CN111733613A - Flange velvet dye liquor and preparation method thereof - Google Patents
Flange velvet dye liquor and preparation method thereof Download PDFInfo
- Publication number
- CN111733613A CN111733613A CN202010723634.5A CN202010723634A CN111733613A CN 111733613 A CN111733613 A CN 111733613A CN 202010723634 A CN202010723634 A CN 202010723634A CN 111733613 A CN111733613 A CN 111733613A
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- Prior art keywords
- parts
- flannel
- dye
- solution
- dye liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 33
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 30
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- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical group CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 35
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
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- D06P1/651—Compounds without nitrogen
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- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
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- D06P1/667—Organo-phosphorus compounds
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- D06P1/673—Inorganic compounds
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
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- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
- D06P3/143—Wool using dispersed dyes
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- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a flannel dye solution and a preparation method thereof, wherein the flannel dye solution is prepared from the following raw materials in parts by weight: 20-30 parts of disperse dye, 3-5 parts of leveling agent, 5-9 parts of glacial acetic acid, 1-3 parts of titanium dioxide, 1-3 parts of nano silver powder, 1-3 parts of perlite, 1-3 parts of traditional Chinese medicine composition extracting solution, 3-6 parts of thickening agent, 0.05-0.1 part of antioxidant and 40-55 parts of water, and has the advantages of killing and inhibiting mites and bacteria on flannel clothes; a preparation method of a flannel dye solution comprises weighing raw materials, stirring disperse dye, leveling agent, glacial acetic acid, thickener and water at 40 deg.C for 5min, adding titanium dioxide, nanometer silver powder and perlite, heating, stirring, adding Chinese medicinal composition extract and antioxidant, and stirring to obtain flannel dye solution; has the advantage of simple operation.
Description
Technical Field
The invention relates to the technical field of dyes, in particular to a flannel dye solution and a preparation method thereof.
Background
Flannel is a soft and textured (cotton) wool fabric woven from carded (cotton) wool yarns; in order to ensure the crease resistance and shape retention of flannel, knitted polyester fabric is often used as gray fabric for processing.
In the prior art, flannel has good heat preservation performance, so that flannel is often used for manufacturing clothes worn in winter, when the seasons are changed, people often collect the clothes in winter, and when the winter of the next year comes, people can take the clothes out for continuous use; because the flannel has good moisture absorption effect, the phenomenon of the clothing getting damp easily appears to the clothing is after long-time the back of putting, easily contacts with house dust mite, dust mite and various bacterium in the air, along with the extension of time and moist living environment, builds good reproductive environment and existence atmosphere for the mite, thereby accelerates mite's reproductive rate.
The common method for removing mites from clothes is to wash the clothes at high temperature or expose the clothes to the sun, and because wool is contained in flannel, when the mite removing method of high-temperature washing is used, the wool is easy to shrink and harden, so that the quality of flannel is influenced; if the flannel is exposed to sunlight, the flannel is easy to fade and yellow; if the conventional cleaning is adopted, the mites and bacteria can be incompletely killed, after people wear clothes breeding the mites, the mites are in contact with the surface of the skin of a human body, allergic dermatitis or papular urticaria can easily occur to the skin, and meanwhile, the mites enter the skin and can absorb secretions of the skin to stimulate the skin to generate inflammation, so that the phenomena of hair follicle blockage and excessive sebum secretion are caused, and the inconvenience is brought to the life of people.
Therefore, after the clothes made of the flange flannel are placed for a long time, mites and bacteria are easy to breed, and inconvenience is brought to life of people.
Disclosure of Invention
Aiming at the defects in the prior art, the first object of the invention is to provide a flannel dye liquor which has the advantages of killing and inhibiting mites and bacteria on flannel clothes under the condition of normal-temperature cleaning.
The second purpose of the invention is to provide a preparation method of a flannel dye liquor, which has the advantages of simple operation and convenient production.
In order to achieve the first object, the invention provides the following technical scheme: dye liquor for flannel, and dye liquorByComprises the following raw materials in parts by weightIs made into: 20-30 parts of disperse dye, 3-5 parts of leveling agent, 5-9 parts of glacial acetic acid, 1-3 parts of titanium dioxide, 1-3 parts of nano silver powder, 1-3 parts of perlite, 1-3 parts of traditional Chinese medicine composition extracting solution, 3-6 parts of thickening agent, 0.05-0.1 part of antioxidant and 40-55 parts of water.
Through adopting above-mentioned technical scheme, the clothing of making for guaranteeing the flannel has good soft nature and guarantees the soft structure of wool, in the cleaning process, often washs with normal atmospheric temperature water, but mite can breed on the flannel clothing surface through placing for a long time, and the mite can not effectively be exterminateed in the normal atmospheric temperature washing.
After the grey cloth is dyed by the dye liquor, flannel clothes are manufactured through processing, after the flannel clothes are cleaned, titanium dioxide valence band electrons are excited to a conduction band under the irradiation of ultraviolet rays, electrons and holes migrate to the surface of the titanium dioxide, electron hole pairs are generated on the surface, positive and trivalent titanium ions and oxygen vacancies are formed, water molecules are dissociated and adsorbed in the oxygen vacancies, and a physical adsorption layer is formed; the dyestuff that the cooperation pearlite made has stronger hydrophilicity, clothing water content after the washing is higher, humidity is great, utilize the hydroscopicity of titanium dioxide and pearlite can be with moisture suction, the heat conductivility stronger of cooperation titanium dioxide and nanometer silver powder makes the temperature on clothing surface be higher than external environment temperature to moisture is by rapid evaporation in the clothing with higher speed, moisture is the essential factor that the mite lives, the evaporation of moisture can make the mite lose water and inactivate, finally reach and kill mite, the effect of disinfecting.
The perlite and the titanium dioxide can be uniformly distributed in the dye solution under the action of the leveling agent, the nano silver powder can be uniformly distributed in the porous structures of the perlite and the titanium dioxide under the action of the leveling agent, water is located in the porous structures of the perlite and the titanium dioxide due to the water absorption effect of the perlite and the titanium dioxide, and the water evaporation can be accelerated under the heat conduction effect of the nano silver powder matched with the titanium dioxide; the accelerated loss of moisture can cause the mites to lose moisture quickly, thereby losing biological activity.
The titanium dioxide has the effects of reflecting and scattering ultraviolet rays, and can avoid the phenomenon of decoloration of flannel in sunlight drying by matching with the antioxidant effect of the antioxidant; when the external environment is not suitable for living, part of mites move towards the inner side of the clothes, so that ultraviolet irradiation is avoided, part of ultraviolet rays reach the inner side of the clothes through the porous structures of the titanium dioxide and the perlite after being refracted and reflected through the porous structures, the ultraviolet rays have strong ultraviolet ray penetrating power at the reflection angle position, and the mites in the clothes can be killed under the action of the plurality of titanium dioxide physical adsorption layers; under the irradiation of ultraviolet rays, physiological systems and nervous systems of mites are disordered due to water loss in vivo, so that the mites lose biological activity and die finally.
The application adds the traditional Chinese medicine composition extracting solution, and can achieve the purpose of expelling the mites by utilizing the unique smell and the bioactive components contained in the traditional Chinese medicine composition extracting solution, so that the mites are prevented from being attached to clothes; the traditional Chinese medicine composition extracting solution and the dispersing agent are matched, so that the traditional Chinese medicine composition extracting solution can be uniformly distributed in the pore structures of the perlite and the titanium dioxide, and the traditional Chinese medicine composition has a strong penetrating effect under the matching of the traditional Chinese medicine composition and the leveling agent, so that the smell of the traditional Chinese medicine composition is more durable.
In the application, the titanium dioxide, the nano silver powder and the perlite are matched, so that the mites lose biological activity due to water loss from the angle of accelerating water loss, and the purpose of killing insects is achieved; the cooperation of the titanium dioxide and the antioxidant disturbs the biological metabolism of the mites from the ultraviolet sterilization angle, thereby achieving the purpose of killing insects; under the coordination of the nano silver powder, the titanium dioxide and the dispersing agent, the moisture in the clothes is accelerated to run off through heat conduction, so that the purpose of killing insects is achieved, and the flannel clothes cleaned at normal temperature have good mite killing and sterilizing effects when being aired; under the matching of the traditional Chinese medicine composition extracting solution and the dispersing agent, the mites are prevented from being attached to clothes from the angle of inhibiting and expelling the mites, so that the problem that the mites and bacteria are easily bred after the clothes made of flannel are placed for a long time is solved.
Further, the traditional Chinese medicine composition extracting solution consists of folium artemisiae argyi extracting solution and clove extracting solution in a weight ratio of 2: 1.
By adopting the technical scheme, the special fragrance of the wormwood and the clove can be utilized to play a role in expelling the mites, so that the mites are prevented from breeding on the surface of the clothes; the wormwood also has the mosquito repelling effect, and the combination of the clove and the wormwood can enable the surface of clothes to have faint scent without causing uncomfortable reaction to human bodies; the folium artemisiae argyi extract and the clove extract can be uniformly distributed in the pore structures of the perlite and the titanium dioxide under the matching of the dispersing agent.
Further, the leveling agent consists of a nonionic dispersant and an anionic dispersant in a weight ratio of 2: 1.
By adopting the technical scheme, the leveling agent can effectively prevent or reduce the thermal coagulation degree of the disperse dye and improve the dispersion stability of the dye solution, and the leveling agent can also effectively disperse titanium dioxide and pearl powder and can be uniformly distributed in the dye solution; the nonionic dispersant can enable the dye to have a certain degree of affinity, has a slow dyeing effect during dyeing, and has strong functions of transfer dyeing and level dyeing, so that the dye can be uniformly printed on cloth, but the nonionic dispersant is poor in stability of a dye solution of a disperse dye under the condition of high-temperature dispersion; the anionic dispersing agent can have a good dispersing effect on disperse dyes, and the dye liquor has good stability at high temperature, but the anionic dispersing agent is lack of a slow dyeing effect, and the prepared dye liquor has good slow dyeing and level dyeing effects on the premise of good thermal stability by utilizing the matching of the anionic dispersing agent and the nonionic dispersing agent.
Further, the nonionic dispersing agent is glycerol polyoxyethylene ether trioleate, and the anionic dispersing agent is sodium methylene dinaphthalene sulfonate.
By adopting the technical scheme, the glycerol polyoxyethylene ether trioleate and the sodium methylenedinaphthalene sulfonate are matched to ensure that the disperse dye has good dispersing performance and the slow dyeing, level dyeing and thermal stability effects are optimal; and the sodium methylenedinaphthalenesulfonate has good foamability and emulsibility, is convenient for cleaning flannel clothes, has certain fragrance, has a certain mite expelling effect, and inhibits mites from staying on the surface of the flannel clothes.
Further, the thickening agent is sodium alginate.
By adopting the technical scheme, sodium alginate is dissolved in water to form a gel substance, so that the viscosity of the disperse dye is enhanced, the adsorption uniformity between the disperse dye and the fiber is improved by adjusting the viscosity of the dyeing solution, the dye migration can be effectively prevented, and the stability of the dyeing solution can be improved; the ammonium alginate has hygroscopicity, the sodium alginate can absorb water, and after the water is evaporated, the ammonium alginate plays a filling role in the pore structure of the perlite, so that air is prevented from entering, and the fragrance of the traditional Chinese medicine composition extracting solution is prevented from being lost in an accelerated manner; after the flannel clothing dries, humidity in the air is greater than the humidity of clothing, and the cooperation of sodium alginate, perlite, titanium dioxide makes the clothing form hydrophobic membrane towards air one side this moment to avoid the hydrone in the air to contact with the cloth through the pore structure of perlite and titanium dioxide, make cloth surface water content rise, promote breeding of mite.
The matching of the sodium alginate and the anionic dispersing agent enables the prepared dye to have good thermal stability and good permeability, and the matching of the sodium alginate and the nonionic dispersing agent enables the prepared dye to have more uniform color, brighter chromaticity and clear lines.
Further, the antioxidant consists of pentaerythritol tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] and phytic acid in a weight ratio of 1: 2.
By adopting the technical scheme, the flannel clothes are dried in the air after being washed, the clothes can be hardened by oxygen in the air, and in order to ensure the softness of the clothes made of flannel, the cooperation of tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester and phytic acid is adopted to prevent flannel fluff from being oxidized and hardened during drying; under the sun exposure, the disperse dye can fade due to the strong irradiation of ultraviolet rays, and the phenomenon that the dye liquor fades on the surface of clothes is avoided by utilizing the principle that titanium dioxide and phytic acid are matched and reflecting the ultraviolet rays.
In order to achieve the second object, the invention provides the following technical scheme: a preparation method of a flannel dye liquor comprises the following steps:
s1, weighing the raw materials according to the proportion, and stirring the disperse dye, the leveling agent, glacial acetic acid, the thickening agent and water at the temperature of 40 ℃ for 5min to prepare a dye solution A;
s2, adding titanium dioxide, nano silver powder and perlite into the dye solution A, heating to 120-150 ℃, and stirring at a stirring speed of 80r/min for 15-20min to obtain a dye solution B;
s3, adding the traditional Chinese medicine composition extracting solution and the antioxidant into the dye solution B, and stirring for 5-10min at the stirring speed of 40-60r/min under the condition of 110-150 ℃ to obtain the flannel dye solution.
By adopting the technical scheme, the disperse dye, the leveling agent and the glacial acetic acid are mixed, so that the disperse dye can be uniformly dispersed in the dye liquor, and the prepared dye liquor has good thermal stability; the prepared dye has good hydrophilic and heat-conducting capabilities along with the addition of the titanium dioxide, the perlite and the nano silver powder, the titanium dioxide and the perlite can be uniformly dispersed in the dye liquor under the coordination of the thickening agent, the water and the leveling agent, and after the dye liquor is coated on the gray cloth, the mites on the clothes are dehydrated, inactivated, quickly aged and dead by utilizing the principles of hydrophilicity, heat conduction and ultraviolet reflection of the dye liquor, so that the aim of killing the mites and bacteria is fulfilled; the traditional Chinese medicine extracting solution and the antioxidant are added finally, so that the smell of the traditional Chinese medicine extracting solution can be kept for a long time, the purpose of expelling mites is achieved, the traditional Chinese medicine extracting solution can also ensure a good sterilization effect, and the prepared dye has good thermal stability and slow dyeing and level dyeing effects by utilizing the cooperation of the antioxidant and the leveling agent.
Further, the clove extracting solution in the S3 traditional Chinese medicine composition is prepared by the following method:
1) the weight portion is: weighing 4-6 parts of clove, 40-60 parts of water, 70-100 parts of ethanol and 0.1-0.4 part of activated carbon;
2) pulverizing flos Caryophylli, placing in water, precooking at 60 deg.C for 1-2 hr, filtering, and collecting filtrate to obtain extractive solution A;
3) placing activated carbon in a filter bag to obtain an activated carbon bag, extracting the activated carbon bag and the extracting solution A in ethanol at 90 deg.C for 5-7 hr, concentrating, filtering, and collecting the filtrate to obtain flos Caryophylli extracting solution.
By adopting the technical scheme, active substances in the pre-cooked clove can be better leached, and part of bacteria and microorganisms can be killed in the leaching process; the color of the clove extracting solution is lighter and is close to a transparent state by utilizing the adsorption function of the activated carbon and matching with the extraction process of ethanol, so that the clove extracting solution is prevented from influencing the excellent effect of the disperse dye.
Further, stirring at 80r/min for 15-20min in S2, and standing for 20-30min under heat preservation.
By adopting the technical scheme, the dye can be well fixed and pure in chromaticity by keeping the temperature for 20-30min, and the dye can be uniformly dyed on the gray cloth.
Further, when the temperature of S2 is in the temperature range of 70-110 ℃, the temperature rise speed is ensured to be 1-3 ℃/min.
Through adopting above-mentioned technical scheme, through injecing the rate of heating up, can guarantee titanium dioxide, the even distribution of pearlite can be in the dye liquor to guarantee that the dyestuff is adsorbed by the uniformity.
In conclusion, the invention has the following beneficial effects:
1. in the application, the titanium dioxide, the nano silver powder and the perlite are matched, so that the mites lose the biological activity from the aspect of quickly losing water, and the purpose of killing insects is achieved; the cooperation of the titanium dioxide and the antioxidant disturbs the biological metabolism of the mites from the ultraviolet sterilization angle, thereby achieving the purpose of killing insects; under the coordination of the nano silver powder, the titanium dioxide and the dispersing agent, the water in the clothes is accelerated to run off, so that the aim of killing insects is fulfilled; under the coordination of the traditional Chinese medicine composition extracting solution and the dispersing agent, the mites are prevented from being attached to clothes from the aspects of inhibiting the mites and expelling the mites, so that the problem that the mites and bacteria are easily bred after the clothes made of flannel are placed for a long time is solved;
2. the leveling agent can effectively prevent or reduce the thermal coagulation degree of the disperse dye and improve the dispersion stability of the dye solution, and the leveling agent can also effectively disperse titanium dioxide and pearl powder and can uniformly distribute the titanium dioxide and the pearl powder in the dye solution; by utilizing the matching of the anionic dispersant and the nonionic dispersant, the prepared dye has good slow dyeing and level dyeing effects on the premise of good thermal stability;
3. the sodium alginate improves the adsorption uniformity between the disperse dye and the fiber by adjusting the viscosity of the dyeing solution, can effectively prevent the migration of the dye, and can improve the stability of the dyeing solution; the ammonium alginate has hygroscopicity, the sodium alginate can absorb water, and after the water is evaporated, the ammonium alginate plays a filling role in the pore structure of the perlite, so that air is prevented from entering, and the fragrance of the traditional Chinese medicine composition extracting solution is prevented from being lost in an accelerated manner; after the flannel clothes are dried, the humidity in the air is greater than that of the clothes, and at the moment, the sodium alginate, the perlite and the titanium dioxide are matched to enable the clothes to form a hydrophobic film on one side facing the air, so that water molecules in the air are prevented from contacting with the cloth through the pore structures of the perlite and the titanium dioxide, the water content of the surface of the cloth is increased, and the breeding of mites is promoted;
4. the clothes are placed in the air for airing after being washed, the clothes are hardened by oxygen in the air, and in order to ensure the softness of the clothes made of flannel, the cooperation of tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester and phytic acid is adopted to prevent fluff from being oxidized and hardened during airing; under the sun exposure, the disperse dye can fade due to the strong irradiation of ultraviolet rays, and the titanium dioxide and the phytic acid are matched to prevent the ultraviolet rays from reaching the surface of flannel villi by utilizing the principle of reflecting the ultraviolet rays, so that the phenomenon of fading of the disperse dye is avoided.
Detailed Description
The present invention will be described in further detail with reference to the following preparation examples and examples.
Preparation example of clove extract
Preparation example 1:
1) weighing 5kg of clove, 50kg of water, 88kg of ethanol (75% of Shandong Deyan chemical engineering Co., Ltd., type LEK-01) and 0.25kg of active carbon;
2) pulverizing flos Caryophylli to 50 mesh, filtering to obtain the filtrate to obtain flos Caryophylli powder, placing flos Caryophylli powder and water in leaching tank, stirring at 40r/min, precooking at 60 deg.C for 1.5 hr, and filtering to obtain filtrate A;
3) placing activated carbon in a square filter bag made of non-woven fabric, sealing to obtain an activated carbon bag, placing the activated carbon bag, the extracting solution A and ethanol in another extraction tank for extraction, stirring at a rotating speed of 50r/min, and extracting at 90 ℃ for 6 hours to obtain an extracting solution B;
4) and (3) putting the extracting solution B into a concentration tank, concentrating at the rotating speed of 30r/min for 1 hour, and filtering to obtain filtrate, namely the clove extracting solution.
Preparation example 2
1) Weighing 4kg of clove, 40kg of water, 70kg of ethanol and 0.1kg of active carbon;
2) pulverizing flos Caryophylli to 50 mesh, filtering to obtain the filtrate to obtain flos Caryophylli powder, placing flos Caryophylli powder and water in leaching tank, stirring at 40r/min, pre-boiling at 60 deg.C for 1 hr, and filtering to obtain filtrate A;
3) placing activated carbon in a square filter bag made of non-woven fabric, sealing to obtain an activated carbon bag, placing the activated carbon bag, the extracting solution A and ethanol in another extraction tank for extraction, stirring at a rotating speed of 50r/min, and extracting at 90 deg.C for 5-7 hr to obtain an extracting solution B;
4) and (3) putting the extracting solution B into a concentration tank, concentrating at the rotating speed of 30r/min for 1 hour, and filtering to obtain filtrate, namely the clove extracting solution.
Preparation example 3
1) Weighing 6kg of clove, 60kg of water, 100kg of ethanol and 0.4kg of active carbon;
2) pulverizing flos Caryophylli to 50 mesh, filtering to obtain the filtrate to obtain flos Caryophylli powder, placing flos Caryophylli powder and water in leaching tank, stirring at 40r/min, pre-boiling at 60 deg.C for 2 hr, and filtering to obtain filtrate A;
3) placing activated carbon in a square filter bag made of non-woven fabric, sealing to obtain an activated carbon bag, placing the activated carbon bag, the extracting solution A and ethanol in another extraction tank for extraction, stirring at a rotating speed of 50r/min, and extracting at 90 ℃ for 7 hours to obtain an extracting solution B;
4) and (3) putting the extracting solution B into a concentration tank, concentrating at the rotating speed of 30r/min for 1 hour, and filtering to obtain filtrate, namely the clove extracting solution.
Examples
Example 1
S1, weighing 26.8kg of disperse red (adopting Jinnan Shanghai Brightness chemical Co., Ltd., model 153), 4.2kg of leveling agent, 7.6kg of glacial acetic acid (adopting Linyi colorful chemical Co., Ltd., purity 99.8%), 2kg of titanium dioxide (adopting Shandong Yousuo chemical science and technology Co., Ltd.), 2kg of nano silver powder (adopting Shenzhen Dongdai chemical Co., Ltd., model Dag-9004), 2kg of perlite (adopting Shanhai hong Yun gardening articles Co., Ltd., particle size 1mm), 2kg of Chinese medicinal composition extract, 4.2kg of sodium alginate and 0.08kg of antioxidant, wherein the leveling agent is composed of glycerol polyoxyethylene ether trioleate (adopting Jiangsu Haian petrochemical plant) and methylene dinaphthalene sodium sulfonate (adopting Jinnan Jinhui chemical Co., Ltd., model NNO) in a weight ratio of 2: 1; the Chinese medicinal composition extractive solution comprises folium Artemisiae Argyi extractive solution (water soluble spice, Guangzhou Baiyu Biotechnology limited) and flos Caryophylli extractive solution prepared in preparation example 1 at weight ratio of 2: 1; the antioxidant consists of pentaerythritol tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] and phytic acid (99% of Anhui-Diagnostii bioengineering Co., Ltd.) in the weight ratio of 1: 2;
s2, weighing 42kg of water with the temperature of 70 ℃ for dissolving sodium alginate, and stirring for 5min at the rotating speed of 30r/min to prepare a sodium alginate solution; grinding perlite in a nanometer sand mill to obtain a powder with a particle size of 50-100 nm; placing disperse red, a leveling agent, glacial acetic acid, a sodium alginate solution and 5kg of water in a stirring kettle, and stirring at the rotating speed of 50r/min at the temperature of 40 ℃ for 5min to prepare a dye solution A;
s3, adding titanium dioxide, nano silver powder, perlite and a thickening agent into the dye solution A, heating to 70 ℃ at a heating rate of 5 ℃/min, then heating to 110 ℃ at a heating rate of 2 ℃/min, heating to 135 ℃ at a heating rate of 5 ℃/min, stirring for 18min at a stirring speed of 80r/min, and standing for 26min to obtain a dye solution B;
s4, adding the traditional Chinese medicine composition extracting solution and the antioxidant into the dye solution B, keeping the temperature at 135 ℃, and stirring for 8min at the stirring speed of 50r/min to obtain the flannel dye solution.
Example 2
S1, weighing 20kg of disperse red, 3kg of leveling agent, 5kg of glacial acetic acid, 1kg of titanium dioxide, 1kg of nano silver powder, 1kg of perlite, 1kg of Chinese medicinal composition extracting solution, 3kg of sodium alginate and 0.05kg of antioxidant, wherein the leveling agent consists of glycerol polyoxyethylene ether trioleate and methylene dinaphthalene sodium sulfonate in a weight ratio of 2: 1; the traditional Chinese medicine composition extracting solution consists of folium artemisiae argyi extracting solution and clove extracting solution which are prepared in the preparation example 2 in a weight ratio of 2: 1; the antioxidant consists of pentaerythritol ester and phytic acid in the weight ratio of 1:2 tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ];
s2, weighing 36kg of water with the temperature of 70 ℃ for dissolving sodium alginate, and stirring for 5min at the rotating speed of 30r/min to prepare a sodium alginate solution; grinding perlite in a nanometer sand mill to obtain a powder with a particle size of 50-100 nm; placing disperse red, a leveling agent, glacial acetic acid, a sodium alginate solution and 4kg of water in a stirring kettle, and stirring at the rotating speed of 50r/min at the temperature of 40 ℃ for 5min to prepare a dye solution A;
s3, adding titanium dioxide, nano silver powder, perlite and a thickening agent into the dye solution A, heating to 70 ℃ at a heating rate of 5 ℃/min, then heating to 110 ℃ at a heating rate of 1 ℃/min, heating to 120 ℃ at a heating rate of 5 ℃/min, stirring for 15min at a stirring speed of 80r/min, and standing for 20min to obtain a dye solution B;
s4, adding the traditional Chinese medicine composition extracting solution and the antioxidant into the dye solution B, cooling to 110 ℃, and stirring at the stirring speed of 40r/min for 5min to obtain the flannel dye solution.
Example 3
S1, weighing 30kg of disperse red, 5kg of leveling agent, 9kg of glacial acetic acid, 3kg of titanium dioxide, 3kg of nano silver powder, 3kg of perlite, 3kg of Chinese medicinal composition extracting solution, 6kg of sodium alginate and 0.1kg of antioxidant, wherein the leveling agent consists of glycerol polyoxyethylene ether trioleate and methylene dinaphthalene sodium sulfonate in a weight ratio of 2: 1; the traditional Chinese medicine composition extracting solution consists of folium artemisiae argyi extracting solution and clove extracting solution which are prepared in the preparation example 3 according to the weight ratio of 2: 1; the antioxidant consists of pentaerythritol ester and phytic acid in the weight ratio of 1:2 tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ];
s2, weighing 50kg of water with the temperature of 70 ℃ for dissolving sodium alginate, and stirring for 5min at the rotating speed of 30r/min to prepare a sodium alginate solution; grinding perlite in a nanometer sand mill to obtain a powder with a particle size of 50-100 nm; placing disperse red, a leveling agent, glacial acetic acid, a sodium alginate solution and 5kg of water in a stirring kettle, and stirring at the rotating speed of 50r/min at the temperature of 40 ℃ for 5min to prepare a dye solution A;
s3, adding titanium dioxide, nano silver powder, perlite and a thickening agent into the dye solution A, heating to 70 ℃ at a heating rate of 5 ℃/min, then heating to 110 ℃ at a heating rate of 3 ℃/min, heating to 120 ℃ at a heating rate of 5 ℃/min, stirring for 20min at a stirring speed of 80r/min, and standing for 30min to obtain a dye solution B;
s4, adding the traditional Chinese medicine composition extracting solution and the antioxidant into the dye solution B, heating to 150 ℃ at the heating rate of 5 ℃/min, and stirring for 10min at the stirring rate of 60r/min to obtain the flannel dye solution.
Example 4: the present embodiment is different from embodiment 1 in that:
s1, weighing 26.8kg of dispersing orange (selected from S-4RL, a Shandong Bolefeier chemical Co., Ltd.), 4.2kg of leveling agent, 7.6kg of glacial acetic acid, 2kg of titanium dioxide, 2kg of nano silver powder, 2kg of perlite, 2kg of Chinese medicinal composition extracting solution, 4.2kg of sodium alginate and 0.08kg of antioxidant, wherein the leveling agent consists of glycerol polyoxyethylene ether trioleate and sodium methylenedinaphthalenesulfonate in a weight ratio of 1: 1; the traditional Chinese medicine composition extracting solution consists of folium artemisiae argyi extracting solution and clove extracting solution in a weight ratio of 1: 1; the antioxidant consists of pentaerythritol tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] and phytic acid in a weight ratio of 1: 1.
Example 5: the present embodiment is different from embodiment 1 in that:
s1, weighing 26.8kg of disperse yellow (purity of 82% from Wuhan Yuancheng science and technology development Co., Ltd.), 4.2kg of leveling agent, 7.6kg of glacial acetic acid, 2kg of titanium dioxide, 2kg of nano silver powder, 2kg of perlite, 2kg of traditional Chinese medicine composition extracting solution, 4.2kg of sodium alginate and 0.08kg of antioxidant, wherein the leveling agent consists of glycerol polyoxyethylene ether trioleate and methylene dinaphthalene sodium sulfonate in a weight ratio of 3: 1; the traditional Chinese medicine composition extracting solution consists of folium artemisiae argyi extracting solution and clove extracting solution in a weight ratio of 3: 1; the antioxidant consists of pentaerythritol ester and phytic acid in the weight ratio of 1:3 tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ].
Application example
Selecting knitted polyester fabric as a gray fabric, and performing ironing treatment at the temperature of 165 ℃;
presetting: placing the blank subjected to the ironing treatment in a pre-setting device for pre-setting treatment at the temperature of 210 ℃;
③ dyeing: placing the pre-shaped gray cloth in a dye vat containing dye liquor, dyeing, and washing for 3 times after dyeing to obtain cloth A;
and fourthly, shaping: placing the cloth A in shaping equipment at 180 ℃ for shaping treatment to obtain cloth B;
finishing: putting the cloth B on a fluffer for napping treatment, and then carrying out carding, shearing, heating and shaking treatment and the like to obtain cloth C;
sixthly, shaping the cloth C at 180 ℃ to obtain the flannel.
Comparative example
Comparative example 1: this comparative example differs from example 1 in that: titanium dioxide and perlite are not added in the raw materials.
Comparative example 2: this comparative example differs from example 1 in that: titanium dioxide and nano silver powder are not added in the raw materials.
Comparative example 3: this comparative example differs from example 1 in that: no titanium dioxide was added to the raw material.
Comparative example 4: this comparative example differs from example 1 in that: the raw materials are not added with nonionic dispersants and anionic dispersants.
Comparative example 5: this comparative example differs from example 1 in that: sodium alginate and anionic dispersing agent are not added in the raw materials.
Comparative example 6: this comparative example differs from example 1 in that: sodium alginate and non-ionic dispersing agent are not added in the raw materials.
Comparative example 7: this comparative example differs from example 1 in that: no antioxidant was added to the raw materials.
Comparative example 8: this comparative example differs from example 1 in that: the flos Caryophylli extractive solution is commercially available (water soluble extractive solution of Guangzhou American Biotechnology limited).
Performance test
Dyes were prepared by the preparation methods of examples 1 to 5 and comparative examples 1 to 8, respectively, and then a flannel fabric was prepared from a knitted polyester fabric by the preparation method of the application example.
1. Mite performance test
Taking a flannel fabric sample with the specification of 30mm multiplied by 30mm, placing the flannel fabric sample in a room with the humidity of 60% and the room temperature of 25 ℃, detecting the total quantity of mites on flannel fabric placed for 90 days, then placing the flannel fabric sample in common commercial laundry detergent (natural fragrant laundry detergent with the product number of 3, ZZC.00.010 of Guangzhou Zhen Yan cosmetics Co., Ltd.) for cleaning, airing for 5 hours at the temperature of 25 ℃, 30 ℃ and 35 ℃ after cleaning, ensuring good ventilation of airing environment, and observing the number of live mites of the flannel fabric sample by using a microscope after airing; the mortality rate of the mites was calculated by the change of the number of mites.
The mortality rate is (the total number of mites-the number of live mites)/the total number of mites is multiplied by 100 percent
And (3) detecting the repelling rate and the inhibiting rate of the mites by adopting an evaluation method of the anti-mite performance of the GB/T24253-2009 textile.
Table 1 mite performance test table
According to the data in Table 1, the examples 1-3 have a mortality rate, a repelling rate and an inhibition rate slightly higher than those of the examples 4-5 compared with those of the examples 4-5, which shows that the leveling agent, the Chinese medicinal composition extract and the antioxidant have an influence on the mortality rate, the repelling rate and the inhibition rate; and the change of the temperature has little influence on the death rate, the repelling rate and the inhibition rate, which shows that the titanium dioxide and the nano silver powder have good heat conduction effect and can quickly dry the moisture of the clothes.
Compared with the comparative examples 1 to 8, the raw materials of the comparative example 1 are not added with titanium dioxide and perlite, compared with the example 1, the death rate, the repelling rate and the inhibition rate of the mites of the comparative example 1 are lower than those of the example 1, and the matching of the titanium dioxide and the perlite is illustrated, so that the dye has stronger hydrophilicity, the moisture of the gray cloth can be sucked out conveniently, the moisture can be evaporated quickly under the irradiation of sunlight, and the mites lose water after the moisture evaporation and are inactivated, thereby playing the effects of killing the mites and sterilizing.
Compared with the example 1, the mortality rate, the repelling rate and the inhibition rate of the mites of the comparative example 2 are lower than those of the example 1 because the titanium dioxide and the nano silver powder are not added into the raw materials of the comparative example 2, which shows that the heat conduction effects of the titanium dioxide and the nano silver powder can be used for rapidly promoting the water evaporation, accelerating the water loss and ensuring that the mites can be efficiently killed and sterilized under the effective airing.
Compared with the example 1, the death rate, the repellent rate and the inhibition rate of the mites of the comparative example 3 are lower than those of the example 1, which shows that the titanium dioxide plays an important role in killing and sterilizing the mites, and the heat conductivity of the nano silver powder and the water absorption of the perlite are reduced under the condition that the perlite and the nano silver powder lose the matching of the titanium dioxide, so that the mite killing and sterilizing effects are poor.
Compared with the example 1, the mortality, the repellent rate and the inhibition rate of the mites of the comparative example 4 are lower than those of the example 1, which shows that the nonionic dispersant and the anionic dispersant can uniformly disperse titanium dioxide and perlite in a dye solution and uniformly disperse nano silver powder in pore structures of the titanium dioxide and the perlite, so that the uniform distribution of the titanium dioxide, the perlite and the nano silver powder can accelerate water loss, thereby facilitating the water loss inactivation of the mites, and enabling the dye to have good mite killing and sterilizing effects; and the cooperation of sodium alginate, titanium dioxide and perlite leads to better water absorption effect, and promotes the evaporation of water under the cooperation of titanium dioxide and nano silver powder.
The raw material of the comparative example 5 is not added with the sodium alginate and the anionic dispersing agent, compared with the raw material of the example 1, the death rate, the repelling rate and the inhibition rate of the mites of the comparative example 5 are lower than those of the example 1 but are not changed greatly, and the fact that the combination of the sodium alginate and the anionic dispersing agent has an influence on the death rate, the repelling rate and the inhibition rate of the mites is shown.
The raw material of the comparative example 6 is not added with the sodium alginate and the cationic dispersant, compared with the raw material of the example 1, the death rate, the repelling rate and the inhibition rate of the acarid of the comparative example 6 are lower than those of the example 1 but are slightly changed, and the fact that the combination of the sodium alginate and the cationic dispersant has influence on the death rate, the repelling rate and the inhibition rate of the acarid is shown.
Comparative example 7 no antioxidant is added to the raw material, comparative example 8 is a commercial clove extracting solution to prepare the dye solution, and the mite mortality, the repelling rate and the inhibition rate of comparative example 7 and comparative example 8 are slightly changed, which shows that the mite mortality, the repelling rate and the inhibition rate of the antioxidant and the commercial clove extracting solution are slightly influenced.
2. Ultraviolet Performance test
And (2) respectively carrying out ultraviolet transmittance detection on the flannel fabrics prepared by the dye by adopting a GB/T17032-1997 textile fabric ultraviolet transmittance test method.
3. Color distribution uniformity test
Respectively preparing dye liquor by adopting the preparation methods of the examples 1-5 and the comparative examples 1-8, and after the gray cloth is dip-dyed by the dye liquor, grading the dyeing uniformity and marking as the gray cloth A; flannel fabrics made from the dyes prepared in examples 1 to 5 and comparative examples 1 to 8 were dried in the air at 30 ℃ for 6 hours, and the degree of uniformity of the flannel fabric color was scored as greige fabric B: the scoring criteria were as follows:
the color distribution is not uniform for 1-4 minutes; the color distribution is relatively uniform, no obvious color difference exists, and no obvious color gradient exists for 4-7 minutes; the color is distributed evenly, has no color difference and has no color gradient of 7 to 10 portions.
4. Color purity test
The dye liquors were prepared according to the preparation methods of examples 1 to 5 and comparative examples 1 to 8, respectively, and the prepared dye liquors were compared with the corresponding colors (for example, the dye prepared by using disperse red in example 1 was compared with the color of disperse red), respectively, and the evaluation criteria for the purity were as follows:
the color turns yellow and no red color is 1-4 points; the color is orange, which is 4 to 7 minutes close to red; 7-10 parts of red.
Table 2 flannel cloth ultraviolet performance test and dye liquor color performance test table
As shown by the data in table 2, in comparison between examples 1 to 5 and comparative examples 1 to 8, the raw material of comparative example 1 is not added with titanium dioxide and perlite, the raw material of comparative example 2 is not added with titanium dioxide and nano silver powder, and the raw material of comparative example 3 is not added with titanium dioxide, and the ultraviolet transmittance, the uniformity fraction and the color purity fraction of comparative examples 1, 2 and 3 are less different than those of example 1, indicating that the titanium dioxide, perlite and nano silver powder have less influence on the ultraviolet transmittance, the uniformity fraction and the color purity.
Compared with the example 1, the ultraviolet transmittance, the uniformity fraction and the color purity of the raw material of the comparative example 4 are reduced, which shows that the dye liquor has good level dyeing, slow dyeing and stability due to the matching of the nonionic dispersant and the anionic dispersant.
Compared with the example 1, the ultraviolet transmittance, the uniformity fraction and the color purity of the raw material of the comparative example 5 are reduced, which shows that the prepared dye has good thermal stability and the sodium alginate also has good permeability due to the matching of the sodium alginate and the anionic dispersing agent.
And sodium alginate and a nonionic dispersing agent are not added in the raw material of the comparative example 6, compared with the example 1, the ultraviolet transmittance, the uniformity fraction and the color purity of the comparative example 6 are reduced, and the matching of the sodium alginate and the nonionic dispersing agent ensures that the prepared dye is more uniformly colored, brighter in chromaticity and clear in line.
Compared with the example 1, the ultraviolet transmittance of the comparative example 7 is less in change and the pure color fraction is reduced, which shows that the surface of the clothes has the anti-oxidation effect due to the addition of the antioxidant, so that the phenomenon of color fading of the flannel fabric after being aired is avoided.
Comparative example 8 is prepared by using a commercially available clove extracting solution, and compared with example 1, the purity of the color of the dye prepared by the disperse dye is reduced in comparative example 8, which shows that the purity of the color of the dye prepared by the disperse dye is influenced when the commercially available clove extracting solution is not subjected to decoloration treatment.
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.
Claims (10)
1. A flannel dye liquor is characterized in that the dye liquorByComprises the following raw materials in parts by weightIs made into: 20-30 parts of disperse dye, 3-5 parts of leveling agent, 5-9 parts of glacial acetic acid, 1-3 parts of titanium dioxide, 1-3 parts of nano silver powder, 1-3 parts of perlite, 1-3 parts of traditional Chinese medicine composition extracting solution, 3-6 parts of thickening agent, 0.05-0.1 part of antioxidant and 40-55 parts of water.
2. The flannel dye liquor according to claim 1, wherein the traditional Chinese medicine composition extract is composed of folium artemisiae argyi extract and clove extract in a weight ratio of 2: 1.
3. The flannel dye liquor according to claim 1, wherein the leveling agent is composed of a nonionic dispersant and an anionic dispersant in a weight ratio of 2: 1.
4. The flannel dye liquor according to claim 1, wherein the non-ionic dispersant is glycerol polyoxyethylene ether trioleate and the anionic dispersant is sodium methylene dinaphthalenesulfonate.
5. The dye liquor for flannel, according to claim 1, wherein the thickener is sodium alginate.
6. The dye liquor for flannel according to claim 1, wherein the antioxidant is composed of pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] and phytic acid in a weight ratio of 1: 2.
7. A process for preparing a flannel dye liquor according to any one of claims 1 to 6, comprising the steps of:
s1, weighing the raw materials according to the proportion, and stirring the disperse dye, the leveling agent, glacial acetic acid, the thickening agent and water at the temperature of 40 ℃ for 5min to prepare a dye solution A;
s2, adding titanium dioxide, nano silver powder and perlite into the dye solution A, heating to 120-150 ℃, and stirring at a stirring speed of 80r/min for 15-20min to obtain a dye solution B;
s3, adding the traditional Chinese medicine composition extracting solution and the antioxidant into the dye solution B, and stirring for 5-10min at the stirring speed of 40-60r/min under the condition of 110-150 ℃ to obtain the flannel dye solution.
8. The method for preparing a flannel dye liquor according to claim 7, wherein the clove extract in the S3 traditional Chinese medicine composition is prepared by the following method:
1) the weight portion is: weighing 4-6 parts of clove, 40-60 parts of water, 70-100 parts of ethanol and 0.1-0.4 part of activated carbon;
2) pulverizing flos Caryophylli, placing in water, precooking at 60 deg.C for 1-2 hr, filtering, and collecting filtrate to obtain extractive solution A;
3) placing activated carbon in a filter bag to obtain an activated carbon bag, extracting the activated carbon bag and the extracting solution A in ethanol at 90 deg.C for 5-7 hr, concentrating, filtering, and collecting the filtrate to obtain flos Caryophylli extracting solution.
9. The method for preparing a flannel dye liquor according to claim 7, wherein the step of stirring at a stirring speed of 80r/min for 15-20min in S2, and then the mixture is kept warm and kept stand for 20-30 min.
10. The method for preparing a flannel dye liquor according to claim 7, wherein the temperature rise rate is ensured to be 1-3 ℃/min when the temperature of S2 is in the temperature range of 70-110 ℃.
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