CN112047673A - C40 inorganic coating composite anti-freezing concrete and preparation method thereof - Google Patents

C40 inorganic coating composite anti-freezing concrete and preparation method thereof Download PDF

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Publication number
CN112047673A
CN112047673A CN202010703880.4A CN202010703880A CN112047673A CN 112047673 A CN112047673 A CN 112047673A CN 202010703880 A CN202010703880 A CN 202010703880A CN 112047673 A CN112047673 A CN 112047673A
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Prior art keywords
concrete
sand
preparation
inorganic coating
stirring
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Inventor
严武建
王平
王兰民
朱朝霞
许世阳
郭海涛
郑海忠
王会娟
牛富航
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Earthquake Administration Of Gansu Province
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Earthquake Administration Of Gansu Province
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/76Use at unusual temperatures, e.g. sub-zero
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)

Abstract

The invention discloses C40 inorganic coating composite antifreeze concrete and a preparation method thereof. The paint comprises the following components in parts by weight: cement 400-450 parts; 750 portions of sand and 800 portions of sand; 1000 portions of stone 950-; 4-5 parts of an additive; 150 portions of water and 200 portions of water; the additive comprises an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent and a polycarboxylic acid water reducing agent in a weight ratio of 1: 1. The invention has simple formula and good freezing resistance and durability, and is suitable for various engineering projects in alpine regions.

Description

C40 inorganic coating composite anti-freezing concrete and preparation method thereof
Technical Field
The invention relates to C40 inorganic coating composite anti-freezing concrete used in alpine regions and a preparation method thereof, belonging to the technical field of concrete.
Background
Most areas in China belong to severe cold regions, and the requirement on the frost resistance of buildings is high. Under the conditions of severe cold and extreme temperature difference, the internal and external contraction of the conventional concrete is inconsistent, so that the internal stress of the concrete is increased, and cracks are generated.
In order to improve the frost resistance of concrete, an inorganic coating is usually added to the concrete, and the bonding property and the waterproof property of the concrete are enhanced depending on the performance of the inorganic coating. However, in the later stage of concrete curing, fine cracks still can be generated inside concrete due to large temperature difference between the inside and the outside in severe cold areas, and the internal cracks gradually increase along with continuous freezing and melting, so that the strength of the whole concrete construction building is influenced.
Disclosure of Invention
In view of the above, the invention provides the C40 inorganic coating composite anti-freezing concrete and the preparation method thereof, and the inorganic coating is added to improve the waterproof and bonding properties of the concrete, thereby improving the anti-freezing durability of the concrete.
The invention solves the technical problems by the following technical means:
the invention relates to C40 inorganic coating composite antifreeze concrete which comprises the following components in parts by weight:
Figure BDA0002593959910000011
the additive comprises an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent and a polycarboxylic acid water reducing agent in a weight ratio of 1: 1.
The stones are continuously graded with a particle size of 5-25 mm.
The sand uses natural medium sand in the II area.
A preparation method of C40 inorganic coating composite antifreeze concrete comprises the following steps:
1) pouring sand and pebbles into respective raw material bins for pre-homogenization, wherein the pre-homogenization time is 5-10min, and the stirring speed is 5-10 r/min;
2) placing the pre-homogenized sand and gravel in a forced stirrer, and stirring at a speed of 3-6r/min for 2 min;
3) adding cement, fiber, a polycarboxylic acid water reducing agent and water into a forced stirrer, stirring for 5min, adding an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent, and stirring for 2 min.
By adopting the technical scheme, the sand and the stones are used as basic lapping frameworks of the concrete, the quantity of the stones is large, and the sand is filled in gaps among the stones and forms the basic lapping frameworks of the concrete with the stones. Cement and a water reducing agent are dissolved in water to form viscous slurry, and the slurry is wrapped on the outside of the lap joint frameworks to enhance the bonding effect between the lap joint frameworks, so that the strength of the concrete basic framework is improved. The XT-HPA is added into concrete to raise the adhesion and prevent concrete shrinkage crack.
In addition, the admixture comprises XT-HPA penetration type and polycarboxylic acid water reducing agent. The XT-HPA penetration type can improve the bonding property between the concrete lap joint framework and the slurry, and the polycarboxylic acid water reducing agent added into the concrete can further reduce the water consumption and increase the bonding strength between the lap joint frameworks.
The invention uses the stones with 5-25mm continuous gradation as basic lapping frameworks, the sizes of the stones are different, the stones with smaller particles are filled among the stones with larger particle sizes, and the concrete frameworks with different lapping levels are integrally formed. The natural medium sand in the area II has smaller grain diameter and is filled in gaps among stones, so that the strength of the lapped framework is further enhanced.
The concrete prepared by the proportion has good compression resistance, and the loss of strength is small after multiple freeze-thaw cycles.
The preparation method is characterized in that after the sand and the stones are pre-homogenized, the surfaces of the sand and the stones are mutually rubbed to form a new section, the section is easily mixed with the slurry, and the adhesion is strong.
When the concrete is prepared, sand and stones for constructing the concrete framework are uniformly stirred in advance, and then the sand and the stones are mixed with cement and a water reducing agent to form a uniformly dispersed concrete system. And then, an XT-HPA environment-friendly high-permeability inorganic crystalline waterproof agent is added and stirred, and the slurry, the sand and the stones are bonded by an XT-HPA environment-friendly high-permeability inorganic crystalline waterproof agent solution, so that the coating is tighter.
The invention has the following beneficial effects:
1. the continuous graded stones and sands are mutually filled and overlapped to form a stable concrete framework, so that the compressive strength of the concrete is increased.
2. The XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent is added into the concrete, so that the bonding effect between the basic lap joint framework of the concrete and the gel substance is improved.
3. The water reducing agent is a polycarboxylic acid water reducing agent, so that the bonding strength of the lap joint framework and the gel substance in the concrete is further improved.
Drawings
FIG. 1 shows the preparation process of the C40 inorganic coating composite antifreeze concrete of the present invention.
Detailed Description
The C40 inorganic coating composite antifreeze concrete comprises the following components in parts by weight:
Figure BDA0002593959910000031
the additive comprises an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent and a polycarboxylic acid water reducing agent in a weight ratio of 1: 1.
The stones are continuously graded with a particle size of 5-25 mm.
The sand uses natural medium sand in the II area.
A preparation method of C40 inorganic coating composite antifreeze concrete comprises the following steps:
1) pouring sand and pebbles into respective raw material bins for pre-homogenization, wherein the pre-homogenization time is 5-10min, and the stirring speed is 5-10 r/min;
2) placing the pre-homogenized sand and gravel in a forced stirrer, and stirring at a speed of 3-6r/min for 2 min;
3) adding cement, fiber, a polycarboxylic acid water reducing agent and water into a forced stirrer, stirring for 5min, adding an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent, and stirring for 2 min.
Example 1
The present invention is described in further detail below with reference to fig. 1.
The raw materials according to the present invention are all commercially available, and specific specifications are shown in table 1.
TABLE 1 Specifications of raw materials used in the examples
Components Specification of
Cement 42.5 grade ordinary portland cement
Sand Natural medium sand in zone II
Stone Crushed stone of 5-25mm
XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent
Water reducing agent Polycarboxylic acid water reducing agent
A method for preparing inorganic coating composite frost resistant concrete comprises the following steps:
the method comprises the following steps: 785kg of sand and 999kg of pebbles are introduced into respective raw material bins for pre-homogenization;
step two: 785kg of sand and 999kg of stones are put in a forced stirrer to be stirred for 2 min;
step three: 440kg of cement and 2.2kg of water reducing agent are added into a forced stirrer to be stirred for 5min, and then 2.2kgXT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent is added to be stirred for 2 min.
Wherein the admixture comprises the following components in percentage by weight of 1:1 XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent and polycarboxylic acid water reducing agent.
The freeze-thaw cycle test of the inorganic coating composite anti-freezing concrete prepared by the mixture ratio is carried out according to the fast freeze-thaw test regulation in the test method for the long-term durability and the durability of common concrete (GBJ82-85), and the dynamic elastic modulus and the quality of the test are tested; the compressive strength is in accordance with GB/T50081-2002 Standard of mechanical Properties test methods of ordinary concrete.
The frost resistance of the inorganic coating concrete is tested as follows: placing the concrete test block and the test piece which are maintained in the water saturation state for 28 days into a rubber barrel, placing the rubber barrel into a rapid freeze-thaw circulating machine for freeze-thaw circulating test, wherein the water surface is 2cm higher than that of the concrete test block and the test block, the concrete test block and the test block are in the water saturation state in the freeze-thaw process, and the compression strength, the dynamic elastic modulus and the quality are tested every 50 times of freeze-thaw circulation. The freezing resistance coefficient, the relative dynamic elastic modulus and the mass loss are respectively obtained for 300 times, and the three types of test data are specifically shown in table 2.
Table 2 shows three types of test data of the inorganic coating composite antifreeze concrete
Figure BDA0002593959910000051
From the above data, it can be seen that the concrete prepared by the above formulation has initial compressive strength, dynamic elastic modulus and mass of 58.5MPa, 47.63GPa and 9.8875kg, respectively, and can bear sufficient strength. After 300 times of circulating freeze thawing, the freeze resistance coefficient, the relative dynamic elastic modulus and the mass loss rate are 114.71%, 103.09% and 0.28% respectively, the compressive strength and the dynamic elastic modulus are increased, which shows that the concrete with the mixing ratio has good frost resistance and the hydration reaction is promoted to increase the strength, the mass loss rate is far lower than 5%, the national standard of testing method of the long-term durability and durability of common concrete (GBJ82-85) is reached, meanwhile, the mass loss rate of the concrete is extremely low due to the internal doping of the inorganic coating, the compressive strength is far higher than the standard of C40 concrete, no crack is generated on the surface of the concrete after 300 times of circulating freeze thawing, the strength is reduced slightly, and the concrete has good frost resistance.
The admixture uses an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent and a polycarboxylic acid water reducing agent in a weight ratio of 1:1, so that the using amount of water in concrete is reduced, and the viscosity of the slurry is increased. The bonding between the lapping skeleton formed by the sand and the stones and the slurry is firmer under the action of an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent and a polycarboxylic acid water reducing agent, so that the frost resistance of the concrete is improved. .
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.

Claims (4)

1. The C40 inorganic coating composite anti-freezing concrete and the preparation method thereof are characterized by comprising the following components in parts by weight:
Figure FDA0002593959900000011
the additive comprises an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent and a polycarboxylic acid water reducing agent in a weight ratio of 1: 1.
2. The composite antifreeze concrete with the C40 inorganic coating and the preparation method thereof according to claim 1, is characterized in that: the stones are continuously graded with a particle size of 5-25 mm.
3. The composite antifreeze concrete with the C40 inorganic coating and the preparation method thereof according to claim 1, is characterized in that: the sand uses natural medium sand in the II area.
4. The C40 inorganic coating composite anti-freezing concrete and the preparation method thereof are characterized by comprising the following steps:
1) pouring sand and pebbles into respective raw material bins for pre-homogenization, wherein the pre-homogenization time is 5-10min, and the stirring speed is 5-10 r/min;
2) placing the pre-homogenized sand and gravel in a forced stirrer, and stirring at a speed of 3-6r/min for 2 min;
3) adding cement, fiber, a polycarboxylic acid water reducing agent and water into a forced stirrer, stirring for 5min, adding an XT-HPA environment-friendly high-permeability inorganic crystalline waterproofing agent, and stirring for 2 min.
CN202010703880.4A 2020-07-21 2020-07-21 C40 inorganic coating composite anti-freezing concrete and preparation method thereof Pending CN112047673A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2660224A1 (en) * 2010-12-28 2013-11-06 Mischenko, Valentyn Nikolayevich Waterproofing composition
CN105272042A (en) * 2015-11-02 2016-01-27 中国三冶集团有限公司 Anti-freezing and anti-cracking concrete
CN105948654A (en) * 2016-05-12 2016-09-21 南通科达建材股份有限公司 High-durability silicate concrete for dam
CN108623246A (en) * 2017-03-24 2018-10-09 北京市小红门混凝土有限责任公司 Frost-resistant concrete and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2660224A1 (en) * 2010-12-28 2013-11-06 Mischenko, Valentyn Nikolayevich Waterproofing composition
CN105272042A (en) * 2015-11-02 2016-01-27 中国三冶集团有限公司 Anti-freezing and anti-cracking concrete
CN105948654A (en) * 2016-05-12 2016-09-21 南通科达建材股份有限公司 High-durability silicate concrete for dam
CN108623246A (en) * 2017-03-24 2018-10-09 北京市小红门混凝土有限责任公司 Frost-resistant concrete and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周睿彤: "渗透结晶防水剂对混凝土抗冻性能影响的研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *

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