CN101805552A - High-dirt-resistance road mark coating and preparation method thereof - Google Patents
High-dirt-resistance road mark coating and preparation method thereof Download PDFInfo
- Publication number
- CN101805552A CN101805552A CN201010154496A CN201010154496A CN101805552A CN 101805552 A CN101805552 A CN 101805552A CN 201010154496 A CN201010154496 A CN 201010154496A CN 201010154496 A CN201010154496 A CN 201010154496A CN 101805552 A CN101805552 A CN 101805552A
- Authority
- CN
- China
- Prior art keywords
- component
- agent
- parts
- dirt
- acrylate resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 40
- 238000000576 coating method Methods 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 37
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 98
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 78
- 239000002216 antistatic agent Substances 0.000 claims abstract description 53
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 36
- 239000000945 filler Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 24
- 238000005507 spraying Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 48
- 239000004408 titanium dioxide Substances 0.000 claims description 48
- 239000004902 Softening Agent Substances 0.000 claims description 34
- 238000001914 filtration Methods 0.000 claims description 24
- 239000004576 sand Substances 0.000 claims description 24
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 23
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 32
- 239000004014 plasticizer Substances 0.000 abstract description 27
- 239000000463 material Substances 0.000 abstract description 3
- 239000002519 antifouling agent Substances 0.000 abstract 2
- 235000010215 titanium dioxide Nutrition 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 241001328813 Methles Species 0.000 abstract 1
- 238000007790 scraping Methods 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 26
- 229920005989 resin Polymers 0.000 description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 23
- 239000003973 paint Substances 0.000 description 18
- 230000003373 anti-fouling effect Effects 0.000 description 8
- 239000002689 soil Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 239000012943 hotmelt Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to high-dirt-resistance road mark coating and a preparation method thereof, aiming to enable coating to have good long-acting dirt resistance. The coating comprises a component A and a component B, wherein the formula of the component A comprises the following materials in parts by weight: 30-50 parts of active MMA (Methl Methacrylate) type acrylate resin, 10-20 parts of titanium white powder, 1-5 parts of plasticizer, 0.1-0.3 part of antistatic agent, 0.1-1 part of anti-fouling agent and the balance of filler, and the total parts are 100 parts; the formula of the component B comprises the following materials in parts by weight: 30-50 parts of active MMA type acrylate resin, 10-20 parts of titanium white powder, 1-5 parts of plasticizer, 0.1-0.3 part of antistatic agent, 0.1-1 part of anti-fouling agent, 0.5-5 parts of curing agent and the balance of filler, and the total parts are 100 parts; and when in use, the component A and the component B are mixed by a weight ratio of 1-4:1. During preparing, the component A and the component B are respectively prepared. When in use, the component A and the component B are mixed in proportion, and marked lines are formed on the road surfaces in spraying or scraping construction modes.
Description
One, technical field
High-dirt-resistance road mark coating of the present invention and method for making thereof belong to traffic and transport field, in particular to a kind of coating of a kind of special raising roadmarking contamination resistance and preparation method thereof.
Two, background technology
Be different from other coating, road mark paint not only will stand rolling of wheel behind construction molding, graticule after the moulding in use also will stand the friction from the silt particle of road table, greasy dirt, the pollution of soil such as clod, destructions such as the etch of rainwater, this makes the environment for use of graticule all want much abominable than the environment for use of the common coating of other types.
Existing hot-melting type, solvent-borne type or aq. type road mark paint, its antifouling property is all very poor behind construction molding, and this especially shows particularly evidently in Bei Fang the urban road at urban road.No matter in the north or south, the road mark paint construction molding is after after a while, especially through rainwater after fewer winter, these graticule materials all are easy to soil such as pickup flying dust, earth, greasy dirt, make graticule become unintelligible, the overall appearance poor effect influences traffic safety.
In traditional road mark paint, the hot melt road mark paint all is to adopt low-molecular-weight dioctyl phthalate (DOP) (DOP) or dibutyl phthalate (DBP) etc. as the softening agent main component usually, in the use of graticule, low-molecular-weight softening agent is moved to the graticule surface easily from gage mark coating, the probability of soil such as the flying dust on increase pickup road surface, earth; On the other hand, the film forming matter of hot melt road mark paint all is to adopt petroleum resin or Gum Rosin usually, because being easy to deliquescing, thermoplasticity Gum Rosin or petroleum resin under the temperature condition with higher (in summer, bituminous pavement surface temperature can up to more than 80 ℃) have further increased the adhesive attraction of graticule to soil; Simultaneously the hot melt road mark paint all adopts very coarse filler, such as 20-100 purpose quartz sand, glass microballon etc., after the coating film forming under the rolling of wheel the graticule surface very coarse, this also can reduce the contamination resistance of graticule; What water base property road mark paint, the solvent type paint for road markers in the tradition road mark paint was similar to the hot melt road mark paint all is to adopt thermoplastic resin, and coarse surface all is unfavorable for the lifting of the antifouling property of graticule after the while film forming.Patent (ZL200710061727.0) provides a kind of two component road mark paints that utilize Resins, epoxy as film forming matter, be to be easy to come off and a kind of gage mark coating that is specifically designed to cement pavement of developing at graticule on the cement pavement, itself reduces greatly to the susceptibility of temperature variation though this gage mark coating is filmed after film forming, but, because the dry and hard time is long, usually want more than 2 hours under the room temperature, the long dry and hard time not only causes polluting easily in the graticule film forming solidification process dirty, the also as easy as rolling off a log traffic jam that causes.In sum, the antifouling property of existing road mark paint is all also undesirable, is badly in need of a kind of road mark paint with high stain resistance of research and development.
Three, summary of the invention
The object of the invention is exactly for overcoming the deficiency of above-mentioned prior art, and a kind of gage mark coating with excellent long-acting antifouling property is provided, and the method for making of this coating.
The present invention mainly sets about improving the antifouling property of roadmarking from the following aspects: the one, improve the warm sex change energy of filming.Inhibition thermoplastic resin low temperature becomes fragile, this defective of high temperature deliquescing, especially will weaken the problem of roadmarking deliquescing at high temperature.Effectively improve the resistance toheat that graticule is filmed by the chemical crosslink reaction film forming ability, therefore adopt two component road mark paints can play certain effect improving graticule antifouling property in use by the chemical crosslink reaction film-forming; The 2nd, improve the compactness and the bright and clean degree of filming, the easy more absorption soil in coarse more surface; The 3rd, the change external plasticizer is internal plasticizer, or utilizes the softening agent of polymeric plasticizer place of low-molecular-weight, suppresses or slow down softening agent to move to the lip-deep phenomenon of graticule in the graticule use; The 4th, eliminate static.Graticule can be because of friction produces static rolling in the process of wheel, and generation of static electricity causes graticule that the adsorption of flying dust etc. is strengthened; The 5th, reduce the surface tension of filming after the coating film forming.Surface tension is low more, and the wettability of other foreign matters on filming is poor more, is difficult for sticking pollutent more; The 6th, improve paint solidification speed, because the surface properties of filming is the heavy-gravity fluid, as easy as rolling off a log dust in the environment, the soil etc. of sticking cause the dirty blackening of graticule in the gage mark coating film-forming process.
The present invention includes two components of A, B: A component prescription is: active MMA response type acrylate resin 30-50 part; Titanium dioxide 10-20 part; Softening agent 1-5 part; Antistatic agent 0.1-0.3 part; Stain control agent 0.1-1 part; Residue is filler; Total umber is 100 parts; B component prescription is: active MMA response type acrylate resin 30-50 part; Titanium dioxide 10-20 part; Softening agent 1-5 part; Antistatic agent 0.1-0.3 part; Stain control agent 0.1-1 part; Solidifying agent 0.5-5 part; Residue is filler; Total umber is 100 parts; Two components of A, B are in use according to weight ratio 1-4: 1 mixed.
Above-mentioned high-dirt-resistance road mark coating is characterized in that: active MMA response type acrylate resin is in the A component
In any one; Active MMA response type acrylate resin is in the B component
In any one; Softening agent is
Stain control agent adopts among fluorocarbon surfactant HG-613, HG-614, HG-6171, the HG-6172 any one; Antistatic agent be among GW90, GW-150, the GW-2 any one; Solidifying agent is dibenzoyl peroxide (BPO); Filler is greater than 1250 purpose dry powders.
The method for making of above-mentioned high-dirt-resistance road mark coating is characterized in that A component and B component prepare respectively, are mixed in proportion during use again:
(1) preparation A component: softening agent, antistatic agent and stain control agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed;
(2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed;
(3) adopt external mix spraying or knife-coat application in the road surface in proportion A component and B component.
The main film forming substance of high-dirt-resistance road mark coating of the present invention is the acrylic resin with reactive behavior, on the one hand, even if active MMA response type acrylate resin also can be adjusted to 15 minutes with interior curing under 0 ℃ extremely low temperature, this is that other reaction resins such as Resins, epoxy can't be compared, on the other hand, even if this resin can form after the crosslinked film forming stable, compactness under comparatively high temps also not remollescent film; The fine and smooth more densification of filming after the coating film forming is given in the use of superfine pigment, filler; The use of polymeric plasticizer has suppressed simple plasticizer in use to the phenomenon of the surface transport of filming; The use of antistatic agent can make graticule and wheel rapidly disappear because of fricative static; Extremely low surface tension after the coating film forming is given in the use of stain control agent, has improved graticule stain resistance in use greatly.The processing of above-mentioned these technology has all improved graticule contamination resistance in use greatly, and this is not also having report aspect present road mark paint research and the production.Coating of the present invention spraying or blade coating in ground in face of strictness forbid the contact of A, B two components, otherwise can antedating response, cause coating to be scrapped.
Coating of the present invention is to be exclusively used in the road mark paint that improves antifouling property after the graticule film forming, has excellent antifouling property at urban road, dry and hard fast, the construction back can be open to traffic in 5-15 minute, can not cause traffic jam.
Four, embodiment
Embodiment 1:
The A component:
Resin 2000g, titanium dioxide 500g,
Polymeric plasticizer 50g, GW90 antistatic agent 15g, HG-613 stain control agent 15g, 1250 order dry powder 2420g amount to 5000g.
The B component:
Resin 2000g, titanium dioxide 500g,
Polymeric plasticizer 50g, GW90 antistatic agent 15g, HG-613 stain control agent 15g, solidifying agent dibenzoyl peroxide (BPO) 200g, 1250 order dry powder 2220g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component adopt the form of construction work that sprays to construct after 1: 1 mixed preparing.About 10 minutes of the dry and hard at ambient temperature time of graticule that this prescription construction forms, the bright and clean exquisiteness of the film coated surface of formation, stain resistance is strong.
Embodiment 2:
The A component:
Resin 1500g, titanium dioxide 1000g,
Polymeric plasticizer 250g, GW150 antistatic agent 5g, HG-614 stain control agent 5g, 1250 order dry powder 2240g amount to 5000g.
The B component:
Resin 1500g, titanium dioxide 1000g,
Polymeric plasticizer 250g, GW150 antistatic agent 5g, HG-614 stain control agent 5g, solidifying agent dibenzoyl peroxide (BPO) 250g, 1250 order dry powder 1990g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component are after 1: 1 mixed preparing, and the form of construction work of employing blade coating is constructed.
About 5 minutes of the dry and hard at ambient temperature time of graticule that this prescription construction forms, the bright and clean exquisiteness of the film coated surface of formation, stain resistance is strong, and anti-static effect is poor slightly.
Embodiment 3:
The A component:
Resin 2000g, titanium dioxide 750g,
Polymeric plasticizer 250g, GW90 antistatic agent 10g, HG-613 stain control agent 50g, 1250 order dry powder 1940g amount to 5000g.
The B component:
Resin 2500g, titanium dioxide 1000g,
Polymeric plasticizer 50g, GW150 antistatic agent 10g, HG-614 stain control agent 5g, solidifying agent dibenzoyl peroxide (BPO) 25g, 1250 order dry powder 1410g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component adopt the form of construction work that sprays to construct after 3: 1 mixed preparing.
The graticule construction effect that this prescription construction forms is fine, but the dry and hard time is slower, the bright and clean exquisiteness of the film coated surface of formation, and stain resistance and anti-static effect are all better.
Embodiment 4:
The A component:
Resin 1500g, titanium dioxide 750g,
Polymeric plasticizer 250g, GW2 antistatic agent 15g, HG-614 stain control agent 30g, 1250 order dry powder 2455g amount to 5000g.
The B component:
Resin 2500g, titanium dioxide 1000g,
Polymeric plasticizer 50g, GW2 antistatic agent 5g, HG-6171 stain control agent 50g, solidifying agent dibenzoyl peroxide (BPO) 200g, 1250 order dry powder 1195g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component are after 4: 1 mixed preparing, and the form of construction work of employing blade coating is constructed.
Embodiment 5:
The A component:
Resin 2000g, titanium dioxide 800g,
Polymeric plasticizer 150g, GW2 antistatic agent 15g, HG-614 stain control agent 15g, 1250 order dry powder 2020g amount to 5000g.
The B component:
Resin 2000g, titanium dioxide 800g,
Polymeric plasticizer 150g, GW2 antistatic agent 15g, HG-6172 stain control agent 15g, solidifying agent dibenzoyl peroxide (BPO) 150g, 1250 order dry powder 1870g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component adopt the form of construction work that sprays to construct after 1: 1 mixed preparing.
Embodiment 6:
The A component:
Resin 2000g, titanium dioxide 500g,
Polymeric plasticizer 50g, GW150 antistatic agent 15g, HG-163 stain control agent 15g, 1250 order dry powder 2420g amount to 5000g.
The B component:
Resin 2000g, titanium dioxide 500g,
Polymeric plasticizer 50g, GW90 antistatic agent 8g, HG-6172 stain control agent 35g, solidifying agent dibenzoyl peroxide (BPO) 200g, 1250 order dry powder 2207g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component adopt the form of construction work that sprays to construct after 1: 1 mixed preparing.Filming of forming is more crisp relatively.
Embodiment 7:
The A component:
Resin 1500g, titanium dioxide 750g,
Polymeric plasticizer 150g, GW90 antistatic agent 15g, HG-6172 stain control agent 5g, 1250 order dry powder 2580g amount to 5000g.
The B component:
Resin 2500g, titanium dioxide 750g,
Polymeric plasticizer 150g, GW90 antistatic agent 5g, HG-614 stain control agent 50g, solidifying agent dibenzoyl peroxide (BPO) 250g, 1250 order dry powder 1295g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component are after 4: 1 mixed preparing, and the form of construction work of employing blade coating is constructed.
Products solidifying is very fast, and shortcoming is that graticule is filmed the yellowing phenomenon is arranged slightly.
Embodiment 8:
The A component:
Resin 1500g, titanium dioxide 750g,
Polymeric plasticizer 150g, GW150 antistatic agent 15g, HG-6171 stain control agent 5g, 1250 order dry powder 2580g amount to 5000g.
The B component:
Resin 2500g, titanium dioxide 750g,
Polymeric plasticizer 150g, GW150 antistatic agent 5g, HG-6171 stain control agent 50g, solidifying agent dibenzoyl peroxide (BPO) 250g, 1250 order dry powder 1295g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component are after 2: 1 mixed preparing, and the form of construction work of employing blade coating is constructed.
Embodiment 9:
The A component:
Resin 2000g, titanium dioxide 700g,
Polymeric plasticizer 150g, GW150 antistatic agent 15g, HG-6172 stain control agent 40g, 1250 order dry powder 2095g amount to 5000g.
The B component:
Resin 2000g, titanium dioxide 700g,
Polymeric plasticizer 150g, GW150 antistatic agent 15g, HG-6172 stain control agent 40g, solidifying agent dibenzoyl peroxide (BPO) 200g, 1250 order dry powder 1895g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component are after 1: 1 mixed preparing, and the form of construction work of employing blade coating is constructed, and construction results is seen accompanying drawing.
About 10 minutes of the dry and hard at ambient temperature time of graticule that this prescription construction forms, the bright and clean exquisiteness of the film coated surface of formation, stain resistance is strong.
Embodiment 10:
The A component:
Resin 1500g, titanium dioxide 750g,
Polymeric plasticizer 150g, HG150 antistatic agent 15g, HG-613 stain control agent 40g, 1250 order dry powder 2545g amount to 5000g.
The B component:
Resin 2500g, titanium dioxide 500g,
Polymeric plasticizer 150g, GW150 antistatic agent 15g, HG-613 stain control agent 40g, solidifying agent dibenzoyl peroxide (BPO) 200g, 1250 order dry powder 1595g amount to 5000g.
The preparation method is: (1) preparation A component: softening agent, antistatic agent and stain control agent are added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed; (3) when construction, A component and B component are after 2: 1 mixed preparing, and the form of construction work of employing blade coating is constructed.
About 10 minutes of the dry and hard at ambient temperature time of graticule that this prescription construction forms, the bright and clean exquisiteness of the film coated surface of formation, stain resistance is strong.
Claims (8)
1. a high-dirt-resistance road mark coating is characterized in that comprising two components of A, B;
The A component according to the prescription of weight unit part meter is: active MMA response type acrylate resin 30-50 part; Titanium dioxide 10-20 part; Softening agent 1-5 part; Antistatic agent 0.1-0.3 part; Stain control agent 0.1-1 part; Residue is filler; Total umber is 100 parts;
The B component according to the prescription of weight unit part meter is: active MMA response type acrylate resin 30-50 part; Titanium dioxide 10-20 part; Softening agent 1-5 part; Antistatic agent 0.1-0.3 part; Stain control agent 0.1-1 part; Solidifying agent 0.5-5 part; Residue is filler; Total umber is 100 parts;
A, B two components are in use according to weight ratio 1-4: 1 mixed.
2. high-dirt-resistance road mark coating as claimed in claim 1 is characterized in that active MMA response type acrylate resin is in the A component
In any one; Active MMA response type acrylate resin is in the B component
In any one.
3. high-dirt-resistance road mark coating as claimed in claim 1 is characterized in that softening agent is
4. high-dirt-resistance road mark coating as claimed in claim 1 is characterized in that stain control agent adopts among fluorocarbon surfactant HG-613, HG-614, HG-6171, the HG-6172 any one.
5. high-dirt-resistance road mark coating as claimed in claim 1, it is characterized in that antistatic agent be among GW90, GW-150, the GW-2 any one.
6. high-dirt-resistance road mark coating as claimed in claim 1 is characterized in that solidifying agent is a dibenzoyl peroxide.
7. high-dirt-resistance road mark coating as claimed in claim 1 is characterized in that filler is greater than 1250 purpose dry powders.
8. the method for making of high-dirt-resistance road mark coating as claimed in claim 1 is characterized in that A component, B component prepare respectively, are mixed in proportion during use again:
(1) preparation A component: softening agent, antistatic agent and stain control agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed;
(2) preparation B component: softening agent, antistatic agent, stain control agent and solidifying agent added fully dispersed with stirring is even in the active MMA response type acrylate resin, add titanium dioxide then and filler fully stirs, change in the sand mill again and grind, after-filtration to be uniformly dispersed;
(3) adopt external mix spraying or knife-coat application in the road surface in proportion A component and B component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010154496XA CN101805552B (en) | 2010-04-22 | 2010-04-22 | High-dirt-resistance road mark coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010154496XA CN101805552B (en) | 2010-04-22 | 2010-04-22 | High-dirt-resistance road mark coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101805552A true CN101805552A (en) | 2010-08-18 |
| CN101805552B CN101805552B (en) | 2011-12-07 |
Family
ID=42607511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010154496XA Expired - Fee Related CN101805552B (en) | 2010-04-22 | 2010-04-22 | High-dirt-resistance road mark coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101805552B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102071654A (en) * | 2010-12-20 | 2011-05-25 | 周良勇 | Construction method for pavement markers |
| CN102585640A (en) * | 2012-02-24 | 2012-07-18 | 山西长达交通设施有限公司 | Three-in-one liquid road marking paint and preparation method and application thereof |
| CN102634258A (en) * | 2012-03-28 | 2012-08-15 | 山西长达交通设施有限公司 | Road marking coating for preventing destroying by snow shovels as well as preparation method and use method thereof |
| CN102775872A (en) * | 2012-08-27 | 2012-11-14 | 山西省交通科学研究院 | Self-cleaning bi-component road marking coating and preparation method thereof |
| CN103254717A (en) * | 2013-05-21 | 2013-08-21 | 保定市科顺达交通设施有限公司 | PMMA (Polymethyl Methacrylate) type two-component road marking material and preparation method thereof |
| CN106243890A (en) * | 2016-08-23 | 2016-12-21 | 陕西世纪交通工程股份有限公司 | A kind of nanoscale MMA double-component superbright type reflexed light ring friendly coating and preparation method thereof and using method |
| CN106634314A (en) * | 2016-12-30 | 2017-05-10 | 山西长达交通材料科技股份有限公司 | High-brightness marking coating and preparation method thereof |
| CN106700918A (en) * | 2017-01-09 | 2017-05-24 | 上海三恩化工有限公司 | Coating for flocking tape roller coating and preparation method of coating |
| CN106833203A (en) * | 2017-02-17 | 2017-06-13 | 云南建投建材科技有限责任公司 | A kind of cold painting quick-dry type colorful pavement antiskid paint |
| CN109777218A (en) * | 2018-12-27 | 2019-05-21 | 武汉华中科大新材料股份有限公司 | A kind of road preventive maintenance material and its construction method |
| CN111607307A (en) * | 2020-06-12 | 2020-09-01 | 安徽名士达新材料有限公司 | zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19844056A1 (en) * | 1998-09-25 | 2000-03-30 | Lippold Enno | Road and traffic warning markings include light-emitting coloring allied to faceted particles or optical fibers transmitting, refracting and reflecting incident sun- or headlamp light to increase visibility at all times |
| US6521718B2 (en) * | 1998-10-05 | 2003-02-18 | 3M Innovative Properties Company | Pavement marking composition |
| CN101343335A (en) * | 2007-07-12 | 2009-01-14 | 赢创罗姆有限责任公司 | Two or more-component system cured by a redox initiator system with controllable working life, and the use thereof |
-
2010
- 2010-04-22 CN CN201010154496XA patent/CN101805552B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19844056A1 (en) * | 1998-09-25 | 2000-03-30 | Lippold Enno | Road and traffic warning markings include light-emitting coloring allied to faceted particles or optical fibers transmitting, refracting and reflecting incident sun- or headlamp light to increase visibility at all times |
| US6521718B2 (en) * | 1998-10-05 | 2003-02-18 | 3M Innovative Properties Company | Pavement marking composition |
| CN101343335A (en) * | 2007-07-12 | 2009-01-14 | 赢创罗姆有限责任公司 | Two or more-component system cured by a redox initiator system with controllable working life, and the use thereof |
Non-Patent Citations (3)
| Title |
|---|
| 《公路交通科技》 20081231 刘冬生 彩色防滑路面在昌九高速公路技改项目小半径反向曲线路段的应用 第137-139页 权利要求第1-8项 , 第11期 2 * |
| 《山西交通科技》 20091231 石铁龙 MMA双组分抗污标线用于北京城市道路 第86页 权利要求第1-8项 , 第3期 2 * |
| 《山西交通科技》 20091231 薛晓东 城市抗污染标线的研究及应用 第67-69页 权利要求第1-8项 , 第6期 2 * |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102071654B (en) * | 2010-12-20 | 2015-09-09 | 温州市正龙市政建设有限公司 | A kind of construction method of pavement marker |
| CN102071654A (en) * | 2010-12-20 | 2011-05-25 | 周良勇 | Construction method for pavement markers |
| CN102585640A (en) * | 2012-02-24 | 2012-07-18 | 山西长达交通设施有限公司 | Three-in-one liquid road marking paint and preparation method and application thereof |
| CN102634258A (en) * | 2012-03-28 | 2012-08-15 | 山西长达交通设施有限公司 | Road marking coating for preventing destroying by snow shovels as well as preparation method and use method thereof |
| CN102775872A (en) * | 2012-08-27 | 2012-11-14 | 山西省交通科学研究院 | Self-cleaning bi-component road marking coating and preparation method thereof |
| CN103254717B (en) * | 2013-05-21 | 2016-01-20 | 保定市科顺达交通设施有限公司 | A kind of PMMA type pavement strip material and preparation method thereof |
| CN103254717A (en) * | 2013-05-21 | 2013-08-21 | 保定市科顺达交通设施有限公司 | PMMA (Polymethyl Methacrylate) type two-component road marking material and preparation method thereof |
| CN106243890A (en) * | 2016-08-23 | 2016-12-21 | 陕西世纪交通工程股份有限公司 | A kind of nanoscale MMA double-component superbright type reflexed light ring friendly coating and preparation method thereof and using method |
| CN106634314A (en) * | 2016-12-30 | 2017-05-10 | 山西长达交通材料科技股份有限公司 | High-brightness marking coating and preparation method thereof |
| CN106634314B (en) * | 2016-12-30 | 2019-06-25 | 山西中涂交通科技股份有限公司 | A kind of highlighted gage mark coating and preparation method thereof |
| CN106700918A (en) * | 2017-01-09 | 2017-05-24 | 上海三恩化工有限公司 | Coating for flocking tape roller coating and preparation method of coating |
| CN106833203A (en) * | 2017-02-17 | 2017-06-13 | 云南建投建材科技有限责任公司 | A kind of cold painting quick-dry type colorful pavement antiskid paint |
| CN109777218A (en) * | 2018-12-27 | 2019-05-21 | 武汉华中科大新材料股份有限公司 | A kind of road preventive maintenance material and its construction method |
| CN109777218B (en) * | 2018-12-27 | 2021-10-26 | 武汉华中科大新材料股份有限公司 | Material for preventive maintenance of road and construction method thereof |
| CN111607307A (en) * | 2020-06-12 | 2020-09-01 | 安徽名士达新材料有限公司 | zero-VOC quick-drying scratch-resistant bright black finish paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101805552B (en) | 2011-12-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101805552B (en) | High-dirt-resistance road mark coating and preparation method thereof | |
| CN102863854B (en) | High chlorinated potyethlene anti-corrosive paint and preparation method thereof | |
| CN108059917B (en) | Nano modified polysilazane antistatic material and preparation method thereof | |
| CN105860657B (en) | A kind of fluorocarbon oil ink and preparation method and a kind of fluorocarbon oil ink transfer film | |
| AU2016213104B2 (en) | Near-infrared ray absorbing microparticle dispersion solution and production method thereof | |
| CN105086823A (en) | Organosilicone room-temperature-cured anticorrosive coating material | |
| CN106243890A (en) | A kind of nanoscale MMA double-component superbright type reflexed light ring friendly coating and preparation method thereof and using method | |
| CN103666181A (en) | Preparation method of anti-pollution road marking paint | |
| CN102898913B (en) | Aqueous inorganic zinc rich paint | |
| CN103113812A (en) | POSS (Polyhedral oligomeric silsesquioxane)-based nano material modified polyester powder coating and preparation method thereof | |
| CN101967329A (en) | Water-based colorful imitation marble paint | |
| CN103073970A (en) | Preparation method of novel solvent-free antistatic antibiosis epoxy self-leveling terrace paint | |
| CN103666180A (en) | Anti-pollution road marking paint | |
| CN103965757A (en) | Solvent-free bicomponent road marking paint | |
| CN109913063A (en) | A kind of anti-graffiti interior wall sealing wax of fluorescence and preparation method thereof | |
| CN108485498A (en) | A kind of super abrasive coating material | |
| AU2014100870A4 (en) | Transparent, heat-insulting, UV-blocking coatings | |
| CN104945983A (en) | UV-curable low-shrinkage environment-friendly coating | |
| CN102010645B (en) | Waterborne epoxy coating specially for nuclear power stations and preparation method thereof | |
| CN103740190B (en) | A kind of rare earth nano insulating mold coating for high-transparent glass and preparation method thereof | |
| CN104231838A (en) | Preparation method anti-pollution road-marking paint | |
| TW201934678A (en) | Sunlight heat-reflection thermal insulation sand-in-water multi-color eco-friendly paint and preparation method thereof capable of providing a decorative surface with a three-dimensional effect | |
| CN104945974A (en) | UV-curable rust-proof environment-friendly coating | |
| CN104945985A (en) | UV-curable environment-friendly coating | |
| CN101306834A (en) | High heat insulation nano composite material and method for preparing heat insulation products |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171205 Address after: 030000, room eight, room 8819, No. 32, high tech street, Shanxi Hi-tech Zone, Taiyuan hi tech Zone Patentee after: CHINA (SHANXI) CHANGDA TRAFFIC FACILITIES CO.,LTD. Address before: 030006 Hi-tech Development Zone, Taiyuan, Shanxi Province, No. 32 Patentee before: SHANXI CHANGDA TRAFFIC FACILITIES Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: Room 8819, 8 / F, high tech building, No. 32, high tech street, Taiyuan Xuefu Park, comprehensive reform demonstration zone, Taiyuan City, Shanxi Province Patentee after: SHANXI ZHONGTU TRAFFIC TECHNOLOGY Co.,Ltd. Address before: 030000, room eight, room 8819, No. 32, high tech street, Shanxi Hi-tech Zone, Taiyuan hi tech Zone Patentee before: CHINA (SHANXI) CHANGDA TRAFFIC FACILITIES Co.,Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20210323 Address after: Room 8819, 8th floor, Gaoke building, 32 Gaoxin street, Taiyuan Xuefu Park, comprehensive reform demonstration zone, Taiyuan City, Shanxi Province 030000 Patentee after: SHANXI ZHONGTU TRAFFIC TECHNOLOGY Co.,Ltd. Patentee after: Hunan Changda Transportation Facilities Co.,Ltd. Address before: Room 8819, 8th floor, Gaoke building, 32 Gaoxin street, Taiyuan Xuefu Park, comprehensive reform demonstration zone, Taiyuan City, Shanxi Province 030000 Patentee before: SHANXI ZHONGTU TRAFFIC TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High antifouling road marking paint and its preparation method Effective date of registration: 20210419 Granted publication date: 20111207 Pledgee: Pudong Shanghai Development Bank Limited by Share Ltd. Taiyuan branch Pledgor: SHANXI ZHONGTU TRAFFIC TECHNOLOGY Co.,Ltd. Registration number: Y2021140000009 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220902 Granted publication date: 20111207 Pledgee: Pudong Shanghai Development Bank Limited by Share Ltd. Taiyuan branch Pledgor: SHANXI ZHONGTU TRAFFIC TECHNOLOGY Co.,Ltd. Registration number: Y2021140000009 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111207 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |