CN108587806A - A kind of preparation method of dry cleaning agent - Google Patents
A kind of preparation method of dry cleaning agent Download PDFInfo
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- CN108587806A CN108587806A CN201810518920.0A CN201810518920A CN108587806A CN 108587806 A CN108587806 A CN 108587806A CN 201810518920 A CN201810518920 A CN 201810518920A CN 108587806 A CN108587806 A CN 108587806A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
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- C11D3/046—Salts
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/185—Hydrocarbons cyclic
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/37—Polymers
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- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
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Abstract
The invention discloses a kind of preparation methods of dry cleaning agent, belong to household chemicals technical field.The flavonoids that the present invention is extracted using grape leaf as raw material, organic acid, the fat-soluble antibacterial chemical substance of tannin class coordinates with natural activity monoterpene D limonenes, with albumen lecithin, D limonenes, carbomer is raw material, prepare limonene-carbomer emulsion, so that there is dry cleaning agent system the construction unit specific surface area of interior three-dimensional network structure to increase, surface tension increases, carbomer dispersion liquid forms hydrogen bond in system, generate stronger mucous gels network structure, play thickening power, to make system stability further be promoted, realize that forming physical intersection to system interior three-dimensional network structure tangles, wrap up antipathogenic composition, it can keep lasting fungistatic effect.The present invention solves at present that common dry cleaning agent degreasing is relatively difficult, and is easy to grow bacterium in clothing, can be to healthy and safe the problem of threatening of wearer.
Description
Technical field
The present invention relates to household chemicals technical field, more particularly to a kind of preparation method of dry cleaning agent.
Background technology
Dry-cleaning industry experienced the blank phase of previous decades in China, to today in Chinese true development also with regard to the more than ten years
History, but be comparatively still not perfect, make a general survey of the dry-cleaning development history of All Around The World, it live as the house of people one
Part, one section of marvellous road of having passed by can be seen that dry-cleaning industry from the operation of cassie Asia dry-cleaning for many years and be intended to global outstanding
It shows a dry-cleaning heat in China.With the development of society, people's living standards continue to improve, the continuous of rhythm of life adds
Soon, people require the dress and maintenance of clothes higher and higher, constantly pursue it is convenient, healthy, quick, leisure, diversification and it is a
Property, and then drive flourishing for the industries such as garment dry cleaning, dyeing, renovation and flavoring beauty.Dry-cleaning refers to using chemical solution
A kind of method that clothing is washed in agent compensates for the defects of shrink of silk wool fabric, fiber are hardened in water-washing process, to
Rapid development is being obtained in recent decades.When being dry-cleaned to fabric, dry cleaning agent be fabric, clothing washing quality it is important
Ensure.Dry cleaning agent refers to non-water system, with organic solvent liquid detergent as main component.It is mainly used for washing oiliness dirt
Dirt, clothes is indeformable after washing, and shrink-proof is for washing the clothings such as various advanced silks, woollen, leather.It is widely used at present
Dry cleaning agent include following four class：Petroleum solvent dry cleaning agent, tetrachloroethylene dry-cleaning agent, Freon solvent dry cleaning agent and liquid dioxy
Change carbon dry cleaning agent.In dry cleaning processes, nonaqueous solvents, can be relatively easily by oil-soluble dirt to the affinity interaction of oil stains dirt
It is dissolved out from fabric, is distributed in nonaqueous solvents under mechanical action, and make to be wrapped in solia particle therein and fall off.Separately
On the one hand, nonaqueous solvents is almost helpless to hydrophilic stains, therefore a small amount of water and appropriate is added in nonaqueous solvents
Surfactant, achieve the purpose that remove hydrophilic stains.To which dry cleaning technology only uses petroleum hydrocarbon as solvent from initial
Hand washing, develop to the full-automatic mechanical cleaning of addition surfactant and auxiliary agent, cleaning performance becomes better and better.In recent years
Come, various detergent release one after another, these products typically just use the laundry liquid formulation technology of concentration, and detergency is not strong；
Even if protease is added, since only with the general stabilizer such as calcium chloride, protease causes product to protein-based dirt after inactivating
The detergency of dirt declines to a great extent；Or only with common alcohols solvent, the fast of product can not be improved compared with conventional detergent
Fast permeance property and dissolving function to oily dirt, can not be such that enzyme preparation is given full play to egg within the prewashing shorter time
The decomposition of white matter class dirt.90% of dry cleaning agent used in the country is tetrachloro-ethylene at present, and tetrachloro-ethylene is that have certain poison
Property and stronger volatile organic solvent.High concentration tetrachloro-ethylene has local stimulation and nervous system anesthetic effect, can generate
Liver kidney poison endangers, and skin contact can lead to dermatitis and eczema.
Invention content
The technical problems to be solved by the invention：It is relatively difficult for current common dry cleaning agent degreasing, and hold in clothing
Bacterium is easily grown, a kind of preparation method of dry cleaning agent can be provided to healthy and safe the problem of threatening of wearer.
In order to solve the above technical problems, the present invention is using technical solution as described below：
A kind of preparation method of dry cleaning agent includes the following steps：
（1）Grape leaf is taken, cleans, dry, pulverize sieving, takes sieving particle in mass ratio 1：7 ~ 10 are dipped in ethyl acetate, stir
30 ~ 50min is mixed, 2 ~ 4h is stood in 20 ~ 35 DEG C, obtains mixed liquor, take mixed liquor 15 ~ 25min of ultrasonic wave extraction, be evaporated under reduced pressure, very
Sky is dry, obtains medicinal extract, takes medicinal extract in mass ratio 1：1~2：5 addition sodium citrates, deionized water are mixed evenly, and obtain antibacterial carry
Liquid is taken, it is spare；
（2）In mass ratio 1：12 ~ 16 take albumen lecithin, the mixing of D- limonenes, stir 1 ~ 1.5h, obtain mixed liquid, take mixed liquid by matter
Measure ratio 3：0.5~1：2：10, which are added carbomer, dimethyl silicone polymer, water, is uniformly mixed, and stirs 40 ~ 60min, ultrasonication
10 ~ 15min obtains limonene-carbomer emulsion；
（3）According to the mass fraction, 20 ~ 30 parts of tetrachloro-ethylenes, 18 ~ 15 parts of steps are taken（1）In spare antibacterial extracting solution, 6 ~ 12 parts
Limonene-carbomer emulsion, 5 ~ 10 parts of Emulsifier EL-60s, 3 ~ 8 portions of coconut oil, 15 ~ 25 parts of dipropylene glycol n-butyl ethers, 3
~ 8 parts of N- methylpyrroles, 5 ~ 10 parts of auxiliary agents, 5 ~ 10 parts of dispersants, 3 ~ 6 parts of thickeners, 8 ~ 15 parts of acetone, 2 ~ 5 parts of essence, 20 ~ 40
Part water；
（4）In 25 ~ 30 DEG C, take tetrachloro-ethylene, limonene-carbomer emulsion, Emulsifier EL-60, coconut oil, acetone,
Essence, dipropylene glycol n-butyl ether, water mixing, stir 30 ~ 50min, are warming up to 45 ~ 60 DEG C, antibacterial extracting solution, N- methyl pyrroles is added
It coughs up, the mixing of auxiliary agent, dispersant, thickener, ultrasonic wave disperses 10 ~ 15 minutes to get dry cleaning agent.
The step（4）In auxiliary agent be in mass ratio 3:4:1 ~ 2 ferric oxalate, ferric sulfate, hydrogen peroxide mix to get helping
Agent.
The step（4）In dispersant be fatty alcohol polyoxyethylene ether, polyglyceryl fatty acid ester, secondary alcohol polyoxyethylene ether
In any one.
The step（4）In thickener be in mass ratio 2:1 takes polyacrylate, alumina silicate mixing to get thickener.
Compared with other methods, advantageous effects are the present invention：
Flavonoids, organic acid, the fat-soluble antibacterial chemical substance of tannin class and the natural work that the present invention is extracted using grape leaf as raw material
Property monoterpene D- limonenes cooperation, fungistatic effect is notable, nontoxic, non-stimulated to human body, with albumen lecithin, D- limonenes,
Carbomer is raw material, prepares limonene-carbomer emulsion, can give full play to decontamination and the fungistatic effect of D- limonenes, is made
Emulsion so that dry cleaning agent system have interior three-dimensional network structure construction unit specific surface area increase, surface tension increase
Greatly, make other ingredients that system carries also can stable sustained-release work the restriction effect of oil and water inside system when dry cleaning agent uses
With improving the clean effect of dry cleaning agent, carbomer dispersion liquid forms hydrogen bond in system, generates stronger mucous gels network
Structure plays thickening power, and to make system stability further be promoted, a large amount of carboxylics are contained in carbomer molecular structure
Base after carboxyl small part is neutralized, in that can make carboxylic ions, due to the repulsive interaction of negative electrical charge, makes carbomer molecule
Disperse is stretched, at great swelling state, to realize that forming physical intersection to system interior three-dimensional network structure tangles, packet
Antipathogenic composition is wrapped up in, lasting fungistatic effect can be kept.
Specific implementation mode
Auxiliary agent：In mass ratio 3:4:1 ~ 2 ferric oxalate, ferric sulfate, hydrogen peroxide mixing are to get auxiliary agent.
Dispersant：Any one in fatty alcohol polyoxyethylene ether, polyglyceryl fatty acid ester, secondary alcohol polyoxyethylene ether.
Thickener：In mass ratio 2:1 takes polyacrylate, alumina silicate mixing to get thickener.
A kind of preparation method of dry cleaning agent, includes the following steps：
（1）Take grape leaf, cleaned with 5 ~ 6 times of water of grape leaf quality, after move to 60 ~ 70 DEG C of oven dryings, obtain dried object, take
Dried object crushed 80 mesh sieve, take sieving particle in mass ratio 1：7 ~ 10 are dipped in ethyl acetate, are stirred with 250 ~ 300r/min
30 ~ 50min, after 2 ~ 4h is stood at a temperature of 20 ~ 35 DEG C, obtain mixed liquor, take mixed liquor with 300W 15 ~ 25min of ultrasonic wave extraction,
Recycling ethyl acetate is evaporated under reduced pressure afterwards, vacuum drying obtains medicinal extract, takes medicinal extract in mass ratio 1：1~2：5 addition sodium citrates, go from
Sub- water is mixed evenly, and obtains antibacterial extracting solution, spare in 4 DEG C of refrigerations；
（2）In mass ratio 1：12 ~ 16 take albumen lecithin, the mixing of D- limonenes, magnetic stirrer are placed in, with 250 ~ 350r/min
1 ~ 1.5h is stirred, mixed liquid is obtained, takes mixed liquid in mass ratio 3：0.5~1：2：10 are added carbomer, dimethyl silicone polymer, water mixing
Uniformly, 40 ~ 60min is stirred with 350 ~ 450r/min, with 250W 10 ~ 15min of ultrasonication, obtains limonene-carbomer emulsification
Liquid；
（3）According to the mass fraction, 20 ~ 30 parts of tetrachloro-ethylenes, 18 ~ 15 parts of steps are taken（1）In spare antibacterial extracting solution, 6 ~ 12 parts
Limonene-carbomer emulsion, 5 ~ 10 parts of Emulsifier EL-60s, 3 ~ 8 portions of coconut oil, 15 ~ 25 parts of dipropylene glycol n-butyl ethers, 3
~ 8 parts of N- methylpyrroles, 5 ~ 10 parts of auxiliary agents, 5 ~ 10 parts of dispersants, 3 ~ 6 parts of thickeners, 8 ~ 15 parts of acetone, 2 ~ 5 parts of essence, 20 ~ 40
Part water；
（4）In 25 ~ 30 DEG C of water-bath, tetrachloro-ethylene, limonene-carbomer emulsion, Emulsifier EL-60, coconut oil, third are taken
Ketone, essence, dipropylene glycol n-butyl ether, water mixing, with 230 ~ 280r/min, 30 ~ 50min of magnetic agitation, after be warming up to 45 ~ 60 DEG C,
Antibacterial extracting solution, N- methylpyrroles, auxiliary agent, dispersant, thickener mixing is added, ultrasonic wave disperses 10 ~ 15 minutes to get dry-cleaning
Agent.
Embodiment 1
Auxiliary agent：In mass ratio 3:4:1 ferric oxalate, ferric sulfate, hydrogen peroxide mixing are to get auxiliary agent.
Dispersant：Any one in fatty alcohol polyoxyethylene ether, polyglyceryl fatty acid ester, secondary alcohol polyoxyethylene ether.
Thickener：In mass ratio 2:1 takes polyacrylate, alumina silicate mixing to get thickener.
A kind of preparation method of dry cleaning agent, includes the following steps：
（1）Take grape leaf, cleaned with 5 times of water of grape leaf quality, after move to 60 DEG C of oven dryings, obtain dried object, take drying
Object crushed 80 mesh sieve, take sieving particle in mass ratio 1：7 are dipped in ethyl acetate, with 250r/min stir 30min, after 20
2h is stood at a temperature of DEG C, obtains mixed liquor, takes mixed liquor with 300W ultrasonic wave extraction 15min, rear be evaporated under reduced pressure recycles ethyl acetate,
Vacuum drying, obtains medicinal extract, takes medicinal extract in mass ratio 1：1：5 addition sodium citrates, deionized water are mixed evenly, and obtain antibacterial carry
Liquid is taken, it is spare in 4 DEG C of refrigerations；
（2）In mass ratio 1：12 take albumen lecithin, the mixing of D- limonenes, are placed in magnetic stirrer, 1h is stirred with 250r/min,
Liquid must be mixed, mixed liquid in mass ratio 3 is taken：0.5：2：10, which are added carbomer, dimethyl silicone polymer, water, is uniformly mixed, with 350r/
Min stirrings 40min obtains limonene-carbomer emulsion with 250W ultrasonication 10min；
（3）According to the mass fraction, 20 ~ 30 parts of tetrachloro-ethylenes, 18 ~ 15 parts of steps are taken（1）In spare antibacterial extracting solution, 6 ~ 12 parts
Limonene-carbomer emulsion, 5 ~ 10 parts of Emulsifier EL-60s, 3 ~ 8 portions of coconut oil, 15 ~ 25 parts of dipropylene glycol n-butyl ethers, 3
~ 8 parts of N- methylpyrroles, 5 ~ 10 parts of auxiliary agents, 5 ~ 10 parts of dispersants, 3 ~ 6 parts of thickeners, 8 ~ 15 parts of acetone, 2 ~ 5 parts of essence, 20 ~ 40
Part water；
（4）In 25 DEG C of water-bath, take tetrachloro-ethylene, limonene-carbomer emulsion, Emulsifier EL-60, coconut oil, acetone,
Essence, dipropylene glycol n-butyl ether, water mixing, with 230r/min magnetic agitation 30min, after be warming up to 45 DEG C, antibacterial extraction is added
Liquid, N- methylpyrroles, auxiliary agent, dispersant, thickener mixing, ultrasonic wave disperse 10 minutes to get dry cleaning agent.
Embodiment 2
Auxiliary agent：In mass ratio 3:4:1.5 ferric oxalates, ferric sulfate, hydrogen peroxide mixing are to get auxiliary agent.
Dispersant：Any one in fatty alcohol polyoxyethylene ether, polyglyceryl fatty acid ester, secondary alcohol polyoxyethylene ether.
Thickener：In mass ratio 2:1 takes polyacrylate, alumina silicate mixing to get thickener.
A kind of preparation method of dry cleaning agent, includes the following steps：
（1）Take grape leaf, cleaned with 5.5 times of water of grape leaf quality, after move to 65 DEG C of oven dryings, obtain dried object, take dry
Dry object crushed 80 mesh sieve, take sieving particle in mass ratio 1：8 are dipped in ethyl acetate, with 280r/min stir 40min, after
3h is stood at a temperature of 28 DEG C, obtains mixed liquor, takes mixed liquor with 300W ultrasonic wave extraction 20min, it is rear that recycling acetic acid second is evaporated under reduced pressure
Ester, vacuum drying, obtains medicinal extract, takes medicinal extract in mass ratio 1：1.5：5 addition sodium citrates, deionized water are mixed evenly, and obtain
Antibacterial extracting solution, it is spare in 4 DEG C of refrigerations；
（2）In mass ratio 1：14 take albumen lecithin, the mixing of D- limonenes, are placed in magnetic stirrer, are stirred with 300r/min
1.3h obtains mixed liquid, takes mixed liquid in mass ratio 3：0.8：2：10, which are added carbomer, dimethyl silicone polymer, water, is uniformly mixed, with
400r/min stirrings 50min obtains limonene-carbomer emulsion with 250W ultrasonication 13min；
（3）According to the mass fraction, 20 ~ 30 parts of tetrachloro-ethylenes, 18 ~ 15 parts of steps are taken（1）In spare antibacterial extracting solution, 6 ~ 12 parts
Limonene-carbomer emulsion, 5 ~ 10 parts of Emulsifier EL-60s, 3 ~ 8 portions of coconut oil, 15 ~ 25 parts of dipropylene glycol n-butyl ethers, 3
~ 8 parts of N- methylpyrroles, 5 ~ 10 parts of auxiliary agents, 5 ~ 10 parts of dispersants, 3 ~ 6 parts of thickeners, 8 ~ 15 parts of acetone, 2 ~ 5 parts of essence, 20 ~ 40
Part water；
（4）In 28 DEG C of water-bath, take tetrachloro-ethylene, limonene-carbomer emulsion, Emulsifier EL-60, coconut oil, acetone,
Essence, dipropylene glycol n-butyl ether, water mixing, with 260r/min magnetic agitation 40min, after be warming up to 55 DEG C, antibacterial extraction is added
Liquid, N- methylpyrroles, auxiliary agent, dispersant, thickener mixing, ultrasonic wave disperse 13 minutes to get dry cleaning agent.
Embodiment 3
Auxiliary agent：In mass ratio 3:4:2 ferric oxalates, ferric sulfate, hydrogen peroxide mixing are to get auxiliary agent.
Dispersant：Any one in fatty alcohol polyoxyethylene ether, polyglyceryl fatty acid ester, secondary alcohol polyoxyethylene ether.
Thickener：In mass ratio 2:1 takes polyacrylate, alumina silicate mixing to get thickener.
A kind of preparation method of dry cleaning agent, includes the following steps：
（1）Take grape leaf, cleaned with 6 times of water of grape leaf quality, after move to 70 DEG C of oven dryings, obtain dried object, take drying
Object crushed 80 mesh sieve, take sieving particle in mass ratio 1：10 are dipped in ethyl acetate, with 300r/min stir 50min, after
4h is stood at a temperature of 35 DEG C, obtains mixed liquor, takes mixed liquor with 300W ultrasonic wave extraction 25min, it is rear that recycling acetic acid second is evaporated under reduced pressure
Ester, vacuum drying, obtains medicinal extract, takes medicinal extract in mass ratio 1：2：5 addition sodium citrates, deionized water are mixed evenly, and must press down
Bacterium extracting solution, it is spare in 4 DEG C of refrigerations；
（2）In mass ratio 1：16 take albumen lecithin, the mixing of D- limonenes, are placed in magnetic stirrer, are stirred with 350r/min
1.5h obtains mixed liquid, takes mixed liquid in mass ratio 3：1：2：10, which are added carbomer, dimethyl silicone polymer, water, is uniformly mixed, with
450r/min stirrings 60min obtains limonene-carbomer emulsion with 250W ultrasonication 15min；
（3）According to the mass fraction, 20 ~ 30 parts of tetrachloro-ethylenes, 18 ~ 15 parts of steps are taken（1）In spare antibacterial extracting solution, 6 ~ 12 parts
Limonene-carbomer emulsion, 5 ~ 10 parts of Emulsifier EL-60s, 3 ~ 8 portions of coconut oil, 15 ~ 25 parts of dipropylene glycol n-butyl ethers, 3
~ 8 parts of N- methylpyrroles, 5 ~ 10 parts of auxiliary agents, 5 ~ 10 parts of dispersants, 3 ~ 6 parts of thickeners, 8 ~ 15 parts of acetone, 2 ~ 5 parts of essence, 20 ~ 40
Part water；
（4）In 30 DEG C of water-bath, take tetrachloro-ethylene, limonene-carbomer emulsion, Emulsifier EL-60, coconut oil, acetone,
Essence, dipropylene glycol n-butyl ether, water mixing, with 280r/min magnetic agitation 50min, after be warming up to 60 DEG C, antibacterial extraction is added
Liquid, N- methylpyrroles, auxiliary agent, dispersant, thickener mixing, ultrasonic wave disperse 15 minutes to get dry cleaning agent.
Comparative example：The dry cleaning agent of Bozhou City company production.
Embodiment 1,2,3 and comparative example are subjected to detergency test：Take the cotton that national standard MLBT4288-2008 is required as dirty
Stain cloth substrate coats soy sauce spot on its surface, for testing after its drying, is cut into the spot of 120 ╳ 120mm sizes
Cloth.Keg is fixed in the equipment of similar roller rotation by the keg for making 2L volume sizes, and simulation drum wash mode carries out
Detergency ability is tested, and takes the soiled cotton of 1 piece of 120 ╳ 120mm size, dry cleaning agent 1Kg, room temperature washing, wash time 30min, complete
Spot cloth, naturally dry are taken out after finishing, the concentration levels for testing spot cloth whiteness and bacterium are recorded in table 1.
Table 1：
In summary, dry cleaning agent dirt-removing power produced by the present invention is stronger it can be seen from detection data in upper table, thin in clothing
Bacterium is greatly reduced, and the health enabled a wearer to is protected, and has broad application prospects.
Claims (4)
1. a kind of preparation method of dry cleaning agent, which is characterized in that the preparation method includes the following steps：
（1）Grape leaf is taken, cleans, dry, pulverize sieving, takes sieving particle in mass ratio 1：7 ~ 10 are dipped in ethyl acetate, stir
Mixing is mixed, 2 ~ 4h is stood in 20 ~ 35 DEG C, obtains mixed liquor, take mixed liquor ultrasonic wave extraction
Extracting solution is obtained, extracting solution is taken to be evaporated under reduced pressure, is dried in vacuo, is obtained medicinal extract, take medicinal extract in mass ratio 1：1~2：5 are added citric acid
Sodium, deionized water are mixed evenly, and obtain antibacterial extracting solution, spare；
（2）In mass ratio 1：12 ~ 16 take albumen lecithin, the mixing of D- limonenes, stir 1 ~ 1.5h, obtain mixed liquid, take mixed liquid by matter
Measure ratio 3：0.5~1：2：10 addition carbomers, dimethyl silicone polymer, water are mixed evenly, and ultrasonication obtains lemon
Alkene-carbomer emulsion；
（3）According to the mass fraction, 20 ~ 30 parts of tetrachloro-ethylenes, 18 ~ 15 parts of steps are taken（1）In spare antibacterial extracting solution, 6 ~ 12 parts
Limonene-carbomer emulsion, 5 ~ 10 parts of Emulsifier EL-60s, 3 ~ 8 portions of coconut oil, 15 ~ 25 parts of dipropylene glycol n-butyl ethers, 3
~ 8 parts of N- methylpyrroles, 5 ~ 10 parts of auxiliary agents, 5 ~ 10 parts of dispersants, 3 ~ 6 parts of thickeners, 8 ~ 15 parts of acetone, 2 ~ 5 parts of essence, 20 ~ 40
Part water；
（4）In 25 ~ 30 DEG C, take tetrachloro-ethylene, limonene-carbomer emulsion, Emulsifier EL-60, coconut oil, acetone,
Essence, dipropylene glycol n-butyl ether, water be mixed, be warming up to 45 ~ 60 DEG C, be added antibacterial extracting solution, N- methylpyrroles, auxiliary agent,
Dispersant, thickener mixing, ultrasonic wave disperse to get dry cleaning agent.
2. the preparation method of dry cleaning agent according to claim 1, which is characterized in that the step（4）In auxiliary agent be by matter
Measure ratio 3:4:1 ~ 2 ferric oxalate, ferric sulfate, hydrogen peroxide mixing are to get auxiliary agent.
3. the preparation method of dry cleaning agent according to claim 1, which is characterized in that the step（4）In dispersant be fat
Any one in fat alcohol polyoxyethylene ether, polyglyceryl fatty acid ester, secondary alcohol polyoxyethylene ether.
4. the preparation method of dry cleaning agent according to claim 1, which is characterized in that the step（4）In thickener be by
Mass ratio 2:1 takes polyacrylate, alumina silicate mixing to get thickener.
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| CN104513709A (en) * | 2013-09-27 | 2015-04-15 | 天津普范科技开发有限公司 | Environmental-protection type fabric dry cleaning agent |
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