CN111601908A - Carburized bearing steel member and steel bar for carburized bearing steel member - Google Patents

Carburized bearing steel member and steel bar for carburized bearing steel member Download PDF

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CN111601908A
CN111601908A CN201980008192.1A CN201980008192A CN111601908A CN 111601908 A CN111601908 A CN 111601908A CN 201980008192 A CN201980008192 A CN 201980008192A CN 111601908 A CN111601908 A CN 111601908A
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bearing steel
steel
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carburized
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CN111601908B (en
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小山达也
宫西庆
根石豊
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Nippon Steel Corp
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Nippon Steel and Sumitomo Metal Corp
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Abstract

A carburized bearing steel component having a predetermined chemical composition and containing CaO and Al and having a circle-equivalent diameter of 5 μm or more in any cross section of the component, and a steel bar for carburized bearing steel component suitable for obtaining the same2O3And SiO2And Al2O3Relative to CaO and Al2O3And SiO2Has a content of 50 mass% or more of an oxide of 3.0 pieces/cm2Hereinafter, the Vickers hardness of the rolling surface is 750 or more at a depth of 50 μm from the rolling surface, and the compressive residual stress of the rolling surface is 900MPa or more.

Description

Carburized bearing steel member and steel bar for carburized bearing steel member
Technical Field
The present disclosure relates to a carburized bearing steel component and a steel bar for a carburized bearing steel component.
Background
In recent years, the severer use environment of bearing steel members used in automobiles and the like has been increasing because of the reduction in size of members for improving fuel efficiency and the reduction in viscosity of lubricating oil. In particular, peeling may occur from a raised portion at the periphery of an indentation formed by biting of foreign matter such as ground powder, and the function as a bearing may be impaired. In order to prevent such a phenomenon, a bearing steel member having an improved rolling fatigue life (hereinafter referred to as indentation resistance life) when indentation is present is desired.
Conventionally, in order to improve the life of the pressure mark, patent document 1 discloses a technique of suppressing a bulge portion at the periphery of the pressure mark by increasing the retained austenite amount of the rolling surface. Patent document 1 describes that the retained austenite amount is set to a range of 20% to 45%.
Patent document 2 discloses that the shot peening of a bearing steel member is softened, that is, compressive residual stress is reduced, thereby suppressing the occurrence of fine cracks generated during shot peening. Further, patent document 2 discloses that the life of the pressure mark is improved by suppressing the occurrence of fine cracks.
In addition, patent documents 3 to 5 disclose techniques for bearing steel members. The details are as follows.
Patent document 3 discloses a case hardening steel in which the amount of AlN precipitated is limited to 0.01% or less, and the density d (pieces/mm) of sulfides having an equivalent circle diameter of more than 20 μm and an aspect ratio of more than 32) With the content of S [ S ]](mass%) satisfies d.ltoreq.1700S]+20. Further, patent document 3 discloses controlling the contents of AlN, sulfide, and SThe occurrence of coarse particles in case hardened steel is prevented, and the cold workability, machinability, and fatigue characteristics after carburizing and quenching are excellent.
Further, patent document 4 discloses a method for producing a bearing steel using CaO — SiO containing substantially no fluorine source2The flux is a flux which is used to stir molten steel deoxidized with Al and the flux in the atmosphere, and then Ca is added to the molten steel, and thereafter, the molten steel is refined under reduced pressure. Further, patent document 4 discloses the use of a catalyst containing no CaF2The flux containing a fluorine source can reduce the number of inclusions in the steel while refining the inclusions in the steel, and can produce bearing steel having high cleanliness and excellent rolling fatigue life characteristics.
Patent document 5 discloses a bearing steel in which oxide inclusions contained in the steel have a total grain size of 15 μm or less, and particles having a grain size of 10 μm or more are less than 2% of the total. Further, patent document 5 discloses that high strength, long life, and high heat resistance are achieved by controlling the particle size of the oxide inclusions.
Patent document 1: japanese laid-open patent publication No. Sho 64-55423
Patent document 2: japanese patent laid-open publication No. 2006-329319
Patent document 3: international publication No. WO2010-116555
Patent document 4: japanese laid-open patent publication No. 2010-196114
Patent document 5: japanese laid-open patent publication No. 5-140696
Disclosure of Invention
Problems to be solved by the invention
However, the bearing steel member of patent document 1 has reduced surface hardness due to the increase in retained austenite, and therefore has reduced rolling fatigue life (i.e., strength against internal fatigue fracture from the inclusion origin in a clean environment or fracture due to sintering) other than indentation life. Further, the surface hardness cannot be maintained at a level of not less than that of a general bearing steel member generally used for automobile applications (vickers hardness of 750 or more).
In order to further improve the pressure mark life, it is necessary to apply sufficient compressive residual stress, not to reduce the compressive residual stress as in the bearing steel member of patent document 2.
The techniques disclosed in patent documents 3 to 5 for bearing steel parts are techniques for suppressing internal fatigue fracture (i.e., improving rolling fatigue life other than the pressure mark life) from non-metallic inclusions, and no consideration is given to the pressure mark life. Therefore, in the techniques for bearing steel members disclosed in patent documents 3 to 5, there is room for improvement in the improvement of the life of the pressure mark.
Accordingly, an object of the present disclosure is to provide a carburized bearing steel member having excellent pressure mark life while maintaining surface hardness at a level equivalent to that of a general bearing steel member, and a steel bar for a carburized bearing steel member suitable for obtaining the same.
Means for solving the problems
The above problems include the following.
<1> a carburized bearing steel component, wherein the chemical composition inside than the depth of 2.00mm from the surface of the carburized bearing steel component comprises, in mass%:
C:0.15~0.25%、
Si:0.70~1.50%、
Mn:0.40~1.50%、
Cr:0.15~1.50%、
Mo:0.001~0.150%、
S:0.001~0.030%、
N:0.004~0.020%、
Ca:0.0002~0.0100%
Al:0.001~0.010%、
O:0~0.005%、
P:0~0.030%、
Ni:0~3.00%、
Cu:0~1.00%、
Co:0~3.00%、
W:0~1.00%、
V:0~0.30%、
Ti:0~0.300%、
Nb:0~0.300%、
B:0~0.0050%
Pb:0~0.50%、
Bi:0~0.50%、
Mg:0~0.0100%、
Zr:0~0.0500%、
Te:0~0.1000%、
rare earth elements: 0 to 0.0050%,
Sn:0~2.0%、
In: 0 to 0.50%, and
the rest is as follows: consists of Fe and impurities, and the Fe-Fe alloy consists of Fe and impurities,
in any cross section of the member, the equivalent circle diameter is 5 μm or more, and CaO and Al are contained2O3And SiO2And the above-mentioned Al2O3With respect to the above CaO and the above Al2O3And the above SiO2Has a content of 50 mass% or more of an oxide of 3.0 pieces/cm2In the following, the following description is given,
a Vickers hardness of 750 or more at a depth of 50 μm from the rolling surface,
the compressive residual stress of the rolling surface is 900MPa or more.
<2> the carburized bearing steel component according to <1>, wherein a chemical composition inside of the carburized bearing steel component at a depth of 2.00mm from a surface of the carburized bearing steel component contains, in mass%:
Ni:0.01~3.00%、
Cu:0.01~1.00%、
Co:0.01~3.00%、
W:0.01~1.00%、
V:0.01~0.30%、
Ti:0.001~0.300%、
nb: 0.001 to 0.300% and
b: 0.0001-0.0050% of 1 or more.
<3> the carburized bearing steel component according to <1> or <2>, wherein a chemical composition inside of a depth of 2.00mm from a surface of the carburized bearing steel component contains, in mass%:
Pb:0.01~0.50%、
Bi:0.01~0.50%、
Mg:0.0001~0.0100%、
Zr:0.0001~0.0500%、
Te:0.0001~0.1000%、
rare earth elements: 0.0001-0.0050% of 1 or more.
<4> the carburized bearing steel component according to any one of <1> to <3>, wherein a C content of the carburized layer in a rolling surface is 0.60 to 1.10% by mass%.
<5> a steel bar for a carburized bearing steel component, which contains, in mass%, chemical components located inside a depth of 2.00mm from the surface of the steel bar for a carburized bearing steel component:
C:0.15~0.25%、
Si:0.70~1.50%、
Mn:0.40~1.50%、
Cr:0.15~1.50%、
Mo:0.001~0.150%、
S:0.001~0.030%、
N:0.004~0.020%、
Ca:0.0002~0.0100%
Al:0.001~0.010%、
O:0~0.005%、
P:0~0.030%、
Ni:0~3.00%、
Cu:0~1.00%、
Co:0~3.00%、
W:0~1.00%、
V:0~0.30%、
Ti:0~0.300%、
Nb:0~0.300%、
B:0~0.0050%
Pb:0~0.50%、
Bi:0~0.50%、
Mg:0~0.0100%、
Zr:0~0.0500%、
Te:0~0.1000%、
rare earth elements: 0 to 0.0050%,
Sn:0~2.0%、
In: 0 to 0.50%, and
the rest is as follows: consists of Fe and impurities, and the Fe-Fe alloy consists of Fe and impurities,
in any cross section of the steel bar, the equivalent circle diameter is 5 μm or more, and CaO and Al are contained2O3And SiO2And the above-mentioned Al2O3With respect to the above CaO and the above Al2O3And the above SiO2Has a content of 50 mass% or more of an oxide of 3.0 pieces/cm2The following.
<6> the steel bar for a carburized bearing steel component according to <5>, wherein the chemical composition in the inner portion of the steel bar for a carburized bearing steel component at a depth of 2.00mm from the surface thereof contains, in mass%:
Ni:0.01~3.00%、
Cu:0.01~1.00%、
Co:0.01~3.00%、
W:0.01~1.00%、
V:0.01~0.30%、
Ti:0.001~0.300%、
nb: 0.001 to 0.300% and
b: 0.0001-0.0050% of 1 or more.
<7> the steel bar for a carburized bearing steel component according to <5> or <6>, wherein the chemical composition inside the steel bar for a carburized bearing steel component at a depth of 2.00mm from the surface thereof contains, in mass%:
Pb:0.01~0.50%、
Bi:0.01~0.50%、
Mg:0.0001~0.0100%、
Zr:0.0001~0.0500%、
Te:0.0001~0.1000%、
rare earth elements: 0.0001-0.0050% of 1 or more species.
Effects of the invention
According to the present disclosure, it is possible to provide a carburized bearing steel member having excellent pressure mark life while maintaining the surface hardness at the same level as that of a general bearing steel member, and a steel bar for a carburized bearing steel member suitable for obtaining the same.
Drawings
FIG. 1 is a schematic surface view showing a cylindrical rolling contact fatigue test piece having an outer dimension of φ 12mm × 22 mm.
Detailed Description
Hereinafter, an embodiment as an example of the present disclosure will be described.
In the present specification, the numerical range expressed by the term "to" means a range including numerical values before and after the term "to" as a lower limit value and an upper limit value.
The numerical ranges in which "more than" or "less than" is added to the numerical values recited before and after "to" mean ranges in which these numerical values are not included as the lower limit or the upper limit.
In addition, "%" means "% by mass" with respect to the content of elements of the chemical composition.
(carburized bearing steel component)
The carburized bearing steel component according to the present embodiment (hereinafter, also simply referred to as "bearing steel component") has a predetermined chemical composition, and has an equivalent circle diameter of 5 μm or more and contains CaO and Al in any cross section of the component2O3And SiO2And Al2O3Relative to CaO and Al2O3And SiO2Has a content of oxide(s) of 50% by mass or more in total (hereinafter, also referred to as "having an equivalent circle diameter of 5 μm or more and containing Al2O3An oxide having a content of 50 mass% or more ". ) The number density of (B) is 3.0 pieces/cm2Below, 50 μm deep from the rolling surfaceThe Vickers hardness is 750 or more, and the compressive residual stress of the rolling surface is 900MPa or more.
The bearing steel member according to the present embodiment has the above-described configuration, and thus has a surface hardness that is maintained at a level equivalent to that of a general bearing steel member, and has an excellent pressure mark life. The bearing steel member according to the present embodiment is found by the following findings.
First, the present inventors carried out the following evaluation in order to realize a bearing steel member having excellent indentation life while maintaining the surface hardness at a level equal to or higher than that of a general bearing steel member. Specifically, for a bearing steel material with a systematically changed chemical composition, evaluation of the life of the pressure mark was carried out when the bearing steel member was produced by combining various working processes. As a result, the following findings (1) to (2) were obtained.
(1) The reduction in the life of the pressure mark is caused by cracks generated from the raised surface at the periphery of the pressure mark.
(2) By selecting Al having an equivalent circle diameter of 5 μm or more2O3The steel material having a small number of oxides with a content of 50 mass% or more can be further subjected to shot peening to impart compressive residual stress to the rolling surface of the member, thereby suppressing cracking and improving the life of the pressure mark.
Here, it is considered that the equivalent circle diameter is 5 μm or more and Al is reduced2O3The content of (b) is 50 mass% or more, and the properties of the fine inclusions (for example, adhesion to the base material) existing in the steel are changed. As a result, it is considered that the generation of fine cracks and cracks in the raised portion generated at the time of shot peening is suppressed.
In patent document 2, the occurrence of micro cracks is suppressed by softening the work of shot peening, that is, reducing the compressive residual stress. However, by performing ordinary shot peening that is not soft, a bearing steel member that imparts sufficient compressive residual stress and does not generate fine cracks can be realized.
Further, the improvement of the withstand voltage mark life is a mechanism in which no retained austenite is used, that is, a mechanism in which an effect by compressive residual stress and an effect of suppressing micro cracks are utilized, and there is an advantage in that a large amount of retained austenite is not required, and therefore, the surface hardness is not lowered.
From the above findings, it was found that the bearing steel member according to the present embodiment is a bearing steel member having excellent indentation life while maintaining the surface hardness at a level equivalent to that of a general bearing steel member.
Further, the bearing steel member according to the present embodiment has an excellent life against pressure marks, and therefore can be used even in an environment where foreign matter is mixed.
Hereinafter, the bearing steel member according to the present embodiment will be described in detail.
(chemical composition)
First, the reason why the chemical composition of the steel according to the present embodiment is limited will be described. The chemical composition of the steel described below indicates the chemical composition inside the carburized bearing steel component at a depth of 2.00mm from the surface.
C:0.15~0.25%
The C content affects the hardness of the non-carburized region of the bearing steel component. In order to secure the required hardness, the lower limit of the C content is set to 0.15%. On the other hand, since the workability in machining is deteriorated when the C content is too large, the upper limit of the C content is set to 0.25%. The lower limit of the C content is preferably 0.17%, and more preferably 0.18%. The upper limit of the C content is preferably 0.24%, and more preferably 0.23%.
Si:0.70~1.50%
Si is an element effective for deoxidizing steel and affecting the composition of oxides, and is an element effective for imparting strength in a high-temperature environment required as a bearing steel member. If the Si content is less than 0.70%, the effect is insufficient. When the Si content exceeds 1.50%, an oxide containing Si appears, which causes cracks in shot peening. For the above reasons, the Si content should be set to be in the range of 0.70 to 1.50%. The lower limit of the Si content is preferably 0.75%, and more preferably 0.80%. The lower limit of the Si content may be more than 0.90% or 1.0%. The upper limit of the Si content is preferably 1.40%, and more preferably 1.20%.
Mn:0.40~1.50%
Mn is an element effective for imparting necessary strength and hardenability to steel. If the Mn content is less than 0.40%, the effect is insufficient. When the Mn content exceeds 1.50%, the retained austenite becomes large after carburizing and quenching, and the hardness decreases. For the above reasons, the Mn content should be set to be in the range of 0.40 to 1.50%. The lower limit of the Mn content is preferably 0.45%, and more preferably 0.5%. The upper limit of the Mn content is preferably 1.40%, and more preferably 1.30%.
Cr:0.15~1.50%
Cr is an element effective for imparting necessary strength and hardenability to steel. If the Cr content is less than 0.15%, the effect is insufficient. If the Cr content exceeds 1.50%, the effect is saturated. For the above reasons, the Cr content should be set to be in the range of 0.15 to 1.50%. The lower limit of the Cr content is preferably 0.18%, and more preferably 0.20%. The upper limit of the Cr content is preferably 1.45%, and more preferably 1.40%.
Mo:0.001~0.150%
Mo is an element effective for improving the fatigue strength of steel, because it provides necessary hardenability and suppresses P segregation in grain boundaries. When the Mo content is less than 0.001%, the effect is insufficient. If the Mo content exceeds 0.150%, the effect is saturated. For the above reasons, the Mo content should be set to be in the range of 0.001 to 0.150%. The lower limit of the Mo content is preferably 0.010%, and more preferably 0.020%. The upper limit of the Mo content is preferably 0.140%, and more preferably 0.130%.
S:0.001~0.030%
S forms MnS in the steel, thereby improving the machinability of the steel. In order to obtain a level of machinability that can be used for cutting components, the S content is required to be equal to that of steel for general machine structural use. For the above reasons, it is necessary to set the S content within the range of 0.001 to 0.030%. The lower limit of the S content is preferably 0.002%, more preferably 0.003%. The upper limit of the S content is preferably 0.025%, and more preferably 0.020%.
N:0.004~0.020%
N is an element that is inevitably mixed, but has an effect of refining crystal grains by forming a compound with Al, Ti, V, Cr, or the like. Therefore, N needs to be added by 0.004% or more. However, if the N content exceeds 0.020%, the compound becomes coarse, and the effect of refining crystal grains cannot be obtained. For the above reasons, it is necessary to set the N content within the range of 0.004 to 0.020%. The lower limit of the N content is preferably 0.0045%, and more preferably 0.005%. The upper limit of the N content is preferably 0.015%, and more preferably 0.012%.
Ca:0.0002~0.0100%
Ca is effective for deoxidizing steel and reducing Al in oxide2O3The content of (b) is as follows. If the Ca content is less than 0.0002%, the effect is insufficient. When the Ca content exceeds 0.0100%, a large amount of coarse oxides containing Ca appear, which causes a reduction in rolling fatigue life. For the above reasons, the Ca content should be set to be in the range of 0.0002 to 0.0100%. The lower limit of the Ca content is preferably 0.0003%, and more preferably 0.0005%. The upper limit of the Ca content is preferably 0.0080%, more preferably 0.0060%.
Al:0.001~0.010%
Al as Al2O3The crystallization in steel affects the generation of cracks generated during shot peening and cracks in the raised portion at the periphery of the indentation. Therefore, the Al content needs to be limited to 0.010% or less. The upper limit of the Al content is preferably 0.009%, and more preferably 0.007%. Since the Al content is preferably small, the Al content is preferably 0%. However, since impurities such as a side material used in production are always mixed, the lower limit of the Al content is 0.001%.
O:0~0.005%
O is an element that affects the generation of cracks and cracks in the raised portion during shot peening because it forms an oxide in steel. The O content is limited to 0.005% or less. The upper limit of the O content is preferably 0.003% or less, and more preferably 0.002%. Since the O content is preferably small, the lower limit of the O content is 0%. That is, O may not be contained.
P:0~0.030%
P segregates in austenite grain boundaries during heating before carburizing and quenching, thereby decreasing the fatigue strength. Therefore, the P content needs to be limited to 0.030% or less. The upper limit of the P content is preferably 0.025% or less, and more preferably 0.023%. Since the P content is preferably small, the lower limit of the P content is 0%. That is, P may not be contained. However, if the removal of P is performed more than necessary, the manufacturing cost increases. Therefore, the lower limit of the P content is preferably 0.004%.
In order to improve hardenability or grain refinement effect, the bearing steel member according to the present embodiment may further contain 1 or 2 or more selected from the group consisting of Ni, Cu, Co, W, V, Ti, Nb, and B in place of part of Fe. Namely, the lower limit of the content of these elements is 0%. When these elements are contained, the upper limit of the content of the element is set to the upper limit of the range described later. The content of each element is preferably more than 0% and not more than the upper limit of the range described later, and more preferably in the range described later.
Ni:0.01~3.00%
Ni is an element effective for imparting the necessary hardenability to steel. If the Ni content is less than 0.01%, the effect may be insufficient. Therefore, the Ni content is preferably 0.01% or more. If the Ni content exceeds 3.00%, the retained austenite becomes large after carburizing and quenching, and the hardness may be lowered. For the above reasons, the upper limit of the Ni content is set to 3.00%. The upper limit of the Ni content is preferably 2.00%, and more preferably 1.80%. The lower limit of the Ni content is preferably 0.10%, and more preferably 0.30%.
Cu:0.01~1.00%
Cu is an element effective for improving the hardenability of steel. If the Cu content is less than 0.01%, the effect may be insufficient. Therefore, the Cu content is preferably 0.01% or more. If the Cu content exceeds 1.00%, the hot ductility may be reduced. Therefore, the upper limit of the Cu content is set to 1.00%. The upper limit of the Cu content may be set to 0.50%, 0.30%, or 0.20%. When Cu is contained to obtain the above-described effects, the lower limit of the Cu content is preferably 0.05%, and more preferably 0.10%.
Co:0.01~3.00%
Co is an element effective for improving the hardenability of steel. When the content of Co is less than 0.01%, the effect may be insufficient. Therefore, the Co content is preferably 0.01% or more. If the Co content exceeds 3.00%, the effect may be saturated. Therefore, the upper limit of the Co content is set to 3.00%. The upper limit of the Co content may be set to 1.00%, 0.50%, or 0.20%. When Co is contained to obtain the above-described effects, the lower limit of the Co content is preferably 0.05%, and more preferably 0.10%.
W:0.01~1.00%
W is an element effective for improving the hardenability of steel. When the W content is less than 0.01%, the effect may be insufficient. Therefore, the W content is preferably 0.01% or more. If the W content exceeds 1.00%, the effect may be saturated. Therefore, the upper limit of the W content is set to 1.00%. The upper limit of the W content may be set to 0.50%, 0.30%, or 0.20%. When W is contained to obtain the above-described effects, the lower limit of the W content is preferably 0.05%, and more preferably 0.10%.
V:0.01~0.30%
V is an element which forms a compound with C and N and brings about an effect of refining crystal grains. If the V content is less than 0.01%, the effect may be insufficient. Therefore, the V content is preferably 0.01% or more. If the V content exceeds 0.30%, the compound may become coarse, and the effect of refining crystal grains may not be obtained. Therefore, the upper limit of the V content is set to 0.30%. The upper limit of the V content may be set to 0.20%. When V is contained to obtain the above-described effects, the lower limit of the V content is preferably 0.10%, and more preferably 0.15%.
Ti:0.001~0.300%
Ti is an element that produces fine Ti precipitates such as TiC, (Ti, Nb) C, and TiCS in steel to provide an effect of refining crystal grains. If the Ti content is less than 0.001%, the effect may be insufficient. Therefore, the Ti content is preferably 0.001% or more. If the Ti content exceeds 0.300%, the effect may be saturated. For the above reasons, the content of Ti is set to 0.300% or less. The upper limit of the Ti content is preferably 0.250%, and more preferably 0.200%.
Nb:0.001~0.300%
Nb is an element that produces (Ti, Nb) C in steel and brings about an effect of refining crystal grains. If the Nb content is less than 0.001%, the effect may be insufficient. Therefore, the Nb content is preferably 0.001% or more. If the Nb content exceeds 0.300%, the effect may be saturated. For the above reasons, the content of Nb is set to 0.300% or less. The upper limit of the Nb content is preferably 0.250%, and more preferably 0.200%.
B:0.0001~0.0050%
B has the function of inhibiting the grain boundary segregation of P. B also has an effect of improving grain boundary strength and intra-grain strength and an effect of improving hardenability, which improve the fatigue strength of steel. If the content of B is less than 0.0001%, the effect may be insufficient. Therefore, the B content is preferably 0.0001% or more. If the B content exceeds 0.0050%, the effect may be saturated. For the above reasons, the content of B is set to 0.0050% or less. The upper limit of the B content is preferably 0.0045%, and more preferably 0.0040%.
The chemical composition of the bearing steel member according to the present embodiment may further contain 1 or 2 or more selected from the group consisting of Pb, Bi, Mg, Zr, Te, and rare earth elements (REM) in place of part of Fe. Namely, the lower limit of the content of these elements is 0%. When these elements are contained, the upper limit of the content of the element is set to the upper limit of the range described later. The content of each element is preferably more than 0% and not more than the upper limit of the range described later, and more preferably in the range described later.
Pb:0.01~0.50%
Pb is an element that improves machinability by melting and embrittlement during cutting. If the Pb content is less than 0.01%, the effect may be insufficient. Therefore, the Pb content is preferably 0.01% or more. On the other hand, if the amount is excessively added, the productivity may be lowered. Therefore, the upper limit of the Pb content is set to 0.50%. The upper limit of the Pb content may be set to 0.30%, 0.20%, or 0.10%. When Pb is contained to obtain the above-described effects, the lower limit of the Pb content is preferably 0.02%, and more preferably 0.05%.
Bi:0.01~0.50%
Bi is an element that improves machinability by finely dispersing sulfides. When the Bi content is less than 0.01%, the effect may be insufficient. Therefore, the Bi content is preferably 0.01% or more. On the other hand, if the amount of the metal compound is excessively added, hot workability of the steel may deteriorate, and hot rolling may become difficult. Therefore, the upper limit of the Bi content is set to 0.50%. The upper limit of the Bi content may be set to 0.20%, 0.10% or 0.05%. When Bi is contained to obtain the above-described effects, the lower limit is preferably 0.02%, and more preferably 0.05%.
Mg:0.0001~0.0100%
Mg is a deoxidizing element, and generates oxides in steel. Further, Mg-based oxides formed from Mg tend to form nuclei for crystallization and/or precipitation of MnS. Further, Mg sulfide becomes Mn and Mg complex sulfide to spheroidize MnS. As described above, Mg is an element effective for controlling the dispersion of MnS and improving the machinability. If the Mg content is less than 0.0001%, the effect may be insufficient. Therefore, the Mg content is preferably 0.0001% or more. However, when the Mg content exceeds 0.0100%, MgS is formed in a large amount, and the machinability of the steel may be lowered. Therefore, when Mg is contained to obtain the above-described effects, the upper limit of the Mg content is set to 0.0100%. The upper limit of the Mg content is preferably 0.0080%, and more preferably 0.0050%. The lower limit of the Mg content is preferably 0.0005%, and more preferably 0.0010%.
Zr:0.0001~0.0500%
Zr is a deoxidizing element, and forms an oxide. Further, Zr-based oxides formed from Zr tend to serve as nuclei for crystallization and/or precipitation of MnS. As described above, Zr is an element effective for controlling the dispersion of MnS and improving machinability. When the Zr content is less than 0.0001%, the effect may be insufficient. Therefore, the Zr content is preferably 0.0001% or more. However, if the amount of Zr exceeds 0.0500%, the effect may be saturated. Therefore, when Zr is contained to obtain the above-described effects, the upper limit of the Zr content is set to 0.0500%. The upper limit of the Zr content is preferably 0.0400%, more preferably 0.0100%. The lower limit of the Zr content is preferably 0.0005%, and more preferably 0.0010%.
Te:0.0001~0.1000%
Te promotes spheroidization of MnS, and thus improves machinability of the steel. When the Te content is less than 0.01%, the effect may be insufficient. Therefore, the Te content is preferably 0.01% or more. When the Te content exceeds 0.1000%, the effect may be saturated. Therefore, when Te is contained to obtain the above-described effects, the upper limit of the Te content is set to 0.1000%. The upper limit of the Te content is preferably 0.0800%, and more preferably 0.0600%. The upper limit of the Te content may be set to 0.0100%, 0.0070%, or 0.0050%. The lower limit of the Te content is preferably 0.0005%, and more preferably 0.0010%.
Rare earth elements: 0.0001-0.0050%
The rare earth element promotes the formation of MnS by forming sulfides in the steel and forming nuclei for precipitation of MnS, thereby improving the machinability of the steel. If the total content of the rare earth elements is less than 0.0001%, the effect may be insufficient. Therefore, the total content of the rare earth elements is preferably 0.0001% or more. However, if the total content of the rare earth elements exceeds 0.0050%, sulfides may become coarse, and the fatigue strength of the steel may be reduced. Therefore, when the above-described effects are obtained by containing rare earth elements, the upper limit of the total content of rare earth elements is set to 0.0050%. The upper limit of the total content of the rare earth elements is preferably 0.0040%, and more preferably 0.0030%. The lower limit of the total content of the rare earth elements is preferably 0.0005%, and more preferably 0.0010%.
The rare earth element referred to in the present specification is a general term for 17 elements obtained by adding yttrium (Y) and scandium (Sc) to 15 elements of lanthanum (La) having an atomic number of 57 to lutetium (Lu) having an atomic number of 71 in the periodic table. The content of the rare earth elements means the total content of 1 or 2 or more elements among them.
The chemical composition of the bearing steel member according to the present embodiment may further contain 1 or 2 selected from the group consisting of Sn and In place of a part of Fe. Namely, the lower limit of the content of these elements is 0%. When these elements are contained, the upper limit of the content of the element is set to the upper limit of the range described later. The content of each element is preferably more than 0% and not more than the upper limit of the range described later, and more preferably in the range described later.
Sn:0.01%~2.0%
Sn embrittles ferrite to extend the tool life and improve the surface roughness after cutting. In order to stably obtain this effect, the Sn content is preferably 0.01% or more. In addition, even if Sn is contained in an amount exceeding 2.0%, the effect is saturated. Therefore, when Sn is contained, the Sn content is set to 2.0% or less.
In:0.01%~0.50%
In is an element that improves machinability by melting and embrittlement during cutting. If the In content is less than 0.01%, the effect may be insufficient. Therefore, the In content is preferably 0.01% or more. On the other hand, if the amount is excessively added, the productivity may be lowered. Therefore, the upper limit of the In content is set to 0.50%. The upper limit of the In content may be set to 0.30%, 0.20%, or 0.10%. In the case where In is contained to obtain the above-described effects, the lower limit of the In content is more preferably 0.02%, and still more preferably 0.05%.
The bearing steel member according to the present embodiment contains the above-described alloy components, and the remainder contains Fe and impurities. Elements other than the above alloy components (for example, elements such As Sb, Ta, As, H, Hf, Zn, etc.) are allowed to be mixed As impurities into the steel from the raw materials and the manufacturing apparatus As long As the mixing amount thereof is a level not affecting the properties of the steel.
Here, the bearing steel member according to the present embodiment is a carburized steel bearing steel member subjected to carburizing treatment. The C content of the carburized layer in the rolling surface of the steel bearing steel member is preferably 0.60 to 1.10%, more preferably 0.65 to 1.05%, from the viewpoint of satisfying the conditions of the microstructure described later.
Here, the C content of the carburized layer was set to the average C content at a position from the surface to a depth of 50 μm in the rolling surface of the steel bearing steel member.
(Metal structure)
Next, the metal structure of the bearing steel member according to the present embodiment will be described.
Has a diameter of 5 μm or more for equivalent circle and Al2O3The number density of the oxide having a content of 50 mass% or more will be described.
In order to suppress the occurrence and propagation of cracks and cracks from the raised portion at the periphery of the indentation during shot peening, the inventors used steel materials different in the kind and amount of oxides and investigated the relationship between the oxides and the life of the pressure mark.
First, the influence of the kind and amount of the oxide species constituting the oxide was examined. The results are known as follows: among the various oxidizing species present in steel, Al2O3CaO and SiO2The ratio of (A) has an influence on the life of the pressure-resistant mark, Al2O3The content ratio with respect to the total mass of these 3 oxides is closely related to the indentation life. That is, it is known that Al is contained even in the oxide2O3CaO and SiO2Oxides other than Al2O3Relative to Al2O3CaO and SiO2The content of the total mass of (2) is also closely related to the life of the pressure mark.
Next, the shape and number of oxides affecting the lifetime of the withstand voltage trace were examined. The results are known as follows: the number density of oxides having an equivalent circle diameter of 5 μm or more is correlated with the lifetime of the pressure mark. Therefore, Al greatly affects the life of the dielectric breakdown voltage2O3The content of (2) and the number density of oxides having an equivalent circle diameter of 5 μm or more are plotted on the vertical axis and the horizontal axis, respectively, and the results show that: has an equivalent circle diameter of 5 μm or more andAl2O3has a number density of 3.0 oxides/cm and a content of (2)2The following region gives a good indentation life, and the indentation life decreases as the region deviates from this region.
This is presumably because the equivalent circle diameter is controlled to 5 μm or more and Al is contained2O3The content of (2) is 50 mass% or more, and "fine cracks generated at the time of shot peening" and "cracks generated at the ridge portion" caused by fine inclusions at a level that cannot be discriminated by an optical microscope can be made harmless.
Further, the equivalent circle diameter is 5 μm or more and Al2O3Has a content of at least 50 mass% and has a number density of 3.0 oxides/cm2No cracks were observed in the following bearing steel parts, and good indentation resistance life was obtained. Therefore, the upper limit of the number density of the oxide is set to 3.0 pieces/cm2。Al2O3The upper limit of the number density of the oxide having a content of (3) or more is preferably 2.0 pieces/cm2More preferably 1.5 pieces/cm2. The oxide is preferably not present, so the lower limit is 0/cm2
The number density of the oxide is determined by selecting the field of view [ examples]The value measured by the method described in (1). The total of 4cm can be ensured as long as the area of the observation part of the cut surface of the observation visual field can be ensured2And (4) finishing.
Next, the Vickers hardness at a depth of 50 μm from the rolling surface will be described.
When the surface hardness is reduced, the raised portion at the periphery of the indentation is crushed, and therefore the life of the pressure mark can be improved. Therefore, in order to maintain the rolling contact fatigue life other than the service life of the pressure marks, a bearing steel member generally used for automobile applications is required to have a hardness of about 750 in terms of vickers hardness. Accordingly, the hardness of the surface, i.e., the vickers hardness at a depth of 50 μm from the rolling surface, needs to be 750 or more. However, since the vickers hardness becomes brittle when it becomes too high, 1050 should be set to the upper limit. The upper limit of vickers hardness is preferably 1000, and more preferably 950.
The vickers hardness is a value measured by the method described in [ example ] except for the cut position. The cutting position differs depending on the shape of the member, and may be a cross section cut perpendicular to the surface of the rolling portion.
Next, the compressive residual stress of the rolling surface will be described.
The compressive residual stress of the rolling surface has an effect of suppressing crack generation from the raised portion at the periphery of the indentation to improve the life of the pressure mark. In order to obtain this effect, the compressive residual stress of the rolling surface needs to be 900MPa or more. The higher the compressive residual stress of the rolling surface is, the more preferable it is, but in order to excessively increase the compressive residual stress, severe working such as increasing the projection pressure at the time of shot peening becomes necessary, and the shape of the member changes and becomes non-functional. Therefore, the upper limit of the compressive residual stress of the rolling surface is 2000 MPa.
The compressive residual stress is a value measured by the method described in [ example ].
Next, the metal structure of the bearing steel member will be described.
The bearing steel member according to the present embodiment is obtained by, for example, carburizing, quenching, and tempering.
Therefore, the metal structure of the bearing steel member is composed of, for example, a surface layer portion (i.e., carburized layer) carburized to have a gradient of C concentration and a core portion having the same C concentration as the base material before carburization.
The microstructure of the surface layer portion (i.e., carburized layer) includes tempered martensite, retained austenite, and the remainder (bainite, ferrite, cementite, and the like).
On the other hand, the microstructure of the core portion may be a microstructure including tempered martensite and the remainder (bainite, ferrite, pearlite, and the like).
The metal structure of the core part was located further inward than the depth of 2.00mm from the surface of the steel bar for bearing steel members.
(Steel bar for bearing Steel Member)
The steel bar for a carburized bearing steel member according to the present embodiment (hereinafter, also referred to as "steel bar for a bearing steel member") suitable for obtaining a bearing steel member according to the present embodiment is as follows.
The steel bar for bearing steel members according to the present embodiment has the same chemical composition as the steel bar for bearing steel members according to the present embodiment, and has an equivalent circle diameter of 5 μm or more and contains CaO and Al in any cross section of the steel bar2O3And SiO2And Al2O3Relative to CaO and Al2O3And SiO2Has a content of 50 mass% or more of an oxide of 3.0 pieces/cm2The following.
The method for measuring the number density of oxides is the same as the method for measuring the number density of oxides in the bearing steel member according to the present embodiment.
The microstructure of the steel bar for bearing steel components according to the present embodiment includes ferrite as a main component (for example, 60% or more in area ratio) and pearlite, bainite, and the remainder.
The metal structure of the steel bar for bearing steel member was located inside the steel bar for bearing steel member at a depth of 2.00mm from the surface of the steel bar.
(method of manufacturing bearing Steel Member)
Next, a method for manufacturing a bearing steel member according to the present embodiment will be described.
The bearing steel member having the above-described metal structure is preferably produced as follows, for example.
First, a raw material using an iron ore or a scrap base is primarily refined in a converter. Si is added to molten steel tapped from a converter, and then Al is added to the molten steel to perform deoxidation treatment. After the deoxidation treatment, the molten steel composition is adjusted to the molten steel composition having the above chemical composition by secondary refining by a ladle refining method or a refining method using a vacuum processing apparatus. Mixing the componentsThe whole molten steel is continuously cast to be made into a steel ingot. By controlling the refining method, the number density of the oxides can be controlled. In the case where only Al deoxidation is performed, for example, even if Si is contained as a chemical component, and even if SiO is contained in the flux to be added2,SiO2The components are not mixed into the oxides as inclusions. This is due to the reduction on Si or SiO2And (4) playing a role.
Wherein, when casting, the molten steel in the tundish is overheated by 5-200 ℃ and is electromagnetically stirred in the casting mould.
Next, the steel ingot was cogging, hot-rolled to be processed into a predetermined cross-sectional shape, and then cooled to obtain a steel bar for a bearing steel member. The cooling rate after hot rolling is preferably controlled to be in the range of 0.1 to 5 ℃/sec based on the average cooling rate of the steel surface temperature of 800 to 300 ℃.
Next, the obtained steel bar for bearing steel parts is hot forged, cold forged, machined, etc. to obtain a part shape to which the components removed by grinding are added, and carburized, quenched, and tempered. In order to improve the efficiency of forging or machining, heat treatment such as normalizing or spheroidizing annealing may be performed during this period. Further, carburizing and quenching can be performed by a carburizing method such as gas carburizing or vacuum carburizing. Tempering may also be performed under reduced pressure, or a non-oxidizing atmosphere. The mechanical processing can also be carried out after carburizing, quenching and tempering.
Then, the processed product is subjected to shot peening. Thereafter, polishing is performed to ensure dimensional accuracy. When a predetermined dimensional accuracy can be secured after the shot peening treatment, the polishing step may be omitted. By manufacturing the bearing steel member in this manner, the above-described metal structure can be obtained.
Examples
Next, examples of the present disclosure will be described, but the conditions in the examples are only one conditional example adopted for confirming the feasibility and the effects of the present disclosure, and the present disclosure is not limited to this conditional example. As long as the object of the present disclosure is achieved without departing from the gist of the present disclosure, various conditions may be adopted in the present disclosure.
Various steel ingots having chemical compositions shown in table 1 were hot-rolled to obtain steel rods. Then, the bar steel was hot forged to a diameter of 28 mm. The heating temperature before forging was set to 1250 ℃. Steel grade 25 is SUJ2 defined in JIS for general bearing steel, and only steel grade 25 differs in heat treatment conditions. Except for steel No.25, the forged product was subjected to normalizing treatment under the condition of keeping at 950 ℃ for 1 hour, completely austenitizing, and then cooling. Steel No.25 was heated at 960 ℃ and normalized. Subsequently, the steel sheet was held at 795 ℃ for 1.5 hours, and then cooled to 650 ℃ at 12 ℃/min and then left to cool, thereby spheroidizing annealing was performed on the annealed product.
Then, the resulting material was processed into a cylinder having a diameter of 12.2mm by 150 mm. Then, the cylindrical product was held at 930 ℃ for 5 hours in an atmosphere of 0.8 carbon potential except for steel grade 22, subjected to gas carburizing treatment under the condition of oil quenching at 130 ℃, and then tempered under the condition of holding at 150 ℃ for 2 hours. Steel No.25 was quenched under the condition of being held at 830 ℃ for 0.5 hour in an argon atmosphere and being cooled with oil at 60 ℃ and then tempered under the condition of being held at 180 ℃ for 2 hours.
Then, the tempered cylinder products of the obtained steel grades 1 to 24, 26 to 33, and 35 to 36 were subjected to shot peening according to Table 2. The shot peening A was performed for Nos. 1 to 24 and 26 to 33, the shot peening B was performed for No.35, and the shot peening C was performed for No. 36. No.25 and No.34 were not shot-peened.
In this manner, a sample of the bearing steel member was obtained.
< shot peening A >
Pellets: steel Round Cut Wire phi 1.0, HV800
Projection pressure: 0.5MPa
Coverage rate: 400 percent
< shot peening B >
Pellets: steel Round Cut Wire phi 1.0, HV800
Projection pressure: 0.3MPa
Coverage rate: 200 percent of
< shot peening C >
Pellets: steel Round Cut Wire phi 1.0, HV600
Projection pressure: 0.2MPa
Coverage rate: 200 percent of
Thereafter, the bearing steel member sample was processed by grinding and finished by lapping to obtain a cylindrical rolling fatigue test piece having outer dimensions of phi 12mm × 22mm shown in FIG. 1. Then, evaluation of the withstand voltage mark life was performed. For evaluation of the pressure mark life, an NTN cylindrical rolling fatigue tester was used. The details are as follows.
First, at 530kgf/mm2Was held at 46240rpm, including the acceleration time, for 10 seconds under load, and the positions of the indentations in the test piece were marked. Indentations were made at 4 every 90 degrees using a rockwell hardness tester at the marked locations. Thereafter, at 600kgf/mm2Under load, JX Nippon Oil was used as the lubricating Oil&FBK TURBINE ISO viscosity grade 56 from Energy Corporation, detection of peel initiation with a vibrometer at 46240rpm, at 107The upper limit is the measured peeling life. The peel life obtained with N ═ 10 was plotted on a Weibull (Weibull) line graph, and the life at 10% breakage was set as the lifetime of the pressure mark. The rolling fatigue life other than the life of the pressure mark was 10 in a state where no indentation was provided8The upper limit is N2, and the average value is set as the rolling fatigue life.
The Vickers hardness was measured at a depth of 50 μm from the rolling surface as follows. A cross section obtained by cutting a cylindrical rolling fatigue test piece perpendicularly to the longitudinal direction at a position corresponding to the test execution of the test specimen, i.e., at a position of about 7mm from the end face, was measured in accordance with JIS Z2244: 2009 is measured using a micro vickers hardness tester. Specifically, the Vickers hardness was determined by measuring the hardness at a depth of 50 μm from the rolling surface at 5 points 150 μm apart in terms of the distance between the centers of the dimples under a load of 200g and a holding time of 10 seconds, and by performing the sum-average of the measured values.
the compressive residual stress on the rolling surface was measured by covering the cylindrical rolling fatigue test piece so that the range of 2mm × 2mm could be measured with the position of the cylindrical rolling fatigue test piece from the end face of about 7mm as the center, and using an Automate (using a Cr bulb) made by a scientific electric system with respect to the range of 2mm × 2mm, the collimator φ 1mm was set to pass through 2 θ sin2The compression residual stress of the rolling surfaces was measured by the psi Method and the isocline Method (Iso-incorporation Method).
An equivalent circle diameter of 5 μm or more and Al2O3the number density of oxides having a content of 50 mass% or more was measured by cutting the cylindrical rolling fatigue test piece at positions 3, 7, 15, 19mm from the end face in the longitudinal direction, mirror-polishing the cut surface of each test piece with a diamond paste, observing a region of 1cm × 1cm set so that the center of the circle coincides with the center of the square in the cut surface of each test piece with an optical microscope, recording the position of an inclusion having an equivalent circle diameter of 5 μm or more, analyzing a spectrum obtained by analyzing the entire inclusion region with an energy dispersion type X-ray analyzer (EDS) mounted on a scanning electron microscope (JSM-6500F, manufactured by japan electronics), and determining oxides, sulfides, and carbonitrides, wherein the acceleration voltage was set to 20keV at the time of analysis, and the measurement was performed for 10 seconds in each region, and the analysis and quantification of the spectrum were performed with the analysis and quantification software analysis by japan electronics system.
For inclusions judged as oxides, the mass ratio of 3 elements of Ca, Al, and Si other than oxygen was determined, and the calculated mass ratio was converted into oxides (i.e., CaO and Al) generated by each of the 3 elements2O3And SiO2) To thereby calculate Al2O3Relative to CaO and Al2O3And SiO2The content of (2) in total mass is calculated by Al2O3The content of (2) is 50 mass% or more, divided by the observed area of 4cm2(observation of 1cm × total observation area of 4 visual fields) and the number density was calculated.
The measurement results were obtained by the same methodThe "equivalent circle diameter" of the steel bar before forging is 5 μm or more and Al2O3The content of (b) is 50 mass% or more of the number density of the oxide.
The method for measuring the C content of the carburized layer of the rolling surface will be described. In a cross section obtained by cutting a cylindrical rolling fatigue test piece at a position corresponding to the test execution of the test specimen, that is, at a position of about 7mm from the end face, perpendicular to the longitudinal direction, the C content of the carburized layer was set by measuring the concentration distribution of C in the depth direction at a 5 μm pitch using EPMA and JXA-8200 manufactured by japan electronics co, and by taking the sum average of the concentrations at a distance of 50 μm from the surface on the rolling surface (that is, the sum average of the concentrations measured at a distance of 5 μm from the surface to 50 μm from the surface as the measurement start point) as the C content of the carburized layer. The size of the measurement point (the electron beam diameter of EPMA) was set to 5 μm.
Table 2 shows that the equivalent circle diameter of each steel type of the test piece is 5 μm or more and Al2O3The content of (a) is 50 mass% or more of the number density of oxides (in the table, the "number density of oxides"), the vickers hardness (in the table, the "surface hardness") at a depth of 50 μm from the rolling surface, the compressive residual stress of the rolling surface, the life of a pressure mark, and the rolling fatigue life. In addition, the C content of the carburized layer is also shown.
In the table, the mark of "10 ^ X" means "10 ^ XX". For example, "10 ^ 6" means "106”。
The underlined values in tables 1 and 2 indicate values outside the range of the present disclosure. The open columns of the chemical composition of table 1 indicate that the elements corresponding to the open columns are not intentionally added.
Figure BDA0002580673630000221
TABLE 2
Figure BDA0002580673630000231
The underlined values indicate values outside the scope of the disclosure.
The samples Nos. 1 to 24 of the publication show good indentation resistance life and rolling fatigue life while maintaining the Vickers hardness at a depth of 50 μm from the rolling surface at a level equivalent to that of a general bearing steel member (Vickers hardness of 750 or more).
Comparative example No.25 is SUJ2 which is commonly used because of its chemical component content, equivalent circle diameter of 5 μm or more and Al2O3The number density of oxides and the compressive residual stress of rolling surfaces with a content of 50 mass% or more are outside the predetermined ranges of the present disclosure, and since no carburizing treatment is performed, both the indentation resistance life and the rolling fatigue life are reduced.
The samples Nos. 26, 27, 30 to 32 of comparative examples had chemical component contents and equivalent circle diameters of 5 μm or more and Al2O3Has a content of 50 mass% or more, is out of the range specified in the present disclosure, and therefore has only a low withstand voltage mark life.
The comparative examples nos. 28 and 29 had a low rolling fatigue life because the chemical component contents were outside the predetermined ranges of the present disclosure and the vickers hardness at a depth of 50 μm from the rolling surface was low even if the appropriate shot peening treatment was performed.
The comparative example No.33 had only a low withstand voltage mark life because the content of the chemical component was outside the specified range of the present disclosure.
Since No.34 of the comparative example was not subjected to the shot peening treatment, the vickers hardness at a depth of 50 μm from the rolling surface and the compressive residual stress of the rolling surface were out of the predetermined ranges of the present disclosure, and as a result, both the indentation life and the rolling fatigue life were reduced.
In comparative example No.35, the shot peening treatment was performed at a low projection pressure and a low coverage, and the compressive residual stress on the rolling surface was outside the predetermined range of the present disclosure, and therefore, the life of the pressure mark was low.
In comparative example No.36, the hardness, projection pressure and coverage of the shot in the shot peening treatment were low, and the vickers hardness at a depth of 50 μm from the rolling surface and the compressive residual stress of the rolling surface were out of the predetermined ranges of the present disclosure, and therefore, both the indentation resistance life and the rolling fatigue life were low.
It is found that a steel bar having the chemical components shown in steel nos. 1 to 24 can be subjected to an appropriate shot peening treatment to obtain a bearing steel member having a surface hardness maintained at a level equivalent to that of a general bearing steel member and having an excellent fracture life, and therefore, the steel bar is suitable for obtaining the bearing steel member.
It is to be noted that the disclosure of japanese patent application No. 2018-008181 is incorporated by reference in its entirety into the present specification.
All documents, patent applications, and technical specifications described in the present specification are incorporated by reference into the present specification to the same extent as if each document, patent application, and technical specification was specifically and individually described.

Claims (7)

1. A carburized bearing steel component, wherein a chemical composition further inside than a depth of 2.00mm from a surface of the carburized bearing steel component comprises, in mass%:
C:0.15~0.25%、
Si:0.70~1.50%、
Mn:0.40~1.50%、
Cr:0.15~1.50%、
Mo:0.001~0.150%、
S:0.001~0.030%、
N:0.004~0.020%、
Ca:0.0002~0.0100%
Al:0.001~0.010%、
O:0~0.005%、
P:0~0.030%、
Ni:0~3.00%、
Cu:0~1.00%、
Co:0~3.00%、
W:0~1.00%、
V:0~0.30%、
Ti:0~0.300%、
Nb:0~0.300%、
B:0~0.0050%
Pb:0~0.50%、
Bi:0~0.50%、
Mg:0~0.0100%、
Zr:0~0.0500%、
Te:0~0.1000%、
rare earth elements: 0 to 0.0050%,
Sn:0~2.0%、
In: 0 to 0.50%, and
the rest is as follows: consists of Fe and impurities, and the Fe-Fe alloy consists of Fe and impurities,
in any cross section of the member, the equivalent circle diameter is 5 μm or more, and CaO and Al are contained2O3And SiO2And said Al2O3With respect to the CaO and the Al2O3And the SiO2Has a content of 50 mass% or more of an oxide of 3.0 pieces/cm2In the following, the following description is given,
a Vickers hardness of 750 or more at a depth of 50 μm from the rolling surface,
the compressive residual stress of the rolling surface is 900MPa or more.
2. The carburized bearing steel component according to claim 1, wherein a chemical composition further inside than a depth of 2.00mm from a surface of the carburized bearing steel component contains, in mass%:
Ni:0.01~3.00%、
Cu:0.01~1.00%、
Co:0.01~3.00%、
W:0.01~1.00%、
V:0.01~0.30%、
Ti:0.001~0.300%、
nb: 0.001 to 0.300% and
b: 0.0001-0.0050% of 1 or more.
3. The carburized bearing steel component according to claim 1 or claim 2, wherein the chemical composition further inside than the depth of 2.00mm from the surface of the carburized bearing steel component contains, in mass%:
Pb:0.01~0.50%、
Bi:0.01~0.50%、
Mg:0.0001~0.0100%、
Zr:0.0001~0.0500%、
Te:0.0001~0.1000%、
rare earth elements: 0.0001-0.0050% of 1 or more.
4. A carburized bearing steel component according to any one of claims 1 to 3, wherein a C content of a carburized layer in a rolling surface is 0.60 to 1.10% by mass%.
5. A steel bar for a carburized bearing steel component, characterized in that it contains, in mass%:
C:0.15~0.25%、
Si:0.70~1.50%、
Mn:0.40~1.50%、
Cr:0.15~1.50%、
Mo:0.001~0.150%、
S:0.001~0.030%、
N:0.004~0.020%、
Ca:0.0002~0.0100%
Al:0.001~0.010%、
O:0~0.005%、
P:0~0.030%、
Ni:0~3.00%、
Cu:0~1.00%、
Co:0~3.00%、
W:0~1.00%、
V:0~0.30%、
Ti:0~0.300%、
Nb:0~0.300%、
B:0~0.0050%
Pb:0~0.50%、
Bi:0~0.50%、
Mg:0~0.0100%、
Zr:0~0.0500%、
Te:0~0.1000%、
rare earth elements: 0 to 0.0050%,
Sn:0~2.0%、
In: 0 to 0.50%, and
the rest is as follows: consists of Fe and impurities, and the Fe-Fe alloy consists of Fe and impurities,
in any cross section of the steel bar, the equivalent circle diameter is 5 μm or more, and CaO and Al are contained2O3And SiO2And said Al2O3With respect to the CaO and the Al2O3And the SiO2Has a content of 50 mass% or more of an oxide of 3.0 pieces/cm2The following.
6. The steel bar for a carburized bearing steel component according to claim 5, wherein the chemical composition in the inner portion of the steel bar for a carburized bearing steel component relative to a depth of 2.00mm from the surface thereof contains, in mass%:
Ni:0.01~3.00%、
Cu:0.01~1.00%、
Co:0.01~3.00%、
W:0.01~1.00%、
V:0.01~0.30%、
Ti:0.001~0.300%、
nb: 0.001 to 0.300% and
b: 0.0001-0.0050% of 1 or more.
7. The steel bar for a carburized bearing steel component according to claim 5 or 6, wherein the chemical composition in the inner portion of the depth of 2.00mm from the surface of the steel bar for a carburized bearing steel component contains, in mass%:
Pb:0.01~0.50%、
Bi:0.01~0.50%、
Mg:0.0001~0.0100%、
Zr:0.0001~0.0500%、
Te:0.0001~0.1000%、
rare earth elements: 0.0001-0.0050% of 1 or more.
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