CN111621191A - Water-based black ink - Google Patents

Water-based black ink Download PDF

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Publication number
CN111621191A
CN111621191A CN202010672695.3A CN202010672695A CN111621191A CN 111621191 A CN111621191 A CN 111621191A CN 202010672695 A CN202010672695 A CN 202010672695A CN 111621191 A CN111621191 A CN 111621191A
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China
Prior art keywords
water
dispersion
dispersing
ink
black ink
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Pending
Application number
CN202010672695.3A
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Chinese (zh)
Inventor
庞行行
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Individual
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Individual
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Priority to CN202010672695.3A priority Critical patent/CN111621191A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters

Abstract

The invention discloses water-based black ink, which comprises the following components in percentage by weight: 30-60% of water-based resin, 8-35% of iron oxide black, 8-20% of carbon black, 3-10% of wax powder, 1-6% of matting powder, 2-4% of zinc stearate, 1% of water-based defoaming agent, 0.3-0.7% of water-based dispersing agent, 1-2% of water-based anti-scraping agent, 2-5% of polyester emulsion, 12-25% of epoxy resin and 15-30% of water. The water-based black ink disclosed by the invention is light in taste, cannot pollute the environment, cannot cause danger in hot summer, and is less harmful to the bodies of field operators due to light taste; when the ink is used, the operation flow of printing is the same as that of a solvent type ink, the operation is easy, the fluidity is good, the solvent type ink is operated by diluting water, and the solvent type ink needs to be diluted by a chemical solvent, so that the ink is more environment-friendly and more economical compared with the existing solvent type ink.

Description

Water-based black ink
Technical Field
The invention relates to ink, in particular to water-based black ink.
Background
Ink is an important material for printing, and is used for expressing patterns and characters on a printing material through printing or inkjet. The ink comprises a main component and an auxiliary component which are uniformly mixed and repeatedly rolled to form a viscous colloidal fluid. Consists of a binder, a pigment, a filler, an auxiliary agent, a solvent and the like. The printing ink is used for various printing of books, periodicals, packaging decoration, building decoration, electronic circuit boards and the like. As social demands increase, ink varieties and yields also expand and grow accordingly.
The black ink on the market at present belongs to a solvent type, and has the following defects: the solvent type ink has high smell and great environmental pollution; hot summer days are very dangerous for solvent-based inks; the harm to the body of field operators is large.
Disclosure of Invention
The present invention is directed to an aqueous black ink, which solves the above problems of the prior art.
In order to achieve the purpose, the invention provides the following technical scheme:
the water-based black ink comprises the following components in percentage by weight: 30-60% of water-based resin, 8-35% of iron oxide black, 8-20% of carbon black, 3-10% of wax powder, 1-6% of matting powder, 2-4% of zinc stearate, 1% of water-based defoaming agent, 0.3-0.7% of water-based dispersing agent, 1-2% of water-based anti-scraping agent, 2-5% of polyester emulsion, 12-25% of epoxy resin and 15-30% of water.
In addition, the invention also provides a preparation process of the water-based black ink, which comprises the following specific process flows:
(1) and dispersing: adding the water-based resin, the iron oxide black, the carbon black, the wax powder, the zinc stearate and the water-based dispersing agent into a dispersion machine according to the formula proportion for dispersion, wherein the rotating speed of the dispersion machine is 1000-1500r/min, and the dispersion time is 8-11 min;
(2) and grinding: grinding the dispersed mixed material in the step (1) by using a three-roller machine for 3-5 times;
(3) and secondary dispersion: adding the mixed material ground in the step (2) into a dispersion machine again, adding a water-based defoaming agent, a water-based anti-scraping agent, polyester emulsion, matting powder, epoxy resin and water, and dispersing again by using the dispersion machine;
(4) and packaging: and (4) obtaining a finished product by dispersing the materials in the step (3) again, and then filling and packaging.
As a further scheme of the invention: the rotating speed of the disperser in the step (1) is 1200r/min, and the dispersing time is 10 min.
As a still further scheme of the invention: and (3) grinding the mixed material for 4 times by using a three-roller grinding machine in the step (2).
As a still further scheme of the invention: and (4) when the secondary dispersion is carried out in the step (3), the rotating speed of a dispersion machine is 1000r/min, and the dispersion time is 15 minutes.
As a still further scheme of the invention: and (4) boiling the black printing ink finished product prepared in the step (4) with water when in use.
Compared with the prior art, the invention has the beneficial effects that:
1. the water-based black ink disclosed by the invention is light in taste, cannot pollute the environment, cannot cause danger in hot summer, and is less harmful to the bodies of field operators due to light taste;
2. when the water-based black ink is used, the printing operation flow is the same as that of a solvent type, the operation is easy, the fluidity is good, the solvent type ink is operated by diluting water, and the solvent type ink needs to be diluted by a chemical solvent, so that the water-based black ink is more environment-friendly and more economical compared with the existing solvent type ink.
Detailed Description
The technical solution of the present invention will be described in further detail with reference to specific embodiments.
Example 1
The water-based black ink comprises the following components in percentage by weight: 30% of water-based resin, 10% of iron black, 8% of carbon black, 3% of wax powder, 2% of extinction powder, 2% of zinc stearate, 1% of water-based defoaming agent, 0.3% of water-based dispersing agent, 1.7% of water-based anti-scraping agent, 2% of polyester emulsion, 12% of epoxy resin and 28% of water.
The invention also provides a preparation process of the water-based black ink, which comprises the following specific process flows:
(1) and dispersing: adding water-based resin, iron black, carbon black, wax powder, zinc stearate and a water-based dispersing agent into a dispersion machine according to a formula ratio for dispersion, wherein the rotating speed of the dispersion machine is 1000r/min, and the dispersion time is 8 min;
(2) and grinding: grinding the dispersed mixed material in the step (1) for 3 times by using a three-roller machine;
(3) and secondary dispersion: adding the mixed material ground in the step (2) into a dispersion machine again, adding a water-based defoaming agent, a water-based anti-scraping agent, polyester emulsion, matting powder, epoxy resin and water, and dispersing again by using the dispersion machine, wherein the rotating speed of the dispersion machine is 1000r/min, and the dispersing time is 15 minutes;
(4) and packaging: and (4) obtaining a finished product by dispersing the materials in the step (3) again, and then filling and packaging.
Example 2
The water-based black ink comprises the following components in percentage by weight: 33% of water-based resin, 12% of iron black, 10% of carbon black, 5% of wax powder, 3% of matting powder, 3% of zinc stearate, 1% of water-based defoaming agent, 0.5% of water-based dispersing agent, 2% of water-based anti-scraping agent, 3% of polyester emulsion, 12.5% of epoxy resin and 15% of water.
The invention also provides a preparation process of the water-based black ink, which comprises the following specific process flows:
(1) and dispersing: adding water-based resin, iron black, carbon black, wax powder, zinc stearate and a water-based dispersing agent into a dispersion machine according to a formula ratio for dispersion, wherein the rotating speed of the dispersion machine is 1200r/min, and the dispersion time is 10 min;
(2) and grinding: grinding the dispersed mixed material in the step (1) for 4 times by using a three-roller machine;
(3) and secondary dispersion: adding the mixed material ground in the step (2) into a dispersion machine again, adding a water-based defoaming agent, a water-based anti-scraping agent, polyester emulsion, matting powder, epoxy resin and water, and dispersing again by using the dispersion machine, wherein the rotating speed of the dispersion machine is 1000r/min, and the dispersing time is 15 minutes;
(4) and packaging: and (4) obtaining a finished product by dispersing the materials in the step (3) again, and then filling and packaging.
Example 3
The water-based black ink comprises the following components in percentage by weight: 30% of water-based resin, 10% of iron black, 15% of carbon black, 4% of wax powder, 1% of matting powder, 2.3% of zinc stearate, 1% of water-based defoaming agent, 0.7% of water-based dispersing agent, 1% of water-based anti-scraping agent, 2% of polyester emulsion, 13% of epoxy resin and 20% of water.
The invention also provides a preparation process of the water-based black ink, which comprises the following specific process flows:
(1) and dispersing: adding water-based resin, iron black, carbon black, wax powder, zinc stearate and a water-based dispersing agent into a dispersion machine according to a formula ratio for dispersion, wherein the rotating speed of the dispersion machine is 1500r/min, and the dispersion time is 11 min;
(2) and grinding: grinding the dispersed mixed material in the step (1) for 5 times by using a three-roller machine;
(3) and secondary dispersion: adding the mixed material ground in the step (2) into a dispersion machine again, adding a water-based defoaming agent, a water-based anti-scraping agent, polyester emulsion, matting powder, epoxy resin and water, and dispersing again by using the dispersion machine, wherein the rotating speed of the dispersion machine is 1000r/min, and the dispersing time is 15 minutes;
(4) and packaging: and (4) obtaining a finished product by dispersing the materials in the step (3) again, and then filling and packaging.
The black ink prepared by the water-based black ink formula disclosed by the invention is light in taste, cannot pollute the environment, cannot cause danger in hot summer, and simultaneously, the light taste reduces harm to the bodies of field operators; when the ink is used, the operation flow of printing is the same as that of a solvent type ink, the operation is easy, the fluidity is good, moreover, the ink is operated by diluting water, the solvent type ink needs to be diluted by chemical solvents, and compared with the existing solvent type ink, the ink is more environment-friendly and economical.
While the preferred embodiments of the present invention have been described in detail, the present invention is not limited to the above embodiments, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art.

Claims (6)

1. The water-based black ink is characterized by comprising the following components in percentage by weight: 30-60% of water-based resin, 8-35% of iron oxide black, 8-20% of carbon black, 3-10% of wax powder, 1-6% of matting powder, 2-4% of zinc stearate, 1% of water-based defoaming agent, 0.3-0.7% of water-based dispersing agent, 1-2% of water-based anti-scraping agent, 2-5% of polyester emulsion, 12-25% of epoxy resin and 15-30% of water.
2. The preparation method of the water-based black ink as claimed in claim 1, wherein the specific process flow is as follows:
(1) and dispersing: adding the water-based resin, the iron oxide black, the carbon black, the wax powder, the zinc stearate and the water-based dispersing agent into a dispersion machine according to the formula proportion for dispersion, wherein the rotating speed of the dispersion machine is 1000-1500r/min, and the dispersion time is 8-11 min;
(2) and grinding: grinding the dispersed mixed material in the step (1) by using a three-roller machine for 3-5 times;
(3) and secondary dispersion: adding the mixed material ground in the step (2) into a dispersion machine again, adding a water-based defoaming agent, a water-based anti-scraping agent, polyester emulsion, matting powder, epoxy resin and water, and dispersing again by using the dispersion machine;
(4) and packaging: and (4) obtaining a finished product by dispersing the materials in the step (3) again, and then filling and packaging.
3. The method for preparing the water-based black ink according to claim 2, wherein the rotation speed of the dispersing machine in the step (1) is 1200r/min, and the dispersing time is 10 min.
4. The method for preparing the aqueous black ink according to claim 2, wherein the step (2) is performed by grinding the mixture using a three-roll mill for 4 times.
5. The method for producing an aqueous black ink according to claim 2, wherein the rotation speed of the dispersion machine is 1000r/min and the dispersion time is 15 minutes in the secondary dispersion in the step (3).
6. The method for preparing the aqueous black ink according to claim 2, wherein the black ink obtained in the step (4) is diluted with water in use.
CN202010672695.3A 2020-07-14 2020-07-14 Water-based black ink Pending CN111621191A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642311A (en) * 2013-11-19 2014-03-19 张家港市威迪森油墨有限公司 Aqueous black ink
CN104893417A (en) * 2015-07-06 2015-09-09 深圳市顾康力化工有限公司 Single-component high-covering-property ink and preparation method thereof
CN106634193A (en) * 2016-10-07 2017-05-10 李勇军 PVC (polyvinyl chloride) water-based ink
CN109370302A (en) * 2018-12-26 2019-02-22 中山市华业油墨涂料有限公司 Universal thermal shrinkage film water-based ink and preparation method thereof
CN110655826A (en) * 2019-10-18 2020-01-07 苏州中亚油墨有限公司 Environment-friendly water-based cigarette label printing ink
CN112662228A (en) * 2021-02-05 2021-04-16 漯河樱花包装材料有限公司 Water-soluble environment-friendly gravure ink and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642311A (en) * 2013-11-19 2014-03-19 张家港市威迪森油墨有限公司 Aqueous black ink
CN104893417A (en) * 2015-07-06 2015-09-09 深圳市顾康力化工有限公司 Single-component high-covering-property ink and preparation method thereof
CN106634193A (en) * 2016-10-07 2017-05-10 李勇军 PVC (polyvinyl chloride) water-based ink
CN109370302A (en) * 2018-12-26 2019-02-22 中山市华业油墨涂料有限公司 Universal thermal shrinkage film water-based ink and preparation method thereof
CN110655826A (en) * 2019-10-18 2020-01-07 苏州中亚油墨有限公司 Environment-friendly water-based cigarette label printing ink
CN112662228A (en) * 2021-02-05 2021-04-16 漯河樱花包装材料有限公司 Water-soluble environment-friendly gravure ink and preparation method thereof

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Application publication date: 20200904

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