CN112018432A - 基于硼化合物的新型软材料 - Google Patents
基于硼化合物的新型软材料 Download PDFInfo
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- CN112018432A CN112018432A CN202010418423.0A CN202010418423A CN112018432A CN 112018432 A CN112018432 A CN 112018432A CN 202010418423 A CN202010418423 A CN 202010418423A CN 112018432 A CN112018432 A CN 112018432A
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- electrolyte composition
- anion
- metal salt
- boron cluster
- organic
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- 239000007779 soft material Substances 0.000 title abstract description 3
- 150000001639 boron compounds Chemical class 0.000 title abstract 2
- 239000003792 electrolyte Substances 0.000 claims abstract description 55
- 150000001450 anions Chemical class 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 229910052796 boron Inorganic materials 0.000 claims abstract description 45
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000007787 solid Substances 0.000 claims abstract description 40
- 229910052751 metal Inorganic materials 0.000 claims abstract description 39
- 239000002184 metal Substances 0.000 claims abstract description 39
- 239000011159 matrix material Substances 0.000 claims abstract description 28
- 150000003839 salts Chemical class 0.000 claims abstract description 27
- 150000001768 cations Chemical class 0.000 claims abstract description 17
- 150000002892 organic cations Chemical class 0.000 claims abstract description 11
- 125000001424 substituent group Chemical group 0.000 claims description 23
- -1 salt anion Chemical class 0.000 claims description 15
- 229910052794 bromium Inorganic materials 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 229910052740 iodine Inorganic materials 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000004428 fluoroalkoxy group Chemical group 0.000 claims description 5
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000004104 aryloxy group Chemical group 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000004407 fluoroaryl group Chemical group 0.000 claims description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N tetrahydropyrrole Substances C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 claims 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- 239000007784 solid electrolyte Substances 0.000 abstract description 13
- 238000000465 moulding Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 11
- 239000012071 phase Substances 0.000 description 6
- 229910001251 solid state electrolyte alloy Inorganic materials 0.000 description 6
- 230000007704 transition Effects 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 5
- 239000011343 solid material Substances 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 238000000113 differential scanning calorimetry Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004992 Ionic Liquid Crystal Substances 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- SODQFLRLAOALCF-UHFFFAOYSA-N 1lambda3-bromacyclohexa-1,3,5-triene Chemical group Br1=CC=CC=C1 SODQFLRLAOALCF-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UILDHOGAFALWAD-UHFFFAOYSA-N C(C)[P](C)(CC)CC Chemical compound C(C)[P](C)(CC)CC UILDHOGAFALWAD-UHFFFAOYSA-N 0.000 description 1
- YPIKYEIMKLDCDN-UHFFFAOYSA-N C(CCC)[P](C)(CCCC)CCCC Chemical compound C(CCC)[P](C)(CCCC)CCCC YPIKYEIMKLDCDN-UHFFFAOYSA-N 0.000 description 1
- LYAPTBUGDOKKON-UHFFFAOYSA-N CC(C)[P](C)(C)C Chemical compound CC(C)[P](C)(C)C LYAPTBUGDOKKON-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZOJZLMMAVKKSFE-UHFFFAOYSA-N [P]=S.[Li] Chemical compound [P]=S.[Li] ZOJZLMMAVKKSFE-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- UORVGPXVDQYIDP-BJUDXGSMSA-N borane Chemical compound [10BH3] UORVGPXVDQYIDP-BJUDXGSMSA-N 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- VJBODIYZSOOKES-UHFFFAOYSA-N butyl-ethyl-dimethylazanium Chemical compound CCCC[N+](C)(C)CC VJBODIYZSOOKES-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- BXHHZLMBMOBPEH-UHFFFAOYSA-N diethyl-(2-methoxyethyl)-methylazanium Chemical compound CC[N+](C)(CC)CCOC BXHHZLMBMOBPEH-UHFFFAOYSA-N 0.000 description 1
- KSRKBDUROZKZBR-UHFFFAOYSA-N diethyl-methyl-propylazanium Chemical compound CCC[N+](C)(CC)CC KSRKBDUROZKZBR-UHFFFAOYSA-N 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- GCRCSLNXFKCFHB-UHFFFAOYSA-N triethyl(hexyl)azanium Chemical compound CCCCCC[N+](CC)(CC)CC GCRCSLNXFKCFHB-UHFFFAOYSA-N 0.000 description 1
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0091—Composites in the form of mixtures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Conductive Materials (AREA)
- Secondary Cells (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/424,849 | 2019-05-29 | ||
| US16/424,849 US20200381776A1 (en) | 2019-05-29 | 2019-05-29 | Novel soft materials based on boron compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112018432A true CN112018432A (zh) | 2020-12-01 |
Family
ID=73507048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010418423.0A Pending CN112018432A (zh) | 2019-05-29 | 2020-05-18 | 基于硼化合物的新型软材料 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20200381776A1 (https=) |
| JP (1) | JP7653002B2 (https=) |
| CN (1) | CN112018432A (https=) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11811020B2 (en) * | 2021-02-02 | 2023-11-07 | Toyota Motor Engineering & Manufacturing North America, Inc. | Electrolytes with ultrahigh closo-borate concentrations |
| JP7563373B2 (ja) * | 2021-12-28 | 2024-10-08 | トヨタ自動車株式会社 | 固体電解質、固体電解質の製造方法および全固体電池 |
| US12469884B2 (en) | 2022-06-22 | 2025-11-11 | Toyota Motor Engineering & Manufacturing North America, Inc. | Electrolytes with low cationic mobility activation energies |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006108862A1 (de) * | 2005-04-14 | 2006-10-19 | Universität Bremen | Ionische flüssigkeit |
| US20150099135A1 (en) * | 2013-10-04 | 2015-04-09 | Toyota Motor Engineering & Manufacturing North America, Inc. | Magnesium ion batteries and magnesium electrodes employing magnesium nanoparticles synthesized via a novel reagent |
| US9455473B1 (en) * | 2015-05-12 | 2016-09-27 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ionic liquids for rechargeable magnesium battery |
| US20160372786A1 (en) * | 2015-06-16 | 2016-12-22 | National Institute Of Standards And Technology | Ambient temperature superionic conducting salt and process for making ambient temperature superionic conducting salt |
| US20170018781A1 (en) * | 2012-04-11 | 2017-01-19 | Ionic Materials, Inc. | Solid ionically conducting polymer material |
| US20170200971A1 (en) * | 2016-01-12 | 2017-07-13 | Toyota Motor Engineering & Manufacturing North America, Inc. | Solid-phase magnesium boranyl electrolytes for a magnesium battery |
| US20180040934A1 (en) * | 2016-08-05 | 2018-02-08 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-aqueous magnesium-air battery |
| CN109485579A (zh) * | 2017-09-13 | 2019-03-19 | 丰田自动车工程及制造北美公司 | 制备基于硼簇的离子液体 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015110869A1 (de) * | 2014-07-10 | 2016-01-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | Magnesiumionenbatterien und Magnesiumelektroden, die über ein neues Reagenz synthetisierte Magnesiumnanopartikel verwenden |
| US10505219B2 (en) * | 2017-05-26 | 2019-12-10 | Toyota Motor Engineering & Manufacturing North America, Inc. | Artificial SEI transplantation |
| EP3699996B1 (en) * | 2017-10-19 | 2024-02-14 | Mitsubishi Gas Chemical Company, Inc. | Production method for all-solid-state battery |
-
2019
- 2019-05-29 US US16/424,849 patent/US20200381776A1/en active Pending
-
2020
- 2020-05-18 CN CN202010418423.0A patent/CN112018432A/zh active Pending
- 2020-05-28 JP JP2020093483A patent/JP7653002B2/ja active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006108862A1 (de) * | 2005-04-14 | 2006-10-19 | Universität Bremen | Ionische flüssigkeit |
| US20170018781A1 (en) * | 2012-04-11 | 2017-01-19 | Ionic Materials, Inc. | Solid ionically conducting polymer material |
| US20150099135A1 (en) * | 2013-10-04 | 2015-04-09 | Toyota Motor Engineering & Manufacturing North America, Inc. | Magnesium ion batteries and magnesium electrodes employing magnesium nanoparticles synthesized via a novel reagent |
| US9455473B1 (en) * | 2015-05-12 | 2016-09-27 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ionic liquids for rechargeable magnesium battery |
| US20160372786A1 (en) * | 2015-06-16 | 2016-12-22 | National Institute Of Standards And Technology | Ambient temperature superionic conducting salt and process for making ambient temperature superionic conducting salt |
| US20170200971A1 (en) * | 2016-01-12 | 2017-07-13 | Toyota Motor Engineering & Manufacturing North America, Inc. | Solid-phase magnesium boranyl electrolytes for a magnesium battery |
| US20180040934A1 (en) * | 2016-08-05 | 2018-02-08 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-aqueous magnesium-air battery |
| CN109485579A (zh) * | 2017-09-13 | 2019-03-19 | 丰田自动车工程及制造北美公司 | 制备基于硼簇的离子液体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP7653002B2 (ja) | 2025-03-28 |
| JP2020194777A (ja) | 2020-12-03 |
| US20200381776A1 (en) | 2020-12-03 |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20250214 Address after: Japan Applicant after: Toyota Motor Corp. Country or region after: Japan Address before: Texas in the United States Applicant before: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, Inc. Country or region before: U.S.A. |
|
| TA01 | Transfer of patent application right |