CN111748426A - Pellet for laundry detergent and preparation method thereof - Google Patents
Pellet for laundry detergent and preparation method thereof Download PDFInfo
- Publication number
- CN111748426A CN111748426A CN202010650445.XA CN202010650445A CN111748426A CN 111748426 A CN111748426 A CN 111748426A CN 202010650445 A CN202010650445 A CN 202010650445A CN 111748426 A CN111748426 A CN 111748426A
- Authority
- CN
- China
- Prior art keywords
- parts
- liquid
- pellet
- laundry detergent
- coating layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/003—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic followed by coating of the granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/14—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic in rotating dishes or pans
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The pellet for the laundry detergent comprises a pellet core and a coating layer for coating the pellet core, wherein the coating layer comprises the following raw materials in parts by weight: 5-20 parts of high-carbon fatty alcohol, 5-30 parts of microcrystalline wax, 20-50 parts of polyethylene glycol and 5-20 parts of hydrogenated castor oil, wherein the sum of the contents of the high-carbon fatty alcohol and the microcrystalline wax is 5-7 times of the content of the hydrogenated castor oil. According to the invention, the components and the proportion of the pellet coating layer are adjusted, so that the coating layer can stably exist in the laundry detergent environment, and the pellet coating layer is prevented from being dissolved and damaged by the laundry detergent after being stored in the laundry detergent for a period of time; and when the pellet core is cleaned, under the water environment and the impact of water flow, the coating layer can be partially or completely damaged, and the functional auxiliary agent in the pellet core is released to improve the washing effect.
Description
Technical Field
The invention relates to the field of washing products, in particular to a pellet for laundry detergent and a preparation process thereof.
Background
Washing powder, soap powder and laundry detergent are common washing products in life. In washing, people usually add functional aids such as bactericides, fragrance-retaining beads, enzyme preparations, fabric conditioners and the like additionally to improve washing and washing-assistant effects and effectively wash specific types of clothes.
In order to achieve the washing effect, a plurality of auxiliary agents are used, and the first way is to use a plurality of products, for example, when a consumer wants to sterilize and deodorize and soften clothes, three products, namely a laundry detergent, a bactericide and a softener, are needed to achieve the effect.
The second mode is that the pellet core made of various functional auxiliary agents is wrapped in the pellet structure. When the washing product is stored, the functional auxiliary agent is wrapped in the coating layer, so that the direct contact between the functional auxiliary agent and the washing product is effectively avoided, and the influence on the washing effect caused by the reaction of the components with incompatibility is prevented. When the washing article is used, the coating layer is dissolved and cracked when clothes are washed, and the internal functional auxiliary agent is contacted with the fabric to generate a specific function and improve the washing and washing assisting effects.
Patent CN108330034A discloses a pellet particle added in laundry soap, which uses polyvinyl chloride, polyvinyl alcohol, polyethylene glycol and other substances as heat insulation filler, and combines with binder and pigment to form a coating layer, so that protease enzyme inside the coating layer can be stably present in the coating layer, and when the washing product is used, the coating layer is peeled off to release the enzyme, thereby improving the decontamination capability. Patent CN102433225B discloses an alkaline protease coated pellet, wherein the coating layer of the pellet mainly adopts dextrin, starch and bean powder, the mixing uniformity with washing powder is good, the dissolving speed is high, the storage period is long, and the activity loss of the functional auxiliary agent in the pellet is small.
In the prior art, the coating layer of the pellet is mainly applied to washing powder and cleaning soap. Washing powders and soaps are solid environments and require a coating layer that is isolated in storage and rapidly dissolved in the rinse state. However, when the pellets are applied to a laundry detergent, the laundry detergent is a liquid environment, which can damage the coating layer, resulting in direct contact between the pellet core and the laundry detergent during storage, resulting in generation of suspended substances in the laundry detergent, loss of activity of functional auxiliaries, and reduction of washing or washing-assistant effects.
Disclosure of Invention
One object of the invention is to provide a pellet for a laundry detergent, which enables a coating layer to stably exist in a laundry detergent environment by adjusting components and proportion of the coating layer, and avoids the dissolution and damage of the pellet coating layer by the laundry detergent after the pellet coating layer is stored in the laundry detergent for a period of time; and when the pellet core is cleaned, the coating layer can be partially or completely damaged under the dilution of a liquid environment and the impact of water flow, and functional auxiliary agents in the pellet core are released to improve the washing effect.
The purpose is realized by the following technical scheme:
the pellet for the laundry detergent comprises a pellet core and a coating layer for coating the pellet core, wherein the coating layer comprises the following raw materials in parts by weight: 5-20 parts of high-carbon fatty alcohol, 5-30 parts of microcrystalline wax, 20-50 parts of polyethylene glycol and 5-20 parts of hydrogenated castor oil.
In the technical scheme, the structure of the pellet is the same as that in the prior art, and the pellet comprises a pellet core and a coating layer, wherein the coating layer coats the pellet core in the pellet core so as to isolate the pellet core from the external space. In one or more embodiments, the mass of the pellet core accounts for 30-80% of the total mass of the pellet, and the mass of the coating layer accounts for 20-70% of the total mass of the pellet.
The differences from the prior art are the components of the coating layer and the content of the components. In the technical scheme, the pellet comprises 5-20 parts of high-carbon fatty alcohol, 5-30 parts of microcrystalline wax, 20-50 parts of polyethylene glycol, 5-20 parts of hydrogenated castor oil and impurities. Wherein the higher fatty alcohol is an aliphatic alcohol with a 12-22 carbon atom chain. Through the components and the content, the coating layer can keep stable structure in the laundry detergent and avoid the contact of the laundry detergent and the pill core, thereby avoiding the generation of white floccule after the contact of the cationic surfactant and the anionic surfactant, resulting in the instability of the laundry detergent system and the layering of the laundry detergent.
In some embodiments, the coating layer further comprises a colorant, and the colorant is 0.1-5 parts by weight. The colorant is one or more selected from red, green, purple, blue, orange, yellow and the like.
As a preferable embodiment of the coating layer in the invention, the sum of the contents of the higher fatty alcohol and the microcrystalline wax is 5-7 times of the content of the hydrogenated castor oil. When the content of the hydrogenated castor oil in the coating layer is low and the content of the higher fatty alcohol and the microcrystalline wax is high, the coating layer can keep higher stability for a longer time to isolate the pellet core from the laundry detergent, but the coating layer is not easy to damage in the cleaning process, and part of intact pellets can still remain after the cleaning is finished; when the content of the hydrogenated castor oil in the coating layer is high and the content of the higher fatty alcohol and the microcrystalline wax is low, the coating layer can be completely damaged in the cleaning process, but the storage time is short, and a small amount of floccules are generated in the laundry detergent after the laundry detergent is stored for a long time. The inventor finds that when the sum of the weight of the higher fatty alcohol and the microcrystalline wax is 5-7 times of the weight of the hydrogenated castor oil through experiments, the coating layer can be stored in the laundry detergent for a long enough time, and can be quickly damaged under the impact and stirring action of water flow, so that the pill core part is released.
Further, the pellet core comprises the following raw materials in parts by weight: 30-50 parts of diluent, 2-10 parts of adhesive, 20-50 parts of disintegrating agent, 0.1-5 parts of essence and 3-20 parts of bactericide. Through the components and the content, the pill core can be dissolved more quickly after contacting with water flow, and meanwhile, the essence and the bactericide serving as functional auxiliaries can play a role in removing peculiar smell and sterilizing, so that the washing effect is improved.
Further, the bactericide is selected from one or more of dodecyl trimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium chloride, tetradecyl trimethyl ammonium chloride, tetradecyl dimethyl benzyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide and tetradecyl dimethyl benzyl ammonium bromide.
Further, the disintegrating agent is selected from one or more of sodium carboxymethyl starch, microcrystalline cellulose and low-substituted hydroxypropyl methyl cellulose.
Further, the adhesive is selected from one or more of hydroxypropyl methyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl cellulose, chitosan, cyclodextrin and sodium alginate.
Further, the diluent is one or more of lactose, sucrose and starch.
The invention also aims to provide a preparation process of the pellets for the laundry detergent, which comprises the steps of adding the components into a disc granulator according to a specific proportion and sequence, and then sequentially forming a pellet core and a coating layer to finally obtain the pellets suitable for the laundry detergent system.
The purpose is realized by the following technical scheme:
a preparation process of a pellet for a laundry detergent comprises the following steps:
preparing a pill core;
pouring the prepared pellet cores into a disc granulating device;
preparing a coating solution, wherein the coating solution comprises the following raw materials in parts by weight: 5-20 parts of high-carbon fatty alcohol, 5-30 parts of microcrystalline wax, 20-50 parts of polyethylene glycol, 5-20 parts of hydrogenated castor oil and 50-200 parts of solvent;
and starting a disc granulation device, spraying coating liquid, forming a coating layer on the surface of the pellet core, and drying to obtain the pellet.
In the above steps, the step of preparing the pellet core comprises the following steps:
pouring 30-50 parts by weight of diluent, 2-10 parts by weight of adhesive and 20-50 parts by weight of disintegrating agent into a disc granulating device;
dissolving 0.1-5 parts by weight of essence and 3-20 parts by weight of bactericide in 30-100 parts by weight of wetting agent to form a spraying liquid;
after the positions of the liquid spraying mechanism and the liquid control mechanism are adjusted according to the quantity of the pill cores, starting a disc granulation device for granulation until the size of the pill cores reaches a preset size;
drying the pellet cores and screening the pellet cores with qualified sizes.
In the above step, the higher fatty alcohol is an aliphatic alcohol with a 12-22 carbon atom chain; the solvent is one of ethyl acetate, petroleum ether, chloroform, benzene and toluene. Preferably, the sum of the contents of the higher fatty alcohol and the microcrystalline wax is 5-7 times of the content of the hydrogenated castor oil.
In some embodiments, the coating solution further comprises 0.1-5 parts by weight of a colorant. The colorant is one or more selected from red, green, purple, blue, orange, yellow and the like.
Further, the bactericide is selected from one or more of dodecyl trimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium chloride, tetradecyl trimethyl ammonium chloride, tetradecyl dimethyl benzyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide and tetradecyl dimethyl benzyl ammonium bromide.
Further, the disintegrating agent is selected from one or more of sodium carboxymethyl starch, microcrystalline cellulose and low-substituted hydroxypropyl methyl cellulose.
Further, the adhesive is selected from one or more of hydroxypropyl methyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl cellulose, chitosan, cyclodextrin and sodium alginate.
Further, the diluent is one or more of lactose, sucrose and starch.
Further, the wetting agent is water, ethanol or a mixture of the two.
As a preferred embodiment of the pellet preparation process, the structure of the disc granulation device is optimized by the process, so that the spraying position and the spraying amount of the spraying liquid can be adjusted according to requirements in the preparation process, the pellets with different preparation amounts can be uniformly sprayed, the conditions of low pellet quality, uneven coating layer thickness and the like caused by over wetting of local pellets are avoided, the product quality is improved, and the uniformity of the coating layer thickness is ensured.
The disc granulation device comprises a base, wherein a large disc and a liquid spraying system are arranged on the base, the liquid spraying system comprises a liquid supply platform, a first driving device and a cylinder body are installed on the liquid supply platform, an air inlet pipe and a liquid inlet pipe are arranged on the cylinder body, the air inlet pipe is used for introducing air into the cylinder body, and the liquid inlet pipe is used for introducing spraying liquid or coating liquid into the cylinder body; the output end of the first driving device is connected with a liquid supply pipe, the liquid supply pipe is of a hollow structure, one end, far away from the first driving device, of the liquid supply pipe movably penetrates through the cylinder body and penetrates through the bottom of the large disc, a nozzle located in the large disc is arranged on the liquid supply pipe, a first through hole is formed in the part, located in the cylinder body, of the liquid supply pipe, the first through hole is communicated with the interior of the cylinder body and the interior of the liquid supply pipe, and spraying liquid or coating liquid in the cylinder body is sprayed into the large disc through the first through hole, the liquid supply pipe and the nozzle in sequence under the pressure of gas; the both sides of base are provided with the mounting bracket, be provided with the crossbeam on the mounting bracket, the bottom of crossbeam is provided with first pneumatic cylinder and second pneumatic cylinder, the lid is installed to the bottom of first pneumatic cylinder, the lid is used for the opening end of closed deep bid, the bottom activity of second pneumatic cylinder runs through the lid, and is connected with accuse liquid mechanism, accuse liquid mechanism is used for adjusting the spray angle of nozzle.
In the technical scheme, the disc granulating device comprises a base in the prior art and a large disc which is arranged on the base and can adjust the angle of the large disc. The improvement lies in the hydrojet system, through the improvement to the hydrojet system for the nozzle can be according to the actual movement track regulation adjustment hydrojet of granule in the deep bid direction and intensity, avoids different volumes, when the granule movement track of size changes under the different rotational speeds of deep bid, and the liquid sprays local granule that uneven leads to and wets, the adhesion on the transfer unit, is unfavorable for the drying, and the inhomogeneous problem of coating layer thickness.
Specifically, the liquid spraying system comprises a liquid supply platform, and the liquid supply platform is arranged on the base. In some embodiments, the angle of the large disc is not adjustable, and the liquid supply platform is parallel to the bottom surface of the large disc; in some embodiments, the angle of the large disk and the angle of the liquid supply platform can be adjusted, and the large disk and the liquid supply platform move synchronously and are always kept parallel.
The liquid supply platform is provided with a first driving device and a cylinder body, an air inlet pipe arranged on the cylinder body is used for introducing air into the cylinder body, and preferably, the air inlet pipe is connected with an inert gas source so as to ensure that all components are in an inert atmosphere during preparation of the pellets. The feed liquor pipe that sets up on the cylinder body is arranged in letting in spray liquid or coating liquid to the cylinder body, and under gaseous promotion, liquid in the cylinder body is pressed in the feed pipe through first through-hole in, removes the one end that keeps away from first drive arrangement to the feed pipe in the feed pipe is inside, and the blowout is finally followed in the nozzle.
In this technical scheme, the outer wall of feed pipe and the bottom surface fixed connection of deep bid, also can rotate through the large bid of feed pipe drive by first drive arrangement, and the rotational speed of deep bid is the same with feed pipe, nozzle.
The mounting bracket upper bracket that the both sides of base set up is equipped with the crossbeam, the bottom of crossbeam is provided with first pneumatic cylinder and second pneumatic cylinder. Wherein, the lid is installed to the bottom of first pneumatic cylinder, when the piston rod extension of first pneumatic cylinder or shorten, can adjust the interval between lid and the big dish of its below, and then open or close the open end of big dish. The bottom activity of second pneumatic cylinder runs through the lid, is connected with accuse hydraulic mechanism on the bottom, accuse hydraulic mechanism can remove along the axis direction of second pneumatic cylinder in the lid is inside, and then shelters from the nozzle totally or partially for the nozzle can spray liquid in the deep bid when rotatory certain angle, and is sheltered from when rotatory certain angle by accuse hydraulic mechanism and seals.
When the device is used, the angle between the large disc and the liquid supply platform is adjusted, and after particles are poured into the large disc, the position of the cover body is adjusted by adjusting the first hydraulic cylinder so as to close the open end of the large disc; then pouring the prepared spraying liquid or coating liquid into the cylinder body, and starting the first driving device to drive the large disc and the nozzle to rotate; and (3) starting the air source, pressing the liquid in the cylinder body into the liquid supply pipe after the air enters the cylinder body, and finally spraying the liquid into the large plate through the nozzle. In the deep bid rotation process, can observe the formation condition of inside granule through observation window on the lid, can adjust accuse liquid mechanism height according to the size and the humidity of granule, with the nozzle is sheltered from totally or partially, realize on the whole moving trajectory of granule, the granule in partial region receives liquid spray, the granule in partial region does not receive liquid spray, can adjust liquid spray angle and liquid spray volume according to the humidity of granule, thereby the degree of consistency and the product quality of coating layer, avoid partial granule too moist and the adhesion at conveyer belt or bin outlet.
As a preferred embodiment of the liquid control mechanism in the disc granulation apparatus of the present invention, the liquid control mechanism includes a housing, a plurality of rows of second through holes are formed in a side wall of the housing from top to bottom, and the number and/or size of the second through holes in two adjacent rows are different. The structure enables the plurality of rows of second through holes arranged from top to bottom on the shell to cover different angles. When the piston rod of the second hydraulic cylinder drives the shell to move up and down, the nozzle can be located at the same height with the second through holes in different rows, and therefore the control of the closing angle and the opening angle of the nozzle can be achieved by adjusting the relative height of the liquid control mechanism and the nozzle. Preferably, the number and size of the through holes of each row of second through holes are different, so as to provide a more flexible control mode.
Compared with the prior art, the invention has the following advantages and beneficial effects:
1. according to the invention, the components and the proportion of the pellet coating layer are adjusted, so that the coating layer can stably exist in the laundry detergent environment, and the pellet coating layer is prevented from being dissolved and damaged by the laundry detergent after being stored in the laundry detergent for a period of time; in addition, during cleaning, under the water environment and the impact of water flow, the coating layer can be partially or completely damaged, and functional auxiliary agents in the pill cores are released to improve the washing effect;
2. in the coating layer, the sum of the weight of the high-carbon fatty alcohol and the microcrystalline wax is 5-7 times of the weight of the hydrogenated castor oil, and the coating layer can be stored in the laundry detergent for a long enough time and can be quickly damaged under the impact and stirring action of water flow, so that a pill core part is released;
3. according to the invention, the components are added into a disc granulator according to a specific proportion and sequence to form a pellet core and a coating layer in sequence, and finally the pellet suitable for a laundry detergent system is obtained.
4. According to the pellet preparation process, the disc granulation device is optimized, so that the spraying position and the spraying amount of the spraying liquid can be adjusted according to requirements in the preparation process, the pellets with different preparation amounts can be uniformly sprayed, the conditions that the quality of the pellets is low and the thickness of a coating layer is not uniform due to over wetting of local pellets are avoided, the product quality is improved, and the thickness of the coating layer is uniform;
5. in the rotating process of the large disc, the forming condition of internal particles can be observed through the observation window on the cover body, the height of the liquid control mechanism can be adjusted according to the size and the wetting degree of the particles so as to completely or partially shield the nozzle, the particles in partial regions are sprayed by liquid on the whole moving track of the particles, the particles in partial regions are not sprayed by the liquid, and the liquid spraying angle and the liquid spraying amount can be adjusted according to the wetting degree of the particles, so that the uniformity and the product quality of a coating layer are improved, and the phenomenon that partial particles are adhered to a conveying belt or a discharge port due to over wetting is avoided;
6. the nozzle and the second through holes in different layers are adjusted to be at the same height, the aim of controlling the closing angle and the opening angle of the nozzle is fulfilled by adjusting the relative height of the liquid control mechanism and the nozzle, and meanwhile, the number and the size of the through holes of the second through holes in each layer are different, so that a more flexible control mode is provided;
7. the nozzle of the liquid spraying system adopts a mode of combining the rigid nozzle and the flexible nozzle, so that the second nozzle is deformed and closed when the nozzle contacts the shell of the liquid control mechanism in the rotating process, liquid cannot be sprayed out of the second nozzle, the second nozzle is restored to the original state when the nozzle does not contact the liquid control mechanism, the liquid is sprayed out of the second nozzle, and the nozzle is further controlled to spray liquid to a specific area on the moving track of particles;
8. the pellet core comprises functional auxiliary agents such as essence and bactericide, and can contact with fabrics or clothes to play a role in removing peculiar smell and sterilizing during cleaning, so that the washing effect is improved.
Drawings
The accompanying drawings, which are included to provide a further understanding of the embodiments of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the principles of the invention. In the drawings:
FIG. 1 is a schematic diagram of the structure of a pellet in an embodiment of the invention;
FIG. 2 is a block flow diagram of a pellet preparation process in an embodiment of the invention;
FIG. 3 is a schematic structural diagram of the main body of a disc granulating apparatus used in the pellet preparation process according to an embodiment of the present invention;
FIG. 4 is a schematic structural diagram of a cover bracket of a disc granulating apparatus according to an embodiment of the present invention;
FIG. 5 is a schematic view of a liquid spraying system of a disk granulating apparatus according to an embodiment of the present invention;
FIG. 6 is a schematic cross-sectional view of a nozzle of a disk granulating apparatus according to an embodiment of the present invention;
FIG. 7 is a schematic structural diagram of a liquid control mechanism of a disc granulating apparatus according to an embodiment of the present invention;
FIG. 8 is a schematic view of a nozzle of a disc granulating apparatus without being shielded by a casing of a liquid control mechanism according to an embodiment of the present invention;
fig. 9 is a schematic view of a disc granulating apparatus according to an embodiment of the present invention, in which a nozzle is shielded by a liquid control mechanism casing.
Reference numbers and corresponding part names in the drawings:
1-pill core, 2-coating layer, 3-base, 4-large disc, 5-cover, 6-first driving device, 7-mounting frame, 8-beam, 9-second driving device, 10-first hydraulic cylinder, 11-scraper, 12-liquid supply platform, 13-liquid spraying mechanism, 131-first through hole, 132-first nozzle, 133-second nozzle, 134-liquid supply pipe, 14-cylinder body, 141-air inlet pipe, 142-liquid inlet pipe, 15-second hydraulic cylinder, 151-piston rod, 16-liquid control mechanism, 161-shell and 162-second through hole.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to examples and accompanying drawings, and the exemplary embodiments and descriptions thereof are only used for explaining the present invention and are not meant to limit the present invention.
In the description of the present invention, it is to be understood that the terms "front", "rear", "left", "right", "upper", "lower", "vertical", "horizontal", "high", "low", "inner", "outer", etc. indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplicity of description, and do not indicate or imply that the referenced devices or elements must have a particular orientation, be constructed and operated in a particular orientation, and therefore, are not to be construed as limiting the scope of the present invention.
All of the starting materials of the present invention, without particular limitation as to their source, are commercially available or can be prepared according to conventional methods well known to those skilled in the art.
All the raw materials of the present invention are not particularly limited in their purity, and the present invention preferably employs purity requirements that are conventional in the field of analytical purification or the preparation of washing products.
All the raw materials, the marks and the acronyms thereof belong to the conventional marks and the acronyms in the field, each mark and acronym is clear and definite in the field of related application, and the raw materials can be purchased from the market or prepared by the conventional method by the technical staff in the field according to the marks, the acronyms and the corresponding application.
[ example 1 ]
Preparation of micropellets for laundry detergent M1:
weighing 30 parts of lactose, 10 parts of sucrose, 2 parts of carboxymethyl cellulose, 2 parts of sodium alginate and 20 parts of microcrystalline cellulose, and pouring into a disc granulating device; dissolving 3 parts of essence and 10 parts of dodecyl trimethyl ammonium chloride in 40 parts of wetting agent to form a spraying liquid, wherein the wetting agent is ethanol: water 1: 1; setting various parameters of a disc granulating device, wherein the air supply parameter is set to be 15Hz, the rotating speed of a large disc is 200rpm, the liquid spraying frequency is 20Hz, and after the setting is finished, sequentially starting an air supply switch, a rotating disc and a liquid supply switch; when the particle size reaches about 100 meshes, stopping spraying liquid; opening the hatch door to discharge, then placing the pellets into a fluidized bed dryer to be dried, controlling the temperature at 60 ℃, and preserving the heat for 30 min; sieving with 80 mesh sieve, and pouring the micropellets with 80 meshes into a disc granulating device; adding 50 parts of coating agent and 0.2 part of coloring agent into 50 parts of toluene, heating and stirring to form a coating solution, starting a spray liquid for coating, and continuously keeping for 5min after spraying is finished, wherein the coating agent comprises 15 parts of high-carbon fatty alcohol, 10 parts of microcrystalline wax, 20 parts of polyethylene glycol and 5 parts of hydrogenated castor oil, and the coloring agent is selected from one or more of red, green, purple, blue, orange, yellow and other pigments; and (3) screening the pellets sprayed with the coating solution by using a 60-80-mesh screen, and collecting the pellets of 60-80 meshes to obtain pellets M1. The sum of the contents of higher fatty alcohols and microcrystalline wax in the coating layer of pellet M1 was about 5.4 times the content of hydrogenated castor oil.
[ example 2 ]
Preparation of micropellets for laundry detergent M2:
weighing 30 parts of lactose, 20 parts of sucrose, 5 parts of carboxymethyl cellulose, 2 parts of sodium alginate and 40 parts of microcrystalline cellulose, and pouring into a disc granulating device; dissolving 0.5 part of essence and 5 parts of tetradecyl dimethyl benzyl ammonium bromide in 60 parts of wetting agent to form spraying liquid, wherein the wetting agent is deionized water; setting various parameters of a disc granulating device, wherein air supply parameters are set to be 25Hz, the rotating speed of a large disc is 500rpm, the liquid spraying frequency is 40Hz, and after the setting is finished, sequentially starting an air supply switch, a rotating disc and a liquid supply switch; when the particle size reaches about 80 meshes, stopping spraying liquid; opening the hatch door to discharge, then placing the pellets into a boiling type dryer to be dried, controlling the temperature at 70 ℃, and preserving the heat for 40 min; sieving with 80 mesh sieve, and pouring the micropellets with 80 meshes into a disc granulating device; adding 50 parts of coating agent and 5 parts of coloring agent into 100 parts of toluene, heating and stirring to form a coating solution, starting a spray liquid for coating, and continuously keeping for 5min after spraying is finished, wherein the coating agent comprises 10 parts of high-carbon fatty alcohol, 10 parts of microcrystalline wax, 20 parts of polyethylene glycol and 10 parts of hydrogenated castor oil, and the coloring agent is selected from one or more of red, green, purple, blue, orange, yellow and other pigments; and (3) screening the pellets sprayed with the coating solution by using a 60-80-mesh screen, and collecting the pellets of 60-80 meshes to obtain pellets M2. The sum of the contents of higher fatty alcohols and microcrystalline wax in the coating layer of pellet M2 was about 2.1 times the content of hydrogenated castor oil.
[ example 3 ]
Preparation of micropellets for laundry detergent M3:
weighing 20 parts of lactose, 10 parts of sucrose, 1 part of carboxymethyl cellulose, 5 parts of sodium alginate, 20 parts of microcrystalline cellulose and 20 parts of sodium carboxymethyl starch, and pouring into a disc granulating device; dissolving 5 parts of essence and 3 parts of tetradecyl dimethyl benzyl ammonium chloride in 50 parts of wetting agent to form spraying liquid, wherein the wetting agent is ethanol; setting various parameters of a disc granulating device, wherein air supply parameters are set to be 30Hz, the rotating speed of a large disc is 800rpm, the liquid spraying frequency is 60Hz, and after the setting is finished, sequentially starting an air supply switch, a rotating disc and a liquid supply switch; when the particle size reaches about 80 meshes, stopping spraying liquid; opening the hatch door to discharge, then placing the pellets into a boiling type dryer to be dried, controlling the temperature at 70 ℃, and preserving the heat for 40 min; sieving with 80 mesh sieve, and pouring the micropellets with 80 meshes into a disc granulating device; adding 100 parts of coating agent and 2 parts of coloring agent into 150 parts of ethyl acetate, heating and stirring to form a coating solution, starting a spray liquid for coating, and continuously keeping for 10min after spraying is finished, wherein the coating agent comprises 35 parts of high-carbon fatty alcohol, 30 parts of microcrystalline wax, 25 parts of polyethylene glycol and 10 parts of hydrogenated castor oil, and the coloring agent is selected from one or more of red, green, purple, blue, orange, yellow and other pigments; and (3) screening the pellets sprayed with the coating solution by using a 60-80-mesh screen, and collecting the pellets of 60-80 meshes to obtain pellets M3. The sum of the contents of higher fatty alcohols and microcrystalline wax in the coating layer of pellet M3 was about 6.7 times the content of hydrogenated castor oil.
[ example 4 ]
Preparation of micropellets for laundry detergent M4:
weighing 20 parts of lactose, 20 parts of starch, 2 parts of carboxymethyl cellulose, 2 parts of sodium alginate, 40 parts of microcrystalline cellulose and 10 parts of sodium carboxymethyl starch, and pouring into a disc granulating device; dissolving 0.1 part of essence and 15 parts of tetradecyltrimethyl ammonium chloride in 70 parts of a wetting agent to form a spraying solution, wherein the wetting agent is deionized water: ethanol ═ 2: 1; setting various parameters of a disc granulating device, wherein air supply parameters are set to be 20Hz, the rotating speed of a large disc is 300rpm, the liquid spraying frequency is 30Hz, and after the setting is finished, sequentially starting an air supply switch, a rotating disc and a liquid supply switch; when the particle size reaches about 80 meshes, stopping spraying liquid; opening the hatch door to discharge, then placing the pellets into a boiling type dryer to be dried, controlling the temperature at 60 ℃, and preserving the heat for 40 min; sieving with 80 mesh sieve, and pouring the micropellets with 80 meshes into a disc granulating device; adding 70 parts of coating agent and 1 part of coloring agent into 120 parts of ethyl acetate, heating and stirring to form a coating solution, starting a spray liquid for coating, and continuously keeping for 10min after spraying is finished, wherein the coating agent comprises 25 parts of high-carbon fatty alcohol, 20 parts of microcrystalline wax, 20 parts of polyethylene glycol and 5 parts of hydrogenated castor oil, and the coloring agent is selected from one or more of red, green, purple, blue, orange, yellow and other pigments; and (3) screening the pellets sprayed with the coating solution by using a 60-80-mesh screen, and collecting the pellets of 60-80 meshes to obtain pellets M4. The sum of the contents of higher fatty alcohols and microcrystalline wax in the coating layer of pellet M4 was about 11.2 times the content of hydrogenated castor oil.
[ example 5 ]
And (3) testing the stability of the pellets:
and (3) adding 5 parts of acetic acid bacteria cellulose into 100 parts of the commercially available laundry detergent A, stirring at the rotating speed of 1000rpm for 20 minutes to obtain a test laundry detergent environment, respectively adding the pellets M1-M4 into the laundry detergent, and uniformly stirring to obtain the laundry detergents D1-D4.
The laundry liquids D1-D4 were placed in environment 1, environment 2 for 7 days and 14 days. Wherein the environment 1 is an oven at 40 +/-2 ℃, and the environment 2 is a refrigerator at-5 +/-2 ℃. And (3) pouring the liquid laundry detergents D1-D4 into a washing machine for washing for 1 hour, wherein the volume of clothes accounts for one third of the total volume of the washing drum, the rotating speed of the washing drum is 800rpm, and sampling to detect whether unbroken pellets exist in the washing liquid. The test results are shown in table 1:
table 1 test results of each laundry detergent in different environments
As can be seen from Table 1, the liquid laundry detergents D1-D4 can be kept in a clear and transparent state for more than 7 days in the environment 1 and the environment 2, the micro-pills M1-M4 are kept to be uniformly suspended without sediment, and the liquid laundry detergent system has good stability. In the cleaning process, under the stirring of water flow and the friction of clothes, the coating layer is damaged and dissolved, the coating layer of part or all of the pellets is broken, and functional additives such as essence, bactericide and the like enter the cleaning liquid to play a role in removing peculiar smell and sterilizing.
As can be seen from table 1, when the sum of the contents of the higher fatty alcohol and the microcrystalline wax in the coating layer is 5 to 7 times the content of the hydrogenated castor oil, the pellets can not only maintain stability for 14 days in at least environment 1 and environment 2, but also can be rapidly broken during the cleaning process. When the content is less than 5 times, after D2 is stored in environment 1 and environment 2 for 14 days, the coating layer of part of the pellets can be cracked, so that the laundry detergent is contacted with the pellet cores, and white floccules are generated; when this content is greater than 7 times, D4 can be stored for 14 days in both environment 1 and environment 2, but unbroken pellets can still be found in randomly sampled wash liquid after 1 hour of washing. Therefore, when the sum of the contents of the higher fatty alcohol and the microcrystalline wax is 5-7 times of the content of the hydrogenated castor oil, the coating layer can be stored in the laundry detergent for a long time, and can be quickly damaged under the impact and stirring action of water flow, so that the pill core part is released.
[ example 6 ]
As shown in fig. 3 to 9, on the basis of the above embodiments, the disc granulation apparatus includes a base 3, a large disc 4 and a liquid spraying system are disposed on the base 3, the liquid spraying system includes a liquid supply platform 12, a first driving device 6 and a cylinder 14 are mounted on the liquid supply platform 12, a gas inlet pipe 141 and a liquid inlet pipe 142 are disposed on the cylinder 14, the gas inlet pipe 141 is used for introducing gas into the cylinder 14, and the liquid inlet pipe 142 is used for introducing spraying liquid or coating liquid into the cylinder 14; the output end of the first driving device 6 is connected with a liquid supply pipe 134, the liquid supply pipe 134 is of a hollow structure, one end, far away from the first driving device 6, of the liquid supply pipe 134 movably penetrates through the cylinder body 14 and penetrates through the bottom of the large disc 4, a nozzle located in the large disc 4 is arranged on the liquid supply pipe 134, a first through hole 131 is formed in the part, located in the cylinder body 14, of the liquid supply pipe 134, the first through hole 131 is communicated with the inside of the cylinder body 14 and the inside of the liquid supply pipe 134, and spraying liquid or coating liquid in the cylinder body 14 sequentially passes through the first through hole 131, the liquid supply pipe 134 and the nozzle and is sprayed into the large disc 4 under the pressure of gas; the both sides of base 3 are provided with mounting bracket 7, are provided with crossbeam 8 on mounting bracket 7, and the bottom of crossbeam 8 is provided with first pneumatic cylinder 10 and second pneumatic cylinder 15, lid 5 is installed to the bottom of first pneumatic cylinder 10, lid 5 is used for the open end of closed deep bid 4, lid 5 is run through in the bottom activity of second pneumatic cylinder 15, and is connected with accuse hydraulic mechanism 16, accuse hydraulic mechanism 16 is used for adjusting the spray angle of nozzle.
When the device is used, the angle between the large disc and the liquid supply platform is adjusted, and after particles are poured into the large disc, the position of the cover body is adjusted by adjusting the first hydraulic cylinder so as to close the open end of the large disc; then pouring the prepared spraying liquid or coating liquid into the cylinder body, and starting the first driving device to drive the large disc and the nozzle to rotate; and (3) starting the air source, pressing the liquid in the cylinder body into the liquid supply pipe after the air enters the cylinder body, and finally spraying the liquid into the large plate through the nozzle. In the deep bid rotation process, can observe the formation condition of inside granule through observation window on the lid, can adjust accuse liquid mechanism height according to the size and the humidity of granule, with the nozzle is sheltered from totally or partially, realize on the whole moving trajectory of granule, the granule in partial region receives liquid spray, the granule in partial region does not receive liquid spray, can adjust liquid spray angle and liquid spray volume according to the humidity of granule, thereby the degree of consistency and the product quality of coating layer, avoid partial granule too moist and the adhesion at conveyer belt or bin outlet.
In some embodiments, the angle of the large disc is not adjustable, and the liquid supply platform is parallel to the bottom surface of the large disc; in some embodiments, the angle of the large disk and the angle of the liquid supply platform can be adjusted, and the large disk and the liquid supply platform move synchronously and are always kept parallel.
In one or more embodiments, the inner diameter of the cover is slightly larger than the outer diameter of the large disc, so that when the cover is covered on the large disc, gas introduced into the cylinder can be discharged from a covered gap between the cover and the large disc.
In one embodiment, a scraper is disposed on the lower surface of the cover.
In one embodiment, the cross beam is provided with a second driving device, and the second driving device is used for driving the cross beam to rotate along the transverse central axis of the cross beam, so as to drive the cover body to adjust the angle, and the angle of the cover body can be changed along with the adjustment of the angle of the large plate.
In some embodiments, the first driving device and the second driving device may be stepping motors or servo motors.
As shown in fig. 6, in some embodiments, the nozzles include a first nozzle fixedly connected to a sidewall of the liquid supply pipe and a second nozzle fixedly connected to the first nozzle, and the liquid supply pipe is communicated with the first nozzle and the second nozzle. Wherein the first nozzle is made of metal or plastic; the second nozzle is made of rubber, preferably silicone rubber or nitrile rubber.
Through the design, the inner diameter of the shell of the liquid control mechanism is larger than the length of the first nozzle and smaller than the total length of the nozzle, so that the second nozzle is deformed and closed when the nozzle is connected with the shell of the liquid control mechanism as shown in fig. 9, liquid cannot be sprayed out from the second nozzle, and when the nozzle is not in contact with the liquid control mechanism as shown in fig. 8, the second nozzle is restored to the original state, and the liquid is sprayed out from the second nozzle.
In some embodiments, the inner diameter of the second nozzle is gradually reduced from inside to outside to accelerate the flow rate of the fluid therein, and the liquid ejection speed can reach a preset speed faster without being blocked by the liquid control mechanism.
As shown in fig. 6, the liquid control mechanism 16 further includes a housing 161, a plurality of rows of second through holes 162 are formed in a side wall of the housing 161 from top to bottom, and the number and/or size of the second through holes 162 in two adjacent rows are different. Preferably, the number and size of the through holes of each row of second through holes are different, so as to provide a more flexible control mode.
As used herein, "first", "second", etc. (e.g., first drive means, second drive means, first through hole, second through hole, etc.) merely distinguish the respective components for clarity of description and are not intended to limit any order or to emphasize importance, etc. Further, the term "connected" used herein may be either directly connected or indirectly connected via other components without being particularly described.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are merely exemplary embodiments of the present invention, and are not intended to limit the scope of the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.
Claims (10)
1. The pellet for the laundry detergent comprises a pellet core (1) and a coating layer (2) for coating the pellet core (1), and is characterized in that the coating layer (2) comprises the following raw materials in parts by weight: 5-20 parts of high-carbon fatty alcohol, 5-30 parts of microcrystalline wax, 20-50 parts of polyethylene glycol and 5-20 parts of hydrogenated castor oil.
2. The pellet for laundry detergent as claimed in claim 1, wherein the sum of the contents of the higher fatty alcohol and the microcrystalline wax is 5-7 times the content of the hydrogenated castor oil.
3. The pellet for laundry detergent according to claim 1, characterized in that the pellet core (1) comprises the following raw materials in parts by weight: 30-50 parts of diluent, 2-10 parts of adhesive, 20-50 parts of disintegrating agent, 0.1-5 parts of essence and 3-20 parts of bactericide.
4. The pellet for laundry detergent of claim 3, wherein the bactericide is selected from one or more of dodecyl trimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium chloride, tetradecyl trimethyl ammonium chloride, tetradecyl dimethyl benzyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide and tetradecyl dimethyl benzyl ammonium bromide.
5. The pellet for laundry detergent as claimed in claim 3, wherein the disintegrant is selected from one or more of sodium carboxymethyl starch, microcrystalline cellulose, and low-substituted hydroxypropyl methyl cellulose.
6. The pellet for laundry detergent as claimed in claim 3, wherein the binder is selected from one or more of hydroxypropyl methylcellulose, sodium carboxymethylcellulose, hydroxyethyl cellulose, chitosan, cyclodextrin and sodium alginate.
7. A preparation process of a pellet for a laundry detergent is characterized by comprising the following steps:
preparing a pill core;
pouring the prepared pellet cores into a disc granulating device;
preparing a coating solution, wherein the coating solution comprises the following raw materials in parts by weight: 5-20 parts of high-carbon fatty alcohol, 5-30 parts of microcrystalline wax, 20-50 parts of polyethylene glycol, 5-20 parts of hydrogenated castor oil and 50-200 parts of solvent;
and starting a disc granulation device, spraying coating liquid, forming a coating layer on the surface of the pellet core, and drying to obtain the pellet.
8. The process for preparing micropellets for laundry detergents according to claim 7, wherein the step of preparing the pellet core comprises the steps of:
pouring 30-50 parts by weight of diluent, 2-10 parts by weight of adhesive and 20-50 parts by weight of disintegrating agent into a disc granulating device;
dissolving 0.1-5 parts by weight of essence and 3-20 parts by weight of bactericide in 30-100 parts by weight of wetting agent to form a spraying liquid;
after the positions of the liquid spraying mechanism and the liquid control mechanism are adjusted according to the quantity of the pill cores, starting a disc granulation device for granulation until the size of the pill cores reaches a preset size;
drying the pellet cores and screening the pellet cores with qualified sizes.
9. The process for preparing pellets for laundry detergent according to claim 7 or 8, wherein the disc granulating device comprises a base (3), the base (3) is provided with a large disc (4) and a liquid spraying system, the liquid spraying system comprises a liquid supplying platform (12), the liquid supplying platform (12) is provided with a first driving device (6) and a cylinder (14), the cylinder (14) is provided with an air inlet pipe (141) and a liquid inlet pipe (142), the air inlet pipe (141) is used for introducing gas into the cylinder (14), and the liquid inlet pipe (142) is used for introducing spraying liquid or coating liquid into the cylinder (14); the output end of the first driving device (6) is connected with a liquid supply pipe (134), the liquid supply pipe (134) is of a hollow structure, one end, far away from the first driving device (6), of the liquid supply pipe (134) movably penetrates through the cylinder body (14) and the bottom of the large disc (4), a nozzle located in the large disc (4) is arranged on the liquid supply pipe (134), a first through hole (131) is formed in the part, located in the cylinder body (14), of the liquid supply pipe (134), the first through hole (131) is communicated with the interior of the cylinder body (14) and the interior of the liquid supply pipe (134), and spraying liquid or coating liquid in the cylinder body (14) is sprayed into the large disc (4) sequentially through the first through hole (131), the liquid supply pipe (134) and the nozzle under the pressure of gas; the both sides of base (3) are provided with mounting bracket (7), be provided with crossbeam (8) on mounting bracket (7), the bottom of crossbeam (8) is provided with first pneumatic cylinder (10) and second pneumatic cylinder (15), lid (5) are installed to the bottom of first pneumatic cylinder (10), lid (5) are used for the opening end of closed big dish (4), the bottom activity of second pneumatic cylinder (15) runs through lid (5), and is connected with accuse hydraulic mechanism (16), accuse hydraulic mechanism (16) are used for adjusting the injection angle of nozzle.
10. The process for preparing pellets for laundry detergent according to claim 9, wherein the liquid control mechanism (16) comprises a housing (161), the side wall of the housing (161) is provided with a plurality of rows of second through holes (162) from top to bottom, and the number and/or size of the second through holes (162) in two adjacent rows are different.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010650445.XA CN111748426B (en) | 2020-07-08 | 2020-07-08 | Pellet for laundry detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010650445.XA CN111748426B (en) | 2020-07-08 | 2020-07-08 | Pellet for laundry detergent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111748426A true CN111748426A (en) | 2020-10-09 |
| CN111748426B CN111748426B (en) | 2021-06-18 |
Family
ID=72680190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010650445.XA Active CN111748426B (en) | 2020-07-08 | 2020-07-08 | Pellet for laundry detergent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111748426B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113481067A (en) * | 2021-06-02 | 2021-10-08 | 兰州石化职业技术学院 | Laundry detergent with anti-bacterial function and preparation method thereof |
| CN117660125A (en) * | 2023-10-20 | 2024-03-08 | 广东星帮尼科技股份有限公司 | Quaternary ammonium salt clothes cleaning disinfectant and preparation method thereof |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000063335A1 (en) * | 1999-04-19 | 2000-10-26 | The Procter & Gamble Company | Bleach-free automatic dishwashing detergent composition having enzyme particles with acid barrier coating |
| CN1471571A (en) * | 2000-10-27 | 2004-01-28 | Stabilized liquid compositions | |
| CN1856567A (en) * | 2003-08-01 | 2006-11-01 | 宝洁公司 | Aqueous liquid laundry detergent compositions with visible beads |
| EP2169041A1 (en) * | 2008-09-30 | 2010-03-31 | The Procter and Gamble Company | Liquid detergent compositions exhibiting two or multicolor effect |
| CN102504977A (en) * | 2011-11-03 | 2012-06-20 | 广州立白企业集团有限公司 | Color particle composition for powdery, flaky or particulate fabric washing agent |
| CN102533708A (en) * | 2011-12-29 | 2012-07-04 | 青岛蔚蓝生物集团有限公司 | Enzyme particle coated with alkali protease and preparation method thereof |
| CN102612553A (en) * | 2009-11-06 | 2012-07-25 | 宝洁公司 | High efficiency capsules comprising benefit agent |
| CN104471045A (en) * | 2012-06-08 | 2015-03-25 | 宝洁公司 | Laundry detergents |
| CN205011660U (en) * | 2015-10-27 | 2016-02-03 | 营口菱镁化工集团有限公司 | Add disc granulation device of disintegrating agent |
| WO2016023145A1 (en) * | 2014-08-11 | 2016-02-18 | The Procter & Gamble Company | Laundry detergent |
| CN107034058A (en) * | 2017-05-15 | 2017-08-11 | 江南大学 | It is a kind of to be used for the method for Simultaneous Stabilization lipase and protease in complex enzyme liquid detergent |
| EP3249031A1 (en) * | 2016-05-23 | 2017-11-29 | The Procter and Gamble Company | Liquid detergent composition comprising an encapsulated enzyme |
| CN207822974U (en) * | 2018-01-16 | 2018-09-07 | 永春雪山靓雪矿泉水有限公司 | A kind of Novel disc comminutor |
| CN110564515A (en) * | 2019-08-20 | 2019-12-13 | 广东工业大学 | Essence microcapsule grafted with organic silicon quaternary ammonium salt and preparation method and application thereof |
-
2020
- 2020-07-08 CN CN202010650445.XA patent/CN111748426B/en active Active
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000063335A1 (en) * | 1999-04-19 | 2000-10-26 | The Procter & Gamble Company | Bleach-free automatic dishwashing detergent composition having enzyme particles with acid barrier coating |
| CN1471571A (en) * | 2000-10-27 | 2004-01-28 | Stabilized liquid compositions | |
| CN1856567A (en) * | 2003-08-01 | 2006-11-01 | 宝洁公司 | Aqueous liquid laundry detergent compositions with visible beads |
| EP2169041A1 (en) * | 2008-09-30 | 2010-03-31 | The Procter and Gamble Company | Liquid detergent compositions exhibiting two or multicolor effect |
| CN102612553A (en) * | 2009-11-06 | 2012-07-25 | 宝洁公司 | High efficiency capsules comprising benefit agent |
| CN102504977A (en) * | 2011-11-03 | 2012-06-20 | 广州立白企业集团有限公司 | Color particle composition for powdery, flaky or particulate fabric washing agent |
| CN102533708A (en) * | 2011-12-29 | 2012-07-04 | 青岛蔚蓝生物集团有限公司 | Enzyme particle coated with alkali protease and preparation method thereof |
| CN104471045A (en) * | 2012-06-08 | 2015-03-25 | 宝洁公司 | Laundry detergents |
| WO2016023145A1 (en) * | 2014-08-11 | 2016-02-18 | The Procter & Gamble Company | Laundry detergent |
| CN205011660U (en) * | 2015-10-27 | 2016-02-03 | 营口菱镁化工集团有限公司 | Add disc granulation device of disintegrating agent |
| EP3249031A1 (en) * | 2016-05-23 | 2017-11-29 | The Procter and Gamble Company | Liquid detergent composition comprising an encapsulated enzyme |
| CN107034058A (en) * | 2017-05-15 | 2017-08-11 | 江南大学 | It is a kind of to be used for the method for Simultaneous Stabilization lipase and protease in complex enzyme liquid detergent |
| CN207822974U (en) * | 2018-01-16 | 2018-09-07 | 永春雪山靓雪矿泉水有限公司 | A kind of Novel disc comminutor |
| CN110564515A (en) * | 2019-08-20 | 2019-12-13 | 广东工业大学 | Essence microcapsule grafted with organic silicon quaternary ammonium salt and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 郭俊华: "香精微胶囊悬浮剂的研制及其在洗衣液中的应用", 《中国洗涤用品工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113481067A (en) * | 2021-06-02 | 2021-10-08 | 兰州石化职业技术学院 | Laundry detergent with anti-bacterial function and preparation method thereof |
| CN117660125A (en) * | 2023-10-20 | 2024-03-08 | 广东星帮尼科技股份有限公司 | Quaternary ammonium salt clothes cleaning disinfectant and preparation method thereof |
| CN117660125B (en) * | 2023-10-20 | 2024-05-28 | 广东星帮尼科技股份有限公司 | Quaternary ammonium salt clothes cleaning disinfectant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111748426B (en) | 2021-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111748426B (en) | Pellet for laundry detergent and preparation method thereof | |
| EP0079234B1 (en) | Apparatus and method for textile laundering and detergent liquors and compositions for use therein | |
| KR900003941B1 (en) | Apparatus for and method of granulating fluidized pulverized material and coating granulated products | |
| KR100623894B1 (en) | Process for the preparation of coated peroxygen compounds | |
| CN105378048B (en) | Novel clean preparation and method | |
| CN102459744B (en) | Method for treating laundry and suitable laundry treatment device for carrying out the method | |
| TW201418542A (en) | Improved cleaning apparatus and method | |
| CN108097110A (en) | A kind of clothes processing lining cloth sizing agent paste mixer | |
| JPS62207400A (en) | Production of granule containing active substance and its use as stain removing agent in treatment of substrate | |
| CN106062164A (en) | Compositions comprising a pungent agent | |
| JPH02207833A (en) | Method and device for granulation coating | |
| EP0521213B1 (en) | Washing apparatus and method for fluidized bed pelletizing and drying machine | |
| US20100249013A1 (en) | Encapsulated active ingredients for cleaning applications | |
| US3601086A (en) | Tablet-coating apparatus | |
| JP2815925B2 (en) | Method for coating particles for detergent formulation | |
| CN115430163B (en) | Be applied to spray drying equipment of ox gall powder production | |
| JP3514677B2 (en) | Enzyme particle aggregate | |
| CN111945383B (en) | Clothes washing device and clothes treatment method | |
| CN209476800U (en) | A kind of Environment-friendlywoven woven bag flushing drying device | |
| CN208785656U (en) | A kind of process equipment of decontaminant amplification synthesis | |
| JP3071427B2 (en) | Enzyme particles | |
| CN211739743U (en) | Drying device of microcapsule granulator | |
| CN108568049A (en) | A kind of process equipment and its processing technology of decontaminant amplification synthesis | |
| CN220758804U (en) | Powder bag mixing device | |
| CN220633025U (en) | Enzyme preparation drying device with spraying function |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |