CN111454681A - Double-component flame-retardant ceramic tile crack beautifying agent and preparation method thereof - Google Patents
Double-component flame-retardant ceramic tile crack beautifying agent and preparation method thereof Download PDFInfo
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- CN111454681A CN111454681A CN202010422833.2A CN202010422833A CN111454681A CN 111454681 A CN111454681 A CN 111454681A CN 202010422833 A CN202010422833 A CN 202010422833A CN 111454681 A CN111454681 A CN 111454681A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
- C08G59/4207—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof aliphatic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention provides a double-component flame-retardant ceramic tile crack beautifying agent which comprises a component A and a component B, wherein the component A comprises the following raw materials in parts by weight: 90-100 parts of flame-retardant epoxy resin and 4-6 parts of thickening agent; the component B comprises the following raw materials: 20-30 parts of curing agent, 3-5 parts of flatting agent, 5-7 parts of flow stopping agent and 30-50 parts of thixotropic agent. The invention also provides a method for preparing the seam beautifying agent, which comprises the following steps: (1) uniformly mixing the raw materials of the component A to obtain the component A; (2) uniformly mixing the raw materials of the component B to obtain the component B; (3) and mixing the component A and the component B according to the weight ratio of 1: 0.5-1.5, and uniformly stirring to obtain the crack sealer. The product prepared by the invention has the advantages of flat and smooth surface of the cured adhesive film, good wear resistance, high adhesion strength, difficult scratch and flame retardance, and can be applied to gaps on the wall surface.
Description
Technical Field
The invention relates to the technical field of crack beautifying agents, in particular to a double-component flame-retardant ceramic tile crack beautifying agent and a preparation method thereof.
Background
The seam beautifying agent is a novel adhesive for seam decoration, has the characteristics of various colors, bright color, safety, environmental protection, no mildew, easy cleaning and the like, and has good development prospect. At present, the following problems exist in the common crack sealer on the market: firstly, the adhesive strength of the cured adhesive film is not high enough, and the adhesive film is easy to fall off; secondly, the cured adhesive film is soft and easily scratched and abraded; and thirdly, the surface is rough, the gap is easy to blacken after curing, and the coating is not suitable for the gap on the wall surface, and the sagging phenomenon is easy to occur.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art. Therefore, the invention provides a double-component flame-retardant ceramic tile crack beautifying agent which comprises a component A and a component B, wherein the weight ratio of the component A to the component B is 1: 0.5-1.5,
the component A comprises the following raw materials in parts by weight:
90-100 parts of flame-retardant epoxy resin,
4-6 parts of a thickening agent;
the component B comprises the following raw materials in parts by weight:
further, the flame-retardant epoxy resin is phosphonitrile trichloride epoxy resin.
Further, the curing agent is maleic anhydride.
Further, the leveling agent is polyamide.
Further, the flow stopping agent is diacetone alcohol.
Further, the thickening agent and the thixotropic agent are fumed silica.
Further, the component B also comprises 20-30 parts of rutile titanium dioxide.
On the other hand, the invention also provides a preparation method of the crack sealer, which comprises the following steps:
(1) mixing the flame-retardant epoxy resin and the thickening agent in parts by weight, and uniformly stirring to obtain the component A;
(2) mixing the curing agent, the flatting agent, the flow stopping agent and the thixotropic agent in parts by weight, and uniformly stirring to obtain the component B;
(3) and mixing the component A and the component B according to the weight ratio of 1: 0.5-1.5, and uniformly stirring to obtain the crack sealer.
The ceramic tile crack beautifying agent provided by the invention is simple in preparation method and easy to operate, and the prepared product has the advantages of flat and smooth adhesive film surface after being cured, good wear resistance, high adhesion strength, difficulty in scratching, flame retardance, applicability to gaps on the ground and wall surfaces and wide application range.
According to the invention, the phosphonitrile trichloride epoxy resin is adopted to be matched with the maleic anhydride curing agent and the fumed silica thixotropic agent, so that the adhesive film cured by the crack sealer has good wear resistance, high adhesive strength and low possibility of scratching, and meanwhile, the crack sealer has flame retardance; the polyamide flatting agent enables the surface of the solidified adhesive film to be flat and smooth; the diacetone alcohol flow stopping agent prevents the phenomenon of sagging, so that the crack beautifying agent can be better suitable for cracks on the wall surface.
Detailed Description
The invention of the present application is further illustrated below with reference to examples, which should not be construed as limiting the claims. In the description herein, references to the description of the term "one embodiment," "some embodiments," "an illustrative embodiment," "an example," "a specific example," or "some examples" or the like mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
Example 1:
a double-component flame-retardant ceramic tile crack beautifying agent, which comprises a component A and a component B,
the component A comprises the following raw materials in parts by weight:
90 parts of flame-retardant epoxy resin,
4 parts of a thickening agent;
the component B comprises the following raw materials in parts by weight:
the flame-retardant epoxy resin is phosphonitrile trichloride epoxy resin, the curing agent is maleic anhydride, the leveling agent is polyamide, the flow stopping agent is diacetone alcohol, and the thickening agent and the thixotropic agent are fumed silica.
A method for preparing the crack sealer comprises the following steps:
(1) mixing the flame-retardant epoxy resin and the thickening agent in parts by weight, and uniformly stirring to obtain the component A;
(2) mixing the curing agent, the flatting agent, the flow stopping agent, the thixotropic agent and the rutile titanium dioxide according to parts by weight, and uniformly stirring to obtain the component B;
(3) and mixing the component A and the component B according to the weight ratio of 1:0.5, and uniformly stirring to obtain the crack sealer.
Example 2:
a double-component flame-retardant ceramic tile crack beautifying agent, which comprises a component A and a component B,
the component A comprises the following raw materials in parts by weight:
95 parts of flame-retardant epoxy resin,
5 parts of a thickening agent;
the component B comprises the following raw materials in parts by weight:
the flame-retardant epoxy resin is phosphonitrile trichloride epoxy resin, the curing agent is maleic anhydride, the leveling agent is polyamide, the flow stopping agent is diacetone alcohol, and the thickening agent and the thixotropic agent are fumed silica.
A method for preparing the crack sealer comprises the following steps:
(1) mixing the flame-retardant epoxy resin and the thickening agent in parts by weight, and uniformly stirring to obtain the component A;
(2) mixing the curing agent, the flatting agent, the flow stopping agent, the thixotropic agent and the rutile titanium dioxide according to parts by weight, and uniformly stirring to obtain the component B;
(3) and mixing the component A and the component B according to the weight ratio of 1:1, and uniformly stirring to obtain the crack sealer.
Example 3:
a double-component flame-retardant ceramic tile crack beautifying agent, which comprises a component A and a component B,
the component A comprises the following raw materials in parts by weight:
100 parts of flame-retardant epoxy resin,
6 parts of a thickening agent;
the component B comprises the following raw materials in parts by weight:
the flame-retardant epoxy resin is phosphonitrile trichloride epoxy resin, the curing agent is maleic anhydride, the leveling agent is polyamide, the flow stopping agent is diacetone alcohol, and the thickening agent and the thixotropic agent are fumed silica.
A method for preparing the crack sealer comprises the following steps:
(1) mixing the flame-retardant epoxy resin and the thickening agent in parts by weight, and uniformly stirring to obtain the component A;
(2) mixing the curing agent, the flatting agent, the flow stopping agent, the thixotropic agent and the rutile titanium dioxide according to parts by weight, and uniformly stirring to obtain the component B;
(3) and mixing the component A and the component B according to the weight ratio of 1:1.5, and uniformly stirring to obtain the crack sealer.
Example 4:
the seam beautifying agents prepared in the embodiments 1 to 3 are subjected to performance tests, and the specific test method is as follows:
(1) testing the wear resistance, namely testing according to GB/T1768-2006, and determining by adopting a rubber grinding wheel with the model number of CS-17, wherein the size of a test piece is 100mm, × 100mm, × 6 mm;
(2) and (3) testing the adhesive strength performance: the test is carried out according to GB/T5210, the diameter of the test column is 20mm, the bonding base material is an unglazed brick, and the bonding thickness is 1 mm;
(3) sag performance test: the test was carried out according to GB/T13477.6, the internal dimensions of the cross-section of the sagging die channel being 10mm wide and 5mm deep, the test temperature being 23 ℃.
The results of the performance test are shown in Table 1
TABLE 1
While embodiments of the invention have been shown and described, it will be understood by those of ordinary skill in the art that: various changes, modifications, substitutions and alterations can be made to the embodiments without departing from the principles and spirit of the invention, the scope of which is defined by the claims and their equivalents.
Claims (8)
1. A double-component flame-retardant ceramic tile crack beautifying agent is characterized by comprising a component A and a component B, wherein the weight ratio of the component A to the component B is 1: 0.5-1.5,
the component A comprises the following raw materials in parts by weight:
90-100 parts of flame-retardant epoxy resin,
4-6 parts of a thickening agent;
the component B comprises the following raw materials in parts by weight:
2. the two-component flame-retardant tile crack sealer according to claim 1, wherein the flame-retardant epoxy resin is a phosphonitrile trichloride epoxy resin.
3. The two-component flame-retardant tile crack sealer according to claim 1, wherein the curing agent is maleic anhydride.
4. The two-component flame retardant tile crack sealer according to claim 1, wherein the leveling agent is polyamide.
5. The two-component flame-retardant tile crack sealer according to claim 1, wherein the flow-stopping agent is diacetone alcohol.
6. The two-component flame-retardant tile crack sealer according to claim 1, wherein the thickener and the thixotropic agent are fumed silica.
7. The two-component flame-retardant tile crack sealer according to claim 1, wherein the raw material composition of the component B further comprises 20-30 parts of rutile titanium dioxide.
8. A method for preparing the crack sealer of claim 1, comprising the steps of:
(1) mixing the flame-retardant epoxy resin and the thickening agent in parts by weight, and uniformly stirring to obtain the component A;
(2) mixing the curing agent, the flatting agent, the flow stopping agent and the thixotropic agent in parts by weight, and uniformly stirring to obtain the component B;
(3) and mixing the component A and the component B according to the weight ratio of 1: 0.5-1.5, and uniformly stirring to obtain the crack sealer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010422833.2A CN111454681B (en) | 2020-05-19 | 2020-05-19 | Double-component flame-retardant ceramic tile crack beautifying agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010422833.2A CN111454681B (en) | 2020-05-19 | 2020-05-19 | Double-component flame-retardant ceramic tile crack beautifying agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN111454681A true CN111454681A (en) | 2020-07-28 |
| CN111454681B CN111454681B (en) | 2022-03-11 |
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| CN202010422833.2A Active CN111454681B (en) | 2020-05-19 | 2020-05-19 | Double-component flame-retardant ceramic tile crack beautifying agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114940862A (en) * | 2022-07-26 | 2022-08-26 | 山东永安胶业有限公司 | Preparation method of bi-component flame-retardant polyurea crack sealer |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105555053A (en) * | 2015-12-24 | 2016-05-04 | 深圳市志凌伟业技术股份有限公司 | Method for reinforcing and binding flexible circuit board and sensor and component for method |
| CN105802451A (en) * | 2016-06-02 | 2016-07-27 | 湖南柯盛新材料有限公司 | Two-component epoxy decorating sealant and preparation method thereof |
| CN109705783A (en) * | 2018-11-16 | 2019-05-03 | 惠州泓海新材料科技有限公司 | A kind of fire retarding epoxide resin joint trimming agent and preparation method thereof |
| CN110003830A (en) * | 2018-12-18 | 2019-07-12 | 海南必凯水性新材料有限公司 | A kind of epoxy adhesive with high-adhesive-strength |
| CN110408171A (en) * | 2018-04-26 | 2019-11-05 | 江苏飞锦毅科技有限公司 | A kind of two-component negative oxygen ion joint trimming agent and preparation method thereof |
| CN110791242A (en) * | 2019-10-17 | 2020-02-14 | 广州化工研究设计院有限公司 | Bi-component epoxy seam beautifying agent and preparation method thereof |
-
2020
- 2020-05-19 CN CN202010422833.2A patent/CN111454681B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105555053A (en) * | 2015-12-24 | 2016-05-04 | 深圳市志凌伟业技术股份有限公司 | Method for reinforcing and binding flexible circuit board and sensor and component for method |
| CN105802451A (en) * | 2016-06-02 | 2016-07-27 | 湖南柯盛新材料有限公司 | Two-component epoxy decorating sealant and preparation method thereof |
| CN110408171A (en) * | 2018-04-26 | 2019-11-05 | 江苏飞锦毅科技有限公司 | A kind of two-component negative oxygen ion joint trimming agent and preparation method thereof |
| CN109705783A (en) * | 2018-11-16 | 2019-05-03 | 惠州泓海新材料科技有限公司 | A kind of fire retarding epoxide resin joint trimming agent and preparation method thereof |
| CN110003830A (en) * | 2018-12-18 | 2019-07-12 | 海南必凯水性新材料有限公司 | A kind of epoxy adhesive with high-adhesive-strength |
| CN110791242A (en) * | 2019-10-17 | 2020-02-14 | 广州化工研究设计院有限公司 | Bi-component epoxy seam beautifying agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 谢荣化: "《塑料购销手册》", 30 May 1994, 中国物资出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114940862A (en) * | 2022-07-26 | 2022-08-26 | 山东永安胶业有限公司 | Preparation method of bi-component flame-retardant polyurea crack sealer |
| CN114940862B (en) * | 2022-07-26 | 2022-09-27 | 山东永安胶业有限公司 | Preparation method of bi-component flame-retardant polyurea crack sealer |
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| Publication number | Publication date |
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| CN111454681B (en) | 2022-03-11 |
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