CN111790356A - 一种水处理材料及其净水方法 - Google Patents
一种水处理材料及其净水方法 Download PDFInfo
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- CN111790356A CN111790356A CN202010623279.4A CN202010623279A CN111790356A CN 111790356 A CN111790356 A CN 111790356A CN 202010623279 A CN202010623279 A CN 202010623279A CN 111790356 A CN111790356 A CN 111790356A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 239000000463 material Substances 0.000 title claims abstract description 38
- 238000000746 purification Methods 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 36
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 29
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 29
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 29
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 29
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 24
- 229940037003 alum Drugs 0.000 claims abstract description 23
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920002472 Starch Polymers 0.000 claims abstract description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 19
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000011591 potassium Substances 0.000 claims abstract description 19
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 239000001509 sodium citrate Substances 0.000 claims abstract description 19
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 19
- 239000008107 starch Substances 0.000 claims abstract description 19
- 235000019698 starch Nutrition 0.000 claims abstract description 19
- 239000010457 zeolite Substances 0.000 claims abstract description 19
- 239000006004 Quartz sand Substances 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052742 iron Inorganic materials 0.000 claims abstract description 18
- -1 alum Chemical compound 0.000 claims abstract description 12
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 10
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 5
- 239000002639 bone cement Substances 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 5
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 5
- 235000010413 sodium alginate Nutrition 0.000 claims description 5
- 239000000661 sodium alginate Substances 0.000 claims description 5
- 229940005550 sodium alginate Drugs 0.000 claims description 5
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 5
- 238000001179 sorption measurement Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 5
- 239000002351 wastewater Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
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- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
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Abstract
本发明公开了一种水处理材料及其净水方法，该水处理材料由活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾组成；净水方法：(1)备料：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾；(2)混合：将步骤(1)中备好的料原料进行混合；(3)将步骤(2)中的混合好的原料投入到水处理器内进行净水处理；(4)水从水处理器的进水口进入，进过净水处理后从出口处流出，从而完成水的净化；本发明的水处理材料可以快速沉降，性能稳定性好，易于与水混合，能够充分发挥材料的快速吸附作用，成本低，具有广阔市场应用前景。
Description
技术领域
本发明涉及水净化处理技术领域，尤其涉及一种水处理材料及其净水方法。
背景技术
随着人口的增长和工业的发展，水资源匮乏、特别是水质型缺水现象日益严重，污水处理技术在生产和生活中的作用也越来越大。水体中的污染物大致可以分为三类：包括重金属的固体污染物、有机物、细菌和病毒。其中含重金属离子固体污染物废水的污染尤为严重。重金属废水主要来源于采矿、选矿、冶炼、电镀、化工、制革和造纸工业，这些行业产生的含铅、汞、镉、铬、镍、铜、锌等重金属的废水排入天然水体后，不仅对水生生物构成威胁，而且可能通过沉淀、吸附及食物链而不断富集，破坏生态环境，并最终危害到人类的健康。并且重金属污染会造成地下水和地表水的污染加剧，水现有水处理设备的改造速度赶不上水的污染速度。水中的有机物和含氯消毒剂结合后产生的卤代物，有许多已被确认为癌症的诱发物。因此，必须严格控制排入环境的工业废水，且注重对饮用水的净化处理。现阶段对于水的净化处理处理已经成为全球性问题，因此需要开发一种高吸附容量、低成本、无二次污染的水处理材料。
发明内容
本发明的目的在于提供一种水处理材料及其净水方法，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种水处理材料，其中，由以下成分组成：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾。
优选的，该水处理材料，包括以下重量份的原料：活性氧化铝6-10份、聚合氯化铝10-25份、碳酸镁6-8份、聚合硫酸铁2-7份、明矾1-3份、石英砂20-30份、海绵铁5-7份、沸石9-15份、多孔淀粉15-20份、柠檬酸钠1-3份、氟锆酸钾6-8份。
优选的，该水处理材料，具体包括以下重量份的原料：活性氧化铝8份、聚合氯化铝17份、碳酸镁7份、聚合硫酸铁5份、明矾2份、石英砂25份、海绵铁6份、沸石12份、多孔淀粉18份、柠檬酸钠2份、氟锆酸钾7份。
优选的，所述碳酸镁可更换成硫酸镁和氯化镁其中的一种或为三种的混合物。
优选的，所述明矾、聚合氯化铝、聚合硫酸铁可任意更换成硫酸铝、聚合硫酸铝、铝酸钠、三氯化铁、硫酸亚铁、碳酸镁、聚合氯化铁、骨胶、聚丙烯酰胺、活化硅酸和海藻酸钠其中的一种或多种。
本发明提供的一种水处理材料的净水方法如下步骤进行：(1)备料：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾；(2)混合：将步骤(1)中备好的料原料进行混合；(3)将步骤(2)中的混合好的原料投入到水处理器内进行净水处理；(4)水从水处理器的进水口进入，进过净水处理后从出口处流出，从而完成水的净化。
有益效果：本发明的有益效果是：本发明的水处理材料可以快速沉降，性能稳定性好，可有效去除水中的有害元素和杂质，能够有效抑制细菌滋生，无毒无味，无异物脱落，不会产生二次污染，体积密度小，易于与水混合，能够充分发挥材料的快速吸附作用，操作性强，成本低，具有广阔市场应用前景。
具体实施方式
下面结合具体实施方式对本专利的技术方案作进一步详细地说明。
实施例1
本实施例的一种水处理材料，其中，由以下成分组成：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾。
进一步的说，该水处理材料，具体包括以下重量份的原料：活性氧化铝6份、聚合氯化铝10份、碳酸镁6份、聚合硫酸铁2份、明矾1份、石英砂20份、海绵铁5份、沸石9份、多孔淀粉15份、柠檬酸钠1份、氟锆酸钾6份。
进一步的说，所述碳酸镁可更换成硫酸镁和氯化镁其中的一种或为三种的混合物。
进一步的说，所述明矾、聚合氯化铝、聚合硫酸铁可任意更换成硫酸铝、聚合硫酸铝、铝酸钠、三氯化铁、硫酸亚铁、碳酸镁、聚合氯化铁、骨胶、聚丙烯酰胺、活化硅酸和海藻酸钠其中的一种或多种。
本发明提供的一种水处理材料的净水方法如下步骤进行：(1)备料：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾；(2)混合：将步骤(1)中备好的料原料进行混合；(3)将步骤(2)中的混合好的原料投入到水处理器内进行净水处理；(4)水从水处理器的进水口进入，进过净水处理后从出口处流出，从而完成水的净化。
实施例2
本实施例的一种水处理材料，其中，由以下成分组成：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾。
进一步的说，该水处理材料，具体包括以下重量份的原料：活性氧化铝8份、聚合氯化铝17份、碳酸镁7份、聚合硫酸铁5份、明矾2份、石英砂25份、海绵铁6份、沸石12份、多孔淀粉18份、柠檬酸钠2份、氟锆酸钾7份。
进一步的说，所述碳酸镁可更换成硫酸镁和氯化镁其中的一种或为三种的混合物。
进一步的说，所述明矾、聚合氯化铝、聚合硫酸铁可任意更换成硫酸铝、聚合硫酸铝、铝酸钠、三氯化铁、硫酸亚铁、碳酸镁、聚合氯化铁、骨胶、聚丙烯酰胺、活化硅酸和海藻酸钠其中的一种或多种。
本发明提供的一种水处理材料的净水方法如下步骤进行：(1)备料：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾；(2)混合：将步骤(1)中备好的料原料进行混合；(3)将步骤(2)中的混合好的原料投入到水处理器内进行净水处理；(4)水从水处理器的进水口进入，进过净水处理后从出口处流出，从而完成水的净化。
实施例3
本实施例的一种水处理材料，其中，由以下成分组成：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾。
进一步的说，该水处理材料，具体包括以下重量份的原料：活性氧化铝10份、聚合氯化铝25份、碳酸镁8份、聚合硫酸铁7份、明矾-份、石英砂30份、海绵铁7份、沸石15份、多孔淀粉20份、柠檬酸钠3份、氟锆酸钾8份。
进一步的说，所述碳酸镁可更换成硫酸镁和氯化镁其中的一种或为三种的混合物。
进一步的说，所述明矾、聚合氯化铝、聚合硫酸铁可任意更换成硫酸铝、聚合硫酸铝、铝酸钠、三氯化铁、硫酸亚铁、碳酸镁、聚合氯化铁、骨胶、聚丙烯酰胺、活化硅酸和海藻酸钠其中的一种或多种。
本发明提供的一种水处理材料的净水方法如下步骤进行：(1)备料：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾；(2)混合：将步骤(1)中备好的料原料进行混合；(3)将步骤(2)中的混合好的原料投入到水处理器内进行净水处理；(4)水从水处理器的进水口进入，进过净水处理后从出口处流出，从而完成水的净化。
本发明的水处理材料可以快速沉降，性能稳定性好，可有效去除水中的有害元素和杂质，能够有效抑制细菌滋生，无毒无味，无异物脱落，不会产生二次污染，体积密度小，易于与水混合，能够充分发挥材料的快速吸附作用，操作性强，成本低，具有广阔市场应用前景。
以上所描述的实施例是本发明的优选实施方式，而不是全部的实施例。本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围，而是仅仅表示本发明的选定实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
Claims (6)
1.一种水处理材料，其特征在于，包括：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾。
2.根据权利要求1所述的一种水处理材料，其特征在于：包括以下重量份的原料：活性氧化铝6-10份、聚合氯化铝10-25份、碳酸镁6-8份、聚合硫酸铁2-7份、明矾1-3份、石英砂20-30份、海绵铁5-7份、沸石9-15份、多孔淀粉15-20份、柠檬酸钠1-3份、氟锆酸钾6-8份。
3.根据权利要求2所述的一种水处理材料，其特征在于：包括以下重量份的原料：活性氧化铝8份、聚合氯化铝17份、碳酸镁7份、聚合硫酸铁5份、明矾2份、石英砂25份、海绵铁6份、沸石12份、多孔淀粉18份、柠檬酸钠2份、氟锆酸钾7份。
4.根据权利要求3所述的一种水处理材料，其特征在于：所述碳酸镁可更换成硫酸镁和氯化镁其中的一种或为三种的混合物。
5.根据权利要求3所述的一种水处理材料，其特征在于：所述明矾、聚合氯化铝、聚合硫酸铁可任意更换成硫酸铝、聚合硫酸铝、铝酸钠、三氯化铁、硫酸亚铁、碳酸镁、聚合氯化铁、骨胶、聚丙烯酰胺、活化硅酸和海藻酸钠其中的一种或多种。
6.根据权利要求1所述的一种水处理材料的净水方法，其特征在于：该净水方法按如下步骤进行：(1)备料：活性氧化铝、聚合氯化铝、碳酸镁、聚合硫酸铁、明矾、石英砂、海绵铁、沸石、多孔淀粉、柠檬酸钠、氟锆酸钾；(2)混合：将步骤(1)中备好的料原料进行混合；(3)将步骤(2)中的混合好的原料投入到水处理器内进行净水处理；(4)水从水处理器的进水口进入，进过净水处理后从出口处流出，从而完成水的净化。
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