CN104893417A - Single-component high-covering-property ink and preparation method thereof - Google Patents
Single-component high-covering-property ink and preparation method thereof Download PDFInfo
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- CN104893417A CN104893417A CN201510392096.5A CN201510392096A CN104893417A CN 104893417 A CN104893417 A CN 104893417A CN 201510392096 A CN201510392096 A CN 201510392096A CN 104893417 A CN104893417 A CN 104893417A
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- ink
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- opacifying property
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses single-component high-covering-property ink and a preparation method thereof and relates to the technical field of ink. The ink is prepared by using the following components in parts by weight: 51-61 parts of resin, 8-15 parts of solvent, 12-16 parts of adhesive force accelerator, 7-9 parts of pigment, 2-4 part of filler and 5-9 parts of assistant, wherein the assistant comprises thickener, delustering agent, wear-resistant anti-scratching agent, oil repellent, defoaming agent, dispersing agent and essence. The resin adopted by the invention is single-component resin, the chlorine content is low, the resin does not react with AB epoxy glue at high temperature of 120-150DEG C, yellowing which influences the brightness of an LED (Light Emitting Diode) lamp is not caused, the alcohol resisting performance is good, the printing adaptability is high, the production efficiency can be improved and the personal harm to construction personnel can be reduced.
Description
Technical field
The invention belongs to technical field of ink, particularly relate to high opacifying property ink of a kind of single-component and preparation method thereof.
Background technology
Adopt black ink coating LED base, the shading performance of pedestal can be increased, improve the brightness of LED, due to LED application widely, but its volume is little, and technique is many, so the performance requriements being applied to the ink in LED base is very high.The black oil of ink coating LED base mainly adopts two component ink at home, two component ink, primarily of filmogen and solidifying agent composition, must use after ink formulation is good, exceed this time under specific time and condition, ink just solidification is rotten, can not re-use.There is following open question in it: 1, two component ink will add the solidifying agent of amine, and smell is large, has harm to the health of construction worker; 2, the storage time is short, and after adding solidifying agent, the storage time of ink is 2-4 hour, easily causes the waste of ink; 3, must toast after adding solidifying agent, power consumption, adds cost; 4, perishable half tone after interpolation solidifying agent, the work-ing life of half tone shortens.
Summary of the invention
For the problems referred to above, the invention provides one and do not react with epoxy AB glue, high temperature non yellowing, ethanol-tolerant performance is good, opacifying property single-component black ink of the height that printing performance is good and preparation method thereof, for promoting the shading performance of LED base, improve the brightness of LED, concrete scheme is as follows:
The high opacifying property ink of a kind of single-component, described ink comprises following parts by weight ingredient:
Described auxiliary agent comprises thickening material, matting agent, wear-resisting scratch-resisting agent, oil-repellent, defoamer, dispersion agent, essence.
Further, described resin is propylene dichloride acid resin.
Further, described solvent is made up of anti-plain boiled water and isophorone, and the mass ratio of anti-plain boiled water and isophorone is 0.5-1.2:1.Preferably, described isophorone is selected from the isophorone 783 of Guangdong Huizhou Kun Yang Industrial Co., Ltd..
Further, described adhesion promoter is polyolefine adhesion promoter, preferably, and her native graceful polyolefine adhesion promoter CP-515-2 of what described polyolefine adhesion promoter adopted is U.S..
Further, described pigment is carbon black, the middle pigment MA-100 carbon black that the 6# carbon black adopting Evonik Degussa Corp.'s channel process to produce and Mitsubishi KCC produce, wherein 6# carbon black: MA-100 carbon black mass ratio is 0.6-1.2:1.
Further, described filler is made up of Zinic stearas and wax powder, and the mass ratio of Zinic stearas and wax powder is 1-2:1; Preferably, described Zinic stearas is preferably PLB Zinic stearas, and described wax powder is preferably the 9610F wax powder that Clariant Corporation of the U.S. produces.
Further, described thickening material is aerosil, is preferably Cabot aerosil M-5; Matting agent is preferably Degussa OK607 flatting silica; Wear-resisting scratch-resisting agent is preferably the agent of DOW CORNING DC-18 wear-resisting scratch-resisting; Oil-repellent is preferably the sub-47V500 oil-repellent in sieve ground; Defoamer is preferably the BYK-066N foam-killing agent of Bi Ke chemistry; Dispersion agent is preferably 983 dispersion agents of Taiwan De Qian company; Essence is preferably tuberose compound.
The preparation method of the high opacifying property ink of above-mentioned single-component, described preparation method comprises the following steps:
Step 1: by weight, mixes resin, dispersion agent, pigment, solvent, adhesion promoter, filler, thickening material, wear-resisting scratch-resisting agent and stirs;
Step 2: step 1 gained mixture is ground to fineness less than 5 μm;
Step 3: add matting agent in step 2 gained mixture, stir;
Step 4: step 3 gained mixture is added three-roller, grinding 2-3 time;
Step 5: add oil-repellent, defoamer, essence in step 4 gained mixture, stir and obtain ink.
Traditional ink adopts two component, and the present invention adopts single-component propylene dichloride acid resin, and the sticking power of this resin is good, and ethanol-tolerant performance is good, and cl content is low, and yellowing resistance can be outstanding, fundamentally solves the sticking power of ink, heatproof corrosion resistance problem; In order to meet the requirement of LED to ink flow leveling, the present invention adopts defoamer, and the ink flow levelling making to obtain, printing improve; Owing to using polyolefine adhesion promoter, make the sticking power of ink of the present invention outstanding.
To sum up, beneficial effect of the present invention is: (1) single-component ink, and do not need reinforcement agent, and seasoning reduces the hazard to person to construction worker, provides cost savings simultaneously; (2) single-component ink printing performance is good, frequently can change printing-ink, improve production efficiency; (3) this patent ink resin cl content is low, does not react under 120-150 DEG C of high temperature with AB epoxy glue, can not produce the brightness that xanthochromia affects LED, even if glue is encountered layer of ink and also do not had impact when encapsulating, improves non-defective unit qualification rate; (4) excellent PPO can be provided, PPA material cohesion; (5) ethanol-tolerant performance is good, the dehydrated alcohol wiping of resistance to 99.99% 50 times, and ink surface layer is colour-fast; (6) printing adaptability is good, directly can print not network blocking in more than 12 hours.Therefore, ensure that printing high efficiency, greatly simplify complicated technology when domestic pair of component ink uses.
Embodiment
In order to more fully understand technology contents of the present invention, below in conjunction with specific embodiment technical scheme of the present invention being introduced further and illustrating.
Embodiment 1
By weight, 51-61 part resin, 0.84 part of dispersion agent, 7-9 part carbon black, 9-15 part solvent, 13.65 parts of adhesion promoters, 2-4 part filler, 0.57 part of thickening material, 0.57 part of wear-resisting scratch-resisting agent are mixed and stir; Gained mixture adds three-roller and grinds 7 times to fineness less than 5 μm; Add 2.61 parts of matting agents again, add in three-roller after stirring and grind 2-3 time; Finally add 0.66 part of oil-repellent, 1.32 parts of defoamers, 0.47 part of tuberose compound, stir and obtain ink.
Wherein, solvent is made up of anti-plain boiled water and isophorone, and the mass ratio of anti-plain boiled water and isophorone is 0.5-1.2:1.Filler is made up of Zinic stearas and wax powder, and the mass ratio of Zinic stearas and wax powder is 1-2:1.
Embodiment 2
By weight, 55 parts of propylene dichloride acid resins, 0.7 part of dispersion agent, 8 parts of carbon blacks, 12 parts of solvents, 13 parts of polyolefine adhesion promoters, 3 parts of fillers, 0.7 part of thickening material, 0.7 part of wear-resisting scratch-resisting agent are mixed and stir; Gained mixture adds three-roller and grinds 7 times to fineness less than 5 μm; Add 2.5 parts of matting agents again, add in three-roller after stirring and grind 2-3 time; Finally add 0.8 part of oil-repellent, 1.52 parts of defoamers, 0.5 part of tuberose compound, stir and obtain ink.
Wherein, solvent is made up of anti-plain boiled water and isophorone, and the mass ratio of anti-plain boiled water and isophorone is 0.8:1.Filler by Zinic stearas and wax powder in mass ratio 1.5:1 mix.
Embodiment 3
By weight, 55 parts of propylene dichloride acid resins, 0.7 part of 983 dispersion agent, 8 parts of pigment, 12 parts of solvents, 13 parts of polyolefine adhesion promoters, 3 parts of fillers, 0.7 part of aerosil M-5, the agent of 0.7 part of DC-18 wear-resisting scratch-resisting are mixed and stir; Gained mixture adds three-roller and grinds 7 times to fineness less than 5 μm; Add 2.5 parts of OK607 matting agents again, add in three-roller after stirring and grind 2-3 time; Finally add 0.8 part of 47V500 oil-repellent, 1.52 parts of BYK-066N foam-killing agents, 0.5 part of tuberose compound, stir and obtain ink.
Wherein, solvent is made up of anti-plain boiled water and isophorone 783, and the mass ratio of anti-plain boiled water and isophorone 783 is 0.8:1.Pigment by 6# carbon black and MA-100 carbon black in mass ratio 0.9:1 proportions form.Filler by PLB Zinic stearas and 9610F wax powder in mass ratio 1.5:1 mix.
Embodiment 4
By weight, 61 parts of propylene dichloride acid resins, 0.7 part of 983 dispersion agent, 9 parts of pigment, 15 parts of solvents, 16 parts of polyolefine adhesion promoter CP-515-2,4 parts of fillers, 0.7 part of aerosil M-5, the agent of 0.6 part of DC-18 wear-resisting scratch-resisting are mixed and stir; Gained mixture adds three-roller and grinds 7 times to fineness less than 5 μm; Add 2.5 parts of OK607 matting agents again, add in three-roller after stirring and grind 2-3 time; Finally add 0.8 part of 47V500 oil-repellent, 1.52 parts of BYK-066N foam-killing agents, 0.5 part of tuberose compound, stir and obtain ink.
Wherein, solvent is made up of anti-plain boiled water and isophorone 783, and the mass ratio of anti-plain boiled water and isophorone 783 is 1.2:1.Pigment by 6# carbon black and MA-100 carbon black in mass ratio 1.2:1 proportions form.Filler by PLB Zinic stearas and 9610F wax powder in mass ratio 2:1 mix.
Embodiment 5
By weight, 51 parts of propylene dichloride acid resins, 0.7 part of 983 dispersion agent, 7 parts of pigment, 9 parts of solvents, 12 parts of polyolefine adhesion promoter CP-515-2,2 parts of fillers, 0.7 part of aerosil M-5, the agent of 0.6 part of DC-18 wear-resisting scratch-resisting are mixed and stir; Gained mixture adds three-roller and grinds 7 times to fineness less than 5 μm; Add 2.5 parts of OK607 matting agents again, add in three-roller after stirring and grind 2-3 time; Finally add 0.8 part of 47V500 oil-repellent, 1.52 parts of BYK-066N foam-killing agents, 0.5 part of tuberose compound, stir and obtain ink.
Wherein, solvent is made up of anti-plain boiled water and isophorone 783, and the mass ratio of anti-plain boiled water and isophorone 783 is 0.6:1.Pigment by 6# carbon black and MA-100 carbon black in mass ratio 0.6:1 proportions form.Filler by PLB Zinic stearas and 9610F wax powder in mass ratio 1:1 mix.
Embodiment 6
By weight, 3.52 parts of Degussa 6# carbon blacks are mixed with into 8.01 parts of pigment with 4.49 parts of TFA-100 carbon blacks; 5.42 parts of anti-plain boiled waters are mixed with into 12.49 parts of solvents with 7.07 parts of isophorones 783; 1.66 parts of PLB Zinic stearass are mixed with into 3.07 parts of fillers with 1.41 parts of 9610F wax powder.
55.74 parts of resins, 0.84 part of dispersion agent, 8.01 parts of pigment, 12.49 parts of solvents, 13.65 parts of polyolefine adhesion promoter CP-515-2,1.66 parts of fillers, 0.57 part of aerosil M-5, the agent of 0.57 part of DC-18 wear-resisting scratch-resisting are mixed and stir; Gained mixture adds three-roller and grinds 7 times to fineness less than 5 μm; Add 2.61 parts of OK607 matting agents again, add in three-roller after stirring and grind 2-3 time; Finally add 0.66 part of 47V500 oil-repellent, 1.32 parts of BYK-066N foam-killing agents, 0.47 part of tuberose compound, stir and obtain ink.
The above only further illustrates technology contents of the present invention with embodiment, so that reader is easier to understand, but does not represent embodiments of the present invention and is only limitted to this, and any technology done according to the present invention extends or recreation, all by protection of the present invention.
Claims (7)
1. the high opacifying property ink of single-component, it is characterized in that, described ink comprises following parts by weight ingredient:
Described auxiliary agent comprises thickening material, matting agent, wear-resisting scratch-resisting agent, oil-repellent, defoamer, dispersion agent, essence.
2. the high opacifying property ink of single-component according to claim 1, it is characterized in that, described resin is propylene dichloride acid resin.
3. the high opacifying property ink of single-component according to claim 1, it is characterized in that, described solvent is made up of anti-plain boiled water and isophorone, and the mass ratio of anti-plain boiled water and isophorone is 0.5-1.2:1.
4. the high opacifying property ink of single-component according to claim 1, it is characterized in that, described adhesion promoter is polyolefine adhesion promoter.
5. the high opacifying property ink of single-component according to claim 1, it is characterized in that, described pigment is carbon black.
6. the high opacifying property ink of single-component according to claim 1, it is characterized in that, described filler is made up of Zinic stearas and wax powder, and the mass ratio of Zinic stearas and wax powder is 1-2:1.
7. a preparation method for opacifying property ink as high in claim 1-6 any one single-component, it is characterized in that, described making method comprises the following steps:
Step 1: by weight, mixes resin, dispersion agent, pigment, solvent, adhesion promoter, filler, thickening material, wear-resisting scratch-resisting agent and stirs;
Step 2: step 1 gained mixture is ground to fineness less than 5 μm;
Step 3: add matting agent in step 2 gained mixture, stir;
Step 4: step 3 gained mixture is added three-roller, grinding 2-3 time;
Step 5: add oil-repellent, defoamer, essence in step 4 gained mixture, stir and obtain ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510392096.5A CN104893417B (en) | 2015-07-06 | 2015-07-06 | A kind of high covering ink of one-component and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510392096.5A CN104893417B (en) | 2015-07-06 | 2015-07-06 | A kind of high covering ink of one-component and preparation method thereof |
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| CN104893417A true CN104893417A (en) | 2015-09-09 |
| CN104893417B CN104893417B (en) | 2017-07-14 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118613A (en) * | 2017-05-10 | 2017-09-01 | 京东方科技集团股份有限公司 | A kind of ink, OLED frames of ink printing and preparation method thereof |
| CN111621191A (en) * | 2020-07-14 | 2020-09-04 | 庞行行 | Water-based black ink |
| CN112980240A (en) * | 2021-02-25 | 2021-06-18 | 苏州欧普照明有限公司 | Printing ink, lampshade applying printing ink, preparation method of lampshade and lamp |
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| JP2006299136A (en) * | 2005-04-22 | 2006-11-02 | Toyo Ink Mfg Co Ltd | Gravure printing ink composition for surface printing |
| CN101698756A (en) * | 2007-11-14 | 2010-04-28 | 谢群林 | Black ink used for printing on PP synthetic paper and production method thereof |
| CN102408782A (en) * | 2011-09-13 | 2012-04-11 | 中华制漆（深圳）有限公司 | Transfer printing ink for polypropylene plastics, and preparation method and application thereof |
| CN103773108A (en) * | 2014-01-29 | 2014-05-07 | 苏州昭奇凯虹精细化工有限公司 | White ink for glass cover plates |
-
2015
- 2015-07-06 CN CN201510392096.5A patent/CN104893417B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006299136A (en) * | 2005-04-22 | 2006-11-02 | Toyo Ink Mfg Co Ltd | Gravure printing ink composition for surface printing |
| CN101698756A (en) * | 2007-11-14 | 2010-04-28 | 谢群林 | Black ink used for printing on PP synthetic paper and production method thereof |
| CN102408782A (en) * | 2011-09-13 | 2012-04-11 | 中华制漆（深圳）有限公司 | Transfer printing ink for polypropylene plastics, and preparation method and application thereof |
| CN103773108A (en) * | 2014-01-29 | 2014-05-07 | 苏州昭奇凯虹精细化工有限公司 | White ink for glass cover plates |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118613A (en) * | 2017-05-10 | 2017-09-01 | 京东方科技集团股份有限公司 | A kind of ink, OLED frames of ink printing and preparation method thereof |
| CN107118613B (en) * | 2017-05-10 | 2021-01-22 | 京东方科技集团股份有限公司 | Printing ink, OLED frame printed by printing ink and preparation method of OLED frame |
| CN111621191A (en) * | 2020-07-14 | 2020-09-04 | 庞行行 | Water-based black ink |
| CN112980240A (en) * | 2021-02-25 | 2021-06-18 | 苏州欧普照明有限公司 | Printing ink, lampshade applying printing ink, preparation method of lampshade and lamp |
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| CN104893417B (en) | 2017-07-14 |
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