CN111938007A - Pure plant-derived vitamin A and vitamin D sandwich type gel candy - Google Patents

Pure plant-derived vitamin A and vitamin D sandwich type gel candy Download PDF

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Publication number
CN111938007A
CN111938007A CN202010620066.6A CN202010620066A CN111938007A CN 111938007 A CN111938007 A CN 111938007A CN 202010620066 A CN202010620066 A CN 202010620066A CN 111938007 A CN111938007 A CN 111938007A
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CN
China
Prior art keywords
vitamin
sandwich
gel candy
powder
type gel
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Pending
Application number
CN202010620066.6A
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Chinese (zh)
Inventor
原敏敏
吴静
薛大玲
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Guangzhou Procept Biotech Co ltd
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Guangzhou Procept Biotech Co ltd
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Priority to CN202010620066.6A priority Critical patent/CN111938007A/en
Publication of CN111938007A publication Critical patent/CN111938007A/en
Priority to AU2021103596A priority patent/AU2021103596A4/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/48Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/0002Processes of manufacture not relating to composition and compounding ingredients
    • A23G3/0004Processes specially adapted for manufacture or treatment of sweetmeats or confectionery
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/364Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
    • A23G3/368Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing vitamins, antibiotics
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/40Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • A23G3/54Composite products, e.g. layered, coated, filled
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

The invention discloses a sandwich type gel candy of vitamin A and vitamin D from pure plant sources, which adopts fat to emulsify and disperse natural raw materials of dunaliella salina and mushroom powder, the particle size of emulsion drops and powder reaches below 1 mu m, so that beta-carotene in the dunaliella salina, other carotenoids and vitamin D in the mushroom powder are easier to absorb, the nutrient substances of the dunaliella salina and mushroom powder are completely reserved by adopting a low-temperature processing technology, the sandwich type gel candy is processed in a form of the sandwich type gel candy, the sandwich type gel candy is nutrient and delicious, the oxidation of the sandwich is effectively prevented, the stability of the beta-carotene and the vitamin D is protected, the problems of low absorptivity, high chemical pollution risk, poor mouthfeel and unpopularity of the prior art adopting artificially synthesized vitamin A and vitamin D are solved, and the problem of excessive supplement of the vitamin A is also solved.

Description

Pure plant-derived vitamin A and vitamin D sandwich type gel candy
The technical field is as follows:
the invention relates to a pure plant-derived vitamin A vitamin D sandwich type gel candy.
Background art:
at present, products for supplementing vitamin A and vitamin D on the market mainly comprise vitamin A and vitamin D soft capsules, cod liver oil soft capsules, except the soft capsules, a small amount of other formulations of vitamin A and vitamin D, VA and VD belong to oil-soluble vitamins, and the vitamin A and the VD are absorbed by chylomicrons formed by the soft capsules and oil, so that the formulations except the soft capsules are not suitable for being made into formulations for supplementing VA and VD, the raw materials used by the vitamin A and vitamin D soft capsules are chemically synthesized raw materials and are not natural vitamin A and vitamin D, the absorption rate is not high as that of natural vitamin A and vitamin D, certain health risks also exist, the cod liver oil is a natural raw material for supplementing the vitamin A and vitamin D, but the vitamin A and vitamin D in the cod liver oil is not completely suitable for the proportion required by a human body, and the ocean pollution is serious at present, so that the cod liver oil also runs the risk of this certain contamination. In addition, excessive vitamin A administration can cause toxic and side effects, and myelosuppression caused by excessive vitamin A in infants and hypercalcemia caused by excessive vitamin A in adults are reported.
The demand of supplementing VA can be met by supplementing beta-carotene, and the beta-carotene after entering a human body is converted into vitamin A, the conversion is adjustable, the accumulated poisoning of the vitamin A caused by excessive ingestion can not happen, however, the products for supplementing the beta-carotene on the market at present use the chemically synthesized beta-carotene, and have low absorption rate and safety risk.
All the products for supplementing VAVD and beta-carotene are in the product form which is not suitable for supplementing VAVD and beta-carotene, or are prepared into soft capsules which are swallowed, so that difficulty is brought to swallowing, and the soft capsules are not delicious and have poor experience.
The invention content is as follows:
the invention aims to provide a vitamin A vitamin D sandwich type gel candy from pure plant sources, which adopts fat which is not easy to oxidize to emulsify and disperse natural raw materials of dunaliella salina and mushroom powder, the grain diameter of emulsion drops and powder reaches below 1 mu m, so that beta-carotene in the dunaliella salina, other carotenoids and vitamin D in the mushroom powder are easier to absorb, and the low-temperature processing technology is adopted to completely reserve the nutrient substances of the dunaliella salina and the mushroom powder, the sandwich type gel candy is processed in a sandwich type gel candy form, the sandwich type gel candy is nutritional and delicious, meanwhile, the oxidation of the sandwich is effectively prevented, the stability of beta-carotene and vitamin D is protected, the problems that in the prior art, the absorption rate of artificially synthesized vitamin A and vitamin D is low, the chemical pollution risk is high, the taste is not good, and the vitamin A is not popular are solved, and the problem of excessive supplement of the vitamin A is also solved.
The invention is realized by the following technical scheme:
the pure plant source vitamin A vitamin D sandwich type gel candy comprises a sandwich and a skin wrapping the sandwich, wherein the sandwich comprises the following raw materials in percentage by weight of 100 percent: 40% -95% of grease, mushroom powder: 1% -20%, dunaliella salina: 1% -20%, emulsifier: 1% -8%, and other auxiliary materials for blending the taste: 1% -20%; the grease is used for the grease which is not easy to oxidize, the peroxide value of the grease is less than or equal to 0.25g/100g after the grease is sealed and stored in an oven at 37 ℃ for 3 months, the grease generally comprises high oleic acid grease (the oleic acid content is more than or equal to 75 percent), medium chain fatty acid grease and other grease, and the medium chain fatty acid grease refers to fatty acid with 6-12 carbon atoms in a carbon chain; the content of the vitamin D in the mushroom powder is over 12000 IU/kg; the emulsifier comprises one or more of monoglyceride and diglyceride fatty acid ester, sucrose fatty acid ester, phospholipid, beeswax and the like; the other taste blending auxiliary materials comprise sugar, sugar alcohol, other sweeteners, acidity regulator, fruit and vegetable powder, food essence and the like.
The outer shell glue solution comprises gelling agent, water-holding agent and others, wherein the gelling agent comprises gelatin, carrageenan, starch (modified and common), gellan gum and xanthan gum, the water-holding agent comprises glycerol, sugar alcohol, sugar, carboxymethyl cellulose, hydroxypropyl cellulose and microcrystalline cellulose, and the others comprise essence, pigment, sweetener, sour agent and fruit and vegetable juice.
Preferably, the sandwich comprises the following raw materials by the total weight percentage of 100 percent: 45% -90% of grease, mushroom powder: 1% -20%, dunaliella salina: 1% -20%, emulsifier: 2% -6%, and other auxiliary materials for blending the taste: 1 to 20 percent.
The preparation method of the pure plant source vitamin A vitamin D sandwich type gel candy comprises the following steps:
1) preparing a sandwich: preparing powder materials, sieving the powder materials by a sieve of 80 meshes, drying the powder materials with the moisture content below 4 percent, and weighing the powder materials for later use; heating oil and fat to 70-75 deg.C, adding emulsifier, stirring, dissolving, cooling to 60-65 deg.C, adding other adjuvants, stirring, continuously cooling to 40-45 deg.C, adding mushroom powder and Dunaliella salina, stirring, emulsifying and homogenizing, the homogenized grain diameter is below 1 μm, and the pressure of homogenizer is maintained at above 20 MPa;
2) preparing a sheath glue solution, pressing the filling and the sheath glue solution into gel candy, and drying to obtain the finished sandwich type gel candy.
The invention has the following beneficial effects:
1) the natural raw material dunaliella salina adopted by the invention replaces chemically synthesized beta-carotene to supplement vitamin A, natural carotenoids contained in the dunaliella salina not only comprise all-trans beta-carotene, but also 9 cis beta-carotene, in addition, alpha-carotene, lutein, zeaxanthin, gamma-carotene and the like, and new natural plant raw materials are provided for supplementing the vitamin A.
2) The invention avoids the risk of vitamin A over-supplement by using the dunaliella salina containing high beta-carotene to supplement the vitamin A.
3) The invention adopts the grease which is not easy to oxidize to prepare the sandwich by an emulsification technology, so that the beta-carotene and the vitamin D can form grease chylomicron, the absorption is more favorable, and the oxidation loss of the product in the long-term storage process is avoided.
4) The invention adopts low-temperature processing technology from the preparation of the sandwich to the pressing, thereby avoiding the loss of the beta-carotene and the vitamin D under the high-temperature processing condition.
5) The invention adopts the final product form of the gel candy, the outer skin effectively prevents the oxidation of the filling, protects the stability of beta-carotene and vitamin D, and the taste of the filling type gel candy is more popular than that of the common vitamin AD soft capsule and other dosage forms.
The specific implementation mode is as follows:
the following is a further description of the invention and is not intended to be limiting.
Example 1:
the pure plant source vitamin A vitamin D sandwich type gel candy comprises a sandwich and a rubber coating for wrapping the sandwich, wherein the sandwich comprises the following raw materials in percentage by weight of 100 percent: 60% of medium-chain triglyceride, 20% of mushroom powder, 5% of dunaliella salina, 3% of mono-diglycerol fatty acid ester, 3.8% of orange powder, 8% of xylitol and 0.2% of sucrose fatty acid ester.
The preparation method of the pure plant source vitamin A vitamin D sandwich type gel candy comprises the following steps:
1) preparing a sandwich: heating medium chain triglyceride to 70-75 deg.C, adding mono-diglycerol fatty acid ester, dissolving, cooling to 60-65 deg.C, adding orange powder and xylitol, stirring, cooling to 40-45 deg.C, adding Agaricus campestris powder and Dunaliella salina, stirring, homogenizing, and cooling to 30-35 deg.C.
2) Preparing a sheath glue solution, wherein the sheath glue solution comprises the following components: 29%, carrageenan 3%, glycerin 20%, water: 43 percent of xylitol, 5 percent of xylitol, and the preparation method comprises the following steps: premixing starch, carrageenan and xylitol, heating water to 90 deg.C, adding premixed starch, carrageenan and xylitol, stirring for dissolving for 90min, and vacuumizing to remove bubbles.
Pressing the sandwich and the sheath glue solution into gel candy, and drying to obtain the finished sandwich type gel candy.
Example 2:
the pure plant source vitamin A vitamin D sandwich type gel candy comprises a sandwich and a rubber coating for wrapping the sandwich, wherein the sandwich comprises the following raw materials in percentage by weight of 100 percent: 90% of low-oleic-acid sunflower seed oil, 1% of mushroom powder, 1% of dunaliella salina, 2% of mono-diglycerol fatty acid ester, 3% of xylitol and 3% of lemon powder.
The preparation process is referred to example 1.
Example 3:
the pure plant source vitamin A vitamin D sandwich type gel candy comprises a sandwich and a rubber coating for wrapping the sandwich, wherein the sandwich comprises the following raw materials in percentage by weight of 100 percent: 45% of low-oleic-acid sunflower seed oil, 15% of mushroom powder, 20% of dunaliella salina, 4% of beeswax, 4% of phospholipid, 4% of strawberry powder, 5% of erythritol and 3% of momordica grosvenori powder.
The preparation process is referred to example 1.
Example 4:
the pure plant source vitamin A vitamin D sandwich type gel candy comprises a sandwich and a rubber coating for wrapping the sandwich, wherein the sandwich comprises the following raw materials in percentage by weight of 100 percent: 70% of low-oleic-acid rapeseed oil, 5% of mushroom powder, 5% of dunaliella salina, 4% of beeswax, 5.98% of strawberry powder, 10% of maltitol and 0.02% of stevioside.
The preparation process is referred to example 1.
Example 5:
the pure plant source vitamin A vitamin D sandwich type gel candy comprises a sandwich and a rubber coating for wrapping the sandwich, wherein the sandwich comprises the following raw materials in percentage by weight of 100 percent: 48% of medium-chain triglyceride, 20% of mushroom powder, 20% of dunaliella salina, 1% of sucrose fatty acid ester, 4% of strawberry powder, 5% of maltitol and 2% of momordica grosvenori powder.
The preparation process is referred to example 1.
Comparative example 1:
the only difference between comparative example 1 and example 1 is that: medium chain triglycerides were replaced with soybean oil. The sandwich comprises the following raw materials in percentage by weight of 100 percent: 60% of soybean oil, 20% of mushroom powder, 5% of dunaliella salina, 3% of mono-diglycerol fatty acid ester, 3.8% of orange powder, 8% of xylitol and 0.2% of sucrose fatty acid ester.
Comparative example 2:
vitamin AD softgel (modified, 0.3 g/capsule) available on the general market
Vitamin a vitamin D sandwich type gel candies obtained in comparative example 1 and being of pure plant source were respectively put into an oven at 37 ℃, and the peroxide value, the content of beta-carotene and the content of vitamin D were measured every month.
Comparison of peroxide values (g/100g) between example 1 and comparative example 1
0 month 1 month 2 months old 3 months old
Example 1 0.05 0.08 0.1 0.12
Comparative example 1 0.06 0.23 0.58 1.15
Example 1 and comparative example 1 vitamin D comparison (IU/granule)
0 month 1 month 2 months old 3 months old
Example 1 200 198 195 195
Comparative example 1 200 190 170 148
Example 1 and comparative example 1 beta-Carotene comparison (μ g/granule)
0 month 1 month 2 months old 3 months old
Example 1 300 305 298 295
Comparative example 1 302 283 253 219
It can be seen from comparative example 1 and example 1 that the choice of fat has a great influence on the peroxide value of the final product and the attenuation of vitamin a and vitamin D.
The vitamin a vitamin D sandwich type gel candies obtained in comparative example 2 and examples 1 to 5 and derived from pure plants were evaluated for the degree of preference, and 30 individuals were randomly selected for evaluation, and the results were as follows:
example 1 Example 2 Example 3 Example 4 Example 5 Comparative example 2
Scoring 9.8 9.5 9 9.3 9.4 1.5
As can be seen from the scoring result, the commercially available vitamin A vitamin D soft capsules cannot meet the requirements of people on nutrition supplementation and taste sense enjoyment, and the novel product form not only supplements the nutrients, but also is delicious and tasty and is deeply liked by the raters.

Claims (5)

1. The pure plant source vitamin A vitamin D sandwich type gel candy is characterized by comprising a sandwich and a skin wrapping the sandwich, wherein the sandwich comprises the following raw materials in percentage by weight of 100 percent: 40% -95% of grease, mushroom powder: 1% -20%, dunaliella salina: 1% -20%, emulsifier: 1% -8%, and other auxiliary materials for blending the taste: 1% -20%; the grease is not easy to oxidize, and the peroxide value is less than or equal to 0.25g/100g after the grease is sealed and stored in an oven at 37 ℃ for 3 months; the content of the vitamin D in the mushroom powder is over 12000 IU/kg; the emulsifier comprises one or more of monoglyceride and diglyceride fatty acid ester, sucrose fatty acid ester, phospholipid and beeswax; the other auxiliary materials for blending the taste comprise a sweetening agent, an acidity regulator, fruit and vegetable powder and essence for food.
2. The vitamin A vitamin D sandwich type gel candy as claimed in claim 1, wherein the ingredients of the coating liquid are gelling agent, water-holding agent and others, the gelling agent comprises gelatin, carrageenan, starch, gellan gum and xanthan gum, the water-holding agent comprises glycerin, sugar alcohol, sugar, carboxymethyl cellulose, hydroxypropyl cellulose and microcrystalline cellulose, and the others comprise more than one of essence, pigment, sweetener, sour agent and fruit and vegetable juice.
3. The pure plant-derived vitamin A vitamin D sandwich type gel candy as claimed in claim 1, wherein the sandwich comprises the following raw materials by the total weight percentage of 100 percent: 45% -90% of grease, mushroom powder: 1% -20%, dunaliella salina: 1% -20%, emulsifier: 2% -6%, and other auxiliary materials for blending the taste: 1 to 20 percent.
4. The pure plant-derived vitamin A vitamin D center-filled gel confection of claim 1, wherein the sweetener comprises sugar, sugar alcohols, and other sweeteners.
5. The process of claim 2 wherein said pure plant-derived vitamin a vitamin D center-filled gel candy is prepared by the steps of:
1) preparing a sandwich: preparing powder materials, sieving the powder materials by a sieve of 80 meshes, drying the powder materials with the moisture content below 4 percent, and weighing the powder materials for later use; heating oil and fat to 70-75 deg.C, adding emulsifier, stirring, dissolving, cooling to 60-65 deg.C, adding other adjuvants, stirring, continuously cooling to 40-45 deg.C, adding mushroom powder and Dunaliella salina, stirring, emulsifying and homogenizing, the homogenized grain diameter is below 1 μm, and the pressure of homogenizer is maintained at above 20 MPa;
2) preparing a sheath glue solution, pressing the filling and the sheath glue solution into gel candy, and drying to obtain the finished sandwich type gel candy.
CN202010620066.6A 2020-06-30 2020-06-30 Pure plant-derived vitamin A and vitamin D sandwich type gel candy Pending CN111938007A (en)

Priority Applications (2)

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CN202010620066.6A CN111938007A (en) 2020-06-30 2020-06-30 Pure plant-derived vitamin A and vitamin D sandwich type gel candy
AU2021103596A AU2021103596A4 (en) 2020-06-30 2021-06-24 A pure plant source of vitamin a vitamin d sandwich gel candy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010620066.6A CN111938007A (en) 2020-06-30 2020-06-30 Pure plant-derived vitamin A and vitamin D sandwich type gel candy

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114886001A (en) * 2022-05-24 2022-08-12 佛山科学技术学院 Sandwich chocolate and preparation method thereof
CN115152881A (en) * 2022-07-11 2022-10-11 广州普正生物科技有限公司 Gel candy containing dextranase and preparation method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN109601678A (en) * 2019-01-10 2019-04-12 广州富诺健康科技股份有限公司 A kind of pure plant type calcium D gel candy and preparation method thereof
CN109619250A (en) * 2019-01-14 2019-04-16 广州富诺健康科技股份有限公司 A kind of natural plant gum integumentary pattern seawood meal gel candy
CN110973333A (en) * 2019-12-26 2020-04-10 宣城柏维力生物工程有限公司 Preparation method of seaweed milk calcium gel candy

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CN109601678A (en) * 2019-01-10 2019-04-12 广州富诺健康科技股份有限公司 A kind of pure plant type calcium D gel candy and preparation method thereof
CN109619250A (en) * 2019-01-14 2019-04-16 广州富诺健康科技股份有限公司 A kind of natural plant gum integumentary pattern seawood meal gel candy
CN110973333A (en) * 2019-12-26 2020-04-10 宣城柏维力生物工程有限公司 Preparation method of seaweed milk calcium gel candy

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114886001A (en) * 2022-05-24 2022-08-12 佛山科学技术学院 Sandwich chocolate and preparation method thereof
CN115152881A (en) * 2022-07-11 2022-10-11 广州普正生物科技有限公司 Gel candy containing dextranase and preparation method thereof
CN115152881B (en) * 2022-07-11 2024-02-02 广州普正生物科技有限公司 Gel candy containing dextranase and preparation method thereof

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Application publication date: 20201117