CN111691187A - Broad-spectrum antiviral antibacterial cap - Google Patents
Broad-spectrum antiviral antibacterial cap Download PDFInfo
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- CN111691187A CN111691187A CN202010541540.6A CN202010541540A CN111691187A CN 111691187 A CN111691187 A CN 111691187A CN 202010541540 A CN202010541540 A CN 202010541540A CN 111691187 A CN111691187 A CN 111691187A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- A—HUMAN NECESSITIES
- A42—HEADWEAR
- A42B—HATS; HEAD COVERINGS
- A42B1/00—Hats; Caps; Hoods
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
The invention relates to a broad-spectrum antiviral antibacterial cap, which is prepared by modifying common cloth to obtain modified cloth, cutting the modified cloth to obtain the broad-spectrum antiviral antibacterial cap, wherein the modification treatment comprises the following steps: adding an oxygen anion material into amino silicone oil according to the mass ratio of 3-8% to form a modifier; spraying a modifier on the common cloth; and after the spraying is finished, naturally drying or drying to obtain the modified cloth. The broad-spectrum antiviral and antibacterial cap can kill more than 90% of viruses and harmful bacteria in a broad spectrum, and can release negative oxygen ions for a long time.
Description
Technical Field
The invention relates to the technical field of clothes accessories, in particular to a broad-spectrum antiviral antibacterial hat.
Background
Hats are items of apparel that are worn on the head, and most can cover the entire top of the head. The hat is mainly used for protecting the head, and a part of the hat has a protruding edge which can cover the sunlight. The hat has the functions of shading, decorating, warming, protecting and the like, and is widely used in daily life.
Generally, the frequency of cleaning the cap is low, and after the cap is worn, grease on the head and dirt in the air can be attached to the cap, and a large amount of bacteria or dust mites can be attached to the grease and the dirt, so that the health of the scalp of a human body can be damaged, and diseases can be caused in serious cases. The traditional cap has no functions of resisting virus and inhibiting bacteria.
Therefore, if an antiviral and bactericidal cap which is effective for a long time can be designed, the method has great significance and wide application prospect for the life health of people.
Disclosure of Invention
The invention provides a broad-spectrum antiviral and antibacterial cap, solves the technical problem that the traditional cap does not have the antiviral and antibacterial functions, and achieves the technical effect of providing a broad-spectrum antiviral and antibacterial cap which can kill more than 90 percent of viruses and harmful bacteria in a broad spectrum and can release negative oxygen ions for a long time.
The invention provides a broad-spectrum antiviral antibacterial cap, which is prepared by modifying common cloth to obtain modified cloth, cutting the modified cloth to obtain the broad-spectrum antiviral antibacterial cap, wherein the modification treatment comprises the following steps:
adding an oxygen anion material into amino silicone oil according to the mass ratio of 3-8% to form a modifier;
spraying the modifier on the common cloth;
and after the spraying is finished, naturally drying or drying to obtain the modified cloth.
Preferably, the mass ratio of the oxygen anion material to the amino silicone oil is 5%.
Preferably, the preparation method of the negative oxygen ion material comprises the following steps:
preparing natural plant mixed slurry;
fermenting the natural plant mixed slurry to obtain a fermentation product;
extracting the fermentation product to obtain plant essential oil;
adding the plant essential oil into porous diatomite, stirring uniformly, and baking to obtain a baked product;
and grinding the cooled baked product to obtain a finished product of the negative oxygen ion material.
Preferably, the preparation of the natural plant mixed slurry specifically comprises the following steps: the natural plant mixed slurry is prepared by mixing 1-5 parts of folium artemisiae argyi, 10-25 parts of chrysanthemum coronarium, 10-25 parts of lettuce, 10-25 parts of watercress, 5-15 parts of chives, 1-5 parts of eucalyptus leaves, 1-5 parts of camphor leaves, 1-5 parts of reeds, 10-20 parts of water hyacinth and 5-15 parts of garlic in parts by mass and then mashing the mixture.
Preferably, the fermentation of the natural plant mixed slurry is specifically as follows:
and (3) putting the natural plant mixed slurry into a sealed stainless steel fermentation tank for fermentation, wherein the fermentation time is controlled to be 25-35 days.
Preferably, the extraction of the fermentation product is specifically: and (3) extracting the fermentation product by using edible alcohol with the purity of 95% as an extraction liquid, wherein the mass ratio of the edible alcohol to the fermentation product is 1 (1-3).
Preferably, the temperature in the baking process is controlled to be 40-55 ℃, and the time is controlled to be 10-16 hours.
Preferably, the fermentation process starts on the third day, and the stainless steel fermenter is vented at a frequency of 2 times per day.
Preferably, the particle size of the porous diatomite is 60 nanometers after grinding; the particle size of the negative oxygen ion material is 30 nanometers.
One or more technical solutions provided in the embodiments of the present application have at least the following technical effects or advantages:
mixing various natural plants by utilizing biotechnology to prepare slurry, then obtaining plant essential oil by fermentation technology and extraction, finally mixing the plant essential oil with porous diatomite to form a negative oxygen ion material, mixing the negative oxygen ion material with amino silicone oil according to a specific ratio to form a modifier, and spraying the modifier on the traditional cloth to prepare the broad-spectrum antiviral antibacterial cap; because the porous diatomite has the characteristics of large porosity, strong absorptivity and stable chemical property, on one hand, the porous diatomite is used as a carrier to fill plant essential oil in pores of the diatomite, and the plant essential oil can slowly release negative oxygen ions for a long time under the irradiation of ultraviolet rays, thereby further playing the effect of purifying air and killing more than 90 percent of viruses and harmful bacteria in a broad spectrum; on the other hand, the porous diatomite can rapidly adsorb formaldehyde and tvoc and remove various peculiar smells. The technical problem that the traditional cap does not have the functions of resisting and inhibiting viruses is solved or partially solved, and the technical effect that the broad-spectrum anti-virus and anti-bacteria cap can kill more than 90 percent of viruses and harmful bacteria in a broad spectrum and can release negative oxygen ions for a long time is achieved.
Drawings
FIG. 1 is a schematic flow chart of a method for preparing an antiviral and bacteriostatic negative oxygen ion material provided by an embodiment of the present application;
fig. 2 is a schematic flow chart of a broad-spectrum antiviral and antibacterial cap modification treatment method provided in the embodiment of the present application.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
Referring to the attached figure 1, the preparation method of the antiviral and antibacterial negative oxygen ion material provided by the invention comprises the following steps:
s1: preparing natural plant mixed slurry, which specifically comprises the following steps: according to the mass parts, 1-5 parts of folium artemisiae argyi, 10-25 parts of chrysanthemum coronarium, 10-25 parts of lettuce, 10-25 parts of watercress, 5-15 parts of chives, 1-5 parts of eucalyptus leaves, 1-5 parts of camphor leaves, 1-5 parts of reeds, 10-20 parts of water hyacinth and 5-15 parts of garlic are mixed and smashed to form natural plant mixed slurry, and chlorophyll can be extracted from the folium artemisiae argyi, the chrysanthemum coronarium, the lettuce, the watercress, the chives, the eucalyptus leaves and the camphor leaves in the smashing process.
S2: fermenting the natural plant mixed slurry to obtain a fermentation product, which specifically comprises the following steps: and (3) putting the natural plant mixed slurry into a sealed stainless steel fermentation tank for fermentation, wherein the fermentation time is controlled to be 25-35 days. The fermentation process was started on the third day, and the stainless steel fermenter was vented at a frequency of 2 times per day.
S3: extracting the fermentation product to obtain plant essential oil, which specifically comprises the following steps: and (3) extracting the fermentation product by using edible alcohol with the purity of 95% as an extraction liquid, wherein the mass ratio of the edible alcohol to the fermentation product is 1 (1-3).
S4: adding plant essential oil into porous diatomite, stirring uniformly, and baking to obtain a baked product; the particle size of the porous diatomite is 60 nanometers after grinding; the temperature in the baking process is controlled to be 40-55 ℃, and the time is controlled to be 10-16 hours.
S5: grinding the cooled baked product to obtain a finished product of the negative oxygen ion material; the particle size of the negative oxygen ion material is 30 nanometers.
Based on the same inventive concept, the application also provides an antiviral and antibacterial cap, wherein the common cloth is modified to obtain modified cloth, the modified cloth is cut into broad-spectrum antiviral and antibacterial caps, and the modification treatment comprises the following steps:
s10: adding an oxygen anion material into amino silicone oil according to the mass ratio of 3-8% to form a modifier;
s20: spraying the modifier on common cloth;
s30: after the spraying is finished, natural drying or drying is carried out to obtain modified cloth, and the drying temperature is generally 60 ℃.
Furthermore, the mass ratio of the negative oxygen ion material to the amino silicone oil is 5%.
Mixing various natural plants by utilizing biotechnology to prepare slurry, then obtaining plant essential oil by fermentation technology and extraction, finally mixing the plant essential oil with porous diatomite to form a negative oxygen ion material, mixing the negative oxygen ion material with amino silicone oil according to a specific ratio to form a modifier, and spraying the modifier on the traditional cloth to prepare the broad-spectrum antiviral antibacterial cap; because the porous diatomite has the characteristics of large porosity, strong absorptivity and stable chemical property, on one hand, the porous diatomite is used as a carrier to fill plant essential oil in pores of the diatomite, and the plant essential oil can slowly release negative oxygen ions for a long time under the irradiation of ultraviolet rays, thereby further playing the effect of purifying air and killing more than 90 percent of viruses and harmful bacteria in a broad spectrum; on the other hand, the porous diatomite can rapidly adsorb formaldehyde and tvoc and remove various peculiar smells. Therefore, the antivirus and antibacterial cap can kill more than 90% of viruses and harmful bacteria in a broad spectrum, and can release negative oxygen ions for a long time to ensure scalp and human health.
Although hundreds of bacteria and viruses can be killed in other sterilization products such as nano silver, chlorine dioxide, nano titanium dioxide, alcohol, zinc oxide and the like, probiotics can be killed in the middle-jiao deficiency, the effective time is short, the corrosivity is strong, rhinitis and hepatitis are easily caused by respiratory respiration, green vegetables and plants which are not live in insects are fermented, and extracted essential oil is treated by a special process, so that bacteria and viruses are killed for a long time, and the extracted essential oil is harmless to the probiotics, people and livestock.
The preparation method of the antiviral and antibacterial negative oxygen ion material is described in detail by the following specific examples, wherein all the raw materials are calculated by mass:
example 1
S1: preparing natural plant mixed slurry; the method specifically comprises the following steps: the natural plant mixed pulp is prepared by mixing and mashing 2 parts of folium artemisiae argyi, 20 parts of chrysanthemum coronarium, 20 parts of lettuce, 20 parts of watercress, 10 parts of chives, 2 parts of eucalyptus leaves, 2 parts of camphor leaves, 2 parts of reeds, 15 parts of water hyacinth and 7 parts of garlic in parts by mass.
S2: fermenting the natural plant mixed slurry to obtain a fermentation product; the method specifically comprises the following steps: and (3) putting the natural plant mixed slurry into a sealed stainless steel fermentation tank for fermentation, wherein the fermentation time is controlled to be 30 days. The fermentation process was started on the third day, and the stainless steel fermenter was vented at a frequency of 2 times per day.
S3: extracting the fermentation product to obtain plant essential oil; the method specifically comprises the following steps: extracting the fermentation product by using edible alcohol with the purity of 95% as an extraction liquid, wherein the mass ratio of the edible alcohol to the fermentation product is 1: 1.5.
S4: adding plant essential oil into porous diatomite, stirring uniformly, and baking to obtain a baked product; the particle size of the porous diatomite is 60 nanometers after grinding; the temperature of the baking process is controlled at 50 ℃ and the time is controlled at 12 hours.
S5: grinding the cooled baked product to obtain a finished product of the negative oxygen ion material; the particle size of the negative oxygen ion material is 30 nanometers.
Example 2
S1: preparing natural plant mixed slurry; the method specifically comprises the following steps: the natural plant mixed slurry is prepared by mixing and mashing 3 parts of folium artemisiae argyi, 18 parts of chrysanthemum coronarium, 18 parts of lettuce, 18 parts of watercress, 12 parts of chives, 3 parts of eucalyptus leaves, 3 parts of camphor leaves, 3 parts of reeds, 12 parts of water hyacinth and 10 parts of garlic in parts by mass.
S2: fermenting the natural plant mixed slurry to obtain a fermentation product; the method specifically comprises the following steps: and (3) putting the natural plant mixed slurry into a sealed stainless steel fermentation tank for fermentation, wherein the fermentation time is controlled to be 30 days. The fermentation process was started on the third day, and the stainless steel fermenter was vented at a frequency of 2 times per day.
S3: extracting the fermentation product to obtain plant essential oil; the method specifically comprises the following steps: and (3) extracting the fermentation product by using edible alcohol with the purity of 95% as an extraction liquid, wherein the mass ratio of the edible alcohol to the fermentation product is 1: 2.
S4: adding plant essential oil into porous diatomite, stirring uniformly, and baking to obtain a baked product; the particle size of the porous diatomite is 60 nanometers after grinding; the temperature of the baking process is controlled at 50 ℃ and the time is controlled at 14 hours.
S5: grinding the cooled baked product to obtain a finished product of the negative oxygen ion material; the particle size of the negative oxygen ion material is 30 nanometers.
Example 3
S1: preparing natural plant mixed slurry; the method specifically comprises the following steps: mixing and mashing 4 parts of folium artemisiae argyi, 15 parts of chrysanthemum coronarium, 15 parts of lettuce, 15 parts of watercress, 10 parts of chives, 4 parts of eucalyptus leaves, 4 parts of camphor leaves, 4 parts of reeds, 15 parts of water hyacinth and 14 parts of garlic to form the natural plant mixed slurry.
S2: fermenting the natural plant mixed slurry to obtain a fermentation product; the method specifically comprises the following steps: and (3) putting the natural plant mixed slurry into a sealed stainless steel fermentation tank for fermentation, wherein the fermentation time is controlled to be 30 days. The fermentation process was started on the third day, and the stainless steel fermenter was vented at a frequency of 2 times per day.
S3: extracting the fermentation product to obtain plant essential oil; the method specifically comprises the following steps: extracting the fermentation product by using edible alcohol with the purity of 95% as an extraction liquid, wherein the mass ratio of the edible alcohol to the fermentation product is 1: 1.5.
S4: adding plant essential oil into porous diatomite, stirring uniformly, and baking to obtain a baked product; the particle size of the porous diatomite is 60 nanometers after grinding; the temperature of the baking process is controlled at 50 ℃ and the time is controlled at 14 hours.
S5: grinding the cooled baked product to obtain a finished product of the negative oxygen ion material; the particle size of the negative oxygen ion material is 30 nanometers.
The method of modifying the antiviral or antibacterial cap of the present application is described in detail below with reference to specific examples:
example 4
S10: the oxygen anion material obtained by the preparation method of example 1 to 3 was added to amino silicone oil in a proportion of 4% by mass to form a modifier.
S20: the modifier is sprayed on the common cloth.
S30: after the spraying is finished, natural drying or drying is carried out to obtain modified cloth, and the drying temperature is 60 ℃.
Example 5
S10: the oxygen anion material obtained by the preparation method of example 1 to 3 was added to amino silicone oil in a proportion of 5% by mass to form a modifier.
S20: the modifier is sprayed on the common cloth.
S30: after the spraying is finished, natural drying or drying is carried out to obtain modified cloth, and the drying temperature is 60 ℃.
Example 6
S10: the oxygen anion material obtained by the preparation method of example 1 to 3 was added to amino silicone oil in a proportion of 6% by mass to form a modifier.
S20: the modifier is sprayed on the common cloth.
S30: after the spraying is finished, natural drying or drying is carried out to obtain modified cloth, and the drying temperature is 60 ℃.
The above-mentioned embodiments, objects, technical solutions and advantages of the present invention are further described in detail, it should be understood that the above-mentioned embodiments are only illustrative of the present invention and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (7)
1. The utility model provides a broad-spectrum antiviral antibiotic cap which characterized in that, obtains modified cloth after carrying out modification treatment with ordinary cloth, through modified cloth tailors and makes broad-spectrum antiviral antibiotic cap, modification treatment is:
adding an oxygen anion material into amino silicone oil according to the mass ratio of 3-8% to form a modifier;
spraying the modifier on the common cloth;
and after the spraying is finished, naturally drying or drying to obtain the modified cloth.
2. The broad spectrum antiviral cap of claim 1 wherein the mass ratio of said oxygen anion material to said amino silicone oil is 5%.
3. The broad spectrum antiviral cap of claim 1 wherein said oxygen anion material is prepared by a process comprising the steps of:
preparing natural plant mixed slurry;
fermenting the natural plant mixed slurry to obtain a fermentation product;
extracting the fermentation product to obtain plant essential oil;
adding the plant essential oil into porous diatomite, stirring uniformly, and baking to obtain a baked product;
and grinding the cooled baked product to obtain a finished product of the negative oxygen ion material.
4. The broad spectrum antiviral and antibacterial cap of claim 3, wherein said preparing a natural plant blend slurry is specifically: the natural plant mixed slurry is prepared by mixing 1-5 parts of folium artemisiae argyi, 10-25 parts of chrysanthemum coronarium, 10-25 parts of lettuce, 10-25 parts of watercress, 5-15 parts of chives, 1-5 parts of eucalyptus leaves, 1-5 parts of camphor leaves, 1-5 parts of reeds, 10-20 parts of water hyacinth and 5-15 parts of garlic in parts by mass and then mashing the mixture.
5. The broad spectrum antiviral and antibacterial cap of claim 3, wherein said natural plant mixed slurry is fermented, in particular:
and (3) putting the natural plant mixed slurry into a sealed stainless steel fermentation tank for fermentation, wherein the fermentation time is controlled to be 25-35 days.
6. The broad spectrum antiviral cap of claim 3 wherein said fermentation product is extracted by: and (3) extracting the fermentation product by using edible alcohol with the purity of 95% as an extraction liquid, wherein the mass ratio of the edible alcohol to the fermentation product is 1 (1-3).
7. The broad spectrum antiviral and antibacterial cap of claim 3, wherein said temperature of said baking process is controlled to be 40-55 ℃ for 10-16 hours.
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| CN202010541540.6A CN111691187A (en) | 2020-06-15 | 2020-06-15 | Broad-spectrum antiviral antibacterial cap |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010541540.6A CN111691187A (en) | 2020-06-15 | 2020-06-15 | Broad-spectrum antiviral antibacterial cap |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042740A (en) * | 1985-05-03 | 1990-06-06 | 张福群 | The textiles that can have ten multinomial functions such as long-acting fragrance |
| CN102120042A (en) * | 2010-01-12 | 2011-07-13 | 张业华 | Negative ion knit, textile and nonwoven fabrics and paper and products thereof and processing method |
| CN107129871A (en) * | 2017-06-13 | 2017-09-05 | 武汉黄鹤楼香精香料有限公司 | A kind of preparation method of fermentation type tobacco cypress leaf essential oil |
| CN107337933A (en) * | 2017-07-18 | 2017-11-10 | 合肥峰腾节能科技有限公司 | A kind of environment-friendly materials capable of purifying air and preparation method thereof |
| CN109701387A (en) * | 2019-01-29 | 2019-05-03 | 马建 | A kind of plant negative oxygen ion air purifying preparation and preparation method thereof |
-
2020
- 2020-06-15 CN CN202010541540.6A patent/CN111691187A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042740A (en) * | 1985-05-03 | 1990-06-06 | 张福群 | The textiles that can have ten multinomial functions such as long-acting fragrance |
| CN102120042A (en) * | 2010-01-12 | 2011-07-13 | 张业华 | Negative ion knit, textile and nonwoven fabrics and paper and products thereof and processing method |
| CN107129871A (en) * | 2017-06-13 | 2017-09-05 | 武汉黄鹤楼香精香料有限公司 | A kind of preparation method of fermentation type tobacco cypress leaf essential oil |
| CN107337933A (en) * | 2017-07-18 | 2017-11-10 | 合肥峰腾节能科技有限公司 | A kind of environment-friendly materials capable of purifying air and preparation method thereof |
| CN109701387A (en) * | 2019-01-29 | 2019-05-03 | 马建 | A kind of plant negative oxygen ion air purifying preparation and preparation method thereof |
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