CN1114536A - Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce - Google Patents
Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce Download PDFInfo
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Abstract
The present invention relates to a preparation method of aflatoxin-free low-sodium salt health-care soya sauce extract. Said invention uses soybean cake or peanut cake and wheat bran as raw materials nd adds the auxiliary materials of edible fungus, yeast and lecithin, and firstly uses one of ammonia or ammonia water soaking disinfection method, chlorine water or sodium hypochlorite solution soaking disinfection method nd tween-80 aqueous solution soaking disinfection method to remove aflatoxin from the raw materials exceeding standard index, and then adds dilute hydrochloric acid to hydrolyze, uses dilute alkali liquor to make neutralization, and adds potassium chloride, potassium dihydrogen phosphate and preservative in its filtrate, so that the invented soya sauce extract without aflatoxin can be obtained.
Description
The present invention relates to a kind of preparation method of flavouring.
As everyone knows, the traditional preparation process method of soy sauce is to adopt to brewage fermentation method (being enzyme hydrolysis method), and its output cycle that feeds intake is long, and the hydrolysis intermediate product is many, easily dyes assorted bacterium.Along with science and technology development, people improve traditional enzyme hydrolysis legal system soy sauce, promptly adopt the acid water solution, as discussing in＜industrial chemistry〉(friendly Tian Xuanxiao work, clear and in March, 17, the 313rd page and the 318th page) in to have introduced amino acid soy sauce be with big dregs of beans hydrochloric acid hydrolysis, the amino acid mixing liquid of gained adds the soy sauce seasoning matter with in the sodium carbonate and back and just makes amino acid soy sauce.It does not have other nutritional labeling substantially again except that amino acid.And raw material that it is used such as big dregs of beans etc. are vulnerable to the pollution of some moulds such as aspergillus flavus, transfinite unexpectedly to 4000-8000PPb when serious, just remain in the soy sauce after their hydrolysis, often make aflatoxin surpass limiting the quantity of of regulation.
In view of above-mentioned weak point of the prior art, the object of the present invention is to provide a kind of with short production cycle and can eradicate the production method of the sauce extract of aflatoxin.
Purpose of the present invention can realize by following measure: a kind of Cardia Salt of eradicating aflatoxin is augmented the preparation method of health-care sauce essence, and it is with the protein raw material hydrochloric acid hydrolysis, with the alkali lye neutralization, it is characterized in that then:
(1) product of the present invention of preparation 1000 parts by weight adopts following raw material:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
(2) purified treatment of raw material
A ammonia or ammoniacal liquor embathe disintoxication: powder raw material is filtered after 3-4 hour in 35-45 ℃ of immersion with the weak aqua ammonia of the 1-2% of 4 times of weight done, the warm water with 3 times of amounts embathes 2-3 time again, soaks big gun 20-30 minute at every turn, and filter is done stand-by,
Or b chlorine water or liquor natrii hypochloritis embathe disintoxication: with powder raw material with the 1-2% aqueous sodium hypochlorite solution of 4 times of weight in 35-45 ℃ soak 3-4 hour after filter do, warm water with 3 times of amounts embathes 2-3 time again, the each immersion 20-30 minute, filter is done stand-by, or the c Tween-80 aqueous solution embathes method: powder raw material is filtered after 3-4 hour with 0.01% Tween-80 emerge in worm water of 4 times of weight done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, filter is done stand-by
(3) preparation technology
A will be through the raw material that exceeds standard of above-mentioned processing with being that the 18-20% hydrochloric acid of 2.5 times of its weight is under stirring condition or atmospheric pressure reflux 20-24 hour, or in gauge pressure 2kg/cm
2115-125 ℃ was reacted 14-16 hour,
B is cooled to 40 ℃, slowly adds the aqueous sodium carbonate of 30-36% or 20% sodium hydroxide solution under stirring condition, makes pH value between 5.5-6.0,
C filters and with quantitative deionization warm water filter wash, filtrate merging is added 0.05-0.10% potassium sorbate anticorrisive agent again.The product of the present invention of best (1) preparation 1000 parts by weight, adopt following raw material and auxiliary material:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
Edible mushroom 20-28 weight portion
Yeast 5-7 weight portion
Lecithin 5-7 weight portion
(2) purified treatment of raw material is identical with (2) in the claim 1,
(3) preparation technology
The raw material that exceeds standard that a crosses above-mentioned purified treatment is with being that the 18-20% hydrochloric acid of 2.5 times of main material weight is under stirring condition or atmospheric pressure reflux 18-20 hour, or in gauge pressure 2kg/cm
2115-125 ℃ was reacted 12-14 hour,
B is cooled to about 60 ℃, adds auxiliary material under stirring condition, and then is warmed up to 100 ℃, and under normal pressure back flow reaction 6-8 hour,
C is cooled to 40 ℃, slowly adds the aqueous sodium carbonate of 30-36% or 20% sodium hydroxide solution under stirring condition, makes pH value between 5.5-6.0,
D filters and with quantitative deionization warm water filter wash, filtrate is merged, and adds 0.05-0.10% potassium sorbate anticorrisive agent again.In product of the present invention, add the 7.6-8.0% potassium chloride of filtrate total amount and the potassium dihydrogen phosphate of 0.3-0.5%.Mushroom is 1: 1 with the weight ratio of auricularia auriculajudae in the edible mushroom.Adopt the hydrochloric acid hydrolysis of 5.5N.
The present invention carries out purified treatment with overproof vegetable protein raw material earlier, preferably adds auxiliary material, the method that adopts hydrochloric acid to be hydrolyzed then again.
Raw material of the present invention mainly contains vegetable protein, and this vegetable protein can be soybean cake dregs, peanut dregs and wheat bran.Though wherein wheat bran can be the manufacturing sauce extract protein sources is provided, but more mainly be owing to also contain a large amount of hemicelluloses (sugar contracts more) in the wheat bran, its hydrolysate combines the color that has determined soy sauce with the hydrolysate amino acid of protein, makes product possess the due style of traditional sauce extract.So the wheat bran micromicro of getting 60-108 part during 1000 parts of products of the present invention when preparation satisfies the needs of this product, remaining protein sources is then by a kind of the providing in other vegetable protein such as soybean cake dregs, the peanut dregs.When 1000 parts of products of the present invention of preparation, desirable soybean cake dregs or peanut dregs 60-100 part can meet the demands.Hydrochloric acid of the present invention is the watery hydrochloric acid of 18-20% (weight), preferably adopt the hydrochloric acid of 5.5N, addition is that 2.5 heavy multiple proportions of raw material are more suitable, and hydrolysis is incomplete very little as addition, and is also too many with the too many sodium chloride that generates of alkali as the too many neutralization of addition.For guarantee that sauce extract never degenerates in storing and using, the anticorrisive agent that is added in product of the present invention is a potassium sorbate, and it is stable that it is lower than antiseptic and inhibiting bacteria function effect in 8.0 o'clock at pH value, and pH value is low more, and its antibacterial action is strong more.Product slant acidity of the present invention, it is very suitable therefore to cook anticorrisive agent with it.When product adds the potassium sorbate of 0.05-0.10%, can satisfy anticorrosion simultaneously and needs mildew-resistant.
For increasing the nutritional labeling in the product of the present invention and improving its delicious degree, selected the auxiliary material that body-care is had help greatly for use: edible mushroom, yeast and lecithin.Wherein edible mushroom includes mushroom, mushroom, straw mushroom, flat mushroom, phoenix-tail mushroom, Hericium erinaceus, black fungus and tremella.Not only amino acid whose content is very high in these edible mushrooms, but also 8 seed amino acids that contain that human body self can not synthesize and must replenish by food.In addition nutrition of edible fungi value also shows and contains abundant vitamin and multiple metallic element.With mushroom, mushroom, flat mushroom, auricularia auriculajudae is example, and the percentage composition of potassium, magnesium, phosphorus (oxide with them calculates) is as follows in their ash content:
K2O P2O5 MgO
Pester 55.95 25.23 1.47
Mushroom 63.92 20.05 1.88
Flat mushroom 64.26 22.91 3.83
Black fungus 35.50 8.64 6.43
The edible mushroom of getting 20-28 part (dry product) when 1000 parts of products of the present invention of preparation gets final product.Because mushroom class and auricularia auriculajudae class are two class fungus strains, for replenishing mutually, the proportionate relationship of the class of preferably pestering and auricularia auriculajudae class is 1: 1.The auxiliary material that also can add has yeast in the present invention, and it can be a Saccharomyces cerevisiae, also can be brewer's yeast.They are not higher than the inosinicacid and the black thuja acid that can progressively generate nucleic acid, mononucleotide and respective numbers under 100 ℃ the hydrolysising condition in temperature.The sodium salt and the L-sodium glutamate that generate them with in the alkali and back coexist, and can make its delicate flavour increase more than tens times.The yeast effect that adds 5-7 part (dry product) when 1000 parts of products of the present invention of preparation is just more satisfactory.It is auxiliary material that the present invention also adopts lecithin, and it generates phosphoglycerol and Choline Chloride after hydrolysis, and in phosphoglycerol and the alkali and generate sodium glycero-phosphate, it is the ideal of nervous system and reproductive system and effective tonic invigorator.Choline helps preventing and treating fatty liver, strengthens memory.The lecithin that adds 5-7 part (dry product) when 1000 parts of products of the present invention of preparation can produce a desired effect.
Need to begin to test for eradicating aflatoxin, when transfiniting (15-20 μ g/kg), must carry out purified treatment as finding raw material to be subjected to aflatoxin contamination by criticizing from raw material.Earlier siccative was pulverized the 60-80 mesh sieve before processing, one of three kinds of modes below selecting are then handled:
A ammonia or ammoniacal liquor embathe disintoxication: with powder raw material with the weak aqua ammonia of the 1-2% of 4 times of weight in 35-45 ℃ soak 3-4 hour after filter do, it is dried stand-by to embathe 2-3 time (at every turn soaking 20-30 minute) filter with the warm water of 3 times of amounts again.
B chlorine water or inferior filter acid sodium solution embathe disintoxication: with powder raw material with the concentration of 4 times of weight be 1-2% filter acid sodium solution in 35-45 ℃ soak 3-4 hour after filter do, the warm water with 3 times of amounts embathes (soaking 20-30 minute) 2-3 time at every turn again, filter is dried stand-by.
The c Tween-80 aqueous solution embathes method: with powder raw material with 4 times of weight contain Tween-80 (Tween80) 0.01% emerge in worm water 3-4 hour after filter do, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, filter is dried stand-by.
Specific operation process of the present invention is as follows: get the vegetable protein metallic substance by above-mentioned proportionate relationship, getting is the hydrochloric acid that main material weighs 2.5 times 18-20% again, both evenly mix, place in the container that is provided with agitator and returned cold radiator cooler, it can be atmospheric pressure reflux 20-24 hour, also can be in gauge pressure 2kg/cm
2115-125 ℃ was reacted 14-16 hour.If want to add auxiliary material, then atmospheric pressure reflux 18-20 hour, or in gauge pressure 2kg/cm
2115-125 ℃ was reacted 12-14 hour, and was cooled to then about 60 ℃.Under stirring condition, add the various auxiliary materials of being got by the aforementioned ratio relation, and then be warmed up to 100 ℃ under normal pressure back flow reaction 6-8 hour, when sample analysis is treated the protein complete hydrolysis material in the container is cooled to below 40 ℃, low adding concentration under stirring condition is the Na2CO3 aqueous solution of 30-36%, or the hydrochloric acid in 20% the NaOH aqueous solution and the reaction vessel carries out neutralization reaction generation salt.When reaching 5.5-6.0, pH value is reaction end.Filter, and, the washing filtrate merging is added the potassium sorbate anticorrisive agent again stir with quantitative deionization warm water filter wash.The 7.6-8.0% potassium chloride that preferably adds the filtrate total amount is used for replenishing the content of potassium.Add an amount of potassium dihydrogen phosphate in addition, can make the mouthfeel of product better.The general 0.3-0.5% that adds is more suitable.Top mixture refilters after fully stirring, and can to obtain outward appearance be dark brown liquid form product to brownish black.Also can be made into the instant series of products of paste, powdery, graininess and sheet according to market demand.
The present invention has following advantage compared to existing technology:
1, the sauce extract that adopts method of the present invention to make, the content of its aflatoxin reaches the purpose of elimination basically below 5PPb,
2, method technology of the present invention simple, with short production cycle (only for brewage fermentation method 1/5), the production efficiency height,
3, the inventive method is an acidic hydrolysis, and not only proteolysis gets fully, also can not cause the optical isomerism effect of chloro acid molecule.Used hydrochloric acid is generated salt by in the alkali and back, makes it to be fully utilized, and the starchiness in the raw material has become glucose.
4, adopt product that the inventive method makes except that containing a large amount of amino acid, also contain the multiple nutritional components of needed by human, play the effect of improving the health.
5, the product that adopts the inventive method to make, its contained salt part is a potassium chloride, is fit to the Human Physiology needs so more, becomes the Cardia Salt flavouring.
Example 1
100 kilograms of big dregs of beans, 60 kilograms of the wheat brans of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve.Through check big dregs of beans to contain aflatoxin 350 μ g/kg, wheat bran contains aflatoxin 600 μ g/kg all above required standard.Adopting ammoniacal liquor to embathe disintoxication handles, being about to the above-mentioned powdery soybean dregs of rice and wheat bran filters dried with 640 kilogram 1% ammoniacal liquor in 35-45 ℃ of immersion after 4 hours, embathing 2 times (at every turn soaking 30 minutes) filter with 480 kilograms warm water again does, place in the container that is provided with agitator and returned cold radiator cooler, the hydrochloric acid that adds 5.5N again is warming up to boiling for 400 kilograms, keeping it refluxed 20 hours under normal pressure, sample analysis is after the protein complete hydrolysis, material in the container is cooled to below 40 ℃, still under stirring condition, adds 20% sodium hydrate aqueous solution lentamente.When reaching 6.0, pH value is reaction end, centrifugal filtration is also measured filtrate volume, use the quantitatively deionization warm water washing and filtering of (i.e. 1000 kilograms-filtrate volume) then, filtrate merging is added 0.5 kilogram of potassium sorbate, 100 kilograms in potassium chloride, 3 kilograms of potassium dihydrogen phosphates, refilter after fully stirring, can obtain outward appearance and be 1000 kilograms of dark brown sauce extracts.
Example 2
Repeat the operation of example 1, be cooled to about 60 ℃ in 18 hours when refluxing, under stirring condition, add 10 kilograms of mushroom powders, 10 kilograms of black fungus powders, 5 kilograms of brewer's yeasts and 5 kilograms of lecithin, and then be warmed up to 100 ℃, 8 hours sample analysis of back flow reaction under normal pressure.After the protein complete hydrolysis, repeat the operation of example 1 again, can obtain outward appearance and be 1000 kilograms of brown soy sauce feelings.
Example 3
100 kilograms of peanut meals, 60 kilograms of the wheat brans of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve, peanut meal contains aflatoxin 2000 μ g/kg, wheat bran contains aflatoxin 4 μ g/kg through checking, and therefore only adopts the liquor natrii hypochloritis to embathe disintoxication processing peanut meal and gets final product.Filter dried with 1% propylhomoserin sodium water solution of 400 kilograms of ratios after 4 hours in 35-45 ℃ of immersion the powdery peanut meal, embathe (soaking 30 minutes) 2 times with 300 kilograms warm water more at every turn, after doing, filter repeats and example 1 identical operations again, wherein return time is 24 hours, neutralize with 30% sodium carbonate liquor, when pH value reaches 5.5, be reaction end, in filtrate, add 1 kilogram of potassium sorbate, 100 kilograms of potassium chloride, 3 kilograms of potassium dihydrogen phosphates, obtain outward appearance at last and be 1000 kilograms of dark brown sauce extracts.
Example 4
Repeat the operation of example 3, be cooled to about 60 ℃ in 20 hours when refluxing, under stirring condition, add 10 kilograms of mushroom powder, 10 kilograms of tremella powder, 5 kilograms of Saccharomyces cerevisiaes and 5 kilograms of lecithin, and then be warmed up to 100 ℃, 6 hours sample analysis of back flow reaction under normal pressure.After the protein complete hydrolysis, repeat the operation of example 2 again, can obtain outward appearance and be 1000 kilograms of brown sauce extracts.
Example 5
60 kilograms of soybean cakes, 108 kilograms of the wheat brans of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve, through check big dregs of beans to contain aflatoxin 280 μ g/kg, wheat bran contains aflatoxin 70 μ g/kg, adopts diverse ways to handle respectively above-mentioned two kinds of raw materials.With the powdery soybean cake with 240 kilogram of 2% weak aqua ammonia in 35-45 ℃ soak 3 hours after filter do, embathe (soaking 20 minutes) 3 times with 180 kilograms warm water more at every turn, filter is dried stand-by.The powdery wheat bran is filtered after 3 hours and done with 432 kilograms Tween-80 0.01% emerge in worm water that contains, embathe 2 times with 324 kilograms warm water, soaked 30 minutes at every turn, filter is dried stand-by.Above-mentioned two kinds of treated raw materials are placed in the container that is provided with agitator and returned cold radiator cooler, add 420 kilograms of 18% hydrochloric acid again, in 2 kilograms/cm of gauge pressure
2115-125 ℃ of reaction 14 hours after sample analysis is treated the protein complete hydrolysis, is cooled to material in the container below 40 ℃, adds concentration lentamente and be 36% aqueous sodium carbonate under normal temperature and stirring condition.When pH value reaches 5.5, be reaction end, filter and with quantitative deionization warm water filter wash, fully refilter after the stirrings for 5 kilograms, can obtain outward appearance and be 1000 kilograms of the sauce extracts of brownish black adding 0.5 kilogram of potassium sorbate, 103 kilograms in potassium chloride, potassium dihydrogen phosphate filtrate merging.
Example 6
Repeat the operation of example 5, be cooled to about 60 ℃ in 12 hours when refluxing, under stirring condition, add 14 kilograms of Hericium erinaceus powder, 14 kilograms of black fungus powders, 7 kilograms of brewer's yeasts and 7 kilograms of lecithin, and then be warmed up to 100 ℃, under normal pressure, refluxed 8 hours sample analysis.After the protein complete hydrolysis, repeat the operation of example 3 again, can obtain outward appearance and be 1000 kilograms of the sauce extracts of brownish black.
Example 7
60 kilograms in peanut cake, 108 kilograms of the wheat brans of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve, peanut cake contains aflatoxin 1650 μ g/kg, wheat bran contains aflatoxin 90 μ g/kg through checking, filter dried with 240 kilogram of 2% aqueous sodium hypochlorite solution after 3 hours in 35-45 ℃ of immersion the pulvis of peanut cake, embathe 3 times with 180 kilograms warm water again, soak filter in 20 minutes at every turn and do stand-by.Again the pulvis of wheat bran is filtered after 4 hours with 432 kilogram of 0.01% Tween-80 emerge in worm water and done.Repeat and example 5 identical operations, wherein the reaction time is 16 hours again, with the neutralization of 20% NaOH, when pH value reaches 6.0, is reaction end.Add 0.8 kilogram of potassium sorbate, 103 kilograms in potassium chloride, 3 kilograms of potassium dihydrogen phosphates in filtrate, obtaining outward appearance at last is 1000 kilograms of dark-brown sauce extracts
Example 8
Repeat the operation of example 7, be cooled to about 60 ℃ in 14 hours when refluxing, under stirring condition, add 14 kilograms of phoenix-tail mushroom powder, 14 kilograms of tremella powder, 7 kilograms of Saccharomyces cerevisiaes and 7 kilograms of lecithin, and then be warmed up to 100 ℃, under normal pressure, refluxed 6 hours sample analysis.After the protein complete hydrolysis, repeat the operation of example 4 again, can obtain outward appearance and be 1000 kilograms of the sauce extracts of brownish black
The quality index contrast of product quality indicator of the present invention and prior art is as follows:
Project product G B2717-81 of the present invention Amino-acid nitrogen (restraining/100 milliliters) 〉=0.6 〉=0.4 Salt (restraining/100 milliliters)≤8.0 〉=15.0 Potassium chloride (restraining/100 milliliters)≤12.0-Total acid (in the lactic acid grams per milliliter)≤2.5≤2.5 Phosphorus (in P2O5, restraining/100 milliliters) 〉=0.15-Arsenic (in As, mg/kg)≤0.5≤0.5 Plumbous (in Pb, mg/kg)≤1.0≤1.0 AFB1 (μ g/ liter)＜5≤5 Annotate: 1, the percentage in the present specification and mark are parts by weight.
2, aflatoxin content is measured and is selected from GB2717-81.
Claims (6)
1, a kind of Cardia Salt of eradicating aflatoxin is augmented the preparation method of health-care sauce essence, and it is with the protein raw material hydrochloric acid hydrolysis, with the alkali neutralization, it is characterized in that then:
(1) the following raw material of product of the present invention of preparation 1000 parts by weight:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
(2) purified treatment of raw material
A ammonia or ammoniacal liquor embathe disintoxication: powder raw material is filtered after 3-4 hour in 35-45 ℃ of immersion with the weak aqua ammonia of 4 times of weight 1-2% done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, and filter is done stand-by,
Or b chlorine water or liquor natrii hypochloritis embathe disintoxication: with powder raw material with the 1-2% liquor natrii hypochloritis of 4 times of weight in 35-45 ℃ soak 3-4 hour after filter do, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, filter is dried stand-by,
Or the c Tween-80 aqueous solution embathes method: powder raw material is filtered after 3-4 hour with 0.01% Tween-80 emerge in worm water of 4 times of weight done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, and filter is done stand-by,
(3) preparation technology
A will through above-mentioned processing exceed standard raw material be the 18-20% hydrochloric acid of 2.5 times of its weight under stirring condition or atmospheric pressure reflux 20-24 hour, or in 115-125 ℃ of reaction of gauge pressure 2Kg/cm 14-16 hour,
B is cooled to 40 ℃ of sodium hydroxide solutions that slowly add 30-36% aqueous sodium carbonate or 20% under stirring condition, makes pH value between 5.5-6.0,
C filters and with quantitative deionization warm water filter wash, filtrate merging is added 0.05-0.1% potassium sorbate anticorrisive agent again.
2, the Cardia Salt of elimination aflatoxins according to claim 1 is augmented the preparation method of health-care sauce essence, it is characterized in that:
(1) product of the present invention of preparation 1000 parts by weight adopts following raw material and auxiliary material:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
Edible mushroom 20-28 weight portion
Yeast 5-7 weight portion
Lecithin 5-7 weight portion
(2) purified treatment of raw material is identical with (2) in the claim 1,
(3) preparation technology:
A with above-mentioned purified treatment cross exceed standard raw material be the 18-20% hydrochloric acid of 2.5 times of main material weight under stirring condition or atmospheric pressure reflux 18-20 hour, or in 115-125 ℃ of reaction of gauge pressure 2kg/cm 12-14 hour,
B is cooled to about 60 ℃, adds auxiliary material under stirring condition, and then is warmed up to 100 ℃ atmospheric pressure reflux reaction 6-8 hour,
C is cooled to 40 ℃ and slowly adds 30-36% aqueous sodium carbonate or 20% sodium hydroxide solution under stirring condition, makes pH value between 5.5-6.0,
D filters and with quantitative deionization warm water filter wash, filtrate merging is added 0.05-0.10% potassium sorbate anticorrisive agent again,
3, the Cardia Salt of elimination aflatoxin according to claim 1 and 2 is augmented the preparation method of health-care sauce essence, it is characterized in that: the 7.6-8.0% potassium chloride that adds the filtrate total amount in product of the present invention.
4, the Cardia Salt of elimination aflatoxin according to claim 3 is augmented the preparation method of health-care sauce essence, it is characterized in that: the 0.3-0.5% potassium dihydrogen phosphate that adds the filtrate total amount in product of the present invention.
5, the Cardia Salt of elimination aflatoxin according to claim 4 is augmented the preparation method of health-care sauce essence, it is characterized in that: mushroom is 1: 1 with the weight ratio of auricularia auriculajudae in the edible mushroom.
6, the Cardia Salt of elimination aflatoxin according to claim 1 is augmented the preparation method of health-care sauce essence, it is characterized in that: the hydrochloric acid hydrolysis that adopts 5.5N.
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| CN94110384A CN1054732C (en) | 1994-07-07 | 1994-07-07 | Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce |
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Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL9000367A (en) * | 1990-02-15 | 1991-09-02 | Feedpro B V I O | Inactivating mycotoxin in particulate raw material for foodstuff - by compressing to expel air, treating with ammonia and steam in reaction chamber, and compressing to expel ammonia and water |
| JPH0670701A (en) * | 1991-11-07 | 1994-03-15 | World Natsutsu:Kk | Method for attenuating aflatoxin and aflatoxin-attenuating solution used in this method |
| CN1039132C (en) * | 1992-12-31 | 1998-07-15 | 孔兆钦 | Method for brewing beer series containing no carcinogen |
| CN1086689A (en) * | 1993-06-17 | 1994-05-18 | 高汝云 | The method of a kind of mildew-resistant and the aflatoxin of dispelling |
-
1994
- 1994-07-07 CN CN94110384A patent/CN1054732C/en not_active Expired - Fee Related
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| CN102532085A (en) * | 2011-12-29 | 2012-07-04 | 晨光生物科技集团股份有限公司 | Method for extracting proanthocyanidin from peanut coats |
| CN102532085B (en) * | 2011-12-29 | 2014-03-12 | 晨光生物科技集团股份有限公司 | Method for extracting proanthocyanidin from peanut coats |
| CN104522755A (en) * | 2014-12-29 | 2015-04-22 | 晨光生物科技集团股份有限公司 | Process for removing aflatoxin in cottonseeds |
| CN104522755B (en) * | 2014-12-29 | 2017-11-17 | 晨光生物科技集团股份有限公司 | The removing process of aflatoxin in a kind of cottonseed |
| CN106522003A (en) * | 2016-11-09 | 2017-03-22 | 厦门壳氏新材料科技有限公司 | Processing method of rice husks |
| CN106638073A (en) * | 2016-11-09 | 2017-05-10 | 厦门壳氏新材料科技有限公司 | Efficient and environment-friendly husk processing method |
| CN106522003B (en) * | 2016-11-09 | 2019-05-24 | 厦门壳氏新材料科技有限公司 | A kind of processing method of husk |
| CN107997114A (en) * | 2017-12-07 | 2018-05-08 | 浙江海洋大学 | A kind of preparation method of less salt krill soy sauce |
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