CN111720848A - A system for reducing flue gas temperature at the outlet of wet desulfurization absorption tower - Google Patents
A system for reducing flue gas temperature at the outlet of wet desulfurization absorption tower Download PDFInfo
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- 238000010521 absorption reaction Methods 0.000 title claims abstract description 29
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title abstract description 47
- 239000003546 flue gas Substances 0.000 title abstract description 46
- 238000006477 desulfuration reaction Methods 0.000 title abstract description 44
- 230000023556 desulfurization Effects 0.000 title abstract description 44
- 238000001816 cooling Methods 0.000 claims abstract description 64
- 239000000498 cooling water Substances 0.000 claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002002 slurry Substances 0.000 claims description 21
- 229910001039 duplex stainless steel Inorganic materials 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims 10
- 238000005507 spraying Methods 0.000 claims 3
- 230000003009 desulfurizing effect Effects 0.000 claims 1
- 239000007921 spray Substances 0.000 abstract description 11
- 239000003595 mist Substances 0.000 abstract description 7
- 230000009466 transformation Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 230000005494 condensation Effects 0.000 description 5
- 238000009833 condensation Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- 239000000428 dust Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000009418 renovation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/06—Arrangements of devices for treating smoke or fumes of coolers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/20—Sulfur; Compounds thereof
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Abstract
本发明涉及工业烟气污染治理技术领域,具体为一种降低湿法脱硫吸收塔出口烟温的系统。本发明系统包括设置在脱硫塔筒体外的冷却水塔,以及设置在脱硫塔筒体内且与冷却水塔连接的若干个降温模块;所述的降温模块设置在脱硫塔内最上层喷淋层与塔内除雾器之间,以及其余各层喷淋层下方;所述的降温模块包括若干冷却水管,冷却水管与脱硫塔筒体通过法兰连接;冷却水管的一端通过降温模块进水管道与冷却水塔的出水口连接,另一端通过降温模块出水管道与冷却水塔的进水口连接。本发明不仅能有效实现吸收塔后烟温降低,而且能减少脱硫塔出口烟气的液滴携带量,改造工程量小、系统简单、投资费用低、适应性大。
The invention relates to the technical field of industrial flue gas pollution control, in particular to a system for reducing the flue gas temperature at the outlet of a wet desulfurization absorption tower. The system of the invention includes a cooling water tower arranged outside the desulfurization tower cylinder, and several cooling modules arranged inside the desulfurization tower cylinder and connected with the cooling water tower; the cooling modules are arranged in the uppermost spray layer in the desulfurization tower and inside the tower Between the mist eliminators and below the other spray layers; the cooling module includes a number of cooling water pipes, and the cooling water pipes are connected with the cylinder of the desulfurization tower through flanges; one end of the cooling water pipe passes through the cooling module inlet pipe and the cooling water tower. The water outlet of the cooling module is connected to the water outlet, and the other end is connected to the water inlet of the cooling water tower through the water outlet pipe of the cooling module. The invention can not only effectively reduce the flue gas temperature after the absorption tower, but also reduce the droplet carrying amount of the flue gas at the outlet of the desulfurization tower, and has the advantages of small transformation engineering quantity, simple system, low investment cost and large adaptability.
Description
技术领域technical field
本发明涉及工业烟气污染治理技术领域,具体为一种降低湿法脱硫吸收塔出口烟温的系统。The invention relates to the technical field of industrial flue gas pollution control, in particular to a system for reducing the flue gas temperature at the outlet of a wet desulfurization absorption tower.
背景技术Background technique
众所周知,湿法脱硫技术在国内工业燃煤锅炉烟气脱硫技术中占据主导地位。然而,采用湿法脱硫技术的工业燃煤锅炉,吸收塔出口湿饱和烟气在经烟囱排出的过程遇冷,产生过饱和凝结从而形成白色烟羽。对此,由于各方面的因素,需要对工业燃煤锅炉吸收塔出口的烟气温度及含湿量进行治理,严格控制器排放值,实现烟羽消白。As we all know, wet desulfurization technology occupies a dominant position in the flue gas desulfurization technology of domestic industrial coal-fired boilers. However, in industrial coal-fired boilers using wet desulfurization technology, the wet saturated flue gas at the outlet of the absorption tower is cooled during the process of being discharged through the chimney, resulting in supersaturated condensation and white plumes. In this regard, due to various factors, it is necessary to control the temperature and moisture content of the flue gas at the outlet of the absorption tower of the industrial coal-fired boiler, and strictly control the emission value to achieve whitening of the plume.
为实现烟囱出口白色烟羽的治理,目前比较主流的技术都是对吸收塔出口烟气先进行冷凝降温,再进行加热升温,最终实现消白。冷凝降温是烟羽治理过程中非常必要的一个环节,它一方面实现了烟气含湿量的降低达到了“减白”的目的;另一方面饱和烟气冷凝后析出大量细小的液滴,液滴可吸附少量粉尘、SO2、SO3等污染物颗粒,起到进一步脱除污染物的作用。现阶段烟气冷凝技术比较常用的有吸收塔后气-液冷凝管式换热器和在吸收塔外浆液循环管道设置液-液浆液板式换热器。前者运行业绩较多,但改造工程量非常大,且对吸收塔与烟囱之间的空间有很高的要求,因为其通常布置在吸收塔与烟囱之间的净烟道上,气-液冷凝管式换热器内的流速远远低于净烟道内的烟气流速,布置气-液冷凝管式换热器的位置往往需要进行较大的烟道变截面;并且为防止烟气对冷凝液产生二次携带,往往需要在气-液冷凝管式换热器后增设烟道除雾器,增加了脱硫系统的复杂性及水耗。后者的运行业绩较少,液-液浆液板式换热器运行的工况恶劣,容易造成堵塞及换热器本体的磨损,且一旦换热器本体发生故障时需停运其对应的浆液循环泵进行检修,对脱硫系统的运行产生极大的压力。In order to achieve the control of white plume at the chimney outlet, the current mainstream technology is to first condense and cool the flue gas at the outlet of the absorption tower, and then heat it up, and finally achieve whitening. Condensation and cooling is a very necessary link in the process of plume control. On the one hand, it achieves the reduction of the moisture content of the flue gas and achieves the purpose of "whitening"; The droplets can absorb a small amount of dust, SO 2 , SO 3 and other pollutant particles to further remove pollutants. At present, the commonly used flue gas condensation technologies are the gas-liquid condensation tube heat exchanger after the absorption tower and the liquid-liquid slurry plate heat exchanger set in the slurry circulation pipeline outside the absorption tower. The former has a lot of performance, but the amount of reconstruction work is very large, and it has high requirements for the space between the absorption tower and the chimney, because it is usually arranged on the clean flue between the absorption tower and the chimney, and the gas-liquid condenser The flow rate in the heat exchanger is much lower than that of the flue gas in the clean flue. The location of the gas-liquid condensing tube heat exchanger often requires a larger flue cross-section; and in order to prevent the flue gas from affecting the condensate To produce secondary carryover, it is often necessary to add a flue demister after the gas-liquid condenser tube heat exchanger, which increases the complexity and water consumption of the desulfurization system. The latter has less operating performance, and the liquid-liquid slurry plate heat exchanger operates in poor operating conditions, which is easy to cause blockage and wear of the heat exchanger body, and once the heat exchanger body fails, its corresponding slurry circulation needs to be shut down. The pump is overhauled, which puts great pressure on the operation of the desulfurization system.
发明内容SUMMARY OF THE INVENTION
针对现有技术中存在的问题,本发明提供一种降低湿法脱硫吸收塔出口烟温的系统,不仅能有效实现吸收塔后烟温降低、烟气含湿量降低及冷凝液不被烟气带出吸收塔,而且具有一定除雾器的功能,能减少脱硫塔出口烟气的液滴携带量;此系统改造工程量小、系统简单、投资费用低、适应性大。In view of the problems existing in the prior art, the present invention provides a system for reducing the flue gas temperature at the outlet of the wet desulfurization absorption tower, which can not only effectively reduce the flue gas temperature after the absorption tower, reduce the moisture content of the flue gas, and prevent the condensate from being absorbed by the flue gas The absorption tower is taken out, and it has the function of a certain mist eliminator, which can reduce the droplet carrying amount of the flue gas at the outlet of the desulfurization tower; the system has a small amount of renovation work, a simple system, low investment cost, and large adaptability.
本发明是通过以下技术方案来实现:The present invention is achieved through the following technical solutions:
一种降低湿法脱硫吸收塔出口烟温的系统,包括设置在脱硫塔筒体外的冷却水塔,以及设置在脱硫塔筒体内且与冷却水塔连接的若干个降温模块;所述的降温模块设置在脱硫塔内最上层喷淋层与塔内除雾器之间,以及其余各层喷淋层下方。A system for reducing flue gas temperature at the outlet of a wet desulfurization absorption tower, comprising a cooling water tower arranged outside the desulfurization tower cylinder, and several cooling modules arranged inside the desulfurization tower and connected to the cooling water tower; the cooling modules are arranged in the Between the uppermost spray layer in the desulfurization tower and the mist eliminator in the tower, and below the other spray layers.
优选的,所述的降温模块包括若干冷却水管,冷却水管与脱硫塔筒体通过法兰连接;冷却水管的一端通过降温模块进水管道与冷却水塔的出水口连接,另一端通过降温模块出水管道与冷却水塔的进水口连接。Preferably, the cooling module includes a plurality of cooling water pipes, and the cooling water pipes are connected with the shell of the desulfurization tower through flanges; one end of the cooling water pipe is connected with the water outlet of the cooling water tower through the cooling module inlet pipe, and the other end is connected through the cooling module outlet pipe. Connect with the water inlet of the cooling water tower.
进一步的,所述的冷却水管的管径范围为φ20mm-φ500mm。Further, the diameter of the cooling water pipe ranges from φ20mm to φ500mm.
进一步的,所述的冷却水管采用双相不锈钢材质制成。Further, the cooling water pipe is made of duplex stainless steel.
进一步的,所述的每根冷却水管的进水管道分别设置有阀门。Further, the water inlet pipes of each cooling water pipe are respectively provided with valves.
进一步的,所述的冷却水管呈一层设置,采用直型管束式或蛇形管束式。Further, the cooling water pipes are arranged in one layer and adopt a straight tube bundle type or a serpentine tube bundle type.
进一步的,所述的若干冷却水管呈上下两层设置,每层中的若干冷却水管采用直型管束式,上下两层呈交错铺设。Further, the plurality of cooling water pipes are arranged in upper and lower layers, and the plurality of cooling water pipes in each layer are of straight tube bundle type, and the upper and lower layers are laid in a staggered manner.
优选的,所述的降温模块进水管道通过若干个连接支管与若干个降温模块连接;所述的连接支管上均设置有降温模块进水控制阀门。Preferably, the water inlet pipeline of the cooling module is connected with a plurality of cooling modules through a plurality of connecting branch pipes; the connecting branch pipes are all provided with water inlet control valves of the cooling module.
优选的,所述的降温模块进水管道和降温模块出水管道上均设置有压力和温度测试元件。Preferably, pressure and temperature test elements are provided on the cooling module water inlet pipe and the cooling module water outlet pipe.
优选的,所述的降温模块进水管道上安装有冷却水循环泵;所述的浆液池和喷淋层的连接管道上分别设置有浆液循环泵。Preferably, a cooling water circulating pump is installed on the water inlet pipe of the cooling module; and a slurry circulating pump is respectively installed on the connecting pipes of the slurry pool and the spray layer.
与现有技术相比,本发明具有以下有益的技术效果:Compared with the prior art, the present invention has the following beneficial technical effects:
本发明通过在脱硫塔内最上层喷淋层与塔内除雾器之间及各层喷淋层下方设置降温模块,使该降温模块直接与塔内烟气进行接触换热,从而实现塔内烟气降温,饱和湿烟气冷凝,冷凝液随烟气一起通过塔内除雾器时,直接被拦截进入吸收塔,从而降低了脱硫运行过程中的脱硫浆液温度和脱硫塔内的烟温,进而降低脱硫塔的排烟温度及浆液温度;在脱硫塔内烟气降温过程中,烟气中的可溶性盐、硫酸雾、有机物等物质随着烟气中水蒸气的冷凝而析出,能有效缓解烟囱出口的有色烟羽排放,并避免烟囱石膏雨的产生;同时,低温浆液可以降低塔内烟气量,提高脱硫装置的液气比,提高脱硫效率和协同除尘效果,相对于现有烟道冷凝换热器,新增电耗小,改造工程量小,投资小,运行可靠,检修维护简单;而且,能根据季节环境温度不同,冷却水温度不同,通过控制浆液降温模块的冷却水量来灵活调节脱硫浆液的温度。In the present invention, a cooling module is arranged between the uppermost spray layer in the desulfurization tower and the mist eliminator in the tower and under each spray layer, so that the cooling module directly contacts the flue gas in the tower for heat exchange, so as to realize the cooling effect in the tower. The flue gas is cooled, the saturated wet flue gas is condensed, and when the condensate passes through the demister in the tower together with the flue gas, it is directly intercepted and enters the absorption tower, thereby reducing the desulfurization slurry temperature and the flue gas temperature in the desulfurization tower during the desulfurization operation. Then reduce the flue gas temperature and slurry temperature of the desulfurization tower; in the process of flue gas cooling in the desulfurization tower, soluble salts, sulfuric acid mist, organic matter and other substances in the flue gas are precipitated with the condensation of water vapor in the flue gas, which can effectively alleviate the The colored plume at the chimney outlet is discharged, and the generation of gypsum rain from the chimney is avoided; at the same time, the low-temperature slurry can reduce the amount of flue gas in the tower, improve the liquid-gas ratio of the desulfurization device, and improve the desulfurization efficiency and synergistic dust removal effect. Compared with the existing flue The condensing heat exchanger has small new power consumption, small amount of renovation work, small investment, reliable operation, simple maintenance and repair; moreover, it can be flexibly controlled by controlling the cooling water volume of the slurry cooling module according to the different ambient temperature and the temperature of the cooling water in the season. Adjust the temperature of the desulfurization slurry.
进一步,采用双相不锈钢及以上的材质制成降温模块中的冷却水管,从而保证冷却水管耐腐蚀耐冲刷磨损,机械性能好,而且强度高。Further, the cooling water pipes in the cooling module are made of duplex stainless steel and above, so as to ensure that the cooling water pipes are resistant to corrosion, erosion and wear, have good mechanical properties, and have high strength.
进一步,采用在每根冷却水管的进口管道设置阀门单独控制的方式,确保冷却水管在故障或损坏时可单独解列不影响整个降温装置的正常运行。Further, the method of setting valves for independent control at the inlet pipe of each cooling water pipe is adopted to ensure that the cooling water pipe can be de-coupled separately without affecting the normal operation of the entire cooling device in the event of failure or damage.
进一步,通过在降温模块进水管道和降温模块出水管道上分别设置压力和温度测试元件,能有效监测冷却水管的运行压力和温度。Further, by disposing pressure and temperature test elements respectively on the water inlet pipe of the cooling module and the water outlet pipe of the cooling module, the operating pressure and temperature of the cooling water pipe can be effectively monitored.
附图说明Description of drawings
图1为本发明系统的结构示意图。FIG. 1 is a schematic structural diagram of the system of the present invention.
图2为本发明实施例1所述降温模块的结构示意图。FIG. 2 is a schematic structural diagram of the cooling module according to Embodiment 1 of the present invention.
图3为本发明实施例2所述降温模块的结构示意图。FIG. 3 is a schematic structural diagram of the cooling module according to
图4为本发明实施例3所述降温模块的结构示意图。FIG. 4 is a schematic structural diagram of the cooling module according to
图中:1-冷却水塔、2-脱硫塔烟气入口、3-浆液池、41-冷却水循环泵、42-浆液循环泵、5-降温模块、51-冷却水管、6-脱硫塔烟气出口、7-降温模块进水管道、8-喷淋层、9-降温模块进水控制阀门、10-降温模块出水管道、11-脱硫塔筒体、12-除雾器。In the picture: 1- cooling water tower, 2- flue gas inlet of desulfurization tower, 3- slurry pool, 41- cooling water circulation pump, 42- slurry circulation pump, 5- cooling module, 51- cooling water pipe, 6- desulfurization tower flue gas outlet , 7- cooling module inlet pipe, 8- spray layer, 9- cooling module inlet control valve, 10- cooling module outlet pipe, 11- desulfurization tower cylinder, 12- demister.
具体实施方式Detailed ways
下面结合附图对本发明做进一步的详细说明,所述是对本发明的解释而不是限定。The present invention will be further described in detail below in conjunction with the accompanying drawings, which are to explain rather than limit the present invention.
实施例1Example 1
本发明一种降低湿法脱硫吸收塔出口烟温的系统,如图1所示,包括脱硫塔筒体11、除雾器12、脱硫塔烟气入口2、脱硫塔烟气出口6、浆液池3、喷淋层8、浆液循环泵42、降温模块5、冷却水管51、冷却水塔1、冷却水循环泵41、降温模块进水管道7、降温模块进水控制阀门9、降温模块出水管道10;A system for reducing the flue gas temperature at the outlet of the wet desulfurization absorption tower of the present invention, as shown in FIG. 1 , includes a
脱硫塔筒体11内脱硫浆液经浆液循环泵42进入多层喷淋层8后从上往下落,烟气从脱硫塔烟气入口2自下而上进入脱硫塔筒体11内,烟气不仅和喷淋浆液进行逆流接触降温,而且通过多层降温模块5中的若干冷却水管51进行进一步换热降温,在此过程中,湿饱和烟气变成过饱和湿烟气,烟气中的水蒸气、可溶性盐、硫酸雾、有机物等物质从烟气中冷凝析出,缓解烟囱出口有色烟羽及烟囱石膏雨的产生,处理后的烟气经除雾器12从脱硫塔烟气出口6排出;The desulfurization slurry in the
换热后的高温冷却水经降温模块出水管道10进入冷却水塔1冷却,冷却后的低温冷却水经降温模块进水管道7和冷却水循环泵41进入降温模块5与脱硫浆液和烟气换热;The high-temperature cooling water after heat exchange enters the cooling water tower 1 through the cooling
其中,降温模块5中的冷却水管51采用直型管束式,如图2所示,加工简单,维护方便。Among them, the
针对不同电厂的冷却水水源不同,本发明的冷却水水源可采用冷却水塔1中的循环水、江河水或者海水等。According to the different cooling water sources of different power plants, the cooling water source of the present invention may adopt circulating water, river water or sea water in the cooling water tower 1 .
实施例2Example 2
本发明一种降低湿法脱硫吸收塔出口烟温的系统,如图3所示,降温模块5中的冷却水管51采用蛇形管束式,增加了冷却水管51的作用面积,提高了冷却效率,其余结构与实施例1中所述相同。The present invention is a system for reducing the flue gas temperature at the outlet of the wet desulfurization absorption tower. As shown in FIG. 3 , the
实施例3Example 3
本发明一种降低湿法脱硫吸收塔出口烟温的系统,如果出口烟温较高,可采用如图4所示的降温模块5,图4中的降温模块5中的冷却水管51采用上下交错铺设的直型管束式,其余结构与实施例1中所述相同。The present invention is a system for reducing the flue gas temperature at the outlet of the wet desulfurization absorption tower. If the flue gas temperature at the outlet is high, the cooling module 5 as shown in FIG. 4 can be used. The
上述实施例1-3为本发明的降温模块5较佳实施例,并不用以限制本发明,降温模块5型式在本发明的原则内可做任何修改、改进或者等效替换。The above-mentioned embodiments 1-3 are the preferred embodiments of the cooling module 5 of the present invention, and are not intended to limit the present invention. The type of the cooling module 5 can be modified, improved or equivalently replaced within the principles of the present invention.
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