CN111607307A - zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof - Google Patents
zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof Download PDFInfo
- Publication number
- CN111607307A CN111607307A CN202010535299.6A CN202010535299A CN111607307A CN 111607307 A CN111607307 A CN 111607307A CN 202010535299 A CN202010535299 A CN 202010535299A CN 111607307 A CN111607307 A CN 111607307A
- Authority
- CN
- China
- Prior art keywords
- agent
- voc
- paint
- quick
- scratch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Abstract
The invention discloses a zero VOC quick-drying scratch-resistant bright black finish paint and a preparation method thereof, belonging to the technical field of paint, and comprising a main paint and a curing agent, wherein the main paint comprises the following components in parts by weight: the weight ratio of the curing agent is 100: 5; the main paint comprises the following components in percentage by mass: 93-96% of polymethyl methacrylate resin, 2-5% of carbon black, 0.2-0.4% of anti-settling agent, 0.8-1% of dispersing agent, 0.4-0.6% of defoaming agent, 0.3-0.5% of flatting agent, 2.3-2.7% of thinner, 2.4-2.9% of auxiliary material and 5.1-6.5% of curing agent, and does not contain organic solvent, so that the paint can be rapidly cured without being influenced by environmental conditions, a coating film is endowed with high fullness, high hardness and high gloss and has a black jade-like coating effect, the scratch resistance is obviously better than that of the existing bright black finish paint, the coating efficiency and the product packaging time are greatly improved, no VOC (volatile organic compound) is discharged in the construction process, and the paint belongs to green environment-friendly paint.
Description
Technical Field
The invention relates to the technical field of coating and paint, in particular to a zero-VOC quick-drying scratch-resistant bright black finish and a preparation method thereof.
Background
Along with social development, people have higher and higher taste to living environment and home furnishing, and like to dress families by furniture with various colors, wherein the furniture coated with the bright black finish paint has full vision like black jade, brings noble enjoyment to consumers, and is deeply favored by market and customers. However, the PU bright black finish paint adopted by the furniture enterprises at present generally has long drying time, needs a large amount of places to place finished products, can be packed after 48 hours, seriously influences the production efficiency and the product delivery rate, simultaneously has poor scratch resistance, is easy to generate clear and visible surface scratches in the using process to influence the attractiveness, particularly discharges a large amount of VOC in the coating process, becomes an important source for polluting the atmospheric environment, does not meet increasingly harsh environmental requirements, is continuously limited to use, and troubles manufacturers and engineering technicians all the time. In order to overcome the defects, the scratch-resistant bright black finish paint for the woodware, which has high hardness, high fullness, low VOC and high coating efficiency, is urgently needed to be developed, and meets the requirements of current consumers on the coating effect and the continuous improvement of environmental protection.
Disclosure of Invention
The invention aims to provide a zero-VOC quick-drying scratch-resistant glossy black finish and a preparation method thereof, wherein no organic solvent or volatile solvent is added, the coating film is endowed with a high-fullness, high-hardness and high-gloss blackish-jade-like coating effect, the scratch resistance is obviously better than that of the existing glossy black finish, the coating efficiency and the product packaging time are greatly improved, and no VOC is discharged in the construction process, so that the stability of the coating is ensured, and the problems in the background technology are solved.
In order to achieve the purpose, the invention provides the following technical scheme: a zero VOC quick-drying scratch-resistant bright black finish paint comprises a main paint and a curing agent, wherein the main paint comprises: the weight ratio of the curing agent is 100: 5;
the main paint comprises the following components in percentage by mass: 93-96% of polymethyl methacrylate resin, 2-5% of carbon black, 0.2-0.4% of anti-settling agent, 0.8-1% of dispersing agent, 0.4-0.6% of defoaming agent and 0.3-0.5% of flatting agent;
the curing agent is benzoyl peroxide.
Further, the solid content of the zero-VOC quick-drying scratch-resistant bright black finish paint is 100%.
Further, the thinner is composed of one or more of epoxy silane coupling agent and thinner.
Further, the polymethyl methacrylate resin is Degaroute465 resin.
Further, the carbon black is high-pigment carbon black, and the anti-settling agent is fumed silica.
Further, the defoaming agent is a modified siloxane type defoaming agent suitable for solvent-free coating systems, and the dispersing agent is a copolymer dispersing agent with a modified block structure.
The invention provides another technical scheme, which comprises a preparation method of a zero VOC quick-drying scratch-resistant bright black finish paint, and comprises the following steps:
s1: preparing a main paint:
weighing the following raw materials in percentage by mass: 93-96% of polymethyl methacrylate resin, 2-5% of carbon black, 0.2-0.3% of anti-settling agent, 0.8-1% of dispersing agent, 0.4-0.6% of defoaming agent and 0.3-0.5% of flatting agent;
putting the polymethyl methacrylate resin with the formula amount of 80%, the anti-settling agent and the dispersing agent into a dispersion cylinder, and dispersing for 10 minutes at 800-;
putting the carbon black in the formula amount into a dispersion cylinder, dispersing for 15 minutes at high speed of 1500 rpm at 1200-;
s2: according to the main paint: and (3) uniformly mixing the two components according to the weight ratio of 100:5 of the curing agent to obtain the zero-VOC quick-drying scratch-resistant bright black finish paint.
Compared with the prior art, the invention has the beneficial effects that: the zero-VOC quick-drying scratch-resistant bright black finish paint and the preparation method thereof have the advantages of excellent construction tolerance, no influence of environmental temperature and humidity, ultralow-temperature curing performance, capability of being constructed at the temperature of-20 ℃ and quickly curing to form a film, generally less than 30 minutes of surface drying time and less than 2 hours of actual drying time, obviously shortened packing time, thoroughly solving the problem that the production period of furniture is prolonged due to slow drying of the paint caused by low temperature in winter, greatly improving production efficiency, and greatly meeting the industrial high-quality and high-efficiency construction requirements of furniture enterprises on products.
The paint has excellent weather resistance, no aromatic structure and no color changing group in the paint system, and no color change after long-term use, thereby ensuring that the paint film is as bright as a mirror for a long time.
The coating agent is completely free of solvent addition, no solvent is volatilized in the construction process, no VOC is discharged, the coating agent is environment-friendly, the production environment of coating workers is improved, the coating agent has important significance on energy conservation, emission reduction, low carbon and environmental protection, and the national environmental protection emission requirement is met.
Excellent scratch resistance, high hardness, smoothness, bright coating effect like a mirror, obviously better performance than the existing bright black finish, meeting the high decoration requirement of high-grade woodware products and being suitable for the aesthetic appearance of consumers and the environmental protection requirement.
The furniture enterprise does not need to increase expensive equipment and change the existing process, the current production situation and the process condition of the current enterprise are met, the energy consumption is not required to be increased, a large-area paint drying place is not required, the production space is saved, and an economic and quick environment-friendly solution is provided for the transformation and upgrading of the furniture enterprise.
Drawings
FIG. 1 is a process flow diagram of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the preparation method of the zero VOC quick-drying scratch-resistant bright black finish comprises the following steps:
the method comprises the following steps: preparing a main paint:
the first step is as follows: weighing the following raw materials in percentage by mass: 93% of polymethyl methacrylate resin, 5% of carbon black, 0.3% of anti-settling agent, 1% of dispersing agent, 0.4% of defoaming agent and 0.3% of flatting agent;
the second step is that: putting the polymethyl methacrylate resin with the formula amount of 80%, the anti-settling agent and the dispersing agent into a dispersion cylinder, and dispersing for 10 minutes at 800-;
the third step: putting the carbon black in the formula amount into a dispersion cylinder, dispersing at high speed of 1500 rpm for 15 minutes at 1200 rpm, grinding by a sand mill until the fineness is less than 15um, cleaning the sand mill by using the remaining polymethyl methacrylate resin, putting the rest of the auxiliary agents in the formula amount, dispersing for 10 minutes at 800 rpm at 600 rpm, and uniformly dispersing to obtain the main paint;
step two: the two components are uniformly mixed according to the weight ratio of the main paint to the curing agent of 100:5, and the zero VOC quick-drying scratch-resistant bright black finish paint is obtained.
Example two:
the preparation method of the zero VOC quick-drying scratch-resistant bright black finish comprises the following steps:
the method comprises the following steps: preparing a main paint:
the first step is as follows: weighing the following raw materials in percentage by mass: 94% of polymethyl methacrylate resin, 4% of carbon black, 0.3% of anti-settling agent, 0.9% of dispersing agent, 0.4% of defoaming agent and 0.4% of flatting agent;
the second step is that: putting the polymethyl methacrylate resin with the formula amount of 80%, the anti-settling agent and the dispersing agent into a dispersion cylinder, and dispersing for 10 minutes at 800-;
the third step: putting the carbon black in the formula amount into a dispersion cylinder, dispersing at high speed of 1500 rpm for 15 minutes at 1200 rpm, grinding by a sand mill until the fineness is less than 15um, cleaning the sand mill by using the remaining polymethyl methacrylate resin, putting the rest of the auxiliary agents in the formula amount, dispersing for 10 minutes at 800 rpm at 600 rpm, and uniformly dispersing to obtain the main paint;
step two: the two components are uniformly mixed according to the weight ratio of the main paint to the curing agent of 100:5, and the zero VOC quick-drying scratch-resistant bright black finish paint is obtained.
Example three:
firstly, the preparation of the zero VOC quick-drying scratch-resistant bright black finish coat comprises the following steps:
the method comprises the following steps: preparing a main paint:
the first step is as follows: weighing the following raw materials in percentage by mass: 96% of polymethyl methacrylate resin, 2% of carbon black, 0.2% of anti-settling agent, 0.8% of dispersing agent, 0.6% of defoaming agent and 0.4% of flatting agent;
the second step is that: putting the polymethyl methacrylate resin with the formula amount of 80%, the anti-settling agent and the dispersing agent into a dispersion cylinder, and dispersing for 10 minutes at 800-;
the third step: putting the carbon black in the formula amount into a dispersion cylinder, dispersing at high speed of 1500 rpm for 15 minutes at 1200 rpm, grinding by a sand mill until the fineness is less than 15um, cleaning the sand mill by using the remaining polymethyl methacrylate resin, putting the rest of the auxiliary agents in the formula amount, dispersing for 10 minutes at 800 rpm at 600 rpm, and uniformly dispersing to obtain the main paint;
step two: the two components are uniformly mixed according to the weight ratio of the main paint to the curing agent of 100:5, and the zero VOC quick-drying scratch-resistant bright black finish paint is obtained.
The polymethyl methacrylate resin is a Degaroute465 resin, the resin is a micromolecule substance, has extremely low viscosity, can quickly wet a substrate, has excellent leveling property, contains a large amount of unsaturated double bonds with high activity, generates free radical polymerization under the initiation action of benzoyl peroxide, is completely and quickly cured to form a macromolecular reticular structure, ensures that a film formed by the film has excellent performance, forms a bright film like a mirror with high hardness and high fullness, has excellent scratch resistance, does not have an aromatic structure and a color-changing group in the resin, has excellent weather resistance, and achieves the effect of ensuring the mirror surface of the film for a long time.
The carbon black is high-pigment carbon black, so that the covering power and the brightness of the coating film are greatly improved. The anti-settling agent is fumed silica, a hydrogen bond network structure with thixotropy is formed in a system, an excellent anti-settling effect is obtained, the construction performance of the coating is improved, good leveling property and anti-sagging property are provided, and a satisfactory coating effect is obtained.
The dispersing agent is a copolymer dispersing agent with a modified block structure, can quickly wet carbon black particles in a solvent-free system, shortens the dispersing and grinding time, enables the bright black finish paint to have good storage stability, improves the tinting strength and the covering power of the paint, improves the leveling property, and obtains higher gloss and blackness.
The defoaming agent is a modified siloxane defoaming agent suitable for a solvent-free coating system, has a very obvious defoaming effect, is easy to permeate into the surface of bubbles for spreading, causes the surface tension of the bubbles to be unbalanced, reduces the stability of the bubbles to break the bubbles, effectively and quickly eliminates the bubbles in a thick coating film without generating the undesirable phenomena of surface fog, shrinkage cavity and the like, and forms a uniform and smooth mirror coating.
The leveling agent is formed by mixing the polyether modified organic silicon leveling agent and the fluorine modified polyacrylic acid leveling agent according to the mass ratio of 1:2, effectively reduces the surface tension, promotes the coating to quickly and effectively wet a substrate, provides excellent flowing and leveling property, has a certain defoaming effect, reduces the risk of occurrence of dark bubbles and miliaria, and endows a coating with the effect of being as bright as a mirror and better smoothness.
The performance of the zero VOC quick-drying scratch resistant glossy black topcoat prepared in the above examples was compared with that of a commercially available PU glossy black topcoat, and the results are shown in the following table:
| item | Example one | Example two | EXAMPLE III | PU |
| Appearance of coating film | Plump and bright as mirror | Plump and bright as mirror | Plump and bright as mirror | Smooth and flat |
| Surface dryness/min | 25 | 27 | 30 | 60 |
| Actual dryness per hour | 2 | 2 | 2 | 24 |
| Hardness of | 2H | 2H | 2H | HB |
| Adhesion force | 0 | 0 | 0 | 0 |
| Flexibility/mm | 1 | 1 | 1 | 1 |
| Gloss of | 101 | 101 | 101 | 98 |
| Scratch resistance | Superior food | Superior food | Superior food | In general |
| VOC(g/L) | Not detected out | Not detected out | Not detected out | 540 |
| Packing time/h | 3 | 3 | 3 | 72 |
As can be seen from the data in the table above: the zero-VOC quick-drying scratch-resistant bright black finish paint prepared by the invention has the characteristics of normal-temperature quick curing, plump and bright coating as a mirror, excellent scratch resistance, good high-grade black bright effect on furniture surface, compensation of the coating defect of the PU bright black finish paint, obvious improvement of the decorative effect and coating efficiency of products, improvement of market competitiveness of the products, no VOC emission in the coating process, belonging to green environment-friendly paint, and capability of meeting the requirements of modern furniture enterprises on decoration, energy conservation, environmental protection and high-efficiency production, and also meeting the environmental protection policy of government.
In summary, the following steps: the zero-VOC quick-drying scratch-resistant bright black finish paint and the preparation method thereof have excellent construction tolerance, are not influenced by environmental temperature and humidity, have ultralow-temperature curing performance, can be constructed at the temperature of minus 20 ℃, can be rapidly cured to form a film, generally have the surface drying time of less than 30 minutes, have the actual drying time of less than 2 hours, obviously shorten the packing time, thoroughly solve the defect that the production period of furniture is prolonged because the coating is dried slowly due to low temperature in winter, greatly improve the production efficiency, and greatly meet the industrial high-quality and high-efficiency construction requirements of furniture enterprises on products;
the paint has excellent weather resistance, does not have aromatic structures and color-changing groups in a paint system, does not change color after long-term use, and ensures that a coating film is as bright as a mirror for a long time;
the coating agent is completely free of solvent addition, no solvent is volatilized in the construction process, no VOC is discharged, the coating agent is environment-friendly, the production environment of coating workers is improved, the coating agent has important significance on energy conservation, emission reduction, low carbon and environmental protection, and the national environmental protection emission requirement is met;
the coating has excellent scratch resistance, obtains the coating effect of high hardness, flatness, fullness, smoothness and brightness as a mirror, has obviously better performance than the prior bright black finish, meets the high decoration requirement of high-grade woodenware products, and is suitable for the aesthetic appearance of consumers and the environmental protection requirement;
the furniture enterprise does not need to increase expensive equipment and change the existing process, the current production situation and the process condition of the current enterprise are met, the energy consumption is not required to be increased, a large-area paint drying place is not required, the production space is saved, and an economic and quick environment-friendly solution is provided for the transformation and upgrading of the furniture enterprise.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be able to cover the technical solutions and the inventive concepts of the present invention within the technical scope of the present invention.
Claims (7)
1. The zero-VOC quick-drying scratch-resistant bright black finish paint is characterized by comprising a main paint and a curing agent, wherein the main paint comprises the following components in parts by weight: the weight ratio of the curing agent is 100: 5;
the main paint comprises the following components in percentage by mass: 93-96% of polymethyl methacrylate resin, 2-5% of carbon black, 0.2-0.4% of anti-settling agent, 0.8-1% of dispersing agent, 0.4-0.6% of defoaming agent and 0.3-0.5% of flatting agent;
the curing agent is benzoyl peroxide.
2. The zero-VOC, quick-drying, scratch-resistant, glossy black topcoat of claim 1, wherein the zero-VOC, quick-drying, scratch-resistant, glossy black topcoat has a solids content of 100%.
3. The zero-VOC, quick-drying, scratch-resistant, glossy black topcoat material of claim 1, wherein the diluent comprises one or more of an epoxy silane coupling agent and a diluent.
4. The zero VOC quick-drying scratch resistant glossy black topcoat according to claim 1, wherein the polymethylmethacrylate resin is Degaroute465 resin.
5. The zero-VOC, quick-drying, scratch-resistant, glossy black topcoat according to claim 1, wherein the carbon black is a high color carbon black and the anti-settling agent is fumed silica.
6. The zero-VOC, quick-drying, scratch-resistant, glossy and black topcoat material of claim 1, wherein the defoamer is a modified siloxane defoamer suitable for solventless coating systems, and the dispersant is a modified block-structured copolymer dispersant.
7. A method of preparing the zero VOC quick-drying scratch resistant brilliant black topcoat of claims 1-6, comprising the steps of:
s1: preparing a main paint:
weighing the following raw materials in percentage by mass: 93-96% of polymethyl methacrylate resin, 2-5% of carbon black, 0.2-0.3% of anti-settling agent, 0.8-1% of dispersing agent, 0.4-0.6% of defoaming agent and 0.3-0.5% of flatting agent;
putting the polymethyl methacrylate resin with the formula amount of 80%, the anti-settling agent and the dispersing agent into a dispersion cylinder, and dispersing for 10 minutes at 800-;
putting the carbon black in the formula amount into a dispersion cylinder, dispersing for 15 minutes at high speed of 1500 rpm at 1200-;
s2: according to the main paint: and (3) uniformly mixing the two components according to the weight ratio of 100:5 of the curing agent to obtain the zero-VOC quick-drying scratch-resistant bright black finish paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010535299.6A CN111607307A (en) | 2020-06-12 | 2020-06-12 | zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010535299.6A CN111607307A (en) | 2020-06-12 | 2020-06-12 | zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111607307A true CN111607307A (en) | 2020-09-01 |
Family
ID=72205333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010535299.6A Pending CN111607307A (en) | 2020-06-12 | 2020-06-12 | zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111607307A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112175472A (en) * | 2020-09-24 | 2021-01-05 | 安徽省沥美道路新型材料有限公司 | MMA (methyl methacrylate) colored anti-slip floor floating sand coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805552A (en) * | 2010-04-22 | 2010-08-18 | 山西长达交通设施有限公司 | High-dirt-resistance road mark coating and preparation method thereof |
| CN102634258A (en) * | 2012-03-28 | 2012-08-15 | 山西长达交通设施有限公司 | Road marking coating for preventing destroying by snow shovels as well as preparation method and use method thereof |
| CN106243890A (en) * | 2016-08-23 | 2016-12-21 | 陕西世纪交通工程股份有限公司 | A kind of nanoscale MMA double-component superbright type reflexed light ring friendly coating and preparation method thereof and using method |
| CN106574141A (en) * | 2014-08-20 | 2017-04-19 | 赢创罗姆有限公司 | Reactive resin sealing for low-contaminant cold plastic markings |
| KR101985520B1 (en) * | 2019-02-28 | 2019-06-03 | 강기수 | Non-slip composition for road pavement excellent in functionality and non-slip paving method therewith |
-
2020
- 2020-06-12 CN CN202010535299.6A patent/CN111607307A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805552A (en) * | 2010-04-22 | 2010-08-18 | 山西长达交通设施有限公司 | High-dirt-resistance road mark coating and preparation method thereof |
| CN102634258A (en) * | 2012-03-28 | 2012-08-15 | 山西长达交通设施有限公司 | Road marking coating for preventing destroying by snow shovels as well as preparation method and use method thereof |
| CN106574141A (en) * | 2014-08-20 | 2017-04-19 | 赢创罗姆有限公司 | Reactive resin sealing for low-contaminant cold plastic markings |
| CN106243890A (en) * | 2016-08-23 | 2016-12-21 | 陕西世纪交通工程股份有限公司 | A kind of nanoscale MMA double-component superbright type reflexed light ring friendly coating and preparation method thereof and using method |
| KR101985520B1 (en) * | 2019-02-28 | 2019-06-03 | 강기수 | Non-slip composition for road pavement excellent in functionality and non-slip paving method therewith |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112175472A (en) * | 2020-09-24 | 2021-01-05 | 安徽省沥美道路新型材料有限公司 | MMA (methyl methacrylate) colored anti-slip floor floating sand coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102286240A (en) | PE (Polyurethane) gloss white paint | |
| CN111040600B (en) | Water-based scratch-resistant full-matte solid-color wood coating and preparation method thereof | |
| CN104530930B (en) | Orange-peel coating | |
| CN108997925A (en) | A kind of coloured dual cure UV coating of automotive upholstery | |
| CN106893423A (en) | Agricultural machinery aqueous amino-stoving varnish and preparation method thereof | |
| CN109054598B (en) | Ultraviolet-curing vacuum coating crystallized paint and preparation method thereof | |
| CN111303733A (en) | UV (ultraviolet) transition primer and preparation method thereof | |
| CN102702888A (en) | Low-temperature quick-drying dual-component automotive trim paint | |
| CN112940570A (en) | Fluorocarbon coating for aluminum veneer and preparation method thereof | |
| CN113845834A (en) | Vacuum coating and coating method thereof | |
| CN111607307A (en) | zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof | |
| CN110903714A (en) | High-temperature-resistant water-based fluorocarbon amino baking paint and preparation method thereof | |
| CN106752250A (en) | A kind of dual cure UV mesh stops filler and preparation method thereof and construction technology | |
| CN110922833B (en) | Matte varnish for scientific wood veneer and preparation method thereof | |
| CN111607306A (en) | Solvent-free quick-drying white primer and preparation method thereof | |
| CN110819185A (en) | XB-S-water-soluble high-reflection photovoltaic backboard glass paint and application scheme thereof | |
| CN109207053A (en) | A kind of color coating composition and its application method | |
| CN111635687A (en) | Anti-yellowing solvent-free quick-drying bright white finish paint and preparation method thereof | |
| CN111978829B (en) | Ultra-yellowing-resistant high-hardness UV full-bright transparent finish paint and preparation method thereof | |
| CN115044287A (en) | Two-component waterborne polyurethane finish paint and preparation method and application thereof | |
| CN111019497B (en) | High-adhesion water-based polyurea colored paint and preparation method thereof | |
| CN103756532A (en) | Polishing-free PE (polyethylene) white primer and preparation method thereof | |
| CN110922869A (en) | Clear primer for scientific wood veneer and preparation method thereof | |
| CN108165159B (en) | Ultra-cured mirror varnish capable of being sprayed on whole vehicle and preparation method thereof | |
| CN111548697A (en) | Yellowing-resistant zero-VOC quick-drying bright top-coat paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200901 |
|
| RJ01 | Rejection of invention patent application after publication |