CN111759754A - Hair care composition, hair care film and preparation method thereof - Google Patents
Hair care composition, hair care film and preparation method thereof Download PDFInfo
- Publication number
- CN111759754A CN111759754A CN202010747409.5A CN202010747409A CN111759754A CN 111759754 A CN111759754 A CN 111759754A CN 202010747409 A CN202010747409 A CN 202010747409A CN 111759754 A CN111759754 A CN 111759754A
- Authority
- CN
- China
- Prior art keywords
- hair care
- parts
- hair
- care composition
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Abstract
The invention provides a hair care composition, a hair care film and a preparation method thereof, wherein the hair care composition comprises the following components in parts by mass: 3-7 parts of a cationic surfactant; 0.2-7 parts of a nonionic surfactant; 2-5 parts of an organic silicon emulsion; 2-6 parts of silicone oil; 0.2-5 parts of ester oil; 2-10 parts of a thickening agent; 0.2-3 parts of a humectant; 0-0.5 part of a pH regulator; the thickening agent is an acrylate polymer. The hair care composition and the hair care film can keep hair moist and smooth, are easy to wash, and can effectively protect the health of the hair and scalp.
Description
Technical Field
The invention relates to the technical field of hair care products, in particular to a hair care composition, a hair care film and a preparation method thereof.
Background
Hair care products such as conditioners can soften hair, but when it remains on the scalp, it can break the scalp cuticle and cause hair loss over time. After the chemicals in the hair care product contact with air, pores can be blocked or dandruff can be generated.
The existing hair care products, particularly hair conditioners, hair membranes and the like are often washed for a long time and easily cause residues. Particularly dry hair users, when using such hair care products, often result in incomplete cleaning, although the moisturization of the hair is maintained.
Therefore, there is a need for a hair care product that can keep hair moist, smooth and easy to rinse.
Disclosure of Invention
The invention aims to provide a hair care product which can keep hair moist, smooth and easy to rinse.
In order to achieve the purpose, the invention provides the following technical scheme:
a hair care composition comprises the following components in parts by mass:
3-7 parts of a cationic surfactant;
0.2-7 parts of a nonionic surfactant;
2-5 parts of an organic silicon emulsion;
2-6 parts of silicone oil;
0.2-5 parts of ester oil;
2-10 parts of a thickening agent;
0.2-3 parts of a humectant;
0-0.5 part of a pH regulator;
wherein the thickening agent is an acrylate polymer.
Preferably, the thickener is a polymethacrylate polymer.
Preferably, the cationic surfactant is selected from at least one of stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, stearamidopropyl dimethylamine, PEG-2 oleic acid methyl ammonium chloride, coco trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, and behenyl trimethyl ammonium chloride.
Preferably, the nonionic surfactant is a polyglycerin fatty acid ester.
Preferably, the polyglycerol fatty acid ester is prepared by reacting fatty acid with glycerol with n being more than or equal to 5.
Preferably, the mass part ratio of the silicone oil to the silicone emulsion is (0.5-2): 1.
preferably, the ester oil is selected from at least one of dioctyl carbonate, 2-octyldodecanol myristate, isopropyl myristate, alkyl benzoate, isopropyl palmitate, butyl octanol salicylate, and cetyl ethylhexanoate.
Preferably, the silicone emulsion is an amino silicone oil emulsion, which is formed by mixing amino-terminated polydimethylsiloxane, cetrimide and tridecyl polyether-10.
The invention also provides a hair care film which comprises the hair care composition.
The invention also provides a preparation method of the hair care film, which comprises the following steps:
weighing the thickening agent, the cationic surfactant and the pH regulator, adding the thickening agent, the cationic surfactant and the pH regulator into preheated water, mixing and stirring, and homogenizing;
sequentially adding the mixed solution of the nonionic surfactant, the thickening agent and water, stirring, homogenizing, and keeping constant temperature;
stirring and defoaming are carried out by vacuumizing, and the stirring process is kept at a constant temperature;
cooling, sequentially adding the silicone oil, the organic silicon emulsion and the ester oil, mixing uniformly, stirring and homogenizing;
adding the humectant, stirring and homogenizing;
adding essence, antiseptic, chelating agent and water, and stirring.
Compared with the prior art, the scheme of the invention has the following advantages:
in the hair care composition and the hair care film, the thickening agent adopts the acrylic ester polymer, and the acrylic ester polymer and the cationic surfactant can form association in the hair care composition system, so that the hair care composition and the hair care film have stronger hydrophobicity; meanwhile, the acrylate polymer needs less dosage and has quick viscosity reduction, thereby being easy to wash hair and protecting the health of scalp.
The hair care composition and the hair care film are compounded by the organic silicon emulsion, the silicone oil and the ester oil, so that the active ingredients in the hair care composition and the hair care film can be ensured to effectively exert long-acting performance, particularly, the hair with the problems of hair fibrous keratin denaturation, hair expansion and breakage, hair scale falling, elasticity reduction and the like caused by high-temperature perm can be repaired, the softness and the moisture of the hair can be maintained in the hair washing process, the dry and wet combing performance of the hair is good, and the hair can be maintained to be durably smooth after washing and caring. Secondly, the hair care composition and the hair care film are fresh and non-greasy after being used, and are suitable for people with various hair qualities including oily hair. In addition, the hair care composition and the hair care film can obviously enhance the toughness of the hair after long-term use.
In the hair care composition and the hair care film, the polyglycerol fatty acid ester is selected as the nonionic surfactant, so that the emulsifying capacity is high, the dosage is small, and the polyglycerol fatty acid ester is matched with the cationic surfactant for use, so that the cleaning power is improved, the irritation is small, and the polyglycerol fatty acid ester can be quickly washed.
Additional aspects and advantages of the invention will be set forth in part in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.
Detailed Description
The following examples are illustrative only and are not to be construed as limiting the invention. In addition, if a detailed description of the known art is not necessary to show the features of the present invention, it is omitted.
The invention provides a hair care composition which comprises the following components in parts by mass:
3-7 parts of a cationic surfactant;
0.2 to 7 parts of a nonionic surfactant
2-5 parts of an organic silicon emulsion;
2-6 parts of silicone oil;
0.2-5 parts of ester oil;
2-10 parts of a thickening agent;
0.2-3 parts of a humectant;
0-0.5 part of a pH regulator;
wherein the thickening agent is an acrylate polymer.
In the hair care composition, the acrylate polymer is used as a thickening agent, and the acrylate polymer and the cationic surfactant in the proportion can form good association in the hair care composition system, so that the hair care composition has stronger hydrophobicity; meanwhile, the acrylate polymer needs less dosage and can accelerate the reduction speed of the system viscosity, thereby being easy for hair washing and protecting the scalp health.
In one embodiment of the invention, the thickener is a polymethacrylate polymer. In another embodiment of the present invention, the thickener may also be added with hydroxyethyl fibers and/or cetyl alcohol. Hydroxyethyl cellulose, as a water-soluble thickener, has enzyme resistance and medium-high viscosity, is white powder in appearance, has an active content of 99%, has a wide pH range, is widely used, and is suitable for the hair care composition of the present invention to effectively form a viscous hair film body.
The cationic surfactant is at least one selected from stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, stearamidopropyl dimethylamine, PEG-2 oleic acid fatty methyl ammonium chloride, coco trimethyl ammonium chloride, cetyl trimethyl ammonium chloride and behenyl trimethyl ammonium chloride. In one embodiment of the invention, the cationic surfactant is stearyl trimethyl ammonium chloride, the active matter content of the cationic surfactant is 26.5% -29.5%, and the specific gravity range is 0.952-0.964.
The nonionic surfactant is polyglyceryl fatty acid ester. In one embodiment of the invention, the polyglycerol fatty acid ester is prepared by reacting fatty acid with glycerol with n being more than or equal to 5, so that the polyglycerol fatty acid ester has strong emulsifying capacity, needs small dosage and has large effect, and the polyglycerol fatty acid ester is matched with a cationic surfactant for use, so that the cleaning power of the hair care composition is improved, the irritation is small, and the polyglycerol fatty acid ester can be quickly washed.
In one embodiment of the invention, the mass part ratio of the silicone oil to the silicone emulsion is (0.5-2): 1. the silicone oil is at least one selected from cyclopentadimethylsiloxane and dimethiconol. The cyclopentadecyldimethicones and dimethiconols are prepared by physical interaction of a high proportion of dimethiconol. The ester oil is selected from at least one of dioctyl carbonate, 2-octyldodecanol myristate, isopropyl myristate, alkyl benzoate, isopropyl palmitate, butyl octanol salicylate, and cetyl ethylhexanoate. The hair care composition and the hair care film are compounded by the organic silicon emulsion, the silicone oil and the ester oil, so that the active ingredients in the hair care composition and the hair care film can be ensured to effectively exert long-acting performance, particularly, the hair with the problems of hair fibrous keratin denaturation, hair expansion and breakage, hair scale falling, elasticity reduction and the like caused by high-temperature perm can be repaired, the softness and the moisture of the hair can be maintained in the hair washing process, the dry and wet combing performance of the hair is good, and the hair can be maintained to be durably smooth after washing and caring. Secondly, the hair care composition and the hair care film are fresh and non-greasy after being used, and are suitable for people with various hair qualities including oily hair. In addition, the hair care composition and the hair care film can obviously enhance the toughness of the hair after long-term use.
In one embodiment of the invention, the silicone emulsion is an amino silicone oil emulsion that is a mixture of amodimethicone, cetrimide, and trideceth-10. Wherein the amino silicone oil emulsion has an active content of 35.0% and an amine value of 0.05% meq/g, and can effectively reduce the discoloration of the hair care composition and maintain stable color.
In one embodiment of the invention, the humectant is sodium hyaluronate, and the sodium hyaluronate is small-molecule sodium hyaluronate obtained by complexing reaction with a proper amount of cationic polymer, has high affinity, and can effectively improve the moisturizing effect of hair.
The invention also provides a hair care film which comprises the hair care composition.
In another embodiment of the present invention, the hair care film further comprises at least one of a fragrance, a preservative, and a chelating agent.
In one embodiment of the invention, the PH adjusting agent is citric acid.
The antiseptic comprises at least one of phenoxyethanol, DMDMH, imidazolidinyl urea, p-hydroxyacetophenone, MIT, and paraben.
The chelating agent is at least one of ethylenediamine tetraacetic acid, sodium methyl tartrate and ammonium citrate.
The preparation method of the hair care mask comprises the following steps:
weighing the thickening agent, the cationic surfactant and the pH regulator, adding the thickening agent, the cationic surfactant and the pH regulator into water preheated to 75-80 ℃, mixing and stirring for 8-20 minutes, and homogenizing for 1.5-3 minutes; in one embodiment of the present invention, the thickener in this step is an acrylic polymer;
adding the nonionic surfactant, mixing and stirring for 8-20 minutes, and homogenizing for 1.5-3 minutes;
adding a pre-prepared mixed solution of the thickening agent and water, stirring for 5-8 minutes, homogenizing for 2-5 minutes until the mixture is completely dissolved, and keeping the temperature at 75-80 ℃; in one embodiment of the present invention, the thickener in this step is any one or more of an acrylate polymer, hydroxyethyl fiber, and cetyl alcohol.
Stirring and defoaming for 12-18 minutes by vacuumizing, and maintaining constant temperature in the stirring process;
cooling to 35-45 ℃, adding the silicone oil, uniformly mixing, stirring for 8-12 minutes, and homogenizing for 2-5 minutes;
adding the organic silicon emulsion and the ester oil, stirring for 18-22 minutes, and homogenizing for 2-5 minutes;
adding the humectant, stirring for 18-22 minutes, and homogenizing for 1-3 minutes until the humectant is completely dissolved;
adding essence, preservative, chelating agent and water, and stirring for 2-5 minutes.
The effect of the hair care films of the present invention was verified by the following hair rinse performance measurement experiment, hair softness sensory evaluation experiment, and hair combing strength and smoothness test through several examples and comparative examples:
example 1:
the nursing hair mask comprises the following components in parts by mass: stearyl trimethyl ammonium chloride 3 parts; 1.0 part of polyglycerol fatty acid ester; 2.0 parts of amino silicone oil emulsion; 3.0 parts of cyclopentasiloxane; 1.2 parts of dioctyl carbonate; 2.0 parts of polymethacrylate polymer; 0.7 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Example 2:
the nursing hair mask comprises the following components in parts by mass: 5.0 parts of hexadecyl trimethyl ammonium chloride; 2.0 parts of polyglycerol fatty acid ester; 3.0 parts of amino silicone oil emulsion; 2.0 parts of cyclopentasiloxane; 0.5 part of dioctyl carbonate; 1.0 part of polymethacrylate polymer; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Example 3:
the nursing hair mask comprises the following components in parts by mass: 7.0 parts of hexadecyl trimethyl ammonium chloride; 0.8 part of polyglycerol fatty acid ester; 4.0 parts of amino silicone oil emulsion; 3.0 parts of cyclopentasiloxane; 0.8 part of dioctyl carbonate; 3.0 parts of polymethacrylate polymer; 1.0 part of cetyl alcohol; 2.0 parts of sodium hyaluronate; 0.02 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Comparative example 1:
the nursing hair mask comprises the following components in parts by mass: 5.0 parts of hexadecyl trimethyl ammonium chloride; 2.0 parts of polyglycerol fatty acid ester; 3.0 parts of amino silicone oil emulsion; 2.0 parts of cyclopentasiloxane; 0.5 part of dioctyl carbonate; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Comparative example 2:
the nursing hair mask comprises the following components in parts by mass: 2.0 parts of polyglycerol fatty acid ester; 3.0 parts of amino silicone oil emulsion; 2.0 parts of cyclopentasiloxane; 0.5 part of dioctyl carbonate; 1.0 part of polymethacrylate polymer; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Comparative example 3:
the nursing hair mask comprises the following components in parts by mass: 2.0 parts of polyglycerol fatty acid ester; 3.0 parts of amino silicone oil emulsion; 2.0 parts of cyclopentasiloxane; 0.5 part of dioctyl carbonate; 1.0 part of polymethacrylate polymer; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Comparative example 4:
the nursing hair mask comprises the following components in parts by mass: 5.0 parts of hexadecyl trimethyl ammonium chloride; 3.0 parts of amino silicone oil emulsion; 2.0 parts of cyclopentasiloxane; 0.5 part of dioctyl carbonate; 1.0 part of polymethacrylate polymer; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Comparative example 5:
the nursing hair mask comprises the following components in parts by mass: 5.0 parts of hexadecyl trimethyl ammonium chloride; 2.0 parts of polyglycerol fatty acid ester; 0.5 part of dioctyl carbonate; 1.0 part of polymethacrylate polymer; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Comparative example 6:
the nursing hair mask comprises the following components in parts by mass: 5.0 parts of hexadecyl trimethyl ammonium chloride; 2.0 parts of polyglycerol fatty acid ester; 2.0 parts of cyclopentasiloxane; 0.5 part of dioctyl carbonate; 1.0 part of polymethacrylate polymer; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Comparative example 7:
the nursing hair mask comprises the following components in parts by mass: 5.0 parts of hexadecyl trimethyl ammonium chloride; 2.0 parts of polyglycerol fatty acid ester; 3.0 parts of amino silicone oil emulsion; 2.0 parts of cyclopentasiloxane; 1.0 part of polymethacrylate polymer; 1.0 part of hydroxyethyl fiber; 0.8 part of sodium hyaluronate; 0.01 part of citric acid; 0.05 part of ethylenediamine tetraacetic acid; an appropriate amount of water.
Experiment one: determination of rinsing Properties
Selecting 7 bundles of hairs with the length of 10cm and the width of 1cm, wherein each bundle of hairs is divided into a group of example 1, example 2, example 3, comparative example 1, comparative example 2, comparative example 3 and comparative example 4, each group corresponds to the nursing hair mask using the examples and the comparative examples, and each experiment is carried out simultaneously;
after using the hair care films of examples 1 to 3 and comparative examples 1 to 4, each group of experimenters washed the hair under the same conditions (wherein the same conditions include the same conditions of water temperature, volume of water discharged per unit time, and time to start rinsing), and evaluated the rinsing performance of the hair care film used. Specifically, 5 times of washing is carried out under the same condition, and the 1 st to 5 th washed care hair mask solutions are respectively collected.
The viscosity of the care hair mask solution washed out by 1-5 times and the viscosity of the pure care hair mask are measured, the percentage of the viscosity reduction after each washing compared with the viscosity reduction after the last washing is calculated, and the statistical result is shown in table 1.
TABLE 1 statistical table for determination of rinsing properties
| Group of | 1 st flush down Percent (%) | 2 nd flushing descent Percent (%) | 3 rd flushing descending Percent (%) | 4 th washing descent Percent (%) | 5 th washing descent Percent (%) |
| Examples Group 1 | 78.1 | 52.3 | 50.4 | 59.1 | 71.3 |
| Examples 2 groups of | 80.6 | 51.2 | 49.8 | 57.5 | 73.1 |
| Examples Group 3 | 77.6 | 50.1 | 48.3 | 55.4 | 74.4 |
| Comparative example Group 1 | 51.3 | 31.2 | 35.7 | 40.6 | 68.7 |
| Comparative example 2 groups of | 56.7 | 35.1 | 37.5 | 43.2 | 70.6 |
| Comparative example Group 3 | 51.8 | 25.3 | 28.6 | 30.4 | 66.5 |
| Comparative example 4 groups of | 63.4 | 39.7 | 40.2 | 43.9 | 70.6 |
According to the experiments, the acrylic polymer with the proportion of the invention is used as the thickening agent to be compounded with the cationic compound, so that the viscosity of the hair care film can be reduced rapidly after each washing. Specifically, the hair care films of examples 1 to 3, which contain both a polymethacrylate polymer and a cationic surfactant, have the ability to lower the viscosity of the hair care film under each washing under the same condition, compared to the hair care film of comparative example 1, which contains only a cationic surfactant, the hair care film of comparative example 2, which contains only a polymethacrylate polymer, and the hair care film of comparative example 3, which does not contain a polymethacrylate polymer and does not contain a cationic surfactant, and thus, the hair care films can be washed efficiently, the residue of the hair care films can be reduced, and the scalp health can be protected effectively.
Meanwhile, the experiments show that the viscosity of the hair care film can be reduced rapidly after each washing by using the polyglycerol fatty acid ester with the proportion of the invention as the nonionic surfactant and the cationic surfactant together. Specifically, the care hair dressings of examples 1 to 3 containing a polyglycerin fatty acid ester were able to lower the viscosity of the care hair dressings under the same washing conditions each time, and thus, the hair was efficiently washed, as compared with the care hair dressings of comparative example 4 containing no polyglycerin fatty acid ester.
Experiment two: sensory evaluation experiment for hair softness
The oily hair quality groups were used as experimental subjects, 500 persons were used for each group, and the hair care films of examples 1 to 3 and comparative examples 5 to 7 were used for each group. After the hair care films of the examples 1-3 and the comparative examples 5-7 are used, the softness of wet-wash hair and the softness of dry-wash hair are evaluated in a sensory mode by each group of oily hair quality workers, wherein the value of each person is 1-5 points, 1 point represents very coarse, 5 points represents very smooth, and the larger the value, the more satisfied the experience of the experiencers is. The scores of each group of experimental subjects were counted to obtain the sensory evaluation of softness experience, which is shown in table 2.
TABLE 2 Hair softness sensory evaluation results statistics Table
| Group of | Mean hair smoothness score |
| EXAMPLE 1 group | 4.7 |
| EXAMPLE 2 group | 4.8 |
| EXAMPLE 3 group | 4.7 |
| Comparative example 5 group | 2.4 |
| Comparative example 6 group | 3.2 |
| Comparative example 7 group | 3.4 |
As can be seen from the above experiments, after the hair care films of examples 1, 2 and 3 were used, the hair of the experimenters was almost smooth as a whole, that is, the repaired hair had high softness. After the hair care film containing only partial ester oil is used by using the silicone-oil-free and silicone-free emulsion of the comparative example 5, the hair of the experimenter is generally favored to be frizzy; after using the hair care films of comparative example 6 above, which contained silicone oil and ester oil, but no silicone emulsion, the hair softness of the experimenters was only moderate; after the hair care film containing the silicone oil and the silicone emulsion in the comparative example 7 but not containing the ester oil is used, the softness of the hair of an experimenter is only on the middle and on the upper side, but has a large difference from the data of the groups of examples 1-3, and the fact that the hair care film adopting the embodiment of the invention can effectively help the oily hair users to maintain the softness of the hair by compounding the silicone emulsion, the silicone oil and the ester oil is shown.
Experiment three: the combing performance of the hair before and after using different hair care films was evaluated using a texture analyzer.
The instrument was used as a texture instrument SMS TA. XT PlusC. The specific experimental steps are as follows:
selecting 120 hair bundles with the length of 10cm and the width of 1cm, dividing the hair bundles into a group of 20 hair bundles, namely an example 1 group, an example 2 group, an example 3 group, a comparative example 5 group, a comparative example 6 group and a comparative example 7 group, wherein each group corresponds to the hair care film of the above example and comparative example, and each experiment is carried out simultaneously;
the hair of each of the groups of example 1, example 2, example 3, comparative example 5, comparative example 6 and comparative example 7 was wetted with clear water and tested by holding the hair with a hair combing device (A/HCR) to obtain combing strength and smoothness after rinsing with clear water;
2g of the hair care films of the corresponding example 1 group, example 2 group, example 3 group, comparative example 5 group, comparative example 6 group and comparative example 7 group were uniformly applied to the hair of each test hair bundle, and after gently rubbing the hair with both hands for 1 minute, the hair was rinsed with clean water and dried, and then the hair was held by a hair comb device (A/HCR) to test the combing strength and smoothness after using the hair care films of the corresponding example group or comparative example group.
The statistical data below in Table 3 indicate that the lower the smoothness value, the lower the combing strength, the more smooth and compliant.
TABLE 3 statistical Table of the results of combing Strength and smoothness of the hair
As can be seen from the experimental data, the hair after washing with the hair care films of the examples was significantly lower in combing strength, the average combing strength was reduced from 56.84g to 13.16g after using the hair care film of example 1 of the present invention, from 55.10g to 12.08g after using the hair care film of example 2 of the present invention, and from 54.74g to 12.10g after using the hair care film of example 3 of the present invention. After the hair care films of comparative examples 1-4 are used, the average combing strength is still over 35g, even close to 40g, and is greatly higher than that of hair after the hair care films of the embodiments of the invention are used. Similarly, the average smoothness of the hair care films of the examples of the invention is generally reduced from 233 g.soc to about 101-104 g.soc, while the average smoothness of the hair care films of the comparative examples is still about 140-150 g.soc.
Therefore, it can be seen that the hair care film using the embodiment of the invention can significantly enhance the toughness and the softness of the hair, the dry and wet combing performance of the hair is good, and the dryness and the frizz can be effectively improved.
In conclusion, the hair care composition and the hair care film can keep hair moist and smooth, are easy to wash, and can effectively protect the hair and scalp health.
The foregoing is only a partial embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (10)
1. The hair care composition is characterized by comprising the following components in parts by mass:
3-7 parts of a cationic surfactant;
0.2-7 parts of a nonionic surfactant;
2-5 parts of an organic silicon emulsion;
2-6 parts of silicone oil;
0.2-5 parts of ester oil;
2-10 parts of a thickening agent;
0.2-3 parts of a humectant;
0-0.5 part of a pH regulator;
wherein the thickening agent is an acrylate polymer.
2. The hair care composition according to claim 1, wherein the thickener is a polymethacrylate polymer.
3. The hair care composition of claim 1, wherein the cationic surfactant is selected from at least one of stearyltrimethylammonium chloride, distearyldimethylammonium chloride, stearamidopropyldimethylamine, PEG-2 oleylmethylammonium chloride, cocotrimethylammonium chloride, cetyltrimethylammonium chloride, behenyltrimethylammonium chloride.
4. The hair care composition according to claim 1, wherein the nonionic surfactant is a polyglyceryl fatty acid ester.
5. The hair care composition according to claim 4, wherein the polyglycerin fatty acid ester is obtained by reacting a fatty acid with glycerin having n.gtoreq.5.
6. The hair care composition according to claim 1, wherein the mass part ratio of the silicone oil to the silicone emulsion is (0.5-2): 1.
7. the hair care composition according to claim 1, wherein the ester oil is selected from at least one of dioctyl carbonate, 2-octyldodecanol myristate, isopropyl myristate, alkyl benzoate, isopropyl palmitate, butyl octanol salicylate, and cetyl ethylhexanoate.
8. The hair care composition according to claim 1, wherein the silicone emulsion is an aminosilicone emulsion mixed from amodimethicone, cetrimide and trideceth-10.
9. A hair care film comprising the hair care composition according to any one of claims 1 to 8.
10. The method of preparing a hair care film according to claim 9, comprising the steps of:
weighing the thickening agent, the cationic surfactant and the pH regulator, adding the thickening agent, the cationic surfactant and the pH regulator into preheated water, mixing and stirring, and homogenizing;
sequentially adding the mixed solution of the nonionic surfactant, the thickening agent and water, stirring, homogenizing, and keeping constant temperature;
stirring and defoaming are carried out by vacuumizing, and the stirring process is kept at a constant temperature;
cooling, sequentially adding the silicone oil, the organic silicon emulsion and the ester oil, mixing uniformly, stirring and homogenizing;
adding the humectant, stirring and homogenizing;
adding essence, antiseptic, chelating agent and water, and stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010747409.5A CN111759754A (en) | 2020-07-29 | 2020-07-29 | Hair care composition, hair care film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010747409.5A CN111759754A (en) | 2020-07-29 | 2020-07-29 | Hair care composition, hair care film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111759754A true CN111759754A (en) | 2020-10-13 |
Family
ID=72727818
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010747409.5A Pending CN111759754A (en) | 2020-07-29 | 2020-07-29 | Hair care composition, hair care film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111759754A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112190493A (en) * | 2020-10-19 | 2021-01-08 | 广州荃智美肤生物科技研究院有限公司 | Anhydrous transparent liquid head conditioning composition and preparation method thereof |
| CN112826763A (en) * | 2021-01-29 | 2021-05-25 | 上海一苓化妆品有限公司 | Hair mask with shape memory function and preparation method thereof |
| CN112932997A (en) * | 2020-10-21 | 2021-06-11 | 李平 | Wash-free shampoo film and preparation method thereof |
| CN114569497A (en) * | 2021-08-25 | 2022-06-03 | 中山中研化妆品有限公司 | Healthy nourishing hair mask and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5653969A (en) * | 1996-03-21 | 1997-08-05 | The Procter & Gamble Company | Low residue hair care compositions |
| CN1921824A (en) * | 2004-02-18 | 2007-02-28 | 威娜股份有限公司 | Hair-treatment agent comprising terpolymer from vinyl pyrrolidone, methacrylamide and vinyl imidazole and active ingredients and additives |
| CN102006852A (en) * | 2008-04-16 | 2011-04-06 | 宝洁公司 | Non-lathering personal care composition in the form of an article |
| US20120219517A1 (en) * | 2009-10-23 | 2012-08-30 | Dow Corning Corporation | Silicone compositions comprising a swollen silicone gel |
| CN111394192A (en) * | 2019-12-31 | 2020-07-10 | 纳爱斯浙江科技有限公司 | Mild and non-irritant full-food grade detergent composition and preparation method thereof |
-
2020
- 2020-07-29 CN CN202010747409.5A patent/CN111759754A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5653969A (en) * | 1996-03-21 | 1997-08-05 | The Procter & Gamble Company | Low residue hair care compositions |
| CN1921824A (en) * | 2004-02-18 | 2007-02-28 | 威娜股份有限公司 | Hair-treatment agent comprising terpolymer from vinyl pyrrolidone, methacrylamide and vinyl imidazole and active ingredients and additives |
| CN102006852A (en) * | 2008-04-16 | 2011-04-06 | 宝洁公司 | Non-lathering personal care composition in the form of an article |
| US20120219517A1 (en) * | 2009-10-23 | 2012-08-30 | Dow Corning Corporation | Silicone compositions comprising a swollen silicone gel |
| CN111394192A (en) * | 2019-12-31 | 2020-07-10 | 纳爱斯浙江科技有限公司 | Mild and non-irritant full-food grade detergent composition and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 广州市粉红格调美容用品有限公司: "艾丽素晴彩修护精华乳", 《国产普通化妆品备案信息》 * |
| 珠海市丝域生物科技有限公司: "丝域盈亮修护护理套装", 《国产普通化妆品备案信息》 * |
| 美蒂蔻思制药株式会社: ""黛丝恩致美 摩洛哥油护发素 头皮养护"", 《进口化妆品》 * |
| 裘炳毅: "《现代化妆品科学与技术 上》", 31 March 2016, 中国轻工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112190493A (en) * | 2020-10-19 | 2021-01-08 | 广州荃智美肤生物科技研究院有限公司 | Anhydrous transparent liquid head conditioning composition and preparation method thereof |
| CN112932997A (en) * | 2020-10-21 | 2021-06-11 | 李平 | Wash-free shampoo film and preparation method thereof |
| CN112826763A (en) * | 2021-01-29 | 2021-05-25 | 上海一苓化妆品有限公司 | Hair mask with shape memory function and preparation method thereof |
| CN114569497A (en) * | 2021-08-25 | 2022-06-03 | 中山中研化妆品有限公司 | Healthy nourishing hair mask and preparation method thereof |
| CN114569497B (en) * | 2021-08-25 | 2024-02-13 | 中山中研化妆品有限公司 | Healthy nourishing hair mask and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111759754A (en) | Hair care composition, hair care film and preparation method thereof | |
| CA2036444C (en) | Hair care composition and methods of treating hair | |
| US6740317B1 (en) | Hair care compositions and improved hair quality | |
| CA1229305A (en) | Neutralizing composition and method for hair waving and straightening | |
| EP0410659A2 (en) | Method and composition to impart improved conditioning properties to the hair | |
| MX2007004432A (en) | Hair care formulations comprising aminofunctional polyorganosiloxane. | |
| US20050142091A1 (en) | Hair cosmetic compositions | |
| SE457601B (en) | HAIR CONDITIONING PREPARATIONS AND PROCEDURES FOR TREATING HER WITH THESE PREPARATIONS | |
| DE102006012707A1 (en) | conditioner | |
| JPH04108725A (en) | Hair cosmetic | |
| CN111821220A (en) | Hair care composition, repairing hair film and preparation method thereof | |
| JP6484029B2 (en) | Hair cosmetics | |
| WO2010046119A2 (en) | Synergistic mixtures of a cationic amino silicone terpolymer and another silicone | |
| TWI826462B (en) | hair cosmetics | |
| CN112972303A (en) | Hair care composition, hair care film and preparation method thereof | |
| TWI821308B (en) | Methods to prevent hair or fiber tangles | |
| JP4606624B2 (en) | Hair cosmetics | |
| KR20130049305A (en) | Self-exothermic hair conditioning composition | |
| JP2549554B2 (en) | Hair treatment agent | |
| JPH04230615A (en) | Hair cosmetic | |
| CN115887256A (en) | Application of batyl alcohol in hair washing and caring products and hair washing and caring products containing batyl alcohol | |
| WO2021104786A1 (en) | A conditioning composition | |
| CN115969726A (en) | Multi-effect composition, shampoo and preparation method thereof | |
| JP2019214570A (en) | Hair cosmetic | |
| KR100839723B1 (en) | A hair conditioning composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20201013 |