CN112062605A - Transparent glaze layer applied to surface of rock plate and preparation method thereof - Google Patents
Transparent glaze layer applied to surface of rock plate and preparation method thereof Download PDFInfo
- Publication number
- CN112062605A CN112062605A CN202010911408.XA CN202010911408A CN112062605A CN 112062605 A CN112062605 A CN 112062605A CN 202010911408 A CN202010911408 A CN 202010911408A CN 112062605 A CN112062605 A CN 112062605A
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- ground
- slurry
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/70—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention discloses a transparent glaze layer applied to the surface of a rock plate, which is formed by combining ground coat and polished glaze and is characterized in that the ground coat comprises the following raw materials in parts by weight: albite, potash feldspar, quartz, barium carbonate, zinc oxide, kaolin, calcined kaolin, alumina and dolomite; the glaze comprises the following raw materials in parts by weight: the transparent glaze layer applied to the surface of the rock plate is prepared by respectively treating a ground glaze material and a glaze-polishing glaze material and then sequentially glazing and sintering the ground glaze material and the glaze-polishing glaze material.
Description
Technical Field
The invention particularly relates to a transparent glaze layer applied to the surface of a rock plate and a preparation method thereof.
Background
With the improvement of living standard of people, the requirements for living environment and living conditions are continuously improved, and the decoration is also pleasing for housing, office buildings, hotels, entertainment places and the like, so that various building material decorative materials are endless. At present, the commonly used building material decorating materials comprise two kinds of natural materials and artificial materials.
Because the limitation of the artificial stone is glaze treatment of the plate, the conventional artificial stone is subjected to glaze generation by using the materials of the stone blank under high-temperature firing, but the glaze is too simple and dull, which is not beneficial to improving the production quality of the artificial stone and can not meet the requirements of customers, so that technicians in the field can develop various glazes applied to the artificial plate according to the requirements, and the application of natural stone is not limited; taking a transparent glaze layer as an example, the traditional transparent glaze layer has similar color and luster with natural rock and can replace the decorative effect of natural stone, but because the inorganic material and the additive are combined, the manufacturing cost is high and the utilization rate is low.
Disclosure of Invention
In view of the above, the present invention aims to provide a transparent glaze layer having similar color and luster to natural stone, capable of replacing natural stone, and having lower cost compared with natural stone due to the adoption of common inorganic materials, and a preparation method thereof.
In order to solve the technical problems, the technical scheme of the invention is as follows:
a transparent glaze layer applied to the surface of a rock plate is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 40-42 parts of albite, 7-11 parts of potassium feldspar, 23-29 parts of quartz, 10-12 parts of barium carbonate, 2-4 parts of zinc oxide, 6-10 parts of kaolin, 2-4 parts of calcined kaolin, 2-4 parts of alumina and 1-3 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 18-22 parts of albite, 13-18 parts of potassium feldspar, 8-12 parts of kaolin, 5-7 parts of talcum powder, 2-4 parts of wollastonite, 15-19 parts of barium carbonate, 2-6 parts of zinc oxide, 11-15 parts of dolomite, 2-4 parts of corundum powder and 8-10 parts of low-temperature transparent frit.
Further, the transparent glaze layer applied to the surface of the rock plate is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 42 parts of albite, 7 parts of potassium feldspar, 23 parts of quartz, 10 parts of barium carbonate, 2 parts of zinc oxide, 6 parts of kaolin, 2 parts of calcined kaolin, 2 parts of alumina and 1 part of dolomite; the glaze comprises the following raw materials in parts by weight: 22 parts of albite, 13 parts of potassium feldspar, 8 parts of kaolin, 5 parts of talcum powder, 2 parts of wollastonite, 15 parts of barium carbonate, 2 parts of zinc oxide, 11 parts of dolomite, 2 parts of corundum powder and 8 parts of low-temperature transparent frit.
Further, the transparent glaze layer applied to the surface of the rock plate is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 40 parts of albite, 11 parts of potassium feldspar, 29 parts of quartz, 12 parts of barium carbonate, 4 parts of zinc oxide, 10 parts of kaolin, 4 parts of calcined kaolin, 4 parts of alumina and 3 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 18 parts of albite, 18 parts of potassium feldspar, 12 parts of kaolin, 7 parts of talcum powder, 4 parts of wollastonite, 19 parts of barium carbonate, 6 parts of zinc oxide, 15 parts of dolomite, 4 parts of corundum powder and 10 parts of low-temperature transparent frit.
Further, the transparent glaze layer applied to the surface of the rock plate is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 41 parts of albite, 9 parts of potassium feldspar, 26 parts of quartz, 11 parts of barium carbonate, 2 parts of zinc oxide, 8 parts of kaolin, 3 parts of calcined kaolin, 3 parts of alumina and 2 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 20 parts of albite, 15 parts of potassium feldspar, 10 parts of kaolin, 6 parts of talcum powder, 3 parts of wollastonite, 17 parts of barium carbonate, 4 parts of zinc oxide, 13 parts of dolomite, 3 parts of corundum powder and 9 parts of low-temperature transparent frit.
A preparation method of a transparent glaze layer applied to the surface of a rock plate comprises the following steps:
step 1, preparing raw materials, which comprises the following steps:
a. grinding a ground glaze raw material and a glaze polishing raw material to prepare powder, and respectively preparing ground glaze raw material mixed powder and glaze polishing raw material mixed powder for later use;
b. before entering a warehouse, sequentially detecting the purity, strength and harmful elements of the mixed powder of the bottom glaze raw material and the mixed powder of the glaze polishing raw material in the specific step a according to production process requirements, entering the warehouse after the detection reaches the standard, and completing homogenization and stacking to fully and uniformly mix the raw materials for later use;
c. b, respectively performing fine processing on the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder which are detected and homogenized and piled in the step b, and removing 0.4-0.6% of coarse grains after passing through a standard sieve of 250 meshes so as to ensure that the grain size distribution of the powder is uniform;
step 2, the specific preparation steps of the ground glaze and the glaze polishing glaze are as follows:
a. removing harmful iron from the ground glaze raw material mixed powder and the glaze polishing raw material mixed powder in the step 1, adding the ground glaze raw material mixed powder and water into a stirrer according to a ratio of 5:4, stirring, adding the glaze polishing raw material mixed powder and water into the stirrer according to a ratio of 1:1, stirring, and respectively preparing ground glaze slurry and glaze polishing slurry for later use;
b. feeding the ground glaze slurry into a ball mill I for ball milling, continuously ball milling for 8-10 hours to ensure that 0.6 percent of impurities are left after the ground glaze slurry passes through a standard sieve with the size of 325 meshes, wherein the specific gravity of the ground glaze is 1.85-1.92g/ml, discharging the slurry to prepare the ground glaze slurry, feeding the glaze polishing slurry into a ball mill II for ball milling for 12-16 hours to ensure that 0.5 percent of impurities are left after the ground glaze slurry passes through the standard sieve with the size of 325 meshes, and the specific gravity of the polished glaze is 1.25-1.27g/ml, and discharging the slurry to prepare the glaze polishing slurry for later use;
c. b, respectively sieving the ground glaze slurry and the glaze polishing slurry prepared in the step b twice through a 160-mesh sieve at normal temperature, simultaneously removing iron through two automatic iron removal machines, controlling the iron content in the ground glaze slurry and the glaze polishing slurry to be less than or equal to 0.1%, and then carrying out aging treatment on the ground glaze slurry and the glaze polishing slurry after iron removal for 24 hours to reduce bubbles in the slurry for later use;
step 3, firing the ground glaze and the polished glaze prepared in the step 2 by using a scraping plate used on a ball and line, testing by using a gloss meter, and firing if the gloss is within the range of 0.5;
step 4, firing: and spraying the ground coat on the surface of the rock slab blank by adopting a glaze spraying mode to finish glazing, controlling the thickness of the ground coat to be 0.6mm, drying at the temperature of 160-1190 ℃ in a drying kiln, finishing glazing on the ground coat by adopting the glaze spraying mode for glaze polishing, controlling the thickness of the polished coat to be 0.3mm, and finally sintering in a roller kiln in the oxidizing atmosphere of 1180-1190 ℃ to obtain the transparent glaze layer applied to the surface of the rock slab.
The technical effects of the invention are mainly reflected in the following aspects: the transparent glaze layer applied to the surface of the rock plate is prepared by respectively treating the ground glaze material and the glaze-polishing glaze material and then sequentially glazing and sintering.
Detailed Description
The embodiments of the present invention are described in further detail to make the technical solutions of the present invention easier to understand and master.
Example one
A transparent glaze layer applied to the surface of a rock plate is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 42 parts of albite, 7 parts of potassium feldspar, 23 parts of quartz, 10 parts of barium carbonate, 2 parts of zinc oxide, 6 parts of kaolin, 2 parts of calcined kaolin, 2 parts of alumina and 1 part of dolomite; the glaze comprises the following raw materials in parts by weight: 22 parts of albite, 13 parts of potassium feldspar, 8 parts of kaolin, 5 parts of talcum powder, 2 parts of wollastonite, 15 parts of barium carbonate, 2 parts of zinc oxide, 11 parts of dolomite, 2 parts of corundum powder and 8 parts of low-temperature transparent frit.
A preparation method of a transparent glaze layer applied to the surface of a rock plate comprises the following steps:
step 1, preparing raw materials, which comprises the following steps:
a. grinding a ground glaze raw material and a glaze polishing raw material to prepare powder, and respectively preparing ground glaze raw material mixed powder and glaze polishing raw material mixed powder for later use;
b. before entering a warehouse, sequentially detecting the purity, strength and harmful elements of the mixed powder of the bottom glaze raw material and the mixed powder of the glaze polishing raw material in the specific step a according to production process requirements, entering the warehouse after the detection reaches the standard, and completing homogenization and stacking to fully and uniformly mix the raw materials for later use;
c. b, respectively performing fine processing on the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder which are detected and homogenized in the step b to enable the fineness of the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder to reach the nanometer level, and removing 0.6% of coarse grains after the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder are subjected to standard screening of 250 meshes to enable the grain size distribution of the powder to be uniform;
step 2, the specific preparation steps of the ground glaze and the glaze polishing glaze are as follows:
a. removing harmful iron from the ground glaze raw material mixed powder and the glaze polishing raw material mixed powder in the step 1, adding the ground glaze raw material mixed powder and water into a stirrer according to a ratio of 5:4, stirring, adding the glaze polishing raw material mixed powder and water into the stirrer according to a ratio of 1:1, stirring, and respectively preparing ground glaze slurry and glaze polishing slurry for later use;
b. feeding the ground glaze slurry into a ball mill I for ball milling, continuously ball milling for 10 hours to ensure that 0.6 percent of impurities are left after the ground glaze slurry passes through a standard sieve with the size of 325 meshes, wherein the specific gravity of the ground glaze is 1.92g/ml, discharging the slurry to prepare the ground glaze slurry, feeding the glaze polishing slurry into a ball mill II for ball milling for 16 hours to ensure that 0.5 percent of impurities are left after the ground glaze slurry passes through the standard sieve with the size of 325 meshes, and discharging the slurry to prepare the glaze polishing slurry for later use, wherein the specific gravity of the polished glaze is 1.27 g/ml;
c. b, respectively sieving the ground glaze slurry and the glaze polishing slurry prepared in the step b twice through a 160-mesh sieve at normal temperature, simultaneously removing iron through two automatic iron removal machines, controlling the iron content in the ground glaze slurry and the glaze polishing slurry to be less than or equal to 0.1%, and then carrying out aging treatment on the ground glaze slurry and the glaze polishing slurry after iron removal for 24 hours to reduce bubbles in the slurry for later use;
step 3, firing the ground glaze and the polished glaze prepared in the step 2 by using a scraping plate used on a ball and line, testing by using a gloss meter, and firing if the gloss is within the range of 0.5;
step 4, firing: and spraying the ground glaze on the surface of the rock board blank by adopting a glaze spraying mode to finish glazing, controlling the thickness of the ground glaze to be 0.6mm, drying at the temperature of 180 ℃ in a drying kiln, then finishing glazing on the ground glaze by adopting the glaze spraying mode for glaze polishing, controlling the thickness of the polished surface to be 0.3mm, and finally sintering in a roller kiln at the temperature of 1190 ℃ in an oxidizing atmosphere to obtain the transparent glaze layer applied to the surface of the rock board.
Example two
A transparent glaze layer applied to the surface of a rock plate is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 40 parts of albite, 11 parts of potassium feldspar, 29 parts of quartz, 12 parts of barium carbonate, 4 parts of zinc oxide, 10 parts of kaolin, 4 parts of calcined kaolin, 4 parts of alumina and 3 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 18 parts of albite, 18 parts of potassium feldspar, 12 parts of kaolin, 7 parts of talcum powder, 4 parts of wollastonite, 19 parts of barium carbonate, 6 parts of zinc oxide, 15 parts of dolomite, 4 parts of corundum powder and 10 parts of low-temperature transparent frit.
A preparation method of a transparent glaze layer applied to the surface of a rock plate comprises the following steps:
step 1, preparing raw materials, which comprises the following steps:
a. grinding a ground glaze raw material and a glaze polishing raw material to prepare powder, and respectively preparing ground glaze raw material mixed powder and glaze polishing raw material mixed powder for later use;
b. before entering a warehouse, sequentially detecting the purity, strength and harmful elements of the mixed powder of the bottom glaze raw material and the mixed powder of the glaze polishing raw material in the specific step a according to production process requirements, entering the warehouse after the detection reaches the standard, and completing homogenization and stacking to fully and uniformly mix the raw materials for later use;
c. b, respectively performing fine processing on the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder which are detected and homogenized in the step b to enable the fineness of the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder to reach the nanometer level, and removing 0.4% of coarse grains after the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder are subjected to standard screening of 250 meshes to enable the grain size distribution of the powder to be uniform;
step 2, the specific preparation steps of the ground glaze and the glaze polishing glaze are as follows:
a. removing harmful iron from the ground glaze raw material mixed powder and the glaze polishing raw material mixed powder in the step 1, adding the ground glaze raw material mixed powder and water into a stirrer according to a ratio of 5:4, stirring, adding the glaze polishing raw material mixed powder and water into the stirrer according to a ratio of 1:1, stirring, and respectively preparing ground glaze slurry and glaze polishing slurry for later use;
b. feeding the ground glaze slurry into a ball mill I for ball milling, continuously ball milling for 8 hours to ensure that 0.6 percent of impurities are left after the ground glaze slurry passes through a standard sieve with the size of 325 meshes, wherein the specific gravity of the ground glaze is 1.85g/ml, discharging the slurry to prepare the ground glaze slurry, feeding the glaze polishing slurry into a ball mill II for ball milling for 12 hours to ensure that 0.5 percent of impurities are left after the ground glaze slurry passes through the standard sieve with the size of 325 meshes, and discharging the slurry to prepare the glaze polishing slurry for later use, wherein the specific gravity of the polished glaze is 1.25 g/ml;
c. b, respectively sieving the ground glaze slurry and the glaze polishing slurry prepared in the step b twice through a 160-mesh sieve at normal temperature, simultaneously removing iron through two automatic iron removal machines, controlling the iron content in the ground glaze slurry and the glaze polishing slurry to be less than or equal to 0.1%, and then carrying out aging treatment on the ground glaze slurry and the glaze polishing slurry after iron removal for 24 hours to reduce bubbles in the slurry for later use;
step 3, firing the ground glaze and the polished glaze prepared in the step 2 by using a scraping plate used on a ball and line, testing by using a gloss meter, and firing if the gloss is within the range of 0.5;
step 4, firing: spraying the ground coat on the surface of the rock board blank by adopting a glaze spraying mode to finish glazing, controlling the thickness of the ground coat to be 0.6mm, drying at the temperature of 160 ℃ in a drying kiln, then finishing glazing on the ground coat by adopting the glaze spraying mode for glaze polishing, controlling the thickness of the polished coat to be 0.3mm, and finally sintering in a roller kiln at 1180 ℃ in an oxidizing atmosphere to obtain the transparent glaze layer applied to the surface of the rock board.
EXAMPLE III
A transparent glaze layer applied to the surface of a rock plate is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 41 parts of albite, 9 parts of potassium feldspar, 26 parts of quartz, 11 parts of barium carbonate, 2 parts of zinc oxide, 8 parts of kaolin, 3 parts of calcined kaolin, 3 parts of alumina and 2 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 20 parts of albite, 15 parts of potassium feldspar, 10 parts of kaolin, 6 parts of talcum powder, 3 parts of wollastonite, 17 parts of barium carbonate, 4 parts of zinc oxide, 13 parts of dolomite, 3 parts of corundum powder and 9 parts of low-temperature transparent frit.
A preparation method of a transparent glaze layer applied to the surface of a rock plate comprises the following steps:
step 1, preparing raw materials, which comprises the following steps:
a. grinding a ground glaze raw material and a glaze polishing raw material to prepare powder, and respectively preparing ground glaze raw material mixed powder and glaze polishing raw material mixed powder for later use;
b. before entering a warehouse, sequentially detecting the purity, strength and harmful elements of the mixed powder of the bottom glaze raw material and the mixed powder of the glaze polishing raw material in the specific step a according to production process requirements, entering the warehouse after the detection reaches the standard, and completing homogenization and stacking to fully and uniformly mix the raw materials for later use;
c. b, respectively performing fine processing on the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder which are detected and homogenized in the step b to enable the fineness of the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder to reach the nanometer level, and removing 0.5% of coarse grains after the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder are subjected to standard screening of 250 meshes to enable the grain size distribution of the powder to be uniform;
step 2, the specific preparation steps of the ground glaze and the glaze polishing glaze are as follows:
a. removing harmful iron from the ground glaze raw material mixed powder and the glaze polishing raw material mixed powder in the step 1, adding the ground glaze raw material mixed powder and water into a stirrer according to a ratio of 5:4, stirring, adding the glaze polishing raw material mixed powder and water into the stirrer according to a ratio of 1:1, stirring, and respectively preparing ground glaze slurry and glaze polishing slurry for later use;
b. feeding the ground glaze slurry into a ball mill I for ball milling, continuously ball milling for 9 hours to ensure that 0.6 percent of impurities are left after the ground glaze slurry passes through a standard sieve with the size of 325 meshes, wherein the specific gravity of the ground glaze is 1.92g/ml, discharging the slurry to prepare the ground glaze slurry, feeding the glaze polishing slurry into a ball mill II for ball milling for 12-16 hours to ensure that 0.5 percent of impurities are left after the ground glaze slurry passes through the standard sieve with the size of 325 meshes, and discharging the slurry to prepare the glaze polishing slurry for later use, wherein the specific gravity of the polished glaze is 1.27 g/ml;
c. b, respectively sieving the ground glaze slurry and the glaze polishing slurry prepared in the step b twice through a 160-mesh sieve at normal temperature, simultaneously removing iron through two automatic iron removal machines, controlling the iron content in the ground glaze slurry and the glaze polishing slurry to be less than or equal to 0.1%, and then carrying out aging treatment on the ground glaze slurry and the glaze polishing slurry after iron removal for 24 hours to reduce bubbles in the slurry for later use;
step 3, firing the ground glaze and the polished glaze prepared in the step 2 by using a scraping plate used on a ball and line, testing by using a gloss meter, and firing if the gloss is within the range of 0.5;
step 4, firing: and spraying the ground glaze on the surface of the rock board blank by adopting a glaze spraying mode to finish glazing, controlling the thickness of the ground glaze to be 0.6mm, drying at the temperature of 170 ℃ in a drying kiln, then finishing glazing on the ground glaze by adopting the glaze spraying mode for glaze polishing, controlling the thickness of the polished surface to be 0.3mm, and finally sintering in a roller kiln at the temperature of 1190 ℃ in an oxidizing atmosphere to obtain the transparent glaze layer applied to the surface of the rock board.
The technical effects of the invention are mainly reflected in the following aspects: the transparent glaze layer applied to the surface of the rock plate is prepared by respectively treating the ground glaze material and the glaze-polishing glaze material and then sequentially glazing and sintering.
The above are only typical examples of the present invention, and besides, the present invention may have other embodiments, and all the technical solutions formed by equivalent substitutions or equivalent changes are within the scope of the present invention as claimed.
Claims (5)
1. The transparent glaze layer applied to the surface of a rock plate is formed by combining ground coat and polished glaze, and is characterized in that the ground coat comprises the following raw materials in parts by weight: 40-42 parts of albite, 7-11 parts of potassium feldspar, 23-29 parts of quartz, 10-12 parts of barium carbonate, 2-4 parts of zinc oxide, 6-10 parts of kaolin, 2-4 parts of calcined kaolin, 2-4 parts of alumina and 1-3 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 18-22 parts of albite, 13-18 parts of potassium feldspar, 8-12 parts of kaolin, 5-7 parts of talcum powder, 2-4 parts of wollastonite, 15-19 parts of barium carbonate, 2-6 parts of zinc oxide, 11-15 parts of dolomite, 2-4 parts of corundum powder and 8-10 parts of low-temperature transparent frit.
2. The transparent glaze layer applied to the surface of a rock plate as claimed in claim 1, which is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 42 parts of albite, 7 parts of potassium feldspar, 23 parts of quartz, 10 parts of barium carbonate, 2 parts of zinc oxide, 6 parts of kaolin, 2 parts of calcined kaolin, 2 parts of alumina and 1 part of dolomite; the glaze comprises the following raw materials in parts by weight: 22 parts of albite, 13 parts of potassium feldspar, 8 parts of kaolin, 5 parts of talcum powder, 2 parts of wollastonite, 15 parts of barium carbonate, 2 parts of zinc oxide, 11 parts of dolomite, 2 parts of corundum powder and 8 parts of low-temperature transparent frit.
3. The transparent glaze layer applied to the surface of a rock plate as claimed in claim 1, which is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 40 parts of albite, 11 parts of potassium feldspar, 29 parts of quartz, 12 parts of barium carbonate, 4 parts of zinc oxide, 10 parts of kaolin, 4 parts of calcined kaolin, 4 parts of alumina and 3 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 18 parts of albite, 18 parts of potassium feldspar, 12 parts of kaolin, 7 parts of talcum powder, 4 parts of wollastonite, 19 parts of barium carbonate, 6 parts of zinc oxide, 15 parts of dolomite, 4 parts of corundum powder and 10 parts of low-temperature transparent frit.
4. The transparent glaze layer applied to the surface of a rock plate as claimed in claim 1, which is formed by combining ground coat and polished glaze, wherein the ground coat comprises the following raw materials in parts by weight: 41 parts of albite, 9 parts of potassium feldspar, 26 parts of quartz, 11 parts of barium carbonate, 2 parts of zinc oxide, 8 parts of kaolin, 3 parts of calcined kaolin, 3 parts of alumina and 2 parts of dolomite; the glaze comprises the following raw materials in parts by weight: 20 parts of albite, 15 parts of potassium feldspar, 10 parts of kaolin, 6 parts of talcum powder, 3 parts of wollastonite, 17 parts of barium carbonate, 4 parts of zinc oxide, 13 parts of dolomite, 3 parts of corundum powder and 9 parts of low-temperature transparent frit.
5. A method for preparing a transparent glaze layer applied to the surface of a rock plate according to claims 1 to 4, comprising the steps of:
step 1, preparing raw materials, which comprises the following steps:
a. grinding a ground glaze raw material and a glaze polishing raw material to prepare powder, and respectively preparing ground glaze raw material mixed powder and glaze polishing raw material mixed powder for later use;
b. before entering a warehouse, sequentially detecting the purity, strength and harmful elements of the mixed powder of the bottom glaze raw material and the mixed powder of the glaze polishing raw material in the specific step a according to production process requirements, entering the warehouse after the detection reaches the standard, and completing homogenization and stacking to fully and uniformly mix the raw materials for later use;
c. b, respectively performing fine processing on the bottom glaze raw material mixed powder and the glaze-throwing raw material mixed powder which are detected and homogenized and piled in the step b, and removing 0.4-0.6% of coarse grains after passing through a standard sieve of 250 meshes so as to ensure that the grain size distribution of the powder is uniform;
step 2, the specific preparation steps of the ground glaze and the glaze polishing glaze are as follows:
a. removing harmful iron from the ground glaze raw material mixed powder and the glaze polishing raw material mixed powder in the step 1, adding the ground glaze raw material mixed powder and water into a stirrer according to a ratio of 5:4, stirring, adding the glaze polishing raw material mixed powder and water into the stirrer according to a ratio of 1:1, stirring, and respectively preparing ground glaze slurry and glaze polishing slurry for later use;
b. feeding the ground glaze slurry into a ball mill I for ball milling, continuously ball milling for 8-10 hours to ensure that 0.6 percent of impurities are left after the ground glaze slurry passes through a standard sieve with the size of 325 meshes, wherein the specific gravity of the ground glaze is 1.85-1.92g/ml, discharging the slurry to prepare the ground glaze slurry, feeding the glaze polishing slurry into a ball mill II for ball milling for 12-16 hours to ensure that 0.5 percent of impurities are left after the ground glaze slurry passes through the standard sieve with the size of 325 meshes, and the specific gravity of the polished glaze is 1.25-1.27g/ml, and discharging the slurry to prepare the glaze polishing slurry for later use;
c. b, respectively sieving the ground glaze slurry and the glaze polishing slurry prepared in the step b twice through a 160-mesh sieve at normal temperature, simultaneously removing iron through two automatic iron removal machines, controlling the iron content in the ground glaze slurry and the glaze polishing slurry to be less than or equal to 0.1%, and then carrying out aging treatment on the ground glaze slurry and the glaze polishing slurry after iron removal for 24 hours to reduce bubbles in the slurry for later use;
step 3, firing the ground glaze and the polished glaze prepared in the step 2 by using a scraping plate used on a ball and line, testing by using a gloss meter, and firing if the gloss is within the range of 0.5;
step 4, firing: and spraying the ground coat on the surface of the rock slab blank by adopting a glaze spraying mode to finish glazing, controlling the thickness of the ground coat to be 0.6mm, drying at the temperature of 160-1190 ℃ in a drying kiln, finishing glazing on the ground coat by adopting the glaze spraying mode for glaze polishing, controlling the thickness of the polished coat to be 0.3mm, and finally sintering in a roller kiln in the oxidizing atmosphere of 1180-1190 ℃ to obtain the transparent glaze layer applied to the surface of the rock slab.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010911408.XA CN112062605A (en) | 2020-09-02 | 2020-09-02 | Transparent glaze layer applied to surface of rock plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010911408.XA CN112062605A (en) | 2020-09-02 | 2020-09-02 | Transparent glaze layer applied to surface of rock plate and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112062605A true CN112062605A (en) | 2020-12-11 |
Family
ID=73664996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010911408.XA Pending CN112062605A (en) | 2020-09-02 | 2020-09-02 | Transparent glaze layer applied to surface of rock plate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112062605A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113603364A (en) * | 2021-08-17 | 2021-11-05 | 广东省新岩素智能家居科技有限公司 | Volcanic glaze and rock plate |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739279A (en) * | 2013-12-16 | 2014-04-23 | 广州锦盈新型材料有限公司 | Full-glazed tile and preparation method thereof |
| CN104557144A (en) * | 2014-12-29 | 2015-04-29 | 广东家美陶瓷有限公司 | Colorful transparent polished-glazed brick and production method thereof |
| CN106007379A (en) * | 2016-05-23 | 2016-10-12 | 广东家美陶瓷有限公司 | Transparent glaze and preparation method thereof |
| CN107879749A (en) * | 2017-10-23 | 2018-04-06 | 鹰牌陶瓷实业（河源）有限公司 | A kind of production technology of Full-glazed tile |
| CN109081592A (en) * | 2018-10-23 | 2018-12-25 | 佛山市陶莹新型材料有限公司 | A kind of microlite thickness throws glaze and preparation method thereof and the application method in ceramic tile |
| CN110255902A (en) * | 2019-05-27 | 2019-09-20 | 湖北杭瑞陶瓷有限责任公司 | A kind of overglaze being rapidly fired to suitable for glazed tile, glazed tile and preparation method thereof |
| CN110627532A (en) * | 2019-11-01 | 2019-12-31 | 江西省建筑卫生陶瓷质量监督检验中心 | Large-size ceramic rock plate and production process thereof |
-
2020
- 2020-09-02 CN CN202010911408.XA patent/CN112062605A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739279A (en) * | 2013-12-16 | 2014-04-23 | 广州锦盈新型材料有限公司 | Full-glazed tile and preparation method thereof |
| CN104557144A (en) * | 2014-12-29 | 2015-04-29 | 广东家美陶瓷有限公司 | Colorful transparent polished-glazed brick and production method thereof |
| CN106007379A (en) * | 2016-05-23 | 2016-10-12 | 广东家美陶瓷有限公司 | Transparent glaze and preparation method thereof |
| CN107879749A (en) * | 2017-10-23 | 2018-04-06 | 鹰牌陶瓷实业（河源）有限公司 | A kind of production technology of Full-glazed tile |
| CN109081592A (en) * | 2018-10-23 | 2018-12-25 | 佛山市陶莹新型材料有限公司 | A kind of microlite thickness throws glaze and preparation method thereof and the application method in ceramic tile |
| CN110255902A (en) * | 2019-05-27 | 2019-09-20 | 湖北杭瑞陶瓷有限责任公司 | A kind of overglaze being rapidly fired to suitable for glazed tile, glazed tile and preparation method thereof |
| CN110627532A (en) * | 2019-11-01 | 2019-12-31 | 江西省建筑卫生陶瓷质量监督检验中心 | Large-size ceramic rock plate and production process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113603364A (en) * | 2021-08-17 | 2021-11-05 | 广东省新岩素智能家居科技有限公司 | Volcanic glaze and rock plate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112062468A (en) | Texture glaze layer applied to surface of rock plate and preparation method thereof | |
| CN112592063B (en) | High-wear-resistance marble-imitated ceramic tile and preparation method thereof | |
| CN115010465B (en) | Low-temperature quick-firing ceramic rock plate and preparation method thereof | |
| CN110642521B (en) | High-wear-resistance antifouling microcrystal decorative ceramic thick plate and preparation method thereof | |
| CN111943724B (en) | Method for manufacturing matt transparent glazed ceramic chip | |
| CN111943729B (en) | Manufacturing method of matte marble tile | |
| WO2021232784A1 (en) | High-wear-resistance far-infrared ceramic polished glazed tile and preparation method therefor | |
| CN112279516A (en) | High-wear-resistance and high-transparency satin glaze, preparation method and large-size satin rock plate | |
| CN105000866A (en) | Glazed tile prepared from sludge with mirror-effect surface and preparation method thereof | |
| CN104591806A (en) | Pure black glazed tile produced by using waste glaze slip and preparation method of pure black glazed tile | |
| CN108484114B (en) | Glazed ceramic tile with high-content polishing waste and preparation method thereof | |
| CN105293912A (en) | Manufacturing method of glazed tile with matte surface | |
| CN113860736B (en) | Full-polished glaze and ceramic tile with iridescent glittering effect, and preparation method and application thereof | |
| CN113968728B (en) | High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof | |
| CN113387679A (en) | Preparation method of high-strength recyclable environment-friendly ceramic pug | |
| CN112062470A (en) | Glaze material and ceramic tile with silk glaze effect and preparation method thereof | |
| CN1050175A (en) | Colour-in-glaze strengthening ceramics and production method thereof | |
| CN112062605A (en) | Transparent glaze layer applied to surface of rock plate and preparation method thereof | |
| CN1314619C (en) | Ultra-white polishing brick and its production process | |
| CN1699269A (en) | Process for making tile with natural jade effect | |
| CN113548910A (en) | Ceramic tile with imitated bright mirror surface and metal electroplating texture and preparation method thereof | |
| CN115385575B (en) | Super wear-resistant glazed brick glaze and preparation method thereof, glazed brick and preparation method thereof | |
| CN114804633B (en) | Ceramic tile with dry particle glaze, glaze surface with diamond light effect and preparation method thereof | |
| CN112079568A (en) | Color development glaze layer applied to surface of rock plate and preparation method thereof | |
| CN114195480B (en) | Fine and smooth anti-fouling antibacterial brick and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20201211 |