CN111793987B - Processing technology for improving non-ironing property of linen fabric - Google Patents

Processing technology for improving non-ironing property of linen fabric Download PDF

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CN111793987B
CN111793987B CN202010751291.3A CN202010751291A CN111793987B CN 111793987 B CN111793987 B CN 111793987B CN 202010751291 A CN202010751291 A CN 202010751291A CN 111793987 B CN111793987 B CN 111793987B
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fabric
linen
washing
ironing
processing technology
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CN111793987A (en
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齐元章
宋琳
张艳
张战旗
许秋生
王桂艳
杨玲玲
李文斌
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Lufeng Weaving and Dyeing Co Ltd
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Lufeng Weaving and Dyeing Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61Polyamines polyimines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention belongs to the technical field of textile printing and dyeing, and particularly relates to a processing technology for improving the non-ironing property of linen fabric. The warp and weft yarns are all linen yarns, and the linen gray fabric is singed → desized → specially bleached → wet cloth dried → liquid ammonia → whitening washing → super soft → damp cross-linking washing → stentering. The production method has continuity, the continuous production of large goods can be realized, the super-soft fabric adopts three auxiliaries to be cooperatively matched for use, the water absorption performance and the hand feeling of the fabric can be improved, the liquid carrying rate of the linen fabric to moisture cross-linked resin is increased, the bending degree of the fabric is increased by combining the characteristics of the super-soft process, and the non-ironing property of the fabric reaches 3.2 grade after the fabric is subjected to resin finishing. According to the invention, two softeners which greatly improve the hand feeling of the linen fabric are selected for tentering and compounded, and the formaldehyde content of the fabric is less than or equal to 20ppm by matching with the formaldehyde catching agent, so that the fabric is softer in hand feeling and comfortable to wear, the hand feeling of the fabric is improved, and the fabric is healthy and environment-friendly.

Description

Processing technology for improving non-ironing property of linen fabric
Technical Field
The invention belongs to the technical field of textile printing and dyeing, and particularly relates to a processing technology for improving the non-ironing property of linen fabric.
Background
The flax is also called as yamamai and flax, is divided into three types of fiber and oil, and is an annual herbaceous plant. The clothing is one of the main fiber raw materials of the clothing in spring and summer due to good moisture absorption, fast moisture conduction and relatively thin diameter. In general, a cloth woven from flax fibers is referred to as a flax fabric.
The linen fabric has natural air permeability, hygroscopicity, freshness, antibacterial property and other properties, and is popular with consumers all the time, but the linen is natural fiber, and the material has high toughness but no elasticity. Other fabrics can slowly recover to the original shape after being deformed, but flax cannot do the deformation, and only wrinkles once being deformed, so that the wearing performance of the fabric is seriously influenced by the characteristic.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the processing technology for improving the non-ironing property of the linen fabric overcomes the defects of the prior art, can realize the non-ironing property of the linen fabric of 3.2 grade, has the formaldehyde content of less than or equal to 20ppm, improves the wearability and the added value of the linen fabric by combining the natural performances of ventilation, antibiosis and the like of the linen fabric, has low formaldehyde content of the linen fabric, and realizes the green and environment-friendly performance of the linen fabric.
According to the processing technology for improving the non-ironing property of the linen fabric, the warps and the wefts are made of linen yarns, and the linen grey fabric is subjected to singeing → desizing → extra bleaching → wet cloth drying → liquid ammonia → whitening washing → ultra-soft → damp cross-linking washing → tentering to obtain the linen fabric.
In the feed liquid used in the ultra-soft process: fatty acid hydrophilic reactivator QQ-N (Kekai Fine chemical Co., ltd.): 3-6 g/L, heat reactive polyurethane softener RPU (On high chemical Co., ltd.): 20-30 g/L, polyamino hydroxyl derivative humectant PN94 (Jodany Post chemical Co., ltd.): 1-3 g/L.
QQ-N is a fatty acid hydrophilic revivifier, so that the water absorption performance of the fabric can be improved; the RPU is thermal reactive polyurethane, so that the hand feeling of the fabric is improved, and the wrinkle recovery angle and the washing and wearing effect of the fabric are improved by matching with a cross-linking agent; PN94 is a humectant of a polyamino hydroxyl derivative, can improve the liquid carrying rate of the linen fabric to resin, three auxiliaries are cooperatively used, can improve the water absorption performance and hand feeling of the fabric, increase the liquid carrying rate of the linen fabric to moisture crosslinking resin, combine the characteristics of an ultra-soft process, increase the bending degree of the fabric, provide a foundation for the subsequent moisture crosslinking process using large overfeeding, improve the warp elasticity of the fabric, and lay a solid foundation for improving the non-ironing performance of the fabric.
The super-soft process comprises the following steps: vehicle speed: 15-25 m/min, temperature: 110-130 ℃, main fan air volume: 70-80%, lower fan air volume: 45-55%, air exhaust volume: 70 to 80 percent.
In the feed liquid used in the damp crosslinking procedure: resin auxiliary AMC (BASF CHEMICAL CO., LTD): 100 to 140g/L, resin catalyst LRMC (Pasf chemical Co., ltd.): 50-70 g/L, fiber protective agent ACN (Hensman textile dyeing company): 20-30 g/L of hydrophilic linear co-polymer silicone oil TF-4911 (Zhejiang chemical Co., ltd.): 1-3 g/L, 1-3 g/L of penetrant SN-10 (Zhejiang Rihua chemical Co., ltd.).
The moisture crosslinking procedure comprises the following steps: on a tenter, speed: 30-40 m/min, drying room air volume: 45-55%, air quantity under the drying room is 35-45%, overfeeding: 4-7%, drying room temperature (8 groups/DEG C): 60/60/70/70/80/80/85/85, cropping humidity: 16-20 percent, and the cropping temperature is controlled between 30-35 ℃.
The invention selects the damp cross-linking resin auxiliary AMC of the modified dihydroxymethyl dihydroxy ethylene urea to improve the non-ironing performance of the linen fabric and has smaller strength reduction; the fiber protective agent is polyethylene ACN, and compared with the common polyethylene wax fiber protective agent, the fabric has good moisture absorption performance and hand feeling and the strength of the fabric is improved; TF-4911 is selected as hydrophilic linear co-polysilicone oil, the hydrophilic linear co-polysilicone oil is used in a moisture crosslinking solution, the tearing strength of the linen fabric can be improved, the moisture content of the linen fabric is improved by adjusting the air quantity of a drying room and the temperature of the drying room, overfeeding is adjusted, and the warp elasticity of the fabric is improved by using large overfeeding, so that the non-ironing property of the fabric is improved.
And (3) after moisture crosslinking and water washing, processing and tentering, wherein in feed liquid used in the tentering process: the multi-component copolymerization block organosilicon emulsion softener TF-4865C (Zhejiang department of agriculture, inc.): 3-6 g/L, novel multicomponent copolymerized silicone oil softening agent DT-5288 (Federal science and speciality chemical Co., ltd.): 3 to 6g/L, a formaldehyde scavenger FDS (Lurui Fine chemical Co., ltd.): 20-30 g/L, penetrant MRZ (On high chemical Co., ltd.): 2-5 g/L.
The tentering step: temperature of the drying room: 120-140 ℃, vehicle speed: 60-80 m/min.
The formaldehyde scavenger FDS is selected to ensure that the formaldehyde content of the fabric is less than or equal to 20ppm, and the fabric is green and environment-friendly; experiments show that the TF-4865C softener and the DT-5288 softener have a great improvement effect on the hand feeling of the linen fabric, and the hand feeling of the fabric is softer by compounding the two softeners, so that the fabric is comfortable to wear, the hand feeling of the fabric is improved, and the formaldehyde content of the fabric is reduced.
The invention adopts the conventional processes and conditions in the field for singeing, desizing, extra bleaching, wet cloth drying, liquid ammonia, whitening and washing and moisture crosslinking and washing.
Compared with the prior art, the invention has the following beneficial effects:
1) The production mode of the invention has continuity and can realize continuous production of large goods.
2) After the fabric is subjected to resin finishing, the non-ironing property of the fabric reaches 3.2 grade, and the washing and wearing performance of the fabric is improved.
3) After the fabric is treated, the content of formaldehyde is less than or equal to 20ppm, and the fabric is healthy and environment-friendly.
4) According to the invention, two softeners which greatly improve the hand feeling of the linen fabric are selected for combination in tentering, so that the hand feeling and the roughness of the linen fabric are improved, and the wearing comfort of the linen fabric is improved.
5) The finished fabric has the following indexes after testing:
(1) breaking strength: ASTM D5034-2009 test method, warp direction: 30Lb, weft: 30Lb;
(2) tearing strength: ASTM D1424-2009 test method, by: 1.6Lb, weft: 1.6Lb;
(3) after washing, the appearance (non-ironing), AATCC 124-2010,5 times of washing, drying test method, grade 3.2;
(4) water absorption, AATCC 79-2014 test method, 10S before washing and 15S after washing.
(5) The formaldehyde content is less than or equal to 20ppm according to a JIS L1041:2011/8.1.4B test method.
Detailed Description
The present invention will be further described with reference to the following examples.
All the raw materials used in the examples are commercially available unless otherwise specified.
Example 1
The linen fabric non-ironing property improving processing technology comprises the following steps: l21 x 65 x 60 x 57/58, tissue: plain weaving;
singeing flax yarns in the warp and weft directions → desizing → special bleaching → wet cloth drying → liquid ammonia → whitening washing → super softness → tide crosslinking water washing → tentering to obtain 100% flax fabric with the non-ironing property reaching 3.2 grade, comprising the following steps:
1) The fabric is super-soft after singeing → desizing → extra bleaching → wet cloth drying → liquid ammonia → whitening and washing;
2) Super-soft: fatty acid hydrophilic reactivator QQ-N (Kekai Fine chemical Co., ltd.): 5g/L, thermal reactive polyurethane softener RPU (Onha chemical Co., ltd.): 30g/L, polyamino hydroxy derivative humectant PN94 (Jodany Post chemical Co., ltd.): 2g/L, vehicle speed: 20m/min, temperature: 120 ℃, main fan air volume: 75%, lower fan air volume: 50% of air exhaust volume: 75 percent.
3) Moisture crosslinking: resin auxiliary AMC (BASF chemical Co., ltd.): 140g/L, resin catalyst LRMC (Passion chemical Co., ltd.): 70g/L, fiber protectant ACN (Hounsfield textile dyeing Co.): 30g/L of hydrophilic linear co-polymer silicone oil TF-4911 (Zhejiang chemical Co., ltd.): 2g/L, and 3g/L of penetrant SN-10 (Zhejiang Rihua chemical Co., ltd.). Vehicle speed: 35m/min, drying room air volume: 50%, the air quantity below the drying room is 40%, and the temperature of the drying room (8 groups/DEG C): 60/60/70/70/80/80/85/85, cropping humidity: 16-20%, overfeeding 6%, and cropping temperature: 35 ℃ is carried out.
4) After the fabric is subjected to damp crosslinking and water washing, stentering is carried out
5) Tentering: the multi-component copolymerization block organosilicon emulsion softener TF-4865C (Zhejiang department of agriculture, inc.): 5g/L, novel multipolymer silicone oil softening agent DT-5288 (Federal science speciality chemical Co., ltd.): 5g/L, formaldehyde scavenger FDS (Lurui Fine chemical Co., ltd.): 30g/L, penetrant MRZ (On high chemical Co., ltd.): 3g/L. Temperature of the drying room: 130 ℃, vehicle speed: 70m/min, drying room air quantity: 60%, air volume under the drying room: 50 percent.
The finished fabric is tested to have the following indexes:
(1) breaking strength: ASTM D5034-2009 test method, warp direction: 64Lb, weft: 42Lb;
(2) tearing strength: ASTM D1424-2009 test method, by: 5.1Lb, weft: 3.6Lb;
(3) after washing, the appearance (non-ironing), AATCC 124-2010,5 times of washing, drying test method, grade 3.2;
(4) water absorption, AATCC 79-2014 test method, 7S before washing, and 10S after washing.
(5) The formaldehyde content is less than or equal to 12ppm by a JIS L1041:2011/8.1.4B test method.
Example 2
The linen fabric non-ironing property improving processing technology comprises the following steps: l21 × L17 × 60 × 54 × 57/58, tissue: plain weaving;
singeing flax yarns in the warp and weft directions → desizing → special bleaching → wet cloth drying → liquid ammonia → whitening washing → super softness → tide crosslinking water washing → tentering to obtain 100% flax fabric with the non-ironing property reaching 3.2 grade, comprising the following steps:
1) The fabric is super-soft after singeing → desizing → extra bleaching → wet cloth drying → liquid ammonia → whitening and washing;
2) Super-soft: fatty acid hydrophilic reactivator QQ-N (Kekai Fine chemical Co., ltd.): 5g/L, thermal reactive polyurethane softener RPU (Onha chemical Co., ltd.): 20g/L, polyamino hydroxy derivative humectant PN94 (Jordan Bose Technida Co., ltd.): 3g/L, vehicle speed: 20m/min, temperature: 120 ℃, main blower air volume: 75%, lower fan air volume: 50% of air exhaust volume: and 75 percent.
3) Moisture crosslinking: resin auxiliary AMC (BASF CHEMICAL CO., LTD): 140g/L, resin catalyst LRMC (Passion chemical Co., ltd.): 70g/L, fiber protectant ACN (Hensmei textile dyeing Co.): 30g/L of hydrophilic linear co-polymer silicone oil TF-4911 (Zhejiang chemical Co., ltd.): 3g/L, 3g/L of penetrant SN-10 (Zhejiang Rihua chemical Co., ltd.). Vehicle speed: 35m/min, drying room air volume: 50%, the air quantity below the drying room is 40%, and the temperature of the drying room (8 groups/DEG C): 60/60/70/70/80/80/85/85, falling cloth humidity: 16-20%, overfeeding 6%, and cropping temperature: 35 ℃ is carried out.
4) After the fabric is subjected to damp crosslinking and water washing, stentering is carried out
5) Tentering: multicomponent copolymerization block organosilicon emulsion softener TF-4865C (Zhejiang chemical Co., ltd.): 6g/L, novel multipolymer silicone oil softening agent DT-5288 (Federal science speciality chemical Co., ltd.): 5g/L, formaldehyde scavenger FDS (Lurui Fine chemical Co., ltd.): 30g/L, penetrant MRZ (On high chemical Co., ltd.): 2g/L. Temperature of the drying room: 130 ℃, vehicle speed: 70m/min, drying room air quantity: 60%, air volume under the drying room: 50 percent.
The finished fabric is tested to have the following indexes:
(1) breaking strength: ASTM D5034-2009 test method, warp direction: 72Lb, weft: 50Lb;
(2) tearing strength: ASTM D1424-2009 test method, by: 5.8Lb, weft: 4.2Lb;
(3) after washing, the appearance (non-ironing), AATCC 124-2010,5 times of washing, drying test method, grade 3.2;
(4) water absorption, AATCC 79-2014 test method, 5S before washing, 8S after washing.
(5) The formaldehyde content is less than or equal to 15ppm according to a JIS L1041:2011/8.1.4B test method.
Example 3
The linen fabric non-ironing property improving processing technology comprises the following steps: l21 × 70 × 65 × 57/58, tissue: plain weaving;
singeing flax yarns in warp and weft directions → desizing → special bleaching → drying of wet cloth → liquid ammonia → whitening washing → super softness → damp cross-linking washing → tentering to obtain 100% flax fabric with non-ironing property reaching 3.2 grade, comprising the following steps:
1) The fabric is super-soft after singeing → desizing → extra bleaching → wet cloth drying → liquid ammonia → whitening and washing;
2) Super-soft: fatty acid hydrophilic reactivator QQ-N (Kekai Fine chemical Co., ltd.): 5g/L, thermal reactive polyurethane softener RPU (Onha chemical Co., ltd.): 30g/L, polyamino hydroxy derivative humectant PN94 (Jodany Post chemical Co., ltd.): 3g/L, vehicle speed: 20m/min, temperature: 120 ℃, main fan air volume: 75%, lower fan air volume: 50% of air exhaust volume: 75 percent.
3) Moisture crosslinking: resin auxiliary AMC (BASF chemical Co., ltd.): 130g/L, resin catalyst LRMC (Passion chemical Co., ltd.): 65g/L, fiber protectant ACN (Hensmei textile dyeing Co.): 30g/L of hydrophilic linear copolymer silicone oil TF-4911 (Zhejiang department of agriculture, ltd.): 3g/L, 3g/L of penetrant SN-10 (Zhejiang Rihua chemical Co., ltd.). Vehicle speed: 35m/min, drying room air volume: 50%, the air quantity below the drying room is 40%, and the temperature of the drying room (8 groups/DEG C): 60/60/70/70/80/80/85/85, falling cloth humidity: 16-20%, overfeed 6%, and cropping temperature: at 35 deg.c.
4) After the fabric is subjected to damp crosslinking and water washing, stentering is carried out
5) Tentering: the multi-component copolymerization block organosilicon emulsion softener TF-4865C (Zhejiang department of agriculture, inc.): 5g/L, novel multipolymer silicone oil softening agent DT-5288 (Federal science speciality chemical Co., ltd.): 5g/L, formaldehyde scavenger FDS (Lurui Fine chemical Co., ltd.): 30g/L, penetrant MRZ (On high chemical Co., ltd.): 3g/L. Temperature of the drying room: 130 ℃, vehicle speed: 70m/min, drying room air volume: 60%, air volume under the drying room: 50 percent.
The finished fabric is tested to have the following indexes:
(1) breaking strength: ASTM D5034-2009 test method, warp direction: 43Lb, weft: 35Lb;
(2) tearing strength: ASTM D1424-2009 test method, by: 4.6Lb, weft: 3.3Lb;
(3) after washing, the appearance (non-ironing), AATCC 124-2010,5 times of washing, drying test method, grade 3.2;
(4) water absorption, AATCC 79-2014 test method, 6S before washing, 9S after washing.
(5) The formaldehyde content is less than or equal to 12ppm by a JIS L1041:2011/8.1.4B test method.
Comparative example 1
The linen fabric non-ironing property improving processing technology comprises the following steps: l21 x 65 x 60 x 57/58, tissue: plain weaving;
singeing flax yarns used in the warp and weft directions → desizing → special bleaching → wet cloth drying → liquid ammonia → whitening washing → tentering → tide crosslinking washing → tentering after washing → super-soft → preshrinking, and the steps are as follows:
1) The fabric is subjected to singeing → desizing → special bleaching → wet cloth drying → liquid ammonia → whitening and washing, and then tentering is carried out;
2) Tentering: SHE-01 (Lurui Fine chemical Co., ltd.): 20g/L, vehicle speed: 70m/min, drying room temperature: dropping at 140 ℃ to form a width: 140cm, air intake: 85%, lower air volume: 75 percent.
3) Moisture crosslinking: resin auxiliary AMC (BASF CHEMICAL CO., LTD): 130g/L, resin catalyst LRMC (Passion chemical Co., ltd.): 65g/L, fiber protectant SF-P (Lurui Fine chemical Co., ltd.): 30g/L and 3g/L of penetrant SN-10 (Zhejiang Rihua chemical Co., ltd.). Amplitude falling: 155cm, vehicle speed: 27m/min, drying room air volume: 60%, 50% of air quantity below the drying room, and the temperature of the drying room (8 groups/DEG C): 60/60/70/70/80/80/85/85, cropping humidity: 8-12%, overfeed 5%, and cropping temperature: at 37 ℃.
4) After the fabric is subjected to damp crosslinking and water washing, stentering is carried out
5) Tentering: formaldehyde scavenger FDS (lurry fine chemical limited): 30g/L, penetrant MRZ (On high chemical Co., ltd.): 3g/L. Temperature of the drying room: 130 ℃, vehicle speed: 70m/min, drying room air quantity: 60%, air volume under the drying room: 50 percent.
The finished fabric is tested to have the following indexes:
(1) breaking strength: ASTM D5034-2009 test method, warp direction: 48Lb, weft: 32Lb;
(2) tearing strength: ASTM D1424-2009 test method, by: 3.7Lb, weft: 2.5Lb;
(3) after washing, the appearance (non-ironing), AATCC 124-2010,5 times of washing, drying test method, grade 2.8;
(4) water absorption, AATCC 79-2014 test method, 15S before washing and 30S after washing.
(5) The formaldehyde content is less than or equal to 15ppm according to a JIS L1041:2011/8.1.4B test method.
Of course, the foregoing is only a preferred embodiment of the invention and should not be taken as limiting the scope of the embodiments of the invention. The present invention is not limited to the above examples, and equivalent changes and modifications made by those skilled in the art within the spirit and scope of the present invention should be construed as being included in the scope of the present invention.

Claims (5)

1. A processing technology for improving the non-ironing property of flax fabric is characterized in that: the warp and weft yarns are all linen yarns, and the linen grey cloth is subjected to singeing → desizing → extra bleaching → wet cloth drying → liquid ammonia → whitening and washing → ultra-soft → damp cross-linking and washing → tentering to obtain the linen grey cloth;
in the feed liquid used in the super-soft process: fatty acid hydrophilic reactivator QQ-N: 3-6 g/L, thermal reactive polyurethane softener RPU: 20-30 g/L, polyamino hydroxyl derivative humectant PN94: 1-3 g/L;
in the feed liquid used in the damp crosslinking procedure: resin auxiliary agent AMC:100 to 140g/L, resin catalyst LRMC: 50-70 g/L, fiber protective agent ACN: 20-30 g/L, hydrophilic linear polysilicone oil TF-4911: 1-3 g/L, and 1-3 g/L of penetrant SN-10.
2. The linen fabric non-ironing-free processing technology according to claim 1, characterized in that: the super-soft process comprises the following steps: vehicle speed: 15-25 m/min, temperature: 110-130 ℃, main fan air volume: 70-80%, lower fan air volume: 45-55%, air volume of air exhaust: 70 to 80 percent.
3. The linen fabric non-ironing-free processing technology according to claim 1, characterized in that: the moisture crosslinking procedure comprises the following steps: on a tenter, vehicle speed: 30-40 m/min, drying room air volume: 45-55%, air quantity under the drying room is 35-45%, overfeeding: 4-7%, cropping humidity: 16-20 percent and the cropping temperature is controlled between 30-35 ℃.
4. The linen fabric non-ironing-free processing technology according to claim 1, characterized in that: in the feed liquid used in the tentering process: multicomponent copolymerization block organosilicon emulsion softener TF-4865C: 3-6 g/L, novel multicomponent copolymerized silicone oil softener DT-5288: 3-6 g/L, formaldehyde scavenger FDS: 20-30 g/L, penetrant MRZ: 2-5 g/L.
5. The linen fabric non-ironing-free processing technology according to claim 1, characterized in that: the tentering step: temperature of the drying room: 120-140 ℃, vehicle speed: 60-80 m/min.
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