CN111484765A - Low-corrosion mirror silver high-pressure impact resistant ink and use method thereof - Google Patents
Low-corrosion mirror silver high-pressure impact resistant ink and use method thereof Download PDFInfo
- Publication number
- CN111484765A CN111484765A CN201910080508.XA CN201910080508A CN111484765A CN 111484765 A CN111484765 A CN 111484765A CN 201910080508 A CN201910080508 A CN 201910080508A CN 111484765 A CN111484765 A CN 111484765A
- Authority
- CN
- China
- Prior art keywords
- ink
- low
- parts
- mirror silver
- corrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
Abstract
The invention relates to low-corrosion mirror silver high-pressure impact resistance ink and a using method thereof, wherein the low-corrosion mirror silver high-pressure impact resistance ink comprises the following components in parts by mass: 25-35 parts of polymethyl methacrylate, 25-30 parts of polymer modified resin, 10-20 parts of carbon black, 20-30 parts of ethylene glycol monobutyl ether and 2-5 parts of an auxiliary agent. The low-corrosion mirror silver high-voltage impact resistant ink disclosed by the invention is low in corrosion to the mirror silver ink, good in insulativity, free of burning-out points after voltage impact, and still capable of keeping good adhesion after being mounted and covered with double-sided adhesive tape and placed for 12 hours.
Description
Technical Field
The invention relates to the technical field of printing ink, in particular to low-corrosion mirror silver high-pressure impact resistant printing ink and a using method thereof.
Background
In the present printing industry, the product of screen printing mirror surface silver at transparent PC class material reverse side is still less, because this type of label has polychrome printing, and after the label of large tracts of land printing mirror surface silver effect reprinted other printing ink that shields, mirror surface silver can be corroded, makes the label openly lose mirror surface effect, especially when this label when using on electrical equipment, receives voltage impact back label can be punctured for this type of label application is limited.
The existing shielding ink has high corrosivity to mirror silver ink, an ink layer completely falls off after the mirror silver ink is placed for 12 hours by mounting a double-sided adhesive tape, the insulating effect is not achieved, and the mirror silver ink is burnt seriously after high-voltage impact.
Disclosure of Invention
The invention aims to provide low-corrosion mirror silver high-pressure impact resistance ink and a using method thereof, and solves the problems that the shielding ink in the prior art has high corrosion to the mirror silver ink, is easy to burn after being subjected to voltage impact and the like.
The technical scheme adopted by the invention for solving the technical problem is as follows: the low-corrosion mirror silver high-pressure impact resistance ink comprises the following components in parts by mass: 25-35 parts of polymethyl methacrylate, 25-30 parts of polymer modified resin, 10-20 parts of carbon black, 20-30 parts of ethylene glycol monobutyl ether and 2-5 parts of an auxiliary agent.
The low-corrosion mirror silver high-pressure impact resistance ink comprises the following components in parts by mass: 28-33 parts of polymethyl methacrylate, 27-28 parts of polymer modified resin, 13-18 parts of carbon black, 22-25 parts of ethylene glycol monobutyl ether and 2-3 parts of an auxiliary agent.
In the low-corrosion mirror silver high-pressure impact resistance ink, the auxiliary agent comprises dimethyl silicone oil and dimethyl polysiloxane, and the mass parts of the dimethyl silicone oil and the dimethyl polysiloxane in the auxiliary agent are as follows: 0.5-2 parts of dimethyl silicone oil and 1-3 parts of dimethyl polysiloxane.
In the low corrosion mirror silver high pressure impact resistant ink of the present invention, the polymeric modified resin is a homopolymer obtained by reacting 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene carboxaldehyde) ] and dioxirane.
In the low-corrosion mirror silver high-pressure impact resistance ink, the mass ratio of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] to dioxirane is 50-75: 35.
the invention also provides a using method of the low-corrosion mirror silver high-pressure impact resistance ink, which comprises the following steps:
A. adding a hardening agent into the low-corrosion mirror silver high-pressure impact resistant ink;
B. printing low-corrosion mirror silver high-pressure impact resistant ink added with a hardening agent on the surface of the mirror silver ink, and drying to form a low-corrosion mirror silver high-pressure impact resistant ink layer;
C. printing light diffusion ink with light diffusion performance on the surface of the low-corrosion mirror silver high-pressure impact resistant ink layer, and drying;
D. the clear gray ink was printed locally on the photodiffusion ink and dried.
In the using method, in the step A, compared with polymethyl methacrylate, polymer modified resin, carbon black, ethylene glycol monobutyl ether and an auxiliary agent, the hardening agent added into the low-corrosion mirror silver high-pressure impact resistant ink is 5-10 parts by weight; the hardener comprises methyl cyclohexanone and ethylene glycol monobutyl ether, and the mass ratio of the methyl cyclohexanone to the ethylene glycol monobutyl ether is 5: 95.
in the using method of the invention, in the step B, the low-corrosion mirror silver high-pressure impact resistant ink added with the hardening agent is printed by a screen printing mode, and the screen printing plate for printing adopts 250-350 meshes.
In the using method of the invention, in step B, C, the drying condition is baking and drying for 10-15min at 70-80 ℃; in the step D, the drying condition is baking and drying for 20-30min at the temperature of 70-80 ℃.
In the using method of the invention, in the step B, the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact resistant ink layer is more than or equal to 20 mu m.
The low-corrosion mirror silver high-pressure impact resistance ink and the use method thereof have the following beneficial effects: the low-corrosion mirror silver high-voltage impact resistant ink disclosed by the invention is low in corrosion to the mirror silver ink, good in insulativity, free of burning-out points after voltage impact, and still capable of keeping good adhesion after being mounted and covered with double-sided adhesive tape and placed for 12 hours.
Detailed Description
The low corrosion specular silver ink and the method of using the same according to the present invention will be further described with reference to the following examples:
the invention relates to a low-corrosion mirror silver high-pressure impact resistant ink which is mainly used for various PC and acrylic materials.
The low-corrosion mirror silver high-pressure impact resistant ink comprises the following components in parts by mass: 25-35 parts of polymethyl methacrylate, 25-30 parts of polymer modified resin, 10-20 parts of carbon black, 20-30 parts of ethylene glycol monobutyl ether and 2-5 parts of an auxiliary agent. Preferably, the low-corrosion mirror silver high-pressure impact resistant ink comprises the following components in parts by mass: 28-33 parts of polymethyl methacrylate, 27-28 parts of polymer modified resin, 13-18 parts of carbon black, 22-25 parts of ethylene glycol monobutyl ether and 2-3 parts of an auxiliary agent. The components are stirred and mixed uniformly to obtain the low-corrosion mirror silver high-pressure impact resistant ink.
The auxiliary agent comprises dimethyl silicone oil and dimethyl polysiloxane, and the mass parts of the dimethyl silicone oil and the dimethyl polysiloxane in the auxiliary agent are as follows: 0.5-2 parts of dimethyl silicone oil and 1-3 parts of dimethyl polysiloxane.
The polymerization modified resin is a homopolymer polymerization modified resin obtained by reacting 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] and dioxirane. Wherein the mass ratio of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] to the diepoxy ethane is 50-75: 35. specifically, 2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] is added into a reactor, then diepoxy ethane is added step by step, and the mixture is sealed and reacted for 80min to 120min at room temperature to obtain the polymer modified resin of homopolymer.
Wherein, CAS number of carbon black: 1333-86-4; CAS number of dimethicone: 9016-00-6; CAS number of dimethicone: 63148-62-9; CAS number of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene carboxaldehyde) ]: 9003-21-8; dioxirane CAS: 25085-99-8.
The application method of the low-corrosion mirror silver high-pressure impact resistant ink comprises the following steps:
A. adding a hardening agent into the low-corrosion mirror silver high-pressure impact resistant ink, and uniformly stirring; compared with polymethyl methacrylate, polymer modified resin, carbon black, ethylene glycol monobutyl ether and auxiliary agent, the hardening agent has the mass portion of 5-10; the hardener comprises methyl cyclohexanone and ethylene glycol monobutyl ether, the mass ratio of the methyl cyclohexanone to the ethylene glycol monobutyl ether is 5: 95, the hardener is preferably JM-100 hardener of Shenzhen Hao Xinzhu science and technology Limited;
B. printing mirror silver ink by a screen printing mode, and drying the surface; printing low-corrosion mirror silver high-pressure impact resistant ink added with a hardening agent on the surface of the mirror silver ink; the screen printing plate for printing adopts 250-350 meshes; then baking and drying the silver paste at the temperature of between 70 and 80 ℃ for 10 to 15 minutes to form a low-corrosion mirror silver high-pressure impact-resistant ink layer; the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-voltage impact resistant ink layer is more than or equal to 20 micrometers, preferably 20-25 micrometers, and the voltage impact resistant effect is good; mirror silver ink can be used, for example, from Shenzhen Yin Tanzhen ink company;
C. printing light diffusion printing ink on the surface of the low-corrosion mirror silver high-pressure impact resistant printing ink layer, preferably printing the light diffusion printing ink on a full plate, and baking and drying for 10-15min at the temperature of 70-80 ℃; the light diffusion ink can be PET DYH-112A type ink of Meilihua company;
D. partially printing transparent gray ink on the photodiffusion ink, and baking and drying the printed transparent gray ink for 20 to 30 minutes at the temperature of between 70 and 80 ℃ to improve the curing adhesive force of the low-corrosion mirror silver high-pressure impact resistant ink on the mirror silver ink; the transparent gray ink comprises 9100 gloss oil and 9092 black ink of ten Japanese companies, and the mass ratio of the 9100 gloss oil to the 9092 black ink is 60-90: 20.
the following is a detailed description of specific examples.
Example 1
50kg of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] is added into a reactor, 35kg of diepoxy ethane is gradually added, and the mixture is sealed and reacted for 80min at room temperature to obtain the polymer modified resin of homopolymer.
25kg of polymethyl methacrylate, 25kg of polymerization modified resin, 10kg of carbon black, 20kg of ethylene glycol monobutyl ether, 0.666kg of dimethyl silicone oil and 1.334kg of dimethyl polysiloxane are taken, stirred and mixed uniformly to obtain the low-corrosion mirror silver high-pressure impact resistant ink.
In the using process, 5kg of JM-100 hardener is added into the low-corrosion mirror silver high-pressure impact resistant ink, and the mixture is uniformly stirred; screen printing mirror silver ink by using a 250-mesh screen plate, and drying the surface; the method comprises the steps of screen printing low-corrosion mirror silver high-pressure impact ink added with a hardening agent on the surface of mirror silver ink by using a 250-mesh screen plate, and then baking and drying for 10min at 80 ℃ to form a low-corrosion mirror silver high-pressure impact ink layer, wherein the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact ink layer is more than or equal to 20 mu m; printing light diffusion printing ink on the surface of the low-corrosion mirror silver high-pressure impact resistant printing ink layer in a full-page mode, and baking and drying the printing ink for 10min at the temperature of 80 ℃; partially printing transparent gray ink on the photodiffusion ink, and baking and drying the transparent gray ink at the temperature of 80 ℃ for 20min, wherein the transparent gray ink comprises 9100 gloss oil and 9092 black ink of ten Japanese companies, and the mass ratio of the 9100 gloss oil to the 9092 black ink is 60: 20.
the low-corrosion mirror silver high-voltage impact resistant ink disclosed by the embodiment has low corrosion to the mirror silver ink, good insulativity and no burning point after voltage impact, and still keeps good adhesion after being mounted and covered with double faced adhesive tapes and placed for 12 hours.
Example 2
75kg of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] is added into a reactor, 35kg of diepoxy ethane is gradually added, and the mixture is sealed and reacted for 120min at room temperature to obtain the polymer modified resin of homopolymer.
Taking 35kg of polymethyl methacrylate, 30kg of polymerization modified resin, 20kg of carbon black, 30kg of ethylene glycol monobutyl ether, 2kg of dimethyl silicone oil and 3kg of dimethyl polysiloxane, and uniformly stirring and mixing to obtain the low-corrosion mirror silver high-pressure impact resistant ink.
In the using process, 10kg of JM-100 hardener is added into the low-corrosion mirror silver high-pressure impact resistant ink, and the mixture is uniformly stirred; screen printing mirror silver ink by using a 350-mesh screen plate, and drying the surface; the method comprises the steps of screen printing low-corrosion mirror silver high-pressure impact ink added with a hardening agent on the surface of mirror silver ink by using a 350-mesh screen plate, and then baking and drying for 15min at 70 ℃ to form a low-corrosion mirror silver high-pressure impact ink layer, wherein the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact ink layer is more than or equal to 20 mu m; printing light diffusion printing ink on the surface of the low-corrosion mirror silver high-pressure impact resistant printing ink layer in a full-page mode, and baking and drying the printing ink at the temperature of 70 ℃ for 15 min; partially printing transparent gray ink on the photodiffusion ink, and baking and drying the transparent gray ink at 70 ℃ for 30min, wherein the transparent gray ink comprises 9100 gloss oil and 9092 black ink of ten Japanese companies, and the mass ratio of the 9100 gloss oil to the 9092 black ink is 90: 20.
the low-corrosion mirror silver high-voltage impact resistant ink disclosed by the embodiment has low corrosion to the mirror silver ink, good insulativity and no burning point after voltage impact, and still keeps good adhesion after being mounted and covered with double faced adhesive tapes and placed for 12 hours.
Example 3
55kg of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] is added into a reactor, 35kg of diepoxy ethane is gradually added, and the mixture is sealed and reacted for 110min at room temperature to obtain the polymer modified resin of homopolymer.
28kg of polymethyl methacrylate, 27kg of polymerization modified resin, 13kg of carbon black, 22kg of ethylene glycol monobutyl ether, 1kg of dimethyl silicone oil and 1kg of dimethyl polysiloxane are taken, stirred and mixed uniformly to obtain the low-corrosion mirror silver high-pressure impact resistant ink.
In the using process, 6kg of JM-100 hardener is added into the low-corrosion mirror silver high-pressure impact resistant ink, and the mixture is uniformly stirred; screen printing mirror silver ink by using a 280-mesh screen plate, and drying the surface; the method comprises the steps of screen printing low-corrosion mirror silver high-pressure impact ink added with a hardening agent on the surface of mirror silver ink by using a 280-mesh screen plate, and then baking and drying for 15min at 75 ℃ to form a low-corrosion mirror silver high-pressure impact ink layer, wherein the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact ink layer is more than or equal to 20 mu m; printing light diffusion printing ink on the surface of the low-corrosion mirror silver high-pressure impact resistant printing ink layer in a full-page mode, and baking and drying the printing ink for 15min at the temperature of 75 ℃; partially printing transparent gray ink on the photodiffusion ink, and baking and drying the transparent gray ink at 75 ℃ for 25min, wherein the transparent gray ink comprises 9100 gloss oil and 9092 black ink of ten Japanese companies, and the mass ratio of the 9100 gloss oil to the 9092 black ink is 70: 20.
the low-corrosion mirror silver high-voltage impact resistant ink disclosed by the embodiment has low corrosion to the mirror silver ink, good insulativity and no burning point after voltage impact, and still keeps good adhesion after being mounted and covered with double faced adhesive tapes and placed for 12 hours.
Example 4
70kg of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] is added into a reactor, 35kg of diepoxy ethane is gradually added, and the mixture is sealed and reacted for 100min at room temperature to obtain the polymer modified resin of homopolymer.
33kg of polymethyl methacrylate, 28kg of polymerization modified resin, 18kg of carbon black, 25kg of ethylene glycol monobutyl ether, 1kg of dimethyl silicone oil and 2kg of dimethyl polysiloxane are taken, stirred and mixed uniformly to obtain the low-corrosion mirror silver high-pressure impact resistant ink.
In the using process, 9kg of JM-100 hardener is added into the low-corrosion mirror silver high-pressure impact resistant ink, and the mixture is uniformly stirred; screen printing mirror silver ink by using a 320-mesh screen plate, and drying the surface; the low-corrosion mirror silver high-pressure impact resistant ink added with a hardening agent is screen-printed on the surface of the mirror silver ink by using a 320-mesh screen plate, and then is baked and dried for 10min at the temperature of 75 ℃ to form a low-corrosion mirror silver high-pressure impact resistant ink layer, wherein the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact resistant ink layer is more than or equal to 20 mu m; printing light diffusion printing ink on the surface of the low-corrosion mirror silver high-pressure impact resistant printing ink layer in a full-page mode, and baking and drying the printing ink for 10min at the temperature of 75 ℃; partially printing transparent gray ink on the photodiffusion ink, and baking and drying the transparent gray ink at 75 ℃ for 20min, wherein the transparent gray ink comprises 9100 gloss oil and 9092 black ink of ten Japanese companies, and the mass ratio of the 9100 gloss oil to the 9092 black ink is 85: 20.
the low-corrosion mirror silver high-voltage impact resistant ink disclosed by the embodiment has low corrosion to the mirror silver ink, good insulativity and no burning point after voltage impact, and still keeps good adhesion after being mounted and covered with double faced adhesive tapes and placed for 12 hours.
Example 5
65kg of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] is added into a reactor, 35kg of diepoxy ethane is gradually added, and the mixture is sealed and reacted for 90min at room temperature to obtain the polymer modified resin of homopolymer.
30kg of polymethyl methacrylate, 28kg of polymerization modified resin, 15kg of carbon black, 23kg of ethylene glycol monobutyl ether, 1.5kg of dimethyl silicone oil and 2.5kg of dimethyl polysiloxane are taken, stirred and mixed uniformly to obtain the low-corrosion mirror silver high-pressure impact resistant ink.
In the using process, 8kg of JM-100 hardener is added into the low-corrosion mirror silver high-pressure impact resistant ink, and the mixture is uniformly stirred; screen printing mirror silver ink by using a 300-mesh screen plate, and drying the surface; the method comprises the steps of screen printing low-corrosion mirror silver high-pressure impact ink added with a hardening agent on the surface of mirror silver ink by using a 300-mesh screen plate, and then baking and drying for 10min at 75 ℃ to form a low-corrosion mirror silver high-pressure impact ink layer, wherein the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact ink layer is more than or equal to 20 mu m; printing light diffusion printing ink on the surface of the low-corrosion mirror silver high-pressure impact resistant printing ink layer in a full-page mode, and baking and drying the printing ink for 10min at the temperature of 75 ℃; partially printing transparent gray ink on the photodiffusion ink, and baking and drying the printed transparent gray ink at 75 ℃ for 30min, wherein the transparent gray ink comprises 9100 gloss oil and 9092 black ink of ten Japanese companies, and the mass ratio of the 9100 gloss oil to the 9092 black ink is 75: 20.
the low-corrosion mirror silver high-voltage impact resistant ink disclosed by the embodiment has low corrosion to the mirror silver ink, good insulativity and no burning point after voltage impact, and still keeps good adhesion after being mounted and covered with double faced adhesive tapes and placed for 12 hours.
Example 6
65kg of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene formaldehyde) ] is added into a reactor, 35kg of diepoxy ethane is gradually added, and the mixture is sealed and reacted for 90min at room temperature to obtain the polymer modified resin of homopolymer.
33kg of polymethyl methacrylate, 28kg of polymerization modified resin, 15kg of carbon black, 22kg of ethylene glycol monobutyl ether, 0.5kg of dimethyl silicone oil and 1.5kg of dimethyl polysiloxane are taken, stirred and mixed uniformly to obtain the low-corrosion mirror silver high-pressure impact resistant ink.
In the using process, 5kg of JM-100 hardener is added into the low-corrosion mirror silver high-pressure impact resistant ink, and the mixture is uniformly stirred; screen printing mirror silver ink by using a 300-mesh screen plate, and drying the surface; the method comprises the steps of screen printing low-corrosion mirror silver high-pressure impact ink added with a hardening agent on the surface of mirror silver ink by using a 300-mesh screen plate, and then baking and drying for 10min at 75 ℃ to form a low-corrosion mirror silver high-pressure impact ink layer, wherein the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact ink layer is more than or equal to 20 mu m; printing light diffusion printing ink on the surface of the low-corrosion mirror silver high-pressure impact resistant printing ink layer in a full-page mode, and baking and drying the printing ink for 10min at the temperature of 75 ℃; partially printing transparent gray ink on the photodiffusion ink, and baking and drying the transparent gray ink at 75 ℃ for 30min, wherein the transparent gray ink comprises 9100 gloss oil and 9092 black ink of ten Japanese companies, and the mass ratio of the 9100 gloss oil to the 9092 black ink is 80: 20.
the low-corrosion mirror silver high-voltage impact resistant ink disclosed by the embodiment has low corrosion to the mirror silver ink, good insulativity and no burning point after voltage impact, and still keeps good adhesion after being mounted and covered with double faced adhesive tapes and placed for 12 hours.
It will be understood that modifications and variations can be made by persons skilled in the art in light of the above teachings, and all such modifications and variations are intended to be included within the scope of the invention as defined in the appended claims.
Claims (10)
1. The low-corrosion mirror silver high-pressure impact resistance ink is characterized by comprising the following components in parts by mass: 25-35 parts of polymethyl methacrylate, 25-30 parts of polymer modified resin, 10-20 parts of carbon black, 20-30 parts of ethylene glycol monobutyl ether and 2-5 parts of an auxiliary agent.
2. The low-corrosion mirror silver high-pressure impact resistant ink according to claim 1, which comprises the following components in parts by mass: 28-33 parts of polymethyl methacrylate, 27-28 parts of polymer modified resin, 13-18 parts of carbon black, 22-25 parts of ethylene glycol monobutyl ether and 2-3 parts of an auxiliary agent.
3. The low-corrosion mirror silver high-pressure impact resistant ink as claimed in claim 1 or 2, wherein the auxiliary agent comprises dimethicone and dimethicone, and the mass parts ratio of the dimethicone to the dimethicone in the auxiliary agent is as follows: 0.5-2 parts of dimethyl silicone oil and 1-3 parts of dimethyl polysiloxane.
4. The low corrosion specular silver high pressure impact resistant ink according to claim 1 or 2, wherein the polymeric modifying resin is a homopolymer obtained by reacting 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene carboxaldehyde) ] and dioxirane.
5. The low corrosion mirror silver high pressure impact resistant ink according to claim 4, wherein the mass ratio of 2,2' - [ (1-methylethylidene) bis (4, 1-phenylene carboxaldehyde) ] to dioxirane is 50 to 75: 35.
6. a method of using the low-corrosion specular silver high-pressure impact resistant ink of any one of claims 1 to 5, comprising:
A. adding a hardening agent into the low-corrosion mirror silver high-pressure impact resistant ink;
B. printing low-corrosion mirror silver high-pressure impact resistant ink added with a hardening agent on the surface of the mirror silver ink, and drying to form a low-corrosion mirror silver high-pressure impact resistant ink layer;
C. printing light diffusion ink with light diffusion performance on the surface of the low-corrosion mirror silver high-pressure impact resistant ink layer, and drying;
D. the clear gray ink was printed locally on the photodiffusion ink and dried.
7. The use method of claim 6, wherein in the step A, compared with polymethyl methacrylate, polymeric modified resin, carbon black, ethylene glycol monobutyl ether and auxiliary agent, the hardening agent is added into the low-corrosion mirror silver high-pressure impact resistant ink, and the mass part of the hardening agent is 5-10 parts; the hardener comprises methyl cyclohexanone and ethylene glycol monobutyl ether, and the mass ratio of the methyl cyclohexanone to the ethylene glycol monobutyl ether is 5: 95.
8. the use method as claimed in claim 6, wherein in step B, the low corrosion mirror silver high pressure impact resistant ink added with the hardening agent is printed by screen printing, and the screen printing plate is 250-350 mesh.
9. The use method according to claim 6, wherein in the step B, C, the drying condition is baking drying at 70-80 ℃ for 10-15 min; in the step D, the drying condition is baking and drying for 20-30min at the temperature of 70-80 ℃.
10. The use method of claim 6, wherein in the step B, the total thickness of the ink layer of the mirror silver ink and the low-corrosion mirror silver high-pressure impact resistant ink layer is more than or equal to 20 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910080508.XA CN111484765A (en) | 2019-01-28 | 2019-01-28 | Low-corrosion mirror silver high-pressure impact resistant ink and use method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910080508.XA CN111484765A (en) | 2019-01-28 | 2019-01-28 | Low-corrosion mirror silver high-pressure impact resistant ink and use method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111484765A true CN111484765A (en) | 2020-08-04 |
Family
ID=71791298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910080508.XA Pending CN111484765A (en) | 2019-01-28 | 2019-01-28 | Low-corrosion mirror silver high-pressure impact resistant ink and use method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111484765A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694644A (en) * | 2013-12-30 | 2014-04-02 | 景旺电子科技(龙川)有限公司 | Epoxy resin composition, metal-based copper-clad plate and manufacturing method thereof |
| CN104231994A (en) * | 2013-06-19 | 2014-12-24 | 聚鼎科技股份有限公司 | Adhesive material |
| CN105199479A (en) * | 2015-09-02 | 2015-12-30 | 王景泉 | Black ink for mylar prepared on basis of PET (polyester) materials and preparation method of black ink |
-
2019
- 2019-01-28 CN CN201910080508.XA patent/CN111484765A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231994A (en) * | 2013-06-19 | 2014-12-24 | 聚鼎科技股份有限公司 | Adhesive material |
| CN103694644A (en) * | 2013-12-30 | 2014-04-02 | 景旺电子科技(龙川)有限公司 | Epoxy resin composition, metal-based copper-clad plate and manufacturing method thereof |
| CN105199479A (en) * | 2015-09-02 | 2015-12-30 | 王景泉 | Black ink for mylar prepared on basis of PET (polyester) materials and preparation method of black ink |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111117342A (en) | Preparation method of high-covering UV resin film | |
| CN111117340B (en) | UV ink film | |
| CN109627695B (en) | Shape memory wave-absorbing material and preparation method thereof | |
| CN110903790A (en) | UV (ultraviolet) viscosity-reducing composition and UV viscosity-reducing adhesive tape with same | |
| CN111154442B (en) | Environment-friendly high-temperature-resistant modified epoxy resin adhesive and preparation method thereof | |
| CN112300661A (en) | High-temperature-resistant coating and application thereof | |
| CN112745787A (en) | High-heat-dissipation pressure-sensitive adhesive and high-heat-dissipation sub-sensitive adhesive tape | |
| CN116285774A (en) | Epoxy adhesive, cover film and printing screen | |
| CN111484765A (en) | Low-corrosion mirror silver high-pressure impact resistant ink and use method thereof | |
| CN103694639A (en) | Halogen-free anti-aging epoxy resin composition and method for preparing cover film by using same | |
| CN109134825B (en) | Modified epoxy resin and preparation and application thereof | |
| CN113736040A (en) | Acrylic acid modified epoxy resin and preparation method and application thereof | |
| CN113025265A (en) | Preparation method of solvent type organic silicon glue for manufacturing optical transparent adhesive film | |
| CN111040663B (en) | Soybean-based protein adhesive for artificial board and preparation method thereof | |
| CN115785862B (en) | Bio-based anti-warping acrylic pressure-sensitive adhesive and preparation method thereof | |
| CN112409891A (en) | Thermosetting powder coating | |
| CN108913065A (en) | A kind of conductive fabric glue and preparation method thereof | |
| CN1244661C (en) | Thermosetting rubber film for flexible circuit assembly and its preparing method | |
| CN112409885A (en) | Corrosion-resistant water-based epoxy floor paint and preparation method thereof | |
| CN112048276A (en) | Shading glue for electronic product and preparation method thereof | |
| WO2020157616A1 (en) | Photocurable adhesive composition and photocurable adhesive tape | |
| CN110791235A (en) | Intelligent watch sealant and preparation method thereof | |
| CN110845881A (en) | Super-printing-resistant photosensitive material and screen printing plate | |
| JP2000171973A (en) | Photosensitive resin composition and photosensitive resin composition for solder resist | |
| JPH08245833A (en) | Thermosetting resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200804 |