CN111676099A - 一种椰子油基去重油污、铁锈的抗菌洗涤液及其制备方法 - Google Patents

一种椰子油基去重油污、铁锈的抗菌洗涤液及其制备方法 Download PDF

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CN111676099A
CN111676099A CN202010755399.XA CN202010755399A CN111676099A CN 111676099 A CN111676099 A CN 111676099A CN 202010755399 A CN202010755399 A CN 202010755399A CN 111676099 A CN111676099 A CN 111676099A
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heavy oil
coconut oil
stirring
rust
cleaning solution
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CN111676099B (zh
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白新鹏
白雪
司德洋
黄贵鑫
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Haikou Zhizhisu Biological Resources Research Institute Co ltd
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Abstract

本发明提供一种椰子油基去重油污、铁锈的抗菌洗涤液及其制备方法，所述洗涤液，包括以下质量百分比原料制得：十二烷醇10～30％、辛酸甲酯1～10％、己戊四醇1～10％、椰子油酰胺丙基甜菜碱1.5～2％、螯合剂1～2％、乙醇3～5％、防腐剂0.05～0.1％、余量为增稠剂、pH调节剂和水。本发明的洗涤液去重油污性能强，而且易冲洗，对皮肤滋润。而且稳定性好，抗菌性强，对皮肤无刺激性。尤其适合去除手部重油污，属于高品质的工业用重油污型洗手液，满足高效去重油污，兼顾温和健康要求。另外，本发明洗涤液还可以应用清洗铁锈等。

Description

一种椰子油基去重油污、铁锈的抗菌洗涤液及其制备方法
技术领域
本发明涉及洗涤液技术领域，特别涉及一种椰子油基去重油污、铁锈的抗菌洗涤液及其制备方法。
背景技术
从事农机维修、汽车维修等工作人员，双手或其他部位常常沾有重油污，使用一般洗涤剂，往往难以清洗。而使用去污能力的洗涤剂往往容易伤手，长时间对手造成伤害。现有工业用去重油污洗手液往往难重洗，使得洗手时间长，或者需要清洗多次才能达到比较干净的程度，使得想要洗干净是件麻烦事，而不被沾有重油污人员的青睐。故急需一种洗涤液，解决上述技术问题。
发明内容
鉴于此，本发明提出一种椰子油基去重油污、铁锈的抗菌洗涤液及其制备方法，该洗涤液能快速去除重油污，而且温和滋润。
本发明的技术方案是这样实现的：一种椰子油基去重油污、铁锈的抗菌洗涤液，包括以下质量百分比原料制得：十二烷醇10～30％、辛酸甲酯1～10％、己戊四醇1～10％、椰子油酰胺丙基甜菜碱1.5～2％、螯合剂1～2％、乙醇3～5％、防腐剂0.05～0.1％、余量为增稠剂、pH调节剂和水。优选配比：十二烷醇23％、辛酸甲酯8％、己戊四醇5％、椰子油酰胺丙基甜菜碱1.8％、螯合剂1.2％、乙醇4％、防腐剂0.08％、余量为增稠剂、pH调节剂和水。
进一步的，所述洗涤液的粘度为1000～3500mPa·s。
进一步的，所述洗涤液的pH值为6.8～7.2。
进一步的，所述螯合剂为谷氨酸二乙酸四钠。
进一步的，所述增稠剂为椰子油脂肪酸二乙醇酰胺。
一种椰子油基去重油污、铁锈的抗菌洗涤液的制备方法，按照配方称取各原料，将各原料混合，先于500～600rpm搅拌0.3～0.5h；再于2000～3000rpm搅拌0.8～1h，同时加入椰子油脂肪酸二乙醇酰胺调整粘度为1000～3500mPa·s，加入pH调节剂调整pH值为6.8～7.2；最后于800～1200rpm搅拌0.2～0.5h，搅拌过程温度控制为35～45℃，即得目标洗涤液。
进一步的，第一次搅拌速率为580rpm，搅拌时间为0.4h；第二次搅拌速率为2300rpm，搅拌时间为0.8h；第三次搅拌速率为1000rpm，搅拌时间为0.3h。
进一步的，所述搅拌温度为40℃。
与现有技术相比，本发明的有益效果是：
(1)本发明的洗涤液去重油污性能强，能够快速溶解重油，对重油污的去除率高，一次清洗可达99.9％以上去污率，满足使用者对清洗速度的要求，而且易冲洗，稳定性好，抗菌性强，温和无刺激性，对皮肤滋润。尤其适合去除手部重油污，属于高品质的工业用重油污型洗手液，满足高效去重油污，兼顾温和健康要求。
(2)另外，经验证，本发明洗涤液还可以有效溶解铁锈，使之具有清理被污染的表面，可以应用清洗铁锈。
(3)而且本发明洗涤液对环境友好，制作方便，使用方便，易于产业化制备。
具体实施方式
为了更好理解本发明技术内容，下面提供具体实施例，对本发明做进一步的说明。
本发明实施例所用的实验方法如无特殊说明，均为常规方法。
本发明实施例所用的材料、试剂等，如无特殊说明，均可从商业途径得到。
本发明使用防腐剂为二羟甲基海因，使用pH调节剂为苹果酸。
实施例1
一种椰子油基去重油污、铁锈的抗菌洗涤液，包括以下质量百分比原料制得：十二烷醇10％、辛酸甲酯8％、己戊四醇2％、椰子油酰胺丙基甜菜碱2％、谷氨酸二乙酸四钠螯合剂1％、乙醇3％、防腐剂0.05％，椰子油脂肪酸二乙醇酰胺增稠剂调整体系粘度约为2500mPa·s，pH调节剂调整体系pH值约为7.0，余量为水。
实施例2
一种椰子油基去重油污、铁锈的抗菌洗涤液，包括以下质量百分比原料制得：十二烷醇28％、辛酸甲酯1.2％、己戊四醇10％、椰子油酰胺丙基甜菜碱1.5％、谷氨酸二乙酸四钠螯合剂2％、乙醇5％、防腐剂0.1％，椰子油脂肪酸二乙醇酰胺增稠剂调整体系粘度约为2500mPa·s，pH调节剂调整体系pH值约为7.0，余量为水。
实施例3
一种椰子油基去重油污、铁锈的抗菌洗涤液，包括以下质量百分比原料制得：十二烷醇23％、辛酸甲酯8％、己戊四醇5％、椰子油酰胺丙基甜菜碱1.8％、谷氨酸二乙酸四钠螯合剂1.2％、乙醇4％、防腐剂0.08％，椰子油脂肪酸二乙醇酰胺增稠剂调整体系粘度约为2500mPa·s，pH调节剂调整体系pH值约为7.0，余量为水。
上述实施例1-3洗涤液的制备方法包括以下步骤：按照配方称取各原料，将各原料混合，先于580rpm搅拌0.4h；再于2300rpm搅拌0.8h，同时加入椰子油脂肪酸二乙醇酰胺增稠剂调整体系粘度约为2500mPa·s，加入pH调节剂调整体系pH值约为7.0；最后于1000rpm搅拌0.3h，搅拌过程控制温度约为40℃，即得目标洗涤液。
实施例4
本实施例与实施例3的区别在于，按照配方称取各原料，将各原料混合，先于500rpm搅拌0.5h；再于2000rpm搅拌1h，同时加入椰子油脂肪酸二乙醇酰胺调整粘度约为1000mPa·s，加入pH调节剂调整pH值约为6.8；最后于800pm搅拌0.5h，搅拌过程控制温度约为35℃，即得目标洗涤液。
实施例5
本实施例与实施例3的区别在于，按照配方称取各原料，将各原料混合，先于600rpm搅拌0.3h；再于3000rpm搅拌0.8h，同时加入椰子油脂肪酸二乙醇酰胺调整粘度约为3500mPa·s，加入pH调节剂调整pH值约为7.2；最后于1200rpm搅拌0.2h，搅拌过程控制温度约为45℃，即得目标洗涤液。
对比例1
本对比例与实施例3区别在于，所述洗涤液包括以下质量百分比原料制得：十二烷醇5％、辛酸甲酯15％、己戊四醇15％、椰子油酰胺丙基甜菜碱1％、谷氨酸二乙酸四钠螯合剂0.5％、乙醇10％、防腐剂0.1％、余量为椰子油脂肪酸二乙醇酰胺增稠剂、pH调节剂和水。调整粘度、pH值、制备方法与实施例3一致。
对比例2
本对比例与实施例3区别在于，所述洗涤液的粘度约为5500mPa·s，pH值约为7.5。
对比例3
本对比例与实施例3区别在于，所述螯合剂替换为EDTA-2Na，所述增稠剂替换为聚丙烯酸增稠剂。
对比例4
本对比例与实施例3区别在于，按照配方称取各原料，将各原料混合，先于1000rpm搅拌0.3h；再于1500rpm搅拌1h，同时加入椰子油脂肪酸二乙醇酰胺调整粘度为2500mPa·s，加入pH调节剂调整pH值为7.0；最后于2500rpm搅拌0.8h，搅拌过程温度控制为55℃，即得目标洗涤液。
试验例1
对实施例1～5以及对比例1～4制得的洗涤液的稳定性、抑菌性、刺激性基本性能进行检测。稳定性、抗菌性按照GB19877.1～2005《特种洗手液》进行。刺激性按照《消毒技术规范》(2002版)对样品进行皮肤刺激实验，观察家兔48h后的局部皮肤反应。结果见下表：
Figure BDA0002611387920000051
由上述结果表明，本发明实施例1～5制得洗涤液耐热耐寒性好，性质稳定；对大肠杆菌和金黄色葡萄球菌具有良好的抗菌性能。而且本发明洗涤液对皮肤无刺激性。
试验例2
对实施例1～5以及对比例1～4制得的洗涤液去重油污性能进行检测。
随机选取100名从事农机维修志愿者，随机分组，每组10人，为试验1～10组，共5组，年龄为25～40岁。其中试验组1～9分别采用实施例1～5以及对比例1～4制得的洗涤液；试验组10采用市售工业去油污洗涤液(蒂固洗涤液)。
试验方法：在清洁、干燥的手部涂抹模拟油污(机械冲压油、润滑油与尘土的质量比为1：1：0.2的混合物)，涂膜量为2克/双手(记为初始重油污量)，常温下静置10分钟，待清洗。采用常规清洗方式：每人先用水将手部打湿，将洗涤液置于在手心处，用量为0.6g/双手，揉搓起泡沫，然后按照掌心对掌心、掌心对掌背、指缝对指缝、指腹对掌心的顺序仔细揉搓30s，用水冲洗，记为一次清洗；再洗涤液置于手心中，用量为0.6g/双手，揉搓起泡沫，然后同样按上述的顺序仔细揉搓30s，用水冲洗，记为二次清洗。
各组手部清洗后自然晾干，然后用乙醇浸泡、彻底清洁双手，收集乙醇洗液，浓缩并旋转蒸发，收集残余物并称重计算，记为残余油污量。重油污去除率＝(初始重油污量～残余油污量)/初始重油污量×100％。结果见下表：
Figure BDA0002611387920000061
上述结果表明，本发明实施例1～5洗涤液去重油污性能强，一次清洗可达99.9％，而且易冲洗，对皮肤滋润。
试验例3
清洗生锈的门，把本发明实施例1～5洗涤液分别均匀涂或喷到生锈的门上，一分钟后，用洗涤布擦拭，铁锈轻易的除去，门如新的，并油光发亮。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所做的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (9)

1.一种椰子油基去重油污、铁锈的抗菌洗涤液，其特征在于，包括以下质量百分比原料制得：十二烷醇10～30％、辛酸甲酯1～10％、己戊四醇1～10％、椰子油酰胺丙基甜菜碱1.5～2％、螯合剂1～2％、乙醇3～5％、防腐剂0.05～0.1％、余量为增稠剂、pH调节剂和水。
2.根据权利要求1所述的一种椰子油基去重油污、铁锈的抗菌洗涤液，其特征在于，包括以下质量百分比原料制得：十二烷醇23％、辛酸甲酯8％、己戊四醇5％、椰子油酰胺丙基甜菜碱1.8％、螯合剂1.2％、乙醇4％、防腐剂0.08％、余量为增稠剂、pH调节剂和水。
3.根据权利要求1所述的一种椰子油基去重油污、铁锈的抗菌洗涤液，其特征在于，所述洗涤液的粘度为1000～3500mPa·s。
4.根据权利要求1所述的一种椰子油基去重油污、铁锈的抗菌洗涤液，其特征在于，所述洗涤液的pH值为6.8～7.2。
5.根据权利要求1所述的一种椰子油基去重油污、铁锈的抗菌洗涤液，其特征在于，所述螯合剂为谷氨酸二乙酸四钠。
6.根据权利要求1所述的一种椰子油基去重油污、铁锈的抗菌洗涤液，其特征在于，所述增稠剂为椰子油脂肪酸二乙醇酰胺。
7.根据权利要求1～6任一项所述的一种椰子油基去重油污、铁锈的抗菌洗涤液的制备方法，其特征在于，按照配方称取各原料，将各原料混合，先于500～600rpm搅拌0.3～0.5h；再于2000～3000rpm搅拌0.8～1h，同时加入椰子油脂肪酸二乙醇酰胺调整粘度为1000～3500mPa·s，加入pH调节剂调整pH值为6.8～7.2；最后于800～1200rpm搅拌0.2～0.5h，搅拌过程温度控制为35～45℃，即得目标洗涤液。
8.根据权利要求7所述的一种椰子油基去重油污、铁锈的抗菌洗涤液的制备方法，其特征在于，第一次搅拌速率为580rpm，搅拌时间为0.4h；第二次搅拌速率为2300rpm，搅拌时间为0.8h；第三次搅拌速率为1000rpm，搅拌时间为0.3h。
9.根据权利要求7或8所述的一种椰子油基去重油污、铁锈的抗菌洗涤液的制备方法，其特征在于，所述搅拌温度为40℃。
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1067263A (zh) * 1991-05-27 1992-12-23 刘冠中 多用途高效免水净洗膏
CN1067672A (zh) * 1991-06-10 1993-01-06 沈阳市光大科技开发研究所 干洗净的配方及制造工艺
CN101503648A (zh) * 2009-02-26 2009-08-12 深圳市合明科技有限公司 一种smt印刷网板的水基清洗剂
CN103103026A (zh) * 2012-11-09 2013-05-15 吴江市钱氏纺织有限公司 一种纺织品防沾污洗涤剂
CN104152290A (zh) * 2014-08-01 2014-11-19 无棣华信石油技术服务有限公司 一种稠油输油管道清洁剂及其制备方法
CN104274334A (zh) * 2013-07-09 2015-01-14 苏州元素集化学工业有限公司 一种用于清洁的组合物
CN105002021A (zh) * 2015-07-12 2015-10-28 张小龙 一种家居用品清洁剂
CN107858210A (zh) * 2017-10-17 2018-03-30 章凯 一种新型环保家用清洁除油剂及其制备方法
CN109288698A (zh) * 2018-11-19 2019-02-01 巩义市宏盛稀有金属有限公司 一种用于工业去重油污的复合型洗手液及其制备方法

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1067263A (zh) * 1991-05-27 1992-12-23 刘冠中 多用途高效免水净洗膏
CN1067672A (zh) * 1991-06-10 1993-01-06 沈阳市光大科技开发研究所 干洗净的配方及制造工艺
CN101503648A (zh) * 2009-02-26 2009-08-12 深圳市合明科技有限公司 一种smt印刷网板的水基清洗剂
CN103103026A (zh) * 2012-11-09 2013-05-15 吴江市钱氏纺织有限公司 一种纺织品防沾污洗涤剂
CN104274334A (zh) * 2013-07-09 2015-01-14 苏州元素集化学工业有限公司 一种用于清洁的组合物
CN104152290A (zh) * 2014-08-01 2014-11-19 无棣华信石油技术服务有限公司 一种稠油输油管道清洁剂及其制备方法
CN105002021A (zh) * 2015-07-12 2015-10-28 张小龙 一种家居用品清洁剂
CN107858210A (zh) * 2017-10-17 2018-03-30 章凯 一种新型环保家用清洁除油剂及其制备方法
CN109288698A (zh) * 2018-11-19 2019-02-01 巩义市宏盛稀有金属有限公司 一种用于工业去重油污的复合型洗手液及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李波等: "水基清洗剂的研究现状及发展趋势", 《清洗世界》 *

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