CN112029320A - Ceramic powder capable of promoting blood circulation, sterilizing and releasing far infrared rays and application of ceramic powder in diatom ooze water-based paint - Google Patents
Ceramic powder capable of promoting blood circulation, sterilizing and releasing far infrared rays and application of ceramic powder in diatom ooze water-based paint Download PDFInfo
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- CN112029320A CN112029320A CN202010965391.6A CN202010965391A CN112029320A CN 112029320 A CN112029320 A CN 112029320A CN 202010965391 A CN202010965391 A CN 202010965391A CN 112029320 A CN112029320 A CN 112029320A
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- ceramic powder
- far infrared
- parts
- blood circulation
- infrared rays
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 239000000843 powder Substances 0.000 title claims abstract description 52
- 239000000919 ceramic Substances 0.000 title claims abstract description 41
- 230000003578 releasing effect Effects 0.000 title claims abstract description 21
- 230000017531 blood circulation Effects 0.000 title claims abstract description 20
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 19
- 230000001737 promoting effect Effects 0.000 title claims abstract description 15
- 239000003973 paint Substances 0.000 title claims description 24
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000002245 particle Substances 0.000 claims abstract description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000000498 ball milling Methods 0.000 claims abstract description 21
- 238000003825 pressing Methods 0.000 claims abstract description 14
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 11
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- 238000005245 sintering Methods 0.000 claims abstract description 10
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011324 bead Substances 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 238000005469 granulation Methods 0.000 claims abstract description 7
- 230000003179 granulation Effects 0.000 claims abstract description 7
- 238000007873 sieving Methods 0.000 claims abstract description 7
- 239000007921 spray Substances 0.000 claims abstract description 7
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 7
- 239000013078 crystal Substances 0.000 claims abstract description 5
- 238000001354 calcination Methods 0.000 claims abstract description 3
- 230000003213 activating effect Effects 0.000 claims abstract 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000000178 monomer Substances 0.000 claims description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 13
- 229910052710 silicon Inorganic materials 0.000 claims description 13
- 239000010703 silicon Substances 0.000 claims description 13
- 239000002518 antifoaming agent Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 230000000844 anti-bacterial effect Effects 0.000 claims description 10
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 235000019359 magnesium stearate Nutrition 0.000 claims description 5
- OKPYIWASQZGASP-UHFFFAOYSA-N n-(2-hydroxypropyl)-2-methylprop-2-enamide Chemical compound CC(O)CNC(=O)C(C)=C OKPYIWASQZGASP-UHFFFAOYSA-N 0.000 claims description 5
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 claims description 5
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 5
- 229940001584 sodium metabisulfite Drugs 0.000 claims description 5
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 5
- NCDYOSPPJZENCU-UHFFFAOYSA-M triethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CCOC(=O)C=C NCDYOSPPJZENCU-UHFFFAOYSA-M 0.000 claims description 5
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 claims description 4
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 3
- UUORTJUPDJJXST-UHFFFAOYSA-N n-(2-hydroxyethyl)prop-2-enamide Chemical compound OCCNC(=O)C=C UUORTJUPDJJXST-UHFFFAOYSA-N 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- IOMDIVZAGXCCAC-UHFFFAOYSA-M diethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](CC)(CC)CC=C IOMDIVZAGXCCAC-UHFFFAOYSA-M 0.000 claims description 2
- 230000005284 excitation Effects 0.000 claims description 2
- ATEAWHILRRXHPW-UHFFFAOYSA-J iron(2+);phosphonato phosphate Chemical compound [Fe+2].[Fe+2].[O-]P([O-])(=O)OP([O-])([O-])=O ATEAWHILRRXHPW-UHFFFAOYSA-J 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 claims description 2
- ZEMHQYNMVKDBFJ-UHFFFAOYSA-N n-(3-hydroxypropyl)prop-2-enamide Chemical compound OCCCNC(=O)C=C ZEMHQYNMVKDBFJ-UHFFFAOYSA-N 0.000 claims description 2
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 claims description 2
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 2
- ZKODLPLYXXUCHB-UHFFFAOYSA-M sodium;hydroxymethanesulfinate;hydrate Chemical compound O.[Na+].OCS([O-])=O ZKODLPLYXXUCHB-UHFFFAOYSA-M 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 claims description 2
- 229910003454 ytterbium oxide Inorganic materials 0.000 claims description 2
- 229940075624 ytterbium oxide Drugs 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- 241000894006 Bacteria Species 0.000 claims 2
- PYSICBWGPVJGHM-UHFFFAOYSA-N 2-ethenyl-1,2-thiazol-3-one Chemical compound C=CN1SC=CC1=O PYSICBWGPVJGHM-UHFFFAOYSA-N 0.000 claims 1
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 239000012855 volatile organic compound Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 239000000017 hydrogel Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- -1 oxygen ions Chemical class 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 244000082946 Tarchonanthus camphoratus Species 0.000 description 1
- 235000005701 Tarchonanthus camphoratus Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012767 functional filler Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays, which is prepared by the following method: (1) preparing mixed material particles: adding transition metal oxide, silicon dioxide, aluminum oxide, cerium dioxide and water into ball milling equipment, performing ball milling for 4-6h, then adding discharged materials, and performing spray granulation to obtain material particles with the particle size of 20 meshes and the water content of 10 +/-2%; (2) and (3) sintering: pressing the material particles in the step (1) into a plate by dry pressing under the pressure of 30MPa, and then calcining for 5-8h in a tubular kiln at the temperature of 1400 ℃ and 1500 ℃ in a weak reducing atmosphereThen cooling to room temperature to obtain a compact plate; (3) crushing: and crushing the compact plate, ball-milling zirconium beads for 48 hours, and sieving with a 1200-mesh sieve to obtain the ceramic powder for activating blood circulation, sterilizing and releasing far infrared rays. Conversion of ceria to Ce during sintering in a weakly reducing atmosphere2O3The crystal phases and the crystal phases among different powder bodies are mutually interpenetrated to form the ceramic powder for activating blood circulation, sterilizing and releasing far infrared rays.
Description
The invention relates to a divisional application of a Chinese patent 'a bicomponent diatom ooze water-based paint with zero VOC emission', wherein the application date is 11 months and 10 days in 2018, and the application number is 201811335452. X.
Technical Field
The invention belongs to the technical field of building coatings, and relates to ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays and application thereof in diatom ooze water-based coatings.
Background
With the rapid development of national economy and the gradual improvement of the living standard of people's materials, indoor decoration is increasingly popularized. Two thirds of the life of a person spends indoors, and the life and working time of modern people in indoor environment reaches 80% -90% of the whole day, so the quality of the indoor environment directly influences the health of the people.
The diatom ooze is a dry powder-shaped interior wall decoration coating material prepared by taking an inorganic gelled substance as a main binding material and a diatom material as a main functional filler. Has the functions of eliminating formaldehyde, purifying air, regulating humidity, releasing negative oxygen ions, preventing fire, retarding fire, self-cleaning wall surface, sterilizing, deodorizing, etc. The diatom ooze paint is used for replacing wallpaper and latex paint and is suitable for decorating inner walls of villas, apartments, hotels, homes, hospitals and the like, but the diatom ooze produced by a plurality of manufacturers is unreasonably matched in materials, the surface area of the diatom ooze is sealed, the performance of the diatom ooze is greatly reduced, a more reasonable formula system is needed for developing the diatom ooze paint, and therefore a better decorating material is provided for people.
CN201710130255.3 discloses a diatom ooze biotechnological water-based paint and a preparation method and application thereof, wherein the diatom ooze biotechnological water-based paint is prepared from the following components in parts by weight: 10-30 parts of deionized water, 10-25 parts of heavy calcium carbonate, 10-25 parts of titanium dioxide, 5-20 parts of talcum powder, 10-25 parts of acrylic emulsion or silicone-acrylic emulsion or polyurethane emulsion, 1-25 parts of kaolin, 10-30 parts of diatom ooze, 1-10 parts of natural camphorwood essential oil, 1-10 parts of biotech coconut essential oil and 5-25 parts of auxiliary agent. The product of the invention has simple production process, generates negative ions through photocatalysis, and improves the comprehensive effect of the water-based paint. However, the invention will be used with acrylic or silicone-acrylic or polyurethane emulsions that generate VOC emissions.
Disclosure of Invention
In order to overcome the defects and shortcomings of the prior art, the invention aims to provide a two-component diatom ooze water-based paint with zero VOC emission.
The invention adopts the following technical scheme that the two-component diatom ooze water-based paint with zero VOC (volatile organic compounds) emission consists of A, B components in parts by weight: the component A comprises 0.5-1 part of potassium persulfate, 30-40 parts of diatom ooze powder, 10-15 parts of rutile titanium dioxide, 6-12 parts of far infrared ceramic powder, 45-75 parts of water, 1-2 parts of flatting agent and 0.3-0.6 part of defoaming agent; the component B comprises 6-12 parts of crosslinkable monomer, 2-4 parts of antibacterial monomer, 0.1-0.3 part of catalyst, 3-5 parts of water-based stearate and 15-25 parts of water.
The leveling agent is polyether modified organic silicon leveling agent, and the defoaming agent is organic silicon defoaming agent.
The crosslinking monomer is at least one of N-hydroxyethyl acrylamide, N-hydroxypropyl acrylamide, N- (2-hydroxypropyl) methacrylamide and N- (1, 1-dimethyl-3-oxobutyl) acrylamide.
The antibacterial monomer is at least one of dimethyl diallyl ammonium chloride, acryloyloxyethyl trimethyl ammonium chloride, diethyl diallyl ammonium chloride, acryloyloxyethyl triethyl ammonium chloride and N-vinyl isothiazole-3-ketone.
The catalyst is at least one of silver nitrate, ferrous pyrophosphate, sucrose, sodium metabisulfite and sodium hydroxymethanesulfinate hydrate.
The water-based stearate is a stearate dispersion liquid with the mass fraction of 40-50%, and the stearate is at least one of magnesium stearate, zinc stearate and calcium stearate.
The particle sizes of the diatom ooze powder, the rutile type titanium dioxide and the far infrared ceramic powder are all 1200 meshes.
The far infrared ceramic powder is prepared by the following method:
(1) preparing mixed material particles: adding 5-10 parts of transition metal oxide, 5-10 parts of silicon dioxide, 5-10 parts of alumina, 10-15 parts of cerium dioxide and 50-80 parts of water into ball milling equipment for ball milling for 4-6h, then adding a discharged material, and carrying out spray granulation to obtain material particles with the particle size of 20 meshes and the water content of 10% +/-2%;
(2) and (3) sintering: pressing the material particles in the step (1) into a plate by dry pressing under the pressure of 30MPa, then calcining for 5-8h in a tubular kiln at the temperature of 1400 ℃ and 1500 ℃ in a weak reducing atmosphere, and then cooling to room temperature to obtain a compact plate;
(3) crushing: and crushing the compact plate, ball-milling the compact plate for 48 hours by using zirconium beads, and sieving the compact plate by using a 1200-mesh sieve to obtain the far infrared ceramic powder.
The transition metal oxide, the silicon dioxide, the alumina, the cerium dioxide and the water in the step (1) have the weight part ratio of (5-10): (5-10): (5-10): (10-15): (50-80); the particle size of the transition metal oxide, the silicon dioxide, the aluminum oxide and the cerium dioxide is 800 meshes.
The transition metal oxide is at least one of scandium oxide, neodymium oxide, erbium oxide and ytterbium oxide; the weak reducing atmosphere is N with the volume fraction of 90 percent2With 10% by volume of H2The gas mixture is uniformly mixed.
The preparation method comprises the steps of respectively and uniformly dispersing the A, B components by using different dispersing agents, and then respectively packaging the components separately for later use to obtain the component A and the component B; the A, B is mixed and stirred evenly half an hour before use, and then is applied to the inner wall surface by brushing or spraying.
Compared with the prior art, the invention has the following advantages or beneficial results:
(1) the ceramic powder which has health care function, blood circulation promoting and sterilization functions and can release far infrared rays is self-prepared and used for the double-component diatom ooze water-based paint; the mechanism of releasing far infrared rays is as follows: conversion of ceria to Ce during sintering in a weakly reducing atmosphere2O3The crystal phases of different powders are mutually interpenetrated to form the far infrared ceramic powder, wherein Ce3+After the excitation light is efficiently absorbed by using the allowed broadband d-f transition, the energy is transferred to the co-doped Sc3+/Nd3+/Er3+/Yb3+Ions to thereby Sc3+/Nd3+/Er3+/Yb3+The ions generate strong far infrared ray emission;
(2) according to the invention, after the A, B bi-components are mixed, the potassium persulfate-catalyst system initiates the room-temperature free radical polymerization of the crosslinking monomer and the antibacterial monomer to form the hydrogel with the open pore structure, the hydrogel has the functions of absorbing water and harmful substances and is supplemented with diatom ooze to form the environment-friendly and green water-based paint capable of preserving moisture and absorbing the harmful substances;
(3) the components of the invention are inorganic substances, organic silicon (flatting agent and defoaming agent), solid organic substances (crosslinkable monomer and antibacterial monomer), do not contain emulsion (containing residual micromolecules) and other film forming substances, and have real zero VOC in the formula;
(4) the diatom ooze water-based paint contains antibacterial monomers, and the antibacterial monomers are polymerized into one part of a hydrogel molecular chain after being mixed with A, B double components, namely, a plurality of quaternary ammonium salt ion antibacterial groups are arranged on hydrogel molecules.
Detailed Description
The following examples further describe a two-component diatom ooze water-based paint with zero VOC emission. It is to be understood that the specific embodiments described herein are merely illustrative of the relevant invention and not restrictive of the invention.
Example 1
A far infrared ceramic powder X is prepared by the following method:
(1) preparing mixed material particles: adding 9 parts of scandium oxide (800 meshes), 6 parts of silicon dioxide (800 meshes), 9 parts of aluminum oxide (800 meshes), 14 parts of cerium dioxide (800 meshes) and 70 parts of water into ball milling equipment for ball milling for 6 hours according to the parts by weight, then adding a discharging material, and carrying out spray granulation to obtain material particles with the particle size of 20 meshes and the water content of 8%;
(2) and (3) sintering: pressing the material particles in the step (1) into a plate by dry pressing under the pressure of 30MPa, and then in a tubular kiln in a weak reducing atmosphere (N with the volume fraction of 90 percent)2With 10% by volume of H2The uniform mixed gas) at 1500 ℃ for 5 hours, and then cooling to room temperature to obtain a compact plate;
(3) crushing: and crushing the compact plate, ball-milling zirconium beads for 48 hours, and sieving with a 1200-mesh sieve to obtain the far infrared ceramic powder X.
Example 2
A far infrared ceramic powder Y is prepared by the following method:
(1) preparing mixed material particles: adding 6 parts of transition metal oxide, 8 parts of silicon dioxide (800 meshes), 9 parts of aluminum oxide (800 meshes), 11 parts of cerium dioxide (800 meshes) and 60 parts of water into ball milling equipment for ball milling for 5 hours in parts by weight, then adding a discharged material, and carrying out spray granulation to obtain material particles with the particle size of 20 meshes and the water content of 12%;
(2) and (3) sintering: pressing the material particles in the step (1) into a plate by dry pressing under the pressure of 30MPa, and then in a tubular kiln in a weak reducing atmosphere (N with the volume fraction of 90 percent)2With 10% by volume of H2The uniform mixed gas) for 8 hours at 1400 ℃, and then cooling to room temperature to obtain a compact plate;
(3) crushing: and crushing the compact plate, ball-milling the compact plate for 48 hours by using zirconium beads, and sieving the compact plate by using a 1200-mesh sieve to obtain the far infrared ceramic powder Y.
Example 3
A far infrared ceramic powder Z is prepared by the following method:
(1) preparing mixed material particles: adding 5 parts of scandium oxide (800 meshes), 5 parts of silicon dioxide (800 meshes), 5 parts of aluminum oxide (800 meshes), 10 parts of cerium dioxide (800 meshes) and 50 parts of water into ball milling equipment for ball milling for 4 hours according to parts by weight, then adding a discharging material, and carrying out spray granulation to obtain material particles with the particle size of 20 meshes and the water content of 8%;
(2) and (3) sintering: pressing the material particles in the step (1) into a plate by dry pressing under the pressure of 30MPa, and then in a tubular kiln in a weak reducing atmosphere (N with the volume fraction of 90 percent)2With 10% by volume of H2The uniform mixed gas) for 5 hours at 1400 ℃, and then cooling to room temperature to obtain a compact plate;
(3) crushing: and crushing the compact plate, ball-milling the compact plate for 48 hours by using zirconium beads, and sieving the compact plate by using a 1200-mesh sieve to obtain the far infrared ceramic powder Z.
Example 4
A far infrared ceramic powder M is prepared by the following method:
(1) preparing mixed material particles: adding 10 parts by weight of scandium oxide (800 meshes), 10 parts by weight of silicon dioxide (800 meshes), 10 parts by weight of aluminum oxide (800 meshes), 15 parts by weight of cerium dioxide (800 meshes) and 80 parts by weight of water into ball milling equipment, carrying out ball milling for 5 hours, then adding a discharged material, and carrying out spray granulation to obtain material particles with the particle size of 20 meshes and the water content of 12%;
(2) and (3) sintering: pressing the material particles in the step (1) into a plate by dry pressing under the pressure of 30MPa, and then in a tubular kiln in a weak reducing atmosphere (N with the volume fraction of 90 percent)2With 10% by volume of H2The uniform mixed gas) at 1500 ℃ for 5 hours, and then cooling to room temperature to obtain a compact plate;
(3) crushing: and crushing the compact plate, ball-milling zirconium beads for 48 hours, and sieving with a 1200-mesh sieve to obtain the far infrared ceramic powder M.
Example 5
The two-component diatom ooze water-based paint with zero VOC emission is characterized by comprising A, B components in parts by weight: the component A comprises 0.5 part of potassium persulfate, 30 parts of diatom ooze powder (1200 meshes), 10 parts of rutile type titanium dioxide (1200 meshes), 6 parts of far infrared ceramic powder X (1200 meshes), 45 parts of water, 1 part of polyether modified organic silicon leveling agent and 0.3 part of organic silicon defoaming agent; the component B comprises 6 parts of N-hydroxyethyl acrylamide, 2 parts of dimethyl diallyl ammonium chloride, 0.1 part of sodium hydroxymethanesulfinate, 3 parts of a calcium stearate dispersion liquid with the mass fraction of 50% and 15 parts of water.
Example 6
The two-component diatom ooze water-based paint with zero VOC emission is characterized by comprising A, B components in parts by weight: the component A comprises 1 part of potassium persulfate, 40 parts of diatom ooze powder (1200 meshes), 15 parts of rutile type titanium dioxide (1200 meshes), 12 parts of far infrared ceramic powder Y (1200 meshes), 75 parts of water, 2 parts of polyether modified organic silicon leveling agent and 0.6 part of organic silicon defoaming agent, and the component B comprises 12 parts of N- (2-hydroxypropyl) methacrylamide, 4 parts of acryloyloxyethyl triethyl ammonium chloride, 0.3 part of sodium metabisulfite, 5 parts of magnesium stearate dispersion liquid with the mass fraction of 40% and 25 parts of water.
Example 7
The two-component diatom ooze water-based paint with zero VOC emission is characterized by comprising A, B components in parts by weight: the component A comprises 0.8 part of potassium persulfate, 32 parts of diatom ooze powder (1200 meshes), 12 parts of rutile type titanium dioxide (1200 meshes), 11 parts of far infrared ceramic powder Z (1200 meshes), 50 parts of water, 1.2 parts of polyether modified organic silicon leveling agent and 0.5 part of organic silicon defoaming agent, and the component B comprises 10 parts of N- (2-hydroxypropyl) methacrylamide, 3 parts of acryloyloxyethyl triethyl ammonium chloride, 0.15 part of sodium metabisulfite, 4 parts of magnesium stearate dispersion liquid with the mass fraction of 40% and 16 parts of water.
Example 8
The two-component diatom ooze water-based paint with zero VOC emission is characterized by comprising A, B components in parts by weight: the component A comprises 0.6 part of potassium persulfate, 36 parts of diatom ooze powder (1200 meshes), 14 parts of rutile type titanium dioxide (1200 meshes), 7 parts of far infrared ceramic powder M (1200 meshes), 60 parts of water, 1.6 parts of polyether modified organic silicon leveling agent and 0.4 part of organic silicon defoaming agent, and the component B comprises 8 parts of N- (2-hydroxypropyl) methacrylamide, 2.5 parts of acryloyloxyethyl triethyl ammonium chloride, 0.2 part of sodium metabisulfite, 3.5 parts of magnesium stearate dispersion liquid with the mass fraction of 40% and 22 parts of water.
The preparation of examples 5-8 is to disperse the A, B two components uniformly with different dispersants, and then to pack separately the component A and the component B; half an hour before use, A, B is mixed and stirred uniformly and then is applied to the surface of the cement board by brushing or spraying; under the same condition, the commercial diatom ooze coating (comparative example) is brushed on the surface of the cement board with the same material.
The performance tests after drying of examples 5-8 and comparative examples (mainly according to the standard GB/T9756-:
TABLE 1 Performance Table of the latex paints
Table 2: antibacterial property meter (GB/T21866-
As can be seen from table 1, the two-component diatom ooze water-based paint of the examples has higher brushing times and formaldehyde purification efficiency than the commercially available diatom ooze paint; as can be seen from Table 2, the Escherichia coli resistance and Staphylococcus aureus resistance of the examples are more than 99.5%; the embodiment can provide a safer and more environment-friendly environment for life, work and study of people.
While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes, modifications and variations can be made therein without departing from the spirit and scope of the invention as defined in the following claims.
Claims (10)
1. The ceramic powder for activating blood circulation, sterilizing and releasing far infrared rays is characterized by being prepared by the following method:
(1) preparing mixed material particles: adding transition metal oxide, silicon dioxide, aluminum oxide, cerium dioxide and water into ball milling equipment, performing ball milling for 4-6h, then adding discharged materials, and performing spray granulation to obtain material particles with the particle size of 20 meshes and the water content of 10 +/-2%;
(2) and (3) sintering: pressing the material particles in the step (1) into a plate by dry pressing under the pressure of 30MPa, then calcining for 5-8h in a tubular kiln at the temperature of 1400 ℃ and 1500 ℃ in a weak reducing atmosphere, and then cooling to room temperature to obtain a compact plate;
(3) crushing: and crushing the compact plate, ball-milling zirconium beads for 48 hours, and sieving with a 1200-mesh sieve to obtain the ceramic powder for activating blood circulation, sterilizing and releasing far infrared rays.
2. The ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays according to claim 1, wherein the transition metal oxide, the silicon dioxide, the aluminum oxide, the cerium dioxide and the water in the step (1) have a weight ratio of (5-10): (5-10): (5-10): (10-15): (50-80); the particle size of the transition metal oxide, the silicon dioxide, the aluminum oxide and the cerium dioxide is 800 meshes.
3. The ceramic powder for promoting blood circulation, killing bacteria and releasing far infrared rays according to claim 1The material is characterized in that the transition metal oxide is at least one of scandium oxide, neodymium oxide, erbium oxide and ytterbium oxide; the weak reducing atmosphere is N with the volume fraction of 90 percent2With 10% by volume of H2The gas mixture is uniformly mixed.
4. The ceramic powder for promoting blood circulation, killing bacteria and releasing far infrared rays as claimed in claim 1, wherein the cerium oxide is converted into Ce during the sintering process in a weakly reducing atmosphere2O3The crystal phases and the crystal phases among different powder bodies are mutually interpenetrated to form the ceramic powder for activating blood circulation, sterilizing and releasing far infrared rays.
5. The ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays as claimed in claim 1, wherein Ce is contained in the ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays3+After the excitation light is efficiently absorbed by using the allowed broadband d-f transition, the energy is transferred to the co-doped Sc3+/Nd3+/Er3+/Yb3+Ions to thereby Sc3+/Nd3+/Er3+/Yb3+The ions produce a strong far infrared emission.
6. The method for applying the ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays as claimed in claims 1 to 5, wherein the ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays is applied to the diatom ooze water-based paint.
7. The method for applying the ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays as claimed in claim 6, wherein the diatom ooze water-based paint is composed of A, B components in parts by weight:
the component A comprises: 0.5-1 part of potassium persulfate, 30-40 parts of diatom ooze powder, 10-15 parts of rutile type titanium dioxide, 6-12 parts of far infrared ceramic powder, 45-75 parts of water, 1-2 parts of flatting agent and 0.3-0.6 part of defoaming agent;
and B component: 6-12 parts of crosslinkable monomer, 2-4 parts of antibacterial monomer, 0.1-0.3 part of catalyst, 3-5 parts of water-based stearate and 15-25 parts of water.
8. The method for applying the ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays as claimed in claim 7, wherein the leveling agent is a polyether modified organic silicon leveling agent; the defoaming agent is an organic silicon defoaming agent; the crosslinking monomer is at least one of N-hydroxyethyl acrylamide, N-hydroxypropyl acrylamide, N- (2-hydroxypropyl) methacrylamide and N- (1, 1-dimethyl-3-oxobutyl) acrylamide.
9. The method of claim 7, wherein the antibacterial monomer is at least one of dimethyldiallylammonium chloride, acryloyloxyethyltrimethylammonium chloride, diethyldiallylammonium chloride, acryloyloxyethyltriethylammonium chloride, and N-vinyl isothiazol-3-one; the catalyst is at least one of silver nitrate, ferrous pyrophosphate, sucrose, sodium metabisulfite and sodium hydroxymethanesulfinate hydrate.
10. The method for applying the ceramic powder for promoting blood circulation, sterilizing and releasing far infrared rays as claimed in claim 7, wherein the aqueous stearate is a stearate dispersion liquid with a mass fraction of 40-50%; the stearate is at least one of magnesium stearate, zinc stearate and calcium stearate; the particle sizes of the diatom ooze powder, the rutile type titanium dioxide and the far infrared ceramic powder are all 1200 meshes.
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| CN202010965391.6A CN112029320B (en) | 2018-11-10 | 2018-11-10 | Ceramic powder capable of promoting blood circulation, sterilizing and releasing far infrared rays and application of ceramic powder in diatom ooze water-based paint |
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