CN111607711A - Liquid tin rapid cooling device and method - Google Patents

Liquid tin rapid cooling device and method Download PDF

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Publication number
CN111607711A
CN111607711A CN202010582199.9A CN202010582199A CN111607711A CN 111607711 A CN111607711 A CN 111607711A CN 202010582199 A CN202010582199 A CN 202010582199A CN 111607711 A CN111607711 A CN 111607711A
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CN
China
Prior art keywords
tin
pot
steam
water
stirring machine
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010582199.9A
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Chinese (zh)
Inventor
宋兴诚
李正永
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Yunnan Tin Industry Co ltd
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Yunnan Tin Industry Co ltd
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Publication date
Application filed by Yunnan Tin Industry Co ltd filed Critical Yunnan Tin Industry Co ltd
Priority to CN202010582199.9A priority Critical patent/CN111607711A/en
Publication of CN111607711A publication Critical patent/CN111607711A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B25/00Obtaining tin
    • C22B25/08Refining
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/06Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being molten; Use of molten metal, e.g. zinc, as heat transfer medium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D15/00Handling or treating discharged material; Supports or receiving chambers therefor
    • F27D15/02Cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

A liquid tin rapid cooling device and a method are disclosed, the device comprises a tin pot and a stirring machine, the tin pot is a steel tin pot, a plurality of groups of cooling tube bundles are welded on the outer wall of the tin pot, ports at the bottom of the cooling tube bundles are softened water inlets, and ports at the top of the cooling tube bundles are steam-water mixture outlets; the softened water inlet is communicated with softened water, and the steam-water mixture outlet is connected to a steam-water separator of the steam system; the stirring machine is an electric integrated tin liquid stirring machine which is arranged on one side of the tin refining pot through a stirring machine mounting foot stand and can rotate around a stirring machine rotating device to place or remove a stirring paddle into or out of a tin liquid layer in the tin refining pot and is driven by a stirring machine transmission motor. The invention does not need to spray water on the surface of the molten tin for cooling, and does not need natural cooling for a long time, thereby shortening the operation time and improving the work efficiency; meanwhile, the phenomenon that a large amount of water vapor containing dust is generated due to the fact that water is directly poured on the surface of the tin liquid to be cooled is avoided, the risk that the high-temperature tin liquid directly meets water for explosion is also avoided, and the safety and environment-friendly effects are obvious.

Description

Liquid tin rapid cooling device and method
Technical Field
The invention belongs to the technical field of nonferrous metal metallurgy equipment, and particularly relates to a liquid tin rapid cooling device and a method.
Background
In the refining process of tin, the temperature of molten tin needs to be increased or decreased according to the requirements of impurity removal, casting and the like, and the method of burning or electric heating under a tin pot is generally adopted for increasing the temperature of the molten tin.
The temperature of the tin liquid is reduced, and the traditional operation method is that cold water is poured on the surface of the high-temperature liquid tin for cooling, so that the temperature of the high-temperature liquid tin is reduced to a target temperature, or the high-temperature tin liquid is naturally cooled to the target temperature for a long time. The method of pouring cold water on the surface of the high-temperature liquid tin for cooling to reduce the temperature of the high-temperature liquid tin to the target temperature needs to spray a large amount of cold water into a tin receiving pot for cooling. Cold water and high temperature liquid tin direct contact can produce a large amount of dust and vapor that contain harmful elements such as heavy metal, have the risk that high temperature liquid tin directly meets water explosion simultaneously, and environmental protection and safety problem are outstanding. The method for naturally cooling the high-temperature tin liquid to the target temperature for a long time needs long-time natural cooling, and has the advantages of slow cooling process, long operation time and low working efficiency. In some cases, the long-term cooling can also cause impurities in the tin liquid to rise, resulting in the condition of unqualified products. For example, the tin of the product with the residual aluminum removed is higher than the optimal casting temperature, and in the process of cooling and waiting for casting, if the cooling speed is too slow, the iron in a tin pot can be dissolved into tin liquid, so that the situation that the iron content of the refined tin product is increased to exceed the standard is caused.
By the two cooling methods, the energy released when the high-temperature liquid tin is cooled to a proper temperature is not utilized, but is wasted, and the energy utilization efficiency is poor.
Disclosure of Invention
The invention aims to solve the problems of the existing liquid tin cooling method, and provides a device and a method for rapidly cooling liquid tin, so as to achieve the purposes of improving the working efficiency and the heat utilization rate and reducing the safety and environmental protection risks.
The purpose of the invention is realized by the following technical scheme:
a liquid tin rapid cooling device is composed of a tin pot and a stirring machine; the tin pot is made of steel, a plurality of groups of cooling tube bundles are welded on the outer wall of the tin pot, ports at the bottoms of the cooling tube bundles are softened water inlets, and ports at the tops of the cooling tube bundles are steam-water mixture outlets; the softened water inlet is communicated with softened water, and the steam-water mixture outlet is connected to a steam-water separator of the steam system;
the stirring machine is an electric integrated tin liquid stirring machine which is arranged on one side of the tin refining pot through a stirring machine mounting foot stand and can rotate around a stirring machine rotating device to place or remove a stirring paddle into or out of a tin liquid layer in the tin refining pot and is driven by a stirring machine transmission motor.
Preferably, the cooling tube bundles are arranged in four groups and are arranged on the outer wall of the tin pot at equal intervals.
The invention also discloses a method for rapidly cooling liquid tin, which comprises the following steps:
1) when the tin liquid in the tin pot needs to be cooled, respectively opening a softened water inlet of the cooling tube bundle to inject softened cooling water into the cooling tube bundle;
2) softened cooling water absorbs heat of a tin liquid layer in the tin pot in the cooling tube bundle and is vaporized into steam, and the steam are discharged to a steam-water separator of an external steam system from a steam-water mixture outlet and are respectively recycled;
3) the stirring paddle is placed into the tin liquid layer in the tin pot to be stirred by the rotary stirring machine, so that the temperature of the tin liquid layer in the tin pot is uniform; and when the temperature of the tin liquid layer is reduced to the required target temperature, the softened water inlet is closed.
The invention has at least the following beneficial effects:
1) the invention can quickly cool the high-temperature tin liquid to the target temperature according to the requirement, does not need to spray water on the surface of the tin liquid for cooling, does not need to naturally cool for a long time, shortens the operation time and improves the work efficiency; meanwhile, the phenomenon that a large amount of water vapor containing dust is generated due to the fact that water is directly poured on the surface of the tin liquid for cooling is avoided, the risk that the high-temperature tin liquid directly encounters water for explosion is also avoided, and the safety and environmental protection effects are obvious;
2) the invention enables a large amount of heat in the high-temperature tin liquid to be efficiently recovered in the process of conducting to the cooling tube bundle on the outer wall of the pot, and the heat is converted into clean steam for a heat supply system, so that the heat utilization rate is greatly improved, and the energy-saving effect is good.
Drawings
FIG. 1 is a schematic diagram of the present invention.
Detailed Description
Embodiments of the present invention will now be described with reference to the accompanying drawings. It will be appreciated by those skilled in the art that the following examples are illustrative of the invention only and should not be taken as limiting the scope of the invention. The specific techniques, connections, conditions, or the like, which are not specified in the examples, are performed according to the techniques, connections, conditions, or the like described in the literature in the art or according to the product specification. The materials, instruments or equipment are not indicated by manufacturers, and all the materials, instruments or equipment are conventional products which can be obtained by purchasing.
Referring to fig. 1, a liquid tin rapid cooling device is composed of a tin pot 1 and a stirring machine 2; the tin pot 1 is made of steel, and four groups of cooling tube bundles 5 are welded on the outer wall of the tin pot 1 at equal intervals; the port at the bottom of the cooling tube bundle 5 is a softened water inlet 6, and the port at the top of the cooling tube bundle 5 is a steam-water mixture outlet 7; a softened water inlet 6 is communicated with softened water, and a steam-water mixture outlet 7 is connected to a steam-water separator of the steam system;
the stirrer 2 is an electric integrated tin liquid stirrer which is arranged on one side of the tin refining pot 1 through a stirrer mounting foot stand 8 and can rotate around a stirrer rotating device 9 to place or move the stirring paddle 4 into or out of the tin liquid layer 3 in the tin refining pot through a stirrer driving motor 10.
The method for using the cooling device comprises the following steps:
1) when the tin liquid in the tin pot 1 needs to be cooled, respectively opening a softened water inlet 6 of the cooling tube bundle 5 to inject softened cooling water into the cooling tube bundle 5;
2) softened cooling water absorbs heat of a tin liquid layer in a tin pot in a cooling tube bundle 5 and is vaporized into steam, the steam is discharged to a steam-water separator of an external steam system from a steam-water mixture outlet 7, and the steam and the water are respectively recovered and utilized;
3) the stirring paddle 4 is placed into the tin liquid layer 3 in the tin pot 1 to be stirred by the rotary stirring machine 2, so that the temperature of the tin liquid layer 3 in the tin pot 1 is uniform; when the temperature of the tin liquid layer 3 is reduced to the required target temperature, the softened water inlet 6 is closed.
The above disclosure is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the scope of the present invention, therefore, the present invention is not limited by the appended claims.

Claims (3)

1. The utility model provides a liquid tin rapid cooling device which characterized in that: the device consists of a tin pot (1) and a stirring machine (2); wherein the content of the first and second substances,
the tin pot (1) is made of steel, a plurality of groups of cooling tube bundles (5) are welded on the outer wall of the tin pot (1), the port of the bottom of each cooling tube bundle (5) is a softened water inlet (6), and the port of the top of each cooling tube bundle (5) is a steam-water mixture outlet (7); a softened water inlet (6) is communicated with softened water, and a steam-water mixture outlet (7) is connected to a steam-water separator of the steam system;
the stirring machine (2) is an electric integrated tin liquid stirring machine which is arranged on one side of the tin refining pot (1) through a stirring machine mounting foot stand (8) and can rotate around a stirring machine rotating device (9) to place or remove the stirring paddle (4) into or out of a tin liquid layer (3) in the tin refining pot and is driven by a stirring machine driving motor (10).
2. The liquid tin rapid cooling device according to claim 1, characterized in that: the cooling tube bundles (5) are arranged in four groups and are arranged on the outer wall of the tin pot (1) at equal intervals.
3. A method of using the cooling device of claim 1 or 2, characterized by the steps of:
1) when the tin liquid in the tin pot (1) needs to be cooled, a softened water inlet (6) of a cooling tube bundle (5) is respectively opened to inject softened cooling water into the cooling tube bundle (5);
2) softened cooling water absorbs heat of a tin liquid layer in a tin pot in a cooling tube bundle (5) and is vaporized into steam, the steam is discharged to a steam-water separator of an external steam system from a steam-water mixture outlet (7), and the steam and the water are respectively recovered;
3) the rotary stirring machine (2) is used for placing the stirring paddle (4) into the tin liquid layer (3) in the tin pot (1) for stirring, so that the temperature of the tin liquid layer (3) in the tin pot (1) is uniform; and when the temperature of the tin liquid layer (3) is reduced to the required target temperature, the softened water inlet (6) is closed.
CN202010582199.9A 2020-06-23 2020-06-23 Liquid tin rapid cooling device and method Pending CN111607711A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010582199.9A CN111607711A (en) 2020-06-23 2020-06-23 Liquid tin rapid cooling device and method

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Application Number Priority Date Filing Date Title
CN202010582199.9A CN111607711A (en) 2020-06-23 2020-06-23 Liquid tin rapid cooling device and method

Publications (1)

Publication Number Publication Date
CN111607711A true CN111607711A (en) 2020-09-01

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113758280A (en) * 2021-09-14 2021-12-07 云南锡业股份有限公司锡业分公司 Tin heating and heat preservation method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4356033A (en) * 1980-06-10 1982-10-26 Davey Thomas R A Process for refining metals by drossing procedures
CN1287575A (en) * 1998-10-29 2001-03-14 同和矿业株式会社 High purity gallium for preparation of compound semiconductor, and method and apparatus for purifying the same
CN204359175U (en) * 2014-12-10 2015-05-27 灵宝金源矿业股份有限公司 A kind of warm sludge cooling heat exchanger
CN107151719A (en) * 2017-06-01 2017-09-12 佘云锋 A kind of blast furnace crucibe
CN208649431U (en) * 2018-07-09 2019-03-26 江西龙天勇有色金属有限公司 A kind of refining furnace that the thick bismuth of oxygen-enriched bottom-blowing metal is smelted
CN212610847U (en) * 2020-06-23 2021-02-26 云南锡业股份有限公司锡业分公司 Liquid tin rapid cooling device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4356033A (en) * 1980-06-10 1982-10-26 Davey Thomas R A Process for refining metals by drossing procedures
CN1287575A (en) * 1998-10-29 2001-03-14 同和矿业株式会社 High purity gallium for preparation of compound semiconductor, and method and apparatus for purifying the same
CN204359175U (en) * 2014-12-10 2015-05-27 灵宝金源矿业股份有限公司 A kind of warm sludge cooling heat exchanger
CN107151719A (en) * 2017-06-01 2017-09-12 佘云锋 A kind of blast furnace crucibe
CN208649431U (en) * 2018-07-09 2019-03-26 江西龙天勇有色金属有限公司 A kind of refining furnace that the thick bismuth of oxygen-enriched bottom-blowing metal is smelted
CN212610847U (en) * 2020-06-23 2021-02-26 云南锡业股份有限公司锡业分公司 Liquid tin rapid cooling device

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
云南锡业公司、昆明工学院《锡冶金》编写组著: "《锡冶金》", 30 November 1977, 北京:冶金工业出版社, pages: 249 - 251 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113758280A (en) * 2021-09-14 2021-12-07 云南锡业股份有限公司锡业分公司 Tin heating and heat preservation method
CN113758280B (en) * 2021-09-14 2023-10-20 云南锡业股份有限公司锡业分公司 Tin heating and heat preserving method

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