CN111579599A - CO distributed in network2Online continuous detection system and detection method - Google Patents
CO distributed in network2Online continuous detection system and detection method Download PDFInfo
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Abstract
The invention relates to a network distributed CO2An on-line continuous detection system and a detection method. Comprising a plurality of diffusing CO2Detection node arranged on surface or underground shallow layer for detecting CO in soil2The gas concentration transmits a detection signal to the node controller through a signal wire; node controller, and diffusion CO2The detection nodes are in one-to-one correspondence and are diffusion type CO2The detection node provides power and diffuses CO2The detection signal sent by the detection node is transmitted to a remote monitoring terminal through a wireless network; the monitoring terminal is in wireless communication with the node controller, receives the data transmitted by the node controller, displays and stores the data, and processes and analyzes the received data to discriminate the diffusion CO2Detecting CO detected by a node2Whether there is an abnormal change in the gas concentration. The invention can continuously monitor CO in real time in large area2The concentration of the gas is changed, the original state of the measured gas is not influenced, the detection accuracy is improved, and the method has the advantages of spatialization of CO2The concentration analysis function and the analysis result are more reliable.
Description
Technical Field
The invention relates to the field of gas concentration analysis and detection, in particular to CO distributed in a network manner2An on-line continuous detection system and a detection method.
Background
Carbon dioxide is abundant in nature and is one of the important constituents of the atmosphere. With the rapid development of industrialization process, CO in the atmosphere2The concentration is increasing, which brings about many negative effects on global climate, ecological environment and human health. The method is divided into atmospheric monitoring, surface monitoring and stratum monitoring according to different gas monitoring positions. The atmospheric monitoring is developed more mature mainly aiming at the fields of environmental pollution, industrial safety and the like, and the detection method comprises a gas chromatography method, an electrochemical method, a contact combustion method and an infrared spectrum absorption method. The gas chromatography and the infrared spectrum absorption method are detection methods which are widely applied, but the gas chromatography is limited by the defect of low measurement efficiency and cannot realize continuous measurement, the infrared spectrum absorption method utilizes gas to enter a sensor for detection, has the advantages of high sensitivity and continuous and rapid measurement, but has the defect that the original state of the measured gas can be damaged to a certain extent by forced air exhaust in the detection process, and meanwhile, the setting of an air pump, a temperature control device and the like greatly increases the system power consumption and increases the difficulty for field long-time measurement.
With the application of CCS technology and the progress of deep earth exploration, CO2The surface monitoring and the stratum monitoring become a monitoring technology hotspot gradually. Monitoring CO in a region2The migration condition of the sensor not only needs an accurate concentration detection technology, but also needs a networked and automatic monitoring system, and needs to meet the requirements of no interference and low power consumption, and certain difficulty exists.
Disclosure of Invention
In order to solve the technical problem, the invention provides a CO distributed in a network manner2The online continuous detection system and the detection method can continuously monitor the surface and the underground shallow layer CO in a large area in real time2The concentration of (a) is varied,the method does not affect the original state of the measured gas, improves the accuracy and reliability of detection, realizes networked and automatic detection, has less interference and low power consumption, and has spatialization CO2The concentration analysis function, the analysis result is more reliable and visual.
The technical problem of the invention is mainly solved by the following technical scheme: the invention relates to a network distributed CO2An on-line continuous detection system comprising:
multiple diffusion type CO2Detection node arranged on surface or underground shallow layer for detecting CO in soil2The gas concentration transmits a detection signal to the node controller through a signal wire;
node controller, and diffusion CO2The detection nodes are in one-to-one correspondence and are diffusion type CO2The detection node provides power and diffuses CO2The detection signal sent by the detection node is transmitted to a remote monitoring terminal through a wireless network;
the monitoring terminal is in wireless communication with the node controller, receives the data transmitted by the node controller, displays and stores the data, and processes and analyzes the received data to discriminate the diffusion CO2Detecting CO detected by a node2Whether there is an abnormal change in the gas concentration.
The technical scheme forms a networked monitoring system with a plurality of monitoring points, and can continuously monitor the surface and the underground shallow layer CO in a large area in real time2The concentration change realizes the networking and automatic detection, and has the spatialization CO2The concentration analysis function, the analysis result is more reliable and visual.
Preferably, the diffusive CO2The detection node is a detection rod, a double-channel structure sensor is arranged at the head of the detection rod, a detection circuit is arranged behind the double-channel structure sensor and is connected with the double-channel structure sensor through a probe, and the detection circuit is connected with the node controller through a plurality of strands of shielding signal wires. The double-channel structure sensor is provided with two detection channels which are respectively used for arranging a gas sensitive element and a reference element. Gas sensor for adsorbing CO2Gas, reference elementThe temperature and humidity sensor is used for inhibiting the drift of the temperature and humidity to the detection signal, thereby improving the accuracy and reliability of detection. The sensing signal of the sensor with the double-channel structure is transmitted to a detection circuit, filtered, mixed and difference-frequency analyzed by the detection circuit, and then processed by a digital signal processing circuit to output CO2And the concentration is transmitted to the node controller through a signal wire. The technical proposal does not need an air pump and a temperature control device, and CO in the soil2The gas automatically escapes to cause the sensor with a double-channel structure at the head of the detection rod, so that the original state of the measured gas is not influenced, the interference is less, and the power consumption is low.
Preferably, the dual-channel structure sensor comprises a piezoelectric layer, two interdigital electrodes are arranged on the piezoelectric layer side by side, one interdigital electrode is coated with a gas-sensitive film to form a gas-sensitive element, and the gas-sensitive film is MWCNTs/SnO2The two interdigital electrodes are respectively positioned in two detection channels of the two-channel structure sensor. The interdigital electrode coated with the gas-sensitive film is a gas-sensitive element, and the other interdigital electrode is a reference element. MWCNTs to CO in gas-sensitive films2Gas has strong adsorbability and is a good conductor, SnO2Is an oxide which is common in a gas sensitive film, has obvious physical response to gas, has gas-sensitive conductivity better than that of a metal oxide but has poor linearity, and thus, the oxide can be used for preparing a gas-sensitive material by SnO2/polymer composite enhanced gas-sensitive film for CO2The gas is linearly responded, and the MWCNTs are used for functionalizing the composite film, so that the adsorbability and the conductivity of the gas-sensitive film are increased, and the response working frequency of a gas-sensitive element is improved. Mixing the MWCNTs polymer solution with SnO2 powder, fully mixing SnO2 with the MWCNTs polymer solution through ultrasonic stirring, controlling the air injection amount to spray the MWCNTs/SnO 2/polymer on an interdigital electrode, and finally performing vacuum drying at 80 ℃ to remove the solvent.
Preferably, the front end of the detection rod is covered with a layer of hydrophobic breathable film, namely, the air inlet of the dual-channel structure sensor is covered with a layer of hydrophobic breathable film, the hydrophobic breathable film is a microporous PTFE hydrophobic filter film, and a distance is reserved between the interdigital electrode and the hydrophobic breathable film. The hydrophobic breathable film is used for blocking water and dust in soil and preventing the gas sensitive element from being damaged due to direct contact with the water or the dust.
Preferably, the piezoelectric layer is made of diamond-like BN, and the interdigital electrodes comprise SnO2The thin film layer and the Au thin film layer are formed by double-layer plating. Diamond-like BN not only has good piezoelectric properties, but also absorbs little water vapor and causes no noise in the signal response process.
Preferably, the node controller comprises a power module and a GPRS communication module, the power module comprises a solar cell panel, a storage battery and a power voltage stabilizing chip which are sequentially connected, and the output end of the power voltage stabilizing chip and the diffusion type CO are connected2The detection nodes are connected, and the GPRS communication module is used for diffusing CO2And the detection signal sent by the detection node is transmitted to a remote monitoring terminal through a GPRS wireless network. The solar cell panel is adopted, so that the solar cell panel is suitable for being installed and used in the field and is convenient for continuous detection.
The invention relates to a network distributed CO2The detection method of the on-line continuous detection system comprises the following steps: according to CO2To the diffused CO2The detection nodes are distributed, and the node controller is fixed on the ground surface and is a diffusion type CO2The detection node provides power supply power and CO in the soil2Free escape of gas to diffusion CO2In a two-channel structure sensor for detecting nodes, CO2Gas contacts a gas sensitive element in the dual-channel structure sensor, a gas sensitive film on the gas sensitive element is physically changed to cause phase change of an interdigital electrode, a changed signal is transmitted to a detection circuit through a probe, the detection circuit transmits a detection signal to a node controller after processing, and the node controller transmits detected CO to a node controller through a wireless network2Transmitting the gas concentration data to the monitoring terminal, and the monitoring terminal transmits all the diffused CO2Detecting CO measured by a node2The gas concentration is stored and analyzed, and the monitoring terminal is used for storing and analyzing the same diffused CO2The concentrations of the detection nodes measured at different times form a group, and the concentration is measured for single diffusion type CO2The concentration measured in a period of time at the detection node is subjected to normal distribution test toAnd performing sliding variance analysis on every 10 concentration data serving as a data segment, then finding out the data segment with obvious difference by using F statistic, thereby finding out a time segment with the maximum concentration change in a group, and if the concentration variance in the time segment is greater than a set threshold, displaying an analysis result by the monitoring terminal and sending alarm information.
The invention has the advantages of spatialization of CO2The concentration analysis function, the analysis result is more reliable and directly perceived, possesses unusual alarming function simultaneously, is convenient for the staff in time to pay close attention to and make the processing.
The invention has the beneficial effects that: can be used for CO in a larger area2Continuously monitoring the change of gas concentration by square difference analysis and normal distribution test to determine CO in the region2The condition of gas concentration change alarms and reminds abnormal points, and the problem of existing wide-area gas concentration monitoring analysis dispersion is solved. The invention takes a surface acoustic wave dual-channel sensor as diffusion type CO2The core of the detection node is a sensor prepared by an oxide composite film and an oxide-polymer composite gas-sensitive film, the sensor takes diffused gas induction and shallow buried soil as detection modes, water and dust are filtered by a hydrophobic breathable film, detection is not required to be carried out by air suction, the gas balance state of a detection environment is not damaged, continuous real-time detection can be carried out, time recovery is not required, the sensitivity of a gas-sensitive element of the sensor is high, and the requirements of low cost, long distance and wide-range detection are met.
Drawings
FIG. 1 is a schematic diagram of a system connection structure according to the present invention.
Fig. 2 is a schematic diagram of a dual channel structure sensor according to the present invention.
FIG. 1. diffusion type CO2The system comprises a detection node, 2 a node controller, 3 a monitoring terminal, 4 a dual-channel structure sensor, 5 a detection circuit, 6 a piezoelectric layer, 7 an interdigital electrode, 8 a gas sensitive element, 9 a reference element, 10 a hydrophobic and breathable film, 11 a power supply module and 12 a GPRS communication module.
Detailed Description
The technical scheme of the invention is further specifically described by the following embodiments and the accompanying drawings.
Example (b): a networked distributed CO of the present embodiment2An on-line continuous detection system, as shown in FIG. 1, includes a plurality of diffusive COs2Detection node 1 and diffusion type CO2The node controllers 2 connected with the detection nodes in a one-to-one correspondence manner and the monitoring terminals 3 in wireless communication with all the node controllers. The diffusion type CO2 detection node is buried in shallow soil on the earth surface, can be buried to a depth not more than 5m and is used for detecting CO in soil2The gas concentration. A node controller arranged on the ground surface and connected with the diffusion type CO through a plurality of signal screen lines2The detection nodes are connected. The node controller is, on the one hand, a diffusion CO2The detection node provides power and receives diffused CO2And detecting a detection signal sent by the node, and transmitting the detection signal to a remote monitoring terminal through a wireless network. The monitoring terminal receives the data transmitted by the node controller, displays and stores the data, and processes and analyzes the received data to discriminate the diffusion CO2Detecting CO detected by a node2Whether there is an abnormal change in the gas concentration.
The diffusion type CO2 detection node 1 is a detection rod, the whole detection rod is a cylinder with the length of 30mm and the diameter of the bottom surface of 30mm, the head of the detection rod is provided with a dual-channel structure sensor 4, and the detection rod is in contact with CO in soil2 A detection circuit 5 is installed behind the double-channel structure sensor, the detection circuit is connected with the double-channel structure sensor through a probe, and the detection circuit is connected with the node controller through a plurality of strands of shielding signal wires with the length of 5 meters. CO22The oscillation signal of the sensor changes due to the change of gas concentration, and CO is output after being processed by a digital signal processing circuit through filtering, mixing and difference frequency analysis in a detection circuit2And the concentration data is transmitted to the node controller through a signal wire. As shown in figure 2, the dual-channel structure sensor comprises a piezoelectric layer 6, the piezoelectric layer is made of diamond-like BN, the thickness of the piezoelectric layer is 2.2-2.5 mm, two interdigital electrodes 7 which are arranged side by side are arranged on the piezoelectric layer, the width of each interdigital electrode is 50-100 micrometers, the number of pairs of interdigital electrodes is 60-80, and SnO is adopted as the interdigital electrodes2And AuComposite film material of SnO2The thin film is combined with the piezoelectric layer and then covered by an Au thin film to increase the bonding force between the Au electrode and the piezoelectric layer, wherein SnO2The film thickness is 200nm, the Au film thickness is 500nm, and the interdigital electrode is formed by photoetching after double-layer plating by a vacuum ion plating method. One of the interdigital electrodes is coated with a gas-sensitive film through a spraying process to form a gas-sensitive element 8, wherein the gas-sensitive film is MWCNTs/SnO2A polymer sensitive film with a gas-sensitive film thickness of 100nm, a gas-sensitive element based on the surface acoustic wave detection principle, and a gas-sensitive film for adsorbing CO2And the other interdigital electrode is used as a reference element 9 for inhibiting the temperature and humidity from drifting on a detection signal. The two interdigital electrodes are respectively positioned in two detection channels of the two-channel sensor, and the interdigital electrode lead-out probe is connected with the detection circuit. The front end of the detection rod is covered with a layer of hydrophobic breathable film 10, namely, the air inlet of the dual-channel structure sensor is covered with a layer of hydrophobic breathable film, the hydrophobic breathable film is a microporous PTFE hydrophobic filter film and is used for blocking water and dust in soil and preventing a gas sensitive element from being directly contacted with the water or the dust to cause damage, and the interdigital electrode coated with the gas sensitive film and the hydrophobic breathable film are separated by 1 mm. The hydrophobic breathable film and the gas sensitive element are encapsulated by PDMS. When CO2 gas contacts the surface of the gas sensitive element through the hydrophobic breathable film, the gas sensitive film adsorbs CO2, the conductive characteristic of the gas sensitive film changes, the reflection coefficient of the interdigital electrode changes, the phase of the interdigital electrode exciting the surface acoustic wave changes, and the change of the CO2 concentration is obtained by analyzing the change of the phase signal through the detection circuit.
The node controller 2 comprises a power supply module 11 and a GPRS communication module 12, the power supply module comprises a solar cell panel, a storage battery and a power supply voltage stabilizing chip which are sequentially connected, the solar cell panel converts solar energy into electric energy and charges the storage battery, and the electric energy output by the storage battery is subjected to voltage stabilization by the power supply voltage stabilizing chip and then is transmitted to the diffusion type CO2Detecting node, supplying power to GPRS communication module, which will diffuse CO2And the detection signal sent by the detection node is transmitted to a remote monitoring terminal through a GPRS wireless network.
The monitoring terminal 3 is used for receiving the digital signals which are transmitted by each node controller and reflect the concentration of CO2, is a computer provided with relevant monitoring software, and converts, processes, analyzes and stores the digital signals. And once the concentration of CO2 detected by a certain diffusion type CO2 detection node in a certain time period is found to be changed greatly, an alarm message is sent out to remind monitoring personnel to pay attention.
The CO distributed in a network manner2The detection method of the on-line continuous detection system comprises the following steps: according to CO2Monitoring range of to diffusion type CO2The detection nodes are distributed, the diffusion type CO2 detection nodes are buried in shallow soil on the ground surface, the buried depth is not more than 5m, the node controller is fixed on the ground surface and is diffusion type CO2The detection node provides power supply power and CO in the soil2Free escape of gas to diffusion CO2In a two-channel structure sensor for detecting nodes, CO2Gas contacts a gas sensitive element in the dual-channel structure sensor, a gas sensitive film on the gas sensitive element is physically changed to cause phase change of an interdigital electrode, a changed signal is transmitted to a detection circuit through a probe, the detection circuit transmits a detection signal to a node controller after processing, and the node controller transmits detected CO to a node controller through a wireless network2Transmitting the gas concentration data to a remote monitoring terminal, and enabling the monitoring terminal to transmit all the diffused CO2Detecting CO measured by a node2The gas concentration is stored and analyzed, and the monitoring terminal is used for storing and analyzing the same diffused CO2The concentrations of the detection nodes measured at different times form a group, and the concentration is measured for single diffusion type CO2And (3) carrying out normal distribution test on the concentration measured by the detection node within a period of time, carrying out sliding variance analysis by taking every 10 concentration data as a data section, finding out the data section with obvious difference by using F statistic so as to find out a period of time with the maximum concentration change in a group, and if the concentration variance in the period of time is greater than a set threshold value, displaying an analysis result by the monitoring terminal and sending alarm information.
The invention can treat CO in a larger area2Continuously monitoring the change of gas concentration by square difference analysis and normal distribution test to determine CO in the region2The condition of gas concentration change alarms and reminds abnormal points, and the problem of existing wide-area gas concentration monitoring analysis dispersion is solved. The invention takes a surface acoustic wave dual-channel sensor as diffusion type CO2The core of the detection node is a sensor prepared by an oxide composite film and an oxide-polymer composite gas-sensitive film, the sensor takes diffused gas induction and shallow buried soil as detection modes, water and dust are filtered by a hydrophobic breathable film without being exhausted, the gas balance state of a detection environment is not damaged, continuous real-time detection can be realized, time recovery is not needed, the sensitivity of a gas-sensitive element of the sensor is high, the requirements of low cost, long distance and wide range detection are met, and the sensor can be applied to CCS leakage monitoring, crustal deflation monitoring and regional environment monitoring.
Claims (7)
1. CO distributed in network2An on-line continuous detection system, comprising:
multiple diffusion type CO2Detection node arranged on surface or underground shallow layer for detecting CO in soil2The gas concentration transmits a detection signal to the node controller through a signal wire;
node controller, and diffusion CO2The detection nodes are in one-to-one correspondence and are diffusion type CO2The detection node provides power and diffuses CO2The detection signal sent by the detection node is transmitted to a remote monitoring terminal through a wireless network;
the monitoring terminal is in wireless communication with the node controller, receives the data transmitted by the node controller, displays and stores the data, and processes and analyzes the received data to discriminate the diffusion CO2Detecting CO detected by a node2Whether there is an abnormal change in the gas concentration.
2. A network distributed CO according to claim 12The on-line continuous detection system is characterized in that the diffusion type CO is2The detection node is a detection rod, the head of the detection rod is provided with a double-channel structure sensor, and the rear of the double-channel structure sensor is provided withAnd the detection circuit is connected with the dual-channel structure sensor through a probe and is connected with the node controller through a plurality of strands of shielding signal wires.
3. A networked CO according to claim 22The on-line continuous detection system is characterized in that the dual-channel structure sensor comprises a piezoelectric layer, two interdigital electrodes which are arranged side by side are arranged on the piezoelectric layer, a gas-sensitive film is coated on one interdigital electrode to form a gas-sensitive element, and the gas-sensitive film is MWCNTs/SnO2The two interdigital electrodes are respectively positioned in two detection channels of the two-channel structure sensor.
4. A networked CO according to claim 32The on-line continuous detection system is characterized in that the front end of the detection rod is covered with a layer of hydrophobic breathable film, namely, the air inlet of the dual-channel structure sensor is covered with a layer of hydrophobic breathable film, the hydrophobic breathable film is a microporous PTFE hydrophobic filter film, and a distance is reserved between the interdigital electrode and the hydrophobic breathable film.
5. A networked CO according to claim 3 or 42The on-line continuous detection system is characterized in that the piezoelectric layer is made of diamond-like BN (boron nitride), and the interdigital electrode comprises SnO (SnO)2The thin film layer and the Au thin film layer are formed by double-layer plating.
6. A networked CO according to claim 1 or 22The on-line continuous detection system is characterized in that the node controller comprises a power module and a GPRS communication module, the power module comprises a solar cell panel, a storage battery and a power voltage stabilizing chip which are sequentially connected, the output end of the power voltage stabilizing chip is connected with the diffusion type CO2The detection nodes are connected, and the GPRS communication module is used for diffusing CO2And the detection signal sent by the detection node is transmitted to a remote monitoring terminal through a GPRS wireless network.
7. A networked CO as claimed in claim 12The detection method of the on-line continuous detection system is characterized in that the detection method is based on CO2To the diffused CO2The detection nodes are distributed, and the node controller is fixed on the ground surface and is a diffusion type CO2The detection node provides power supply power and CO in the soil2Free escape of gas to diffusion CO2In a two-channel structure sensor for detecting nodes, CO2Gas contacts a gas sensitive element in the dual-channel structure sensor, a gas sensitive film on the gas sensitive element is physically changed to cause phase change of an interdigital electrode, a changed signal is transmitted to a detection circuit through a probe, the detection circuit transmits a detection signal to a node controller after processing, and the node controller transmits detected CO to a node controller through a wireless network2Transmitting the gas concentration data to the monitoring terminal, and the monitoring terminal transmits all the diffused CO2Detecting CO measured by a node2The gas concentration is stored and analyzed, and the monitoring terminal is used for storing and analyzing the same diffused CO2The concentrations of the detection nodes measured at different times form a group, and the concentration is measured for single diffusion type CO2And (3) carrying out normal distribution test on the concentration measured by the detection node within a period of time, carrying out sliding variance analysis by taking every 10 concentration data as a data section, finding out the data section with obvious difference by using F statistic so as to find out a period of time with the maximum concentration change in a group, and if the concentration variance in the period of time is greater than a set threshold value, displaying an analysis result by the monitoring terminal and sending alarm information.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112162012A (en) * | 2020-09-07 | 2021-01-01 | 天地（常州）自动化股份有限公司 | Automatic calibration device and automatic calibration method for gas sensing module |
| CN112630298A (en) * | 2020-12-15 | 2021-04-09 | 阜阳科优检测科技有限公司 | Soil VOCs detection device based on surface acoustic wave |
| CN115975754A (en) * | 2022-11-24 | 2023-04-18 | 清华大学 | Based on real-time detection of CO 2 Method for monitoring concentration solid state fermentation state |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060114113A1 (en) * | 2004-11-26 | 2006-06-01 | Koichi Yokosawa | Gas detection system |
| CN101135670A (en) * | 2007-10-12 | 2008-03-05 | 电子科技大学 | Two-channel sonic surface wave gas sensors having humidity compensate function |
| CN201673272U (en) * | 2010-05-18 | 2010-12-15 | 泉州物联电子有限公司 | Mandarin growing environment monitoring system based on wireless sensor network |
| CN204855494U (en) * | 2015-09-02 | 2015-12-09 | 山东交通学院 | Many gas strengths of boats and ships monitoring system based on zigBee wireless network |
| CN106018549A (en) * | 2016-06-12 | 2016-10-12 | 肖小玉 | Environment monitoring device capable of detecting gas at high reliability |
| CN109211824A (en) * | 2018-09-20 | 2019-01-15 | 国网黑龙江省电力有限公司鹤岗供电公司 | A kind of cable tunnel gas on-line monitoring system |
| CN211785286U (en) * | 2019-12-17 | 2020-10-27 | 杭州超钜科技有限公司 | Online continuous CO2 detection system with networked distribution |
-
2019
- 2019-12-17 CN CN201911305889.3A patent/CN111579599B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060114113A1 (en) * | 2004-11-26 | 2006-06-01 | Koichi Yokosawa | Gas detection system |
| CN101135670A (en) * | 2007-10-12 | 2008-03-05 | 电子科技大学 | Two-channel sonic surface wave gas sensors having humidity compensate function |
| CN201673272U (en) * | 2010-05-18 | 2010-12-15 | 泉州物联电子有限公司 | Mandarin growing environment monitoring system based on wireless sensor network |
| CN204855494U (en) * | 2015-09-02 | 2015-12-09 | 山东交通学院 | Many gas strengths of boats and ships monitoring system based on zigBee wireless network |
| CN106018549A (en) * | 2016-06-12 | 2016-10-12 | 肖小玉 | Environment monitoring device capable of detecting gas at high reliability |
| CN109211824A (en) * | 2018-09-20 | 2019-01-15 | 国网黑龙江省电力有限公司鹤岗供电公司 | A kind of cable tunnel gas on-line monitoring system |
| CN211785286U (en) * | 2019-12-17 | 2020-10-27 | 杭州超钜科技有限公司 | Online continuous CO2 detection system with networked distribution |
Non-Patent Citations (2)
| Title |
|---|
| 魏雪鹏等: ""MWCNTs@TiO/聚合物纳米导电复合材料的制备、薄膜组装及传感应用"", 《中国化学会第18届反应性高分子学术研讨会》 * |
| 黄小菲等: "《城市灾害极早期预警技术应用》", 31 October 2018, 北京：国家行政学院出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112162012A (en) * | 2020-09-07 | 2021-01-01 | 天地（常州）自动化股份有限公司 | Automatic calibration device and automatic calibration method for gas sensing module |
| CN112630298A (en) * | 2020-12-15 | 2021-04-09 | 阜阳科优检测科技有限公司 | Soil VOCs detection device based on surface acoustic wave |
| CN115975754A (en) * | 2022-11-24 | 2023-04-18 | 清华大学 | Based on real-time detection of CO 2 Method for monitoring concentration solid state fermentation state |
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