CN112090222A - Treatment method for treating waste gas of laboratory animal house in pharmaceutical enterprise - Google Patents

Treatment method for treating waste gas of laboratory animal house in pharmaceutical enterprise Download PDF

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Publication number
CN112090222A
CN112090222A CN202011008160.2A CN202011008160A CN112090222A CN 112090222 A CN112090222 A CN 112090222A CN 202011008160 A CN202011008160 A CN 202011008160A CN 112090222 A CN112090222 A CN 112090222A
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CN
China
Prior art keywords
treatment
waste gas
field
treatment tank
temperature
Prior art date
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Pending
Application number
CN202011008160.2A
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Chinese (zh)
Inventor
陈慧
王昌斌
吴刚
刘思川
刘文军
谭鸿波
郭晓英
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Sichuan Kelun Pharmaceutical Co Ltd
Original Assignee
Sichuan Kelun Pharmaceutical Co Ltd
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Filing date
Publication date
Application filed by Sichuan Kelun Pharmaceutical Co Ltd filed Critical Sichuan Kelun Pharmaceutical Co Ltd
Priority to CN202011008160.2A priority Critical patent/CN112090222A/en
Publication of CN112090222A publication Critical patent/CN112090222A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/806Microwaves

Abstract

The invention discloses a treatment method for treating waste gas of an experimental animal room of a pharmaceutical enterprise, and belongs to the technical field of waste gas treatment. The treatment method for treating the waste gas of the experimental animal room of the pharmaceutical enterprise comprises the following steps: introducing the exhaust gas into a treatment tank; constructing a microwave field in the treatment tank; constructing a UV ultraviolet light field in the treatment tank; introducing the waste gas treated by the microwave field and the UV lamp field into an adsorption tower; and constructing a plurality of activated carbon fiber filter layers in the adsorption tower, and performing adsorption deodorization treatment on the waste gas introduced into the adsorption tower. The waste gas treatment method provided by the invention can effectively treat the waste gas generated by the animal house and then discharge the waste gas after reaching the standard, fully considers the maturity and reliability of the process, and has the advantages of short process flow, simple required equipment, low treatment cost, stable system operation and convenient operation and management.

Description

Treatment method for treating waste gas of laboratory animal house in pharmaceutical enterprise
Technical Field
The invention relates to the technical field of waste gas treatment, in particular to a treatment method for waste gas treatment of laboratory animal rooms of pharmaceutical enterprises.
Background
At present, in some pharmaceutical factories, animal houses are built by themselves to raise some animals for animal experiments for convenience of making medicines, and the animals can generate some waste gas with smelly taste in the daily raising process, and if the waste gas is not treated and is directly discharged outdoors, the waste gas can cause great environmental pollution to factory areas and the periphery.
Disclosure of Invention
The invention aims to provide a treatment method for treating waste gas in laboratory animal rooms of pharmaceutical enterprises, aiming at solving the technical problems in the background technology.
In order to achieve the purpose, the invention adopts the following technical scheme:
a treatment method for treating waste gas of laboratory animal houses in pharmaceutical enterprises comprises the following steps: introducing the exhaust gas into a treatment tank; constructing a microwave field in the treatment tank; constructing a UV ultraviolet light field in the treatment tank; introducing the waste gas treated by the microwave field and the UV lamp field into an adsorption tower; and constructing a plurality of activated carbon fiber filter layers in the adsorption tower, and performing adsorption deodorization treatment on the waste gas introduced into the adsorption tower.
Further, the constructing a microwave field in the processing tank includes: and a microwave generator is arranged in the treatment tank to generate microwaves and control the microwaves to form a microwave field.
Further, the frequency of the microwave is 0.3-300 GHZ.
Further, the building a UV lamp field in a treatment tank includes: and a plurality of UV ultraviolet lamp tubes are arranged in the treatment tank to generate UV ultraviolet light and control the UV ultraviolet light to form a UV ultraviolet light field.
Further, the UV ultraviolet lamp tube is an electrodeless UV ultraviolet lamp tube.
Furthermore, the activated carbon fiber filter layer is formed by carbonizing and activating a fibrous precursor, so that more than 50% of carbon atoms are positioned on the inner surface and the outer surface of the fibrous precursor.
Further, the conditions for carbonizing the fibrous precursor are as follows: the temperature was set to 350-380 ℃ under nitrogen.
Furthermore, when the waste gas is treated by the microwave field and the UV lamp field in the treatment tank, the treatment tank is subjected to alternating temperature of temperature rise and temperature drop, so that the waste gas is treated by the microwave field and the UV lamp field under the alternating temperature condition of temperature rise and temperature drop.
Further, the maximum temperature of temperature rise is 75 ℃, and the minimum temperature of temperature drop is 30 ℃.
Furthermore, a plurality of activated carbon fiber filter layers constructed in the adsorption tower are arranged at equal intervals.
Compared with the prior art, the invention has the beneficial effects that:
the waste gas treatment method provided by the invention can effectively treat the waste gas generated by the animal house and then discharge the waste gas after reaching the standard, fully considers the maturity and reliability of the process, and has the advantages of short process flow, simple required equipment, low treatment cost, stable system operation and convenient operation and management.
Detailed Description
The present invention will be further described with reference to the following examples, which are intended to illustrate only some, but not all, of the embodiments of the present invention. Based on the embodiments of the present invention, other embodiments used by those skilled in the art without any creative effort belong to the protection scope of the present invention.
Example 1:
a treatment method for treating waste gas of laboratory animal houses in pharmaceutical enterprises comprises the following steps:
s100, introducing waste gas into a treatment tank;
this treatment tank adopts 304 stainless steel to make, if the treatment tank adopts carbon steel preparation, inside and outside spraying paint anticorrosive treatment, because the paint belongs to the organic matter, under UV ultraviolet beam irradiation, the destruction that the paint anticorrosive coating can be very fast, after the paint anticorrosive coating damaged, carbon steel equipment is very easily rusted and corroded, therefore equipment main part adopts 304 stainless steel preparation.
S200, constructing a microwave field in the treatment tank;
the constructing a microwave field in a treatment tank includes: and a microwave generator is arranged in the treatment tank to generate microwaves and control the microwaves to form a microwave field. The microwave described in this embodiment is an ultra-high frequency electromagnetic wave with a frequency of 0.3-300GHZ, and exhaust gas molecules in the microwave field will make hundreds of millions of violent movements per second following the microwave field, which greatly improves the chemical activity of exhaust gas molecule treatment.
The microwave energy excites the electrodeless UV lamp tube with high performance, high efficiency and long service life to radiate high-energy ultraviolet light mainly comprising 185 NM; 185NM belongs to high-energy C wave band, which can directly crack and destroy odor molecules. Meanwhile, ozone is generated after the reaction with oxygen in the air, the ozone has a strong oxidation effect, and simultaneously under the wave band ultraviolet radiation, the nano titanium dioxide catalyst is activated to react with surrounding water molecules to generate free radical OH < - >, and a molecular chain of waste gas is decomposed through OH < - >.
The nano titanium dioxide catalyst is coated on the multi-layer porous stainless steel metal plate arranged in the treatment tank, and the nano titanium dioxide catalyst is coated on the multi-layer porous stainless steel metal plate, so that the waste gas can be in contact with catalytic decomposition materials in a larger area, and the decomposition of waste gas components is accelerated.
S300, constructing a UV ultraviolet field in the treatment tank;
the building of a field of UV lamps in a treatment tank comprises: and a plurality of UV ultraviolet lamp tubes are arranged in the treatment tank to generate UV ultraviolet light and control the UV ultraviolet light to form a UV ultraviolet light field. The UV ultraviolet lamp tube is an electrodeless UV ultraviolet lamp tube.
At present, UV photoelectric decomposers on the market adopt ballasts and UV polarized lamps.
In terms of energy consumption, the power consumption of each ballast and the UV active lamp tube is between 120 and 150W, the power consumption of the electrodeless lamp tube is 50W, and the energy consumption of the electrodeless lamp tube is less than 1/2 of the active lamp tube; in terms of using performance, the magnetic induction generator excites the vapor mercury and inert gas in the electrodeless lamp tube by using magnetic induction microwave, and the light source without electrodes can not generate blackening phenomenon caused by the problems of electrode oxidation, loss and sealing like other discharge light sources.
The electrodeless light source has the advantages of easy shape change, quick start, stable light emission, high luminous efficiency and the like, and the characteristics of the electrodeless light source cannot be reached by an electrodeless lamp tube. The ballast of the polarized lamp tube belongs to a quick-wear part and is not resistant to high temperature, and the ballast can generate great heat when the lamp tube works, and if the ballast is in a high-temperature environment, the ballast is extremely easy to melt and damage.
S400, introducing the waste gas treated by the microwave field and the UV lamp field into an adsorption tower;
s500, constructing a plurality of activated carbon fiber filter layers in the adsorption tower, and performing adsorption deodorization treatment on the waste gas introduced into the adsorption tower.
The activated carbon fiber filtering layer is formed by carbonizing and activating a fibrous precursor, so that more than 50% of carbon atoms are positioned on the inner surface and the outer surface of the fibrous precursor. Wherein the fibrous precursor is carbonized under the following conditions: the temperature was set to 350-380 ℃ under nitrogen.
More than 50% of carbon atoms are positioned on the inner surface and the outer surface, a unique adsorption structure is constructed, and the fast adsorption and desorption speed and the large adsorption capacity are realized due to the more developed specific surface area and the narrower pore size distribution. The adsorption principle is physical adsorption, the adsorption process has reversibility and is easy to desorb and regenerate, and gas enters an adsorption tower through a pipeline, wherein a plurality of activated carbon fiber filter layers constructed in the adsorption tower are arranged at equal intervals. Equidistant setting is convenient for the segmentation to adsorb the processing to waste gas, has the efficient adsorption to poisonous and harmful gas, and it is fast to adsorb and desorption. And (4) generating a diffusion process between two different interfaces, finishing diffusion, and discharging the finally qualified tail gas into the atmosphere through an exhaust funnel at high altitude.
In this embodiment, when the microwave field and the UV lamp field in the treatment tank treat the exhaust gas, the treatment tank is subjected to alternating temperatures of temperature rise and temperature fall, so that the microwave field and the UV lamp field treat the exhaust gas under the alternating temperature conditions of temperature rise and temperature fall.
By applying alternating temperature of temperature rise and temperature drop to the microwave field and the UV ultraviolet lamp field in the treatment tank, the exhaust gas molecules in the microwave field can move more violently, and the chemical activity of the exhaust gas molecule treatment is greatly improved. The alternating temperature of raising and lowering the temperature is mainly used for balancing the improvement of the chemical activity and the safety of the molecular treatment of the waste gas, because a large amount of heat is generated in the waste gas treatment process, if the temperature is too high, the explosion danger exists, therefore, when the temperature in the treatment tank is detected to be too high, the temperature is lowered, and when the temperature is lower, the temperature is raised, so that the waste is treated in the optimal and safe temperature range.
Preferably, the maximum temperature of the temperature rise is 75 ℃, and the minimum temperature of the temperature decrease is 30 ℃.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.

Claims (10)

1. A treatment method for treating waste gas in laboratory animal rooms of pharmaceutical enterprises is characterized by comprising the following steps:
introducing the exhaust gas into a treatment tank;
constructing a microwave field in the treatment tank;
constructing a UV ultraviolet light field in the treatment tank;
introducing the waste gas treated by the microwave field and the UV lamp field into an adsorption tower;
and constructing a plurality of activated carbon fiber filter layers in the adsorption tower, and performing adsorption deodorization treatment on the waste gas introduced into the adsorption tower.
2. The treatment method for the treatment of the exhaust gas of the laboratory animal rooms of the pharmaceutical enterprises according to claim 1, wherein the construction of the microwave field in the treatment tank comprises the following steps: and a microwave generator is arranged in the treatment tank to generate microwaves and control the microwaves to form a microwave field.
3. The method as claimed in claim 2, wherein the frequency of the microwave is 0.3-300 GHZ.
4. The treatment method for the treatment of the exhaust gas of the laboratory animal house of the pharmaceutical enterprise according to claim 1, wherein the construction of the UV ultraviolet lamp field in the treatment tank comprises the following steps: and a plurality of UV ultraviolet lamp tubes are arranged in the treatment tank to generate UV ultraviolet light and control the UV ultraviolet light to form a UV ultraviolet light field.
5. The method as claimed in claim 1, wherein the UV lamp is an electrodeless UV lamp.
6. The treatment method for the treatment of the waste gas of the laboratory animal houses of the pharmaceutical enterprises as claimed in claim 1, wherein the activated carbon fiber filter layer is formed by carbonizing and activating a fibrous precursor, so that more than 50% of carbon atoms are located on the inner and outer surfaces of the fibrous precursor.
7. The treatment method for the treatment of the waste gas of the laboratory animal house of the pharmaceutical enterprise according to claim 6, wherein the carbonization condition of the fibrous precursor is as follows: the temperature was set to 350-380 ℃ under nitrogen.
8. The treatment method for the treatment of the waste gas in the laboratory animal rooms of the pharmaceutical enterprises according to any one of claims 1 to 7, wherein when the waste gas is treated by the microwave field and the UV lamp field in the treatment tank, the treatment tank is subjected to alternating temperatures of temperature rise and temperature fall, so that the waste gas is treated by the microwave field and the UV lamp field under the alternating temperature conditions of temperature rise and temperature fall.
9. The treatment method for the treatment of the exhaust gas of the laboratory animal room of the pharmaceutical enterprise according to claim 8, wherein the maximum temperature of the temperature rise is 75 ℃ and the minimum temperature of the temperature drop is 30 ℃.
10. The method as claimed in claim 1, wherein the activated carbon fiber filter layers are arranged at equal intervals.
CN202011008160.2A 2020-09-23 2020-09-23 Treatment method for treating waste gas of laboratory animal house in pharmaceutical enterprise Pending CN112090222A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007102701A1 (en) * 2006-03-07 2007-09-13 Puripax Co., Ltd. Photolysis and photocatalaysis air pollution treatment system using electrodeless uv lamp
CN103611418A (en) * 2013-11-26 2014-03-05 中国化学工业桂林工程有限公司 Joint treatment device and method for organic waste gas
CN104941382A (en) * 2015-06-11 2015-09-30 陆钢 Organic waste gas treatment device and method
CN105126611A (en) * 2015-09-16 2015-12-09 苏州韵蓝环保科技有限公司 Organic waste gas microwave deodorization purifier
CN206355830U (en) * 2016-12-16 2017-07-28 南通万年青环保科技有限公司 A kind of combined type exhaust gas purification equipment
CN206483338U (en) * 2017-01-25 2017-09-12 青岛明朗环境工程有限公司 A kind of efficient VOCs treatment equipment
CN208275246U (en) * 2018-02-11 2018-12-25 山东润圣环保科技有限公司 A kind of photochemical catalytic oxidation waste gas pollution control and treatment equipment
US20190209729A1 (en) * 2018-01-11 2019-07-11 Chengdu Tiantian Medical Electric Apparatus Science And Technology Co., Ltd. Multifunctional Microwave Plasma and Ultraviolet Light Deodorization Treatment Device

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007102701A1 (en) * 2006-03-07 2007-09-13 Puripax Co., Ltd. Photolysis and photocatalaysis air pollution treatment system using electrodeless uv lamp
CN103611418A (en) * 2013-11-26 2014-03-05 中国化学工业桂林工程有限公司 Joint treatment device and method for organic waste gas
CN104941382A (en) * 2015-06-11 2015-09-30 陆钢 Organic waste gas treatment device and method
CN105126611A (en) * 2015-09-16 2015-12-09 苏州韵蓝环保科技有限公司 Organic waste gas microwave deodorization purifier
CN206355830U (en) * 2016-12-16 2017-07-28 南通万年青环保科技有限公司 A kind of combined type exhaust gas purification equipment
CN206483338U (en) * 2017-01-25 2017-09-12 青岛明朗环境工程有限公司 A kind of efficient VOCs treatment equipment
US20190209729A1 (en) * 2018-01-11 2019-07-11 Chengdu Tiantian Medical Electric Apparatus Science And Technology Co., Ltd. Multifunctional Microwave Plasma and Ultraviolet Light Deodorization Treatment Device
CN208275246U (en) * 2018-02-11 2018-12-25 山东润圣环保科技有限公司 A kind of photochemical catalytic oxidation waste gas pollution control and treatment equipment

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