CN111646731A - Non-toxic antibacterial artware clay sculpture material - Google Patents
Non-toxic antibacterial artware clay sculpture material Download PDFInfo
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- CN111646731A CN111646731A CN202010357406.0A CN202010357406A CN111646731A CN 111646731 A CN111646731 A CN 111646731A CN 202010357406 A CN202010357406 A CN 202010357406A CN 111646731 A CN111646731 A CN 111646731A
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- 239000000463 material Substances 0.000 title claims abstract description 127
- 239000004927 clay Substances 0.000 title claims abstract description 70
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 37
- 231100000252 nontoxic Toxicity 0.000 title claims abstract description 35
- 230000003000 nontoxic effect Effects 0.000 title claims abstract description 35
- 239000004615 ingredient Substances 0.000 claims abstract description 37
- 239000002245 particle Substances 0.000 claims abstract description 33
- 239000007787 solid Substances 0.000 claims abstract description 33
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 235000021419 vinegar Nutrition 0.000 claims abstract description 22
- 239000000052 vinegar Substances 0.000 claims abstract description 22
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 17
- 229910021538 borax Inorganic materials 0.000 claims abstract description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 17
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 17
- 238000005187 foaming Methods 0.000 claims abstract description 16
- 239000011780 sodium chloride Substances 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000010893 paper waste Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000002994 raw material Substances 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000010422 painting Methods 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 description 7
- 230000001580 bacterial effect Effects 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
In order to solve the defects of the prior art, the invention provides a non-toxic antibacterial artware clay sculpture material which comprises ingredients, a solvent and a base material. The ingredients comprise the following components in parts by weight: 5-20 parts of polyvinyl alcohol, 0.1-2 parts of borax and 0.5-5 parts of foaming powder. The solvent is as follows: 20-60 parts of water. The base material is as follows: 15-40 parts of solid particles. The ingredients also comprise, in parts by weight: 10-30 parts of sodium chloride. The ingredients also comprise, in parts by weight: 10-20 parts of brewed vinegar. The base material adopted by the invention is waste paper, so that the waste is utilized, and the invention is non-toxic, harmless, safe and environment-friendly, the raw materials are cheap and easy to obtain, and the preparation method is simple and easy to implement. The clay sculpture material prepared by the invention has good antibacterial ability and longer storage period. Meanwhile, the clay sculpture material prepared by the invention has good adhesive capacity, can be coated outside other objects, and is used for texture manufacturing of paintings.
Description
Technical Field
The invention belongs to the technical field of preparation of artware materials, and particularly relates to a non-toxic antibacterial artware clay sculpture material.
Background
The clay sculpture handicraft is an ancient and common folk art in China folk tradition, takes earth, especially clay soil as a raw material, is manually kneaded and formed, or is plain or colored, and is mainly made of characters and animals. The common preparation method is to mix a little cotton fiber into clay, to be smashed evenly, to be kneaded into mud blank of various characters, to be dried in shade, to be coated with base powder, and to be painted with color.
However, the existing clay sculpture materials are relatively suitable for manufacturing high-value artware, and the clay sculpture materials used for children enlightenment, clay sculpture process popularization and the like exist: 1. the use cost is too high, and 2. children may eat by mistake and the like.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a non-toxic antibacterial artware clay sculpture material which comprises ingredients, a solvent and a base material. The ingredients comprise the following components in parts by weight: 5-20 parts of polyvinyl alcohol, 0.1-2 parts of borax and 0.5-5 parts of foaming powder. The solvent is as follows: 20-60 parts of water. The base material is as follows: 15-40 parts of solid particles.
Further, the coating comprises the following components in parts by weight: 7.8-12 parts of polyvinyl alcohol, 0.15-1 part of borax, 1.2-3 parts of foaming powder, 43-48 parts of water and 24-29 parts of solid particles.
Further, the ingredients also comprise, in parts by weight: 10-30 parts of sodium chloride.
Further, the ingredients also comprise, in parts by weight: 15.5-21 parts of sodium chloride.
Further, the ingredients also comprise, in parts by weight: 10-20 parts of brewed vinegar.
Further, the ingredients also comprise, in parts by weight: 12.6 to 18 portions of brewed vinegar.
Further, the clay sculpture material is prepared by the following method:
(1) respectively weighing and mixing the polyvinyl alcohol and the borax according to the formula ratio to obtain a first mixed material. Simultaneously, mixing the water with the formula amount with the solid particles, soaking for 12-48 hours, taking out the solid particles, and removing the excessive water of the soaked solid particles to obtain a second mixed material
(2) And (3) mixing the first mixed material obtained in the step (1) with the foaming powder with the formula amount to obtain a third mixed material.
(3) And (3) mixing the third mixed material obtained in the step (2) with the rest ingredients according to the formula amount to obtain a fourth mixed material.
(4) And fully stirring the fourth mixed material and the second mixed material until the mixture is uniformly mixed to obtain the non-toxic antibacterial artware clay sculpture material.
Further, the rest ingredients in the step (3) comprise: 10-30 parts of sodium chloride and 10-20 parts of brewed vinegar. At this time, the third mixture is mixed with sodium chloride and brewed vinegar, and then stirred and mixed in an environment of carbon dioxide at 35 to 40 ℃.
Further, the solid particles are: waste paper. Before use, the shredded paper is cut into shredded paper scraps by a shredder.
Furthermore, the polyvinyl alcohol used in the invention is pharmaceutical grade polyvinyl alcohol. The borax is pharmaceutical grade borax. The foaming powder is an edible quick loosening agent. The sodium chloride is edible salt. The water is boiled water. The edible brewing vinegar is light or white vinegar without salt.
The invention has at least one of the following advantages:
1. the base material adopted by the invention is waste paper, so that the waste is utilized, the method is nontoxic and harmless, safe and environment-friendly, the raw materials are cheap and easy to obtain, and the preparation method is simple and easy to implement.
2. The clay sculpture material prepared by the method has good antibacterial ability and longer storage period.
3. The clay sculpture material prepared by the invention has good adhesive capacity, can be coated outside other objects, and is used for texture manufacturing of paintings.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
A non-toxic antibacterial clay sculpture as artistic article is prepared from raw materials, solvent and basic material. The ingredients comprise the following components in parts by weight: 20 parts of polyvinyl alcohol, 2 parts of borax and 5 parts of foaming powder. The solvent is as follows: 60 parts of water. The base material is as follows: 40 parts of solid particles. The solid particles are: waste paper. Before use, the shredded paper is cut into shredded paper scraps by a shredder. The clay sculpture material is prepared by the following method:
(1) respectively weighing and mixing the polyvinyl alcohol and the borax according to the formula ratio to obtain a first mixed material. Simultaneously, mixing the water with the formula amount with the solid particles, taking out the solid particles after soaking for 48 hours, and removing the excessive water of the soaked solid particles to obtain a second mixed material
(2) And (3) mixing the first mixed material obtained in the step (1) with the foaming powder with the formula amount to obtain a third mixed material.
(3) And (3) mixing the third mixed material obtained in the step (2) with the rest ingredients according to the formula amount to obtain a fourth mixed material.
(4) And fully stirring the fourth mixed material and the second mixed material until the mixture is uniformly mixed to obtain the non-toxic antibacterial artware clay sculpture material.
Example 2
A non-toxic antibacterial clay sculpture as artistic article is prepared from raw materials, solvent and basic material. The ingredients comprise the following components in parts by weight: 5 parts of polyvinyl alcohol, 0.1 part of borax and 0.5 part of foaming powder. The solvent is as follows: and 20 parts of water. The base material is as follows: and 15 parts of solid particles. The solid particles are: waste paper. Before use, the shredded paper is cut into shredded paper scraps by a shredder. The clay sculpture material is prepared by the following method:
(1) respectively weighing and mixing the polyvinyl alcohol and the borax according to the formula ratio to obtain a first mixed material. Simultaneously, mixing the water with the formula amount with the solid particles, taking out the solid particles after soaking for 12 hours, and removing the excessive water of the soaked solid particles to obtain a second mixed material
(2) And (3) mixing the first mixed material obtained in the step (1) with the foaming powder with the formula amount to obtain a third mixed material.
(3) And (3) mixing the third mixed material obtained in the step (2) with the rest ingredients according to the formula amount to obtain a fourth mixed material.
(4) And fully stirring the fourth mixed material and the second mixed material until the mixture is uniformly mixed to obtain the non-toxic antibacterial artware clay sculpture material.
Example 3
A non-toxic antibacterial clay sculpture as artistic article is prepared from raw materials, solvent and basic material. The ingredients comprise the following components in parts by weight: 12 parts of polyvinyl alcohol, 1 part of borax and 3 parts of foaming powder. The solvent is as follows: 48 parts of water. The base material is as follows: 29 parts of solid particles. The solid particles are: waste paper. Before use, the shredded paper is cut into shredded paper scraps by a shredder. The clay sculpture material is prepared by the following method:
(1) respectively weighing and mixing the polyvinyl alcohol and the borax according to the formula ratio to obtain a first mixed material. Simultaneously, mixing the water with the formula amount with the solid particles, taking out the solid particles after soaking for 36 hours, and removing the excessive water of the soaked solid particles to obtain a second mixed material
(2) And (3) mixing the first mixed material obtained in the step (1) with the foaming powder with the formula amount to obtain a third mixed material.
(3) And (3) mixing the third mixed material obtained in the step (2) with the rest ingredients according to the formula amount to obtain a fourth mixed material.
(4) And fully stirring the fourth mixed material and the second mixed material until the mixture is uniformly mixed to obtain the non-toxic antibacterial artware clay sculpture material.
Example 4
A non-toxic antibacterial clay sculpture as artistic article is prepared from raw materials, solvent and basic material. The ingredients comprise the following components in parts by weight: 7.8 parts of polyvinyl alcohol, 0.15 part of borax and 1.2 parts of foaming powder. The solvent is as follows: and 43 parts of water. The base material is as follows: and 24 parts of solid particles. The solid particles are: waste paper. Before use, the shredded paper is cut into shredded paper scraps by a shredder. The clay sculpture material is prepared by the following method:
(1) respectively weighing and mixing the polyvinyl alcohol and the borax according to the formula ratio to obtain a first mixed material. Simultaneously, mixing the water with the formula amount with the solid particles, taking out the solid particles after soaking for 24 hours, and removing the excessive water of the soaked solid particles to obtain a second mixed material
(2) And (3) mixing the first mixed material obtained in the step (1) with the foaming powder with the formula amount to obtain a third mixed material.
(3) And (3) mixing the third mixed material obtained in the step (2) with the rest ingredients according to the formula amount to obtain a fourth mixed material.
(4) And fully stirring the fourth mixed material and the second mixed material until the mixture is uniformly mixed to obtain the non-toxic antibacterial artware clay sculpture material.
The results of the plasticity tests of the clay sculpture materials obtained in examples 1 to 4 mainly adopt an observation mode to check whether the clay sculpture can sink and deform under the influence of self weight after being shaped for 2 hours, 24 hours and 5 days, whether the clay sculpture can rebound and deform, and whether obvious plastic surface cracks can appear after drying.
Therefore, the clay sculpture material prepared by the formula and the preparation method can basically meet the plasticity requirement of clay sculpture, and is safe and nontoxic because the materials are all medical or edible materials.
Example 5
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: 30 parts of sodium chloride.
Example 6
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: 10 parts of sodium chloride.
Example 7
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: 21 parts of sodium chloride.
Example 8
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: 15.5 parts of sodium chloride.
The applicant finds that the antibacterial performance of the clay sculpture material can be obviously improved by adding the salt with the formula amount into the clay sculpture material. The bacterial colony number of the clay sculpture material without the salt exceeds 10000cfu/g 1-2 hours after preparation, the plasticity of the clay sculpture material with the salt added according to the formula does not obviously decrease, the basic requirement that the clay sculpture does not deform within 5 days can be still met, and the bacterial colony number of the material per se can be kept to be not more than 10000cfu/g within 5 days. The salt with the amount lower than the formula amount can not play a good antibacterial role, and the salt with the amount higher than the formula amount can cause the viscosity of the clay sculpture material to be sharply reduced, so that the clay sculpture material can not be shaped.
Example 9
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: 20 parts of brewed vinegar.
Example 10
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: 10 portions of brewed vinegar.
Example 11
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: brewing vinegar 18 parts.
Example 12
Based on the non-toxic antibacterial artware clay sculpture material prepared according to any one of embodiments 1 to 4, the ingredients further comprise, in parts by weight: 12.6 parts of brewed vinegar.
The applicant finds that the adhesive property of the clay sculpture material can be obviously improved by adding the brewing vinegar with the formula amount into the clay sculpture material. The clay sculpture material without the addition of the brewing vinegar can not be attached to smooth interfaces, such as glass, stainless steel, ceramic tiles and the like. The clay sculpture material added with the brewing vinegar in the formula amount has excellent adhesiveness, can form good adhesiveness even on a smooth interface, and the clay sculpture material can not fall off from the adhesion interface during use. The brewing vinegar with the amount lower than the formula amount can not realize the result, and the brewing vinegar with the amount higher than the formula amount can obviously cause the strength of the clay sculpture material to be increased, the curing time to be shortened, and the clay sculpture material is not beneficial to shaping.
Example 13
Based on the above embodiment, the rest of the ingredients in step (3) include: 10-30 parts of sodium chloride and 10-20 parts of brewed vinegar. At this time, the third mixture is mixed with sodium chloride and brewed vinegar, and then stirred and mixed in an environment of carbon dioxide at 35 to 40 ℃.
Through research, the antibacterial property and plasticity of the clay sculpture material prepared in the environment are obviously improved. The concrete points are as follows: the colony count of the material per se can be kept to be not more than 6000cfu/g within 5 days. The clay sculpture material has good adhesive capacity and can keep good plasticity within 5 hours. The clay sculpture material prepared in the air environment is generally cured within 3 hours and cannot be molded continuously.
It is to be noted and understood that various modifications and improvements can be made to the invention described in detail above without departing from the spirit and scope of the invention as claimed. Accordingly, the scope of the claimed technical solution is not limited by any of the specific exemplary teachings given.
Claims (9)
1. A non-toxic antibacterial artware clay sculpture material is characterized by comprising ingredients, a solvent and a base material; the ingredients comprise the following components in parts by weight: 5-20 parts of polyvinyl alcohol, 0.1-2 parts of borax and 0.5-5 parts of foaming powder; the solvent is as follows: 20-60 parts of water; the base material is as follows: 15-40 parts of solid particles.
2. The non-toxic antibacterial artware clay sculpture material as claimed in claim 1, is characterized by comprising, by weight: 7.8-12 parts of polyvinyl alcohol, 0.15-1 part of borax, 1.2-3 parts of foaming powder, 43-48 parts of water and 24-29 parts of solid particles.
3. The non-toxic antibacterial artware clay sculpture material as claimed in claim 1, wherein the ingredients further comprise, in parts by weight: 10-30 parts of sodium chloride.
4. The non-toxic antibacterial artware clay sculpture material according to claim 3, wherein the ingredients further comprise, in parts by weight: 15.5-21 parts of sodium chloride.
5. The non-toxic antibacterial artware clay sculpture material as claimed in claim 1, wherein the ingredients further comprise, in parts by weight: 10-20 parts of brewed vinegar.
6. The non-toxic antibacterial artware clay sculpture material according to claim 5, wherein the ingredients further comprise, in parts by weight: 12.6 to 18 portions of brewed vinegar.
7. The non-toxic antibacterial artware clay sculpture material as claimed in any one of claims 1 to 6, wherein the clay sculpture material is prepared by the following method:
(1) respectively weighing and mixing the polyvinyl alcohol and the borax according to the formula ratio to obtain a first mixed material; simultaneously, mixing the water with the formula amount with the solid particles, soaking for 12-48 hours, taking out the solid particles, and removing the excessive water of the soaked solid particles to obtain a second mixed material
(2) Mixing the first mixed material obtained in the step (1) with foaming powder in a formula amount to obtain a third mixed material;
(3) mixing the third mixed material obtained in the step (2) with the rest ingredients in the formula amount to obtain a fourth mixed material;
(4) and fully stirring the fourth mixed material and the second mixed material until the mixture is uniformly mixed to obtain the non-toxic antibacterial artware clay sculpture material.
8. The non-toxic antibacterial artware clay sculpture material as claimed in claim 7, wherein the rest of the ingredients in the step (3) comprise: 10-30 parts of sodium chloride and 10-20 parts of brewed vinegar; at this time, the third mixture is mixed with sodium chloride and brewed vinegar, and then stirred and mixed in an environment of carbon dioxide at 35 to 40 ℃.
9. The non-toxic antibacterial artware clay sculpture material as claimed in claim 1, wherein the solid particles are: waste paper; before use, the shredded paper is cut into shredded paper scraps by a shredder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010357406.0A CN111646731B (en) | 2020-04-29 | 2020-04-29 | Nontoxic antibacterial artware clay sculpture material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010357406.0A CN111646731B (en) | 2020-04-29 | 2020-04-29 | Nontoxic antibacterial artware clay sculpture material |
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| Publication Number | Publication Date |
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| CN111646731A true CN111646731A (en) | 2020-09-11 |
| CN111646731B CN111646731B (en) | 2024-06-21 |
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| CN106494145A (en) * | 2016-11-07 | 2017-03-15 | 崔宝良 | A kind of processing technology of calcite clay sculpture craftwork |
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| CN108609919A (en) * | 2018-04-26 | 2018-10-02 | 河南工学院 | A kind of handicraft clay sculpture material and preparation method thereof |
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| CN109176869A (en) * | 2018-08-08 | 2019-01-11 | 佛山市保登科技有限公司 | A kind of clay sculpture is used and mud equipment |
| CN110157208A (en) * | 2019-04-18 | 2019-08-23 | 河南工业大学 | A kind of nontoxic antibacterial plasticine and preparation method thereof |
| CN111072356A (en) * | 2020-02-20 | 2020-04-28 | 怀化市艺翔城市园林雕塑景观工程有限公司 | Novel clay sculpture environment-friendly material and manufacturing method thereof |
-
2020
- 2020-04-29 CN CN202010357406.0A patent/CN111646731B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107304296A (en) * | 2016-08-19 | 2017-10-31 | 如皋长江科技产业有限公司 | A kind of nontoxic antibacterial plasticine and preparation method thereof |
| CN106494145A (en) * | 2016-11-07 | 2017-03-15 | 崔宝良 | A kind of processing technology of calcite clay sculpture craftwork |
| CN108609919A (en) * | 2018-04-26 | 2018-10-02 | 河南工学院 | A kind of handicraft clay sculpture material and preparation method thereof |
| CN109176869A (en) * | 2018-08-08 | 2019-01-11 | 佛山市保登科技有限公司 | A kind of clay sculpture is used and mud equipment |
| CN108888971A (en) * | 2018-08-16 | 2018-11-27 | 临沂市博士爱文具有限公司 | A kind of preparation method of edible plasticine |
| CN110157208A (en) * | 2019-04-18 | 2019-08-23 | 河南工业大学 | A kind of nontoxic antibacterial plasticine and preparation method thereof |
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| CN111646731B (en) | 2024-06-21 |
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