CN109207053A - A kind of color coating composition and its application method - Google Patents

A kind of color coating composition and its application method Download PDF

Info

Publication number
CN109207053A
CN109207053A CN201810911169.0A CN201810911169A CN109207053A CN 109207053 A CN109207053 A CN 109207053A CN 201810911169 A CN201810911169 A CN 201810911169A CN 109207053 A CN109207053 A CN 109207053A
Authority
CN
China
Prior art keywords
coating composition
coating
film
composition according
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810911169.0A
Other languages
Chinese (zh)
Other versions
CN109207053B (en
Inventor
李翠芝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jinhua Xintuo Material Technology Co.,Ltd.
Original Assignee
Ningbo Leather Innovation Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo Leather Innovation Mstar Technology Ltd filed Critical Ningbo Leather Innovation Mstar Technology Ltd
Priority to CN201810911169.0A priority Critical patent/CN109207053B/en
Publication of CN109207053A publication Critical patent/CN109207053A/en
Application granted granted Critical
Publication of CN109207053B publication Critical patent/CN109207053B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The present invention provides the color coating compositions and its application method of a kind of environmental protection, especially suitable for gentrify surface of vehicle appearance and color.The coating composition includes urethane methacylate resins 14-18%, acrylic resin 14-18%, polyisocyanates 2-5%, ethyl acetate 33-38%, hexahydrotoluene 18-22%, methylisobutylketone 5-8%, pigment 3-8%, ultraviolet absorbing agent 1-3%, light stabilizer 1-4%.Wherein, pigment includes flakey metal such as tabular alumina and cellulose ether, and ultraviolet absorbing agent includes benzotriazole and nano-titanium oxide.

Description

A kind of color coating composition and its application method
Technical field
The present invention relates to the technical field of vehicle paintwork, the especially reparation of surface color of especially a kind of vehicle appearance or Improve and uses color coating composition and its application method.
Background technique
The prime coat that existing coating vehicle part is formed above by vehicle part raw material, vehicle part raw material The subcoat (base coat) that (primer coat), prime coat are formed above, the clear coat that subcoat is formed above (clear coat) is constituted.Wherein, the thickness of prime coat is about 8 μm;Subcoat is usually colored paint layer, and thickness is about 20 μm;And clear coat is then usually to be formed by clear dope and provide the layer of high glaze, thickness is about 30 μm.
As the rapid development and ordinary consumer of automobile industry possess automobile and what is used becomes increasingly popular, vapour The quantity of vehicle is increasing, and the demand to for car surface coating material paint is also more and more.Moreover, due to people The generally raising of aesthetic pursuit, automobile consumer are also more next for including the requirement of the inner surfaces appearance properties such as color and texture It is higher.
And in the daily production and living of actual use, on the one hand, the surface of automobile is easily damaged by dust storm rubble, vehicle Paint surface easily forms scratch, and the scratch such as small rut is damaged, so that the overall beautiful and texture of vehicle is affected, although can adopt Repairing work is carried out to surface of vehicle breakage with repair paint, but current repairing varnish paint is it is difficult to ensure that mend The texture such as color, the uniformity of gloss and richness, the requirement of repairing rear vehicle appearance is unable to satisfy, after especially repairing For vehicle paint under conditions of the repeated flushing of poor air quality environment and carwash alkalies, existing coating is often wear-resisting, resistance to Erosion, weatherability etc. Shortcomings, color the case where dimmed or even vehicle paint integrally falls off that wear are difficult to avoid that.Another party Face, consumer also often occurs carrying out automobile the demand of whole repacking or vehicle renovation in use, and is reequiping Or during renovation, consumer often tends to be modified as the former vehicle color of oneself to prefer, the new face of more fashion Color, at this time if the colored paint without subcoat coats, and province would be much more convenient in the varnish paint of direct spraying colour, operation Thing also can more effectively save time and cost.
It can be seen that paintability is good, operation is easy, richness and the surface of vehicle of excellent gloss are clear with colour after coating Painting coating has extremely wide application prospect.However opposite with the great market demand is then current varnish paint in coating The various aspects such as the whole consistent, wear-and corrosion-resistant of vehicle appearance and weatherability are kept all much to be difficult to reach order after workability, repairing The satisfied performance of people.
Therefore, the purpose of the present invention is to provide that a kind of paintability is good, wear-resisting, anti-corrosion, weather resistance is excellent, coating The gentrify color coating composition and its application method of the specious surface of vehicle color for having texture.
Summary of the invention
The purpose of the present invention is to be to provide a kind of color coating composition of environmental protection, which passes through unique Ingredient, which is chosen, and preferred component proportion realizes the coating composition has convenient for being coated in surface of vehicle breakage The paintability repaired, while the surface after coating has gloss texture, color is bright and beautiful, and have both it is excellent it is wear-resisting, anti-corrosion, Weatherability.
To achieve the above object, present invention employs the following technical solutions:
A kind of environment-protecting color coating composition, it is characterised in that: the coating composition includes polyurethane methacrylic acid Ester resin 14-18%, acrylic resin 14-18%, polyisocyanates 2-5%, ethyl acetate 33-38%, hexahydrotoluene 18- 22%, methylisobutylketone 5-8%, pigment 3-8%, ultraviolet absorbing agent 1-3%, light stabilizer 1-4%.
Preferably, the pigment includes flakey metal such as tabular alumina and cellulose ether.
It is further preferred that the flakey metal and cellulose ether mass ratio are 3-5:1.
It is further preferred that the flakey metal surface is handled through silica cladding, the partial size of the flakey metal It is 0.2-0.5 μm
Preferably, the ultraviolet absorbing agent includes benzotriazole and nano-titanium oxide.
It is further preferred that the benzotriazole and nano-titanium oxide mass ratio are 10-15:1.
It is further preferred that the partial size of the nano-titanium oxide is 20-40nm.
The object of the invention is also to provide the coating film forming application method of above-mentioned environment-protecting color coating composition, the sides Method includes:
1) coating composition be sufficiently stirred being uniformly mixed each component;
2) coating composition is stood after surface to be repaired uniformly coat using aerial spraying technique;
3) heated-air drying is carried out to film after coating;
4) ultraviolet curing processing is carried out to film after drying.
Preferably, the film with a thickness of 40-60 μm.
Preferably, standing 5-10min after coating;The temperature of heated-air drying is 50-60 DEG C, drying time 5- 10min;The ultraviolet wavelength of ultraviolet curing processing is 380nm, irradiation distance 15-20cm, irradiation energy 800- 1000mj/cm2, curing time 5-10min.
The unique ingredient that has the beneficial effect that of environment-protecting color coating composition of the present invention and its application method is chosen and preferably Component proportion realize the coating composition and have convenient for carrying out coating and repairing when surface of vehicle breakage or vehicle renovate Good paintability again, while the surface after coating has gloss texture, color is bright and beautiful, and has both excellent wear-resisting, anti-corrosion, resistance to Hou Xing.
Specific embodiment
Embodiment 1
Firstly, preparing coating composition, including urethane methacylate resins 14%, acrylic resin 14% are more Isocyanates 2%, ethyl acetate 38%, hexahydrotoluene 18%, methylisobutylketone 5%, pigment 5%, ultraviolet absorbing agent 2%, light stabilizer 2%.Wherein,
The urethane methacrylate has 9 acryloyl groups;
The acrylic resin is the macromonomer of polymethyl methacrylate and the polymerization of acrylic acid -2- hydroxyl ethyl ester Object, wherein the number-average molecular weight of the macromonomer of polymethyl methacrylate is 2500, the polymethyl methacrylate Macromonomer and the mass ratio of acrylic acid -2- hydroxyl ethyl ester are 1:5, the Weight-average molecular of the acrylic resin obtained after polymerization Amount is 250,000;
The polyisocyanates is hexamethylene diisocyanate;
It include flakey aluminium powder and cellulose ether in the pigment;Specifically, flakey aluminium powder and cellulose ether mass ratio Example is 4:1, and flakey aluminium powder surface is handled through silica cladding, and the partial size of the flakey aluminium powder is 0.3 μm
The ultraviolet absorbing agent includes benzotriazole and nano-titanium oxide;Specifically, the benzotriazole and nano oxygen Change titanium mass ratio is 12:1, the partial size 30nm of the nano-titanium oxide.
The light stabilizer is hindered amine type light stabilizer.
It prepares said components example in mass ratio to obtain coating composition, the coating composition be sufficiently stirred making Each component is uniformly mixed;It is then using aerial spraying technique that the coating composition is enterprising in the sample for simulating surface to be repaired Uniformly coating stands 5min to after forming 50 μm of films to row;Heated-air drying 5min is then carried out under the conditions of 55 DEG C to film;With Use wavelength for the ultraviolet light of 380nm, 800/cm afterwards2Irradiation energy, at the position of about 20cm carry out hardening with radiation, solidification Time 5min.
Embodiment 2-8 adjusts the content of each component, remaining is same as Example 1, specific content ratio Example is listed in table 1, wherein and A-I respectively represents the urethane methacylate resins that include in the present invention in table 1, acrylic resin, Polyisocyanates, ethyl acetate, hexahydrotoluene, methylisobutylketone, pigment, ultraviolet absorbing agent, light stabilizer.
In embodiment 9, flakey aluminium powder and cellulose ether mass ratio are 8:1, remaining is same as Example 1.
In embodiment 10, flakey aluminium powder surface with aluminium oxide substitution silica carry out cladding processing, remaining with implementation Example 1 is identical.
In embodiment 11, the partial size of flakey aluminium powder is 1 μm, remaining is same as Example 1.
In embodiment 12, benzotriazole and nano-titanium oxide mass ratio are 20:1, remaining is same as Example 1.
In embodiment 13, the partial size 60nm of the nano-titanium oxide, remaining is same as Example 1.
Table 1
A B C D E F G H I
1 14 14 2 38 18 5 5 2 2
2 14 14 4 33 22 5 5 1 2
3 18 18 2 33 18 6 3 1 1
4 14 16 3 34 18 5 8 1 1
5 10 12 2 38 22 8 4 2 2
6 18 18 3 30 15 5 5 3 3
7 14 14 2 35 18 5 10 1 1
8 16 16 3 33 20 5 6 0.5 0.5
By the sample of aforementioned coating composition film, following experiment test is carried out, forms film to obtain coating composition Properties, be as a result listed in table 2.
One, film coating performance is tested
1. drying property: to be coated with coating composition film of the present invention merely through drying and the surface without hardening with radiation is straight It connects in such a way that finger tip touches and examines, if finger tip has clagging after touching, then it is assumed that drying property is bad (×), such as Finger tip does not have clagging after fruit touching, then it is assumed that drying property is excellent (zero).
2. appearance of film: the surface for being coated with coating composition film of the present invention is observed by way of range estimation, The appearance for the defects of color is beautiful uniformly, without any bubble is excellent (zero), has no obvious bubble and color light and shade is substantially homogeneous Appearance is fine (△), has obvious bubble and color is dull and non-uniform appearance is poor (×).
Two, coating weatherability can be tested
Using QUV tester, carry out accelerating weather-proof test, specifically, use to coating composition film of the present invention is coated 200W/m2Energy intensity simulated solar irradiation irradiation, with+50 DEG C × 4 hours 70 DEG C × 8 hours (Dry) (Wet) for a period into The circulation in 200 periods of row, wherein
1. coated film sample after recycling is kept using (60 °) progress glossiness measurements of gloss meter with testing the gloss of front and back Rate (%) evaluates the weatherability of film, and gloss retention is excellent (zero) 90% or more, and gloss retention is 70-90%'s For still (△), gloss retention is below for poor (×) 70%;
2. there is the testing time (h) of the obvious shortcomings such as striped in record coated film sample surface, to evaluate the weatherability of film, Testing time, longer weatherability was better, and do not occur obvious shortcoming is denoted as "-".
Three, film light transmission is tested
The light transmittance (%) of coating composition film of the present invention is coated with using spectrophotometer measuring and calculation, it is specific to test Wavelength is 300-400nm (ultra-violet bands), 400-700nm (visible light wave range).
Table 2
It is further described below for the formula of coating system of the present invention:
There is in urethane methacylate resins a large amount of acryloyl group in coating of the present invention, can significantly improve The alkali resistance and solvent resistance of coating composition, thus in corrosive atmosphere and alkalies carwash operation etc. after improving coating film forming Corrosion resistance in the process, and then extend Tu film service life, in order to guarantee urethane methacylate resins in system Above-mentioned effect is played, needs its content at least to should be 14%, but its content is also unsuitable excessively high, such as more than 18%, otherwise influences The performance of other resin effects.Meanwhile in order to guarantee enough corrosion resistances, preferably have in guarantee urethane methacrylate There is at least nine acryloyl group.
Acrylic Resin in Coatings of the present invention uses the macromonomer and acrylic acid -2- hydroxyl second of polymethyl methacrylate The polymer of ester has lower viscosity than common coating resin, to help to obtain good coating performance, content is answered At least 14%, but also unsuitable excessive, the performance that will affect other resin effects more than 18%;Also film is had simultaneously The comprehensive performance of excellent intensity and ductility, so that film has excellent wear-resisting and scraping and wiping resistance performance, in order to protect It demonstrate,proves acrylic resin and plays above-mentioned effect, the preferably number-average molecular weight of the macromonomer of polymethyl methacrylate is 2000- 3500.Meanwhile the macromonomer of polymethyl methacrylate do not answered with acrylic acid -2- hydroxyl ethyl ester mass ratio it is excessive, if Ratio is greater than 1:5, although film has the good scratch resistance of better wearability, whole coating performance is deteriorated, but Cannot too small such as less than 1:5.5, otherwise the wearability of film and scraping and wiping resistance performance do not reach requirement;In addition, acrylic resin Weight average molecular weight comprehensively considers from intensity, ductility and coating, should control in 25-30 ten thousand.
Hexamethylene diisocyanate can be used as curing agent in coating of the present invention, in order to guarantee heating irradiance process In sufficient crosslinking curing, to guarantee the properties such as the wear resistance and corrosion resistance of film, content should be at least 2%, and its Content is also unsuitable excessively high, once more than 5%, the extra hexamethylene diisocyanate for being not involved in reaction will affect film instead The performances such as scratch-resistant.
The major ingredient of solvent is ethyl acetate in coating of the present invention, and ethyl acetate has excellent drying property and assigns coating The excellent coating performance of composition, in order to enable ethyl acetate plays above-mentioned effect in system, content should be at least 33%, But can not additive amount it is excessive, if it exceeds 38% meeting so that formed appearance of film deteriorate.
Auxiliary material in coating of the present invention in solvent is hexahydrotoluene, and hexahydrotoluene can effectively improve Coating material composition Coating adhesive ability of the object on priming paint, finishing coat, so that the film after especially repairing has excellent adhesion and goes out The appearance tactile impression of color, in order to enable hexahydrotoluene plays above-mentioned effect in system, content should be at least 18%, but its Additive amount can not be excessively high, if it exceeds 22% meeting is so that the coating performance of coating composition deteriorates.
Solvent also contains a certain proportion of methylisobutylketone in coating of the present invention, and methylisobutylketone can be improved Coating material composition The coating performance of object and the resting period of coating composition, in order to enable methylisobutylketone plays above-mentioned effect in system, Its content at least should be 5%, but its additive amount can not be excessively high, if it exceeds 8% can be because of its biggish resin solvability And appearance of film is made to generate apparent uneven deterioration.
Pigment is the important component of color coating composition in the present invention, in order to enable film can obtain corresponding color, And guarantee that gloss is beautiful and uniformity, preferred pigments are the mixing of flakey metal (such as tabular alumina) and cellulose ether, More preferably flakey metal is oxidized the processing of silicon face cladding, and through silica, treated that flakey metal can be more uniformly It is scattered in resin solution, and avoids agglomerating in resin solution, so that coating performance and wear-resisting scraping and wiping resistance performance are influenced, And cellulose ether can more preferably help flakey metallic adjusted direction, to obtain better color luminance, flakey metal with 5:1 is not to be exceeded in the ratio of cellulose ether, but can not be too small, and it is excessively high and influence coating appearance otherwise to will lead to system viscosity Etc. performances;Meanwhile the partial size of flakey metal is preferably 0.2-0.5 μm, to obtain uniform color beautiful enough.According to reality It needs, content is preferably greater than 3%, but in order to not influence the overall performance for applying film system, preferably its content is less than 8%.
In order to guarantee the enough weather resistances of coating composition film forming in the present invention, ultraviolet absorbing agent also added, purple Ultraviolet absorbers are preferably the mixing of organic uv absorbers benzotriazole and inorganic ultraviolet absorbent nano-titanium oxide, are Guarantee to realize its effect, content is preferably greater than 1%, but adds excessive ultraviolet absorbing agent, is easy to cause coating The cohesion of system, so will affect the coating of coating system, film etc. appearances etc., in order to not influence the entirety for applying film system Performance, preferably its content is less than 3%.Meanwhile in order to guarantee nano-titanium oxide excellent raising ultraviolet radiation absorption effect and The ratio of the weatherability of film, nano-titanium oxide and benzotriazole is no less than 15:1, but also otherwise can no more than 10:1 Lead to the various problems such as dispersibility and cohesion.In addition, the partial size of nano-titanium oxide is preferably 20-30nm, excessive partial size will be difficult To play enough ultraviolet radiation absorption effects, and lead to uniformly dispersed problem.
Coating composition of the invention is also added with light stabilizer, is preferably common hindered amine type light stabilizer, light The addition of stabilizer can be effectively improved the weather resistance of film, in order to guarantee that additive effect, the additive amount of light stabilizer are preferred More than 1%, but in order to not influence the performances such as the coating of coating composition and wear-resisting scratch-resistant, should controller content be less than 4%.
Coating composition of the invention has excellent coating performance, solid using simple aerial spraying and ultraviolet irradiation Change can the excellent film of forming properties using the painting and in order to guarantee the excellent properties of coating composition of the present invention film forming When feed composition carries out painting operation, in 50 DEG C or more of at a temperature of drying 5min or more, and it should adopt at least after spray coating Use 800mj/cm2Above wavelength 380nm ultraviolet irradiation is more than 5min, so available sufficient drying of coating, can Form the film layer of even compact and firm attachment.But pay attention to avoiding excessively crosslinking etc. caused by excessively heating and irradiate to ask It inscribes and influences filming performance.
Although the present invention is explained by the above embodiments coating effect of the present invention, the invention is not limited to above-mentioned realities Apply example.It should be clear to those skilled in the art, any improvement in the present invention, to each raw material of product of the present invention etc. Effect replacement and addition, the selection of concrete mode of auxiliary element etc., all of which fall within the scope of protection and disclosure of the present invention.

Claims (10)

1. a kind of environment-protecting color coating composition, it is characterised in that: the coating composition includes urethane methacrylate Resin 14-18%, acrylic resin 14-18%, polyisocyanates 2-5%, ethyl acetate 33-38%, hexahydrotoluene 18- 22%, methylisobutylketone 5-8%, pigment 3-8%, ultraviolet absorbing agent 1-3%, light stabilizer 1-4%.
2. coating composition according to claim 1, it is characterised in that: the pigment includes flakey metal such as sheet Aluminium oxide and cellulose ether.
3. coating composition according to claim 2, it is characterised in that: the flakey metal and cellulose ether mass ratio Example is 3-5:1.
4. coating composition according to claim 2, it is characterised in that: the flakey metal surface is coated through silica Processing, the partial size of the flakey metal are 0.2-0.5 μm.
5. coating composition according to claim 1, it is characterised in that: the ultraviolet absorbing agent include benzotriazole and Nano-titanium oxide.
6. coating composition according to claim 5, it is characterised in that: the benzotriazole and nano-titanium oxide mass ratio Example is 10-15:1.
7. coating composition according to claim 6, it is characterised in that: the partial size of the nano-titanium oxide is 20-40nm.
8. the coating film forming user that coating composition is used in the repairing of surface of vehicle described in a kind of any one of claim 1-7 Method, which comprises
1) coating composition be sufficiently stirred being uniformly mixed each component;
2) coating composition is stood after surface to be repaired uniformly coat using aerial spraying technique;
3) heated-air drying is carried out to film after coating;
4) ultraviolet curing processing is carried out to film after drying.
9. application method according to claim 8, it is characterised in that: the film with a thickness of 40-60 μm.
10. application method according to claim 8, it is characterised in that: stand 5-10min after coating;The temperature of heated-air drying Degree is 50-60 DEG C, drying time 5-10min;The ultraviolet wavelength of ultraviolet curing processing is 380nm, irradiation distance 15- 20cm, irradiation energy 800-1000mj/cm2, curing time 5-10min.
CN201810911169.0A 2018-08-10 2018-08-10 Color coating composition and application method thereof Active CN109207053B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810911169.0A CN109207053B (en) 2018-08-10 2018-08-10 Color coating composition and application method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810911169.0A CN109207053B (en) 2018-08-10 2018-08-10 Color coating composition and application method thereof

Publications (2)

Publication Number Publication Date
CN109207053A true CN109207053A (en) 2019-01-15
CN109207053B CN109207053B (en) 2021-05-07

Family

ID=64987664

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810911169.0A Active CN109207053B (en) 2018-08-10 2018-08-10 Color coating composition and application method thereof

Country Status (1)

Country Link
CN (1) CN109207053B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109762387A (en) * 2019-01-29 2019-05-17 宁波革创新材料科技有限公司 A kind of coating composition and its preparation process
CN112940586A (en) * 2021-02-01 2021-06-11 宁波革创新材料科技有限公司 Polyurethane modified epoxy resin anticorrosive paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1233635A (en) * 1998-02-25 1999-11-03 巴斯福公司 Straight-shade coating compositions
CN102260421A (en) * 2011-06-08 2011-11-30 四川大学 Magic-color nacreous aluminum powder pigment and preparation method thereof
CN102827501A (en) * 2012-08-02 2012-12-19 中山大桥化工企业集团中山智亨实业发展有限公司 Double-curing varnish paint
CN105331154A (en) * 2015-11-20 2016-02-17 湖南邦弗特新材料技术有限公司 High-weather-resistant UV (ultraviolet) coating for decorative plate and preparation method of high-weather-resistant UV coating
CN106634555A (en) * 2017-01-13 2017-05-10 北京涑酷特威科技有限公司 UV dual-cured automobile repairing coating and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1233635A (en) * 1998-02-25 1999-11-03 巴斯福公司 Straight-shade coating compositions
CN102260421A (en) * 2011-06-08 2011-11-30 四川大学 Magic-color nacreous aluminum powder pigment and preparation method thereof
CN102827501A (en) * 2012-08-02 2012-12-19 中山大桥化工企业集团中山智亨实业发展有限公司 Double-curing varnish paint
CN105331154A (en) * 2015-11-20 2016-02-17 湖南邦弗特新材料技术有限公司 High-weather-resistant UV (ultraviolet) coating for decorative plate and preparation method of high-weather-resistant UV coating
CN106634555A (en) * 2017-01-13 2017-05-10 北京涑酷特威科技有限公司 UV dual-cured automobile repairing coating and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
李劲: "《汽车维修涂装工[中级]》", 30 September 2004, 中国劳动社会保障出版社 *
杨成德: "《涂料开发与试验》", 28 February 2015, 科学技术文献出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109762387A (en) * 2019-01-29 2019-05-17 宁波革创新材料科技有限公司 A kind of coating composition and its preparation process
CN112940586A (en) * 2021-02-01 2021-06-11 宁波革创新材料科技有限公司 Polyurethane modified epoxy resin anticorrosive paint and preparation method thereof

Also Published As

Publication number Publication date
CN109207053B (en) 2021-05-07

Similar Documents

Publication Publication Date Title
CN101679806B (en) Peelable temporary coating
CN114561134B (en) Special UV (ultraviolet) photocuring finish paint and wear-resistant paint for vibration wear resistance, and preparation methods and spraying process thereof
CN110240860B (en) High-wear-resistance high-toughness UV (ultraviolet) bright coating and application thereof
CN107057547B (en) Acrylic acid-polyurethane type finishing varnish composition, preparation method and application thereof
CN102558981B (en) A kind of High-temperature varnish with high scratch resistance and preparation method thereof
CN107418410B (en) Low VOC aqueous UV-curable single layer coating composition, method of coating and substrates coated therewith
CN107083150B (en) A kind of UV coating for automobile interiors and its preparation method and application
CN113717631B (en) Water-based UV coating and preparation method and application thereof
CN104927620B (en) A kind of solid wood board solidifies painting design with crack resistence ultraviolet light
CN109207053A (en) A kind of color coating composition and its application method
CN107903802B (en) high-RCA (Rolling circle amplification) resistant single-coating PU (polyurethane) paint for nylon and carbon fiber composite material
CN105820720A (en) UV curing coating for PVC material coating process and preparation method for UV curing material
CN108219578A (en) A kind of inflatable toy halftone aqueous ink
JP6585408B2 (en) Paint composition for wooden building materials and wooden building materials
CN109762387B (en) Coating composition and preparation process thereof
CN108977032B (en) Water-based dual-component high-gloss finish paint for helmet and preparation method thereof
CN109535992B (en) High-wear-resistance high-gloss UV coating for PC (polycarbonate) substrate of automotive interior optical part and preparation method thereof
CN109266152B (en) Coating composition for repairing and using method thereof
JP2005213274A (en) Aqueous paint and method for preparing and applying the same
CN112724818B (en) AG glass effect-imitated UV coating and preparation method and application thereof
CN110616034B (en) Anti-fog UV coating for automobile exterior trimming part and automobile lamp, preparation method of anti-fog UV coating and paint film formed by anti-fog UV coating
CN112680051A (en) High-brightness high-weather-resistance varnish for spraying automobile bumper and preparation method thereof
CN110938371B (en) Recoating anti-glare UV (ultraviolet) curing coating and preparation method and application thereof
CN114539895A (en) Water-based PU (polyurethane) coating and coating process
CN108165159B (en) Ultra-cured mirror varnish capable of being sprayed on whole vehicle and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20210419

Address after: 321000, Zhejiang Province, Wucheng District, Jinhua Bailong town hole Creek Village

Applicant after: Jinhua Xintuo powder coating Co.,Ltd.

Address before: 315040 No. 002, No. 305, Jiangnan Yi Pin garden, Ningbo high tech Zone, Zhejiang, 6-7

Applicant before: NINGBO GECHUANG NEW MATERIAL TECHNOLOGY Co.,Ltd.

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant
CP03 Change of name, title or address

Address after: 321075 unit 3, building 9, No. 918, Dengyun street, Tangxi Town, Wucheng District, Jinhua City, Zhejiang Province

Patentee after: Jinhua Xintuo Material Technology Co.,Ltd.

Address before: 321000 Dongxi village, bailongqiao Town, Wucheng District, Jinhua City, Zhejiang Province

Patentee before: Jinhua Xintuo powder coating Co.,Ltd.

CP03 Change of name, title or address