CN111777756A - Finishing agent for endowing fabric with drapability and preparation method and application thereof - Google Patents
Finishing agent for endowing fabric with drapability and preparation method and application thereof Download PDFInfo
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- CN111777756A CN111777756A CN202010584469.XA CN202010584469A CN111777756A CN 111777756 A CN111777756 A CN 111777756A CN 202010584469 A CN202010584469 A CN 202010584469A CN 111777756 A CN111777756 A CN 111777756A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention belongs to the field of functional finishing of textile fabrics, and discloses a finishing agent capable of endowing fabric with drapability, a preparation method and application thereof, wherein the preparation method of the finishing agent comprises the following steps: pouring polyol into a reaction kettle, starting a stirring device, adding a catalyst into the reaction kettle, starting a heating device, heating to 100-120 ℃, and carrying out heat preservation reaction for 2-4 hours; after the heat preservation reaction is finished, adding inorganic salt into the mixture, and continuously preserving heat, stirring and reacting for 2-4 hours; and cooling after the reaction is finished, adding water when the temperature is reduced to 80-90 ℃, and uniformly stirring to obtain the finishing agent capable of endowing the fabric with drapability. The fabric draping finishing agent prepared by the invention is simple to operate and low in cost, and most importantly, when the fabric draping finishing agent is finished on an ultrathin natural fiber fabric, the draping effect is excellent, the color is low, and the durability is good.
Description
Technical Field
The invention belongs to the field of functional finishing of textile fabrics, and particularly relates to a finishing agent capable of endowing fabric with drapability, and a preparation method and application thereof.
Background
Due to the limitation of production technology, the past garment materials are thicker, superfine high count yarns are more and more increased along with the more mature spinning technology, some high-grade ultrathin garment materials with good air permeability appearing in summer are more and more popular, especially natural fiber type high count ultrathin fabrics, the ultrathin garment materials are light to wear, good in air permeability and soft in hand feeling, the defects that the ultrathin fabric is more lacking in bones and poor in drapability, the ultrathin fabric is easy to stick to a body, especially sweat in summer, the fabric is more uncomfortable to be stained to the body and is wet to be used, and therefore drapability style finishing is needed for the ultrathin fabric.
To increase the drapability of a fabric, it is primarily relied upon to substantially increase the weight of the fabric to promote sagging. However, through domestic and international research and reports, the weight increasing treatment of silk protein fiber fabrics is mainly focused, and the weight increasing treatment research of high-count and high-density ultrathin cellulose fiber fabrics is not found. Even in the case of weight increasing treatment of silk-based fabrics, there have been reported mainly a tannin weight increasing method, a tin weight increasing method, a methacrylamide graft weight increasing method, a fibroin solution weight increasing method, and the like. Wherein, the tannic acid is extracted from plants or synthesized, the cost is high, the color of light-colored fabrics is changed greatly, and the vividness of the fabrics is reduced; the tin weight method can cause rough hand feeling, and excessive weight increase can cause fiber embrittlement, color change, and reduction of dyeability and hygroscopicity; when the grafting weighting method dyes silk by active dye and weak acid dye, the dyeing dye uptake after grafting is slightly reduced, the influence on the color light of the weak acid dye is large, and the moisture absorption and the antistatic property of the fabric are also influenced to a certain extent; the weight increasing rule of silk fibroin solution is to use waste silk and silk fibroin raw material to make silk fibroin aqueous solution by chemical method, and to combine with silk protein macromolecule to fix by using similar compatibility principle, but the weight increasing rate is only about 10%. The above methods have advantages and disadvantages, but are mainly applicable to silk fabrics containing protein fibers. Therefore, there is a need to develop a drape finishing agent suitable for not only protein fabrics of silk, but also high-count, high-density and ultra-thin cellulose fiber fabrics which are newly appeared and popular at present.
Disclosure of Invention
In order to overcome the disadvantages and shortcomings of the prior art, the invention aims to provide a preparation method of a finishing agent capable of endowing fabric with drapability.
It is another object of the present invention to provide a finishing agent prepared by the above method which imparts drapability to fabrics. The draping finishing agent can be suitable for protein fabrics of silk and high-count ultrathin cellulose fiber fabrics which are newly appeared and popular at present, is convenient to finish, and has little influence on the original performances of the fabrics, such as strength, color light change, hand feeling and the like. Especially, after the fabric is padded in the working solution of the finishing agent, the residual hydroxyl groups of the polyalcohol in the finishing agent can be combined with the hydroxyl groups, amino groups or carboxyl groups in fiber molecules in a crosslinking way during baking, so that good fastness is achieved, and the draping effect has good durability.
The invention also aims to provide the application of the finishing agent capable of endowing fabric drapability to natural fiber and regenerated cellulose fiber fabrics.
The purpose of the invention is realized by the following scheme:
a process for preparing a finish capable of imparting drape to a fabric comprising the steps of:
(1) pouring the polyol into a reaction kettle, and starting a stirring device;
(2) adding a catalyst into the reaction kettle, starting a heating device, heating to 100-120 ℃, and carrying out heat preservation reaction for 2-4 hours;
(3) after the heat preservation reaction is finished, adding inorganic salt into the reaction kettle, and continuing to preserve heat and stir for reaction for 2-4 hours;
(4) and cooling after the reaction is finished, adding water when the temperature is reduced to 80-90 ℃, and uniformly stirring to obtain the finishing agent for endowing the fabric with drapability.
The polyhydric alcohol in the step (1) is at least one of ethylene glycol, diethylene glycol, glycerol, solid sorbitol, polyethylene glycol 200 and the like.
The catalyst in the step (2) is 18-crown-6.
The dosage of the catalyst in the step (2) meets the following requirements: the weight of the catalyst is 0.1-0.5% of the total weight of the polyhydric alcohol.
The inorganic salt in the step (3) is at least one of magnesium chloride and magnesium sulfate;
the dosage of the inorganic salt in the step (3) meets the following requirements: the weight of the inorganic salt is 100-200% of the total weight of the polyhydric alcohol.
The water consumption in the step (4) meets the following requirements: the weight of the water is 50-150% of the total weight of the polyhydric alcohol and the inorganic salt.
The stirring in steps (1) to (4) is performed in order to sufficiently contact the raw materials, and therefore, the stirring speed is not limited.
A finishing agent capable of imparting drapability to a fabric prepared by the above process.
The finishing agent capable of endowing fabric drapability is applied to natural fiber and regenerated cellulose fiber fabrics, in particular to silk fabrics, cotton fabrics, modal fabrics, viscose fabrics and blended fabrics formed by at least two of the four fabrics.
Compared with the prior art, the invention has the following advantages and beneficial effects:
the preparation process of the draping style finishing agent is simple, the cost is low, and most importantly, the draping style finishing agent can be used for silk protein fiber fabrics and cellulose fiber high-count ultrathin fabrics. In the preparation process, catalyst 18-crown ether-6 is catalyzed to ensure that micromolecular dihydric alcohol is subjected to etherification reaction to generate macromolecule even macromolecule polyhydric alcohol, and then the mass ratio of alcohol to magnesium salt in a certain range is controlled to ensure that partial hydroxyl in the polyhydric alcohol and Mg in the magnesium salt can react under the high temperature condition2+The coordination reaction is carried out to generate a macromolecule community to form an alcohol complex of the magnesium salt, when the finishing agent working solution is padded on the fabric and is baked at high temperature, the hydroxyl with reactive activity in the rest part of the alcohol complex of the magnesium salt can also carry out chemical reaction with active groups in various fiber molecules such as amino, carboxyl or hydroxyl to carry out graft crosslinking, and after the alcohol complex finishing agent is grafted on the fabric, the self weight of the complex salt is utilized on one hand; on the other hand, the fabric weight is greatly improved by depending on the moisture absorption of a large amount of alcoholic hydroxyl groups and magnesium salts in the graft, thereby achieving good drapability. The finishing agent and the fabric form graft crosslinking, so the effect is durable and the washability is good. In addition, the finish is ultra-clear during applicationThe original properties of the tissue, such as strength and shade, are not affected.
Detailed Description
The present invention will be described in further detail with reference to examples, but the embodiments of the present invention are not limited thereto. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
In the examples, the washing resistance test refers to GB/T3921-2008' textile color fastness test soaping color fastness: test 1 "method 1 was performed, namely: putting the sample into a washing solution containing a neutral detergent 5g/L (bath ratio is 1:50), washing for 10min at 40 ℃, then washing with clean water, dehydrating, spin-drying, repeatedly washing for a certain number of times, then drying at 80 ℃, standing in the atmosphere for 24h, and testing the fabric performance. Such as weight gain after 20 washes.
The strength loss test is carried out according to GB/T3923.1-2013 part 1 of tensile property of textile fabrics, namely determination of breaking strength and breaking elongation (bar sample method);
the color change Δ E was measured with a Datacolor model 800 spectrophotometer.
Example 1
A process for preparing a finish capable of imparting drape to a fabric comprising the steps of:
step 1: pouring 3 parts by weight of diethylene glycol into a reaction kettle, and starting a stirring device;
step 2: then adding a catalyst 18-crown ether-6 with the weight of 0.4 percent of that of the diethylene glycol, starting a heating device, heating to 100 ℃, and carrying out heat preservation reaction for 3 hours;
and step 3: then adding 3 parts by weight of anhydrous magnesium chloride while stirring, and stirring for 4 hours under the condition of keeping the temperature at 100 ℃ to fully dissolve and react;
and 4, step 4: and finally, opening a built-in cooling coil to cool the reaction material, adding 4 parts by weight of tap water when the temperature is reduced to 80-90 ℃, and fully stirring to obtain the finished product of the draping finishing agent.
The prepared drapability finishing agent is prepared into 150g/L working solution by using tap water, and then the real silk fabric (01 creped white silk) is applied according to the following process: padding working fluid (with a liquid ratio of 75%) → heat setting (150 ℃x90 s) → cropping moisture regain equilibrium, and performing an effect test, the results are as follows in table 1:
TABLE 1
Initial rate of weight gain | Weight gain after washing for 20 times | Color change △ E | Loss of strength | |
Unfinished blank real silk fabric | 0 | 0 | ---- | ---- |
Finished real silk fabric | 25.54% | 24.27% | 0.30 | 2.4% |
Example 2
A process for preparing a finish capable of imparting drape to a fabric comprising the steps of:
step 1: pouring 2 parts by weight of glycerol into a reaction kettle, and starting a stirring device;
step 2: then adding catalyst 18-crown ether-6 with the weight of 0.2 percent of the weight of the glycerol, starting a heating device, heating to 110 ℃, and carrying out heat preservation reaction for 4 hours;
and step 3: then slowly adding 3 parts by weight of anhydrous magnesium chloride while stirring, and stirring for 2 hours under the condition of keeping the temperature at 110 ℃ to fully dissolve and react;
and 4, step 4: and finally, opening a built-in cooling coil to cool the reaction material, adding 5 parts by weight of tap water when the temperature is reduced to 80-90 ℃, and uniformly stirring to obtain the finished product of the draping finishing agent.
The prepared draping finishing agent is prepared into 150g/L working solution by using tap water, and then the ultrathin combed high-count high-density pure cotton fabric (all-cotton poplin 100s multiplied by 156 multiplied by 80) is applied according to the following process: padding working fluid (90% of liquid carrying rate) → heat setting (160 ℃x180 s) → cropping moisture regain equilibrium, and performing an effect test, the results are as follows in table 2:
TABLE 2
Initial rate of weight gain | Weight gain after washing for 20 times | Color change △ E | Loss of strength | |
Unfinished blank ultra-thin cotton fabric | 0 | 0 | ---- | ---- |
Finished ultrathin cotton fabric | 18.54% | 17.78% | 0.36 | 2.0% |
Example 3
A process for preparing a finish capable of imparting drape to a fabric comprising the steps of:
step 1: pouring 2.5 parts by weight of solid sorbitol into a reaction kettle, and slowly starting a stirring device;
step 2: then adding catalyst 18-crown ether-6 with the weight of 0.25 percent of that of the sorbitol, starting a heating device, heating to 120 ℃, and carrying out heat preservation reaction for 2 hours;
and step 3: then slowly adding 3.5 parts by weight of magnesium sulfate while stirring, and stirring for 2 hours under the condition of keeping the temperature at 120 ℃ to fully dissolve and react;
and 4, step 4: and finally, opening a built-in cooling coil to cool the reaction material, adding 4 parts by weight of tap water when the temperature is reduced to 80-90 ℃, and fully stirring to obtain the finished product of the draping finishing agent.
Preparing 180g/L working solution from tap water for the prepared draping finishing agent, and then applying real silk fabric (georgette with 12m/m yarn count 2/20/22D) according to the following process: padding working fluid (with liquid rate of 60%) → heat setting (140 ℃x120 s) → cropping moisture regain equilibrium, and performing an effect test, the results are as follows in table 3:
TABLE 3
Initial rate of weight gain | Weight gain after washing for 20 times | Color change △ E | Loss of strength | |
Unfinished blank real silk fabric | 0 | 0 | ---- | ---- |
Finished real silk fabric | 30.25% | 29.68% | 0.44 | 3.2% |
Example 4
A process for preparing a finish capable of imparting drape to a fabric comprising the steps of:
step 1: pouring 1 part by weight of diethylene glycol, 1 part by weight of glycerol and 1 part by weight of solid sorbitol into a reaction kettle, and starting a stirring device;
step 2: then adding a catalyst 18-crown ether-6 with the weight of 0.5 percent of the total weight of the mixed polyol, starting a heating device, heating to 110 ℃, and carrying out heat preservation reaction for 3 hours;
and step 3: then slowly adding 3 parts by weight of magnesium chloride while stirring, and stirring for 3 hours under the condition of keeping the temperature at 110 ℃ to fully dissolve and react;
and 4, step 4: and finally, opening a built-in cooling coil to cool the reaction material, adding 4 parts by weight of tap water when the temperature is reduced to 80-90 ℃, and fully and uniformly stirring to obtain the finished product of the draping finishing agent.
The prepared draping finishing agent is prepared into 180g/L working solution by using tap water, and then a high-count ultrathin cellulose fiber fabric (Modal plain fabric 60s multiplied by 110 multiplied by 102) is applied according to the following process: padding working fluid (80% of liquid carrying rate) → heat setting (170 ℃x150 s) → cropping moisture regain equilibrium, and performing an effect test, the results are as follows in table 4:
TABLE 4
Initial rate of weight gain | Weight gain after washing for 20 times | Color change △ E | Loss of strength | |
Unfinished blank modal fabric | 0 | 0 | ---- | ---- |
Finished modal fabric | 22.82% | 22.36% | 0.35 | 2.8% |
Example 5
A preparation method of a finishing agent capable of endowing ultra-thin natural fiber fabric with drapability comprises the following steps:
step 1: pouring 0.5 weight part of polyethylene glycol 200, 1 weight part of glycerol and 0.5 weight part of solid sorbitol into a reaction kettle, and starting a stirring device;
step 2: then adding a catalyst 18-crown ether-6 with the weight of 0.5 percent of the total weight of the mixed polyol, starting a heating device, heating to 100 ℃, and carrying out heat preservation reaction for 4 hours;
and step 3: then adding 0.5 weight part of magnesium chloride and 3 weight parts of magnesium sulfate while stirring, and stirring for 4 hours under the condition of keeping the temperature at 100 ℃ to fully dissolve and react;
and 4, step 4: and finally, opening a built-in cooling coil to cool the reaction material, adding 4.5 parts by weight of tap water when the temperature is reduced to 80-90 ℃, and fully stirring to obtain the finished product of the draping finishing agent.
Preparing 200g/L working solution from the prepared draping finishing agent by using tap water, and then applying the high-count ultrathin cotton/viscose blended fabric (knitted undershirt JC 60/R4060 s) according to the following process: padding working fluid (60% of liquid carrying rate) → heat setting (160 ℃x140 s) → cropping moisture regain equilibrium, and performing an effect test, the results are as follows in table 5:
TABLE 5
Initial rate of weight gain | Weight gain after washing for 20 times | Color change △ E | Loss of strength | |
Unfinished white cotton/viscose blended fabric | 0 | 0 | ---- | ---- |
Finished cotton/viscose blended fabric | 26.97%% | 26.31%% | 0.41 | 3.5%% |
From the above examples, it can be seen that when the prepared drapability style finishing agent is applied to real silk fabrics or high-count ultrathin cellulose fiber fabrics (cotton, modal or cotton/viscose blended fabrics), the weight of the fabrics can be remarkably increased, so that the drapability of the fabrics is increased, especially under the condition of large using amount, the effect is better, and after 20 times of washing, the effect can still be kept good!
The invention can be realized by the raw materials listed in the invention, the upper and lower limit values of the raw materials and the upper and lower limit values of the process parameters, and the examples are not listed.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (10)
1. A process for preparing a finish capable of imparting drape to a fabric, characterized by the steps of:
(1) pouring the polyol into a reaction kettle, and starting a stirring device;
(2) adding a catalyst into the reaction kettle, starting a heating device, heating to 100-120 ℃, and carrying out heat preservation reaction for 2-4 hours;
(3) after the heat preservation reaction is finished, adding inorganic salt into the reaction kettle, and continuing to preserve heat and stir for reaction for 2-4 hours;
(4) and cooling after the reaction is finished, adding water when the temperature is reduced to 80-90 ℃, and uniformly stirring to obtain the finishing agent for endowing the fabric with drapability.
2. A process for preparing a finishing agent capable of imparting drape to a fabric according to claim 1, characterized in that:
the polyhydric alcohol in the step (1) is at least one of ethylene glycol, diethylene glycol, glycerol, solid sorbitol and polyethylene glycol 200.
3. A process for preparing a finishing agent capable of imparting drape to a fabric according to claim 1, characterized in that:
the catalyst in the step (1) is 18-crown-6.
4. A process for preparing a finishing agent capable of imparting drape to a fabric according to claim 1, characterized in that:
the dosage of the catalyst in the step (2) meets the following requirements: the weight of the catalyst is 0.1-0.5% of the total weight of the polyhydric alcohol.
5. A process for preparing a finishing agent capable of imparting drape to a fabric according to claim 1, characterized in that:
the inorganic salt in the step (3) is at least one of magnesium chloride and magnesium sulfate.
6. A process for preparing a finishing agent capable of imparting drape to a fabric according to claim 1, characterized in that:
the dosage of the inorganic salt in the step (3) meets the following requirements: the weight of the inorganic salt is 100-200% of the total weight of the polyhydric alcohol.
7. A process for preparing a finishing agent capable of imparting drape to a fabric according to claim 1, characterized in that:
the water consumption in the step (4) meets the following requirements: the weight of the water is 50-150% of the total weight of the polyhydric alcohol and the inorganic salt.
8. A finishing agent capable of imparting drape to a fabric prepared by the method of any one of claims 1 to 7.
9. Use of the finishing agent capable of imparting drape to fabrics according to claim 8 in natural fiber and regenerated cellulose fiber fabrics.
10. Use of a finishing agent capable of imparting drape to a fabric according to claim 8 in silk fabrics, cotton fabrics, modal fabrics, viscose fabrics and blended fabrics formed from at least two of these four fabrics.
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Cited By (1)
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CN114108322A (en) * | 2021-11-30 | 2022-03-01 | 深圳天鼎新材料有限公司 | Meat-feeling smooth and elastic fabric finishing agent and preparation method and application thereof |
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2020
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US4964873A (en) * | 1985-01-15 | 1990-10-23 | Lever Brothers Company | Fabric conditioning method |
CN102491883A (en) * | 2011-12-16 | 2012-06-13 | 东华大学 | Polyethylene glycol magnesium and preparation method and application thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114108322A (en) * | 2021-11-30 | 2022-03-01 | 深圳天鼎新材料有限公司 | Meat-feeling smooth and elastic fabric finishing agent and preparation method and application thereof |
CN114108322B (en) * | 2021-11-30 | 2024-01-30 | 深圳天鼎新材料有限公司 | Meat smooth and elastic fabric finishing agent and preparation method and application thereof |
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