4 and a semi-curing glue layer 2 which are sequentially arranged.
The process flow of the invention comprises the following steps:
step 1): preparing the liquid semi-cured adhesive into a semi-cured adhesive by a UV curing method, a temperature curing method or a moisture curing method;
step 2): coating the semi-cured adhesive on the substrate layer
Step 3): adhering a glue layer and a silica gel layer;
step 4): and (3) pressing and exhausting, namely pressing and exhausting air between the film body and the screen by utilizing mechanical force, so that the film body and the screen are tightly attached, and the tolerance can be filled.
Step 5) secondary curing molding, wherein the secondary curing molding adopts a process method comprising the following steps: and curing and forming the semi-cured adhesive by a UV curing method, a temperature curing method or a moisture curing method to finish the application.
As can be seen from the above process flow of the present invention, the process undergoes two curing steps: the first curing is a semi-curing process from glue generation to glue film, and applicable curing methods include a thermal curing method, a UV curing method, a moisture curing method, and the like. The second curing is from a semi-solid glue to a hard body, and usable curing methods include a thermal curing method, a UV curing method, a moisture curing method, and the like.
Through twice curing process treatment, the glue is firstly made into a semi-cured jelly shape, then the glass film and the mobile phone screen are clamped tightly and then the section difference is filled again, and then the UV curing is carried out again, so that the glue layer does not rebound and deform, the full lamination is realized comprehensively, and compared with a flexible film, the flexible film has the advantage of difficulty in leaving marks.
UV curing is ultraviolet curing, which is an acronym for ultraviolet light, and curing refers to the process by which a substance is converted from a low molecule to a high molecule. UV curing generally refers to the curing conditions or requirements of coatings (paints), inks, adhesives (glues) or other potting, sealants, etc. that require curing with ultraviolet light, as distinguished from thermal curing, curing with crosslinking agents (curing agents), natural curing, etc.
The resin systems employed by the UV curing technique, which involve a basic oligomer, essentially a low molecular weight (about 2500) prepolymer, commonly used urethane acrylates (urethane acrylates), epoxy acrylates, polyester acrylates or polyether acrylates, vinyl ethers, acrylate-free oligomers and the like, are also being increasingly employed. The oligomer has high viscosity, and in order to facilitate construction and increase the crosslinking and curing speed, a monomer is required to be added as a reactive diluent to adjust the rheological property of the resin. The structure of the reactive diluent has an important influence on the properties of the final coating film, such as flowability, slip, wettability, swellability, shrinkage, adhesion and migration within the coating film. The reactive diluent may be monofunctional or polyfunctional, the latter being preferred because it provides an increased degree of crosslinking upon curing. The performance requirements of reactive diluents are the dilution power, solubility, odor, ability to reduce the viscosity of the medium, volatility, functionality, surface tension, shrinkage during polymerization, glass transition temperature (Tg) of the homopolymer, influence on the overall curing speed and toxicity.
The present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof, and it is therefore intended that all such changes and modifications as fall within the true spirit and scope of the invention be considered as within the following claims.

Claims (7)

1. The utility model provides a pad pasting, includes the substrate layer and from the exhaust glue film, its characterized in that is provided with composite bed structure between the substrate layer and from the exhaust glue film, including the semi-solid glue film among the composite bed structure.
2. The film as recited in claim 1, wherein the composite layer structure is a glue layer and a semi-cured glue layer arranged in sequence from top to bottom.
3. The film according to claim 1, wherein the composite layer structure is a glue layer, a polyethylene terephthalate layer, a semi-cured glue layer, and a polyethylene terephthalate layer arranged in this order from top to bottom.
4. The film according to claim 1, wherein the composite layer structure comprises a glue layer, a semi-cured glue layer and a polyethylene terephthalate layer arranged in sequence from top to bottom.
5. The film as recited in claim 1, wherein the composite layer structure comprises a semi-cured glue layer and a glue layer arranged from top to bottom.
6. The film according to any one of claims 1 to 5, wherein the material of the substrate layer is polyethylene terephthalate, organic glass, polyimide, glass or polycarbonate.
7. A method of applying a film, comprising the steps of:
step 1): preparing the liquid semi-cured adhesive into a semi-cured adhesive by a UV curing method, a temperature curing method or a moisture curing method;
step 2): coating the semi-cured adhesive on the substrate layer;
step 3): an adhesive glue layer and a self-venting glue layer;
step 4): pressing and exhausting, namely pressing and exhausting air between the film body and the screen by utilizing mechanical force to enable the film body and the screen to be tightly attached;
step 5) secondary curing molding, wherein the secondary curing molding adopts a process method comprising the following steps: and curing and forming the semi-cured adhesive by a UV curing method, a temperature curing method or a moisture curing method to finish the application.
CN202011066117.1A 2020-09-30 2020-09-30 Adhesive film and application method thereof Pending CN112175532A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011066117.1A CN112175532A (en) 2020-09-30 2020-09-30 Adhesive film and application method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011066117.1A CN112175532A (en) 2020-09-30 2020-09-30 Adhesive film and application method thereof

Publications (1)

Publication Number Publication Date
CN112175532A true CN112175532A (en) 2021-01-05

Family

ID=73948817

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011066117.1A Pending CN112175532A (en) 2020-09-30 2020-09-30 Adhesive film and application method thereof

Country Status (1)

Country Link
CN (1) CN112175532A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114854363A (en) * 2022-04-21 2022-08-05 东莞亨通光学技术有限公司 Method for pasting film on curved screen and filling adhesive used in method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207059410U (en) * 2017-03-09 2018-03-02 深圳市佩晟科技有限公司 A kind of diaphragm with fruit juice gel
CN209307281U (en) * 2018-10-11 2019-08-27 江苏斯迪克新材料科技股份有限公司 The automatic exhaust protective film of Curved screen
CN111334217A (en) * 2020-05-18 2020-06-26 苏州世华新材料科技股份有限公司 Regionally cured high-filling AB adhesive, and preparation method and application thereof
CN213232097U (en) * 2020-07-23 2021-05-18 绍兴旭源新材料科技有限公司 Semi-cured screen protection film

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207059410U (en) * 2017-03-09 2018-03-02 深圳市佩晟科技有限公司 A kind of diaphragm with fruit juice gel
CN209307281U (en) * 2018-10-11 2019-08-27 江苏斯迪克新材料科技股份有限公司 The automatic exhaust protective film of Curved screen
CN111334217A (en) * 2020-05-18 2020-06-26 苏州世华新材料科技股份有限公司 Regionally cured high-filling AB adhesive, and preparation method and application thereof
CN213232097U (en) * 2020-07-23 2021-05-18 绍兴旭源新材料科技有限公司 Semi-cured screen protection film

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114854363A (en) * 2022-04-21 2022-08-05 东莞亨通光学技术有限公司 Method for pasting film on curved screen and filling adhesive used in method

Similar Documents

Publication Publication Date Title
CN103608160A (en) Transfer film for in-mold molding and method for producing same
CN105729964A (en) Molded article with decorative sheet
CN103087276B (en) Active energy ray curable resin, resin combination, hard paint, cured film, decorating film and injection-moulding plastic product
JPH08128458A (en) Covering method of plastic base material
CN104263229B (en) The film build method of a kind of preparation method of antistatic UV coating and this antistatic UV coating
Tucker et al. Ambient cure POSS–epoxy matrices for marine composites
JP2013014638A (en) Tacky adhesive composition, tacky adhesive sheet, and laminate
CN103937197A (en) Polyurethane synthetic resin for preparing traceless glue sticker and traceless glue sticker prepared by applying polyurethane synthetic resin
CN112175532A (en) Adhesive film and application method thereof
JP3036818B2 (en) Molded article having hard coat layer and method for producing the same
KR20140043752A (en) Epoxy resins with high thermal stability and toughness
CN110591051A (en) Preparation method and application of silicone rubber film with underwater self-healing capability and adhesiveness
CN111777977A (en) Room-temperature fast-curing transparent epoxy adhesive for bonding engineering plastics and preparation method thereof
Deng et al. Repairable, reprocessable and recyclable rigid silicone material enabled by dual dynamic covalent bonds crosslinking side-chain
Yan et al. The improvement of thermal stability and adhesion of silicone rubber composites modified by phenolic epoxy resin
KR20200016280A (en) Laminated film
CN104927589A (en) Organosilicone wear-resisting hardened coating and preparation method thereof
KR20130123510A (en) Uv-curable adhesive composition having light transparance and heat resistance, and adhesive sheet employing the same
JP2003004921A (en) Open type porous reflector
JP7270983B2 (en) Recyclable low adhesion polyurethane material
Moini et al. Green adhesives—Past, present, and future outlook
JPH07156279A (en) Method for molding transparent glass fiber reinforced resin
CN109867894B (en) High-temperature-resistant UV polymerization type body foam damping material and preparation method thereof
CN112920752A (en) PUR adhesive for bonding polycarbonate substrate and use method thereof
CN112250898A (en) Organic glass with good heat resistance

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination