CN112066621B - Cooling device for electrolyte preparation - Google Patents

Cooling device for electrolyte preparation Download PDF

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Publication number
CN112066621B
CN112066621B CN202010910329.7A CN202010910329A CN112066621B CN 112066621 B CN112066621 B CN 112066621B CN 202010910329 A CN202010910329 A CN 202010910329A CN 112066621 B CN112066621 B CN 112066621B
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Prior art keywords
box
cooling
refrigeration
telescopic
pipe
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CN202010910329.7A
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CN112066621A (en
Inventor
叶泉
梁振洋
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Yinke Tianrun New Energy Materials Shandong Co ltd
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Shandong Tianrun New Energy Materials Co ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D15/00Devices not covered by group F25D11/00 or F25D13/00, e.g. non-self-contained movable devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B21/00Machines, plants or systems, using electric or magnetic effects
    • F25B21/02Machines, plants or systems, using electric or magnetic effects using Peltier effect; using Nernst-Ettinghausen effect
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/02Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating liquids, e.g. brine
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/06Arrangements for modifying heat-transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media
    • F28F13/12Arrangements for modifying heat-transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media by creating turbulence, e.g. by stirring, by increasing the force of circulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention relates to the field of electrolyte processing, and discloses a cooling device for preparing electrolyte, which comprises a cooling box, wherein a spiral cooling pipe is arranged in the cooling box, a refrigeration box is arranged at the lower end of the cooling box, a refrigeration mechanism is arranged at one end of the inner side of the refrigeration box, a circulation box is arranged at the lower end of the refrigeration mechanism, the bottom end of the spiral cooling pipe is communicated with the refrigeration box through a circulation pipe, a stirring shaft is arranged in the spiral cooling pipe in the vertical direction, the bottom end of the stirring shaft penetrates through the cooling box and is connected with a cam, two ends of the cam are respectively contacted with a telescopic ball, a telescopic rod is arranged in the middle of the other end of the telescopic ball, a telescopic plate is arranged at the other end of the telescopic rod and is arranged in the circulation box, and a telescopic spring is sleeved outside the telescopic rod between the telescopic ball and the circulation box. The invention realizes that the cooling liquid in the spiral cooling pipe can ensure to reciprocate on the inner wall of the cooling box under the action of the circulating box, and can realize the rapid cooling effect in the electrolyte preparation process under the coordination of the stirring shaft.

Description

Cooling device for electrolyte preparation
Technical Field
The invention relates to the field of electrolyte processing, in particular to a cooling device for electrolyte preparation.
Background
The battery electrolyte is the carrier for ion transport in the battery. Generally consisting of a lithium salt and an organic solvent. The electrolyte plays a role in conducting ions between the positive electrode and the negative electrode of the lithium battery, and is a guarantee for the lithium battery to obtain the advantages of high voltage, high specific energy and the like. The electrolyte is prepared from high-purity organic solvent, electrolyte lithium salt, necessary additives and other raw materials according to a certain proportion under a certain condition.
The electrolyte cooling device is a device for cooling the electrolyte in the production and processing process, is generally used in a production workshop, and has the characteristics of durability, convenience, easy operation and the like; the existing electrolyte cooling device has certain defects when in use, the electrolyte cooling device can not cool electrolyte conveniently in the use process, so that the working requirements of people can not be met, people can not feed from different positions conveniently, the working efficiency of people is reduced, in addition, people need to stop to process the electrolyte after centralized processing and cooling, the capacity is reduced, and certain influence is brought to the use of the electrolyte cooling device.
Chinese patent (No. CN 209843871U) discloses a cooling device for preparing lithium ion electrolyte, which comprises a supporting seat, wherein the upper end of the supporting seat is provided with a transfer box and a storage tank, the transfer box is positioned at the upper end of one side of the storage tank, the outer surface of one side of the upper end of the storage tank is provided with a through pipe, the outer surface of the lower end of one side of the transfer box is provided with a fixed pipe, the outer surface of one end of the fixed pipe is provided with a hose, the outer surface of the upper end of the transfer box is provided with a discharge pipe, the outer surface of the upper end of the discharge pipe is fixedly provided with a discharge funnel, the outer surface of the upper end of the discharge funnel is fixedly provided with a cooling chamber, the interior of the cooling chamber is provided with a conical feed funnel, a spiral cooling pipe and a cooling box, the conical feed funnel is positioned in the cooling box, the spiral cooling pipe is positioned on the outer surface of the cooling box, although the cooling effect in the electrolyte preparation process can be realized through the spiral cooling pipe to a certain extent, however, the cooling effect is poor and continuous cooling cannot be achieved, and therefore, further improvement is required.
Disclosure of Invention
The present invention is directed to a cooling device for preparing an electrolyte, so as to solve the problems of the background art mentioned above.
In order to achieve the purpose, the invention provides the following technical scheme:
the utility model provides a cooling device of electrolyte preparation, includes the cooler bin, the inside spiral cooling tube that is provided with of cooler bin, cooler bin lower extreme installation refrigeration case, refrigeration incasement side one end installation refrigeration mechanism, refrigeration mechanism lower extreme installation circulation case, spiral cooling tube bottom has the refrigeration case through circulating pipe intercommunication, the inside vertical direction installation (mixing) shaft of spiral cooling tube, (mixing) shaft bottom is passed the cooler bin and is connected with the cam, and the cam both ends contact respectively has flexible ball, flexible ball other end mid-mounting telescopic link, and flexible board is installed to the flexible link other end, and the flexible board is located inside the circulation case, the flexible link outside cover between flexible ball and the circulation case is equipped with expanding spring, the circulation case outside communicates in spiral cooling tube both ends through the back flow respectively, is located the inboard (mixing) shaft mid-mounting heat dissipation leaf of refrigeration mechanism.
As a further scheme of the invention: the middle part of the stirring shaft positioned in the cooling box is provided with a plurality of stirring blades.
As a further scheme of the invention: the cooling box top mid-mounting inlet pipe, the bottom outside installation discharging pipe.
As a further scheme of the invention: and the lower end of the circulation box is provided with a supporting leg.
As a further scheme of the invention: a fixing plate is arranged between the lower ends of the circulating boxes, a stirring motor is arranged in the middle of the fixing plate, and an output shaft of the stirring motor is connected with a stirring shaft.
As a further scheme of the invention: the refrigeration box is of an annular cavity structure.
As a further scheme of the invention: the refrigerating mechanism is of an annular structure and comprises a semiconductor refrigerating piece, a hot end is arranged at one end of the inner side of the semiconductor refrigerating piece, and a cold end is arranged at one end of the outer side of the semiconductor refrigerating piece.
As a further scheme of the invention: the expansion plate and the circulation box are in interference fit.
As a further scheme of the invention: the semiconductor refrigeration piece is electrically connected with a direct current power supply.
As a still further scheme of the invention: and sealing gaskets are arranged in the middle of the bottom ends of the stirring shaft and the cooling box.
Compared with the prior art, the invention has the beneficial effects that:
the utility model provides a cooling device of electrolyte preparation, rational in infrastructure, the modern design, through the cam that is equipped with and the mutually supporting between the flexible ball, realized that the inside coolant liquid of spiral cooling pipe ensures the reciprocating motion back and forth at the cooler bin inner wall under the effect of circulation case to under the cooperation of (mixing) shaft, can realize the quick cooling action of electrolyte preparation in-process, set up the refrigeration effect that the leaf can increase refrigeration mechanism simultaneously and set up, further increased the cooling effect of electrolyte, therefore, the clothes hanger is strong in practicability, and high reliability.
Drawings
Fig. 1 is a schematic structural view of a cooling apparatus for electrolyte preparation.
Fig. 2 is a schematic structural diagram of a refrigerating box in a cooling device for preparing electrolyte.
Fig. 3 is a schematic structural diagram of a refrigerating mechanism in a cooling device for preparing electrolyte.
In the figure: 1-cooling box, 2-circulating box, 3-expansion plate, 4-expansion rod, 5-stirring motor, 6-fixing plate, 7-expansion ball, 8-expansion spring, 9-supporting leg, 10-refrigeration box, 11-radiating blade, 12-spiral cooling pipe, 15-feeding pipe, 16-stirring shaft, 17-stirring blade, 18-backflow pipe, 19-cam, 20-circulating pipe, 21-refrigeration mechanism, 22-semiconductor refrigeration piece, 23-cold end and 24-hot end.
Detailed Description
It should be noted that the embodiments and features of the embodiments may be combined with each other without conflict.
In the description of the present invention, it is to be understood that the terms "central," "longitudinal," "lateral," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like are used in the orientations and positional relationships indicated in the drawings, which are based on the orientations and positional relationships indicated in the drawings, and are used for convenience in describing the present invention and for simplicity in description, but do not indicate or imply that the device or element so referred to must have a particular orientation, be constructed in a particular orientation, and be operated, and thus should not be construed as limiting the present invention. Furthermore, the terms "first", "second", etc. are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first," "second," etc. may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless otherwise specified.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood by those of ordinary skill in the art through specific situations.
The present invention will be described in detail below with reference to the embodiments with reference to the attached drawings.
Example 1
Referring to fig. 1 to 3, in the embodiment of the invention, a cooling device for preparing an electrolyte comprises a cooling box 1, wherein a feeding pipe 15 is installed in the middle of the top end of the cooling box 1 and is used for timely supplementing raw materials required for preparing the electrolyte into the cooling box 1, a discharging pipe is installed on the outer side of the bottom end of the cooling box 1 and is used for timely discharging the electrolyte after the coolant is prepared, a spiral cooling pipe 12 is arranged inside the cooling box 1, the spiral cooling pipe 12 is filled with the coolant and is used for timely discharging heat generated when the electrolyte is prepared inside the cooling box 1, a refrigeration box 10 is installed at the lower end of the cooling box 1, the refrigeration box 10 is of an annular cavity structure, a refrigeration mechanism 21 is installed at one end of the inner side of the refrigeration box 10, the refrigeration mechanism 21 is of an annular structure and comprises a semiconductor refrigeration piece 22, the semiconductor refrigeration piece 22 is electrically connected with a direct-current power supply, the semiconductor refrigeration piece 22 is provided with a hot end 24 at one end of the inner side thereof, the hot end 24 is used for generating temperature difference and further increasing the refrigeration effect of the cold end 23, the cold end 23 is arranged at one end of the outer side thereof, the cold end 23 is arranged inside the refrigeration box 10, the lower end of the refrigeration mechanism 21 is provided with the circulation box 2, the fixing plate 6 is arranged between the lower ends of the circulation box 2, the stirring motor 5 is arranged in the middle of the fixing plate 6, the output shaft of the stirring motor 5 is connected with the stirring shaft 16, the lower end of the circulation box 2 is provided with the supporting leg 9 for supporting and fixing the whole device, the bottom end of the spiral cooling pipe 12 is communicated with the refrigeration box 10 through the circulation pipe 20, the stirring shaft 16 is arranged in the spiral cooling pipe 12 in the vertical direction, the bottom end of the stirring shaft 16 passes through the refrigeration box 1 and is connected with the cam 19, the two ends of the cam 19 are respectively contacted with the telescopic ball 7, the telescopic rod 4 is arranged in the middle of the other end of the telescopic ball 7, and the telescopic plate 3 is arranged at the other end of the telescopic rod 4, inside circulation case 2 was located to expansion plate 3 to ensure that expansion plate 3 can remove along the removal of circulation case 2 inner wall, realized the circulation extrusion circulation effect to the coolant liquid, expansion plate 3 is interference fit with circulation case 2, has further ensured sealing performance, telescopic link 4 outside cover between expansion ball 7 and circulation case 2 is equipped with expanding spring 8, makes telescopic link 4 when not contacting with the salient direction of cam 19 through setting up expanding spring 8, can realize the ascending reset motion of direction of going back, circulation case 2 outside communicates in spiral cooling tube 12 both ends through back flow 18 respectively, is located the 16 mid-mounting heat dissipation leaves 11 of the (mixing) shaft of refrigerating mechanism 21 inboard for heat produced to hot junction 23 carries out timely radiating effect, thereby has increased the refrigeration effect of cold junction 24.
Example 2
In another embodiment of the invention, a cooling device for preparing electrolyte comprises a cooling box 1, wherein a feeding pipe 15 is installed in the middle of the top end of the cooling box 1, a discharging pipe is installed on the outer side of the bottom end of the cooling box 1, a spiral cooling pipe 12 is arranged in the cooling box 1, a refrigerating box 10 is installed at the lower end of the cooling box 1, the refrigerating box 10 is of an annular cavity structure, a refrigerating mechanism 21 is installed at one end of the inner side of the refrigerating box 10, the refrigerating mechanism 21 is of an annular structure, the refrigerating mechanism 21 comprises a semiconductor refrigerating sheet 22, the semiconductor refrigerating sheet 22 is electrically connected with a direct-current power supply, a hot end 24 is arranged at one end of the inner side of the semiconductor refrigerating sheet 22, a cold end 23 is arranged at one end of the outer side, a circulating box 2 is installed at the lower end of the refrigerating mechanism 21, a fixing plate 6 is installed between the lower ends of the circulating box 2, a stirring motor 5 is installed in the middle of the fixing plate 6, and a stirring shaft 16 is connected with an output shaft of the stirring motor 5, the lower end of the circulation box 2 is provided with a supporting leg 9, the bottom end of the spiral cooling pipe 12 is communicated with a refrigeration box 10 through a circulation pipe 20, a stirring shaft 16 is vertically arranged in the spiral cooling pipe 12, the bottom end of the stirring shaft 16 penetrates through the cooling box 1 and is connected with a cam 19, two ends of the cam 19 are respectively contacted with a telescopic ball 7, a telescopic rod 4 is arranged in the middle of the other end of the telescopic ball 7, a telescopic plate 3 is arranged at the other end of the telescopic rod 4, the telescopic plate 3 is arranged in the circulating box 2, the expansion plate 3 is in interference fit with the circulation box 2, an expansion spring 8 is sleeved outside the expansion link 4 between the expansion ball 7 and the circulation box 2, the outer side of the circulation box 2 is respectively communicated with the two ends of the spiral cooling pipe 12 through a return pipe 18, the middle part of a stirring shaft 16 positioned at the inner side of the refrigerating mechanism 21 is provided with a heat dissipation blade 11, this embodiment differs from the previous embodiments in that the stirring shaft 16 is fitted with a sealing gasket in the middle of the bottom end of the cooling box 1.
In the invention, when the cooling box works, raw materials required for preparing electrolyte are placed in the cooling box 1 through the feeding pipe, then the stirring motor 5 and the refrigerating mechanism 21 are started, the refrigerating mechanism 21 enables cooling liquid in the refrigerating box 10 to be cooled, meanwhile, the stirring shaft 16 rotates to enable the heat dissipation blades 17 to rotate, so that the refrigerating effect of the refrigerating mechanism is increased, on one hand, the protruding parts of the cam 19 are alternately matched with the telescopic balls 7 on the two sides, so that the cooling liquid and the refrigerating box 10 alternately circulate in the spiral cooling pipe 12, the heat absorption effect on the inside of the cooling box 10 is realized, and meanwhile, the stirring blades 17 rotate in the cooling box 10, so that the cooling effect is further increased. The cooling device is reasonable in structure and novel in design, the cooling liquid in the spiral cooling pipe 12 is ensured to reciprocate on the inner wall of the cooling box 1 under the action of the circulating box 2 through the mutual matching of the cam 19 and the telescopic ball 7, the rapid cooling effect in the electrolyte preparation process can be realized under the matching of the stirring shaft, meanwhile, the cooling effect of the refrigerating mechanism 21 can be improved through the arrangement of the heat dissipation blades 11, the cooling effect of the electrolyte is further improved, the practicability is high, and the reliability is high.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (8)

1. A cooling device for preparing electrolyte comprises a cooling box (1), wherein a spiral cooling pipe (12) is arranged in the cooling box (1), and is characterized in that a refrigeration box (10) is installed at the lower end of the cooling box (1), a refrigeration mechanism (21) is installed at one end of the inner side of the refrigeration box (10), a circulation box (2) is installed at the lower end of the refrigeration mechanism (21), the bottom end of the spiral cooling pipe (12) is communicated with the refrigeration box (10) through a circulation pipe (20), a stirring shaft (16) is installed in the spiral cooling pipe (12) in the vertical direction, and a plurality of stirring blades (17) are installed in the middle of the stirring shaft (16); the bottom end of the stirring shaft (16) penetrates through the cooling box (1) and is connected with a cam (19), two ends of the cam (19) are respectively contacted with a telescopic ball (7), the middle part of the other end of the telescopic ball (7) is provided with a telescopic rod (4), the other end of the telescopic rod (4) is provided with a telescopic plate (3), the telescopic plate (3) is arranged in the circulating box (2), the outer side of the telescopic rod (4) between the telescopic ball (7) and the circulating box (2) is sleeved with a telescopic spring (8), the outer side of the circulating box (2) is respectively communicated with two ends of a spiral cooling pipe (12) through return pipes (18), and the middle part of the stirring shaft (16) positioned at the inner side of the refrigerating mechanism (21) is provided with a radiating blade (11); refrigerating mechanism (21) are loop configuration, and refrigerating mechanism (21) include semiconductor refrigeration piece (22), and semiconductor refrigeration piece (22) inboard one end is provided with hot junction (24), and outside one end is provided with cold junction (23).
2. The cooling device for preparing the electrolyte according to claim 1, wherein the cooling box (1) is provided with a feeding pipe (15) at the middle part of the top end and a discharging pipe at the outer side of the bottom end.
3. A cooling device for the preparation of electrolytes according to claim 2, characterized in that the lower end of the circulation box (2) is provided with supporting legs (9).
4. A cooling device for preparing electrolyte according to claim 3, characterized in that a fixing plate (6) is arranged between the lower ends of the circulating boxes (2), a stirring motor (5) is arranged in the middle of the fixing plate (6), and an output shaft of the stirring motor (5) is connected with a stirring shaft (16).
5. A cooling device for the preparation of electrolytes according to claim 1, characterized in that said refrigeration case (10) is of toroidal cavity configuration.
6. A cooling device for the preparation of electrolytes according to claim 1, characterized in that said telescopic plates (3) are in interference fit with the circulation box (2).
7. The apparatus for cooling the preparation of an electrolyte as claimed in claim 1, characterized in that the semiconductor chilling plates (22) are electrically connected to a direct current power supply.
8. A cooling device for electrolyte preparation according to claim 1, characterized in that the stirring shaft (16) and the middle of the bottom end of the cooling box (1) are provided with sealing gaskets.
CN202010910329.7A 2020-09-02 2020-09-02 Cooling device for electrolyte preparation Active CN112066621B (en)

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CN115468377B (en) * 2022-09-15 2023-08-29 洛阳大生新能源开发有限公司 Cooling device for electrolyte preparation

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CN109163581A (en) * 2018-06-30 2019-01-08 湖州全优电工材料有限公司 A kind of circulating mill base is fully cooled device
CN210206849U (en) * 2019-05-31 2020-03-31 东莞市天丰电源材料有限公司 Take electrolyte reaction tank of control by temperature change
CN210856356U (en) * 2019-08-22 2020-06-26 丁亮 High-efficient electrolysis trough for chemical industry

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