CN111890501A - Wicker pretreatment method for wickerwork - Google Patents

Abstract

The invention discloses a wicker pretreatment method for wicker handicraft articles, which comprises the following steps: removing branches and leaves of willow rattans with bark, naturally drying the willow rattans, and placing the willow rattans in a reaction kettle to react with a soak solution; taking out the willow rattan with the skin from the reaction kettle, soaking in clear water, washing and drying; taking out willow rattan from a drying box, spirally winding a modified activated carbon fiber rope on the outer side of the willow rattan, then soaking the willow rattan in a carbonization solution, taking out the willow rattan, draining, placing the willow rattan in a microwave oven, and performing microwave treatment; taking out the willow rattan from the microwave oven, loosening the modified activated carbon fiber rope, soaking the willow rattan in clear water, washing, drying, and putting the willow rattan in a fumigation furnace for fumigation; taking out willow rattan from the fumigation furnace, washing with clear water, drying in a drying oven, taking out after drying, grinding and polishing the surface, and storing in a sealed manner in a roll. The wicker handicraft woven by the wicker after the treatment has the advantages of aromatic flavor, high strength, beautiful appearance and long service life.

Description

Wicker pretreatment method for wickerwork

Technical Field

The invention belongs to the technical field of wicker weaving processes, and particularly relates to a wicker pretreatment method for wicker crafts.

Background

Wickerwork is one of the traditional handicraft articles in China, and is only used as a common daily practical article in ancient times, and the wickerwork is gradually made up until decades after the 20 th century and also gradually becomes an export-earning project in parts of China. The wicker is soft and easy to bend, uniform in thickness and elegant in color, and various simple, natural, attractive in appearance, light and durable practical artworks can be woven through a novel design. The wicker products are handcrafts widely distributed among China, and due to wide raw material sources, the wicker products are abundant around the country, and the processing technology of the wicker products is stricter and stricter along with the increase of market demands.

The wicker handicraft has good ornamental value, such as a plurality of hanging baskets, lampshades, flower-inserting baskets, ornamental handicrafts and the like, forms a value-increasing effect that low-grade commodities are changed into high-grade commodities in foreign trade, and is popular among people. The color of the existing wicker handicraft is mostly obtained by paint, the uniformity is not strong, the ornamental value of the wicker handicraft is affected, and meanwhile, the wicker handicraft is difficult to form rich appearance lines.

Disclosure of Invention

The invention aims to overcome the defects of the prior art and provides a wicker pretreatment method for wicker handicraft articles.

The invention is realized by the following technical scheme:

a wicker pretreatment method for wicker handicraft articles is characterized by comprising the following steps: the method comprises the following steps:

1) removing branches and leaves of willow rattan with bark, naturally drying, placing in a reaction kettle, holding soak solution in the reaction kettle, heating the reaction kettle until the pressure of the reaction kettle reaches 0.6-0.8MPa, maintaining the pressure for 1-2h, naturally cooling to 70-80 ℃, then preserving heat for 10-30min, circularly treating for 3-5 times according to the steps of upper heating, pressure maintaining, natural cooling and heat preservation, and naturally cooling to room temperature;

2) taking out the willow rattan with bark from the reaction kettle, soaking and washing for 3-5 times, peeling the willow rattan with bark, placing the peeled willow rattan in a drying box, and drying at 60-80 ℃ until the water content is 10-15%;

3) taking out the willow rattan from the drying box, spirally winding the modified activated carbon fiber rope on the outer side of the willow rattan, then placing the willow rattan into a carbonization solution to be soaked for 2-3h, taking out the willow rattan to be drained, placing the willow rattan into a microwave oven, standing for 3-5s after microwave treatment for 3-5s with the microwave power of 800W and the microwave frequency of 3-6GHZ, standing for 3-5s after microwave treatment for 3-5s, and circularly treating for 3-4 h;

4) taking out the willow rattan from the microwave oven, loosening the modified activated carbon fiber rope, soaking and washing the willow rattan for 3-5 times by clear water, drying the willow rattan in a drying furnace until the water content is 10-13%, taking out the willow rattan, putting the willow rattan in a fumigation furnace for fumigation, burying the willow rattan in modified spice to enable the willow rattan to be positioned at the upper part of a modified spice layer, introducing 650 ℃ steam from the bottom of the modified spice, controlling the temperature at the bottom of the spice layer to be 350-450 ℃, spraying water on the upper part of the spice layer after the temperature at the upper part of the spice layer reaches 160-180 ℃, reducing the temperature at the upper part of the spice layer to 60-80 ℃, stopping spraying water, and fumigating for;

5) taking out willow rattan from the fumigation furnace, washing with clear water for 4-6 times, drying in a drying oven at 40-50 deg.C until the water content of willow rattan is reduced to 13-15%, taking out, grinding, polishing, rolling, sealing, and storing.

Preferably, in the step 1), the soak solution is prepared from ethanol, diethyl ether, acetone, zinc chloride and clear water, and is prepared according to the mass parts during preparation, wherein the ethanol is 6-8 parts, the diethyl ether is 6-8 parts, the acetone is 3-5 parts, the zinc chloride is 3-6 parts, and the clear water is 100 parts, and the ethanol, the diethyl ether, the acetone and the zinc chloride are mixed and stirred during preparation, are placed into a reaction kettle and are stirred, and then the clear water is poured into the reaction kettle and is stirred until the mixture is uniformly stirred.

Preferably, in the step 3), the carbonized solution is prepared from ethanol, toluene, phenol, phosphoric acid and clear water, and is prepared according to the mass parts during preparation, wherein 7-10 parts of ethanol, 3-5 parts of toluene, 3-6 parts of phenol, 20-30 parts of phosphoric acid and 100 parts of clear water are mixed and stirred during preparation, and then are put into a reaction kettle for stirring;

preferably, in the step 3), the method for modifying the modified activated carbon fiber rope comprises the following steps: 10-13 parts of sodium hydroxide solution, 10-13 parts of silicon dioxide and 10 parts of ethanol are mixed according to the mass ratio and react for 1-2 hours to obtain a mixed solution, the activated carbon fiber rope is added into a container containing acetone, ultrasonic oscillation is carried out for 30-50 minutes, the activated carbon fiber rope is taken out, sealed and kept stand for 12-15 hours, then ultrasonic cleaning is carried out for a plurality of times by deionized water until ions are removed, the activated carbon fiber rope is taken out, drying is carried out at the temperature of 60-70 ℃, the dried activated carbon fiber rope is soaked in the mixed solution for 3-5 minutes, the activated carbon fiber rope is taken out, drying is carried out for 1-2 hours at the temperature of 80-90 ℃, finally the activated carbon fiber rope is put into a sintering furnace, sintering is carried out for 1-2 hours at the temperature of 850-.

Preferably, in the step 4), the modified spice is prepared from 2-3 parts of mint leaves, 4-6 parts of bamboo bark powder, 3-7 parts of fresh pine needles, 1-2 parts of sweet osmanthus, 2-3 parts of orchid, 3-6 parts of rose, 6-10 parts of sandalwood powder, 10-12 parts of pine wood powder, 3-6 parts of ethanol, 2-4 parts of ether, 3-6 parts of acetone and 100 parts of clear water by mass;

the preparation process of the fumigation material comprises the following steps: weighing mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, rose, sandalwood powder, pine wood powder, ethanol, diethyl ether, acetone and clear water for later use, drying the mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder at the temperature of 50-60 ℃, crushing the dried mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder until the water content is 10-13%, adding the crushed mint leaves, the dried mint leaves, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder into a frying pan, frying the mixture at the temperature.

The working principle of the invention is as follows:

1) the willow rattan with bark reacts with the soak solution in the reaction kettle, the effective components of the soak solution are ethanol, ether, acetone and zinc chloride, the ethanol, ether and acetone have a dissolving effect, so that part of lignin in the willow rattan with bark is hydrolyzed to form micropores, the zinc chloride reacts with H ions and OH ions in the willow rattan with bark under the high-temperature and high-pressure state, so that the willow bark and the willow rattan are subjected to partial carbonization reaction, the surface of the willow rattan is reddish brown, and the willow bark plays a protection role, so that the toughness of the willow rattan is prevented from being influenced by excessive carbonization;

2) the modified activated carbon fiber rope is wound on the outer side of the willow rattan, after the willow rattan is soaked in a carbonization liquid, the carbonization liquid is soaked on the surface of the willow rattan and the modified activated carbon fiber rope, the main components of the carbonization liquid are ethanol, toluene, phenol and phosphoric acid, the ethanol, the toluene and the phenol have a dissolving effect, the phosphoric acid can capture H ions and OH ions on the surface of the willow rattan, only the modified activated carbon fiber rope can absorb microwaves of 3-6GHZ under the microwave state, so that the temperature of the modified activated carbon fiber rope is rapidly increased, the phosphoric acid on the modified activated carbon fiber rope and the surface of the willow rattan are subjected to a carbonization reaction under the high-temperature state, so that black spiral stripes are formed on the surface of the willow rattan, meanwhile, the carbonized part of the willow rattan can also absorb a small amount of microwaves, other parts on the surface of the willow ratt;

3) the activated carbon fiber rope is modified, so that the ignition point of the activated carbon fiber rope can be effectively improved, and the activated carbon fiber rope can be effectively prevented from burning during microwave heating;

4) in the fumigating process, organic matters in lemon, sandalwood leaves, bamboo chips, fresh pine needles, mint leaves, sweet osmanthus, roses, sandalwood chips and pine wood chips are dissolved by phenol, phosphoric acid, acetone, ethanol and hydrochloric acid to promote aromatic substances to be separated out, when high-temperature smoke is introduced into a fumigating material layer, the temperature is reduced, the smoke carries aromatic substances to contact with the willow rattan at the upper part, low-temperature fumigation and high-temperature fumigation are circularly carried out, during low-temperature fumigation, separating out part of aromatic substances and water, allowing the aromatic substances and water to enter the inner layer and black carbon layer on the surface of willow rattan, separating out water from the inner layer and black carbon layer on the surface of willow rattan during high temperature fumigation, while the aromatic substances stay in the inner layer of the willow rattan and the black carbon layer on the surface of the willow rattan, the water plays a role in carrying, the aromatic substances can be sealed, so that the knitted wicker storage basket can emit rich fragrance.

5) After polishing treatment, impurities attached to the surface layer of the willow rattan are removed, and the willow rattan is finally carbonized for multiple times, so that the whole willow rattan is dark reddish brown, and the upper part of the willow rattan is provided with black spiral stripes.

Compared with the prior art, the invention has the beneficial effects that:

1) through hydrolytic carbonization and microwave carbonization treatment, the carbon layer can adsorb organic aromatic substances, so that the formed wicker handicraft can emit rich fragrance without greatly influencing the strength of the wicker;

2) because the black spiral stripes are distributed on the surface of the willow rattan, the willow rattan is more beautiful in appearance, and the processed artware is more ornamental;

3) insect eggs and bacteria in the willow rattans can be killed through hydrolysis, carbonization and fumigation treatment, and the willow rattans handicraft is more favorably stored.

Detailed Description

A wicker pretreatment method for wicker handicraft articles is characterized by comprising the following steps: the method comprises the following steps:

1) removing branches and leaves of willow rattan with bark, naturally drying, placing in a reaction kettle, holding soak solution in the reaction kettle, heating the reaction kettle until the pressure of the reaction kettle reaches 0.6-0.8MPa, maintaining the pressure for 1-2h, naturally cooling to 70-80 ℃, then preserving heat for 10-30min, circularly treating for 3-5 times according to the steps of upper heating, pressure maintaining, natural cooling and heat preservation, and naturally cooling to room temperature;

2) taking out the willow rattan with bark from the reaction kettle, soaking and washing for 3-5 times, peeling the willow rattan with bark, placing the peeled willow rattan in a drying box, and drying at 60-80 ℃ until the water content is 10-15%;

3) taking out the willow rattan from the drying box, spirally winding the modified activated carbon fiber rope on the outer side of the willow rattan, then placing the willow rattan into a carbonization solution to be soaked for 2-3h, taking out the willow rattan to be drained, placing the willow rattan into a microwave oven, standing for 3-5s after microwave treatment for 3-5s with the microwave power of 800W and the microwave frequency of 3-6GHZ, standing for 3-5s after microwave treatment for 3-5s, and circularly treating for 3-4 h;

4) taking out the willow rattan from the microwave oven, loosening the modified activated carbon fiber rope, soaking and washing the willow rattan for 3-5 times by clear water, drying the willow rattan in a drying furnace until the water content is 10-13%, taking out the willow rattan, putting the willow rattan in a fumigation furnace for fumigation, burying the willow rattan in modified spice to enable the willow rattan to be positioned at the upper part of a modified spice layer, introducing 650 ℃ steam from the bottom of the modified spice, controlling the temperature at the bottom of the spice layer to be 350-450 ℃, spraying water on the upper part of the spice layer after the temperature at the upper part of the spice layer reaches 160-180 ℃, reducing the temperature at the upper part of the spice layer to 60-80 ℃, stopping spraying water, and fumigating for;

5) taking out willow rattan from the fumigation furnace, washing with clear water for 4-6 times, drying in a drying oven at 40-50 deg.C until the water content of willow rattan is reduced to 13-15%, taking out, grinding, polishing, rolling, sealing, and storing.

In the step 1), the soak solution is prepared from ethanol, diethyl ether, acetone, zinc chloride and clear water, and is prepared according to the mass parts during preparation, wherein the ethanol is 6-8 parts, the diethyl ether is 6-8 parts, the acetone is 3-5 parts, the zinc chloride is 3-6 parts, and the clear water is 100 parts.

In the step 3), the carbonized solution is prepared from ethanol, toluene, phenol, phosphoric acid and clear water, and is prepared according to the mass parts during preparation, wherein 7-10 parts of ethanol, 3-5 parts of toluene, 3-6 parts of phenol, 20-30 parts of phosphoric acid and 100 parts of clear water are mixed and stirred during preparation, and then are put into a reaction kettle for stirring;

in the step 3), the modification method of the modified activated carbon fiber rope comprises the following steps: 10-13 parts of sodium hydroxide solution, 10-13 parts of silicon dioxide and 10 parts of ethanol are mixed according to the mass ratio and react for 1-2 hours to obtain a mixed solution, the activated carbon fiber rope is added into a container containing acetone, ultrasonic oscillation is carried out for 30-50 minutes, the activated carbon fiber rope is taken out, sealed and kept stand for 12-15 hours, then ultrasonic cleaning is carried out for a plurality of times by deionized water until ions are removed, the activated carbon fiber rope is taken out, drying is carried out at the temperature of 60-70 ℃, the dried activated carbon fiber rope is soaked in the mixed solution for 3-5 minutes, the activated carbon fiber rope is taken out, drying is carried out for 1-2 hours at the temperature of 80-90 ℃, finally the activated carbon fiber rope is put into a sintering furnace, sintering is carried out for 1-2 hours at the temperature of 850-.

In the step 4), the modified spice is prepared from 2-3 parts of mint leaves, 4-6 parts of bamboo bark powder, 3-7 parts of fresh pine needles, 1-2 parts of sweet osmanthus, 2-3 parts of orchid, 3-6 parts of rose flowers, 6-10 parts of sandalwood powder, 10-12 parts of pine wood powder, 3-6 parts of ethanol, 2-4 parts of ether, 3-6 parts of acetone and 100 parts of clear water;

the preparation process of the fumigation material comprises the following steps: weighing mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, rose, sandalwood powder, pine wood powder, ethanol, diethyl ether, acetone and clear water for later use, drying the mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder at the temperature of 50-60 ℃, crushing the dried mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder until the water content is 10-13%, adding the crushed mint leaves, the dried mint leaves, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder into a frying pan, frying the mixture at the temperature.

Example 1

1) Removing branches and leaves of willow rattans with bark, naturally drying, placing in a reaction kettle, holding soak solution in the reaction kettle, heating the reaction kettle until the pressure of the reaction kettle reaches 0.6MPa, maintaining the pressure for 1h, naturally cooling to 70 ℃, preserving the temperature for 10min, circularly treating for 3 times according to the steps of upper heating, pressure maintaining, natural cooling and heat preserving, and naturally cooling to room temperature;

the soaking liquid is prepared from 6 parts by weight of ethanol, 6 parts by weight of diethyl ether, 3 parts by weight of acetone, 3 parts by weight of zinc chloride and 100 parts by weight of clear water, wherein the ethanol, the diethyl ether, the acetone and the zinc chloride are mixed and stirred in a reaction kettle, and then the clear water is poured into the reaction kettle and stirred until the mixture is uniformly stirred.

2) Taking out the willow rattan with the bark from the reaction kettle, soaking and washing the willow rattan with the bark for 3 times, peeling the willow rattan with the bark, placing the willow rattan with the peeled willow rattan into a drying box, and drying the willow rattan with the peeled willow rattan at the temperature of 60 ℃ until the water content is 10%;

3) taking out willow rattan from a drying box, spirally winding a modified activated carbon fiber rope on the outer side of the willow rattan, then placing the willow rattan into a carbonization solution for soaking for 2 hours, taking out the willow rattan for draining, placing the willow rattan into a microwave oven with the power of 600W and the microwave frequency of 3GHZ, standing for 3 seconds after microwave treatment for 3 seconds, and circularly treating for 3 hours;

the carbonization solution is prepared from 7 parts by weight of ethanol, 3 parts by weight of toluene, 3 parts by weight of phenol, 20 parts by weight of phosphoric acid and 100 parts by weight of clear water, and the carbonization solution is prepared by mixing and stirring the ethanol, the toluene, the phenol and the phosphoric acid and putting the mixture into a reaction kettle for stirring;

the modification method of the modified activated carbon fiber rope comprises the following steps: mixing 10 parts of sodium hydroxide solution, 10 parts of silicon dioxide and 10 parts of ethanol according to a mass ratio, reacting for 1 hour to obtain a mixed solution, adding the activated carbon fiber rope into a container filled with acetone, ultrasonically oscillating for 30 minutes, taking out, sealing and standing for 12 hours, ultrasonically cleaning for a plurality of times by using deionized water until ions are removed, clearing and transparent, taking out the activated carbon fiber rope, drying at the temperature of 60 ℃, soaking the dried activated carbon fiber rope in the mixed solution for 3 minutes, taking out the activated carbon fiber rope, drying at the temperature of 80 ℃ for 1 hour, finally putting the activated carbon fiber rope into a sintering furnace, sintering at the temperature of 850 ℃ for 1 hour, and introducing nitrogen for protection in the sintering process.

4) Taking out willow rattan from a microwave oven, loosening the modified activated carbon fiber rope, soaking and washing the willow rattan for 3 times in clear water, drying the willow rattan in a drying oven until the water content is 10%, taking out the willow rattan, putting the willow rattan into a fumigation oven for fumigation, burying the willow rattan in modified spice to enable the willow rattan to be positioned at the upper part of a modified spice layer, introducing 500 ℃ water vapor from the bottom of the modified spice, controlling the temperature of the bottom of the spice layer to be 350 ℃, spraying water on the upper part of the spice layer when the temperature of the upper part of the spice layer reaches 160 ℃, reducing the temperature of the upper part of the spice layer to 60;

the modified spice is prepared from mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, roses, sandalwood powder, pine needle powder, ethanol, ethyl ether, acetone and clear water, and is prepared according to the mass parts during preparation, wherein 2 parts of mint leaves, 4 parts of bamboo bark powder, 3 parts of fresh pine needles, 1 part of sweet osmanthus, 2 parts of orchid, 3 parts of roses, 6 parts of sandalwood powder, 10 parts of pine needle powder, 3 parts of ethanol, 2 parts of ethyl ether, 3 parts of acetone and 100 parts of clear water;

the preparation process of the fumigation material comprises the following steps: weighing mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, rose, sandalwood powder, pine wood powder, ethanol, diethyl ether, acetone and clear water for later use, drying the mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder at the temperature of 50 ℃, crushing the dried mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder until the water content is 10 percent, adding the crushed mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder into a frying pan.

5) Taking out willow rattan from the fumigation furnace, washing with clear water for 4 times, drying in a drying oven at 40 deg.C until the water content of willow rattan is reduced to 13%, taking out, grinding, polishing, and rolling, sealing and storing.

The willow rattan processed by the method is dark reddish brown, is bright in color and luster, has the bending resistance of 165N, is woven into an artwork, is sprayed with varnish on the surface of the willow woven artwork, can observe black spiral lines on the willow rattan, is attractive in appearance, and can give out heavy fragrance for a long time.

Example 2

1) Removing branches and leaves of willow rattans with bark, naturally drying, placing in a reaction kettle, holding soak solution in the reaction kettle, heating the reaction kettle until the pressure of the reaction kettle reaches 0.8MPa, maintaining the pressure for 2h, naturally cooling to 80 ℃, preserving the temperature for 30min, circularly treating for 5 times according to the steps of upper heating, pressure maintaining, natural cooling and heat preserving, and naturally cooling to room temperature;

the soaking liquid is prepared from 8 parts by weight of ethanol, 8 parts by weight of diethyl ether, 5 parts by weight of acetone, 6 parts by weight of zinc chloride and 100 parts by weight of clear water, wherein the ethanol, the diethyl ether, the acetone and the zinc chloride are mixed and stirred in a reaction kettle, and then the clear water is poured into the reaction kettle and stirred until the mixture is uniformly stirred.

2) Taking out the willow rattan with the bark from the reaction kettle, soaking and washing the willow rattan with the bark for 5 times, peeling the willow rattan with the bark, placing the willow rattan with the peeled willow rattan into a drying box, and drying the willow rattan with the peeled willow rattan at the temperature of 80 ℃ until the water content is 15%;

3) taking out willow rattan from a drying box, spirally winding a modified activated carbon fiber rope on the outer side of the willow rattan, then soaking the willow rattan in a carbonization solution for 3 hours, taking out the willow rattan, draining, placing the willow rattan in a microwave oven with the power of 800W and the microwave frequency of 6GHZ, standing for 5 seconds after microwave treatment for 5 seconds, and circularly treating for 4 hours;

the carbonization solution is prepared from 10 parts by weight of ethanol, 5 parts by weight of toluene, 6 parts by weight of phenol, 30 parts by weight of phosphoric acid and 100 parts by weight of clear water, and the carbonization solution is prepared by mixing and stirring the ethanol, the toluene, the phenol and the phosphoric acid and putting the mixture into a reaction kettle for stirring;

the modification method of the modified activated carbon fiber rope comprises the following steps: mixing 13 parts of sodium hydroxide solution, 13 parts of silicon dioxide and 10 parts of ethanol according to a mass ratio, reacting for 2 hours to obtain a mixed solution, adding the activated carbon fiber rope into a container filled with acetone, ultrasonically oscillating for 50 minutes, taking out, sealing and standing for 15 hours, ultrasonically cleaning for a plurality of times by using deionized water until ions are removed, clearing and transparent, taking out the activated carbon fiber rope, drying at 70 ℃, soaking the dried activated carbon fiber rope in the mixed solution for 5 minutes, taking out the activated carbon fiber rope, drying at 90 ℃ for 2 hours, finally putting the activated carbon fiber rope into a sintering furnace, sintering at 900 ℃ for 2 hours, and introducing nitrogen for protection in the sintering process.

4) Taking out the willow rattan from the microwave oven, loosening the modified activated carbon fiber rope, soaking and washing the willow rattan for 5 times in clear water, drying the willow rattan in a drying oven until the water content is 13%, taking out the willow rattan, putting the willow rattan in a fumigation oven for fumigation, burying the willow rattan in modified spice to enable the willow rattan to be positioned at the upper part of a modified spice layer, introducing 650 ℃ steam from the bottom of the modified spice, controlling the temperature of the bottom of the spice layer to be 450 ℃, spraying water on the upper part of the spice layer when the temperature of the upper part of the spice layer reaches 180 ℃, reducing the temperature of the upper part of the spice layer to 80 ℃;

the modified spice is prepared from mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, roses, sandalwood powder, pine needle powder, ethanol, ether, acetone and clear water, and is prepared according to the mass parts during preparation, wherein 3 parts of mint leaves, 6 parts of bamboo bark powder, 7 parts of fresh pine needles, 2 parts of sweet osmanthus, 3 parts of orchid, 6 parts of roses, 10 parts of sandalwood powder, 12 parts of pine needle powder, 6 parts of ethanol, 4 parts of ether, 6 parts of acetone and 100 parts of clear water are used as raw materials;

the preparation process of the fumigation material comprises the following steps: weighing mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, rose, sandalwood powder, pine wood powder, ethanol, diethyl ether, acetone and clear water for later use, drying the mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder at the temperature of 60 ℃, crushing the dried mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder until the water content is 13%, adding the crushed mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder into a frying pan, frying.

5) Taking out willow rattan from the fumigation furnace, washing with clear water for 6 times, drying in a drying oven at 50 deg.C until the water content of willow rattan is reduced to 15%, taking out, grinding, polishing, and rolling, sealing and storing.

The wicker treated by the method is dark reddish brown, is bright in color and luster, has the bending resistance of 159N, is woven into an artwork, is sprayed with varnish on the surface of the artwork, can observe black spiral lines on the wicker, is attractive in appearance, and can give off strong fragrance for a long time.

Example 3

1) Removing branches and leaves of willow rattans with bark, naturally drying, placing in a reaction kettle, holding soak solution in the reaction kettle, heating the reaction kettle until the pressure of the reaction kettle reaches 0.7MPa, maintaining the pressure for 1.5h, naturally cooling to 75 ℃, keeping the temperature for 20min, circularly treating for 4 times according to the steps of upper heating, pressure maintaining, natural cooling and heat preservation, and naturally cooling to room temperature;

the soaking liquid is prepared from 7 parts by weight of ethanol, 7 parts by weight of diethyl ether, 4 parts by weight of acetone, 5 parts by weight of zinc chloride and 100 parts by weight of clear water, wherein the ethanol, the diethyl ether, the acetone and the zinc chloride are mixed and stirred in a reaction kettle, and then the clear water is poured into the reaction kettle and stirred until the mixture is uniformly stirred.

2) Taking out the willow rattan with the bark from the reaction kettle, soaking and washing the willow rattan with the bark for 4 times, peeling the willow rattan with the bark, placing the willow rattan with the peeled willow rattan into a drying box, and drying the willow rattan with the peeled willow rattan at the temperature of 70 ℃ until the water content is 13%;

3) taking out willow rattan from a drying box, spirally winding a modified activated carbon fiber rope on the outer side of the willow rattan, then soaking the willow rattan in a carbonization solution for 2.5 hours, taking out the willow rattan, draining, placing the willow rattan in a microwave oven, standing for 4 seconds after microwave treatment for 4 seconds, and circularly treating for 3.5 hours;

the carbonization solution is prepared from 8.5 parts of ethanol, 4 parts of toluene, 4.5 parts of phenol, 25 parts of phosphoric acid and 100 parts of clear water by mass, and the ethanol, the toluene, the phenol and the phosphoric acid are mixed and stirred and are put into a reaction kettle for stirring;

the modification method of the modified activated carbon fiber rope comprises the following steps: mixing 11.5 parts of sodium hydroxide solution, 11.5 parts of silicon dioxide and 10 parts of ethanol according to a mass ratio, reacting for 1.5 hours to obtain a mixed solution, adding the activated carbon fiber rope into a container containing acetone, ultrasonically oscillating for 40min, taking out, sealing and standing for 13.5 hours, ultrasonically cleaning for several times by using deionized water until ions are removed, clearing and transparent, taking out the activated carbon fiber rope, drying at 65 ℃, soaking the dried activated carbon fiber rope in the mixed solution for 4min, taking out the activated carbon fiber rope, drying at 85 ℃ for 1.5 hours, finally putting into a sintering furnace, sintering at 875 ℃ for 1.5 hours, and introducing nitrogen for protection in the sintering process.

4) Taking out willow rattan from a microwave oven, loosening the modified activated carbon fiber rope, soaking and washing the willow rattan for 4 times in clear water, drying the willow rattan in a drying oven until the water content is 11.5%, taking out the willow rattan, putting the willow rattan in a fumigation oven for fumigation, burying the willow rattan in modified spice to enable the willow rattan to be positioned at the upper part of a modified spice layer, introducing 575 ℃ water vapor from the bottom of the modified spice, controlling the temperature of the bottom of the spice layer to be 400 ℃, spraying water on the upper part of the spice layer when the temperature of the upper part of the spice layer reaches 170 ℃, reducing the temperature of the upper part of the spice layer to 70 ℃, stopping;

the modified spice is prepared from mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, roses, sandalwood powder, pine needle powder, ethanol, ether, acetone and clear water, and is prepared according to the mass parts during preparation, wherein 2.5 parts of mint leaves, 5 parts of bamboo bark powder, 5 parts of fresh pine needles, 1.5 parts of sweet osmanthus, 2.5 parts of orchid, 4.5 parts of rose, 8 parts of sandalwood powder, 11 parts of pine needle powder, 4.5 parts of ethanol, 3 parts of ether, 4.6 parts of acetone and 100 parts of clear water;

the preparation process of the fumigation material comprises the following steps: weighing mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, rose, sandalwood powder, pine wood powder, ethanol, diethyl ether, acetone and clear water for later use, drying the mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder at the temperature of 55 ℃, crushing the dried mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder until the water content is 11.5 percent, adding the crushed mint leaves, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder into a frying pan, frying the mixture at the.

5) Taking out willow rattan from the fumigation furnace, washing with clear water for 5 times, drying in a drying oven at 45 deg.C until the water content of willow rattan is reduced to 14%, taking out, grinding, polishing, and rolling, sealing and storing.

The willow rattan processed by the method is dark reddish brown, is bright in color and luster, has the bending resistance of 145N, is woven into an artwork, is sprayed with varnish on the surface of the willow rattan artwork, can observe black spiral lines on the willow rattan, is attractive in appearance, and can give out heavy fragrance for a long time.

The technical solution of the present invention is only exemplary described, and it is obvious that the specific implementation of the present invention is not limited by the above-mentioned manner, and it is within the protection scope of the present invention as long as various insubstantial modifications are made by using the method concept and technical solution of the present invention, or the inventive concept and technical solution are directly applied to other occasions without modifications.

Claims (5)

1. A wicker pretreatment method for wicker handicraft articles is characterized by comprising the following steps: the method comprises the following steps:

1) removing branches and leaves of willow rattan with bark, naturally drying, placing in a reaction kettle, holding soak solution in the reaction kettle, heating the reaction kettle until the pressure of the reaction kettle reaches 0.6-0.8MPa, maintaining the pressure for 1-2h, naturally cooling to 70-80 ℃, then preserving heat for 10-30min, circularly treating for 3-5 times according to the steps of upper heating, pressure maintaining, natural cooling and heat preservation, and naturally cooling to room temperature;

2) taking out the willow rattan with bark from the reaction kettle, soaking and washing for 3-5 times, peeling the willow rattan with bark, placing the peeled willow rattan in a drying box, and drying at 60-80 ℃ until the water content is 10-15%;

3) taking out the willow rattan from the drying box, spirally winding the modified activated carbon fiber rope on the outer side of the willow rattan, then placing the willow rattan into a carbonization solution to be soaked for 2-3h, taking out the willow rattan to be drained, placing the willow rattan into a microwave oven, standing for 3-5s after microwave treatment for 3-5s with the microwave power of 800W and the microwave frequency of 3-6GHZ, standing for 3-5s after microwave treatment for 3-5s, and circularly treating for 3-4 h;

4) taking out the willow rattan from the microwave oven, loosening the modified activated carbon fiber rope, soaking and washing the willow rattan for 3-5 times by clear water, drying the willow rattan in a drying furnace until the water content is 10-13%, taking out the willow rattan, putting the willow rattan in a fumigation furnace for fumigation, burying the willow rattan in modified spice to enable the willow rattan to be positioned at the upper part of a modified spice layer, introducing 650 ℃ steam from the bottom of the modified spice, controlling the temperature at the bottom of the spice layer to be 350-450 ℃, spraying water on the upper part of the spice layer after the temperature at the upper part of the spice layer reaches 160-180 ℃, reducing the temperature at the upper part of the spice layer to 60-80 ℃, stopping spraying water, and fumigating for;

5) taking out willow rattan from the fumigation furnace, washing with clear water for 4-6 times, drying in a drying oven at 40-50 deg.C until the water content of willow rattan is reduced to 13-15%, taking out, grinding, polishing, rolling, sealing, and storing.

2. The wicker pretreatment method for wicker handicraft according to claim 1, wherein the method comprises the following steps: in the step 1), the soak solution is prepared from ethanol, diethyl ether, acetone, zinc chloride and clear water, and is prepared according to the mass parts during preparation, wherein the ethanol is 6-8 parts, the diethyl ether is 6-8 parts, the acetone is 3-5 parts, the zinc chloride is 3-6 parts, and the clear water is 100 parts.

3. The wicker pretreatment method for wicker handicraft according to claim 1, wherein the method comprises the following steps: in the step 3), the carbonized solution is prepared from ethanol, toluene, phenol, phosphoric acid and clear water, and is prepared according to the mass parts during preparation, wherein 7-10 parts of ethanol, 3-5 parts of toluene, 3-6 parts of phenol, 20-30 parts of phosphoric acid and 100 parts of clear water are mixed and stirred during preparation, and then are put into a reaction kettle for stirring;

4. the wicker pretreatment method for wicker handicraft according to claim 1, wherein the method comprises the following steps: in the step 3), the modification method of the modified activated carbon fiber rope comprises the following steps: 10-13 parts of sodium hydroxide solution, 10-13 parts of silicon dioxide and 10 parts of ethanol are mixed according to the mass ratio and react for 1-2 hours to obtain a mixed solution, the activated carbon fiber rope is added into a container containing acetone, ultrasonic oscillation is carried out for 30-50 minutes, the activated carbon fiber rope is taken out, sealed and kept stand for 12-15 hours, then ultrasonic cleaning is carried out for a plurality of times by deionized water until ions are removed, the activated carbon fiber rope is taken out, drying is carried out at the temperature of 60-70 ℃, the dried activated carbon fiber rope is soaked in the mixed solution for 3-5 minutes, the activated carbon fiber rope is taken out, drying is carried out for 1-2 hours at the temperature of 80-90 ℃, finally the activated carbon fiber rope is put into a sintering furnace, sintering is carried out for 1-2 hours at the temperature of 850-.

5. The wicker pretreatment method for wicker handicraft according to claim 1, wherein the method comprises the following steps: in the step 4), the modified spice is prepared from 2-3 parts of mint leaves, 4-6 parts of bamboo bark powder, 3-7 parts of fresh pine needles, 1-2 parts of sweet osmanthus, 2-3 parts of orchid, 3-6 parts of rose flowers, 6-10 parts of sandalwood powder, 10-12 parts of pine wood powder, 3-6 parts of ethanol, 2-4 parts of ether, 3-6 parts of acetone and 100 parts of clear water;

the preparation process of the fumigation material comprises the following steps: weighing mint leaves, bamboo bark powder, fresh pine needles, sweet osmanthus, orchid, rose, sandalwood powder, pine wood powder, ethanol, diethyl ether, acetone and clear water for later use, drying the mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder at the temperature of 50-60 ℃, crushing the dried mint leaves, the bamboo bark powder, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder until the water content is 10-13%, adding the crushed mint leaves, the dried mint leaves, the fresh pine needles, the sweet osmanthus, the orchid, the rose, the sandalwood powder and the pine wood powder into a frying pan, frying the mixture at the temperature.