CN111484781A - Limestone-imitated multicolor paint and construction method thereof - Google Patents

Limestone-imitated multicolor paint and construction method thereof Download PDF

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Publication number
CN111484781A
CN111484781A CN202010350114.4A CN202010350114A CN111484781A CN 111484781 A CN111484781 A CN 111484781A CN 202010350114 A CN202010350114 A CN 202010350114A CN 111484781 A CN111484781 A CN 111484781A
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limestone
parts
paint
sand
preservative
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CN111484781B (en
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施展
杨源河
朱伯虎
张庆笃
李志军
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Tianjin Dpv Coating Co ltd
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Tianjin Dpv Coating Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/02Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/02Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
    • E04F13/04Bases for plaster
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/02Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
    • E04F13/04Bases for plaster
    • E04F13/047Plaster carrying meshes
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention relates to an limestone-imitated multicolor paint and a construction method thereof, belonging to the field of paints, wherein the paint sequentially comprises the following components from inside to outside: primer, coarse limestone sand-containing intermediate coat paint, fine limestone sand-containing intermediate coat paint, limestone color wiping paint, limestone spot material and limestone matte finish coat paint. The limestone-like multicolor paint has excellent bonding strength under the condition of ensuring the sanding property, and is not easy to crack. Moreover, a plurality of color points can be sprayed at one time in the construction process of the limestone point material, so that the working procedures are reduced, and the construction efficiency is improved. The coating also has good water resistance, and can avoid foaming in rainy season. And the coating is easy to polish, and the construction efficiency is improved. In addition, the weather resistance and the stain resistance of the coating are obviously improved.

Description

Limestone-imitated multicolor paint and construction method thereof
Technical Field
The invention relates to the field of coatings, in particular to an limestone-imitated multicolor coating and a construction method thereof.
Background
The stone-like material becomes the mainstream of the prior exterior wall coating, and the limestone has the advantages of noble odour, attractive appearance, high bulkiness and elegant style and is an ideal material for the exterior wall of a high-end building.
The painting is coated on the surface of leveling putty in a scraping mode during the construction of the limestone-imitated painting, then the surface texture is modified by the color-repairing painting of the spray gun construction veneer, and the vivid effect of the limestone-imitated painting is achieved by polishing. One of the great features of the apatite-like coating is that it needs to be polished to smooth the surface of the paint film. In actual construction, the content of the emulsion is often reduced in order to make the coating easily sandable. However, the decrease in the content of the emulsion lowers the weather resistance of the coating itself, and the powdering phenomenon is liable to occur. And the flexibility of the coating is reduced and the crack resistance is reduced. The coating cracks over time, rainwater permeates into the interior of the coating from the cracks, and the durability of the coating is reduced.
Disclosure of Invention
The invention aims to provide an limestone-like multicolor paint and a construction method thereof, aiming at solving the problems that the paint is easy to pulverize when being polished due to the fact that the content of emulsion is reduced, the flexibility of the paint is reduced, and the crack resistance is reduced. Cracking of the coating can occur after a long time, rainwater permeates into the interior of the coating from the cracks, and the durability of the coating is reduced.
In order to solve the technical problem, the invention provides an apatite-imitated multicolor paint which sequentially comprises the following components from inside to outside: the paint comprises a primer, a coarse limestone sand-containing intermediate coat, a fine limestone sand-containing intermediate coat, a limestone color wiping paint, a limestone point material and a limestone matte finish coat, wherein the limestone color wiping paint comprises the following components in parts by weight: 2-4 parts of preservative, 7-9 parts of ammonium salt dispersant, 4-6 parts of defoaming agent, 10-12 parts of hydroxyethyl cellulose, 10-20 parts of titanium dioxide, 80-100 parts of calcined kaolin, 50-70 parts of triple superphosphate, 15-20 parts of ethylene glycol antifreezing agent, 10-18 parts of film forming additive, 1-1.5 parts of multifunctional additive, 300 parts of pure acrylic osmotic emulsion 250-containing material, 5-7 parts of lithium magnesium silicate, 3-5 parts of alkali swelling thickener and 481.6-526 parts of water.
Preferably, the limestone point material is prepared from a limestone point material A component, a limestone point material B component and a limestone point material C component according to the weight portion ratio of 300-380:500-600: 80-120.
Preferably, the limestone spot material A component has the same components and parts by weight as the limestone brushing paint.
Preferably, the limestone spot material B comprises the following components in parts by weight: 2-3 parts of preservative, 20-26 parts of lithium magnesium silicate, 1-2 parts of xanthan gum, 1-2 parts of carboxymethyl cellulose, 0.6-1 part of multifunctional assistant and 966.6-974.4 parts of water.
Preferably, the limestone spot material C comprises the following components in parts by weight: 3-4 parts of preservative, 25-35 parts of film-forming additive, 25-30 parts of glycol antifreezing agent, 500-600 parts of silicone-acrylic emulsion, 1-1.5 parts of multifunctional additive, 7-9 parts of alkali swelling thickener and 321.5-437.4 parts of water.
Preferably, the fine limestone sand-containing intermediate coat is prepared from a fine limestone intermediate base material, quartz sand, heavy calcium carbonate, an alkali swelling thickener and water in parts by weight of 400:300-400:150-200:1-3:48-107, wherein the fine limestone middle layer base material comprises the following components in parts by weight: 7-9 parts of ammonium salt dispersant, 4-5 parts of defoaming agent, 4-8 parts of inorganic gel, 1.5-2.5 parts of polypropylene short fiber, 10-15 parts of slow drying agent, 5-6 parts of hydroxypropyl methyl cellulose, 60-80 parts of heavy calcium carbonate, 200 parts of talcum powder 180-containing material, 15-25 parts of propylene glycol antifreezing agent, 15-20 parts of film-forming auxiliary agent, 1-1.5 parts of multifunctional auxiliary agent, 160 parts of pure acrylic emulsion 140-containing material, 160 parts of styrene-acrylic emulsion 140-containing material, 4-5 parts of preservative, 3-5 parts of alkali swelling thickener and 330-377.2 parts of water.
Preferably, the polypropylene staple fiber has a length of 3mm, a fiber modulus of 350MPa and a fiber strength of 3500 MPa.
Preferably, the limestone matte finish paint comprises the following components in parts by weight: 1.5-2.5 parts of preservative, 12-15 parts of glycol antifreezing agent, 20-25 parts of film-forming additive, 300 parts of silicone-acrylic emulsion, 250 parts of pure acrylic osmotic emulsion, 1-1.5 parts of multifunctional additive, 2-3 parts of alkali swelling thickener, 10-15 parts of hydrophobic agent and 394.4-498 parts of water.
In addition, the invention also provides a construction method of the limestone-imitated multicolor paint, which comprises the following steps:
step one, uniformly roller-coating a primer on the surface of leveling putty and drying;
secondly, scraping the coarse sand-containing apatite intermediate coat on the primer in batches, and then paving a layer of fine mesh cloth on the coarse sand-containing apatite intermediate coat and drying the fine mesh cloth;
thirdly, scraping a first layer of fine limestone sand-containing primer paint on the coarse limestone sand-containing primer paint and drying;
scraping a second layer of the fine limestone sand-containing intermediate coat on the surface of the first layer of fine limestone sand-containing intermediate coat again to cover large particles integrally, drying, polishing and removing surface dust;
step five, coating limestone color wiping paint on the surface of the second layer of fine limestone sand-containing middle paint according to natural limestone patterns, drying, polishing and removing surface dust;
step six, spraying limestone dot materials on the surface of the limestone color wiping paint according to the density of color points of natural limestone, drying, polishing and removing surface dust;
and seventhly, uniformly and flatly spraying the limestone matte finish coat on the surface of the limestone spot material, and drying to finish the construction of the limestone-like coating.
Preferably, the preparation method of the limestone clinker in the sixth step comprises the following steps:
step one, adding a preservative, an ammonium salt dispersant, a defoaming agent, hydroxyethyl cellulose, titanium dioxide, calcined kaolin and heavy calcium into water in sequence, and fully and uniformly stirring;
step two, adding an ethylene glycol antifreezing agent, a film forming aid and a multifunctional aid into the mixture obtained in the step one, and increasing the stirring speed after the viscosity is increased;
step three, reducing the stirring speed, adding the pure acrylic osmotic emulsion into the mixture obtained in the step two, uniformly mixing, adding the magnesium lithium silicate, and increasing the speed while adding until the mixture is uniformly mixed;
step four, adding a defoaming agent, a preservative and an alkali swelling thickener aqueous solution into the mixture obtained in the step three in sequence, and continuing stirring until the mixture is uniformly mixed to obtain a limestone spot material A component;
step five, adding a preservative, lithium magnesium silicate, xanthan gum and carboxymethyl cellulose into water in sequence, and mixing uniformly;
step six, after the viscosity is increased, adding the multifunctional auxiliary agent until the multifunctional auxiliary agent is completely dissolved;
step seven, adding a preservative and water into the mixture obtained in the step six, and uniformly mixing to obtain a limestone spot material B component;
step eight, sequentially adding a preservative, a film-forming aid, an ethylene glycol anti-freezing agent, a silicone-acrylic emulsion and a multifunctional aid into water, and uniformly stirring;
step nine, adding the aqueous solution of the alkali swelling thickener into the mixture obtained in the step eight, uniformly stirring, then adding the preservative, and continuously and uniformly stirring to obtain a limestone point material C component;
step ten, according to the ratio of each color point of the natural limestone, adding 380 portions of 300-600 portions of the limestone point material A component into the 500-600 portions of the limestone point material B component, uniformly mixing, and then dispersing to the size of the color point of the natural limestone;
and step eleven, adding 80-120 parts of limestone point material C into the mixture obtained in the step eleven, and uniformly mixing to obtain the limestone point material.
Compared with the prior art, the invention has the characteristics and beneficial effects that:
(1) the limestone-imitated multicolor paint improves the formulas of the limestone color-wiping paint and the limestone spot material A component, and is added with the permeable hydrophilic emulsion, so that the permeable emulsion has small particle size, extremely low surface tension and excellent wetting and permeating effects. In addition, most of the fine limestone sand-containing intermediate coating is hydrophilic quartz sand, so that the limestone color wiping paint and the limestone spot paint are easier to permeate into the fine limestone sand-containing intermediate coating, and the limestone spot paint, the limestone color wiping paint and the fine limestone sand-containing intermediate coating have good fusion, are integrated and have natural decorative effect. Particularly, in terms of functions, the limestone spot material and the limestone color-wiping paint can be bonded with the fine limestone sand-containing middle painting paint, so that the bonding strength is increased, the transverse adhesive force is increased, and cracking is prevented.
(2) The limestone imitation multicolor paint improves the formula of limestone spot materials, the limestone spot materials comprise a limestone spot material A component, a limestone spot material B component and a limestone spot material C component, and multiple color points can be sprayed at one time in the construction process, so that the working procedures are reduced, and the construction efficiency is improved.
(3) The limestone-imitated multicolor paint comprises a layer of coarse limestone sand-containing intermediate paint and two layers of fine limestone sand-containing intermediate paint, has the effect of inlaying large and small particles, and also has the effects of preventing bottom exposure, being easy to level and preventing cracking. And ammonium salt is used as a dispersing agent in the fine limestone sand-containing painting, so that the paint has super water resistance, and the problem of easy foaming in rainy seasons can be avoided. In addition, the talcum powder is added into the fine limestone sand-containing intermediate coating, so that the smoothness and the grindability are improved, and the labor force is greatly reduced.
(4) The limestone-imitated multicolor paint disclosed by the invention improves the formula of the fine limestone sand-containing intermediate coat paint, and polypropylene short fibers are added into the fine limestone sand-containing intermediate coat paint, so that the moisture in the system is rapidly transmitted to the surface and the interface of the slurry due to the capillary action of a fiber structure, the moisture in the slurry is uniformly distributed, and the skinning and cracking caused by too fast surface drying are obviously reduced. In addition, a slow drying agent is added into the paint containing fine limestone sand, so that the opening time is prolonged, and the surface is not dried too fast to cause cracking.
(5) The limestone-like multicolor paint improves the formula of the limestone matte finish paint, and two emulsions are added into the finish paint, wherein one emulsion is a silicone-acrylic emulsion which is a matte emulsion, has certain hydrophobicity, and has higher glass transition temperature and harder texture. The other is pure acrylic emulsion, because the pure acrylic emulsion has fine and small particle size, and the emulsion ultra-dispersion technology enriches a large amount of functional groups on the surface of emulsion particles of the product through structural design and process control, and assists the molecular weight control technology, thereby improving the dispersion and the wrapping of the emulsion on powder and achieving excellent base material permeability. The emulsion permeates into the loose base material, and the functional groups on the surface of the particles are crosslinked to form a compact layer in the film forming process, so that the emulsion has good flexibility, reinforces the base material and enhances the transverse adhesive force. In addition, the monomers are hydrophilic, and the emulsion can be hydrophilic. Because most of the fine limestone sand-containing intermediate coat is quartz sand which is hydrophilic, and the permeable emulsion has hydrophilicity and super-strong permeability, the pure acrylic permeable emulsion compounded in the limestone matte finish coat can be firstly wetted and spread on the fine limestone sand-containing intermediate coat to play a role in permeating and bonding again, and the emulsion has certain flexibility and is less prone to cracking caused by external influence. Finally, the hydrophobic emulsion in the compound emulsion of the limestone matte finish coat paint floats at the top, has a hydrophobic effect, is hard in texture, has a good water-resistant effect, and has certain strength, and the weather resistance and the stain resistance are obviously improved.
Drawings
FIG. 1 is a schematic structural view of a limestone-like multicolor paint.
The attached drawings are marked as follows: 1-primer, 2-coarse limestone sand-containing intermediate coat paint, 3-fine limestone sand-containing intermediate coat paint, 4-limestone color wiping paint, 5-limestone dot material and 6-limestone matte finish coat paint.
Detailed Description
In order to make the technical means, innovative features, objectives and functions realized by the present invention easy to understand, the present invention is further described below.
The examples described herein are specific embodiments of the present invention, are intended to be illustrative and exemplary in nature, and are not to be construed as limiting the scope of the invention. In addition to the embodiments described herein, those skilled in the art will be able to employ other technical solutions which are obvious based on the disclosure of the claims and the specification of the present application, and these technical solutions include technical solutions which make any obvious replacement or modification for the embodiments described herein.
The invention provides an apatite-imitated multicolor paint, which comprises the following components in sequence from inside to outside as shown in figure 1: the coating comprises a primer 1, a coarse limestone sand-containing intermediate coat 2, a fine limestone sand-containing intermediate coat 3, a limestone color wiping coat 4, a limestone spot material 5 and a limestone matte finish coat 6.
Wherein the primer 1 comprises styrene-acrylic emulsion, a film-forming auxiliary agent, an HF preservative, a multifunctional auxiliary agent and water.
The coarse limestone sand-containing intermediate coating 2 comprises a defoaming agent, a sodium salt dispersing agent, inorganic gel, a propylene glycol antifreezing agent, hydroxypropyl methyl cellulose, a film forming auxiliary agent, a multifunctional auxiliary agent, heavy calcium carbonate, a styrene-acrylic emulsion, a preservative, an alkali swelling thickener and water. Wherein the defoamer is mineral oil defoamer, the coarse whiting is 800 meshes coarse whiting, and the inorganic gel is SM-HV. The preservative is HF.
The fine limestone sand-containing intermediate coating 3 is prepared from a fine limestone middle layer base material, quartz sand, heavy calcium carbonate, an alkali swelling thickener and water according to the weight part ratio of 400:300-400:150-200:1-3: 48-107. Wherein the quartz sand is 150-200 mesh sand powder, and the coarse whiting is 200 mesh coarse whiting. The fine limestone middle-layer base material comprises the following components in parts by weight: 7-9 parts of ammonium salt dispersant, 4-5 parts of defoaming agent, 4-8 parts of inorganic gel, 1.5-2.5 parts of polypropylene short fiber, 10-15 parts of slow drying agent, 5-6 parts of hydroxypropyl methyl cellulose, 60-80 parts of heavy calcium carbonate, 200 parts of talcum powder 180-containing material, 15-25 parts of propylene glycol antifreezing agent, 15-20 parts of film-forming auxiliary agent, 1-1.5 parts of multifunctional auxiliary agent, 160 parts of pure acrylic emulsion 140-containing material, 160 parts of styrene-acrylic emulsion 140-containing material, 4-5 parts of preservative, 3-5 parts of alkali swelling thickener and 330-377.2 parts of water. Wherein the defoamer in the middle base material of the fine limestone is mineral oil defoamer, the inorganic gel is SM-HV, the coarse whiting is 800 meshes coarse whiting, and the talcum powder is 800 meshes talcum powder. The preservative is HF.
The limestone wiping color paint 4 comprises the following components in parts by weight: 2-4 parts of preservative, 7-9 parts of ammonium salt dispersant, 4-6 parts of defoaming agent, 10-12 parts of hydroxyethyl cellulose, 10-20 parts of titanium dioxide, 80-100 parts of calcined kaolin, 50-70 parts of triple superphosphate, 15-20 parts of ethylene glycol antifreezing agent, 10-18 parts of film forming additive, 1-1.5 parts of multifunctional additive, 300 parts of pure acrylic osmotic emulsion 250-containing material, 5-7 parts of lithium magnesium silicate, 3-5 parts of alkali swelling thickener and 481.6-526 parts of water. The preservative comprises 0-2 parts of MBS5050 long-acting preservative and 0-2 parts of HF preservative, the MBS5050 long-acting preservative is a long-acting bactericide, but the sterilization efficiency is general, and the HF preservative is a quick and strong bactericide, has high sterilization efficiency but is relatively short-acting. The defoaming agent comprises 1-3 parts of mineral oil defoaming agent and 1-3 parts of silicon dioxide defoaming agent, the mineral oil defoaming agent eliminates large bubbles, and the silicon dioxide defoaming agent eliminates broken bubbles. The coarse whiting is 800 meshes coarse whiting. The pure acrylic osmotic emulsion is RS-369 available from New materials, Inc. of Badfei, Cinderland, Foshan. The alkali swelling thickener comprises TT-6151 parts to 3 parts available from the Dow chemical and ASE-601 parts to 3 parts also available from the Dow chemical. TT-615 is mainly used for thickening the whole system and preventing water from demixing and dividing in the storage process. The ASE-60 mainly has the function of making the prepared dots more mellow, uniform and tough, and can also thicken the whole system.
The limestone spot material 5 is prepared from a limestone spot material component A, a limestone spot material component B and a limestone spot material component C according to the following weight ratio of 300-: 500- & ltSP & gt 600- & lt 80- & gt 120. The component and the weight portion of the limestone spot material A are the same as those of the limestone color wiping paint 4.
The limestone spot material B comprises the following components in parts by weight: 2-3 parts of preservative, 20-26 parts of lithium magnesium silicate, 1-2 parts of xanthan gum, 1-2 parts of carboxymethyl cellulose, 0.6-1 part of multifunctional assistant and 966.6-974.4 parts of water. Wherein the preservative comprises 1-2 parts of MBS5050 long-acting preservative and 1-2 parts of HF preservative.
The limestone spot material C comprises the following components in parts by weight: 3-4 parts of preservative, 25-35 parts of film-forming additive, 25-30 parts of glycol antifreezing agent, 500-600 parts of silicone-acrylic emulsion, 1-1.5 parts of multifunctional additive, 7-9 parts of alkali swelling thickener and 321.5-437.4 parts of water. Wherein the preservative comprises 1-2 parts of MBS5050 long-acting preservative and 1.5-3 parts of HF preservative. The alkali swelling thickener comprises TT-9355 parts-7 parts available from the Dow chemical and ASE-602 parts-4 parts also available from the Dow chemical.
The limestone matte finish coat 6 comprises the following components in parts by weight: 1.5-2.5 parts of preservative, 12-15 parts of glycol antifreezing agent, 20-25 parts of film-forming additive, 300 parts of silicone-acrylic emulsion, 250 parts of pure acrylic osmotic emulsion, 1-1.5 parts of multifunctional additive, 2-3 parts of alkali swelling thickener, 10-15 parts of hydrophobic agent and 394.4-498 parts of water. Wherein the preservative is HF. The alkali swelling thickener is TT-935 available from Dow chemistry.
The preparation method of the limestone-imitated multicolor paint comprises the following steps:
step one, uniformly rolling and coating the primer 1 on the surface of the leveling putty and drying.
And step two, scraping the coarse limestone sand-containing primer paint 2 on the primer 1 in batches, and then paving a layer of fine mesh cloth on the coarse limestone sand-containing primer paint 2 and drying. The method for paving the mesh cloth is to cover and stick the mesh cloth to the coarse limestone sand primer surfacer 2 by using the fine limestone sand primer surfacer 3 while paving the mesh cloth after the coarse limestone sand primer surfacer 2 is dried.
And step three, scraping a first layer of fine limestone sand primer surfacer 3 on the coarse limestone sand primer surfacer 2 and drying.
And step four, scraping the surface of the first layer of the fine limestone sand-containing intermediate coat paint 3 again to obtain a second layer of the fine limestone sand-containing intermediate coat paint 3, wherein large particles are required to be covered integrally, and polishing and removing surface dust after drying.
And step five, constructing a limestone color wiping paint 4 on the surface of the second layer of fine limestone sand-containing intermediate paint 3 according to natural limestone patterns, drying, polishing and removing surface dust.
And sixthly, spraying limestone dot materials 5 on the surface of the limestone color wiping paint 4 according to the density of color points of the natural limestone, drying, polishing and removing surface dust.
And seventhly, uniformly and flatly spraying the limestone matte finish coat paint 6 on the surface of the limestone spot paint 5, and drying to finish the construction of the limestone-like paint.
(1) Preparation of primer 1
Adding water into a stirring cylinder, and then adding the styrene-acrylic emulsion, the film-forming auxiliary agent, the preservative, the water and the multifunctional auxiliary agent. And (5) the primer is qualified after inspection, and the preparation of the primer 1 is finished.
(2) Preparation of coarse limestone sand-containing primer surfacer 2
Adding water into a stirring cylinder, adding the defoaming agent, the dispersing agent and the inorganic gel SM-HV, continuing stirring until the inorganic gel is not agglomerated, and carrying out the next step.
Then adding propylene glycol antifreezing agent, hydroxypropyl methyl cellulose and film forming auxiliary agent, continuously stirring until fully wetting, and then carrying out the next step.
Then adding multifunctional auxiliary agent, 800-mesh heavy calcium carbonate, water, styrene-acrylic emulsion, preservative HF and alkali swelling thickener to obtain the elastic texture base material.
And finally, mixing the texture base material with the snowflake white, adding the alkali swelling thickener after uniform mixing, and uniformly mixing again to obtain the coarse limestone sand-containing primer surfacer 2.
(3) Preparation of fine limestone sand-containing middle layer base material
Adding water into a stirring cylinder, stirring at a low speed of 400-500r/min, then sequentially adding an ammonium salt dispersant, a slow drying agent, a mineral oil defoamer and inorganic gel, stirring at a medium speed of 10min, wherein the rotating speed is required to be 800-1000 r/min, and then continuing the next step.
Then adding hydroxypropyl methyl cellulose, wetting and stirring for 5 minutes, then adding 800-mesh coarse whiting, 800-mesh talcum powder, film forming auxiliary agent and multifunctional auxiliary agent, dispersing at high speed for 10min, wherein the rotating speed is 1300r/min, and then carrying out the next step.
And finally, adding the pure acrylic emulsion and the styrene-acrylic emulsion, then continuously adding the preservative HF and the alkali swelling thickener, adding the alkali swelling thickener and the rest water together after mixing, finally adding the polypropylene short fiber, and uniformly stirring. And after the fine limestone sand-containing middle-layer base material is qualified, obtaining the fine limestone sand-containing middle-layer base material.
(4) Preparation of fine limestone sand-containing primer surfacer 3
Mixing the middle base material of fine limestone with quartz sand and heavy calcium according to the proportion of 400:300-400:150 and 200, adding a mixture of an alkali swelling thickener and water (the alkali swelling thickener is 1-3:48-107), and mixing again to obtain the fine limestone sand primer surfacer 3.
(5) Preparation of limestone color-wiping paint 4
After adding water, starting a stirrer for 500r/min at 400-.
Adding glycol antifreezing agent, film forming assistant and multifunctional assistant, dispersing at high speed 1300r/min for 10min after viscosity is increased, and then carrying out the next step.
Adjusting the rotating speed to 800r/min, adding the pure acrylic osmotic emulsion, uniformly mixing, adding a 10% magnesium lithium silicate solution, preparing the 10% magnesium lithium silicate solution in advance, and dispersing at high speed for 40min at the rotating speed of 1300 r/min. Adding while accelerating, rotating speed is 1000-1300r/min, mixing uniformly and continuing to the next step.
Sequentially adding a silicon dioxide defoaming agent, a preservative HF, an alkali swelling thickener TT-615 and an alkali swelling thickener ASE-60 in sequence, respectively mixing the two thickeners with the remaining water in equal parts, adding the mixture, stirring at a medium speed of 800r/min-1000r/min for 5min, and preparing the limestone color-wiping paint 4 after the viscosity is qualified.
(6) Preparation of limestone spot material 5
Step one, adding a preservative, an ammonium salt dispersant, a defoaming agent, hydroxyethyl cellulose, titanium dioxide, calcined kaolin and heavy calcium into water in sequence, and fully and uniformly stirring;
step two, adding an ethylene glycol antifreezing agent, a film forming aid and a multifunctional aid into the mixture obtained in the step one, and increasing the stirring speed after the viscosity is increased;
step three, reducing the stirring speed, adding pure acrylic osmotic emulsion into the mixture obtained in the step two, uniformly mixing, adding lithium magnesium silicate, and increasing the speed while adding until uniformly mixing;
step four, adding a defoaming agent, a preservative and an alkali swelling thickener aqueous solution into the mixture obtained in the step three in sequence, and continuing stirring until the mixture is uniformly mixed to obtain a limestone spot material A component;
step five, adding a preservative, lithium magnesium silicate, xanthan gum and carboxymethyl cellulose into water in sequence, and mixing uniformly;
step six, after the viscosity is increased, adding the multifunctional auxiliary agent until the multifunctional auxiliary agent is completely dissolved;
step seven, adding a preservative and water into the mixture obtained in the step six, and uniformly mixing to obtain a limestone spot material B component;
step eight, sequentially adding a preservative, a film-forming aid, an ethylene glycol anti-freezing agent, a silicone-acrylic emulsion and a multifunctional aid into water, and uniformly stirring;
step nine, adding the aqueous solution of the alkali swelling thickener into the mixture obtained in the step eight, uniformly stirring, then adding the preservative, and continuously and uniformly stirring to obtain a limestone point material C component;
step ten, according to the ratio of each color point of the natural limestone, adding 380 portions of 300-600 portions of the limestone point material A component into the 500-600 portions of the limestone point material B component, uniformly mixing, and then dispersing to the size of the color point of the natural limestone;
and step eleven, adding 80-120 parts of limestone spot material C into the mixture obtained in the step eleven, and uniformly mixing to obtain limestone spot material 5.
It should be noted that the limestone spot material a component, the limestone spot material B component and the limestone spot material C component may be prepared at the same time or prepared in advance for later use, and then the three components are mixed in the order of the tenth step and the eleventh step to obtain the limestone spot material 5.
(7) Preparation of limestone matte finish 6
Adding water into a stirring cylinder, stirring at low speed for 400-500r/min, adding antiseptic HF, ethylene glycol antifreeze, film-forming assistant, silicone-acrylic emulsion, pure acrylic emulsion and multifunctional assistant, mixing for 5min, and continuing the next step after mixing uniformly. The pure acrylic emulsion has good water resistance, alkali resistance and weather resistance, but the pure acrylic emulsion has good penetration effect and low surface tension besides good water resistance, alkali resistance and weather resistance, and is easier to spread on a base material.
Then adding the mixture of the alkali swelling thickener TT-935 and the rest water, and stirring at a medium speed of 800-1000 r/min for 8 min. And finally, adding a hydrophobing agent, mixing for 3 minutes, and obtaining the limestone matte finish coat 6 after the inspection is qualified.
Table 1 shows the components and parts by weight of the limestone wiping paint or limestone spot material a component in each example.
The components and parts by weight of the limestone clinker B component in each example are shown in Table 2.
The components and parts by weight of the limestone clinker C component in each example are shown in Table 3.
Table 4 shows the components and parts by weight of the base material for the middle layer of fine limestone in each example.
Table 5 shows the components and parts by weight of the paint in the sand of fine limestone in each example.
Table 6 shows the components and parts by weight of the limestone matte finishes in the examples.
Table 7 shows the results of the performance tests of the examples.
Table 8 shows the results of the performance tests of the wall surfaces constructed in each proportion.
TABLE 1 composition and parts by weight of limestone wiping paints or limestone topping A Components of the examples
Figure BDA0002471651280000091
TABLE 2 ingredient and weight portion of limestone Point feed B ingredient in each example
Figure BDA0002471651280000092
TABLE 3 ingredient and weight part of limestone Point material C ingredient in each example
Figure BDA0002471651280000101
TABLE 4 Components and parts by weight of middle layer base of fine limestone in the examples
Example 1 Example 2 Example 3 Example 4 Example 5 Example 6
Ammonium salt dispersants 8.0 7 7.5 8 8.5 9
Defoaming agent 4.0 4.5 4.5 5 4 4
Inorganic gel 5.0 4 5 6 7 8
Polypropylene short fiber 2.0 1.5 2 2 2.5 2.5
Slow-release preparation 10.0 11 12 13 14 15
Hydroxypropyl methylcellulose 5.5 6 5.8 5.6 5.4 5
Heavy calcium carbonate 62.5 80 75 70 65 60
Talcum powder 187.5 180 185 190 195 200
Propylene glycol antifreezing agent 20 15 18 21 23 25
Film forming aid 20 15 16 17 18 20
Multifunctional auxiliary agent 1.5 1.0 1.1 1.2 1.3 1.4
Pure acrylic emulsion 150 140 150 160 140 160
Styrene-acrylic emulsion 150 150 140 140 160 150
HF preservative 4.0 4.2 4.4 4.6 4.8 5
Alkali swelling thickener 3.0 3.5 4 4.5 5 5
Water (W) 367 377.2 369.6 352 346.4 330
TABLE 5 Components and parts by weight of the middle coat paint in the fine limestone sand of the examples
Figure BDA0002471651280000102
TABLE 6 composition and parts by weight of limestone matte finishes in the examples
Example 1 Example 2 Example 3 Example 4 Example 5 Example 6
HF preservative 1.5 1.8 2.0 2.2 2.4 2.5
Ethylene glycol antifreezing agent 12 12 13 14 15 15
Film forming aid 20 21 22 23 24 25
Silicone-acrylic emulsion 250 260 270 280 290 300
Pure acrylic osmotic emulsion 200 210 220 230 240 250
Multifunctional auxiliary agent 1.0 1.5 1.4 1.3 1.2 1.1
Alkali swelling thickener 2.5 3 3 2.5 2 2
Water repellent 15 14 13 12 11 10
Water (W) 498 476.7 455.6 435 414.4 394.4
TABLE 7 Performance test results of the wall surface constructed in each example
Figure BDA0002471651280000111
The method for testing the initial cracking resistance of the fine limestone sand-containing intermediate coating comprises the following steps:
and (3) coating the cement board with the size of A4 with a transparent primer, drying at room temperature for 24h, then preparing a wet film with the thickness by using a fine limestone sand-containing intermediate coating with a 6 cm-14.5 cm-1 mm stripping preparation device, immediately putting the wet film into an air-blowing dryer for air-blowing drying for 1h, and observing the cracking condition of the paint film after the experiment is finished.
The method for testing the crack resistance of the finished product wall surface bound by the limestone-like multicolor paint comprises the following steps:
and (3) manufacturing the finished product of the limestone-like multicolor paint on the wall surface according to the construction steps, binding 3.3mm by 45.8mm cement steel nails on the finished product after the finished product is completely dried, and observing the sizes of cracks around the nails on the wall surface after one week.
The manual grindability test method of the fine limestone sand-containing intermediate coating comprises the following steps:
and (3) coating the cement board with the size of A4 with a transparent primer, drying the cement board at room temperature for 24h, scraping the fine limestone sand-containing intermediate coating on the cement board in batches, and drying the cement board for 20h after 4h of drying for the first time and the second time of scraping in batches. And (3) polishing the board by using 300-mesh sand paper, rotating the board to polish for 10 circles with the same strength, and observing the surface polishing degree and the powder falling amount.
The method for testing the water resistance of finished product of the limestone-like multicolor paint comprises the following steps:
carrying out plate making on a cement board with the size of A4 according to the construction steps of the limestone-like multicolor paint, carrying out a water-resistant experiment after room-temperature maintenance for 24 hours after the last step, immersing half of the test board in water for soaking for 24 hours, and finally observing whether the board surface has the phenomena of bubbling, falling and the like after soaking in water, and whether the board surface loses luster after drying.
The test method of the matte lotus leaf effect of the finished product of the limestone-imitated multicolor paint comprises the following steps:
carrying out finished product plate making on a cement board with the size of A4 according to the construction steps of the limestone-like multicolor paint, carrying out testing after room temperature maintenance for 24 hours after the last step, immersing half of the test board in water for 1min, taking out the test board, placing the test board vertically to an experiment table top for 15s, and observing the percentage of the finish paint on the surface of the board, wherein the finish paint flows out of the board surface and accounts for the total area of the immersed water.
Comparative example 1
Unlike example 1, the pure acrylic emulsion of the limestone color wiping paint was replaced with one of the elastic pure acrylic emulsion (comparative example 1-1) and the modified silicone acrylic emulsion (comparative example 1-2) in this comparative example, and the rest was the same as example 1.
Comparative example 2
The difference from example 1 is that the fine limestone sand-containing intermediate coat paint of this example is the same as example 1 except that polypropylene short fibers are not added.
Comparative example 3
The difference from the example 1 is that the fine limestone sand-containing intermediate coat paint of the example is not added with a slow drying agent, and the rest is the same as the example 1.
Comparative example 4
Unlike example 1, the limestone matte finish of this example was identical to example 1 except that no clear acrylic emulsion was added.
TABLE 8 Performance test results for each pair of wall surfaces finished with proportional construction
Figure BDA0002471651280000121
In comparative example 1-1, although the elastic emulsion had a soft texture and a certain flexibility but had no permeability, the emulsion could be merely applied to a fine limestone sand primer to flexibly modify the surface thereof, but the fine limestone sand primer had no toughness inside, so that the fine limestone sand primer still had a slight crack phenomenon after the nail binding. In addition, due to the fact that the elastic emulsion is added, the particle size of the elastic emulsion is large, after the elastic emulsion meets water, water is absorbed easily among particle gaps, the elastic emulsion is hydrophilic, water on the board surface is not easy to remain, and the lotus leaf effect is weakened.
In comparative examples 1-2, not only the emulsion itself was not flexible, but also was not permeable, so that the fine limestone sand-containing intercoat was not assisted in the crack direction by this emulsion, eventually leading to severe cracking.
Comparative example 2 fine limestone sand-containing intermediate coat is not added with polypropylene short fibers, the position with excessively thick batch scraping has no water guide effect of the polypropylene short fibers, so that the internal moisture is not led out to the surface of the product in time, the internal drying is slow, the surface drying is fast, the internal and external contraction forces are unequal, and finally the cracking phenomenon is caused.
Comparative example 3 fine limestone sand-containing medium coat without slow drying agent, the product particles are fine, the batch scraped paint film is thin, the open time is short, and the water loss is too fast, so that the trowel can not reach the leveling of the paint film, and finally the paint film is uneven and easy to crack.
Comparative example 4 no penetrating emulsion was added to the matte finish, the fine limestone sand-containing primer was bonded and drawn together only by the limestone spot material and the limestone wiping paint locally, and it was difficult to ensure that the fine limestone sand-containing primer did not crack. Only partial penetrating emulsion is added into the matte surface, and the fine limestone sand-containing middle paint is subjected to supplementary penetration and bonding, so that the binding of the fine limestone sand-containing middle paint is enough to crack. In addition, as no penetrating emulsion is added, the surface hydrophilicity is reduced, the surface is more hydrophobic, and the lotus leaf effect is improved.
The above embodiments are merely illustrative, and not restrictive, of the scope of the claims, and other alternatives that may occur to those skilled in the art from consideration of the specification should be construed as being within the scope of the claims.

Claims (10)

1. The limestone-like multicolor paint is characterized by sequentially comprising the following components from inside to outside: the paint comprises a primer (1), a coarse limestone sand-containing intermediate coat (2), a fine limestone sand-containing intermediate coat (3), a limestone color wiping paint (4), a limestone spot material (5) and a limestone matte finish coat (6), wherein the limestone color wiping paint (4) comprises the following components in parts by weight: 2-4 parts of preservative, 7-9 parts of ammonium salt dispersant, 4-6 parts of defoaming agent, 10-12 parts of hydroxyethyl cellulose, 10-20 parts of titanium dioxide, 80-100 parts of calcined kaolin, 50-70 parts of triple superphosphate, 15-20 parts of ethylene glycol antifreezing agent, 10-18 parts of film forming additive, 1-1.5 parts of multifunctional additive, 300 parts of pure acrylic osmotic emulsion 250-containing material, 5-7 parts of lithium magnesium silicate, 3-5 parts of alkali swelling thickener and 481.6-526 parts of water.
2. The apatite-imitated multicolor paint as claimed in claim 1, wherein: the limestone point material (5) is prepared from a limestone point material A component, a limestone point material B component and a limestone point material C component according to the weight portion of 300-380:500-600: 80-120.
3. The apatite-imitated multicolor paint as claimed in claim 2, wherein: the component and the weight part of the limestone spot material A are the same as those of the limestone color wiping paint (4).
4. The limestone-like multicolor paint as claimed in claim 2, wherein the limestone spot material B comprises the following components in parts by weight: 2-3 parts of preservative, 20-26 parts of lithium magnesium silicate, 1-2 parts of xanthan gum, 1-2 parts of carboxymethyl cellulose, 0.6-1 part of multifunctional assistant and 966.6-974.4 parts of water.
5. The limestone-like multicolor paint as claimed in claim 2, wherein the limestone spot material C comprises the following components in parts by weight: 3-4 parts of preservative, 25-35 parts of film-forming additive, 25-30 parts of glycol antifreezing agent, 500-600 parts of silicone-acrylic emulsion, 1-1.5 parts of multifunctional additive, 7-9 parts of alkali swelling thickener and 321.5-437.4 parts of water.
6. The limestone-like multicolor paint as claimed in claim 1, wherein the fine limestone sand-containing intermediate paint (3) is prepared from a fine limestone intermediate base material, quartz sand, heavy calcium carbonate, an alkali swelling thickener and water in a weight ratio of 400:300-400:150-200:1-3:48-107, wherein the fine limestone middle layer base material comprises the following components in parts by weight: 7-9 parts of ammonium salt dispersant, 4-5 parts of defoaming agent, 4-8 parts of inorganic gel, 1.5-2.5 parts of polypropylene short fiber, 10-15 parts of slow drying agent, 5-6 parts of hydroxypropyl methyl cellulose, 60-80 parts of heavy calcium carbonate, 200 parts of talcum powder 180-containing material, 15-25 parts of propylene glycol antifreezing agent, 15-20 parts of film-forming auxiliary agent, 1-1.5 parts of multifunctional auxiliary agent, 160 parts of pure acrylic emulsion 140-containing material, 160 parts of styrene-acrylic emulsion 140-containing material, 4-5 parts of preservative, 3-5 parts of alkali swelling thickener and 330-377.2 parts of water.
7. The apatite-imitated multicolor paint as claimed in claim 6, wherein: the length of the polypropylene short fiber is 3mm, the fiber modulus is 350MPa, and the fiber strength is 3500 MPa.
8. The limestone-like multicolor paint as claimed in claim 1, wherein the limestone matte finish (6) comprises the following components in parts by weight: 1.5-2.5 parts of preservative, 12-15 parts of glycol antifreezing agent, 20-25 parts of film-forming additive, 300 parts of silicone-acrylic emulsion, 250 parts of pure acrylic osmotic emulsion, 1-1.5 parts of multifunctional additive, 2-3 parts of alkali swelling thickener, 10-15 parts of hydrophobic agent and 394.4-498 parts of water.
9. The method of constructing a multi-color paint based on an imitated limestone as claimed in any one of claims 1 to 8, characterized in that it comprises the following steps:
step one, uniformly rolling a primer (1) on the surface of leveling putty and drying;
secondly, scraping the coarse limestone sand-containing primer (2) on the primer (1), laying a layer of fine mesh cloth on the coarse limestone sand-containing primer (2), and drying;
thirdly, scraping a first layer of fine limestone sand-containing primer surfacer (3) on the coarse limestone sand-containing primer surfacer (2) and drying;
scraping the second layer of the fine limestone sand-containing intermediate coating (3) again on the surface of the first layer of the fine limestone sand-containing intermediate coating (3) to ensure that large particles are integrally covered, and polishing and removing surface dust after drying;
fifthly, constructing limestone color wiping paint (4) on the surface of the second layer of fine limestone sand-containing intermediate paint (3) according to natural limestone patterns, drying, polishing and removing surface dust;
step six, spraying limestone dot materials (5) on the surface of the limestone color wiping paint (4) according to the density of color points of natural limestone, drying, polishing and removing surface dust;
and seventhly, uniformly and flatly spraying the limestone matte finish coat paint (6) on the surface of the limestone spot paint (5) and drying to finish the construction of the limestone-like paint.
10. The construction method of the limestone-like multicolor paint as claimed in claim 9, wherein the preparation method of the limestone spot material (5) in the sixth step comprises the following steps:
step one, adding a preservative, an ammonium salt dispersant, a defoaming agent, hydroxyethyl cellulose, titanium dioxide, calcined kaolin and heavy calcium into water in sequence, and fully and uniformly stirring;
step two, adding an ethylene glycol antifreezing agent, a film forming aid and a multifunctional aid into the mixture obtained in the step one, and increasing the stirring speed after the viscosity is increased;
step three, reducing the stirring speed, adding the pure acrylic osmotic emulsion into the mixture obtained in the step two, uniformly mixing, adding the magnesium lithium silicate, and increasing the speed while adding until the mixture is uniformly mixed;
step four, adding a defoaming agent, a preservative and an alkali swelling thickener aqueous solution into the mixture obtained in the step three in sequence, and continuing stirring until the mixture is uniformly mixed to obtain a limestone spot material A component;
step five, adding a preservative, lithium magnesium silicate, xanthan gum and carboxymethyl cellulose into water in sequence, and mixing uniformly;
step six, after the viscosity is increased, adding the multifunctional auxiliary agent until the multifunctional auxiliary agent is completely dissolved;
step seven, adding a preservative and water into the mixture obtained in the step six, and uniformly mixing to obtain a limestone spot material B component;
step eight, sequentially adding a preservative, a film-forming aid, an ethylene glycol anti-freezing agent, a silicone-acrylic emulsion and a multifunctional aid into water, and uniformly stirring;
step nine, adding the aqueous solution of the alkali swelling thickener into the mixture obtained in the step eight, uniformly stirring, then adding the preservative, and continuously and uniformly stirring to obtain a limestone point material C component;
step ten, according to the ratio of each color point of the natural limestone, adding 380 portions of 300-600 portions of the limestone point material A component into the 500-600 portions of the limestone point material B component, uniformly mixing, and then dispersing to the size of the color point of the natural limestone;
step eleven, adding 80-120 parts of limestone point material C component into the mixture obtained in the step eleven, and uniformly mixing to obtain limestone point material (5).
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CN107989297A (en) * 2017-12-11 2018-05-04 江苏旌翔建材科技有限公司 A kind of finish coat and preparation method thereof
CN208950213U (en) * 2018-08-24 2019-06-07 嘉兴才蛮幕墙材料有限公司 A kind of Scagliola aluminum veneer
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CN210342494U (en) * 2019-06-03 2020-04-17 上海三银涂料科技股份有限公司 Stone-imitated outer wall coating structure
CN111040535A (en) * 2019-12-02 2020-04-21 嘉宝莉化工集团股份有限公司 Stone-imitated textured paint and preparation method thereof

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CN112761275A (en) * 2020-12-26 2021-05-07 浙江异涂新材料有限公司 Rammed-soil texture-imitated outer wall manufacturing method and rammed-soil coating surface making device

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