CN1121353A - A composition of detergent for clothing - Google Patents
A composition of detergent for clothing Download PDFInfo
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- CN1121353A CN1121353A CN94191831A CN94191831A CN1121353A CN 1121353 A CN1121353 A CN 1121353A CN 94191831 A CN94191831 A CN 94191831A CN 94191831 A CN94191831 A CN 94191831A CN 1121353 A CN1121353 A CN 1121353A
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- detergent composition
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
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- Life Sciences & Earth Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a detergent composition for clothing, which is characterized in that its main component is D-Limonene, a natural vegetable solvent, combined with higher fatty acid oil, emulsifier, polyhydric higher alcohol and amine in a preselected proportion, so that it provides a good washing effect for wool and silk fabrics, so that it makes washing possible without addition of mechanical energy, and so that it has a shrinkage-resistant effect in the original form after water washing, with excellent efficiency of prevention against contamination and of freezing-resistance.
Description
The present invention relates to a kind of detergent composition that is used for the clothing class, the main ingredient that is characterized in it is D-Limonene (a kind of natural phant solvent) and a kind of emulsifying agent.If necessary, propylene glycol also can be united use in specific ratio with general known detergent additives.This detergent composition makes clothing become possibility with the immersion way washing, this is different from original method, it allows wool, these forbade originally that the clothing of washing washed silk or flax, and it has a kind of shrinkproof result after the washing with regard to original shape, and it has good detersive efficiency and anti-freeze effect.
A kind of existing laundry detergent is typically a kind of solid-state laundry soap class, mainly by a kind of mineral emulsifying agent such as LAS (linear alkyl sulfonate), ABS (alkylbenzene sulfonate) or AOS (alpha-olefin sulfonate) and a kind of fatty acid alcohol plant emulsifying agent are formed, and it also can be made up of lipid acid soda and the synthetic detergent powder that contains various functional groups preparation.
This washing composition can effectively be removed dust, urban district emission gases, lipid composition such as synthetic oil or skin secretion, protein-based composition such as collagen protein, and starch ingredients such as food residual, and they can effectively wash synthetic textiles or polyester, the BLENDED FABRIC of nylon or acryloyl class.
Yet along with the improvement of standard of living, the dress custom has turned to preference natural fabric clothing, therefore has a kind of full wool to washing, silk or sodolin, or the demand of their BLENDED FABRIC now.
Because laundry detergent originally mainly is made up of synthetic mineral emulsifying agent class and because need mechanical energy (as the mechanical energy that is produced by vibrator rotation in washing machine in addition, by sound wave or mechanical energy that impact produced), the clothing of water-wash resistance difference such as full wool or silk clothing are because washing by soaking produces distortion and contraction is a major defect.
Therefore, this so far clothing is to wash by dry cleaning process in the laundry, and wherein the use of dry cleaning composition produces serious environmental or economic problems.Dry cleaning process originally is a kind of petroleum-based solvent and mineral emulsifying agent to be used to wash senior clothing such as full wool, and the dry cleaning process of silk or hemp cloth wherein mainly uses tetrachloroethylene as a kind of petroleum-based solvent.
The reason that this dry cleaning process produces recent problem to environment is because the physical and chemical performance of tetrachloroethylene, and it has low water solubility as everyone knows, carinogenicity (Sigma﹠amp; The Aldrich laboratory), and because the toxicity of washing back residual solvent reaches the suction of volatile matter causes serious problems in washing process.
In addition, usually do not handle the measure of tetrachloroethylene waste liquid and because soil, the pollution of water and air produces serious problem.
Correspondingly, for solving the problem of above-mentioned original washing composition and dry cleaning composition simultaneously, the inventor has developed a kind of pollution that do not produce, does not poison human body, and can solve the shrink that clothing is washed or the problem of distortion.
At first, by using a kind of natural solvent D-Limonene, the present invention has changed the chemical constitution of former washing composition and original washing methods, like this clothing utilization infusion method washing that is applied to dry-clean and do not make the clothing distortion or shrink.
Be the extraction liquid of a natural orange peel as the D-Limonene of solvent in the present invention, and it is a kind of in Brazil, Australia, the by product that the U.S. and European fractionation orange peel extraction liquid obtain.As for chemical structure, D-Limonene is a kind of C with constitutional features similar to benzene
10Terpenoid, therefore with regard to its degrease speed, it has the ability that the removal stronger than tetrachloroethylene stain.
And, according to its content, D-Limonene with octanol, nonyl alcohol, the deodorant composition components one of description is used from industry among Walnut oil. (pecanal) or mile which oil (linanol) and the open No.90-6845 of a kind of as Korean Patent, in food or the spices.
As a kind of liquid, also because the boiling point of D-Limonene is higher than 155 ℃, be chemically stable therefore, and according to the clause of FDA (food and drug administration), it is generally regarded as safe using D-Limonene in washing composition.
Use the example of D-Limonene can be, find in 511,488 and 4,620,937, and English Patent NO.1,603,047 at United States Patent (USP) NO.4.These disclosures are herein incorporated by reference this paper, and wherein D-Limonene is the composition that is used for a kind of industrial detergent.D-Limonene is being used in a kind of technology of industrial detergent composition, it only is applied to wash the clean-out system that industry oil is stain as a kind of, and never is applied to the clothing class or washes senior fabric detergent composition yielding as that shrink or easily decolour.
Particularly, unlike dry cleaning composition, still do not know to be useful on washing so far and do not make the detergent composition of clothing sex change.And with regard to using method, must apply mechanical energy during washing, as rotating or ballistic effect by utilizing.
Usually, the mechanism that separate solid stains from the matrix may be interpreted as a kind of effect of electrostatic energy.Separate to be that wherein the mutual gap of hydration by bringing out emulsifying agent and the absorption between foul particle and matrix realizes.
After this, foul separates from the matrix infinity, and wherein Bi Yao energy is by the motion in washing machine, and the dispersion of water or ultrasonic wave produce.Under the situation of using the washing machine washing, owing to the kinetic energy of vibrator in water drum, clothing has been applied in excess energy, and therefore other sex change of shrink and clothing is inevitable.
Correspondingly, if a kind of detergent composition with shrinkproof result utilizes a kind of natural solvent to take the immersion way dissolving to stain and make it to separate and prevent that it from adsorbing again, then can reach the dry-cleaning effect in the laundry at home.
Correspondingly, for making great efforts to overcome the above-mentioned defective of former washing composition, the inventor has developed a kind of new clothing detergent composition.When this D-Limonene extraction liquid and emulsifying agent with orange peel is main component, and contain the more senior lipid acid of a specified proportion in case of necessity, the detergent composition of a kind of mixture of polynary senior alkohol and amine provides when using, with regard to garment shape stability (as, wool or silk), washing effect is improved greatly.And if desired, by adding propylene glycol, washing composition can prevent to freeze in storage process.
An object of the present invention is a kind of its main ingredient will be provided the clothing detergent composition that is D-Limonene, it can make wool or silk clothing keep shape after washing.
The present invention relates to a kind of detergent composition that is used for clothing, it is characterized in that it contains D-Limonene and emulsifying agent as main ingredient.
In addition, specific embodiments of the present invention is characterised in that in above-mentioned cleaning composition, D-Limonene and emulsifying agent account for 10-35wt% and 15-35wt% respectively.
Another specific embodiments of the present invention is characterised in that except that above-mentioned D-Limonene and emulsifying agent, higher fatty acid, and polynary senior alkohol and amine accounts for 0.5-15wt% respectively, 3.0-5.0wt% and 1.0-2.5wt%.
The present invention relates to keep dimensionally stable after a kind of fabric washing, have obvious washing effect by adding higher fatty acid oil, and with D-Limonene---a kind of tangerine peel extraction liquid is the latex detergent composition that is used for clothing of its main ingredient.Particularly, according to preferred detergent composition, for obtaining better washing effect, the usage quantity of D-Limonene and emulsifying agent is respectively 10-35wt% and 15-35wt%, and higher fatty acid, polynary higher alcohols, and organic amine compound adds 0.5-1.5wt% respectively, 3.0-5.0wt% and 1.0-2.5wt%.
According to the present invention, be lower than under the situation of 10wt% at the content of D-Limonene, its generally is difficult to obtain enough good washing effect by soaking, and is higher than under the situation of 35wt% at the content of D-Limonene, and clothing is yielding usually and decolour.
According to the present invention, a kind of emulsifying agent such as oxygen ethylidene oxygen propylidene alkyl oxide, oxygen ethylidene oxygen propyl group alkyl phenylate, the consumption of oxygen ethylidene lauryl ether and oxygen ethylidene alkyl phenylate is preferably 15.0-35.0wt%.These emulsifying agents can mix use to remedy single various incomplete function of planting emulsifying agent, like this, when they mix, are expected to obtain a kind of effect collaborative or that increase.In the present invention, if emulsifier content is lower than 15.0wt% or is higher than 35.0wt%, will cause the difficulty of a kind of unstable emulsification and long-term storage aspect usually.
According to a specific embodiments of the present invention, as higher fatty acid, preferably use oleic acid, one or more in stearic acid and the palmitinic acid, its consumption are 0.5-1.5wt%.Be lower than at fatty acid content under the situation of 0.5wt%, the basicity in the product raises usually, produces a kind of effect that is harmful to protein-based fabrics such as wool and silk.Content at lipid acid is higher than under the situation of 1.5wt%, may not reach the viscosity of product requirement usually.The optimum viscosity of utilizing the No.2 rotor to measure during with 20 ℃ of Brookfield Viscometer under 2.25 rev/mins of conditions is 80,000-150,000 cp.
According to a specific embodiments of the present invention, polyoxyethylene glycol, polynary higher alcohols also are preferably used as and are a kind of softening agent for fibres, it is correlated with molecular weight and has different performances, for producing best effect, its mean value is preferably 300-600, and its consumption is preferably at 3.0-5.0wt%.Be lower than at the polyoxyethylene glycol molecular-weight average under 300 the situation, it can go wrong usually with regard to the emulsifying stability of the finished product, produces the defective that forms separating layer.Be lower than in add-on under the situation of 3.0wt%, can not reach bating effect usually, and under the situation of its addition, after the existence washing the residual defective of polynary higher alcohols is arranged greater than 5.0wt%.
In addition, according to a specific embodiments of the present invention, a kind of organic amine compound as monoethanolamine, diethanolamine and trolamine, preferably uses with one or both or multiple mixture, and its usage quantity is 1.0-2.5wt%.
Consumption at this compound is lower than under the situation of 1.0wt%, may not reach suitable product viscosity usually, and under the situation of consumption greater than 2.5wt% of this compound, it produces causes the high basicity of unnecessary modification for usually wool or silk fabric.
A further specific embodiments of the present invention is to contain 10-15wt%D-Limonene, 0.5 the higher fatty acid of-1.5wt%, the emulsifying agent of 15-35wt%, 1.0 add the propylene glycol of 1.0-10.0wt% in the composition of the amine of-2.5wt% and the polynary higher alcohols of 3.0-5.0wt%, it can prevent washing composition freezing and be stable being low to moderate under 20 ℃ in the storage process in the winter time very effectively.Be higher than in content of propylene glycol under the situation of 10wt%, it loses emulsifying stability usually, and is lower than under the situation of 1.0wt% common inaccessible anti-freeze effect in content of propylene glycol.
With respect to the whole water yields in the washing machine, when the composition among use the present invention, the concentration of preferred D-Limonene is that 0.01-0.2wt% is to reach maximum detersive efficiency in the washing water.
According to another specific embodiments of the present invention, remove above-mentioned oil base component D-Limonene, higher fatty acid, outside emulsifying agent and the polynary higher alcohols, all the other components of detergent composition preferably contain one and comprise water, the water base component of trolamine and propylene glycol.
Like this, above-mentioned latex detergent composition of the present invention, it is mainly preferably by D-Limonene, higher fatty acid, emulsifying agent, polynary higher alcohols and organic amine compound are formed by the proportioning of specific requirement, produce tangible washing effect, they prevent to wash back wool or silk distortion and shrink to keep dimensionally stable, they have improved dye separation and electrostatic and have produced, and they have a kind of anti-freeze effect, so they are favourable as various fabric washing composition.
Below, the present invention specifically describes by the embodiment of following various embodiments, but the present invention is not limited to these specific embodiments.
Embodiment 1～4, comparative example 1～3
According to the listed stoicheiometry of table 1, aqueous portion and oil phase part under 55-60 ℃ condition, utilize an Agihomo mixing tank 500-3000 rev/mins of following thorough mixing 15-30 minutes to produce a detergent composition.
Table 1 (unit: wt%)
| Component | Embodiment | Comparative example | |
| ????1????2????3????4 | ??1?????2?????3 | ||
| Oil phase component | D-Limonene (1) | ???19.0?30.5?21.5?21.5 | ??-??????-?????- |
| Isoparaffin (2) | ?????-?????-???-????- | ??21.5???-?????- | |
| Naphthenic hydrocarbon (3) | ????-?????-???-?????- | ??-????21.5????- | |
| Kerosene | ????-????-???-??????- | ??-?????-??????21.5 | |
| Stearic acid | ????-????-???1.5????- | ??-?????-??????- | |
| Oleic acid | ???2.5??2.5??1.5??1.5 | ??2.5???2.5????2.5 | |
| The inferior ethoxy propylidene of oxygen alkyl oxide (4) | ???9.0??9.0??12.0?12.0 | ?9.0???9.0?????9.0 | |
| Oxygen ethylidene oxygen propylidene alkyl phenylate (5) | ???3.5??3.0???-????4.0 | ?3.5????3.5????3.5 | |
| Oxygen ethylidene lauryl ether (6) | ???7.5?7.0???4.0???4.0 | ?7.5????7.5????7.5 | |
| Oxygen ethylidene alkyl phenylate (7) | ??5.0??7.O???4.0???4.0 | ?5.0????5.0????5.0 | |
| Polynary higher alcohols (8) | ??4.0??4.0???4.0???4.0 | ?4.0????4.0????4.0 | |
| Antioxidant (9) | ??0.1??0.1???0.1???0.1 | ?0.1????0.1????0.1 | |
| The water component | Water | ??47.6?35.9??47.0??41．5 | ?45.1??45.1???45.1 |
| Polyoxyethylene glycol | ??-????-?????3.0????6.0 | ??-??????-??????- | |
| Trolamine | ?1.8??1.0????1.4????1.4 | ?1.8????1.8????2.0 | |
(notes :)
(1) uses D-Limonene (a kind of Cargill, the product of Brazil)
(2) use Isopa4-H (a kind of Exxon, the product of U.S.A)
(3) use Actrel-1047 (a kind of Exxon, the product of U.S.A)
(4) use SL-62 (a kind of OLIN, the product of U.S.A.)
(5) use RCS-48 (a kind of OLIN, the product of U.S.A)
(6) use LA-7N (a kind of Poliol, the product of KOREA)
(7) use NP-5 (a kind of poliol, the product of KOREA)
(8) use PEG-400 (a kind of Poliol, the product of KOREA)
(9) use BHT (a kind of Jin Yang Chemistry Co.Ltd., the product of KOREA)
Comparative example 4～7
Various components are added according to the listed stoicheiometry of table 2 and under 55-60 ℃ condition, utilize an agitator to produce a kind of detergent composition 500-3000 rev/mins of uniformly emulsifies 20 minutes with thorough mixing.
Table 2
(unit: wt%)
| Component | Comparative example | |||
| ????4 | ????5 | ?6 | ????7 | |
| Sodium alkanesulfonate (1)Tetrachloroethylene linear alkylbenzene sulphonic acid straight chained alkyl sodium sulfonate oxygen ethylidene alkyl oxide (2)Natrium citricum sodium metasilicate sodium carbonate sodium nitrilo triacetate β-firpene terpinolene phenmethylol glycol hexyl ether quinene sodium sulfonate water | ????4.5 ????- ????- ????- ????2.0 ????3.5 ????- ????3.0 ????- ????- ????- ????2.0 ????- ????2.0 ????83.0 | ????- ????- ????4.0 ????- ????2.0 ????- ????- ????- ????6.0 ????3.0 ????- ????1.5 ????- ????2.0 ????81.5 | ?6.0 ?- ?- ?- ?0.5 ?8.0 ?1.0 ?- ?- ?- ?2.0 ?- ?2.0 ?2.0 ?78.5 | ????- ????99.3 ????- ????0.7 ????- ????- ????- ????- ????- ????- ????- ????- ????- ????- ????- |
(notes)
(1) uses Hostapur sts (a kind of HOECHST, the product of GERMANY)
(2) use Dobanol 91-8 (a kind of Shell, the product of U.S.A)
Experimental example 1
The sample of table 1 and table 2 composition is tested by the shrink effect of measuring after various original fabrics are washed, and test result is listed in table 3.These tests are carried out under following condition.The original fabrics of preparing: wool, silk, polyester and acetate fabric.Pre-treatment: is to wash once under the 2g/l with washing powder 20 ℃ of concentration, and flushing once, then the size of dry (65 ℃ of following 30min) original fabrics: 9cm * 9cm washing methods: 1. embodiment 1～4, comparative example 1～6; Corresponding original fabrics is embathed with the respective samples of 0.5g/l, dewaters, seasoning and ironing (embathe condition: (1) Shi Wen @20 minute, (2) Shi Wen @1 hour, (3) Shi Wen @24 hour, (4) 50 ℃ @20 minutes).
2. comparative example 7
(1) first operation: sample and 150ml tetrachloroethylene, 1ml dry cleaning composition and 100 hard balls place washing machine and close the lid; Washing machine is at 27 ℃, and operation is 10 minutes under the room temperature, gives off scrub raffinate then.
(2) second operations: the 150ml tetrachloroethylene is placed washing machine, move 10 minutes, discharge solution then.
(3) the 3rd operations: repeat second operation.Take out sample and sample is placed between the paper to utilize flatiron to remove solution, then at air drying.The processing of this sample is finished by following a kind of method.
(4) hand-ironed: the sample water-wet, and use with respect to dry weight and wring out to a 135～153g/m who contains 75% moisture
3Wet plain goods cover, then 135～150 ℃ of following pressings until drying.
(5) steam ironing: level and smooth fabric under hott bed or level and smooth metallic surface with 448～482KPa (vapour pressure flatiron of 65～70Psi), an and coarse wrinkle yarn woven fabric presses under the surface that piece of cloth material covers.Fall to compress fabric, fabric Steam Press 5～10 seconds the front portion of machine.
Table 3 (unit: warp/latitude contraction percentage (%))
See that from top shrink percentage result the composition exhibiting among the embodiment embodiment 1～4 goes out usually and the irrelevant good result of original fabrics kind.
Simultaneously, can see in the comparative example 1～6 that composition has demonstrated washing back wool and the fine fabric of vinegar and shunk terribly, the percentage that wherein shrinks increases greatly with embathing time lengthening, and the shrink percentage is not subjected to the fabric washing Temperature Influence.
Comparative example 7 is the results that obtain according to former dry cleaning process, and has demonstrated the shrinkproof result similar to the present composition.Consider that washing normally at room temperature carries out 15min, this point is listed in table 3, can see that composition exhibiting of the present invention goes out the washing shrinkage more much lower than comparative example composition, has good shrinkproof result under the condition of fully soaking 1 hour under the room temperature.
Experimental example 2
Listed composition sample is tested it according to the ASTMD4256 method and is removed the ability of staiing on two kinds of original fabrics in last table 1 and the table 2, the results are shown in table 4.Test condition is as follows:
The original fabrics of preparing: wool, silk fabric
Pre-treatment: with concentration be 2g/l washing powder solution 20 ℃ down washing once, and flushing is once, seasoning then.
Original fabrics size: 15cm * 15cm
Stain material: coffee, wine, machine oil and Sucus Vitis viniferae
The contamination method: on every original fabrics, drip 0.205cc (5) and stain material, after 20 minutes at 65 ℃ dry 3 minutes down (except that dry 1 hour of Sucus Vitis viniferaes).
Washing methods:
1. embodiment 1～4, comparative example 1～6
Fabric soaked 20 minutes with the corresponding sample of 0.5g/l, dehydration and seasoning.
2. comparative example 7
Washing methods is with the experiment 1 of top embodiment.
The decontamination index calculation formula=
C: washed nonstaining source textile
W: the source textile after the washed contamination
L: reflectance
A: red/green
B: Huang/indigo plant
See that from the test of top relevant decontamination the composition of comparative example 1～7 all demonstrates good washing effect except that machine oil is stain.
Yet the composition exhibiting of embodiment 1～4 goes out the washing effect better than comparative example 1～7.
Correspondingly, with regard to shrinkproof result and soil removability, the composition among the embodiment 1-4 really is used as a kind of washing composition.
Experimental example 3
The listed composition sample storage stability under winter low temperature in the table 1 on the mensuration.
Table 5 has been listed the experimental result that the method according to the test chill point of stipulating among the KSM2142 records.
Table 4
| Decontamination index | |||
| Sample | Embodiment | Comparative example | |
| Original fabrics | Stain material | ?1??2??3??4 | ?1??2??3??4??5??6??7 |
| Wool | Coffee red wine machine oil Sucus Vitis viniferae | ?99?99?99?99 ?99?99?99?99 ?40?55?41?50 ?98?99?99?99 | ?99?99?99?99?99?99?99 ?99?99?99?99?99?99?99 ?32?34?31?50?42?47?51 ?97?96?96?93?92?90?93 |
| Silk | Coffee red wine machine oil Sucus Vitis viniferae | ?99?99?99?99 ?99?99?98?99 ?50?56?51?50 ?98?98?98?98 | ?99?99?99?98?97?97?96 ?98?99?98?96?94?96?96 ?47?43?46?34?40?42?37 ?96?96?97?94?94?96?95 |
See by following freezing temperature, under-10～-15 ℃ of significant temps, still demonstrate stability even contain the composition of propylene glycol, and comparatively speaking those compositions that do not contain propylene glycol may reach very high viscosity when demonstrate freeze very big when storing winter.
Table 5
| Types of compositions | Embodiment 3 | Embodiment 4 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Freezing temperature (℃)) | ????-10 | ????-15 | ????-4 | ????-3 | ?????-4 |
Claims (9)
1. detergent composition that is used for clothing that contains D-Limonene and a kind of emulsifying agent.
2. according to the detergent composition of claim 1, wherein with respect to whole detergent composition weight, the usage quantity of said D-Limonene is in the scope of 10-35wt%, and the usage quantity of said emulsifying agent is in 15-35wt% scope.
3. according to the detergent composition of claim 1 or 2, further contain the higher fatty acid of 0.5-1.5wt%, the polynary higher alcohols of 3.0-5.0wt% and the organic amine compound of 1.0-2.5wt%.
4. according to the detergent composition of claim 3, further contain quantity at the propylene glycol in 1-10wt% scope.
5. according to the detergent composition of claim 3, wherein higher fatty acid is by stearic acid, the mixture of one or more in oleic acid and the palmitinic acid form a group.
6. according to the detergent composition of claim 3, wherein said emulsifying agent is by oxygen ethylidene oxygen propylidene alkyl oxide, a kind of mixture of two or more in the oxygen ethylidene oxygen propyl group alkyl phenylate, oxygen ethylidene lauryl ether and oxygen ethylidene alkyl phenylate form a group.
7. according to the detergent composition of claim 3, wherein said polynary higher alcohols is that molecular-weight average is at the polyoxyethylene glycol in 300-600 scopes.
8. according to the detergent composition of claim 3, wherein said organic amine compound is by monoethanolamine, the mixture of one or more in diethanolamine and the trolamine form a group.
9. according to the cleaning composition of claim 1, wherein said detergent composition is used for washed wool, silk or hemp cloth.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1993-6641 | 1993-04-20 | ||
| KR930006641 | 1993-04-20 | ||
| KR1994-5940 | 1994-03-24 | ||
| KR1019940005940A KR960011675B1 (en) | 1993-04-20 | 1994-03-24 | Cleaning compositions for textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1121353A true CN1121353A (en) | 1996-04-24 |
Family
ID=26629618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94191831A Pending CN1121353A (en) | 1993-04-20 | 1994-04-20 | A composition of detergent for clothing |
Country Status (6)
| Country | Link |
|---|---|
| KR (1) | KR960011675B1 (en) |
| CN (1) | CN1121353A (en) |
| AU (1) | AU6513894A (en) |
| BR (1) | BR9406279C1 (en) |
| GB (1) | GB2291650A (en) |
| WO (1) | WO1994024252A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104419541A (en) * | 2013-08-22 | 2015-03-18 | 南通丝乡丝绸有限公司 | Silk washing agent |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU1249895A (en) * | 1994-12-02 | 1996-06-19 | Daewoo Electronics Co., Ltd. | Detergent composition and method for washing using the same |
| CN111979059A (en) * | 2020-08-31 | 2020-11-24 | 上海申仰实业有限公司 | Cleaning agent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5414406A (en) * | 1977-07-05 | 1979-02-02 | Dotolo V | Deterging compositions |
| US4511488A (en) * | 1983-12-05 | 1985-04-16 | Penetone Corporation | D-Limonene based aqueous cleaning compositions |
| US4620937A (en) * | 1985-02-11 | 1986-11-04 | Joseph Dellutri | All purpose cleaner containing D-Limonene |
| JPS63159500A (en) * | 1986-12-24 | 1988-07-02 | ライオン株式会社 | Gel detergent |
-
1994
- 1994-03-24 KR KR1019940005940A patent/KR960011675B1/en not_active IP Right Cessation
- 1994-04-20 AU AU65138/94A patent/AU6513894A/en not_active Abandoned
- 1994-04-20 CN CN94191831A patent/CN1121353A/en active Pending
- 1994-04-20 WO PCT/KR1994/000035 patent/WO1994024252A1/en active Search and Examination
- 1994-04-20 GB GB9521357A patent/GB2291650A/en not_active Withdrawn
- 1994-04-20 BR BR9406279-0A patent/BR9406279C1/en active Search and Examination
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104419541A (en) * | 2013-08-22 | 2015-03-18 | 南通丝乡丝绸有限公司 | Silk washing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2291650A (en) | 1996-01-31 |
| BR9406279A (en) | 1996-01-02 |
| KR960011675B1 (en) | 1996-08-29 |
| GB9521357D0 (en) | 1995-12-20 |
| WO1994024252A1 (en) | 1994-10-27 |
| BR9406279C1 (en) | 2002-04-16 |
| AU6513894A (en) | 1994-11-08 |
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