CN112062480A - Surface strengthening treatment method for ultrathin large-plate-surface glass - Google Patents

Surface strengthening treatment method for ultrathin large-plate-surface glass Download PDF

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Publication number
CN112062480A
CN112062480A CN202010951174.1A CN202010951174A CN112062480A CN 112062480 A CN112062480 A CN 112062480A CN 202010951174 A CN202010951174 A CN 202010951174A CN 112062480 A CN112062480 A CN 112062480A
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CN
China
Prior art keywords
glass
plate
ultra
molten salt
strengthening treatment
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CN202010951174.1A
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Chinese (zh)
Inventor
沈江民
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Henan Zhuojin Photoelectric Technology Co ltd
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Henan Zhuojin Photoelectric Technology Co ltd
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Priority to CN202010951174.1A priority Critical patent/CN112062480A/en
Publication of CN112062480A publication Critical patent/CN112062480A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C21/00Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
    • C03C21/001Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
    • C03C21/002Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B11/00Cleaning flexible or delicate articles by methods or apparatus specially adapted thereto
    • B08B11/04Cleaning flexible or delicate articles by methods or apparatus specially adapted thereto specially adapted for plate glass, e.g. prior to manufacture of windshields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/12Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

The invention discloses a surface strengthening treatment method of ultrathin large-plate-surface glass, which comprises a glass surface cleaning treatment method before tempering; an anti-crushing method for a toughened bearing substrate frame; a molten salt pool three-dimensional omnibearing intelligent temperature control method; a method for uniformly replacing sodium and potassium ions on the surface of the ultrathin large-plate-surface glass and controlling the density of the potassium ions in a molten salt pool; a method for desalting the surface of ultra-thin large-plate glass after toughening. The invention solves the technical problems of uneven surface strengthening treatment, easy breaking and difficult cutting of the ultrathin large-plate-surface glass, ensures that the breaking rate of the ultrathin large-plate-surface glass in the toughening process is less than three thousandth, the toughened particle size is more uniform, and the cuttability of the ultrathin large-plate-surface toughened glass is realized.

Description

Surface strengthening treatment method for ultrathin large-plate-surface glass
Technical Field
The invention belongs to the technical field of glass deep processing, and particularly relates to a surface strengthening treatment method for ultrathin large-plate-surface glass.
Background
With the rapid development of electronic science and technology and the wide application of electronic glass display panels in the work and life of people, as the fragility of glass panels and manufacturers begin to perform strengthening treatment on the surfaces of electronic glass display panels, the strengthening treatment specification of electronic glass surfaces is generally no more than 550x650, and with the rapid increase of the market demand of electronic glass display panels with ultra-thin and ultra-large panel surfaces, a surface strengthening treatment technology of the ultra-thin and large panel surfaces with the specification of 1220x1830 and above is urgently needed.
Disclosure of Invention
In order to overcome the problems, the invention provides a surface strengthening treatment method of ultra-thin large-plate glass, which solves the technical problems of uneven surface strengthening treatment, easy breaking and difficult cutting of the ultra-thin large-plate glass through the technical method, so that the breakage rate of the ultra-thin large-plate glass in the toughening process is lower than three thousandth, the toughening grain size is more uniform, and the cuttability of the ultra-thin large-plate toughened glass is realized.
The technical scheme adopted by the invention is as follows:
a surface strengthening treatment method for ultra-thin large-plate glass comprises a surface cleaning treatment method for glass before tempering; an anti-crushing method for a toughened bearing substrate frame; a molten salt pool three-dimensional omnibearing intelligent temperature control method; a method for uniformly replacing sodium and potassium ions on the surface of the ultrathin large-plate-surface glass and controlling the density of the potassium ions in a molten salt pool; a method for desalting the surface of ultra-thin large-plate glass after toughening.
The method for cleaning the glass surface before tempering comprises the steps of cleaning the surface of the glass by using a special cleaning agent for glass in a disc brushing mode, removing dirt, cleaning by using a plurality of groups of composite rolling brushes, spraying deionized water at high pressure in a double-channel mode and removing water by strong wind; the vertical washing and decontamination of the surface plate brush by adopting the special cleaning agent for the glass comprises two rows of vertical soft bristle circular brushes, wherein when the surface of the ultrathin large-plate-surface glass is uniformly sprayed with a cleaning agent diluent and moves to the vertical soft bristle circular brushes, the circular brush is linked by a speed reduction motor and grinds the upper surface and the lower surface of the passing glass at a rotary grinding speed of 680 r/min to remove oil stains and surface attachments.
The anti-crushing method of the toughened bearing substrate frame comprises the steps of bearing substrate frame glass anti-collision material selection, structural design and sinking damping design of ultrathin large-plate-surface glass; the glass anti-collision material of the bearing substrate frame is preferably a high-temperature-resistant and corrosion-resistant 316 stainless steel material; the glass anti-collision structure of the bearing substrate frame comprises high-temperature-resistant and corrosion-resistant 316 stainless steel 80-mesh and 120-mesh gauze, and the anti-collision structure at the upper end is designed into a 120-mesh stainless steel double-layer spheroid and is embedded at the lower ends of the spaced broken bolts of the plates; the sinking damping structure of the ultrathin large-plate-surface glass comprises two layers of 80-mesh and 120-mesh 316 stainless steel gauze rolls arranged on a toughened bearing substrate frame glass base, wherein the 80-mesh gauze roll is fixed on the bearing substrate frame glass base, and the 120-mesh gauze roll is fixed on the 80-mesh gauze roll.
The molten salt pool three-dimensional all-dimensional temperature control method comprises molten salt pool heating source power arrangement, thermocouple temperature sensing arrangement and an intelligent temperature control system; the molten salt pool heating source power arrangement and the thermocouple temperature sensing arrangement are that 16 heating sources and 16 temperature sensing thermocouples are uniformly arranged at the bottom of the molten salt pool, the vertical surfaces around the molten salt pool and the surface of a cover plate at the top of the pool; the intelligent temperature control system comprises a three-dimensional omnibearing temperature sensing thermocouple arrangement, a temperature signal feedback processing system and a sodium-potassium ion replacement process temperature setting.
The method for uniformly replacing the sodium and potassium ions on the surface of the ultrathin large-plate-surface glass mainly comprises a molten salt pool potassium ion density distribution and control method; the density distribution of the potassium ions in the molten salt pool is the local density of the potassium ions in the molten salt pool liquid salt body; the molten salt pool potassium ion density control method is to regulate and control local area temperature through measurement data fed back by a metal ion probe.
The method for desalting the surface of the glass after the ultra-thin large plate surface is tempered mainly comprises a double-sided clear water spraying method, a warm water soaking method, a large ultrasonic surface oscillation method and a multi-group composite rolling brush cleaning method; the double-sided clear water spraying comprises desalting clear water spraying on the first surface of the toughened glass substrate; the warm water soaking comprises the steps of hoisting the toughened glass substrate sprayed by clear water and the bearing substrate frame into a warm water tank together for soaking and desalting; the large ultrasonic surface oscillation comprises an ultrasonic pool and an ultrasonic oscillator; cleaning multiple groups of composite rolling brushes and cleaning the glass surface before tempering, namely, taking out the tempered glass substrate subjected to ultrasonic surface treatment and finally cleaning the multiple groups of composite rolling brushes.
The invention has the following advantages:
the invention provides a surface strengthening treatment method of ultrathin large-plate-surface glass, which comprises a glass surface cleaning treatment method before tempering; an anti-crushing method for a toughened bearing substrate frame; a molten salt pool three-dimensional omnibearing intelligent temperature control method; a method for uniformly replacing sodium and potassium ions on the surface of the ultrathin large-plate-surface glass and controlling the density of the potassium ions in a molten salt pool; the technical problems of uneven surface strengthening treatment, easy breakage and difficult cutting of the ultra-thin large-plate glass are solved by the method, the breakage rate of the ultra-thin large-plate glass in the toughening process is lower than three thousandth, the toughened particle size is more uniform, and the cuttability of the ultra-thin large-plate toughened glass is realized.
Detailed Description
The present invention will be further described below, but the present invention is not limited to these.
Examples
A surface strengthening treatment method for ultra-thin large-plate glass comprises a surface cleaning treatment method for glass before tempering; an anti-crushing method for a toughened bearing substrate frame; a molten salt pool three-dimensional omnibearing intelligent temperature control method; a method for uniformly replacing sodium and potassium ions on the surface of the ultrathin large-plate-surface glass and controlling the density of the potassium ions in a molten salt pool; a method for desalting the surface of ultra-thin large-plate glass after toughening.
The method for cleaning the glass surface before tempering comprises the steps of cleaning the surface of the glass by using a special cleaning agent for glass in a disc brushing mode, removing dirt, cleaning by using a plurality of groups of composite rolling brushes, spraying deionized water at high pressure in a double-channel mode and removing water by strong wind; the vertical washing and decontamination of the surface disc brush by adopting the special glass cleaning agent comprises two rows of vertical soft bristle circular brushes, wherein each row of vertical soft bristle circular brushes is arranged in a mode of one centimeter at intervals, the front row and the rear row of vertical soft bristle circular brushes are arranged in a mode of Chinese character 'pin', the adjusting gap is set between 0mm and 3mm by the tip-to-tip arrangement of the soft bristles of the upper and lower groups of disc brushes, and the length of the soft bristles of the disc brushes is 30 mm; when the surface of the ultrathin large-plate-surface glass is uniformly sprayed with a cleaning agent diluent and moves to a vertical soft-bristle disc brush, the upper surface and the lower surface of the passing glass are ground at a 680 r/min rotary grinding speed in a linkage manner by a speed reduction motor to remove oil stains and surface attachments.
The tempered bearing substrate frame anti-crushing method comprises bearing substrate frame glass anti-collision material selection, structural design and sinking damping design of ultrathin large-plate-surface glass, wherein the bearing substrate frame glass anti-collision material selection is preferably high-temperature-resistant and corrosion-resistant 316 stainless steel material, the bearing substrate frame glass anti-collision structure comprises high-temperature-resistant and corrosion-resistant 316 stainless steel 80-mesh and 120-mesh gauze, and the upper-end anti-collision structure is designed into a 120-mesh stainless steel double-layer spheroid and is embedded at the lower end of a piece interval broken bolt; the sinking damping structure of the ultrathin large-plate-surface glass comprises two layers of 80-mesh and 120-mesh 316 stainless steel gauze rolls arranged on a toughened bearing substrate frame glass base, wherein the 80-mesh gauze roll is fixed on the bearing substrate frame glass base, and the 120-mesh gauze roll is fixed on the 80-mesh gauze roll.
The three-dimensional omnibearing temperature control method for the molten salt pool comprises a molten salt pool heating source power arrangement, a thermocouple temperature sensing arrangement and an intelligent temperature control system, wherein the molten salt pool heating source power arrangement and the thermocouple temperature sensing arrangement are that 16 heating sources and 16 temperature sensing thermocouples are uniformly arranged at the bottom of the molten salt pool, the vertical surfaces around the molten salt pool and the surface of a pool top cover plate; the intelligent temperature control system comprises a three-dimensional omnibearing temperature sensing thermocouple arrangement, a temperature signal feedback processing system and a sodium-potassium ion replacement process temperature setting.
The method mainly comprises a molten salt pool potassium ion density distribution and control method, wherein the molten salt pool potassium ion density distribution is the local density of potassium ions in a molten salt pool liquid salt body, and the molten salt pool potassium ion density control method is used for carrying out local location temperature regulation and control through measurement data fed back by a metal ion probe.
The method for desalting the surface of the glass after the ultra-thin large plate surface is tempered mainly comprises a double-sided clear water spraying method, a warm water soaking method, a large ultrasonic surface oscillation method and a multi-group composite rolling brush cleaning method; the double-sided clear water spraying comprises desalting clear water spraying on the first surface of the toughened glass substrate; the warm water soaking comprises the steps of hoisting the toughened glass substrate sprayed by clear water and the bearing substrate frame into a warm water tank together for soaking and desalting; the large ultrasonic surface oscillation comprises an ultrasonic pool and an ultrasonic oscillator; cleaning multiple groups of composite rolling brushes and cleaning the glass surface before tempering, namely, taking out the tempered glass substrate subjected to ultrasonic surface treatment and finally cleaning the multiple groups of composite rolling brushes.
It is noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.

Claims (6)

1. A surface strengthening treatment method of ultrathin large-plate-surface glass is characterized by comprising the following steps: comprises a glass surface cleaning treatment method before tempering; an anti-crushing method for a toughened bearing substrate frame; a molten salt pool three-dimensional omnibearing intelligent temperature control method; a method for uniformly replacing sodium and potassium ions on the surface of the ultrathin large-plate-surface glass and controlling the density of the potassium ions in a molten salt pool; a method for desalting the surface of ultra-thin large-plate glass after toughening.
2. The surface strengthening treatment method of the ultra-thin large-plate-surface glass according to claim 1, characterized in that: the method for cleaning the surface of the glass before tempering comprises the steps of cleaning the surface of the glass by using a special cleaning agent for the glass in a disc brushing mode, removing dirt, cleaning by using a plurality of groups of composite rolling brushes, spraying deionized water at high pressure in a double-channel mode and removing water by strong wind.
3. The surface strengthening treatment method of the ultra-thin large-plate-surface glass according to claim 1, characterized in that: the anti-crushing method of the toughened bearing substrate frame comprises the steps of selection of anti-collision materials of the glass of the bearing substrate frame, structural design and sinking damping design of the ultra-thin large-plate-surface glass.
4. The surface strengthening treatment method of the ultra-thin large-plate-surface glass according to claim 1, characterized in that: the three-dimensional omnibearing temperature control method for the molten salt pool comprises molten salt pool heating source power arrangement, thermocouple temperature sensing arrangement and an intelligent temperature control system.
5. The surface strengthening treatment method of the ultra-thin large-plate-surface glass according to claim 1, characterized in that: the method for uniformly replacing the sodium and potassium ions on the surface of the ultrathin large-plate-surface glass mainly comprises a molten salt pool potassium ion density distribution and control method.
6. The surface strengthening treatment method of the ultra-thin large-plate-surface glass according to claim 1, characterized in that: the method for desalting the surface of the glass after the ultra-thin large plate surface is tempered mainly comprises the steps of double-sided clear water spraying, warm water soaking, large-scale ultrasonic surface oscillation and multi-group composite rolling brush cleaning.
CN202010951174.1A 2020-09-11 2020-09-11 Surface strengthening treatment method for ultrathin large-plate-surface glass Pending CN112062480A (en)

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CN202010951174.1A CN112062480A (en) 2020-09-11 2020-09-11 Surface strengthening treatment method for ultrathin large-plate-surface glass

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Application Number Priority Date Filing Date Title
CN202010951174.1A CN112062480A (en) 2020-09-11 2020-09-11 Surface strengthening treatment method for ultrathin large-plate-surface glass

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030090005A1 (en) * 2001-11-09 2003-05-15 Nippon Sheet Glass Co., Ltd. Chemical strengthening treatment unit for applying chemical strengthening treatment to glass substrates used in information recording media applications
US20150329406A1 (en) * 2012-12-21 2015-11-19 Nippon Electric Glass Co., Ltd. Strengthened glass, strengthened glass plate, strengthened glass container, and glass for strengthening
WO2016037343A1 (en) * 2014-09-12 2016-03-17 Schott Glass Technologies (Suzhou) Co. Ltd. Ultrathin chemically toughened glass article and method for producing such a glass article
CN105936589A (en) * 2016-07-01 2016-09-14 广东拓捷科技股份有限公司 Manufacturing method of ultrathin toughened glass and ultrathin, superlight, bendable and permanently antibacterial protection film prepared from ultrathin toughened glass
CN205676364U (en) * 2016-06-06 2016-11-09 中国洛阳浮法玻璃集团有限责任公司 A kind of chemical tempering ultra-thin glass tempering support
CN107056046A (en) * 2017-03-23 2017-08-18 彩虹集团公司 A kind of tempering sheet glass and preparation method thereof
WO2018062141A1 (en) * 2016-09-30 2018-04-05 旭硝子株式会社 Method for producing chemically toughened glass
CN108623140A (en) * 2018-05-31 2018-10-09 福耀玻璃工业集团股份有限公司 A kind of fused salt and its steel process for ultra-thin soda-lime glass chemical tempering
JP2019006615A (en) * 2017-06-21 2019-01-17 Agc株式会社 Manufacturing method of chemically strengthened glass
CN110436764A (en) * 2019-08-07 2019-11-12 秦皇岛玻璃工业研究设计院有限公司 A kind of ultra-thin glass chemical tempering equipment and toughening method

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030090005A1 (en) * 2001-11-09 2003-05-15 Nippon Sheet Glass Co., Ltd. Chemical strengthening treatment unit for applying chemical strengthening treatment to glass substrates used in information recording media applications
US20150329406A1 (en) * 2012-12-21 2015-11-19 Nippon Electric Glass Co., Ltd. Strengthened glass, strengthened glass plate, strengthened glass container, and glass for strengthening
WO2016037343A1 (en) * 2014-09-12 2016-03-17 Schott Glass Technologies (Suzhou) Co. Ltd. Ultrathin chemically toughened glass article and method for producing such a glass article
CN205676364U (en) * 2016-06-06 2016-11-09 中国洛阳浮法玻璃集团有限责任公司 A kind of chemical tempering ultra-thin glass tempering support
CN105936589A (en) * 2016-07-01 2016-09-14 广东拓捷科技股份有限公司 Manufacturing method of ultrathin toughened glass and ultrathin, superlight, bendable and permanently antibacterial protection film prepared from ultrathin toughened glass
WO2018062141A1 (en) * 2016-09-30 2018-04-05 旭硝子株式会社 Method for producing chemically toughened glass
CN107056046A (en) * 2017-03-23 2017-08-18 彩虹集团公司 A kind of tempering sheet glass and preparation method thereof
JP2019006615A (en) * 2017-06-21 2019-01-17 Agc株式会社 Manufacturing method of chemically strengthened glass
CN108623140A (en) * 2018-05-31 2018-10-09 福耀玻璃工业集团股份有限公司 A kind of fused salt and its steel process for ultra-thin soda-lime glass chemical tempering
CN110436764A (en) * 2019-08-07 2019-11-12 秦皇岛玻璃工业研究设计院有限公司 A kind of ultra-thin glass chemical tempering equipment and toughening method

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Application publication date: 20201211