CN111607688B - Method for laser phase transformation hardening of shot blasting machine blade surface - Google Patents

Method for laser phase transformation hardening of shot blasting machine blade surface Download PDF

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CN111607688B
CN111607688B CN202010640356.7A CN202010640356A CN111607688B CN 111607688 B CN111607688 B CN 111607688B CN 202010640356 A CN202010640356 A CN 202010640356A CN 111607688 B CN111607688 B CN 111607688B
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blasting machine
shot blasting
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吴成萌
冯爱新
韩磊
张成龙
林晋豪
徐国秀
余满江
肯尼斯
巴米莱
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
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    • C21D1/09Surface hardening by direct application of electrical or wave energy; by particle radiation
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
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    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0068Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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Abstract

本发明涉及对抛丸机叶片表面激光相变硬化的方法,将配比的抛丸机叶片的原料成分投入中频感应电阻炉中熔炼,升温至1535~1555℃,将熔炼的铁水浇筑到预先用砂子制成的抛丸机叶片模具中进行铸造;铁水冷却成型后得到抛丸机叶片,将抛丸机叶片从砂型模具内取出,去除表面残留的砂子和浇冒口,清理抛丸机叶片上的飞边和毛刺;根据抛丸机叶片不同区域性能要求和控制冷却条件,选择激光加工参数;在激光相变硬化装置上将抛丸机叶片预热到120℃后,对抛丸机叶片按照扫描路径进行相变强化。激光相变硬化具有“极快极冷”特点,在极短的时间内将抛丸机叶片淬火层组织从原来的柱状马氏体变为针状马氏体,避免长时间的过渡而产生其它的脆性组织。

Figure 202010640356

The invention relates to a method for laser phase transformation hardening on the surface of a shot blasting machine blade. The raw material components of the shot blasting machine blade are put into an intermediate frequency induction resistance furnace for smelting, and the temperature is raised to 1535-1555 DEG C. Casting is carried out in the shot blasting machine blade mold made of sand; after the molten iron is cooled and formed, the shot blasting machine blade is obtained, and the shot blasting machine blade is taken out from the sand mold, the residual sand and pouring riser on the surface are removed, and the shot blasting machine blade is cleaned. Select the laser processing parameters according to the performance requirements of different areas of the shot blasting machine blade and control the cooling conditions; after preheating the shot blasting machine blade to 120 °C on the laser phase transformation hardening device, the shot blasting machine blade according to Scan path for phase transformation strengthening. Laser phase transformation hardening has the characteristics of "extremely fast and extremely cold", which changes the structure of the quenched layer of the shot blasting machine blade from the original columnar martensite to acicular martensite in a very short time, avoiding long-term transition and other brittle tissue.

Figure 202010640356

Description

对抛丸机叶片表面激光相变硬化的方法Method for laser phase transformation hardening of shot blasting machine blade surface

技术领域technical field

本发明涉及一种对抛丸机叶片表面激光相变硬化的方法。The invention relates to a method for hardening the surface of a shot blasting machine blade by laser phase transformation.

背景技术Background technique

目前,随着我国工业的快速发展,磨损现象是造成机械零件失效和能源损失的重要因素之一,有数据表明,约有30%的世界一次能源是因磨损而损失的,大约70%的机电设备是因各种形式的磨损而损坏的。At present, with the rapid development of my country's industry, wear and tear is one of the important factors causing failure of mechanical parts and energy loss. According to data, about 30% of the world's primary energy is lost due to wear and tear, and about 70% of electromechanical energy is lost due to wear and tear. Equipment is damaged by various forms of wear and tear.

抛丸机应用广泛,通过依靠叶片对弹丸进行做功,来使零件达到一定耐磨性、高强度等性能要求。对于整个抛丸机来说抛丸器上的叶片是最关键的部件,由于弹丸持续高速冲击和周期应力的影响,更是加剧叶片的损耗,因此叶片是抛丸机中最容易磨碎的部件,而且在我们国家每年因叶片的磨损而消耗的材料成本不断增加,高达数千万,给国家以及相应企业带来巨大的经济损失。The shot blasting machine is widely used. By relying on the blades to perform work on the projectile, the parts can meet certain performance requirements such as wear resistance and high strength. For the entire shot blasting machine, the blade on the shot blasting machine is the most critical component. Due to the continuous high-speed impact of the projectile and the influence of cyclic stress, the loss of the blade is aggravated, so the blade is the most easily ground part in the shot blasting machine. Moreover, the cost of materials consumed by the wear of blades in our country is increasing every year, reaching tens of millions, which brings huge economic losses to the country and corresponding enterprises.

淬火的目的是使过冷奥氏体进行马氏体或贝氏体转变,得到马氏体或贝氏体组织,传统的抛丸机叶片的淬火工艺中采用的是箱式电阻炉对抛丸机叶片淬火,从而延长其耐磨性的主要手段,但大多数企业甚至在发达国家也存在重加热轻冷却,对淬火冷却过程的投入研发力度不大,再加上淬火冷却工艺复杂方面的技术障碍,所以一直没有形成标准的淬火冷却工艺流程,所以淬火过后的抛丸机叶片质量不稳定,甚至还会出现脆裂,耽误生产效率。The purpose of quenching is to transform the supercooled austenite into martensite or bainite to obtain martensite or bainite structure. The main means of quenching the blade of the machine, thereby prolonging its wear resistance, but most companies even in developed countries have heavy heating and light cooling, the investment in research and development of the quenching and cooling process is not large, and the technology in the complex quenching and cooling process is Therefore, the standard quenching and cooling process has not been formed, so the quality of the shot blasting machine blades after quenching is unstable, and even brittle cracks may occur, delaying production efficiency.

综上所述,要保证叶片具有高的冲击韧性和硬度,不仅需要控制好叶片材料中化学成分及含量,确保叶片的微观组织中基体和碳化物的平衡,还要保证淬火工艺的稳定性,避免表面开裂。In summary, to ensure that the blade has high impact toughness and hardness, it is not only necessary to control the chemical composition and content of the blade material, to ensure the balance of matrix and carbide in the microstructure of the blade, but also to ensure the stability of the quenching process. Avoid surface cracking.

发明内容SUMMARY OF THE INVENTION

本发明的目的是克服现有技术存在的不足,提供一种对抛丸机叶片表面激光相变硬化的方法。The purpose of the present invention is to overcome the deficiencies in the prior art and provide a method for laser phase transformation hardening of the surface of a shot blasting machine blade.

本发明的目的通过以下技术方案来实现:The object of the present invention is achieved through the following technical solutions:

对抛丸机叶片表面激光相变硬化的方法,特点是:包括以下步骤:The method for laser phase transformation hardening on the surface of a shot blasting machine blade is characterized by including the following steps:

1)将配比的抛丸机叶片的原料成分投入中频感应电阻炉中熔炼,升温至1535~1555℃,将熔炼的铁水浇筑到预先用砂子制成的抛丸机叶片模具中进行铸造;1) put the raw material composition of the shot blasting machine blade in proportion into the intermediate frequency induction resistance furnace for smelting, heat up to 1535~1555 ℃, pour the smelted molten iron into the shot blasting machine blade mold made in advance with sand for casting;

2)铁水冷却成型后得到抛丸机叶片,将抛丸机叶片从砂型模具内取出,去除表面残留的砂子和浇冒口,清理抛丸机叶片上的飞边和毛刺;2) After the molten iron is cooled and formed, the shot blasting machine blade is obtained, the shot blasting machine blade is taken out from the sand mold, the residual sand and pouring riser on the surface are removed, and the flash and burr on the shot blasting machine blade are cleaned;

3)根据抛丸机叶片不同区域性能要求和控制冷却条件,选择激光加工参数;3) According to the performance requirements of different areas of the shot blasting machine blade and the control cooling conditions, select the laser processing parameters;

4)在激光相变硬化装置上将抛丸机叶片预热到120℃后,对抛丸机叶片按照扫描路径进行相变强化。4) After preheating the shot blasting machine blade to 120°C on the laser phase transformation hardening device, phase transformation strengthening is performed on the shot blasting machine blade according to the scanning path.

进一步地,上述的对抛丸机叶片表面激光相变硬化的方法,其中,抛丸机叶片的成分及质量百分比为:C:2.8~3.2%,Cr:4~5%,Si:0.4~0.8%,Mn:0.5~1.2%,P≤0.035%,S≤0.035%,Re≤0.05%,余量为Fe和通常炼钢中存在的化学元素。Further, in the above-mentioned method for laser phase transformation hardening of the surface of a shot blasting machine blade, the composition and mass percentage of the shot blasting machine blade are: C: 2.8-3.2%, Cr: 4-5%, Si: 0.4-0.8 %, Mn: 0.5~1.2%, P≤0.035%, S≤0.035%, Re≤0.05%, the balance is Fe and chemical elements usually present in steelmaking.

进一步地,上述的对抛丸机叶片表面激光相变硬化的方法,其中,将熔炼的铁水温度降至100~1420℃时,浇筑到预先用砂子制成的抛丸机叶片模具中进行铸造Further, the above-mentioned method for laser phase transformation hardening of the surface of a shot blasting machine blade, wherein, when the temperature of the molten iron is lowered to 100-1420 ° C, it is poured into a shot blasting machine blade mold made of sand in advance for casting.

进一步地,上述的对抛丸机叶片表面激光相变硬化的方法,其中,所述抛丸机叶片不同区域性能要求,抛丸机叶片工作过程中,受到弹丸持续的冲击产生循环应力,弹丸在抛丸机叶片上发生滚动摩擦和滑动摩擦,根据抛丸机叶片使用的性能要求,叶片表面划分为冲击区和滑动、磨损区,冲击区弹丸入射角为20°,磨损区弹丸入射角为0°,滑动、磨损区的磨损高于冲击区,造成基体材料变形和碳化物扩展断裂失效,弹丸在冲击区与抛丸机叶片发生冲击磨料磨损,在滑动、磨损区由于离心力的作用半径大,发生大的滑动摩擦,滑动、磨损区需具有高的冲击韧性和耐磨性,冲击区需具有比滑动、磨损区小的冲击韧性和耐磨性。Further, the above-mentioned method for laser phase transformation hardening of the surface of a shot blasting machine blade, wherein, the performance requirements of different regions of the shot blasting machine blade, during the working process of the shot blasting machine blade, the continuous impact of the projectile generates cyclic stress, and the projectile is in the process. Rolling friction and sliding friction occur on the blade of the shot blasting machine. According to the performance requirements of the blade of the shot blasting machine, the surface of the blade is divided into an impact area and a sliding and wear area. The projectile incident angle in the impact area is 20°, and the projectile incident angle in the wear area is 0. °, the wear in the sliding and wear area is higher than that in the impact area, resulting in the deformation of the matrix material and the failure of the carbide expansion and fracture. The projectile and the shot blasting machine blade impact abrasive wear in the impact area. In the sliding and wear area, due to the large radius of centrifugal force, When large sliding friction occurs, the sliding and wear areas need to have high impact toughness and wear resistance, and the impact area needs to have smaller impact toughness and wear resistance than the sliding and wear areas.

进一步地,上述的对抛丸机叶片表面激光相变硬化的方法,其中,所述抛丸机叶片不同区域控制冷却条件,根据材料的过冷奥氏体等温冷却转变曲线即TTT曲线,或者过冷奥氏体连续冷却转变曲线即CCT曲线,得到获得组织达到一温度的最长冷却时间或最小冷却速率,根据抛丸机叶片弹出弹丸的一端位置为起点,设定一距离范围内预期的组织;抛丸机叶片表面和心部的冷却速度不同,抛丸机叶片沿截面从表面到中心划分为表层区域、亚表层区域和心部,表层区域区域通过控制冷却速度获得预期的组织进而满足力学性能要求,亚表层区域和心部通过缓速冷却,避免冷却速度区域已经转变的马氏体或贝氏体组织因温度回升过高而发生过回火,影响抛丸机叶片的使用性能。Further, in the above-mentioned method for laser phase transformation hardening of the surface of a shot blasting machine blade, wherein the cooling conditions are controlled in different areas of the shot blasting machine blade, according to the isothermal cooling transformation curve of the supercooled austenite of the material, that is, the TTT curve, or the supercooled austenite. The continuous cooling transformation curve of cold austenite is the CCT curve, and the longest cooling time or the minimum cooling rate for the obtained structure to reach a temperature is obtained. According to the position of one end of the shot blasting machine blade ejecting the projectile as the starting point, the expected structure within a distance range is set. ; The cooling speed of the surface and the core of the shot blasting machine blade is different. The shot blasting machine blade is divided into surface area, subsurface area and core part from the surface to the center along the cross section. The surface area area can obtain the expected structure by controlling the cooling rate to meet the mechanical requirements Performance requirements, the subsurface area and the core are cooled slowly to avoid the over-tempering of the martensite or bainite structure that has been transformed in the cooling rate area due to the high temperature recovery, which affects the performance of the shot blasting machine blade.

进一步地,上述的对抛丸机叶片表面激光相变硬化的方法,其中,激光相变硬化装置包含用于运载抛丸机叶片的工作台以及用于对其预热的加热器,光纤激光器输出光路上依次布置宽带扫描转镜和激光头,宽带扫描转镜将激光转成宽带激光,即线形光斑,通过激光头聚焦于工作台上的抛丸机叶片表面。Further, the above-mentioned method for laser phase transformation hardening of the surface of a shot blasting machine blade, wherein the laser phase transformation hardening device includes a worktable for carrying the shot blasting machine blade and a heater for preheating it, and the fiber laser output The broadband scanning rotating mirror and the laser head are arranged in sequence on the optical path. The broadband scanning rotating mirror converts the laser into a broadband laser, that is, a linear light spot, which is focused on the surface of the shot blasting machine blade on the worktable through the laser head.

进一步地,上述的对抛丸机叶片表面激光相变硬化的方法,其中,在激光相变硬化装置上对抛丸机叶片进行相变强化,步骤如下:Further, the above-mentioned method for laser phase transformation hardening of the surface of a shot blasting machine blade, wherein the phase transformation strengthening of the shot blasting machine blade is performed on a laser phase transformation hardening device, and the steps are as follows:

41)对抛丸机叶片进行黑化处理;41) Blackening treatment of shot blasting machine blades;

42)利用加热器对抛丸机叶片预热到120℃;42) Use a heater to preheat the blades of the shot blasting machine to 120°C;

43)启动光纤激光器,光纤激光器输出的光束进入宽带扫描转镜,宽带扫描转镜将激光转成宽带激光,即线形光斑,通过激光头聚焦于工作台上的工件表面;43) Start the fiber laser, the light beam output by the fiber laser enters the broadband scanning rotating mirror, and the broadband scanning rotating mirror converts the laser into a broadband laser, that is, a linear spot, which is focused on the workpiece surface on the workbench through the laser head;

44)根据抛丸机叶片划分不同区域冷却速度的要求计算结果,设置激光器加工的功率、扫描速度,光斑尺寸以及扫描路径。44) Set the laser processing power, scanning speed, spot size and scanning path according to the calculation results of the cooling speed requirements for different areas of the shot blasting machine blade.

进一步地,上述的对抛丸机叶片表面激光相变硬化的方法,其中,激光器加工的功率为2.5KW、扫描速度5mm/s,光斑尺寸10mm×4mm,选择无搭接的扫描路径。Further, in the above-mentioned method for laser phase transformation hardening of the surface of a shot blasting machine blade, the laser processing power is 2.5KW, the scanning speed is 5mm/s, the spot size is 10mm×4mm, and the scanning path without overlap is selected.

本发明与现有技术相比具有显著的优点和有益效果,具体体现在以下方面:Compared with the prior art, the present invention has significant advantages and beneficial effects, which are embodied in the following aspects:

本发明对抛丸机叶片表面激光相变硬化的工艺,由于激光相变硬化具有“极快极冷”特点,即加热快和冷却快,可以在极短的时间内将抛丸机叶片淬火层组织从原来的柱状马氏体变为针状马氏体,避免长时间的过渡而产生其它的脆性组织,从而极大改善了抛丸机叶片的性能;For the laser phase transformation hardening process of the shot blasting machine blade surface of the present invention, because the laser phase transformation hardening has the characteristics of "extremely fast and extremely cold", that is, fast heating and fast cooling, the quenching layer of the shot blasting machine blade can be quenched in a very short time. The structure changes from the original columnar martensite to acicular martensite, avoiding the long-term transition and producing other brittle structures, thus greatly improving the performance of the shot blasting machine blade;

抛丸机叶片在避免开裂的前提下获得要求的性能或组织,适用于不同成分的抛丸机叶片表面的激光相变硬化处理,表面的柱状马氏体变为针状的马氏体,从而极大的提高了抛丸机叶片的硬度、耐磨性以及淬火层深,避免传统淬火-回火处理技术带来的缺陷,使得材料或零件表面产生残余压应力,从而提升了表层的机械性能;不仅提高抛丸机的效率,而且极大的提升抛丸机叶片的服役性能,从而减低生产成本。The shot blasting machine blade obtains the required performance or structure on the premise of avoiding cracking, and is suitable for the laser phase transformation hardening treatment of the surface of the shot blasting machine blade with different compositions, and the columnar martensite on the surface becomes acicular martensite, thereby The hardness, wear resistance and quenching layer depth of the shot blasting machine blade are greatly improved, avoiding the defects caused by the traditional quenching-tempering treatment technology, resulting in residual compressive stress on the surface of the material or part, thereby improving the mechanical properties of the surface layer. ; Not only improves the efficiency of the shot blasting machine, but also greatly improves the service performance of the shot blasting machine blade, thereby reducing the production cost.

本发明的其他特征和优点将在随后的说明书阐述,并且,部分地从说明书中变得显而易见,或者通过实施本发明具体实施方式了解。本发明的目的和其他优点可通过在所写的说明书、权利要求书中所特别指出的结构来实现和获得。Other features and advantages of the invention will be set forth in the description which follows, and in part will be apparent from the description, or learned by practice of the detailed description of the invention. The objectives and other advantages of the invention may be realized and attained by the structure particularly pointed out in the written description and claims.

附图说明Description of drawings

图1:抛丸机叶片表面激光相变硬化装置的示意图;Figure 1: Schematic diagram of the laser phase transformation hardening device on the blade surface of the shot blasting machine;

图2:抛丸机叶片表面激光相变硬化扫描路径的示意图;Figure 2: Schematic diagram of the laser phase transformation hardening scanning path on the surface of the shot blasting machine blade;

图3:抛丸机叶片表面激光相变硬化工艺流程示意图。Figure 3: Schematic diagram of the laser phase transformation hardening process flow of the blade surface of the shot blasting machine.

具体实施方式Detailed ways

为了对本发明的技术特征、目的和效果有更加清楚的理解,现详细说明具体实施方案。In order to have a clearer understanding of the technical features, objects and effects of the present invention, specific embodiments will now be described in detail.

如图1,激光相变硬化装置包含用于运载抛丸机叶片4的工作台5以及用于对其预热的加热器6,光纤激光器1输出光路上依次布置宽带扫描转镜2和激光头3,宽带扫描转镜3将激光转成宽带激光,即线形光斑,通过激光头3聚焦于工作台上的抛丸机叶片表面。As shown in Figure 1, the laser phase change hardening device includes a table 5 for carrying the shot blasting machine blade 4 and a heater 6 for preheating it. The broadband scanning mirror 2 and the laser head are sequentially arranged on the output optical path of the fiber laser 1 3. The broadband scanning mirror 3 converts the laser light into a broadband laser, that is, a linear light spot, which is focused on the surface of the shot blasting machine blade on the worktable through the laser head 3 .

对抛丸机叶片表面激光相变硬化的方法,如图3,包括以下步骤:The method of laser phase transformation hardening on the surface of the shot blasting machine blade, as shown in Figure 3, includes the following steps:

1)将配比的抛丸机叶片的原料成分投入中频感应电阻炉中熔炼,升温至1535~1555℃,将熔炼的铁水温度降至100~1420℃时,浇筑到预先用砂子制成的抛丸机叶片模具中进行铸造;1) Put the raw material components of the shot blasting machine blades into the intermediate frequency induction resistance furnace for smelting, heat up to 1535-1555 ℃, and when the molten iron temperature is lowered to 100-1420 ℃, pour it to the cast iron made of sand in advance. Casting in a pellet mill blade mold;

2)铁水冷却成型后得到抛丸机叶片,将抛丸机叶片从砂型模具内取出,去除表面残留的砂子和浇冒口,清理抛丸机叶片上的飞边和毛刺;2) After the molten iron is cooled and formed, the shot blasting machine blade is obtained, the shot blasting machine blade is taken out from the sand mold, the residual sand and pouring riser on the surface are removed, and the flash and burr on the shot blasting machine blade are cleaned;

3)根据抛丸机叶片不同区域性能要求和控制冷却条件,选择激光加工参数;3) According to the performance requirements of different areas of the shot blasting machine blade and the control cooling conditions, select the laser processing parameters;

抛丸机叶片不同区域性能要求,抛丸机叶片工作过程中,受到弹丸持续的冲击产生循环应力,弹丸在抛丸机叶片上发生滚动摩擦和滑动摩擦,根据抛丸机叶片使用的性能要求,叶片表面划分为冲击区和滑动、磨损区,冲击区弹丸入射角为20°,滑动、磨损区弹丸入射角为0°,滑动、磨损区的磨损高于冲击区,造成基体材料变形和碳化物扩展断裂失效,弹丸在冲击区与抛丸机叶片发生冲击磨料磨损,在滑动、磨损区由于离心力的作用半径较大,还发生较大的滑动摩擦,滑动、磨损区需具有高的冲击韧性和耐磨性,冲击区需具有比滑动、磨损区小的冲击韧性和耐磨性;The performance requirements of different areas of the shot blasting machine blade. During the working process of the shot blasting machine blade, the continuous impact of the projectile produces cyclic stress, and the projectile produces rolling friction and sliding friction on the shot blasting machine blade. According to the performance requirements of the shot blasting machine blade, The blade surface is divided into impact area and sliding and wear area. The projectile incident angle in the impact area is 20°, and the projectile incident angle in the sliding and wear area is 0°. The wear of the sliding and wear area is higher than that of the impact area, resulting in deformation of the matrix material and carbides The extended fracture fails. The projectile has impact and abrasive wear on the impact zone and the blade of the shot blasting machine. In the sliding and wear zone, due to the large radius of action of centrifugal force, large sliding friction also occurs. The sliding and wear zone needs to have high impact toughness and Wear resistance, the impact area needs to have less impact toughness and wear resistance than the sliding and wear areas;

抛丸机叶片不同区域控制冷却条件,根据材料的过冷奥氏体等温冷却转变曲线即TTT曲线,或者过冷奥氏体连续冷却转变曲线即CCT曲线,得到获得组织达到一温度的最长冷却时间或最小冷却速率,根据抛丸机叶片弹出弹丸的一端位置为起点,设定一距离范围内预期的组织;抛丸机叶片表面和心部的冷却速度不同,抛丸机叶片沿截面从表面到中心划分为表层区域、亚表层区域和心部,表层区域区域通过控制冷却速度获得预期的组织进而满足力学性能要求,亚表层区域和心部通过缓速冷却,避免冷却速度区域已经转变的马氏体或贝氏体组织因温度回升过高而发生过回火,影响抛丸机叶片的使用性能;The cooling conditions are controlled in different areas of the shot blasting machine blade. According to the isothermal cooling transformation curve of the supercooled austenite of the material, namely the TTT curve, or the continuous cooling transformation curve of the supercooled austenite, the CCT curve, the longest cooling time to obtain the microstructure to a temperature is obtained. Time or minimum cooling rate, according to the position of one end of the shot blasting machine blade ejecting the projectile as the starting point, the expected structure within a distance range is set; To the center, it is divided into surface area, subsurface area and core. The surface area can obtain the expected structure by controlling the cooling rate to meet the requirements of mechanical properties. The subsurface area and the core are cooled slowly to avoid the change of the cooling rate area. The intenite or bainite structure is over-tempered due to the high temperature rise, which affects the service performance of the shot blasting machine blade;

4)在激光相变硬化装置上将抛丸机叶片预热到120℃后,对抛丸机叶片按照扫描路径进行相变强化;具体工艺步骤如下:4) After preheating the shot blasting machine blade to 120°C on the laser phase transformation hardening device, phase transformation strengthening is performed on the shot blasting machine blade according to the scanning path; the specific process steps are as follows:

41)对抛丸机叶片进行黑化处理;41) Blackening treatment of shot blasting machine blades;

42)利用加热器6将工件(抛丸机叶片)4预热到120℃;42) Use the heater 6 to preheat the workpiece (blade of the shot blasting machine) 4 to 120°C;

43)启动光纤激光器1,光纤激光器1输出的光束进入宽带扫描转镜2,宽带扫描转镜2将激光转成宽带激光,即线形光斑,通过激光头3聚焦于工作台5上的工件(抛丸机叶片)4的表面;43) Start the fiber laser 1, the beam output from the fiber laser 1 enters the broadband scanning mirror 2, and the broadband scanning mirror 2 converts the laser into a broadband laser, that is, a linear spot, and is focused on the workpiece (polishing) on the table 5 through the laser head 3. The surface of the pill machine blade) 4;

44)根据抛丸机叶片划分不同区域冷却速度的要求计算结果,设置激光器加工的功率为2.5KW、扫描速度5mm/s,光斑尺寸10mm×4mm,选择无搭接的扫描路径,如图2。44) According to the calculation results of the cooling speed requirements for different areas of the shot blasting machine blade, set the laser processing power to 2.5KW, the scanning speed of 5mm/s, the spot size of 10mm × 4mm, and the scanning path without overlap, as shown in Figure 2.

实施例:Example:

对抛丸机叶片进行相变强化时,通过试样,了解抛丸机叶片材料的过冷奥氏体等温冷却转变曲线(TTT曲线)或过冷奥氏体连续冷却转变曲线(CCT曲线),最后可通过冷却温度场的计算确定激光淬火工艺参数。When carrying out phase transformation strengthening of shot blasting machine blades, through the sample, understand the isothermal cooling transformation curve of supercooled austenite (TTT curve) or the continuous cooling transformation curve of supercooled austenite (CCT curve) of the material of the shot blasting machine blade, Finally, the laser quenching process parameters can be determined through the calculation of the cooling temperature field.

S1、按照抛丸机叶片中所含的化学成分及含量,其化学成分及质量百分比为:C:2.8-3.2%,Cr:4~5%,Si:0.4-0.8%,Mn:0.5-1.2%,P≤0.035%,S≤0.035%,Re≤0.05%,余量为Fe和通常炼钢中存在的化学元素,在中频感应电阻炉中进行熔炼加热到1535~1555℃时,将生成的铁水降温到1400℃时,浇筑到预先用砂子制成的抛丸机叶片模具中进行铸造;S1. According to the chemical composition and content contained in the blade of the shot blasting machine, its chemical composition and mass percentage are: C: 2.8-3.2%, Cr: 4-5%, Si: 0.4-0.8%, Mn: 0.5-1.2 %, P≤0.035%, S≤0.035%, Re≤0.05%, the balance is Fe and chemical elements usually present in steelmaking, when smelted in an intermediate frequency induction resistance furnace and heated to 1535 ~ 1555 ℃, the resulting When the molten iron is cooled to 1400 °C, it is poured into the shot blasting machine blade mold made of sand in advance for casting;

S2、等铁水冷却成型后得到抛丸机叶片,将抛丸机叶片从砂型模具内部取出来,去除表面残留的砂子和浇冒口,并清理抛丸机叶片上产生的飞边和毛刺;S2. After the molten iron is cooled and formed, the shot blasting machine blade is obtained, and the shot blasting machine blade is taken out from the inside of the sand mold, the residual sand and pouring riser on the surface are removed, and the flash and burr generated on the shot blasting machine blade are cleaned;

S3、根据抛丸机叶片不同区域性能要求和控制冷却条件,选择合适激光加工的参数,激光功率2.5Kw,扫描速度5mm/s,光斑大小10mm×4mm;S3. According to the performance requirements of different areas of the shot blasting machine blade and the control cooling conditions, select the appropriate laser processing parameters, the laser power is 2.5Kw, the scanning speed is 5mm/s, and the spot size is 10mm×4mm;

根据叶片的受力和使用性能要求,将叶片表面划分为冲击区(弹丸入射角为20°)和滑动、磨损区(弹丸入射角为0°),且滑动、磨损区的磨损较磨损区严重,造成基体材料变形和碳化物扩展断裂失效;According to the force and performance requirements of the blade, the blade surface is divided into impact zone (projectile incident angle is 20°) and sliding and wear zone (projectile incident angle is 0°), and the wear of sliding and wear zone is more serious than that of wear zone , causing the deformation of the matrix material and the failure of carbide expansion fracture;

弹丸在冲击区与抛丸机叶片发生冲击磨料磨损,而在滑动、磨损区由于离心力的作用半径较大,还发生较大的滑动摩擦,因此,叶片表面的滑动、磨损区要具有高的冲击韧性和耐磨性,而冲击区要具有比滑动、磨损区较小的冲击韧性和耐磨性,因此,滑动、磨损区的叶片表面预测所含的针状马氏体组织比冲击区所含的针状马氏体组织要多;The projectile has impact abrasive wear on the blade of the shot blasting machine in the impact area, and in the sliding and wear area, due to the large radius of action of centrifugal force, large sliding friction also occurs. Therefore, the sliding and wear area of the blade surface must have high impact. Toughness and wear resistance, while the impact zone has smaller impact toughness and wear resistance than the sliding and wear zone. Therefore, the blade surface of the sliding and wear zone is predicted to contain acicular martensite structure than the impact zone. The acicular martensitic structure is more;

结合材料的过冷奥氏体等温冷却转变曲线(TTT曲线),可根据奥氏体冷却到临界点A1以下在各不同温度下的保温过程中的转变量与转变时间的关系曲线,选择合适的转变温度以及所对应的转变时间;Combined with the isothermal cooling transformation curve (TTT curve) of the supercooled austenite of the material, the appropriate one can be selected according to the relationship between the transformation amount and the transformation time during the heat preservation process at different temperatures when the austenite is cooled to below the critical point A1. transition temperature and corresponding transition time;

结合材料的过冷奥氏体连续冷却转变曲线(CCT曲线),激光加热是在极短的时间间隔内完成,不会影响随后的激光淬火组织,因此可以选择的加热温度范围宽,所以在CCT曲线中可以选择出合适的临界淬火速度Vc(上临界速度),因为当冷却速度大于临界淬火速度Vc,则过冷奥氏体只发生马氏体转变;Combined with the supercooled austenite continuous cooling transformation curve (CCT curve) of the material, the laser heating is completed in a very short time interval and will not affect the subsequent laser quenching structure, so the heating temperature range that can be selected is wide, so in CCT The appropriate critical quenching speed Vc (upper critical speed) can be selected in the curve, because when the cooling rate is greater than the critical quenching speed Vc, the supercooled austenite only undergoes martensitic transformation;

将抛丸机叶片沿截面从表面到中心划分为表层区域、亚表层区域和心部,根据抛丸机叶片弹出弹丸的一端位置为起点,设定在合适距离的范围内预期组织,由于抛丸机叶片表面和心部的冷却速度不同,将表层区域区域通过控制冷却速度获得预期的组织进而满足力学性能要求,亚表层区域和心部通过缓速冷却,从而避免冷却速度区域已经转变的马氏体或贝氏体组织因温度回升过高而发生过回火,从而降低了抛丸机叶片的性能;The shot blasting machine blade is divided into surface area, sub-surface area and core part from the surface to the center along the cross section. According to the position of one end of the shot blasting machine blade ejecting the projectile as the starting point, the expected structure is set within a suitable distance. The cooling speed of the surface and the core of the blade is different. The surface area is controlled by the cooling speed to obtain the expected structure to meet the mechanical performance requirements. The sub-surface area and the core are cooled slowly, so as to avoid the transformation of the cooling speed area. The body or bainite structure is over-tempered due to the high temperature rise, thereby reducing the performance of the shot blasting machine blade;

还根据表面换热系数对抛丸机叶片在冷却过程的温度场进行数值模拟,进一步确定划分区域合适的距离和激光淬火加工的参数,保证表面区域避免出现脆裂,心部位置避免出现淬不硬现象的发生;According to the surface heat transfer coefficient, the temperature field of the shot blasting machine blade during the cooling process is numerically simulated, and the appropriate distance of the divided area and the parameters of laser quenching processing are further determined to ensure that the surface area avoids brittle cracking, and the core position avoids quenching. occurrence of hard phenomena;

S4、在激光相变硬化装置上先进行预热处理后,对抛丸机叶片按照预定的扫描路径进行相变强化,其激光相变硬化装置如图1,扫描路径如图2所示;S4. After preheating treatment on the laser phase transformation hardening device, phase transformation strengthening is performed on the blades of the shot blasting machine according to the predetermined scanning path. The laser phase transformation hardening device is shown in Figure 1, and the scanning path is shown in Figure 2;

对抛丸机叶片利用线切割机进行取样,并通过丙酮去除表面杂质,利用石墨和碳素墨水进行黑化处理、风干;The shot blasting machine blade is sampled by a wire cutting machine, and the surface impurities are removed by acetone, and graphite and carbon ink are used for blackening treatment and air drying;

对黑化后的抛丸机叶片通过加热器进行加热,将抛丸机叶片的温度加热到120℃;The blackened shot blasting machine blade is heated by a heater, and the temperature of the shot blasting machine blade is heated to 120 °C;

启动激光器,利用扫描转镜将激光转成宽带激光,聚焦在工件表面,根据淬火深度和激光比能密度的关系,验证所选的根据抛丸机叶片划分不同区域冷却速度的要求计算出的结果,设置激光器相变强化加工需要的激光功率2.5KW,扫描速度5mm/s,光斑大小10mm×4mm,采用不搭接,减少搭接处因重复加热而软化,避免导致表面的硬度不均。Start the laser, use the scanning mirror to convert the laser into a broadband laser, focus on the surface of the workpiece, and verify the selected result calculated according to the requirements of the cooling rate of the shot blasting machine blade to divide the different areas according to the relationship between the quenching depth and the laser specific energy density , Set the laser power required for laser phase change strengthening processing to 2.5KW, the scanning speed of 5mm/s, the spot size of 10mm × 4mm, and the use of non-lap joints to reduce the softening of the overlapped joints due to repeated heating and avoid uneven hardness on the surface.

实施例制备的抛丸机叶片,与传统电阻炉淬火的抛丸机叶片以及未淬火的抛丸机叶片进行对比,采用维氏硬度计测试显微硬度,测试结果如下表所示:The shot blasting machine blade prepared in the embodiment is compared with the traditional resistance furnace quenched shot blasting machine blade and the unquenched shot blasting machine blade, and the microhardness is tested by a Vickers hardness tester. The test results are shown in the following table:

Figure BDA0002570816320000081
Figure BDA0002570816320000081

Figure BDA0002570816320000091
Figure BDA0002570816320000091

由上表可知,本发明采用激光相变硬化工艺对抛丸机叶片表面强化,其硬度值显著提高,从而保证抛丸机叶片的使用性能。It can be seen from the above table that the present invention adopts the laser phase transformation hardening process to strengthen the surface of the shot blasting machine blade, and its hardness value is significantly improved, thereby ensuring the service performance of the shot blasting machine blade.

综上所述,本发明对抛丸机叶片表面激光相变硬化的工艺,由于激光相变硬化具有“极快极冷”特点,即加热快和冷却快,可以在极短的时间内将抛丸机叶片淬火层组织从原来的柱状马氏体变为针状马氏体,避免长时间的过渡而产生其它的脆性组织,从而极大改善了抛丸机叶片的性能;To sum up, the process of the present invention for the laser phase transformation hardening of the surface of the shot blasting machine blade, because the laser phase transformation hardening has the characteristics of "extremely fast and extremely cold", that is, fast heating and fast cooling, and can be shot blasting in a very short time. The structure of the quenched layer of the shot blasting machine blade changes from the original columnar martensite to acicular martensite, avoiding the long-term transition and other brittle structures, thus greatly improving the performance of the shot blasting machine blade;

抛丸机叶片在避免开裂的前提下获得要求的性能或组织,适用于不同成分的抛丸机叶片表面的激光相变硬化处理,表面的柱状马氏体变为针状的马氏体,从而极大的提高了抛丸机叶片的硬度、耐磨性以及淬火层深,避免传统淬火-回火处理技术带来的缺陷,使得材料或零件表面产生残余压应力,从而提升了表层的机械性能。不仅提高抛丸机的效率,而且极大的提升抛丸机叶片的服役性能,从而减低生产成本。The shot blasting machine blade obtains the required performance or structure on the premise of avoiding cracking, and is suitable for the laser phase transformation hardening treatment of the surface of the shot blasting machine blade with different compositions, and the columnar martensite on the surface becomes acicular martensite, thereby The hardness, wear resistance and quenching layer depth of the shot blasting machine blade are greatly improved, avoiding the defects caused by the traditional quenching-tempering treatment technology, resulting in residual compressive stress on the surface of the material or part, thereby improving the mechanical properties of the surface layer. . It not only improves the efficiency of the shot blasting machine, but also greatly improves the service performance of the shot blasting machine blade, thereby reducing the production cost.

需要说明的是:以上所述仅为本发明的优选实施方式,并非用以限定本发明的权利范围;同时以上的描述,对于相关技术领域的专门人士应可明了及实施,因此其它未脱离本发明所揭示的精神下所完成的等效改变或修饰,均应包含在申请专利范围中。It should be noted that: the above description is only the preferred embodiment of the present invention, and is not intended to limit the scope of the right of the present invention; at the same time, the above description should be understood and implemented by professionals in the relevant technical field, so others do not deviate from the present invention. Equivalent changes or modifications accomplished under the spirit of the disclosed invention shall be included in the scope of the patent application.

Claims (5)

1. The laser phase change hardening method for the surface of the shot blasting machine blade is characterized by comprising the following steps: the method comprises the following steps:
1) putting the raw material components of the shot blasting machine blade into a medium-frequency induction resistance furnace for smelting, heating to 1535-1555 ℃, pouring the smelted molten iron into a shot blasting machine blade mould made of sand in advance for casting;
2) cooling and molding the molten iron to obtain a shot blasting machine blade, taking the shot blasting machine blade out of the sand mold, removing sand and a casting head remained on the surface, and cleaning burrs and fins on the shot blasting machine blade;
3) selecting laser processing parameters according to performance requirements and cooling control conditions of different areas of the shot blasting machine blade;
4) preheating the blades of the shot blasting machine to 120 ℃ on a laser phase change hardening device, and then carrying out phase change strengthening on the blades of the shot blasting machine according to a scanning path, wherein the steps are as follows:
41) carrying out blackening treatment on the shot blasting machine blade;
42) preheating the shot blasting machine blade to 120 ℃ by using a heater;
43) starting the fiber laser, enabling a light beam output by the fiber laser to enter a broadband scanning rotating mirror, converting laser into broadband laser by the broadband scanning rotating mirror, namely linear light spots, and focusing the laser on the surface of a workpiece on a workbench through a laser head;
44) setting the processing power, scanning speed, spot size and scanning path of a laser according to the calculation result of the cooling speed requirements of different areas divided by the shot blasting machine blades;
the method comprises the steps that different areas of the blades of the shot blasting machine are required to have high performance, the blades of the shot blasting machine are continuously impacted to generate cyclic stress, the shot generates rolling friction and sliding friction on the blades of the shot blasting machine, according to the performance requirements of the blades of the shot blasting machine, the surfaces of the blades are divided into an impact area and a sliding and abrasion area, the shot incident angle of the impact area is 20 degrees, the shot incident angle of the sliding and abrasion area is 0 degree, the abrasion of the sliding and abrasion area is higher than that of the impact area, so that deformation of a base material and expansion and fracture failure of carbide are caused, the shot generates impact abrasive material abrasion with the blades of the shot blasting machine in the impact area, the sliding and abrasion area generates large sliding friction due to large acting radius of centrifugal force, the sliding and abrasion area needs to have high impact toughness and abrasion resistance, and the impact area needs to have smaller impact toughness and abrasion resistance than the sliding and abrasion area;
controlling cooling conditions in different areas of the shot blasting machine blade, obtaining the longest cooling time or the minimum cooling rate when the obtained tissue reaches a certain temperature according to a supercooled austenite isothermal cooling transformation curve (TTT curve) or supercooled austenite continuous cooling transformation curve (CCT curve) of the material, and setting an expected tissue in a distance range by taking one end position of the shot ejected by the shot blasting machine blade as a starting point; the cooling speed of the surface and the core of the shot blasting machine blade is different, the shot blasting machine blade is divided into a surface layer area, a sub-surface layer area and a core from the surface to the center along the cross section, the surface layer area obtains an expected structure by controlling the cooling speed so as to meet the requirement of mechanical property, and the sub-surface layer area and the core are cooled slowly, so that the phenomenon that the martensite or bainite structure converted in the cooling speed area is over-tempered due to the fact that the temperature rises back to be too high and the use performance of the shot blasting machine blade is influenced is avoided.
2. The method for laser phase change hardening of the surface of the shot blasting machine blade as recited in claim 1, wherein: the shot blasting machine blade comprises the following components in percentage by mass: c: 2.8-3.2%, Cr: 4-5%, Si: 0.4-0.8%, Mn: 0.5-1.2%, P is less than or equal to 0.035%, S is less than or equal to 0.035%, Re is less than or equal to 0.05%, and the balance is Fe and chemical elements existing in common steel making.
3. The method for laser phase change hardening of the surface of the shot blasting machine blade as recited in claim 1, wherein: and when the temperature of the smelted molten iron is reduced to 100-1420 ℃, pouring the molten iron into a shot blasting machine blade mould made of sand in advance for casting.
4. The method for laser phase change hardening of the surface of the shot blasting machine blade as recited in claim 1, wherein: the laser phase change hardening device comprises a workbench for carrying the shot blasting machine blades and a heater for preheating the shot blasting machine blades, a broadband scanning rotating mirror and a laser head are sequentially arranged on an output light path of the optical fiber laser, and the broadband scanning rotating mirror converts laser into broadband laser, namely linear light spots, and the broadband laser is focused on the surfaces of the shot blasting machine blades on the workbench through the laser head.
5. The method for laser phase change hardening of the surface of the shot blasting machine blade as recited in claim 1, wherein: the power of laser processing is 2.5KW, the scanning speed is 5mm/s, the spot size is 10mm multiplied by 4mm, and a non-overlapping scanning path is selected.
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