CN111433970A - Cooling body and electricity storage pack using same - Google Patents
Cooling body and electricity storage pack using same Download PDFInfo
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- CN111433970A CN111433970A CN201880078206.2A CN201880078206A CN111433970A CN 111433970 A CN111433970 A CN 111433970A CN 201880078206 A CN201880078206 A CN 201880078206A CN 111433970 A CN111433970 A CN 111433970A
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- cooling body
- power storage
- insulating material
- glass wool
- heat insulating
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/61—Types of temperature control
- H01M10/613—Cooling or keeping cold
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/133—Halogenated aldehydes; Halogenated ketones ; Halogenated ketenes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/14—Arrangements or processes for adjusting or protecting hybrid or EDL capacitors
- H01G11/18—Arrangements or processes for adjusting or protecting hybrid or EDL capacitors against thermal overloads, e.g. heating, cooling or ventilating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/655—Solid structures for heat exchange or heat conduction
- H01M10/6554—Rods or plates
- H01M10/6555—Rods or plates arranged between the cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/656—Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
- H01M10/6567—Liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/656—Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
- H01M10/6569—Fluids undergoing a liquid-gas phase change or transition, e.g. evaporation or condensation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/658—Means for temperature control structurally associated with the cells by thermal insulation or shielding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/211—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for pouch cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Power Engineering (AREA)
- Textile Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Secondary Cells (AREA)
- Battery Mounting, Suspending (AREA)
Abstract
The cooling body comprises a refrigerant, a porous flat plate-like heat insulating material, and a seal for sealing the refrigerant and the heat insulating material in a sealed stateAn assembly wherein the thermal conductivity of the insulating material per unit area is at most 300W/(K.m)2) And has a thickness of 0.5mm to 10.0 mm.
Description
Technical Field
The present disclosure relates to a cooling body and an electricity storage pack using the same.
This application claims priority to japanese patent application No.2017-236187, filed on 8/12/2017, the entire contents of which are incorporated herein by reference.
Background
An example of a cooling body for cooling a heat generating element such as a single cell or a battery module is a heat pipe. For example, patent document 1 (japanese laid-open patent publication No. h11-023169) discloses a cooling body (heat pipe) having a structure in which a heat transfer fluid is enclosed inside a pipe made of a metal material in a liquid-tight manner.
As a method for dissipating heat from each unit cell in the battery pack, for example, patent document 2 (japanese laid-open patent publication No.2012-155858) discloses providing each unit cell with a heat conduction member (heat transfer plate) that connects an electrolyte in the cell to a cooling system provided outside the cell.
Further, patent document 3 (japanese laid-open patent publication No.2010-211963) discloses an electric storage device including an absorption sheet that is in contact with an outer surface of an electric storage element and absorbs a liquid refrigerant that can evaporate upon receiving heat from the electric storage element.
Reference list
[ patent document ]
Patent document 1: japanese laid-open patent publication No. H11-023169
Patent document 2: japanese laid-open patent publication No.2012-155858
Patent document 3: japanese laid-open patent publication No.2010-211963
Disclosure of Invention
The cooling body of the present disclosure includes a refrigerant, a porous flat plate-shaped heat insulating material, and a packing body in which the refrigerant and the heat insulating material are packed in a sealed state, wherein
The thermal conductivity per unit area of the thermal insulation material is 300W/(K.m)2) And a thickness of 0.5mm to 10.0 mm.
The power storage pack of the present disclosure is a power storage pack including a plurality of power storage modules, wherein
Each of the power storage modules includes a plurality of power storage cells, and
the electricity storage pack includes the cooling body of the present disclosure at least between the plurality of electricity storage units.
Another power storage pack of the present disclosure is a power storage pack including a plurality of power storage modules, wherein
Each of the power storage modules includes a plurality of power storage cells, and
the electricity storage pack includes the cooling body of the present disclosure at least between the plurality of electricity storage modules.
Drawings
Fig. 1 is a diagram showing an outline of an example of a cooling body according to an embodiment of the present disclosure.
Fig. 2 is a diagram showing an outline of an example of the power storage module in the power storage pack according to the embodiment of the present disclosure.
Fig. 3 is a diagram showing an outline of an apparatus used when evaluating the heat insulating performance of each cooling body manufactured in the example.
Fig. 4 is an enlarged view of the interior of the chamber shown in fig. 3.
Detailed Description
[ problem ] to
The conventional heat sink is formed of a metal material having high thermal conductivity so as to effectively dissipate heat in a normal use state.
However, when a material having high thermal conductivity is used as the cooling body, if the single battery cells in the battery pack generate abnormal heat for some reason, the heat is immediately transferred to the adjacent single battery cells through the heat conductive member.
Therefore, in view of the above-described problems, it is an object of the present disclosure to provide a cooling body capable of exhibiting cooling performance for cooling a heat generating element such as an electric storage unit or an electric storage module at ordinary times and capable of exhibiting heat insulating performance for making it difficult for heat to be transferred to an adjacent member when the heat generating element causes abnormal heat generation.
[ advantageous effects of the present disclosure ]
According to the present disclosure, it is possible to provide a cooling body that can exhibit cooling performance for cooling a heat generating element such as an electric storage unit or an electric storage module at ordinary times, and can exhibit heat insulating performance for making it difficult for heat to be transferred to an adjacent component when the heat generating element causes abnormal heat generation.
Further, according to the present disclosure, it is possible to provide a power storage pack in which power storage units or power storage modules in the power storage pack are cooled at ordinary times, and in which when abnormal heat generation is caused by a part of the power storage units or power storage modules in the power storage pack, it is difficult to transfer heat to the nearby power storage units or power storage modules.
[ description of the embodiments ]
First, embodiments of the present disclosure will be enumerated and described.
(1) The cooling body according to an embodiment of the present disclosure includes a refrigerant, a porous flat plate-shaped heat insulating material, and a packing body in which the refrigerant and the heat insulating material are packed in a sealed state. The thermal conductivity per unit area of the thermal insulation material is 300W/(K.m)2) And a thickness of 0.5mm to 10.0 mm.
According to the cooling body described in the above (1), it is possible to provide a cooling body capable of exhibiting cooling performance for cooling the heat generating element such as the power storage unit or the power storage module at ordinary times and capable of exhibiting heat insulating performance for making it difficult for heat to be transferred to the adjacent component when the heat generating element causes abnormal heat generation.
In the present disclosure, "thermal conductivity per unit area (W/(K · m)2) "means a value obtained by dividing the thermal conductivity (W/(K · m)) inherent to the material by the thickness of the material.
(2) In the cooling body described in the above (1), the thermal conductivity of the thermal insulating material per unit area is preferably 100W/(K · m)2) The following.
(3) In the cooling body according to the above (1) or (2), the thermal insulation material preferably has a thermal conductivity of 60W/(K · m) per unit area2) The following.
According to the cooling body described in the above (2) or (3), it is possible to provide a cooling body capable of exhibiting more excellent heat insulating performance when abnormal heat generation is caused by a heat generating element such as an electric storage unit or an electric storage module.
(4) In the cooling body according to any one of the above (1) to (3), the thickness of the heat insulating material is preferably 0.5mm or more and 5.0mm or less.
(5) In the cooling body according to any one of the above (1) to (4), the thickness of the heat insulating material is preferably 0.5mm or more and 2.0mm or less.
According to the cooling body described in the above (4) or (5), it is possible to provide a cooling body capable of exhibiting more excellent heat insulating performance when abnormal heat generation is caused by a heat generating element such as an electric storage unit or an electric storage module, and contributing to downsizing of an electric storage pack.
(6) In the cooling body described in any one of (1) to (5) above, the heat insulating material is preferably glass wool, a porous microbead or a nonwoven fabric.
According to the cooling body described in the above (6), it is possible to provide a cooling body which retains a large amount of refrigerant and can exhibit higher cooling performance at ordinary times.
(7) In the cooling body according to the above (1), it is preferable that the heat insulating material is glass wool, the refrigerant is a fluorine-containing organic solvent, and the package is formed of a sheet member containing aluminum or an aluminum alloy.
(8) The power storage pack according to the embodiment of the present disclosure is a power storage pack that includes a plurality of power storage modules, wherein each power storage module includes a plurality of power storage units, and the power storage pack includes the cooling body described in any one of (1) to (7) above at least between the plurality of power storage units.
(9) A power storage pack according to another embodiment of the present disclosure is a power storage pack that includes a plurality of power storage modules, wherein each power storage module includes a plurality of power storage cells, and the power storage pack includes the cooling body described in any one of (1) to (7) above at least between the plurality of power storage modules.
According to the power storage pack of the above (8) or (9), it is possible to provide a power storage pack in which the power storage units or the power storage modules in the power storage pack are cooled at ordinary times, and in which it is difficult to transfer heat to the nearby power storage units or power storage modules when abnormal heat generation is caused by a part of the power storage units or power storage modules in the power storage pack.
(10) In the electricity storage group described in the above (8) or (9), the electricity storage cells preferably include an organic electrolytic solution as the electrolytic solution.
According to the electricity storage pack described in the above (9), it is possible to provide an electricity storage pack which has a high energy density and includes an organic electrolytic solution, and in which even when abnormal heat generation is caused by a heat generating element such as an electricity storage unit or an electricity storage module, the cooling body can exhibit heat insulating performance, thereby making it difficult for heat to be transferred to another normal heat generating element. Further, it is possible to provide an electricity storage pack that can prolong the time during which a fire extends to an adjacent electricity storage unit or electricity storage module even when a part of the electricity storage units or electricity storage modules in the electricity storage pack ignite.
[ details of the embodiment ]
Hereinafter, specific examples of the cooling body and the power storage pack using the cooling body according to the embodiment of the present disclosure will be described in more detail. The present invention is not limited to these examples but defined by the claims, and is intended to include meanings equivalent to the claims and all modifications within the scope of the claims.
< Cooling body >
Fig. 1 shows a schematic view of an example of a cooling body according to an embodiment of the present disclosure. As shown in fig. 1, a cooling body 10 according to an embodiment of the present disclosure includes a refrigerant 12, a porous flat plate-shaped heat insulating material 11, and a packing body 13. The packing body 13 serves to pack the refrigerant 12 and the heat insulating material 11 in a sealed state. The thermal conductivity of the thermal insulating material 11 per unit area was 300W/(K.m)2) And a thickness of 0.5mm to 10.0 mm.
The cooling body according to the embodiment of the present disclosure is used by being disposed between heat generating elements such as power storage units or power storage modules. By using the cooling body according to the embodiment of the present disclosure, the heat generating elements such as the electric storage unit and the electric storage module can be cooled at ordinary times, and when the heat generating element becomes very hot due to an unexpected abnormality, the heat insulating performance can be exhibited so that the heat of the heat generating element causing the abnormal heat generation is difficult to be transferred to another heat generating element.
More specifically, in a temperature range (about-40 ℃ to 70 ℃ (see non-patent document 1)) in a normal use state of a heat generating element such as an electric storage unit or an electric storage module, when heat from the heat generating element is transferred to the cooling body 10, the heat generating element can be cooled by latent heat of vaporization generated when the refrigerant 12 inside the cooling body 10 is evaporated from liquid to gas. When the refrigerant 12 evaporates, the internal pressure of the package 13 rises, and the remaining portion of the package 13 other than the portion interposed between the heat generating elements is deformed so as to expand, thereby forming a bulging portion. The expansion of the portion of the package between the heat generating elements is restricted, and therefore the portion is not deformed. When the refrigerant 12 is cooled to condense, the internal pressure of the package 13 is lowered, and the bulging portion disappears.
[ non-patent document 1]
"automatic parts-Test methods and general requirements for wireless telephones", JASO standards for automobiles, society of Automotive Engineers, Japan, JASO D616:2011
Meanwhile, when the heat generating element is abnormal for some reason and reaches a high temperature of about 450 ℃, the packing body 13 cannot withstand the volume expansion due to the evaporation of the refrigerant 12, so that the packing body 13 is opened. Then, the refrigerant 12 overflows from the package body 13, and the heat insulating material 11 remains in the package body 13. Therefore, the heat insulating material 11 having a high heat insulating property is interposed between the heat generating element causing abnormal heat generation and the surrounding normal heat generating elements, so that it is possible to slow down the rate at which the heat of the heat generating element causing abnormal heat generation is transferred to the surrounding heat generating elements.
Hereinafter, portions of the cooling body according to the embodiment of the present disclosure will be described in detail.
(refrigerant)
The refrigerant 12 changes its state between liquid and gas. As the refrigerant 12, for example, one or more substances selected from the group consisting of fluorine-containing organic solvents such as perfluorocarbons, hydrofluoroethers, hydrofluoroketones, and fluorine-inert liquids, water, and alcohols such as methanol and ethanol may be used. The refrigerant 12 may have electrical insulation properties, or may have electrical conductivity. The amount of the refrigerant 12 encapsulated in the encapsulation body 13 may be appropriately selected as necessary.
(Heat insulating Material)
The heat insulating material 11 has a flat plate shape and is generally substantially rectangular in shape. The heat insulating material 11 only needs to be formed of a porous material so that the heat insulating material 11 can absorb the refrigerant 12. Examples of materials that can be used as the heat insulating material 11 include woven or nonwoven fabrics formed of materials processed into fiber forms, and materials obtained by sintering particles. The material forming the heat insulating material 11 may be natural fibers, synthetic fibers formed of synthetic resin, or a material using both natural fibers and synthetic fibers.
As the heat insulating material 11, glass wool, a porous material of beads, or a nonwoven fabric is preferably used.
Examples of the glass wool include glass wool obtained by aggregating glass fibers into a wool-like form and glass wool obtained by mixing and shaping glass fibers with a binder. The glass wool is preferably formed into a sheet shape using a binder from the viewpoint of thickness stability and prevention of shedding of glass fibers. The higher the density of the glass wool, the higher the thermal insulation performance. Therefore, glass wool having a high density is preferably used. The density of the glass wool is preferably 1.5kg/m3Above, more preferably 2kg/m3Above, and more preferably 2.2kg/m3The above.
An example of the microbead porous body is a porous body obtained by sintering spherical particles of about 1 μm to 10 μm and shaping the particles into a sheet shape. Examples of the material of the microbead porous body include polymers such as polyamideimide and polyimide, and glass.
Examples of the nonwoven fabric include a fiber sheet, a net (a film-like sheet composed of only fibers), and a felt (バツト) (a felt-like fiber).
In general, in a state where a heat generating element (for example, a lithium ion battery) such as an electric storage unit or an electric storage module causes abnormal heat generation to cause ignition, the temperature reaches about 450 ℃ (see non-patent document 2) further, L iCoO is being used2In the case of the lithium ion battery of (1), the positive electrode active material is thermally decomposed at about 200 ℃ and oxygen is generated (see non-patent document 3). Therefore, for the above-described lithium ion battery, it is necessary to make the time taken for the temperature of the normal heat generating element around the heat generating element causing abnormal heat generation to reach 200 ℃ as much as possibleLong. In view of the time taken for the passenger to escape from the vehicle or the like equipped with the heat generating element such as the power storage unit or the power storage module, the time taken for the temperature of the surrounding normal heat generating element to reach 200 ℃. Through experiments conducted by the present inventors, it was found that about 70 seconds is sufficient to get 20 passengers on and off a 20-seat small bus, and about 40 seconds is sufficient to get on and off an 8-seat passenger car.
[ non-patent document 2]
Hideki Matsumura, Kazuo Matsumima, "Occurence Events in safety evaluation Test for L ituum-Ion Cells", national traffic safety and environmental research laboratory Forum lecture paper set, Japanese national traffic safety and environmental laboratory, 2012, pp.135-138
[ non-patent document 3]
Shinya Kitano et al, "Thermal Behavior of overloaded State of L ithium-IonCells Using L iCoO2Positive Electrode ", GS Yuasa Technical Report, GS Yuasa corporation, 2005-12 months, Vol.2, No.2, pp.18-24
From the above viewpoint, the thermal conductivity per unit area is set to 300W/(K.m)2) The following and a thermal insulation material having a thickness of 0.5mm to 10.0mm are used in the cooling body according to the embodiment of the present disclosure. The insulating material is more preferable if the thermal conductivity per unit area of the insulating material is lower.
Since the cooling body according to the embodiment of the present disclosure is disposed between heat generating elements such as power storage units or power storage modules and used, the thickness of the cooling body that does not contribute to output is preferably as small as possible to increase the energy density. In order to reduce the thickness of the cooling body 10, the heat insulating material 11 is also preferably thin.
When the thickness of the heat insulating material is about 0.5mm or more, the cooling body 10 may have sufficient strength. Further, when the thickness of the heat insulating material is 10.0mm or less, the energy density of the electricity storage pack including the cooling body 10 can be increased. From these viewpoints, the thickness of the heat insulating material is preferably 0.5mm or more and 5.0mm or less, and more preferably 0.5mm or more and 2.0mm or less.
When the thermal conductivity per unit area of the thermal insulation material 11 is 300W/(K.m)2) The cooling body 10 can exhibit excellent cooling performance and heat insulating performance as follows. When the thermal conductivity per unit area of the heat insulating material 11 is lower, the cooling body 10 can exhibit more excellent heat insulating performance. Therefore, the thermal conductivity of the thermal insulation material 11 per unit area is preferably 100W/(K · m)2) Hereinafter, and more preferably 60W/(K · m)2) The following.
The size of the cooling body 10 according to the embodiment of the present disclosure is not particularly limited as long as it is appropriately selected according to the size of the heat generating element such as the power storage unit or the power storage module disposed adjacent to the cooling body 10.
In general, the heat generating element has a flat plate shape, and therefore the cooling body 10 only needs to be a cooling body having a main surface whose size is substantially equal to or slightly larger than that of each main surface of the heat generating element.
(packaging body)
The package 13 is formed by joining two sheet members having a substantially rectangular shape in a liquid-tight manner by a known method such as adhesion, welding, or fusion bonding, for example. Each sheet member is preferably obtained by laminating a synthetic resin film on both surfaces of a metal sheet. The package 13 is formed, for example, by overlapping the surfaces of the sheet-like members on which the synthetic resin films are laminated with each other and thermally fusing the sheet-like members.
Examples of the metal forming the metal sheet include aluminum, aluminum alloy, copper, and copper alloy, and any metal may be selected as needed.
Examples of the synthetic resin forming the synthetic resin film include polyolefins such as polyethylene and polypropylene, polyesters such as polybutylene terephthalate and polyethylene terephthalate, and polyamides such as nylon 6 and nylon 6, and any synthetic resin may be selected as needed.
< Electrical storage group >
The electricity storage pack is mounted on a vehicle such as an electric vehicle or a hybrid vehicle, and supplies electricity to a load such as a motor.
In an example of the power storage group according to the embodiment of the present disclosure, the power storage group includes a plurality of power storage modules, each of the power storage modules includes a plurality of power storage units, and it suffices that the above-described cooling body according to the embodiment of the present disclosure is provided at least between the plurality of power storage units.
Fig. 2 shows a schematic diagram of an example of the power storage module in the power storage pack according to the embodiment of the present disclosure. As shown in fig. 2, the power storage module 20 includes a plurality of power storage units 21, and includes the above-described cooling body 10 according to the embodiment of the present disclosure between the plurality of power storage units 21. In the example shown in fig. 2, one cooling body 10 is provided at intervals of every two power storage units 21, but the arrangement of the cooling bodies 10 may be appropriately changed, for example, one cooling body 10 may be provided at intervals of one power storage unit 21 so that all the power storage units 21 are not adjacent to each other, or one cooling body 10 may be provided at intervals of three power storage units 21.
In the electricity storage group, the cooling body 10 may be provided or not provided between the electricity storage modules. From the viewpoint of improving the heat insulating performance in an emergency, it is preferable to provide the cooling body 10 between the power storage modules.
In another example of the power storage group according to the embodiment of the present disclosure, the power storage group includes a plurality of power storage modules, each of the power storage modules includes a plurality of power storage cells, and the above-described cooling body according to the embodiment of the present disclosure may be provided at least between the plurality of power storage modules. In this case, the cooling body 10 may or may not be provided between the power storage units in each power storage module. From the viewpoint of improving the heat insulating performance in an emergency, it is preferable to provide the cooling body 10 also between the power storage cells in each power storage module.
In the electricity storage module, the terminals of the electrodes 22 are connected to each other, whereby the electricity storage cells 21 are connected in series or in parallel. In each of the electric storage units 21, it is only necessary to sandwich an electric storage element (not shown) between a pair of electric storage unit laminate sheets and join the side edges of the electric storage unit laminate sheets in a liquid-tight manner by a known method such as hot melt adhesion.
As each electric storage unit 21, for example, a secondary battery such as a lithium ion secondary battery and a nickel hydrogen secondary battery, or a capacitor such as an electric double layer capacitor and a lithium ion capacitor may be used, and any type may be appropriately selected as necessary. In the case where each power storage unit includes an organic electrolytic solution as an electrolytic solution, since there is a risk of fire due to abnormal heat generation, the power storage group preferably includes the cooling body according to the embodiment of the present disclosure between the power storage units or between the power storage modules.
Examples of the present invention
Hereinafter, the present disclosure will be described in more detail by way of examples, but these examples are merely illustrative, and the cooling body and the power storage pack of the present disclosure are not limited to these examples. The scope of the invention is defined by the description of the claims, and includes meanings equivalent to the description of the claims and all modifications within the scope of the claims.
(example 1)
An aluminum laminate sheet having three thermally fused edges was prepared as a package, and a fluorine-containing organic solvent was prepared as a refrigerant.
As a heat insulating material, glass wool No.1 was prepared, and the thermal conductivity per unit area of this glass wool No.1 was 300W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 10.0mm, and a density of 2.3kg/m3. As the glass wool No.1, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
The refrigerant and glass wool No.1 were sealed in a package to obtain a cooling body No. 1.
(example 2)
As a heat insulating material, glass wool No.2 was prepared, and the thermal conductivity per unit area of glass wool No.2 was 300W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 5.0mm, and a density of 3.5kg/m3. As the glass wool No.2, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.2 was obtained in the same manner as in example 1 except that glass wool No.2 was used in place of glass wool No.1 in example 1.
(example 3)
As a heat insulating material, glass wool No.3 was prepared, and the thermal conductivity per unit area of glass wool No.3 was 300W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 0.5mm, and a density of 10kg/m3. As the glass wool No.3, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.3 was obtained in the same manner as in example 1 except that glass wool No.3 was used in place of glass wool No.1 in example 1.
(example 4)
As a heat insulating material, glass wool No.4 was prepared, and the thermal conductivity per unit area of glass wool No.4 was 100W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 10.0mm, and a density of 5.2kg/m3. As the glass wool No.4, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.4 was obtained in the same manner as in example 1 except that glass wool No.4 was used in place of glass wool No.1 in example 1.
(example 5)
As a heat insulating material, glass wool No.5 was prepared, and the thermal conductivity per unit area of glass wool No.5 was 100W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 5.0mm, and a density of 7.6kg/m3. As the glass wool No.5, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.5 was obtained in the same manner as in example 1 except that glass wool No.5 was used in place of glass wool No.1 in example 1.
(example 6)
As a heat insulating material, glass wool No.6 was prepared, and the thermal conductivity per unit area of glass wool No.6 was 100W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 0.5mm, and a density of 15kg/m3. As the glass wool No.6, glass wool obtained byGlass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping.
A cooling body No.6 was obtained in the same manner as in example 1 except that glass wool No.6 was used in place of glass wool No.1 in example 1.
(example 7)
As a heat insulating material, glass wool No.7 was prepared, and the thermal conductivity per unit area of glass wool No.7 was 60W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 10.0mm, and a density of 7.6kg/m3. As the glass wool No.7, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.7 was obtained in the same manner as in example 1 except that glass wool No.7 was used in place of glass wool No.1 in example 1.
(example 8)
As a heat insulating material, glass wool No.8 was prepared, and the thermal conductivity per unit area of glass wool No.8 was 60W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 5.0mm, and a density of 14.2kg/m3. As the glass wool No.8, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.8 was obtained in the same manner as in example 1 except that glass wool No.8 was used in place of glass wool No.1 in example 1.
(example 9)
As a heat insulating material, glass wool No.9 was prepared, and the thermal conductivity per unit area of glass wool No.9 was 60W/(K.m)2) A major surface size of 5cm × 5cm, a thickness of 2.0mm, and a density of 17kg/m3. As the glass wool No.9, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.9 was obtained in the same manner as in example 1 except that glass wool No.9 was used in place of glass wool No.1 in example 1.
(example 10)
As a heat insulating material, a prepared glassThe glass wool No.10 has a thermal conductivity per unit area of 60W/(K.m) of the glass wool No.102) A major surface size of 5cm × 5cm, a thickness of 0.5mm, and a density of 24kg/m3. As the glass wool No.10, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No.10 was obtained in the same manner as in example 1 except that glass wool No.10 was used in place of glass wool No.1 in example 1.
Comparative example 1
As a heat insulating material, glass wool No. A having a thermal conductivity of 400W/(K.m) per unit area was prepared2) A major surface size of 5cm × 5cm, a thickness of 1.0mm, and a density of 3.5kg/m3. As the glass wool No. a, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping is used.
A cooling body No. A was obtained in the same manner as in example 1 except that glass wool No. A was used in place of glass wool No.1 in example 1.
Comparative example 2
As a heat insulating material, glass wool No. B having a thermal conductivity per unit area of 300W/(K.m) was prepared2) A major surface size of 5cm × 5cm, a thickness of 15.0mm, and a density of 1.7kg/m3. As the glass wool No. b, glass wool obtained by mixing glass fibers with polyvinyl alcohol (binder) and shaping was used.
A cooling body No. B was obtained in the same manner as in example 1 except that glass wool No. B was used in place of glass wool No.1 in example 1.
< evaluation >
Evaluation of the heat insulating property was carried out using the cooling body Nos. 1 to 10, the cooling body No. A and the cooling body No. B.
As shown in FIG. 3, the evaluation of the thermal insulation performance was performed by bringing the cooling body 30 into contact with the hot plate 31 by the automatic recorder 37. in order to eliminate the influence of convection, the hot plate 31 and the like were disposed in the chamber 36, and the inside of the chamber 36 was degassed by the scrubber 38. FIG. 4 is an enlarged view showing the inside of the chamber 36. in the chamber 36, each cooling body 30, the aluminum plate 33 having a thickness of 2mm, the thermocouple 32, the aluminum oxide plate 34 having a thickness of 1mm, and the metal block 35 were disposed on the hot plate 31 adjusted to 450 ℃ in advance, and the change in temperature with time was measured. the metal block 35 was used to prevent the contact failure with the hot plate 31 due to the expansion of the cooling body 30, and a load of 1.1kg was applied every 5cm × 5 cm.
Table 1 shows the temperatures after 40 seconds and 70 seconds from the start of measurement of each cooling body.
[ Table 1]
In order to prevent a change in the measured value due to a change in the shape of the package during the evaluation, the heat insulating performance of each cooling body was evaluated with the end portion of the cooling body open. When each cooling body is in a sealed state, the cooling body exhibits higher heat insulating performance.
Table 1 shows that the cooling bodies No.1 to No.3 according to the embodiments of the present disclosure can maintain the state of 200 ℃ or lower for 40 seconds or more, and the cooling bodies No.4 to No.10 can maintain the state of 200 ℃ or lower for 70 seconds or more, after being in contact with the heat generating element (hot plate) of 450 ℃.
List of reference numerals
10 Cooling body
11 insulating material
12 refrigerant
13 Package
20 electric storage module
21 electric storage unit
22 electrode
30 cooling body
31 Hot plate
32 thermocouple
33 aluminum plate
34 alumina plate
35 Metal block
36 chamber
37 automatic recorder
38 washing device
Claims (10)
1. A cooling body comprising a refrigerant, a porous flat plate-like heat insulating material, and a package body in which the refrigerant and the heat insulating material are packaged in a sealed state, wherein
The thermal conductivity of the thermal insulation material per unit area is 300W/(K.m)2) And a thickness of 0.5mm to 10.0 mm.
2. The cooling body according to claim 1, wherein the thermal conductivity per unit area of the thermal insulating material is 100W/(K · m)2) The following.
3. The cooling body according to claim 1 or 2, wherein the thermal conductivity per unit area of the thermal insulation material is 60W/(K · m)2) The following.
4. The cooling body according to any one of claims 1 to 3, wherein the thickness of the heat insulating material is 0.5mm or more and 5.0mm or less.
5. The cooling body according to any one of claims 1 to 4, wherein the thickness of the heat insulating material is 0.5mm or more and 2.0mm or less.
6. The cooling body according to any one of claims 1 to 5, wherein the heat insulating material is glass wool, a microbead porous body, or a nonwoven fabric.
7. The cooling body of claim 1, wherein
The heat-insulating material is made of glass wool,
the refrigerant is a fluorine-containing organic solvent, and
the package is composed of a sheet member containing aluminum or an aluminum alloy.
8. An electricity storage pack comprising a plurality of electricity storage modules, wherein
Each of the power storage modules includes a plurality of power storage units, and
the electricity storage group includes the cooling body according to any one of claims 1 to 7, which is located at least between the plurality of electricity storage units.
9. An electricity storage pack comprising a plurality of electricity storage modules, wherein
Each of the power storage modules includes a plurality of power storage units, and
the power storage group includes the cooling body according to any one of claims 1 to 7 at least between the plurality of power storage modules.
10. The electricity storage group according to claim 8 or 9, wherein each of the electricity storage units includes an organic electrolyte as an electrolyte.
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PCT/JP2018/034012 WO2019111488A1 (en) | 2017-12-08 | 2018-09-13 | Coolant and power storage pack using same |
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JP (1) | JP7209949B2 (en) |
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CN116345020A (en) * | 2021-12-23 | 2023-06-27 | 比亚迪股份有限公司 | Battery and battery pack |
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