CN112157770A - Environment-friendly type bamboo wood mildew-proof treatment method - Google Patents

Environment-friendly type bamboo wood mildew-proof treatment method Download PDF

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CN112157770A
CN112157770A CN202011101453.5A CN202011101453A CN112157770A CN 112157770 A CN112157770 A CN 112157770A CN 202011101453 A CN202011101453 A CN 202011101453A CN 112157770 A CN112157770 A CN 112157770A
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bamboo
mildew
ultrasonic
compound
environment
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CN112157770B (en
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关明杰
汤新元
徐香君
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Nanjing Forestry University
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Nanjing Forestry University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00Chemical or physical treatment of reed, straw, or similar material
    • B27K9/002Cane, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/003Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
    • B27K5/0065Ultrasonic treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/04Combined bleaching or impregnating and drying of wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/20Removing fungi, molds or insects

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Mechanical Engineering (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an environment-friendly mildew-proof treatment method for bamboo wood, which comprises the steps of S1, treating green and yellow removed bamboo wood by ultrasonic, wherein the ultrasonic frequency is 50KHz-100KHz, the ultrasonic power is 400-800W, and the ultrasonic temperature is 20-80 ℃; s2 compounding mildew inhibitor with sodium acetate and butyl paraben or sodium diacetate and propyl paraben; s3, preparing a compound paraffin emulsion from No. 58 food paraffin, 2-hydroxy-1, 4 naphthoquinone, Tween 60 and distilled water; the invention utilizes the thermal effect and the mechanical effect of ultrasonic waves to destroy starch and inclusions in the bamboo wood, combines the food-grade mildew preventive and the food-grade paraffin, and can be used for mildew prevention treatment of common daily bamboo product appliances such as bamboo barrels, bamboo chopsticks, bamboo cutting boards, bamboo toothbrushes and the like, and greatly improve the dimensional stability, the mechanical property, the hardness, the wear resistance and the hydrophobicity of the bamboo wood.

Description

Environment-friendly type bamboo wood mildew-proof treatment method
Technical Field
The invention relates to an environment-friendly bamboo mildew-proof treatment method, belonging to the technical field of bamboo mildew-proof treatment
Background
The bamboo wood has the characteristics of high growth speed, degradability, short growth period, high yield and the like, and has good physical and mechanical properties and great development value. The mildew-proof treatment of bamboo is a very important process in the processing and manufacturing process of bamboo daily necessities, bamboo furniture and bamboo engineering materials. The existing mildew-proof treatment process is greatly improved in the aspect of toxicity to human bodies and environment, but cannot be used for common daily bamboo product appliances such as bamboo barrels, bamboo chopsticks, bamboo chopping boards, bamboo toothbrushes and the like. Therefore, the method for developing the environment-friendly type bamboo mildew-proof treatment method aiming at the daily bamboo product appliances has important significance.
The Chinese patent CN 110253706A firstly soaks bamboo in mixed enzyme solution for ultrasonic treatment, then soaks modified treatment liquid, then bundles the bamboo and wraps the bamboo with heat preservation coiled material, is connected with a steam generator and adds antiseptic treatment agent to treat the bamboo, and finally dries the bamboo. Aiming at the problem that the existing daily bamboo product appliance is easy to mildew in the using process, the invention provides an environment-friendly bamboo mildew-proof treatment method.
Disclosure of Invention
The invention can destroy the starch and the inclusion in the bamboo based on the thermal effect and the mechanical effect of the ultrasonic wave, combines the food mildew preventive and the food paraffin, and the bamboo processed by the technology not only can obviously improve the mildew resistance of the bamboo, but also can greatly improve the dimensional stability, the mechanical property, the hardness, the wear resistance and the hydrophobicity of the bamboo, thereby having obvious economic value and social benefit.
The technical scheme of the invention comprises the following process steps:
s1, soaking the green and yellow removed bamboo wood in water, and carrying out ultrasonic treatment for 1-2 h;
s2, washing the bamboo subjected to ultrasonic treatment for 1-2 hours by using running water;
s3, placing the washed bamboo into a compound mildew inhibitor, and soaking for 1-2h at normal temperature and normal pressure;
s4, drying the bamboo processed by the mildew preventive at 30-50 ℃ until the water content is controlled at 8-12%;
s5, placing the dried bamboo into compound paraffin emulsion, and soaking for 1-2h at normal temperature and normal pressure;
s6, drying the bamboo wood subjected to paraffin treatment at 30-50 ℃ until the water content is controlled to be 15-20%;
s7 tempering the dried bamboo material at 60-80 deg.C for 0.5-1.5h, and controlling the water content at 8-12%.
The ultrasonic treatment process is characterized in that the ultrasonic frequency is 50KHz-100KHz, the ultrasonic power is 400-800W, and the ultrasonic temperature is 20-80 ℃.
The compound mildew preventive is sodium acetate and butylparaben or sodium diacetate and propylparaben with the mass ratio of 1:1-3:1, a certain amount of water is added, and the mixture is stirred for 10-30min at the temperature of 20-50 ℃ to prepare a solution with the concentration of 0.6-1.4%.
The compound paraffin emulsion is prepared by homogenizing 20-25 parts of No. 58 food paraffin, 1.5-2 parts of 2-hydroxy-1, 4 naphthoquinone, 2-3 parts of Tween 60 and 80-100 parts of distilled water at 80-100 ℃ for 1-2 h.
The method has the advantages of simple process, energy conservation, environmental protection and suitability for popularization.
Drawings
FIG. 1 is a process flow diagram of the present invention.
FIG. 2 is a scanning electron micrograph of the bamboo chips before and after modification in example 1.
Detailed Description
Hereinafter, preferred embodiments of the present invention will be described in detail. It should be understood that the preferred embodiments are illustrative of the invention only and are not limiting upon the scope of the invention.
Example 1: the method for processing the environment-friendly bamboo material to prevent mildew comprises the following steps:
step 1) soaking green and yellow removed bamboo wood in water, and performing ultrasonic treatment, wherein the ultrasonic frequency is 50KHz, the ultrasonic power is 400W, the ultrasonic time is 1h, and the ultrasonic temperature is 20 ℃;
step 2), washing the bamboo subjected to ultrasonic treatment for 1 hour by using running water;
step 3) placing the washed bamboo wood into a compound mildew preventive, wherein the compound mildew preventive is composed of sodium acetate and butylparaben with the mass ratio of 1:1, adding a certain amount of water, stirring at 20 ℃ for 10min to prepare a solution with the concentration of 0.6%, and soaking at normal temperature and normal pressure for 1 h;
step 4), drying the bamboo processed by the mildew preventive at 30 ℃ until the water content is controlled at 8%;
step 5) placing the dried bamboo into compound paraffin emulsion, and then soaking for 1h at normal temperature and normal pressure, wherein the compound paraffin emulsion is prepared by mechanically stirring 20 parts of No. 58 food paraffin, 1.5 parts of 2-hydroxy-1, 4 naphthoquinone, 2 parts of tween and 80 parts of distilled water for 1h at 80 ℃;
and 6) drying the bamboo subjected to paraffin treatment at 30 ℃, and controlling the water content to be 20%.
Step 7) tempering the dried bamboo wood at 60 ℃ for 1.5h, and controlling the water content to be 12%
Example 2: the method for processing the environment-friendly bamboo material to prevent mildew comprises the following steps:
step 1), soaking green and yellow removed bamboo wood in water, and performing ultrasonic treatment, wherein the ultrasonic frequency is 80KHz, the ultrasonic power is 600W, the ultrasonic time is 1.5h, and the ultrasonic temperature is 40 ℃;
step 2), washing the bamboo subjected to ultrasonic treatment for 1.5 hours by using running water;
step 3) placing the washed bamboo wood into a compound mildew preventive, wherein the compound mildew preventive is composed of sodium diacetate and butyl paraben with the mass ratio of 2:1, adding a certain amount of water, stirring at 35 ℃ for 20min to prepare a solution with the concentration of 1.0%, and soaking at normal temperature and normal pressure for 1.5 h;
step 4), drying the bamboo processed by the mildew preventive at 40 ℃ until the water content is controlled at 10%;
step 5) placing the dried bamboo into compound paraffin emulsion, and then soaking for 1.5h at normal temperature and normal pressure, wherein the compound paraffin emulsion is prepared by homogenizing 25 parts of No. 58 food paraffin, 1.5 parts of 2-hydroxy-1, 4 naphthoquinone, 2 parts of tween and 100 parts of distilled water in a homogenizer for 1.5h at 80 ℃;
and 6) drying the bamboo subjected to paraffin treatment at 40 ℃ until the water content is controlled at 18%.
And 7) tempering the dried bamboo material at 70 ℃ for 1h, and controlling the water content to be 10%.
Example 3: the method for processing the environment-friendly bamboo material to prevent mildew comprises the following steps:
step 1), soaking green and yellow removed bamboo wood in water, and performing ultrasonic treatment, wherein the ultrasonic frequency is 100KHz, the ultrasonic power is 800W, the ultrasonic time is 2h, and the ultrasonic temperature is 80 ℃;
step 2), washing the bamboo subjected to ultrasonic treatment for 2 hours by using running water;
step 3) placing the washed bamboo wood into a compound mildew preventive, wherein the compound mildew preventive is composed of sodium diacetate and propylparaben with the mass ratio of 3:1, adding a certain amount of water, stirring for 30min at 50 ℃ to prepare a solution with the concentration of 1.4%, and soaking for 2h at normal temperature and normal pressure;
step 4), drying the bamboo processed by the mildew preventive at 50 ℃ until the water content is controlled at 12%;
step 5) placing the dried bamboo into compound paraffin emulsion, and then soaking for 2 hours at normal temperature and normal pressure, wherein the compound paraffin emulsion is prepared by magnetically stirring 25 parts of No. 58 food paraffin, 2 parts of 2-hydroxy-1, 4 naphthoquinone, 2 parts of tween and 80 parts of distilled water for 2 hours at 100 ℃;
and 6) drying the bamboo subjected to paraffin treatment at 50 ℃, and controlling the water content to be 15%.
And 7) tempering the dried bamboo material at 80 ℃ for 0.5h, and controlling the water content at 8%.
The bamboo materials obtained by the treatment of the examples 1-3 are tested for antibacterial performance (Aspergillus niger, Trichoderma viride and Penicillium citrinum) according to GB/T18261-2013, hardness test is carried out according to GB/T1941-2009, and the axial and radial water absorption expansion rates are tested according to ASTM D1037, and the test results are shown in the following table 1:
TABLE 1
Figure BDA0002725492170000061
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (5)

1. An environment-friendly type bamboo wood mildew-proof treatment method is characterized by comprising the following process steps:
s1, soaking green and yellow removed bamboo wood in water, and performing ultrasonic treatment for 1-2 hours;
s2, washing the bamboo subjected to ultrasonic treatment for 1-2 hours by using running water;
s3, placing the washed bamboo wood into a compound mildew inhibitor, and soaking for 1-2 hours at normal temperature and normal pressure;
s4, drying the bamboo processed by the mildew preventive at 30-50 ℃ until the water content is controlled at 8-12%;
s5, placing the dried bamboo into compound paraffin emulsion, and soaking for 1-2 hours at normal temperature and normal pressure;
s6, drying the bamboo subjected to paraffin treatment at 30-50 ℃ until the water content is controlled to be 15-20%;
s7, tempering the dried bamboo wood at 60-80 ℃ for 0.5-1.5h, and controlling the water content to be in
8-12%。
2. The processing method of the environment-friendly type bamboo material mildew prevention according to the claim 1, is characterized in that:
the S1 comprises the ultrasonic frequency of 50KHz-100KHz, the ultrasonic power of 400-800W and the ultrasonic temperature of 20-80 ℃.
3. The processing method of the environment-friendly type bamboo material mildew prevention according to the claim 1, is characterized in that:
the compound mildew preventive comprises sodium acetate and butyl paraben;
the compound mildew preventive comprises sodium diacetate and butylparaben;
the compound mildew preventive comprises sodium diacetate and propylparaben,
the mass ratio of the compound mildew preventive is 1:1-3: 1.
4. The processing method of the environment-friendly type bamboo material mildew prevention according to the claim 1, is characterized in that:
adding a plurality of water into the compound mildew preventive, and stirring for 10-30min at 20-50 ℃ to prepare a solution with the concentration of 0.6-1.4%.
5. The processing method of the environment-friendly type bamboo material mildew prevention according to the claim 1, is characterized in that:
the compound paraffin emulsion is prepared by homogenizing 20-25 parts of No. 58 food paraffin, 1.5-2 parts of 2-hydroxy-1, 4 naphthoquinone, 2-3 parts of Tween 60 and 80-100 parts of distilled water at 80-100 ℃ for 1-2 h.
CN202011101453.5A 2020-10-15 2020-10-15 Environment-friendly type bamboo wood mildew-proof treatment method Active CN112157770B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114953076A (en) * 2022-05-05 2022-08-30 南京林业大学 Method for preparing hydrophobic mildew-proof waxy bamboo and product thereof

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Publication number Priority date Publication date Assignee Title
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CN105331318A (en) * 2015-11-23 2016-02-17 安徽福佳竹木日用品有限公司 Preparation method of mould-proof bamboo plywood with high bonding strength
CN107584618A (en) * 2017-07-20 2018-01-16 广德县泉村竹制品有限公司 A kind of inexpensive bamboo mat preparation method of environmental protection
CN108673670A (en) * 2018-05-21 2018-10-19 韩立根 A kind of anti-mildew processing method of bamboo product
CN109866298A (en) * 2019-02-28 2019-06-11 北京林业大学 A kind of paraffinic base Pickering lotion and preparation method thereof containing hydridization montmorillonite

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CN105331318A (en) * 2015-11-23 2016-02-17 安徽福佳竹木日用品有限公司 Preparation method of mould-proof bamboo plywood with high bonding strength
CN107584618A (en) * 2017-07-20 2018-01-16 广德县泉村竹制品有限公司 A kind of inexpensive bamboo mat preparation method of environmental protection
CN108673670A (en) * 2018-05-21 2018-10-19 韩立根 A kind of anti-mildew processing method of bamboo product
CN109866298A (en) * 2019-02-28 2019-06-11 北京林业大学 A kind of paraffinic base Pickering lotion and preparation method thereof containing hydridization montmorillonite

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114953076A (en) * 2022-05-05 2022-08-30 南京林业大学 Method for preparing hydrophobic mildew-proof waxy bamboo and product thereof
CN114953076B (en) * 2022-05-05 2023-03-03 南京林业大学 Method for preparing hydrophobic mildew-proof waxy bamboo and product thereof

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