CN111909290A - Natural rubber latex coagulating additive - Google Patents

Natural rubber latex coagulating additive Download PDF

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Publication number
CN111909290A
CN111909290A CN202010874284.2A CN202010874284A CN111909290A CN 111909290 A CN111909290 A CN 111909290A CN 202010874284 A CN202010874284 A CN 202010874284A CN 111909290 A CN111909290 A CN 111909290A
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Prior art keywords
parts
additive
natural rubber
agent
ultraviolet
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Pending
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CN202010874284.2A
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Chinese (zh)
Inventor
吴胜文
张桂芬
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Individual
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Priority to CN202010874284.2A priority Critical patent/CN111909290A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C1/00Treatment of rubber latex
    • C08C1/14Coagulation
    • C08C1/15Coagulation characterised by the coagulants used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a natural rubber latex coagulating additive, which consists of sulfur, polymetallic organic siloxane, a bactericide, an anti-ultraviolet agent, fumed silica, nano kaolin powder, sodium carboxymethyl cellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil. The additive not only reduces the production cost, but also plays a role of rapid solidification (about 30 minutes), simultaneously greatly improves the quality of dry rubber, ensures thorough solidification, is more environment-friendly and meets the standard of products, and the bactericide, the ultraviolet-proof agent, the flame retardant and the plasticizer which are additionally added can effectively improve the bactericidal property, the ultraviolet-proof property, the flame retardance and the integral toughness of the natural rubber, thereby expanding the market competitiveness of the additive and meeting the self benefits of enterprises.

Description

Natural rubber latex coagulating additive
Technical Field
The invention relates to the technical field of additives, in particular to a natural rubber latex coagulating additive.
Background
The inside of the traditional industry is extracted the dry glue of gluing clear inside from water and rubber through adding sulphur now, dry glue content each ton rubber glues about 4% of the inside content, the cost of every extracting a ton of dry glue product and need adding sulphur is 4000 pieces of cost probably, and original technique has added the sulphur and has extracted the clear dry glue that can only extract the clear glue 10 more hours such as the clear dry glue of impurity glue that extracts white glue probably needs, the production efficiency is reduced, do not accord with the benefit of enterprise self, for this reason, we propose natural rubber latex coagulating additive.
Disclosure of Invention
The present invention has been made to solve the above problems occurring in the prior art, and an object of the present invention is to provide a natural rubber latex coagulant additive.
In order to achieve the purpose, the invention provides the following technical scheme: the natural rubber latex coagulating additive comprises sulfur, polymetallic organic siloxane, a bactericide, an anti-ultraviolet agent, fumed silica, nano kaolin powder, sodium carboxymethyl cellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil, and comprises the following components in parts by weight: 60-80 parts of sulfur; 5-10 parts of polymetallic organosiloxane; 7-12 parts of a bactericide; 7-12 parts of an ultraviolet-proof agent; 8-17 parts of fumed silica; 20-30 parts of nano kaolin powder; 10-15 parts of sodium carboxymethylcellulose; 6-10 parts of propyl palmitate; 5-10 parts of polyoxy alkylene ether; 15-25 parts of a flame retardant; 18-25 parts of calcium carbonate; 30-45 parts of silicon dioxide; 20-35 parts of a plasticizer; 50-80 parts of methyl ethyl silicone oil.
Preferably, the bactericide consists of 2-methyl propionate, sodium carbonate, kaempferol, ethyl acetate, organic acid, calcium hydroxide, piperine, dimethyl dicarbonate and an antifreezing agent, and the components in parts by weight are as follows: 8-15 parts of 2-methyl propionate; 3-8 parts of sodium carbonate; kaempferol 0.5-1.5 shares; 60-70 parts of ethyl acetate; 5-8 parts of organic acid; 8-15 parts of calcium hydroxide; 10-15 parts of piperine; 7-15 parts of dimethyl dicarbonate; 5-10 parts of an antifreezing agent.
Preferably, the ultraviolet-proof agent consists of silicon dioxide, nano zinc oxide, magnesium hydroxide, N-di-N-butyl nickel dithiocarbamate, guanidine antibacterial agent, epoxy resin, 8-hydroxyquinoline copper, dibutyl phthalate, aluminum zirconium acid ester coupling agent and silver powder, and the components in parts by weight are as follows: 40-60 parts of silicon dioxide; 3-7 parts of nano zinc oxide; 7-12 parts of magnesium hydroxide; 20-35 parts of nickel N, N-di-N-butyl dithiocarbamate; 4-10 parts of guanidine antibacterial agent; 3-8 parts of epoxy resin; 1-3 parts of 8-hydroxyquinoline copper; 8-15 parts of dibutyl phthalate; 5-12 parts of an aluminum zirconate coupling agent; 1-4 parts of silver powder.
Preferably, the flame retardant consists of guanyl urea phosphate, water-soluble ammonium polyphosphate, resorcinol bis (diphenyl phosphate), ammonium molybdate, borax, antimony trioxide, sodium pyrophosphate and diguanidine phosphate, and comprises the following components in parts by weight: 25-35 parts of guanylurea phosphate; 8-15 parts of water-soluble ammonium polyphosphate; 10-15 parts of resorcinol bis (diphenyl phosphate); 4-10 parts of ammonium molybdate; 25-40 parts of borax; 10-20 parts of antimony trioxide; 7-15 parts of sodium pyrophosphate; 3-11 parts of diguanidine phosphate.
Preferably, the plasticizer consists of citric acid high-carbon alcohol ester, dioctyl terephthalate, butanol, oxypropane-1, 2-diol, furan dicarboxylic acid compound, aromatic acid source, polyvinyl chloride, butadiene and sodium carbonate, and the components in parts by weight are as follows: 7-12 parts of citric acid higher alcohol ester; 5-10 parts of dioctyl terephthalate; 3-8 parts of butanol; 4-9 parts of oxypropane-1, 2-diol; 2-6 parts of furan dicarboxylic acid compound; 4-10 parts of an aromatic acid source; 8-15 parts of polyvinyl chloride; 6-12 parts of butadiene; 10-18 parts of sodium carbonate.
Compared with the prior art, the invention has the following beneficial effects:
the additive not only reduces the production cost, but also plays a role of rapid solidification (about 30 minutes), simultaneously greatly improves the quality of dry rubber, ensures thorough solidification, is more environment-friendly and meets the standard of products, and the bactericide, the ultraviolet-proof agent, the flame retardant and the plasticizer which are additionally added can effectively improve the bactericidal property, the ultraviolet-proof property, the flame retardance and the integral toughness of the natural rubber, thereby expanding the market competitiveness of the additive and meeting the self benefits of enterprises.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The natural rubber latex coagulating additive comprises sulfur, polymetallic organic siloxane, a bactericide, an anti-ultraviolet agent, fumed silica, nano kaolin powder, sodium carboxymethyl cellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil, and comprises the following components in parts by weight: 60-80 parts of sulfur; 5-10 parts of polymetallic organosiloxane; 7-12 parts of a bactericide; 7-12 parts of an ultraviolet-proof agent; 8-17 parts of fumed silica; 20-30 parts of nano kaolin powder; 10-15 parts of sodium carboxymethylcellulose; 6-10 parts of propyl palmitate; 5-10 parts of polyoxy alkylene ether; 15-25 parts of a flame retardant; 18-25 parts of calcium carbonate; 30-45 parts of silicon dioxide; 20-35 parts of a plasticizer; 50-80 parts of methyl ethyl silicone oil.
The additive not only reduces the production cost, but also plays a role of rapid solidification (about 30 minutes), simultaneously greatly improves the quality of dry rubber, ensures thorough solidification, is more environment-friendly and meets the standard of products, and the bactericide, the ultraviolet-proof agent, the flame retardant and the plasticizer which are additionally added can effectively improve the bactericidal property, the ultraviolet-proof property, the flame retardance and the integral toughness of the natural rubber, thereby expanding the market competitiveness of the additive and meeting the self benefits of enterprises.
The first embodiment is as follows:
the natural rubber latex coagulating additive comprises sulfur, polymetallic organic siloxane, a bactericide, an anti-ultraviolet agent, fumed silica, nano kaolin powder, sodium carboxymethyl cellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil, and comprises the following components in parts by weight: 60-80 parts of sulfur; 5-10 parts of polymetallic organosiloxane; 7-12 parts of a bactericide; 7-12 parts of an ultraviolet-proof agent; 8-17 parts of fumed silica; 20-30 parts of nano kaolin powder; 10-15 parts of sodium carboxymethylcellulose; 6-10 parts of propyl palmitate; 5-10 parts of polyoxy alkylene ether; 15-25 parts of a flame retardant; 18-25 parts of calcium carbonate; 30-45 parts of silicon dioxide; 20-35 parts of a plasticizer; 50-80 parts of methyl ethyl silicone oil, wherein the bactericide consists of 2-methyl propionate, sodium carbonate, kaempferol, ethyl acetate, organic acid, calcium hydroxide, piperine, dimethyl dicarbonate and an antifreezing agent, and the components in parts by weight are as follows: 8-15 parts of 2-methyl propionate; 3-8 parts of sodium carbonate; kaempferol 0.5-1.5 shares; 60-70 parts of ethyl acetate; 5-8 parts of organic acid; 8-15 parts of calcium hydroxide; 10-15 parts of piperine; 7-15 parts of dimethyl dicarbonate; 5-10 parts of an antifreezing agent.
Example two:
the natural rubber latex coagulating additive comprises sulfur, polymetallic organic siloxane, a bactericide, an anti-ultraviolet agent, fumed silica, nano kaolin powder, sodium carboxymethyl cellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil, and comprises the following components in parts by weight: 60-80 parts of sulfur; 5-10 parts of polymetallic organosiloxane; 7-12 parts of a bactericide; 7-12 parts of an ultraviolet-proof agent; 8-17 parts of fumed silica; 20-30 parts of nano kaolin powder; 10-15 parts of sodium carboxymethylcellulose; 6-10 parts of propyl palmitate; 5-10 parts of polyoxy alkylene ether; 15-25 parts of a flame retardant; 18-25 parts of calcium carbonate; 30-45 parts of silicon dioxide; 20-35 parts of a plasticizer; 50-80 parts of methyl ethyl silicone oil, wherein the ultraviolet-proof agent consists of silicon dioxide, nano zinc oxide, magnesium hydroxide, N-di-N-butyl nickel dithiocarbamate, guanidine antibacterial agent, epoxy resin, 8-hydroxyquinoline copper, dibutyl phthalate, aluminum zirconate coupling agent and silver powder, and the components in parts by weight are as follows: 40-60 parts of silicon dioxide; 3-7 parts of nano zinc oxide; 7-12 parts of magnesium hydroxide; 20-35 parts of nickel N, N-di-N-butyl dithiocarbamate; 4-10 parts of guanidine antibacterial agent; 3-8 parts of epoxy resin; 1-3 parts of 8-hydroxyquinoline copper; 8-15 parts of dibutyl phthalate; 5-12 parts of an aluminum zirconate coupling agent; 1-4 parts of silver powder.
Example three:
the natural rubber latex coagulating additive comprises sulfur, polymetallic organic siloxane, a bactericide, an anti-ultraviolet agent, fumed silica, nano kaolin powder, sodium carboxymethyl cellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil, and comprises the following components in parts by weight: 60-80 parts of sulfur; 5-10 parts of polymetallic organosiloxane; 7-12 parts of a bactericide; 7-12 parts of an ultraviolet-proof agent; 8-17 parts of fumed silica; 20-30 parts of nano kaolin powder; 10-15 parts of sodium carboxymethylcellulose; 6-10 parts of propyl palmitate; 5-10 parts of polyoxy alkylene ether; 15-25 parts of a flame retardant; 18-25 parts of calcium carbonate; 30-45 parts of silicon dioxide; 20-35 parts of a plasticizer; 50-80 parts of methyl ethyl silicone oil, wherein the flame retardant consists of guanyl urea phosphate, water-soluble ammonium polyphosphate, resorcinol bis (diphenyl phosphate), ammonium molybdate, borax, antimony trioxide, sodium pyrophosphate and diguanidine phosphate, and the flame retardant comprises the following components in parts by weight: 25-35 parts of guanylurea phosphate; 8-15 parts of water-soluble ammonium polyphosphate; 10-15 parts of resorcinol bis (diphenyl phosphate); 4-10 parts of ammonium molybdate; 25-40 parts of borax; 10-20 parts of antimony trioxide; 7-15 parts of sodium pyrophosphate; 3-11 parts of diguanidine phosphate.
Example four:
the natural rubber latex coagulating additive comprises sulfur, polymetallic organic siloxane, a bactericide, an anti-ultraviolet agent, fumed silica, nano kaolin powder, sodium carboxymethyl cellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil, and comprises the following components in parts by weight: 60-80 parts of sulfur; 5-10 parts of polymetallic organosiloxane; 7-12 parts of a bactericide; 7-12 parts of an ultraviolet-proof agent; 8-17 parts of fumed silica; 20-30 parts of nano kaolin powder; 10-15 parts of sodium carboxymethylcellulose; 6-10 parts of propyl palmitate; 5-10 parts of polyoxy alkylene ether; 15-25 parts of a flame retardant; 18-25 parts of calcium carbonate; 30-45 parts of silicon dioxide; 20-35 parts of a plasticizer; 50-80 parts of methyl ethyl silicone oil, wherein the plasticizer consists of citric acid high-carbon alcohol ester, dioctyl terephthalate, butanol, oxypropane-1, 2-diol, furan dicarboxylic acid compound, aromatic acid source, polyvinyl chloride, butadiene and sodium carbonate, and the components in parts by weight are as follows: 7-12 parts of citric acid higher alcohol ester; 5-10 parts of dioctyl terephthalate; 3-8 parts of butanol; 4-9 parts of oxypropane-1, 2-diol; 2-6 parts of furan dicarboxylic acid compound; 4-10 parts of an aromatic acid source; 8-15 parts of polyvinyl chloride; 6-12 parts of butadiene; 10-18 parts of sodium carbonate.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. The natural rubber latex coagulating additive is characterized in that: the additive comprises sulfur, polymetallic organic siloxane, a bactericide, an ultraviolet-proof agent, fumed silica, nano kaolin powder, sodium carboxymethylcellulose, propyl palmitate, polyoxy alkylene ether, a flame retardant, calcium carbonate, silicon dioxide, a plasticizer and methyl ethyl silicone oil, and comprises the following components in parts by weight: 60-80 parts of sulfur; 5-10 parts of polymetallic organosiloxane; 7-12 parts of a bactericide; 7-12 parts of an ultraviolet-proof agent; 8-17 parts of fumed silica; 20-30 parts of nano kaolin powder; 10-15 parts of sodium carboxymethylcellulose; 6-10 parts of propyl palmitate; 5-10 parts of polyoxy alkylene ether; 15-25 parts of a flame retardant; 18-25 parts of calcium carbonate; 30-45 parts of silicon dioxide; 20-35 parts of a plasticizer; 50-80 parts of methyl ethyl silicone oil.
2. The natural rubber latex coagulum additive of claim 1, wherein: the bactericide consists of 2-methyl propionate, sodium carbonate, kaempferol, ethyl acetate, organic acid, calcium hydroxide, piperine, dimethyl dicarbonate and an antifreezing agent, and comprises the following components in parts by weight: 8-15 parts of 2-methyl propionate; 3-8 parts of sodium carbonate; kaempferol 0.5-1.5 shares; 60-70 parts of ethyl acetate; 5-8 parts of organic acid; 8-15 parts of calcium hydroxide; 10-15 parts of piperine; 7-15 parts of dimethyl dicarbonate; 5-10 parts of an antifreezing agent.
3. The natural rubber latex coagulum additive of claim 1, wherein: the ultraviolet-proof agent consists of silicon dioxide, nano zinc oxide, magnesium hydroxide, N-di-N-butyl nickel dithiocarbamate, guanidine antibacterial agent, epoxy resin, 8-hydroxyquinoline copper, dibutyl phthalate, aluminum zirconium acid ester coupling agent and silver powder, and comprises the following components in parts by weight: 40-60 parts of silicon dioxide; 3-7 parts of nano zinc oxide; 7-12 parts of magnesium hydroxide; 20-35 parts of nickel N, N-di-N-butyl dithiocarbamate; 4-10 parts of guanidine antibacterial agent; 3-8 parts of epoxy resin; 1-3 parts of 8-hydroxyquinoline copper; 8-15 parts of dibutyl phthalate; 5-12 parts of an aluminum zirconate coupling agent; 1-4 parts of silver powder.
4. The natural rubber latex coagulum additive of claim 1, wherein: the flame retardant consists of guanyl urea phosphate, water-soluble ammonium polyphosphate, resorcinol bis (diphenyl phosphate), ammonium molybdate, borax, antimony trioxide, sodium pyrophosphate and diguanidine phosphate, and comprises the following components in parts by weight: 25-35 parts of guanylurea phosphate; 8-15 parts of water-soluble ammonium polyphosphate; 10-15 parts of resorcinol bis (diphenyl phosphate); 4-10 parts of ammonium molybdate; 25-40 parts of borax; 10-20 parts of antimony trioxide; 7-15 parts of sodium pyrophosphate; 3-11 parts of diguanidine phosphate.
5. The natural rubber latex coagulum additive of claim 1, wherein: the plasticizer consists of citric acid high-carbon alcohol ester, dioctyl terephthalate, butanol, oxypropane-1, 2-diol, furan dicarboxylic acid compound, aromatic acid source, polyvinyl chloride, butadiene and sodium carbonate, and comprises the following components in parts by weight: 7-12 parts of citric acid higher alcohol ester; 5-10 parts of dioctyl terephthalate; 3-8 parts of butanol; 4-9 parts of oxypropane-1, 2-diol; 2-6 parts of furan dicarboxylic acid compound; 4-10 parts of an aromatic acid source; 8-15 parts of polyvinyl chloride; 6-12 parts of butadiene; 10-18 parts of sodium carbonate.
CN202010874284.2A 2020-08-27 2020-08-27 Natural rubber latex coagulating additive Pending CN111909290A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023187357A1 (en) * 2022-03-28 2023-10-05 Codikoat Ltd Antimicrobial and/or antiviral materials
WO2024074830A1 (en) * 2022-10-05 2024-04-11 Codikoat Ltd Antimicrobial and/or antiviral materials

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1222528A (en) * 1998-11-18 1999-07-14 中国科学院昆明植物研究所 Biological solidification technology of natural latex
US6025451A (en) * 1997-06-23 2000-02-15 Sumitomo Rubber Industries, Ltd. Method of producing particulate natural rubber
JP2007002176A (en) * 2005-06-27 2007-01-11 Sumitomo Rubber Ind Ltd Rubber composition and method for producing the same
CN101323652A (en) * 2008-03-07 2008-12-17 上海生大医保股份有限公司 Preparing methods of polyisoprene emulsion and rubber thereof
US20100120956A1 (en) * 2007-05-22 2010-05-13 The Yokohama Rubber Co., Ltd. Method for Production of Natural Rubber
US20110021664A1 (en) * 2008-02-08 2011-01-27 Cabot Corporation Elastomer Composite and Method for Producing It
CN102585309A (en) * 2012-01-04 2012-07-18 北京化工大学 Method for preparing high-dispersion white carbon black/rubber nano composite material
US20160102193A1 (en) * 2014-10-08 2016-04-14 Sumitomo Rubber Industries, Ltd. Rubber composition for tires and pneumatic tire

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6025451A (en) * 1997-06-23 2000-02-15 Sumitomo Rubber Industries, Ltd. Method of producing particulate natural rubber
CN1222528A (en) * 1998-11-18 1999-07-14 中国科学院昆明植物研究所 Biological solidification technology of natural latex
JP2007002176A (en) * 2005-06-27 2007-01-11 Sumitomo Rubber Ind Ltd Rubber composition and method for producing the same
US20100120956A1 (en) * 2007-05-22 2010-05-13 The Yokohama Rubber Co., Ltd. Method for Production of Natural Rubber
US20110021664A1 (en) * 2008-02-08 2011-01-27 Cabot Corporation Elastomer Composite and Method for Producing It
CN101323652A (en) * 2008-03-07 2008-12-17 上海生大医保股份有限公司 Preparing methods of polyisoprene emulsion and rubber thereof
CN102585309A (en) * 2012-01-04 2012-07-18 北京化工大学 Method for preparing high-dispersion white carbon black/rubber nano composite material
US20160102193A1 (en) * 2014-10-08 2016-04-14 Sumitomo Rubber Industries, Ltd. Rubber composition for tires and pneumatic tire

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023187357A1 (en) * 2022-03-28 2023-10-05 Codikoat Ltd Antimicrobial and/or antiviral materials
WO2024074830A1 (en) * 2022-10-05 2024-04-11 Codikoat Ltd Antimicrobial and/or antiviral materials

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Application publication date: 20201110