CN112060734A - 一种自清洁型pvc覆膜金属板 - Google Patents
一种自清洁型pvc覆膜金属板 Download PDFInfo
- Publication number
- CN112060734A CN112060734A CN202010913490.XA CN202010913490A CN112060734A CN 112060734 A CN112060734 A CN 112060734A CN 202010913490 A CN202010913490 A CN 202010913490A CN 112060734 A CN112060734 A CN 112060734A
- Authority
- CN
- China
- Prior art keywords
- layer
- pvc
- metal plate
- self
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 98
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 98
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 72
- 239000002184 metal Substances 0.000 title claims abstract description 72
- 238000004140 cleaning Methods 0.000 title claims abstract description 42
- 239000002313 adhesive film Substances 0.000 claims abstract description 25
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 20
- 239000010959 steel Substances 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 19
- 239000000853 adhesive Substances 0.000 claims abstract description 9
- 230000001070 adhesive effect Effects 0.000 claims abstract description 9
- -1 aluminum magnesium manganese Chemical compound 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920001577 copolymer Polymers 0.000 claims description 36
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 23
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 18
- 239000003381 stabilizer Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 239000004014 plasticizer Substances 0.000 claims description 8
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 6
- 239000003431 cross linking reagent Substances 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 6
- 229920000098 polyolefin Polymers 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 claims description 3
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 claims description 3
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- FIYMNUNPPYABMU-UHFFFAOYSA-N 2-benzyl-5-chloro-1h-indole Chemical compound C=1C2=CC(Cl)=CC=C2NC=1CC1=CC=CC=C1 FIYMNUNPPYABMU-UHFFFAOYSA-N 0.000 claims description 3
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 3
- HTCRKQHJUYBQTK-UHFFFAOYSA-N 2-ethylhexyl 2-methylbutan-2-yloxy carbonate Chemical compound CCCCC(CC)COC(=O)OOC(C)(C)CC HTCRKQHJUYBQTK-UHFFFAOYSA-N 0.000 claims description 3
- RFSCGDQQLKVJEJ-UHFFFAOYSA-N 2-methylbutan-2-yl benzenecarboperoxoate Chemical compound CCC(C)(C)OOC(=O)C1=CC=CC=C1 RFSCGDQQLKVJEJ-UHFFFAOYSA-N 0.000 claims description 3
- CARSMBZECAABMO-UHFFFAOYSA-N 3-chloro-2,6-dimethylbenzoic acid Chemical compound CC1=CC=C(Cl)C(C)=C1C(O)=O CARSMBZECAABMO-UHFFFAOYSA-N 0.000 claims description 3
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 3
- 102100035474 DNA polymerase kappa Human genes 0.000 claims description 3
- 101710108091 DNA polymerase kappa Proteins 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- RZLXRFDFCORTQM-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCCn1c(=O)n(CCO)c(=O)n(CCO)c1=O Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCCn1c(=O)n(CCO)c(=O)n(CCO)c1=O RZLXRFDFCORTQM-UHFFFAOYSA-N 0.000 claims description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 3
- XRMBQHTWUBGQDN-UHFFFAOYSA-N [2-[2,2-bis(prop-2-enoyloxymethyl)butoxymethyl]-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CC)COCC(CC)(COC(=O)C=C)COC(=O)C=C XRMBQHTWUBGQDN-UHFFFAOYSA-N 0.000 claims description 3
- KNSXNCFKSZZHEA-UHFFFAOYSA-N [3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical class C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C KNSXNCFKSZZHEA-UHFFFAOYSA-N 0.000 claims description 3
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 claims description 3
- 230000002745 absorbent Effects 0.000 claims description 3
- 239000002250 absorbent Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical compound O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 claims description 3
- 239000012760 heat stabilizer Substances 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 210000002489 tectorial membrane Anatomy 0.000 claims description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 abstract description 96
- 239000002131 composite material Substances 0.000 abstract description 13
- 239000000463 material Substances 0.000 abstract description 8
- 238000010276 construction Methods 0.000 abstract description 5
- 239000002861 polymer material Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002344 surface layer Substances 0.000 abstract description 3
- 238000007789 sealing Methods 0.000 abstract description 2
- 238000003466 welding Methods 0.000 abstract description 2
- 239000004831 Hot glue Substances 0.000 description 6
- 229920006254 polymer film Polymers 0.000 description 6
- 239000003292 glue Substances 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000002905 metal composite material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 238000010345 tape casting Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004795 extruded polystyrene foam Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010096 film blowing Methods 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/712—Weather resistant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/754—Self-cleaning
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
本发明公开了一种自清洁型PVC覆膜金属板，包括依次层叠的：金属板层、高分子胶膜层和聚氯乙烯层；所述聚氯乙烯层延伸至金属板层和高分子胶膜层外围，且聚氯乙烯层的厚度不小于高分子胶膜层的厚度；所述聚氯乙烯层选用均质型PVC或内增强型PVC；所述金属板层选用钢板、铝板或铝镁锰板。本发明自清洁型PVC覆膜金属板生产工艺简单，一次成型，无需使用油性和水性的胶粘剂，全部采用高分子材料生产完成。本发明自清洁型PVC覆膜金属板是一种便捷化施工、耐候性优良、自清洁表层、更优异复合力的覆膜金属板。聚氯乙烯层具有延伸部分，主要用于材料的密封焊接，可实现板材和板材之间无缝施工，确保防水性。
Description
技术领域
本发明涉及一种自清洁型PVC覆膜金属板。
背景技术
彩涂钢板是钢板和有机材料的复合，既具有钢板的机械强度、易成型性能，又具有涂层材料良好的装饰性、耐腐蚀性，广泛应用于工厂厂房、车站、机场、体育馆等各类建筑。彩涂板目前国内外广泛使用，但随着中国经济的高速发展，国内客户对彩涂板的需求和要求越来越高。
现有彩涂板质量问题较多，比如钢板质量不一，选择非品牌类金属板；油漆和喷漆工艺不良，经常发生漏涂、有色差、耐候性差、褪色较快等问题，目前彩涂板使用寿命差的话也就1-2年就会漏水，只能返工维修处理，好一些的也只能质保4-5年。
专利CN109648949A公开一种高分子防水复合金属板及其制备办法，该专利通过将第一高分子防水卷材层、玻璃纤维非织物内增强层、第二高分子防水层、第一胶粘层和金属板层连接成一体，需要靠胶粘剂进行粘结，且胶粘剂是压敏胶。
专利CN102995840A公开一种屋面金属复合板，该专利构造包括金属基板、挤塑聚苯乙烯泡沫板、金属面板，通过胶合剂粘合在一起，但未公开胶合剂的品类。
发明内容
为解决现有技术的缺陷，本发明提供一种自清洁型PVC覆膜金属板，包括依次层叠的：金属板层、高分子胶膜层和聚氯乙烯层；
所述聚氯乙烯层延伸至金属板层和高分子胶膜层外围，且聚氯乙烯层的厚度不小于高分子胶膜层的厚度；
所述聚氯乙烯层选用均质型PVC或内增强型PVC；
所述金属板层选用钢板、铝板或铝镁锰板。
优选的，所述聚氯乙烯层具有两个相反表面特性，一面和胶膜层粘结，另一面有自清洁功能。
优选的，所述聚氯乙烯层延伸出金属板层和高分子胶膜层外围的长度为20～100mm。
优选的，所述高分子胶膜层厚度均一，高分子胶膜层的平均厚度为0.01～0.2mm。
优选的，按重量份计，聚氯乙烯层由以下组分组成：
100份PVC树脂粉，
30～80份增塑剂，
2～6份稳定剂，
5～30份钛白粉，
10～20份填料，
0.01～0.2份抗紫外剂，
0.1～1份PE蜡，
0.1～1份硬脂酸，
0.1～5份丙烯酸加工助剂。
优选的，所述PVC树脂粉为聚氯乙烯悬浮树脂，由乙烯法聚合而成，聚合度1000～1500；
所述增塑剂选自DOP、DINP、DOTP、环氧大豆油中的一种或几种；
述稳定剂为热稳定剂，选自铅盐类、钙锌类、有机类稳定剂中的一种或几种；
所述钛白粉为金红石型钛白粉；
所述填料选自碳酸钙、滑石粉、陶土中的一种或几种；
所述抗紫外剂选自紫外线吸收剂、光屏蔽剂、受阻胺类稳定剂中的一种或几种。
优选的，按重量份计，高分子胶膜层由以下组分组成：
10-35份马来酸酐改性的聚乙烯-酯类共聚物；
30-60份聚乙烯-酯类共聚物；
5-40份聚烯烃共聚物；
0.1-1份引发剂；
0.2-2份硅烷；
0.1-2份交联剂。
优选的，所述的硅烷选自乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三(β-甲氧基乙氧基)硅烷中的一种或几种；
所述马来酸酐改性的聚乙烯-酯类共聚物选自马来酸酐改性的聚乙烯-醋酸乙烯酯共聚物、马来酸酐改性的聚乙烯-丙烯酸甲酯共聚物、马来酸酐改性的聚乙烯-丙烯酸乙酯共聚物和马来酸酐改性的聚乙烯-丙烯酸丁酯共聚物中的一种或几种；
所述聚乙烯-酯类共聚物选自聚乙烯-醋酸乙烯酯共聚物、聚乙烯-丙烯酸甲酯共聚物、聚乙烯-丙烯酸乙酯共聚物和聚乙烯-丙烯酸丁酯共聚物中的一种或几种；
所述聚烯烃共聚物选自聚乙烯-丁烯共聚物、聚乙烯-辛烯共聚物、聚乙烯-丙烯共聚物、非晶态α-烯烃共聚物中的一种或几种；
所述引发剂选自过氧化二苯甲酰、过氧化3,5,5三甲基己酸叔丁酯、过氧化苯甲酸叔戊酯、过氧化2-乙基己基碳酸叔丁酯、过氧化2-乙基己基碳酸叔戊酯、1,1-二叔戊基过氧化-3,3,5-三甲基环己烷、1,1-二叔丁基过氧化-3,3,5-三甲基环己烷、1,1-二叔丁基过氧化环己烷中的一种或几种；
所述交联剂选自三烯丙基异氰脲酸酯、三羟甲基丙烷三甲基丙烯酸酯、三羟甲基丙烷三丙烯酸酯、三(2-羟乙基)异氰脲酸三丙烯酸酯、季戊四醇三丙烯酸酯、(3)乙氧化三羟甲基丙烷三丙烯酸酯、(3)丙氧化三羟甲基丙烷三丙烯酸酯、(4)乙氧化季戊四醇四丙烯酸酯、(3)丙氧化丙三醇三丙烯酸酯、季戊四醇四丙烯酸酯、二-三羟甲基丙烷四丙烯酸酯、双季戊四醇六丙烯酸酯中的一种或几种。
本发明通过将聚氯乙烯层、高分子胶膜层和金属板层连接成一体，可采用传统彩涂板的施工工艺，施工便捷、耐候性优异、质保20年以上，表面的聚氯乙烯层还具有自清洁功能层，有效避免灰尘等异物，可提供屋面彩色方案，另外也可应用于维修屋面。
本发明自清洁型PVC覆膜金属板生产工艺简单，一次成型，无需使用油性和水性的胶粘剂，全部采用高分子材料生产完成。本发明自清洁型PVC覆膜金属板是一种便捷化施工、耐候性优良、自清洁表层、更优异复合力的覆膜金属板。
聚氯乙烯层是可以作为外露层使用的卷材，表层涂覆自清洁层；高分子胶膜层是采用多层共挤吹膜工艺生产的，兼顾PVC和钢板的粘结力，较传统一层复合力提高2倍。
本发明自清洁型PVC覆膜金属板可用作金属屋面板，可设计耐久年限，常规耐久年限起底保证10年；杜绝传统普通彩钢板喷漆后，没有几年就出现褪色、生锈等情况。另外，本发明一体化覆膜金属板可以有效节约施工工期，在维修项目上具有节约时效性、节约人工和提供材料使用寿命的特点。
本发明解决户外使用无自清洁性、胶膜不在单一使用一层，能够有效提高复合力。
与现有技术相比，本发明还具备如下优点和有益效果：
1、本发明采用高分子材料进行PVC和金属板的粘结，有效避免传统采用胶粘剂涉及的环保问题；
2、本发明聚氯乙烯层为耐候层，适用面广泛，灵活多变；如果是维修项目可直接使用玻纤均质型PVC和钢板复合，如果是新建项目要求高，也可采用内增强型PVC进行复合；
3、本发明金属板层可选用的钢板、铝板、铝镁锰板等金属板；
4、本发明金属屋面板是一体化材料，施工便捷，操作灵活；
5、本发明聚氯乙烯层耐候性优异、表面有自清洁层，可以减少屋面污染；
6、本发明高分子胶膜层是通过选用特殊材料共挤而成，有效提高现有单层胶膜复合力不足的问题。
为了提供足够的耐候性，聚氯乙烯层的厚度不小于高分子胶膜层的厚度。
聚氯乙烯层延伸至金属板层和高分子胶膜层外围，即聚氯乙烯层具有延伸部分，延伸部分长度20～100mm，主要用于材料的密封焊接，可实现板材和板材之间无缝施工，确保防水性。
附图说明
图1和图2是本发明的示意图。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
如图1和图2所示，本发明提供一种自清洁型PVC覆膜金属板，包括金属板层，金属板层为镀锌钢板、铝板或铝镁锰板，在金属板层上具有厚度均一的高分子胶膜层，高分子胶膜层平均厚度0.01～0.2mm，以及具有两个相反表面特性(一面有自清洁层，一面和胶膜层粘结)的聚氯乙烯层，为了提供足够的耐候性，聚氯乙烯层厚度大于等于高分子胶膜层，并且材料为保持良好的防水性，聚氯乙烯层会延伸出20～100mm用于焊接密封功能。
自清洁型PVC覆膜金属板的宽度50～200cm，优选的在80～120cm。
高分子胶膜层的厚度小于聚氯乙烯层和金属板层。
所述聚氯乙烯层选用均质型PVC或内增强型PVC。均质型PVC层或内增强型PVC层提供产品整体的耐候性、防水功能。还可以设计彩色、自清洁层和抗静电层等特殊需求。
所述聚氯乙烯层包括PVC树脂粉、增塑剂、填充料、加工助剂、钛白粉等组成，通过双螺杆挤出机挤出压延而成；
按重量份计，聚氯乙烯层由以下组分组成：
100份PVC树脂粉，
30～80份增塑剂，
2～6份稳定剂，
5～30份钛白粉，
10～20份填料，
0.01～0.2份抗紫外剂，
0.1～1份PE蜡，
0.1～1份硬脂酸，
0.1～5份丙烯酸加工助剂；
所述PVC树脂粉为聚氯乙烯悬浮树脂，由乙烯法聚合而成，聚合度1000～1500，优选1300聚合度；
所述增塑剂为添加到聚合物材料中能使聚合物塑性增加的物质，选自DOP、DINP、DOTP、环氧大豆油等增塑剂中的一种或几种；
所述稳定剂为热稳定剂，选自铅盐类、钙锌类、有机类稳定剂中的一种或几种；
所述钛白粉为金红石型钛白粉；
所述填料选自碳酸钙、滑石粉、陶土中的一种或几种；
所述抗紫外剂选自紫外线吸收剂、光屏蔽剂、受阻胺类稳定剂中的一种或几种；
所述PE蜡为加工助剂；
所述硬脂酸为加工助剂；
所述丙烯酸加工助剂为陶氏生产，增加加工性。
高分子胶膜层是一种PVC与金属粘结的双层复合热熔胶膜，可以由上下双层胶膜复合构成，双层复合胶膜的厚度是0.01mm～0.20mm，优选厚度0.02～0.12mm，最优选厚度0.03～0.08mm；上层为与金属粘结的热熔胶层，厚度为复合膜厚度的20％～60％，下层为与PVC粘结的热熔胶层，厚度为复合膜厚度的40％～80％，利用普通流延机经过两次挤出流延复合得到双层复合热熔胶膜；
按重量份计，高分子胶膜层由以下组分组成：
10-35份马来酸酐改性的聚乙烯-酯类共聚物；
30-60份聚乙烯-酯类共聚物；
5-40份聚烯烃共聚物；
0.1-1份引发剂；
0.2-2份硅烷；
0.1-2份交联剂；
所述的硅烷选自乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三(β-甲氧基乙氧基)硅烷中的一种或几种；
所述马来酸酐改性的聚乙烯-酯类共聚物选自马来酸酐改性的聚乙烯-醋酸乙烯酯共聚物、马来酸酐改性的聚乙烯-丙烯酸甲酯共聚物、马来酸酐改性的聚乙烯-丙烯酸乙酯共聚物和马来酸酐改性的聚乙烯-丙烯酸丁酯共聚物中的一种或几种；
所述聚乙烯-酯类共聚物选自聚乙烯-醋酸乙烯酯共聚物、聚乙烯-丙烯酸甲酯共聚物、聚乙烯-丙烯酸乙酯共聚物和聚乙烯-丙烯酸丁酯共聚物中的一种或几种；
所述聚烯烃共聚物选自聚乙烯-丁烯共聚物、聚乙烯-辛烯共聚物、聚乙烯-丙烯共聚物、非晶态α-烯烃共聚物中的一种或几种；
所述引发剂选自过氧化二苯甲酰、过氧化3,5,5三甲基己酸叔丁酯、过氧化苯甲酸叔戊酯、过氧化2-乙基己基碳酸叔丁酯、过氧化2-乙基己基碳酸叔戊酯、1,1-二叔戊基过氧化-3,3,5-三甲基环己烷、1,1-二叔丁基过氧化-3,3,5-三甲基环己烷、1,1-二叔丁基过氧化环己烷中的一种或几种；
所述交联剂选自三烯丙基异氰脲酸酯、三羟甲基丙烷三甲基丙烯酸酯、三羟甲基丙烷三丙烯酸酯、三(2-羟乙基)异氰脲酸三丙烯酸酯、季戊四醇三丙烯酸酯、(3)乙氧化三羟甲基丙烷三丙烯酸酯、(3)丙氧化三羟甲基丙烷三丙烯酸酯、(4)乙氧化季戊四醇四丙烯酸酯、(3)丙氧化丙三醇三丙烯酸酯、季戊四醇四丙烯酸酯、二-三羟甲基丙烷四丙烯酸酯、双季戊四醇六丙烯酸酯中的一种或几种。
金属板层主要从宝钢、首钢、马钢、中铝等优质供应商采购。优异的金属板必须经过上料→开卷→夹送、矫直→焊接→清洗→入口活套→退火→镀锌→(合金化)→冷却→中间活套→平整→拉矫→后处理→出口活套→检查卷取一系列工艺流程处理方可使用。所述金属板厚度在0.1-3mm，优选0.3-2mm，最优选0.5-1mm。
主要考察金属板与胶膜层和PVC层的粘结强度要足够牢靠。要求粘结力≥75N/mm，在沸水中蒸煮≥72h，不出现鼓包、脱开等现象。
表1自清洁型PVC覆膜金属板需满足的性能指标
专利CN111231451A公开一种TPO覆膜金属板，TPO覆膜金属板的结构同本发明类似，但本发明解决户外使用无自清洁性、胶膜不在单一使用一层，能够有效提高复合力。
取自清洁型PVC覆膜金属板和TPO金属复合板、普通彩钢板进行人工气候加速老化、耐酸碱盐、外观和颜色的变化
主要实验方案：
1、取400*400mm的PVC覆膜金属板和普通彩钢板放于人工气候老化箱，进行老化性能的测试，分别以2500h为单位，进行2500h、5000h、7500h、10000h的性能测试外观、颜色变化、粘结力的测试
表2自清洁型PVC覆膜金属板与TPO覆膜金属板以及普通彩钢板的老化性能对比表
2、取200*100mm的自清洁型PVC覆膜金属板和普通彩钢板置于5％酸、氢氧化钙饱和碱溶液、10％氯化钠盐溶液中，浸泡72h观察鼓包分层情况
表3自清洁型PVC覆膜金属板与TPO覆膜金属板以及普通彩钢板的耐酸、耐碱和耐盐性能对比表
3、取少量炭黑均匀涂抹至自清洁型PVC覆膜金属板、普通彩涂板表面，然后使用湿抹布进行擦拭，观察效果
表4自清洁型PVC覆膜金属板与TPO覆膜金属板的自清洁性能对比表
| 自清洁性 | |
| 自清洁型PVC覆膜金属板 | 通过 |
| 普通彩钢板 | 不通过，炭黑擦拭不掉 |
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (8)
1.一种自清洁型PVC覆膜金属板，其特征在于，包括依次层叠的：金属板层、高分子胶膜层和聚氯乙烯层；
所述聚氯乙烯层延伸至金属板层和高分子胶膜层外围，且聚氯乙烯层的厚度不小于高分子胶膜层的厚度；
所述聚氯乙烯层选用均质型PVC或内增强型PVC；
所述金属板层选用钢板、铝板或铝镁锰板。
2.根据权利要求1所述的自清洁型PVC覆膜金属板，其特征在于，所述聚氯乙烯层一面和胶膜层粘结，另一面有自清洁功能。
3.根据权利要求1所述的自清洁型PVC覆膜金属板，其特征在于，所述聚氯乙烯层延伸出金属板层和高分子胶膜层外围的长度为20～100mm。
4.根据权利要求1所述的自清洁型PVC覆膜金属板，其特征在于，所述高分子胶膜层的平均厚度为0.01～0.2mm。
5.根据权利要求1所述的自清洁型PVC覆膜金属板，其特征在于，按重量份计，聚氯乙烯层由以下组分组成：
100份PVC树脂粉，
30～80份增塑剂，
2～6份稳定剂，
5～30份钛白粉，
10～20份填料，
0.01～0.2份抗紫外剂，
0.1～1份PE蜡，
0.1～1份硬脂酸，
0.1～5份丙烯酸加工助剂。
6.根据权利要求5所述的自清洁型PVC覆膜金属板，其特征在于，所述PVC树脂粉为聚氯乙烯悬浮树脂，由乙烯法聚合而成，聚合度1000～1500；
所述增塑剂选自DOP、DINP、DOTP、环氧大豆油中的一种或几种；
述稳定剂为热稳定剂，选自铅盐类、钙锌类、有机类稳定剂中的一种或几种；
所述钛白粉为金红石型钛白粉；
所述填料选自碳酸钙、滑石粉、陶土中的一种或几种；
所述抗紫外剂选自紫外线吸收剂、光屏蔽剂、受阻胺类稳定剂中的一种或几种。
7.根据权利要求6所述的自清洁型PVC覆膜金属板，其特征在于，按重量份计，高分子胶膜层由以下组分组成：
10-35份马来酸酐改性的聚乙烯-酯类共聚物；
30-60份聚乙烯-酯类共聚物；
5-40份聚烯烃共聚物；
0.1-1份引发剂；
0.2-2份硅烷；
0.1-2份交联剂。
8.根据权利要求7所述的自清洁型PVC覆膜金属板，其特征在于，所述的硅烷选自乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三(β-甲氧基乙氧基)硅烷中的一种或几种；
所述马来酸酐改性的聚乙烯-酯类共聚物选自马来酸酐改性的聚乙烯-醋酸乙烯酯共聚物、马来酸酐改性的聚乙烯-丙烯酸甲酯共聚物、马来酸酐改性的聚乙烯-丙烯酸乙酯共聚物和马来酸酐改性的聚乙烯-丙烯酸丁酯共聚物中的一种或几种；
所述聚乙烯-酯类共聚物选自聚乙烯-醋酸乙烯酯共聚物、聚乙烯-丙烯酸甲酯共聚物、聚乙烯-丙烯酸乙酯共聚物和聚乙烯-丙烯酸丁酯共聚物中的一种或几种；
所述聚烯烃共聚物选自聚乙烯-丁烯共聚物、聚乙烯-辛烯共聚物、聚乙烯-丙烯共聚物、非晶态α-烯烃共聚物中的一种或几种；
所述引发剂选自过氧化二苯甲酰、过氧化3,5,5三甲基己酸叔丁酯、过氧化苯甲酸叔戊酯、过氧化2-乙基己基碳酸叔丁酯、过氧化2-乙基己基碳酸叔戊酯、1,1-二叔戊基过氧化-3,3,5-三甲基环己烷、1,1-二叔丁基过氧化-3,3,5-三甲基环己烷、1,1-二叔丁基过氧化环己烷中的一种或几种；
所述交联剂选自三烯丙基异氰脲酸酯、三羟甲基丙烷三甲基丙烯酸酯、三羟甲基丙烷三丙烯酸酯、三(2-羟乙基)异氰脲酸三丙烯酸酯、季戊四醇三丙烯酸酯、(3)乙氧化三羟甲基丙烷三丙烯酸酯、(3)丙氧化三羟甲基丙烷三丙烯酸酯、(4)乙氧化季戊四醇四丙烯酸酯、(3)丙氧化丙三醇三丙烯酸酯、季戊四醇四丙烯酸酯、二-三羟甲基丙烷四丙烯酸酯、双季戊四醇六丙烯酸酯中的一种或几种。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010913490.XA CN112060734A (zh) | 2020-09-03 | 2020-09-03 | 一种自清洁型pvc覆膜金属板 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010913490.XA CN112060734A (zh) | 2020-09-03 | 2020-09-03 | 一种自清洁型pvc覆膜金属板 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112060734A true CN112060734A (zh) | 2020-12-11 |
Family
ID=73665990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010913490.XA Pending CN112060734A (zh) | 2020-09-03 | 2020-09-03 | 一种自清洁型pvc覆膜金属板 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112060734A (zh) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202106619U (zh) * | 2011-05-13 | 2012-01-11 | 北京市物佳攀士科技贸易有限公司 | 金属板 |
| CN103756577A (zh) * | 2013-12-31 | 2014-04-30 | 广州鹿山新材料股份有限公司 | 一种pvc/金属粘接热熔胶膜及其制备方法 |
| CN204659085U (zh) * | 2015-02-10 | 2015-09-23 | 朝闻电梯装备科技（苏州）有限公司 | 一种电梯用覆膜钢板 |
| CN105585793A (zh) * | 2014-10-21 | 2016-05-18 | 中国石油化工股份有限公司 | 一种具有表面自洁功能的pvc混合物及其制备方法 |
| CN108532879A (zh) * | 2018-04-16 | 2018-09-14 | 鲁志高 | 外墙装饰件及其制备方法 |
| CN111171492A (zh) * | 2020-01-16 | 2020-05-19 | 江苏凯伦建材股份有限公司 | Pvc防水卷材 |
-
2020
- 2020-09-03 CN CN202010913490.XA patent/CN112060734A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202106619U (zh) * | 2011-05-13 | 2012-01-11 | 北京市物佳攀士科技贸易有限公司 | 金属板 |
| CN103756577A (zh) * | 2013-12-31 | 2014-04-30 | 广州鹿山新材料股份有限公司 | 一种pvc/金属粘接热熔胶膜及其制备方法 |
| CN105585793A (zh) * | 2014-10-21 | 2016-05-18 | 中国石油化工股份有限公司 | 一种具有表面自洁功能的pvc混合物及其制备方法 |
| CN204659085U (zh) * | 2015-02-10 | 2015-09-23 | 朝闻电梯装备科技（苏州）有限公司 | 一种电梯用覆膜钢板 |
| CN108532879A (zh) * | 2018-04-16 | 2018-09-14 | 鲁志高 | 外墙装饰件及其制备方法 |
| CN111171492A (zh) * | 2020-01-16 | 2020-05-19 | 江苏凯伦建材股份有限公司 | Pvc防水卷材 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8603272B2 (en) | Multilayer films containing a fluorinated copolymer resin layer and an encapsulant layer | |
| CN108440848B (zh) | 一种内增强复合丁基自粘乙丙橡胶防水卷材及其生产方法 | |
| EP2046574A2 (en) | Roofing membrane | |
| JP2013501102A (ja) | 光起電力セル用の架橋性封止材 | |
| KR20130093611A (ko) | 플루오르화된 공중합체 수지 층 및 에틸렌 삼원공중합체 층을 함유하는 다층 구조체 | |
| CN111231451B (zh) | 覆膜金属板 | |
| US20030198813A1 (en) | Polymeric membranes | |
| CN103950256B (zh) | 一种表面易清洁的tpo防水卷材及其制备方法 | |
| CN112060734A (zh) | 一种自清洁型pvc覆膜金属板 | |
| CN203831866U (zh) | 一种eva复合片材双面自粘防水卷材 | |
| CN112606498A (zh) | 一种可粘结的tpo防水卷材、其制备方法及应用 | |
| CN103730531A (zh) | 一种免胶黏剂且耐湿热的太阳能电池背板及其制造方法 | |
| CN104314246B (zh) | 一种一体化防渗漏节能降噪屋面系统 | |
| CN205890067U (zh) | 一种三元乙丙橡胶防水卷材、混凝土基防水结构 | |
| CN205488164U (zh) | 一种高粘结性防水型太阳能背板 | |
| CN204282738U (zh) | 一种集装箱房屋专用铝箔复合地板 | |
| CN218966343U (zh) | 一种矿物粒保护型外露高分子防水卷材 | |
| CN214423785U (zh) | 一种用于金属屋面的防水卷材 | |
| CN212603811U (zh) | 一种钢板tpo卷材复合防水结构 | |
| CN218321203U (zh) | 一种外露用高强耐候防水卷材 | |
| CN217175395U (zh) | 一种预铺反粘型高分子自粘胶膜防水片材 | |
| CN210767530U (zh) | 一种可循环利用的波纹瓦 | |
| CN213501258U (zh) | 一种内部耐撕扯缠绕膜 | |
| CN214266933U (zh) | 一种hdpe土工膜 | |
| CN209794792U (zh) | 一种复合环保防水卷材 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20201211 |
|
| RJ01 | Rejection of invention patent application after publication |