CN111607297A - Environment-friendly waterproof architectural decorative coating and preparation method thereof - Google Patents
Environment-friendly waterproof architectural decorative coating and preparation method thereof Download PDFInfo
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- CN111607297A CN111607297A CN202010569620.2A CN202010569620A CN111607297A CN 111607297 A CN111607297 A CN 111607297A CN 202010569620 A CN202010569620 A CN 202010569620A CN 111607297 A CN111607297 A CN 111607297A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
- C09D109/08—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an environment-friendly waterproof architectural decorative coating and a preparation method thereof, wherein the coating comprises the following raw materials in parts by weight: 60-80 parts of styrene-butadiene emulsion, 0.1-0.3 part of PH regulator, 30-60 parts of heavy calcium carbonate, 0.3-3 parts of weather-resistant titanium dioxide, 0.3-0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2-0.5 part of thickener, 6-9 parts of water and 0.2-0.8 part of color paste; the method comprises the following steps: s1, weighing the raw materials according to the requirements; s2, mixing the butylbenzene emulsion, the PH regulator, the heavy calcium carbonate, the weather-resistant titanium dioxide, the defoaming agent, the preservative thickener, the water and the color paste, and adding the mixture into a stirrer to obtain a mixture A; s3, adding the polyurethane resin, the butyl acrylate and the polyvinyl alcohol into a reaction kettle with a stirrer, and stirring to obtain a mixture B; and S4, adding the mixture A prepared in the S2 and the mixture B prepared in the S3 into a high-speed stirrer to prepare the green environment-friendly waterproof decorative paint. By adjusting the formula and the dosage of the architectural decorative coating, the architectural decorative coating has the advantages of environmental protection, decoration and water resistance.
Description
Technical Field
The invention relates to the technical field of building coating manufacturing, in particular to an environment-friendly waterproof building decorative coating and a preparation method thereof.
Background
In recent years, because the amount of the coating is larger and larger, the application range is wider and wider, the importance of the coating is gradually acknowledged, the research on the basic application is developed, but the higher demand of the development of the coating is still difficult to deal with, along with the progress of scientific technology, the coating which is a material playing an important role in the whole national economic development and the improvement of the people's life is inevitably developed more and more in China, and the research on the coating is gradually enhanced.
However, the existing architectural decorative coating is simpler to produce and manufacture, and the waterproof and environment-friendly properties of the coating are poorer, so that the using effect of the coating is influenced.
Disclosure of Invention
1. Technical problem to be solved
The invention aims to solve the problems of simple production and manufacture of architectural decorative coatings and poor waterproof and environment-friendly properties of the coatings in the prior art, and provides an environment-friendly waterproof architectural decorative coating and a preparation method thereof.
2. Technical scheme
In order to achieve the purpose, the invention adopts the following technical scheme:
the environment-friendly waterproof architectural decorative coating comprises the following raw materials in parts by weight: 60-80 parts of styrene-butadiene emulsion, 0.1-0.3 part of PH regulator, 30-60 parts of heavy calcium carbonate, 0.3-3 parts of weather-resistant titanium dioxide, 0.3-0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2-0.5 part of thickener, 6-9 parts of water and 0.2-0.8 part of color paste.
Preferably, the feed comprises the following raw materials in parts by weight: 60 parts of butylbenzene emulsion, 0.3 part of PH regulator, 30 parts of ground limestone, 3 parts of weather-resistant titanium dioxide, 0.3 part of defoamer, 0.4 part of preservative, 0.2 part of thickener, 9 parts of water and 0.8 part of color paste.
Preferably, the feed comprises the following raw materials in parts by weight: 80 parts of butylbenzene emulsion, 0.1 part of PH regulator, 60 parts of heavy calcium carbonate, 0.3 part of weather-resistant titanium dioxide, 0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2 part of thickener, 6 parts of water and 0.2 part of color paste.
Preferably, the feed comprises the following raw materials in parts by weight: 70 parts of butylbenzene emulsion, 0.2 part of PH regulator, 50 parts of heavy calcium carbonate, 2 parts of weather-resistant titanium dioxide, 0.4 part of defoamer, 0.2 part of preservative, 0.3 part of thickener, 8 parts of water and 0.5 part of color paste.
The invention also provides a preparation method of the environment-friendly waterproof architectural decorative coating, which comprises the following steps:
s1, weighing the raw materials according to the requirements;
s2, mixing the butylbenzene emulsion, the PH regulator, the heavy calcium carbonate, the weather-resistant titanium dioxide, the defoaming agent, the preservative thickener, the water and the color paste, and adding the mixture into a stirrer to obtain a mixture A;
s3, adding the polyurethane resin, the butyl acrylate and the polyvinyl alcohol into a reaction kettle with a stirrer, and stirring to obtain a mixture B;
and S4, adding the mixture A prepared in the S2 and the mixture B prepared in the S3 into a high-speed stirrer to prepare the green environment-friendly waterproof decorative paint.
Preferably, in the S2, the temperature is 30 ℃ for 20 minutes, the stirring speed is 400-.
Preferably, in the S3, the stirring is carried out for 10-20 minutes at the temperature of 50-60 ℃ and the rotating speed of 200-300r/min, then the temperature is increased to 90-100 ℃, the processing and performance enhancing additive is added, and the stirring is continued for 20-30 minutes.
Preferably, in S4, the rotation speed of the high-speed stirrer is 400-500r/min, the stirring is carried out for 30 minutes at 40-50 ℃, and then the mixture is added into the homogenizer and homogenized for 8 minutes under the pressure of 14MPa and the rotation speed of 6000-7000 r/min.
3. Advantageous effects
Compared with the prior art, the invention has the advantages that:
by adjusting the formula and the dosage of the architectural decorative coating, the architectural decorative coating has the advantages of environmental protection, decoration and water resistance.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
Example 1:
the environment-friendly waterproof architectural decorative coating comprises the following raw materials in parts by weight: 60-80 parts of styrene-butadiene emulsion, 0.1-0.3 part of PH regulator, 30-60 parts of heavy calcium carbonate, 0.3-3 parts of weather-resistant titanium dioxide, 0.3-0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2-0.5 part of thickener, 6-9 parts of water and 0.2-0.8 part of color paste.
The preparation method of the environment-friendly waterproof architectural decorative coating comprises the following steps:
s1, weighing the raw materials according to the requirements;
s2, mixing the butylbenzene emulsion, the PH regulator, the heavy calcium carbonate, the weather-resistant titanium dioxide, the defoaming agent, the preservative thickener, the water and the color paste, and adding the mixture into a stirrer to obtain a mixture A;
s3, adding the polyurethane resin, the butyl acrylate and the polyvinyl alcohol into a reaction kettle with a stirrer, and stirring to obtain a mixture B;
and S4, adding the mixture A prepared in the S2 and the mixture B prepared in the S3 into a high-speed stirrer to prepare the green environment-friendly waterproof decorative paint.
In the invention, in S2, stirring is carried out for 20 minutes at the temperature of 30 ℃, the stirring rotation speed is 400-.
In the invention, in S3, stirring is carried out for 10-20 minutes at the temperature of 50-60 ℃ and the rotating speed of 200-300r/min, then the temperature is raised to 90-100 ℃, the processing and enhancing additive is added, and the stirring is continued for 20-30 minutes.
In the invention, in S4, the rotation speed of the high-speed stirrer is 400-7000 r/min, the stirring is carried out for 30 minutes at 40-50 ℃, and then the mixture is added into a homogenizer and homogenized for 8 minutes under the pressure of 14MPa and the rotation speed of 6000-7000 r/min.
Example 2:
the environment-friendly waterproof architectural decorative coating comprises the following raw materials in parts by weight: 60-80 parts of styrene-butadiene emulsion, 0.1-0.3 part of PH regulator, 30-60 parts of heavy calcium carbonate, 0.3-3 parts of weather-resistant titanium dioxide, 0.3-0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2-0.5 part of thickener, 6-9 parts of water and 0.2-0.8 part of color paste.
The invention comprises the following raw materials in parts by weight: 60 parts of butylbenzene emulsion, 0.3 part of PH regulator, 30 parts of ground limestone, 3 parts of weather-resistant titanium dioxide, 0.3 part of defoamer, 0.4 part of preservative, 0.2 part of thickener, 9 parts of water and 0.8 part of color paste.
The invention comprises the following raw materials in parts by weight: 80 parts of butylbenzene emulsion, 0.1 part of PH regulator, 60 parts of heavy calcium carbonate, 0.3 part of weather-resistant titanium dioxide, 0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2 part of thickener, 6 parts of water and 0.2 part of color paste.
The invention comprises the following raw materials in parts by weight: 70 parts of butylbenzene emulsion, 0.2 part of PH regulator, 50 parts of heavy calcium carbonate, 2 parts of weather-resistant titanium dioxide, 0.4 part of defoamer, 0.2 part of preservative, 0.3 part of thickener, 8 parts of water and 0.5 part of color paste.
The preparation method of the environment-friendly waterproof architectural decorative coating comprises the following steps:
s1, weighing the raw materials according to the requirements;
s2, mixing the butylbenzene emulsion, the PH regulator, the heavy calcium carbonate, the weather-resistant titanium dioxide, the defoaming agent, the preservative thickener, the water and the color paste, and adding the mixture into a stirrer to obtain a mixture A;
s3, adding the polyurethane resin, the butyl acrylate and the polyvinyl alcohol into a reaction kettle with a stirrer, and stirring to obtain a mixture B;
and S4, adding the mixture A prepared in the S2 and the mixture B prepared in the S3 into a high-speed stirrer to prepare the green environment-friendly waterproof decorative paint.
In the invention, in S2, stirring is carried out for 20 minutes at the temperature of 30 ℃, the stirring rotation speed is 400-.
In the invention, in S3, stirring is carried out for 10-20 minutes at the temperature of 50-60 ℃ and the rotating speed of 200-300r/min, then the temperature is raised to 90-100 ℃, the processing and enhancing additive is added, and the stirring is continued for 20-30 minutes.
In the invention, in S4, the rotation speed of the high-speed stirrer is 400-7000 r/min, the stirring is carried out for 30 minutes at 40-50 ℃, and then the mixture is added into a homogenizer and homogenized for 8 minutes under the pressure of 14MPa and the rotation speed of 6000-7000 r/min.
Example 3:
the environment-friendly waterproof architectural decorative coating comprises the following raw materials in parts by weight: 60 parts of butylbenzene emulsion, 0.3 part of PH regulator, 30 parts of ground limestone, 3 parts of weather-resistant titanium dioxide, 0.3 part of defoamer, 0.4 part of preservative, 0.2 part of thickener, 9 parts of water and 0.8 part of color paste.
The preparation method of the environment-friendly waterproof architectural decorative coating comprises the following steps:
s1, weighing the raw materials according to the requirements;
s2, mixing the butylbenzene emulsion, the PH regulator, the heavy calcium carbonate, the weather-resistant titanium dioxide, the defoaming agent, the preservative thickener, the water and the color paste, and adding the mixture into a stirrer to obtain a mixture A;
s3, adding the polyurethane resin, the butyl acrylate and the polyvinyl alcohol into a reaction kettle with a stirrer, and stirring to obtain a mixture B;
and S4, adding the mixture A prepared in the S2 and the mixture B prepared in the S3 into a high-speed stirrer to prepare the green environment-friendly waterproof decorative paint.
In the invention, in S2, stirring is carried out for 20 minutes at the temperature of 30 ℃, the stirring rotation speed is 400-.
In the invention, in S3, stirring is carried out for 10-20 minutes at the temperature of 50-60 ℃ and the rotating speed of 200-300r/min, then the temperature is raised to 90-100 ℃, the processing and enhancing additive is added, and the stirring is continued for 20-30 minutes.
In the invention, in S4, the rotation speed of the high-speed stirrer is 400-7000 r/min, the stirring is carried out for 30 minutes at 40-50 ℃, and then the mixture is added into a homogenizer and homogenized for 8 minutes under the pressure of 14MPa and the rotation speed of 6000-7000 r/min.
Example 4:
the environment-friendly waterproof architectural decorative coating comprises the following raw materials in parts by weight: 70 parts of butylbenzene emulsion, 0.2 part of PH regulator, 50 parts of heavy calcium carbonate, 2 parts of weather-resistant titanium dioxide, 0.4 part of defoamer, 0.2 part of preservative, 0.3 part of thickener, 8 parts of water and 0.5 part of color paste.
The preparation method of the environment-friendly waterproof architectural decorative coating comprises the following steps:
s1, weighing the raw materials according to the requirements;
s2, mixing the butylbenzene emulsion, the PH regulator, the heavy calcium carbonate, the weather-resistant titanium dioxide, the defoaming agent, the preservative thickener, the water and the color paste, and adding the mixture into a stirrer to obtain a mixture A;
s3, adding the polyurethane resin, the butyl acrylate and the polyvinyl alcohol into a reaction kettle with a stirrer, and stirring to obtain a mixture B;
and S4, adding the mixture A prepared in the S2 and the mixture B prepared in the S3 into a high-speed stirrer to prepare the green environment-friendly waterproof decorative paint.
In the invention, in S2, stirring is carried out for 20 minutes at the temperature of 30 ℃, the stirring rotation speed is 400-.
In the invention, in S3, stirring is carried out for 10-20 minutes at the temperature of 50-60 ℃ and the rotating speed of 200-300r/min, then the temperature is raised to 90-100 ℃, the processing and enhancing additive is added, and the stirring is continued for 20-30 minutes.
In the invention, in S4, the rotation speed of the high-speed stirrer is 400-7000 r/min, the stirring is carried out for 30 minutes at 40-50 ℃, and then the mixture is added into a homogenizer and homogenized for 8 minutes under the pressure of 14MPa and the rotation speed of 6000-7000 r/min.
According to the invention, by adjusting the formula and the dosage of the architectural decorative coating, the architectural decorative coating has the advantages of environmental protection, decoration and water resistance.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (8)
1. The environment-friendly waterproof architectural decorative coating is characterized by comprising the following raw materials in parts by weight: 60-80 parts of styrene-butadiene emulsion, 0.1-0.3 part of PH regulator, 30-60 parts of heavy calcium carbonate, 0.3-3 parts of weather-resistant titanium dioxide, 0.3-0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2-0.5 part of thickener, 6-9 parts of water and 0.2-0.8 part of color paste.
2. The environment-friendly waterproof architectural decorative coating according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 60 parts of butylbenzene emulsion, 0.3 part of PH regulator, 30 parts of ground limestone, 3 parts of weather-resistant titanium dioxide, 0.3 part of defoamer, 0.4 part of preservative, 0.2 part of thickener, 9 parts of water and 0.8 part of color paste.
3. The environment-friendly waterproof architectural decorative coating according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 80 parts of butylbenzene emulsion, 0.1 part of PH regulator, 60 parts of heavy calcium carbonate, 0.3 part of weather-resistant titanium dioxide, 0.5 part of defoamer, 0.04-0.4 part of preservative, 0.2 part of thickener, 6 parts of water and 0.2 part of color paste.
4. The environment-friendly waterproof architectural decorative coating according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 70 parts of butylbenzene emulsion, 0.2 part of PH regulator, 50 parts of heavy calcium carbonate, 2 parts of weather-resistant titanium dioxide, 0.4 part of defoamer, 0.2 part of preservative, 0.3 part of thickener, 8 parts of water and 0.5 part of color paste.
5. The preparation method of the environment-friendly waterproof architectural decorative coating is characterized by comprising the following steps:
s1, weighing the raw materials according to the requirements;
s2, mixing the butylbenzene emulsion, the PH regulator, the heavy calcium carbonate, the weather-resistant titanium dioxide, the defoaming agent, the preservative thickener, the water and the color paste, and adding the mixture into a stirrer to obtain a mixture A;
s3, adding the polyurethane resin, the butyl acrylate and the polyvinyl alcohol into a reaction kettle with a stirrer, and stirring to obtain a mixture B;
and S4, adding the mixture A prepared in the S2 and the mixture B prepared in the S3 into a high-speed stirrer to prepare the green environment-friendly waterproof decorative paint.
6. The method for preparing the environment-friendly waterproof architectural decorative coating according to claim 5, wherein in S2, stirring is carried out at 30 ℃ for 20 minutes at a stirring rotation speed of 400-500r/min, and then the temperature is reduced to 10-20 ℃.
7. The method for preparing environment-friendly waterproof architectural decorative coating according to claim 1, wherein in S3, stirring is carried out at 50-60 ℃ for 10-20 minutes at a rotation speed of 200-300r/min, then the temperature is raised to 90-100 ℃, and the processing and enhancing additive is added, and stirring is continued for 20-30 minutes.
8. The method for preparing environment-friendly waterproof architectural decorative coating according to claim 1, wherein in S4, the high-speed stirrer rotates at 400-7000 r/min and stirs at 40-50 ℃ for 30 minutes, and then the mixture is added into a homogenizer and homogenized at 6000-7000r/min and 14MPa for 8 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN202010569620.2A CN111607297A (en) | 2020-06-20 | 2020-06-20 | Environment-friendly waterproof architectural decorative coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010569620.2A CN111607297A (en) | 2020-06-20 | 2020-06-20 | Environment-friendly waterproof architectural decorative coating and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1857503A1 (en) * | 2005-03-09 | 2007-11-21 | Kuraray Co., Ltd. | Aqueous emulsion and coating |
| CN108329834A (en) * | 2018-03-13 | 2018-07-27 | 合肥雅克丽新型建材有限公司 | Heat-preservation flame-retardant environment-friendly deodorizing and humidifying coating and preparation method thereof |
| CN108359218A (en) * | 2018-02-06 | 2018-08-03 | 合肥广民建材有限公司 | A kind of waterproof material and preparation method thereof for building construction |
| CN108395745A (en) * | 2018-02-05 | 2018-08-14 | 合肥梵腾环保科技有限公司 | Mould decorative paint of a kind of environmentally protective waterproof sterilization suppression and preparation method thereof |
| CN110511623A (en) * | 2019-08-16 | 2019-11-29 | 河北晨阳工贸集团有限公司 | A kind of aqueous architectural decorative paint and preparation method thereof with water-proof function |
-
2020
- 2020-06-20 CN CN202010569620.2A patent/CN111607297A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1857503A1 (en) * | 2005-03-09 | 2007-11-21 | Kuraray Co., Ltd. | Aqueous emulsion and coating |
| CN108395745A (en) * | 2018-02-05 | 2018-08-14 | 合肥梵腾环保科技有限公司 | Mould decorative paint of a kind of environmentally protective waterproof sterilization suppression and preparation method thereof |
| CN108359218A (en) * | 2018-02-06 | 2018-08-03 | 合肥广民建材有限公司 | A kind of waterproof material and preparation method thereof for building construction |
| CN108329834A (en) * | 2018-03-13 | 2018-07-27 | 合肥雅克丽新型建材有限公司 | Heat-preservation flame-retardant environment-friendly deodorizing and humidifying coating and preparation method thereof |
| CN110511623A (en) * | 2019-08-16 | 2019-11-29 | 河北晨阳工贸集团有限公司 | A kind of aqueous architectural decorative paint and preparation method thereof with water-proof function |
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Application publication date: 20200901 |