CN111885909B - Pressing technology of golden finger and antenna - Google Patents

Pressing technology of golden finger and antenna Download PDF

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Publication number
CN111885909B
CN111885909B CN202010689279.4A CN202010689279A CN111885909B CN 111885909 B CN111885909 B CN 111885909B CN 202010689279 A CN202010689279 A CN 202010689279A CN 111885909 B CN111885909 B CN 111885909B
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antenna
weight
sensitive adhesive
pressure
parts
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CN111885909A (en
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谢涛
彭建
张尚高
朱宗玉
李书磊
詹亿元
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Dongguan Hua Precision Technology Co Ltd
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K13/00Apparatus or processes specially adapted for manufacturing or adjusting assemblages of electric components
    • H05K13/04Mounting of components, e.g. of leadless components
    • H05K13/046Surface mounting
    • H05K13/0469Surface mounting by applying a glue or viscous material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/12Supports; Mounting means
    • H01Q1/22Supports; Mounting means by structural association with other equipment or articles
    • H01Q1/24Supports; Mounting means by structural association with other equipment or articles with receiving set
    • H01Q1/241Supports; Mounting means by structural association with other equipment or articles with receiving set used in mobile communications, e.g. GSM
    • H01Q1/242Supports; Mounting means by structural association with other equipment or articles with receiving set used in mobile communications, e.g. GSM specially adapted for hand-held use
    • H01Q1/243Supports; Mounting means by structural association with other equipment or articles with receiving set used in mobile communications, e.g. GSM specially adapted for hand-held use with built-in antennas

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Computer Networks & Wireless Communication (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention relates to the technical field of mobile phone shell processing, in particular to a pressing process of a golden finger and an antenna, which comprises the following steps: the gold fingers and the antenna are respectively clamped by the jig, the mobile phone shell is placed below the jig, and then the gold fingers and the antenna are sequentially pressed on the mobile phone shell by the jig. The gold finger and the antenna are clamped by the same jig and are sequentially pressed on the shell of the mobile phone, so that the gold finger and the antenna can be attached by single-station operation, manpower and equipment are simplified, the production cost is reduced, the production efficiency is improved, and the industrial production is facilitated.

Description

Pressing technology of golden finger and antenna
Technical Field
The invention relates to the technical field of mobile phone shell processing, in particular to a pressing process of a golden finger and an antenna.
Background
With the continuous promotion of mobile phone manufacturing technology, the auxiliary material types that the cell-phone trade will laminate are more and more, and the subsides technical requirement is higher and higher. In the laminating process of the accessories of the existing mobile phone shell, the golden finger and the antenna are pressed together to separate two stations, and different jigs are needed to assist implementation, which means the increase of labor cost and equipment cost.
Disclosure of Invention
In order to overcome the defects and shortcomings in the prior art, the invention aims to provide a laminating process of a gold finger and an antenna operated in a single station.
The purpose of the invention is realized by the following technical scheme:
a pressing technology of a golden finger and an antenna comprises the following steps: the gold fingers and the antenna are respectively clamped by the jig, the mobile phone shell is placed below the jig, and then the gold fingers and the antenna are sequentially pressed on the mobile phone shell by the jig.
The gold finger and the antenna are clamped by the same jig and are sequentially pressed on the shell of the mobile phone, so that the gold finger and the antenna can be attached by single-station operation, manpower and equipment are simplified, the production cost is reduced, the production efficiency is improved, and the industrial production is facilitated. Further, the jig used in the present invention may be a mobile phone case processing apparatus described in CN 202388203U.
The antenna comprises an FPC mainboard and a pressure-sensitive adhesive layer arranged on the lower surface of the FPC mainboard, wherein the pressure-sensitive adhesive layer is prepared by the following method: mixing 20-30 parts by weight of acrylic prepolymer, 30-40 parts by weight of vulcanized nano styrene-butadiene rubber, 50-70 parts by weight of reactive diluent monomer and 1-3 parts by weight of photoinitiator, coating the mixture on the upper surface of a release film to a coating thickness of 10-30 mu m, carrying out UV curing to obtain a pressure-sensitive adhesive layer, and attaching the upper surface of the pressure-sensitive adhesive layer to the lower surface of an FPC (flexible printed circuit) main board to obtain the antenna.
There are three major requirements for pressure sensitive adhesive for FPC antennas: firstly, the FPC antenna needs to have higher bonding strength, so that the FPC antenna needs to be bonded after being bent under certain conditions, the pressure-sensitive adhesive can be subjected to larger rebound force, and the pressure-sensitive adhesive needs to have high bonding strength to prevent the pressure-sensitive adhesive from dislocating; secondly, the pressure-sensitive adhesive needs to have better toughness and higher elongation at break resistance due to the requirement of bending; third, a lower thickness is required, which is a development demand for electronic products to be light and thin. According to the invention, the vulcanized nano styrene-butadiene rubber is added into the pressure-sensitive adhesive component, and the unsaturated bond and the vulcanized grafted group of the vulcanized nano styrene-butadiene rubber can be crosslinked with the acrylic monomer, so that as an additional crosslinking prepolymer, the crosslinking can be developed from a body structure to a linear structure, and the toughness of the pressure-sensitive adhesive can be improved; in addition, the vulcanized nano styrene-butadiene rubber is used as an elastomer, so that the reinforcing and toughening effects can be improved, the nano styrene-butadiene rubber can be used as a pure rubber layer, a PET carrier layer is not required to be involved, and the thickness is favorably reduced; in addition, the proper amount of the vulcanized nano styrene butadiene rubber can obviously improve the adhesive property of the pressure-sensitive adhesive, so that the pressure-sensitive adhesive has higher peel strength.
Wherein each part by weight of the acrylic prepolymer is prepared by the following method: mixing 4-8 parts by weight of butyl acrylate, 3-5 parts by weight of methyl acrylate and 0.04-0.08 part by weight of dibenzoyl peroxide, heating to 63-73 ℃, reacting for 1-2h, then gradually dropwise adding 4-8 parts by weight of butyl acrylate, 3-5 parts by weight of methyl acrylate, 2-4 parts by weight of glycidyl methacrylate and 0.04-0.08 part by weight of dibenzoyl peroxide, continuing the dropwise adding process for 1.2-1.4h, and continuing to react for 1.5-2.5h to obtain the acrylic prepolymer.
According to the invention, butyl acrylate is used as a soft monomer, methyl acrylate is used as a hard monomer, the synthesized acrylic prepolymer can improve the adhesive property of the pressure-sensitive adhesive, glycidyl methacrylate is added as a functional monomer, and the flexibility of the pressure-sensitive adhesive can be further improved by adding an epoxy group; in addition, the step-by-step polymerization method ensures that the synthesized acrylic prepolymer is fully polymerized, and improves the cohesive energy and the adhesive property of the pressure-sensitive adhesive.
The vulcanized nano styrene-butadiene rubber is prepared by the following method: mixing the styrene-butadiene rubber emulsion and an irradiation agent according to the weight ratio of 10-20:1, then carrying out irradiation crosslinking for 14-16h under an electron beam of 10-20kGy, and carrying out vacuum spray drying to obtain the vulcanized nano styrene-butadiene rubber.
According to the invention, the irradiation crosslinking method is utilized to crosslink the irradiation agent and the butadiene styrene rubber molecules to form a net structure, and then the nanometer rubber which is not easy to adhere is prepared by vacuum spray drying, so that the dispersion of the nanometer rubber in the components of the pressure-sensitive adhesive is facilitated, and the adhesive property and the strength of the pressure-sensitive adhesive can be obviously improved. In addition, the nano rubber adopted by the invention is styrene butadiene rubber, is easier to obtain compared with other rubbers such as nitrile butadiene rubber, polybutadiene rubber and the like, and has better compatibility with an acrylic acid system; compared with inorganic nano powder, the nano powder is less prone to agglomeration, can well improve the toughness of the pressure-sensitive adhesive, and cannot reduce the viscosity of the pressure-sensitive adhesive.
Wherein the irradiation agent is at least one of n-butyl methacrylate, trimethylolpropane triacrylate and propane trimethacrylate. In the selected irradiation agent, n-butyl methacrylate, acrylic acid prepolymer and reactive diluent monomer have better compatibility, so that the surface is more favorably soaked, and the occurrence of agglomeration phenomenon is reduced; trimethylolpropane triacrylate and propane trimethanol triacrylate have more functional groups, so that the crosslinking speed can be accelerated, the network structure of rubber particles can be improved, and the anti-adhesion performance of the rubber particles can be improved. Preferably, the irradiation agent is composed of n-butyl methacrylate and propane trimethacrylate in a weight ratio of 1-2:1, so that the crosslinking efficiency is high, the multifunctional propane trimethacrylate can endow rubber particles with more unsaturated bonds, crosslinking of the nano rubber particles and an acrylic monomer is facilitated, the dispersibility and stability of the vulcanized nano styrene-butadiene rubber in the pressure-sensitive adhesive are improved, and the comprehensive performance of the pressure-sensitive adhesive is improved more remarkably.
Wherein the styrene-butadiene rubber emulsion is styrene-butadiene latex KSL341 produced in Korea brocade lake.
Wherein the reactive diluent monomer is at least one of butyl acrylate, isooctyl acrylate and propane trimethanol triacrylate. The suspension dispersibility of the vulcanized nano styrene-butadiene rubber and the viscosity of the pressure-sensitive adhesive can be improved by selecting a proper active diluent monomer, and further preferably, the active diluent monomer is composed of butyl acrylate, isooctyl acrylate and propane trimethacrylate according to the weight ratio of 1-2:1-2:1, the crosslinking structure of the pressure-sensitive adhesive can be improved by properly adding the propane trimethacrylate, and the crosslinking structure of the pressure-sensitive adhesive can be effectively improved by compounding the butyl acrylate and the isooctyl acrylate within a certain range.
The photoinitiator consists of UV1173 and UV184 according to the weight ratio of 4-5:1, so that the photocuring efficiency is improved, and the photocuring time is shortened.
Wherein the light energy of UV curing is 400-2The curing time is 1-3 min.
The invention has the beneficial effects that: the gold finger and the antenna are clamped by the same jig and are sequentially pressed on the shell of the mobile phone, so that the gold finger and the antenna can be attached by single-station operation, manpower and equipment are simplified, the production cost is reduced, the production efficiency is improved, and the industrial production is facilitated.
Detailed Description
The present invention will be further described with reference to the following examples for facilitating understanding of those skilled in the art, and the description of the embodiments is not intended to limit the present invention.
Example 1
A pressing technology of a golden finger and an antenna comprises the following steps: the gold fingers and the antenna are respectively clamped by the jig, the mobile phone shell is placed below the jig, and then the gold fingers and the antenna are sequentially pressed on the mobile phone shell by the jig.
The antenna comprises an FPC mainboard and a pressure-sensitive adhesive layer arranged on the lower surface of the FPC mainboard, wherein the pressure-sensitive adhesive layer is prepared by the following method: mixing 25 parts by weight of acrylic prepolymer, 35 parts by weight of vulcanized nano styrene-butadiene rubber, 60 parts by weight of reactive diluent monomer and 2 parts by weight of photoinitiator, coating the mixture on the upper surface of a release film to a coating thickness of 20 mu m, carrying out UV curing to obtain a pressure-sensitive adhesive layer, and attaching the upper surface of the pressure-sensitive adhesive layer to the lower surface of an FPC (flexible printed circuit) main board to obtain the antenna.
Wherein each part by weight of the acrylic prepolymer is prepared by the following method: mixing 6 parts by weight of butyl acrylate, 4 parts by weight of methyl acrylate and 0.06 part by weight of dibenzoyl peroxide, heating to 68 ℃, reacting for 1.5h, then gradually dropwise adding 6 parts by weight of butyl acrylate, 4 parts by weight of methyl acrylate, 3 parts by weight of glycidyl methacrylate and 0.06 part by weight of dibenzoyl peroxide, continuing the dropwise adding process for 1.3h, and continuing to react for 2h to obtain the acrylic prepolymer.
The vulcanized nano styrene-butadiene rubber is prepared by the following method: mixing the styrene-butadiene rubber emulsion and an irradiation agent according to the weight ratio of 15:1, then carrying out irradiation crosslinking for 15h under an electron beam of 15kGy, and carrying out vacuum spray drying to obtain the vulcanized nano styrene-butadiene rubber.
Wherein the irradiation agent consists of n-butyl methacrylate and propane trimethacrylate in a weight ratio of 1.5:1.
Wherein the styrene-butadiene rubber emulsion is styrene-butadiene latex KSL341 produced in Korea brocade lake.
The reactive diluent monomer consists of butyl acrylate, isooctyl acrylate and propane trimethacrylate in a weight ratio of 1.5:1.5: 1.
Wherein the photoinitiator consists of UV1173 and UV184 according to the weight ratio of 4.5: 1.
Wherein the irradiation energy of UV curing is 450mJ/cm2The curing time was 2 min.
Example 2
This example differs from example 1 in that:
the pressure-sensitive adhesive layer is prepared by the following method: mixing 20 parts by weight of acrylic prepolymer, 30 parts by weight of vulcanized nano styrene-butadiene rubber, 50 parts by weight of reactive diluent monomer and 1 part by weight of photoinitiator, coating the mixture on the upper surface of a release film to a coating thickness of 10 microns, carrying out UV curing to obtain a pressure-sensitive adhesive layer, and attaching the upper surface of the pressure-sensitive adhesive layer to the lower surface of an FPC (flexible printed circuit) main board to obtain the antenna.
Wherein each part by weight of the acrylic prepolymer is prepared by the following method: mixing 4 parts by weight of butyl acrylate, 3 parts by weight of methyl acrylate and 0.04 part by weight of dibenzoyl peroxide, heating to 63 ℃, reacting for 1h, then gradually dropwise adding 4 parts by weight of butyl acrylate, 3 parts by weight of methyl acrylate, 2 parts by weight of glycidyl methacrylate and 0.04 part by weight of dibenzoyl peroxide, continuing the dropwise adding process for 1.2h, and continuing to react for 1.5h to obtain the acrylic prepolymer.
The vulcanized nano styrene-butadiene rubber is prepared by the following method: mixing styrene-butadiene rubber emulsion and an irradiation agent according to the weight ratio of 10:1, then carrying out irradiation crosslinking for 14h under an electron beam of 10kGy, and carrying out vacuum spray drying to obtain the vulcanized nano styrene-butadiene rubber.
Wherein the irradiation agent consists of n-butyl methacrylate and propane trimethacrylate in a weight ratio of 1: 1.
Wherein the styrene-butadiene rubber emulsion is styrene-butadiene latex KSL341 produced in Korea brocade lake.
The reactive diluent monomer consists of butyl acrylate, isooctyl acrylate and propane trimethacrylate in a weight ratio of 1:1: 1.
Wherein the photoinitiator consists of UV1173 and UV184 according to the weight ratio of 4: 1.
Wherein the irradiation energy of UV curing is 400mJ/cm2The curing time was 1 min.
Example 3
This example differs from example 1 in that:
the pressure-sensitive adhesive layer is prepared by the following method: mixing 30 parts by weight of acrylic prepolymer, 40 parts by weight of vulcanized nano styrene-butadiene rubber, 70 parts by weight of reactive diluent monomer and 3 parts by weight of photoinitiator, coating the mixture on the upper surface of a release film to a coating thickness of 30 mu m, carrying out UV curing to obtain a pressure-sensitive adhesive layer, and attaching the upper surface of the pressure-sensitive adhesive layer to the lower surface of an FPC (flexible printed circuit) main board to obtain the antenna.
Wherein each part by weight of the acrylic prepolymer is prepared by the following method: mixing 8 parts by weight of butyl acrylate, 5 parts by weight of methyl acrylate and 0.08 part by weight of dibenzoyl peroxide, heating to 73 ℃, reacting for 2 hours, then gradually dropwise adding 8 parts by weight of butyl acrylate, 5 parts by weight of methyl acrylate, 4 parts by weight of glycidyl methacrylate and 0.08 part by weight of dibenzoyl peroxide, continuing the dropwise adding process for 1.4 hours, and continuing to react for 2.5 hours to obtain the acrylic prepolymer.
The vulcanized nano styrene-butadiene rubber is prepared by the following method: mixing the styrene-butadiene rubber emulsion and an irradiation agent according to the weight ratio of 20:1, then carrying out irradiation crosslinking for 16h under an electron beam of 20kGy, and carrying out vacuum spray drying to obtain the vulcanized nano styrene-butadiene rubber.
Wherein the irradiation agent is trimethylolpropane triacrylate.
Wherein the styrene-butadiene rubber emulsion is styrene-butadiene latex KSL341 produced in Korea brocade lake.
The reactive diluent monomer consists of butyl acrylate, isooctyl acrylate and propane trimethacrylate in a weight ratio of 2:2: 1.
Wherein the photoinitiator consists of UV1173 and UV184 according to the weight ratio of 5:1.
Wherein the irradiation energy of UV curing is 500mJ/cm2The curing time was 3 min.
Comparative example 1
This comparative example differs from example 1 in that:
the pressure-sensitive adhesive layer is prepared by the following method: mixing 25 parts by weight of acrylic prepolymer, 60 parts by weight of reactive diluent monomer and 2 parts by weight of photoinitiator, coating the mixture on the upper surface of a release film to a coating thickness of 20 microns, carrying out UV curing to obtain a pressure-sensitive adhesive layer, and attaching the upper surface of the pressure-sensitive adhesive layer to the lower surface of an FPC (flexible printed circuit) main board to obtain the antenna.
Comparative example 2
This comparative example differs from example 1 in that:
100nm nano calcium carbonate in equal weight portions is used to replace vulcanized nano styrene butadiene rubber.
Comparative example 3
This comparative example differs from example 1 in that:
the nanometer vulcanized butadiene-styrene rubber is replaced by VP-401 (vulcanized nanometer butadiene-acrylonitrile rubber) in equal weight parts.
The pressure-sensitive adhesive layers of example 1 and comparative examples 1 to 3 were respectively subjected to initial tack, 180 DEG peel strength and elongation at break in accordance with GB/T4852-2002, GB/T4851-2014 (vertical gauge steel), GB/T2792-2014 and GB/T7753-1987, and the results are shown in the following tables:
Figure BDA0002588722200000071
as can be seen from the comparison between the example 1 and the comparative example 1, after the vulcanized nano styrene butadiene rubber is added, the performances of the pressure-sensitive adhesive are obviously improved; as can be seen from the comparison of example 1, comparative example 1 and comparative example 2, the effect of the addition of nano calcium carbonate on the various properties of the pressure-sensitive adhesive is negative, and although some reports claim that the addition of nano inorganic substance can improve the viscosity of the pressure-sensitive adhesive, it is obviously not suitable for the ultra-thin pressure-sensitive adhesive layer of the present invention; it can be known from the comparison of example 1, comparative example 1 and comparative example 3 that the initial tack and peel strength of the pressure sensitive adhesive can be improved by the vulcanized nano nitrile rubber, but the compatibility of the vulcanized nano nitrile rubber in an acrylic system is poor due to the high polarity of the vulcanized nano nitrile rubber, so that the expression of cohesive energy (permanent tack) and elongation at break is obviously reduced.
The above-described embodiments are preferred implementations of the present invention, and the present invention may be implemented in other ways without departing from the spirit of the present invention.

Claims (6)

1. A pressing technology of a golden finger and an antenna is characterized in that: the method comprises the following steps: respectively clamping the golden finger and the antenna by using a jig, placing the mobile phone shell below the jig, and then sequentially pressing the golden finger and the antenna on the mobile phone shell by using the jig;
the antenna comprises an FPC mainboard and a pressure-sensitive adhesive layer arranged on the lower surface of the FPC mainboard, wherein the pressure-sensitive adhesive layer is prepared by the following method: mixing 20-30 parts by weight of acrylic prepolymer, 30-40 parts by weight of vulcanized nano styrene-butadiene rubber, 50-70 parts by weight of reactive diluent monomer and 1-3 parts by weight of photoinitiator, coating the mixture on the upper surface of a release film to a coating thickness of 10-30 mu m, carrying out UV curing to obtain a pressure-sensitive adhesive layer, and attaching the upper surface of the pressure-sensitive adhesive layer to the lower surface of an FPC (flexible printed circuit) main board to obtain the antenna;
the vulcanized nano styrene butadiene rubber is prepared by the following method: mixing the styrene-butadiene rubber emulsion and an irradiation agent according to the weight ratio of 10-20:1, then carrying out irradiation crosslinking for 14-16h under an electron beam of 10-20kGy, and carrying out vacuum spray drying to obtain the vulcanized nano styrene-butadiene rubber.
2. The process of claim 1, wherein the step of laminating the gold finger and the antenna comprises the steps of: the irradiation agent is at least one of n-butyl methacrylate, trimethylolpropane triacrylate and propane trimethacrylate.
3. The process of claim 2, wherein the step of laminating the gold finger and the antenna comprises the steps of: the irradiation agent consists of n-butyl methacrylate and propane trimethacrylate in the weight ratio of 1-2: 1.
4. The process of claim 1, wherein the step of laminating the gold finger and the antenna comprises the steps of: the reactive diluent monomer is at least one of butyl acrylate, isooctyl acrylate and propane trimethanol triacrylate.
5. The process of claim 1, wherein the step of laminating the gold finger and the antenna comprises the steps of: the photoinitiator consists of UV1173 and UV184 according to the weight ratio of 4-5: 1.
6. The process of claim 1, wherein the step of laminating the gold finger and the antenna comprises the steps of: the light irradiation energy of the UV curing is 400-500mJ/cm2, and the curing time is 1-3 min.
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Citations (2)

* Cited by examiner, † Cited by third party
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CN106634697A (en) * 2016-12-27 2017-05-10 苏州市新广益电子有限公司 Heat-resistant pressure-sensitive adhesive
CN107300792A (en) * 2017-07-24 2017-10-27 武汉华星光电技术有限公司 Surface mount method

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CN203607534U (en) * 2013-07-09 2014-05-21 深圳市方格精密器件有限公司 Shell-stuck type flexible printed circuit (FPC) machining equipment
CN106867435B (en) * 2015-12-11 2019-03-08 华烁科技股份有限公司 A kind of flexible printed circuit polyimides stiffening plate modified acrylic ester adhesion agent and its application
CN108492976B (en) * 2018-03-13 2021-05-07 上海威斯科电子材料有限公司 Coil structure and preparation method of composite coil structure
CN109233664A (en) * 2018-06-12 2019-01-18 哈尔滨工业大学无锡新材料研究院 A kind of UV curing type adhesive, preparation method and application
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Publication number Priority date Publication date Assignee Title
CN106634697A (en) * 2016-12-27 2017-05-10 苏州市新广益电子有限公司 Heat-resistant pressure-sensitive adhesive
CN107300792A (en) * 2017-07-24 2017-10-27 武汉华星光电技术有限公司 Surface mount method

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