CN111423710A - Rubber automobile accessory material - Google Patents
Rubber automobile accessory material Download PDFInfo
- Publication number
- CN111423710A CN111423710A CN202010198690.1A CN202010198690A CN111423710A CN 111423710 A CN111423710 A CN 111423710A CN 202010198690 A CN202010198690 A CN 202010198690A CN 111423710 A CN111423710 A CN 111423710A
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- CN
- China
- Prior art keywords
- parts
- rubber
- carbon black
- polyvinyl chloride
- trimethoxy silane
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a rubber automobile accessory material, which comprises the following components: the automobile accessory prepared by the rubber formula has strong ageing resistance, is more durable, and has obviously improved impact resistance and thermal stability, overcomes the limit value of the processing and performance of a rubber product on high hardness, the rubber has high hardness, excellent rigidity and mechanical property, better damping effect and long service life.
Description
Technical Field
The invention belongs to the field of rubber production and preparation, and particularly relates to a rubber automobile accessory material.
Background
Auto parts (auto parts) are units that constitute the whole of an automobile and a product that serves the automobile. The automobile parts are various in types, people consume more and more automobiles along with the improvement of living standard of people, and the market of the automobile parts is getting larger and larger. Automobile parts manufacturers have also developed rapidly in recent years.
For the travelling comfort that provides the vehicle, the car adopts the accessory of rubber products in a large number, and the accessory that passes through rubber products when the auto parts can reduce the produced vibrations of installation, isolated noise improves and drives the enjoyment, but the accessory of current rubber products is in the use, and current yielding rubber life is short, intensity is low, cause the absorbing travelling comfort poor.
Disclosure of Invention
The purpose of the invention is as follows: the invention aims to solve the defects in the prior art, provides a rubber automobile accessory material and solves the problems.
The technical scheme is as follows: the invention relates to a rubber automobile accessory material, which comprises the following components: the rubber material comprises polyurethane rubber, ethylene propylene diene monomer rubber, chlorohydrin rubber, carbon black, white carbon black, glycerol methacrylate, zinc oxide, stearic acid, trimethoxy silane, sulfur, dibenzothiazyl disulfide, benzothiazole sulfenamide, chlorosulfonated polyvinyl chloride, butyl benzyl phthalate, disodium dihydrogen pyrophosphate, tert-butyl hydroperoxide, polyvinyl chloride alcohol, calcium stearate, sodium carboxymethyl cellulose, an anti-aging agent, trimethoxy silane, a silane coupling agent, modified glass fiber and epoxy fatty acid methyl ester, and the raw material composition comprises the following components in parts by weight: 40-50 parts of polyurethane rubber, 25-35 parts of ethylene propylene diene monomer, 15-35 parts of chlorohydrin rubber, 8-15 parts of carbon black, 5-8 parts of white carbon black, 2-3 parts of glycerol methacrylate, 3-6 parts of zinc oxide, 1-2 parts of stearic acid, 1-2 parts of trimethoxy silane, 2-4 parts of sulfur, 0.5-1 part of dibenzothiazyl disulfide, 1-1.5 parts of benzothiazole sulfonamide, 8-16 parts of chlorosulfonated polyvinyl chloride, 3-6 parts of butyl benzyl phthalate, 3-4 parts of disodium dihydrogen pyrophosphate, 1-2 parts of tert-butyl hydroperoxide, 2-6 parts of polyvinyl chloride, 1-3 parts of calcium stearate, 0.5-0.8 part of sodium carboxymethylcellulose, 1.1-1.5 parts of anti-aging agent, 1-2 parts of trimethoxy silane, sodium hydrogen peroxide, sodium hydrogen chloride, sodium hydrogen sulfate, sodium, 2-3 parts of silane coupling agent, 2-3 parts of modified glass fiber and 2-4 parts of epoxy fatty acid methyl ester.
Preferably, the formula raw material composition comprises the following components in parts by weight: 40 parts of polyurethane rubber, 25 parts of ethylene propylene diene monomer, 15 parts of chlorohydrin rubber, 8 parts of carbon black, 5 parts of white carbon black, 2 parts of glycerol methacrylate, 3 parts of zinc oxide, 1 part of stearic acid, 1 part of trimethoxy silane, 2 parts of sulfur, 0.5 part of dibenzothiazyl disulfide, 1 part of benzothiazole sulfenamide, 8 parts of chlorosulfonated polyvinyl chloride, 3 parts of butyl benzyl phthalate, 3-4 parts of disodium dihydrogen pyrophosphate, 1 part of tert-butyl hydroperoxide, 2 parts of polyvinyl chloride, 1 part of calcium stearate, 0.5 part of sodium carboxymethyl cellulose, 1.1 part of an anti-aging agent, 1 part of trimethoxy silane, 2 parts of a silane coupling agent, 2 parts of modified glass fiber and 2-4 parts of epoxy fatty acid methyl ester.
Preferably, the formula raw material composition comprises the following components in parts by weight: 45 parts of polyurethane rubber, 30 parts of ethylene propylene diene monomer, 28 parts of chlorohydrin rubber, 12 parts of carbon black, 6 parts of white carbon black, 2.4 parts of glycerol methacrylate, 5 parts of zinc oxide, 1.6 parts of stearic acid, 1.4 parts of trimethoxy silane, 3 parts of sulfur, 0.7 part of dibenzothiazyl disulfide, 1.2 parts of benzothiazole sulfenamide, 13 parts of chlorosulfonated polyvinyl chloride, 4.5 parts of butyl benzyl phthalate, 3.4 parts of disodium dihydrogen pyrophosphate, 1.6 parts of tert-butyl hydroperoxide, 4 parts of polyvinyl chloride, 2 parts of calcium stearate, 0.6 part of sodium carboxymethyl cellulose, 1.3 parts of an anti-aging agent, 1.6 parts of trimethoxy silane, 2.5 parts of a silane coupling agent, 2.7 parts of modified glass fiber and 3 parts of epoxy fatty acid methyl ester.
Preferably, the formula raw material composition comprises the following components in parts by weight: 50 parts of polyurethane rubber, 35 parts of ethylene propylene diene monomer, 35 parts of chlorohydrin rubber, 15 parts of carbon black, 8 parts of white carbon black, 3 parts of glycerol methacrylate, 6 parts of zinc oxide, 2 parts of stearic acid, 2 parts of trimethoxy silane, 4 parts of sulfur, 1 part of dibenzothiazyl disulfide, 1.5 parts of benzothiazole sulfenamide, 16 parts of chlorosulfonated polyvinyl chloride, 6 parts of butyl benzyl phthalate, 4 parts of disodium dihydrogen pyrophosphate, 2 parts of tert-butyl hydroperoxide, 6 parts of polyvinyl chloride alcohol, 3 parts of calcium stearate, 0.8 part of sodium carboxymethyl cellulose, 1.5 parts of an anti-aging agent, 2 parts of trimethoxy silane, 3 parts of a silane coupling agent, 3 parts of modified glass fiber and 4 parts of epoxy fatty acid methyl ester.
Has the advantages that: the automobile parts prepared by the rubber formula have strong ageing resistance, are more durable, have obviously improved impact resistance and thermal stability, and overcome the limit value of high-hardness processing and performance of rubber products, so that the rubber has high hardness, excellent rigidity and mechanical performance, better damping effect and long service life.
Detailed Description
A rubber auto-parts material comprising: the rubber material comprises polyurethane rubber, ethylene propylene diene monomer rubber, chlorohydrin rubber, carbon black, white carbon black, glycerol methacrylate, zinc oxide, stearic acid, trimethoxy silane, sulfur, dibenzothiazyl disulfide, benzothiazole sulfenamide, chlorosulfonated polyvinyl chloride, butyl benzyl phthalate, disodium dihydrogen pyrophosphate, tert-butyl hydroperoxide, polyvinyl chloride alcohol, calcium stearate, sodium carboxymethyl cellulose, an anti-aging agent, trimethoxy silane, a silane coupling agent, modified glass fiber and epoxy fatty acid methyl ester, and the raw material composition comprises the following components in parts by weight: 40-50 parts of polyurethane rubber, 25-35 parts of ethylene propylene diene monomer, 15-35 parts of chlorohydrin rubber, 8-15 parts of carbon black, 5-8 parts of white carbon black, 2-3 parts of glycerol methacrylate, 3-6 parts of zinc oxide, 1-2 parts of stearic acid, 1-2 parts of trimethoxy silane, 2-4 parts of sulfur, 0.5-1 part of dibenzothiazyl disulfide, 1-1.5 parts of benzothiazole sulfonamide, 8-16 parts of chlorosulfonated polyvinyl chloride, 3-6 parts of butyl benzyl phthalate, 3-4 parts of disodium dihydrogen pyrophosphate, 1-2 parts of tert-butyl hydroperoxide, 2-6 parts of polyvinyl chloride, 1-3 parts of calcium stearate, 0.5-0.8 part of sodium carboxymethylcellulose, 1.1-1.5 parts of anti-aging agent, 1-2 parts of trimethoxy silane, sodium hydrogen peroxide, sodium hydrogen chloride, sodium hydrogen sulfate, sodium, 2-3 parts of silane coupling agent, 2-3 parts of modified glass fiber and 2-4 parts of epoxy fatty acid methyl ester.
Example one
The rubber automobile accessory material comprises the following components in parts by weight: 40 parts of polyurethane rubber, 25 parts of ethylene propylene diene monomer, 15 parts of chlorohydrin rubber, 8 parts of carbon black, 5 parts of white carbon black, 2 parts of glycerol methacrylate, 3 parts of zinc oxide, 1 part of stearic acid, 1 part of trimethoxy silane, 2 parts of sulfur, 0.5 part of dibenzothiazyl disulfide, 1 part of benzothiazole sulfenamide, 8 parts of chlorosulfonated polyvinyl chloride, 3 parts of butyl benzyl phthalate, 3-4 parts of disodium dihydrogen pyrophosphate, 1 part of tert-butyl hydroperoxide, 2 parts of polyvinyl chloride, 1 part of calcium stearate, 0.5 part of sodium carboxymethyl cellulose, 1.1 part of an anti-aging agent, 1 part of trimethoxy silane, 2 parts of a silane coupling agent, 2 parts of modified glass fiber and 2-4 parts of epoxy fatty acid methyl ester.
Example two
The rubber automobile accessory material comprises the following components in parts by weight: 45 parts of polyurethane rubber, 30 parts of ethylene propylene diene monomer, 28 parts of chlorohydrin rubber, 12 parts of carbon black, 6 parts of white carbon black, 2.4 parts of glycerol methacrylate, 5 parts of zinc oxide, 1.6 parts of stearic acid, 1.4 parts of trimethoxy silane, 3 parts of sulfur, 0.7 part of dibenzothiazyl disulfide, 1.2 parts of benzothiazole sulfenamide, 13 parts of chlorosulfonated polyvinyl chloride, 4.5 parts of butyl benzyl phthalate, 3.4 parts of disodium dihydrogen pyrophosphate, 1.6 parts of tert-butyl hydroperoxide, 4 parts of polyvinyl chloride, 2 parts of calcium stearate, 0.6 part of sodium carboxymethyl cellulose, 1.3 parts of an anti-aging agent, 1.6 parts of trimethoxy silane, 2.5 parts of a silane coupling agent, 2.7 parts of modified glass fiber and 3 parts of epoxy fatty acid methyl ester.
Example three
The rubber automobile accessory material comprises the following components in parts by weight: 50 parts of polyurethane rubber, 35 parts of ethylene propylene diene monomer, 35 parts of chlorohydrin rubber, 15 parts of carbon black, 8 parts of white carbon black, 3 parts of glycerol methacrylate, 6 parts of zinc oxide, 2 parts of stearic acid, 2 parts of trimethoxy silane, 4 parts of sulfur, 1 part of dibenzothiazyl disulfide, 1.5 parts of benzothiazole sulfenamide, 16 parts of chlorosulfonated polyvinyl chloride, 6 parts of butyl benzyl phthalate, 4 parts of disodium dihydrogen pyrophosphate, 2 parts of tert-butyl hydroperoxide, 6 parts of polyvinyl chloride alcohol, 3 parts of calcium stearate, 0.8 part of sodium carboxymethyl cellulose, 1.5 parts of an anti-aging agent, 2 parts of trimethoxy silane, 3 parts of a silane coupling agent, 3 parts of modified glass fiber and 4 parts of epoxy fatty acid methyl ester.
The automobile parts prepared by the rubber formula have strong ageing resistance and are more durable, the impact resistance and the thermal stability are obviously improved, and the limit values of high hardness processing and performance of rubber products are overcome, so that the rubber has high hardness, excellent rigidity and mechanical performance, better damping effect and long service life.
Although the present invention has been described with reference to a preferred embodiment, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (4)
1. A rubber auto-parts material, comprising: the rubber material comprises polyurethane rubber, ethylene propylene diene monomer rubber, chlorohydrin rubber, carbon black, white carbon black, glycerol methacrylate, zinc oxide, stearic acid, trimethoxy silane, sulfur, dibenzothiazyl disulfide, benzothiazole sulfenamide, chlorosulfonated polyvinyl chloride, butyl benzyl phthalate, disodium dihydrogen pyrophosphate, tert-butyl hydroperoxide, polyvinyl chloride alcohol, calcium stearate, sodium carboxymethyl cellulose, an anti-aging agent, trimethoxy silane, a silane coupling agent, modified glass fiber and epoxy fatty acid methyl ester, and the raw material composition comprises the following components in parts by weight: 40-50 parts of polyurethane rubber, 25-35 parts of ethylene propylene diene monomer, 15-35 parts of chlorohydrin rubber, 8-15 parts of carbon black, 5-8 parts of white carbon black, 2-3 parts of glycerol methacrylate, 3-6 parts of zinc oxide, 1-2 parts of stearic acid, 1-2 parts of trimethoxy silane, 2-4 parts of sulfur, 0.5-1 part of dibenzothiazyl disulfide, 1-1.5 parts of benzothiazole sulfonamide, 8-16 parts of chlorosulfonated polyvinyl chloride, 3-6 parts of butyl benzyl phthalate, 3-4 parts of disodium dihydrogen pyrophosphate, 1-2 parts of tert-butyl hydroperoxide, 2-6 parts of polyvinyl chloride, 1-3 parts of calcium stearate, 0.5-0.8 part of sodium carboxymethylcellulose, 1.1-1.5 parts of anti-aging agent, 1-2 parts of trimethoxy silane, sodium hydrogen peroxide, sodium hydrogen chloride, sodium hydrogen sulfate, sodium, 2-3 parts of silane coupling agent, 2-3 parts of modified glass fiber and 2-4 parts of epoxy fatty acid methyl ester.
2. The rubber automobile accessory material as claimed in claim 1, wherein the formulation raw material composition comprises the following components in parts by weight: 40 parts of polyurethane rubber, 25 parts of ethylene propylene diene monomer, 15 parts of chlorohydrin rubber, 8 parts of carbon black, 5 parts of white carbon black, 2 parts of glycerol methacrylate, 3 parts of zinc oxide, 1 part of stearic acid, 1 part of trimethoxy silane, 2 parts of sulfur, 0.5 part of dibenzothiazyl disulfide, 1 part of benzothiazole sulfenamide, 8 parts of chlorosulfonated polyvinyl chloride, 3 parts of butyl benzyl phthalate, 3-4 parts of disodium dihydrogen pyrophosphate, 1 part of tert-butyl hydroperoxide, 2 parts of polyvinyl chloride, 1 part of calcium stearate, 0.5 part of sodium carboxymethyl cellulose, 1.1 part of an anti-aging agent, 1 part of trimethoxy silane, 2 parts of a silane coupling agent, 2 parts of modified glass fiber and 2-4 parts of epoxy fatty acid methyl ester.
3. The rubber automobile accessory material as claimed in claim 1, wherein the formulation raw material composition comprises the following components in parts by weight: 45 parts of polyurethane rubber, 30 parts of ethylene propylene diene monomer, 28 parts of chlorohydrin rubber, 12 parts of carbon black, 6 parts of white carbon black, 2.4 parts of glycerol methacrylate, 5 parts of zinc oxide, 1.6 parts of stearic acid, 1.4 parts of trimethoxy silane, 3 parts of sulfur, 0.7 part of dibenzothiazyl disulfide, 1.2 parts of benzothiazole sulfenamide, 13 parts of chlorosulfonated polyvinyl chloride, 4.5 parts of butyl benzyl phthalate, 3.4 parts of disodium dihydrogen pyrophosphate, 1.6 parts of tert-butyl hydroperoxide, 4 parts of polyvinyl chloride, 2 parts of calcium stearate, 0.6 part of sodium carboxymethyl cellulose, 1.3 parts of an anti-aging agent, 1.6 parts of trimethoxy silane, 2.5 parts of a silane coupling agent, 2.7 parts of modified glass fiber and 3 parts of epoxy fatty acid methyl ester.
4. The rubber automobile accessory material as claimed in claim 1, wherein the formulation raw material composition comprises the following components in parts by weight: 50 parts of polyurethane rubber, 35 parts of ethylene propylene diene monomer, 35 parts of chlorohydrin rubber, 15 parts of carbon black, 8 parts of white carbon black, 3 parts of glycerol methacrylate, 6 parts of zinc oxide, 2 parts of stearic acid, 2 parts of trimethoxy silane, 4 parts of sulfur, 1 part of dibenzothiazyl disulfide, 1.5 parts of benzothiazole sulfenamide, 16 parts of chlorosulfonated polyvinyl chloride, 6 parts of butyl benzyl phthalate, 4 parts of disodium dihydrogen pyrophosphate, 2 parts of tert-butyl hydroperoxide, 6 parts of polyvinyl chloride alcohol, 3 parts of calcium stearate, 0.8 part of sodium carboxymethyl cellulose, 1.5 parts of an anti-aging agent, 2 parts of trimethoxy silane, 3 parts of a silane coupling agent, 3 parts of modified glass fiber and 4 parts of epoxy fatty acid methyl ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010198690.1A CN111423710A (en) | 2020-03-20 | 2020-03-20 | Rubber automobile accessory material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010198690.1A CN111423710A (en) | 2020-03-20 | 2020-03-20 | Rubber automobile accessory material |
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| Publication Number | Publication Date |
|---|---|
| CN111423710A true CN111423710A (en) | 2020-07-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010198690.1A Pending CN111423710A (en) | 2020-03-20 | 2020-03-20 | Rubber automobile accessory material |
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| CN (1) | CN111423710A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108148293A (en) * | 2017-12-18 | 2018-06-12 | 德施普科技发展温州有限公司 | A kind of arctic rubber and preparation method thereof |
| CN109679360A (en) * | 2019-02-20 | 2019-04-26 | 南通迅达橡塑制造有限公司 | A kind of anti-corrosive rubber |
| CN109749150A (en) * | 2019-02-19 | 2019-05-14 | 江苏骆氏减震件有限公司 | A kind of high intensity yielding rubber |
| CN109762320A (en) * | 2019-02-19 | 2019-05-17 | 江苏骆氏减震件有限公司 | A kind of antidetonation rubber composition material prescription |
| CN109762216A (en) * | 2019-02-20 | 2019-05-17 | 南通迅达橡塑制造有限公司 | A kind of fire-resistant corrosion-resistant rubber |
| CN109796648A (en) * | 2019-02-19 | 2019-05-24 | 江苏骆氏减震件有限公司 | A kind of yielding rubber pad material prescription |
| CN109810302A (en) * | 2019-02-19 | 2019-05-28 | 江苏骆氏减震件有限公司 | A kind of damping natural rubber composition material formula |
| CN110628147A (en) * | 2019-09-12 | 2019-12-31 | 宁波东胜橡胶制品有限公司 | Modified PVC (polyvinyl chloride) foamed floor mat and preparation method thereof |
-
2020
- 2020-03-20 CN CN202010198690.1A patent/CN111423710A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108148293A (en) * | 2017-12-18 | 2018-06-12 | 德施普科技发展温州有限公司 | A kind of arctic rubber and preparation method thereof |
| CN109749150A (en) * | 2019-02-19 | 2019-05-14 | 江苏骆氏减震件有限公司 | A kind of high intensity yielding rubber |
| CN109762320A (en) * | 2019-02-19 | 2019-05-17 | 江苏骆氏减震件有限公司 | A kind of antidetonation rubber composition material prescription |
| CN109796648A (en) * | 2019-02-19 | 2019-05-24 | 江苏骆氏减震件有限公司 | A kind of yielding rubber pad material prescription |
| CN109810302A (en) * | 2019-02-19 | 2019-05-28 | 江苏骆氏减震件有限公司 | A kind of damping natural rubber composition material formula |
| CN109679360A (en) * | 2019-02-20 | 2019-04-26 | 南通迅达橡塑制造有限公司 | A kind of anti-corrosive rubber |
| CN109762216A (en) * | 2019-02-20 | 2019-05-17 | 南通迅达橡塑制造有限公司 | A kind of fire-resistant corrosion-resistant rubber |
| CN110628147A (en) * | 2019-09-12 | 2019-12-31 | 宁波东胜橡胶制品有限公司 | Modified PVC (polyvinyl chloride) foamed floor mat and preparation method thereof |
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