CN111403555A - Battery piece preparation process, battery piece preparation device and battery piece - Google Patents

Battery piece preparation process, battery piece preparation device and battery piece Download PDF

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Publication number
CN111403555A
CN111403555A CN202010232076.2A CN202010232076A CN111403555A CN 111403555 A CN111403555 A CN 111403555A CN 202010232076 A CN202010232076 A CN 202010232076A CN 111403555 A CN111403555 A CN 111403555A
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battery piece
battery
whole
piece
insulating layer
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CN111403555B (en
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不公告发明人
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Wuxi Lead Intelligent Equipment Co Ltd
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Wuxi Lead Intelligent Equipment Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Computer Hardware Design (AREA)
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  • Condensed Matter Physics & Semiconductors (AREA)
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  • Microelectronics & Electronic Packaging (AREA)
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Abstract

The application discloses a battery piece preparation process, which at least carries out passivation treatment on a battery piece opening end to form an insulating layer on the battery piece opening end; through the formation of the insulating layer, the positions of the openings of the battery segments are passivated, so that a suspension key is removed, the surface state is reduced, the power loss in the battery assembly is reduced, and the reliability of the battery assembly is improved. The application also provides a battery piece preparation device, which can realize the battery piece preparation process; the cell preparation device comprises a scribing mechanism, a breaking mechanism and a passivation mechanism; the scribing mechanism is matched with the sheet breaking mechanism to break the whole battery sheet into a plurality of battery sheets meeting the specification; and then, the passivation mechanism carries out passivation treatment on the broken battery piece, so that an insulating layer is formed at the opening end of the battery piece. The application also provides a battery piece, which is prepared by the battery piece preparation device; the fracture end of the battery piece is provided with the insulating layer, so that the battery piece is high in reliability and high in conductive power.

Description

Battery piece preparation process, battery piece preparation device and battery piece
Technical Field
The application relates to the technical field of battery piece preparation, in particular to a battery piece preparation process, a battery piece preparation device and a battery piece.
Background
In order to increase the power of the cell string, in the current photovoltaic device, the whole cell is divided into two, or divided into three, or more.
However, after the whole battery piece is divided, the divided ends have dangling bonds, which affects the voltage and finally reduces the performance of the battery assembly, resulting in poor bending strength of the battery piece and low photoelectric conversion power.
Disclosure of Invention
The application provides a battery piece preparation process, a battery piece preparation device and a battery piece, which aim to overcome the technical defect that the performance of the battery piece is reduced after the battery piece is divided into whole battery pieces in the prior art.
In order to solve the technical problem, the application adopts a technical scheme that: the preparation process of the battery piece is provided, and at least passivation treatment is carried out on the opening end of the battery piece, so that an insulating layer is formed at the opening end of the battery piece.
Further, the preparation process of the battery piece comprises the following steps: scribing the surface of the whole cell by laser; breaking the whole battery piece along the scribing line, so that the whole battery piece is divided into a plurality of battery pieces; and passivating the battery piece to form an insulating layer at the opening end of the battery piece.
Further, the passivation process employs an a L D deposition technique.
Further, when the a L D deposition technique is adopted, the cell is placed into the a L D reaction chamber, and the chemical source material is carried out by inert gas, so that the chemical reaction is generated at the open end of the cell segment to form the insulating layer.
Further, the passivation treatment is to spray insulating material on the battery segment opening end to form an insulating layer.
The application also provides a battery piece preparation device, which can realize the battery piece preparation process; the battery piece preparation facilities includes: the scribing mechanism is used for scribing the surface of the whole battery piece; the sheet breaking mechanism is arranged at the downstream of the scribing mechanism and can break the whole cell along the scribing line; and the passivation mechanism is arranged at the downstream of the sheet breaking mechanism and can passivate the broken battery sheets.
Further, the dicing mechanism includes: the bearing table is used for bearing the whole battery piece; the working end of the laser equipment is aligned with the bearing table, and laser can be emitted to scribe the whole battery piece on the bearing table.
Further, the whole battery piece is divided into two parts; the scribing mechanism can scribe a straight line on the surface of the whole battery piece and divide the whole battery piece into a first part and a second part; break a piece mechanism off with fingers and thumb includes: a first extraction element for extracting a first portion; a second extraction element for extracting a second portion; and the rotating driving part is connected with the first extraction part and/or the second extraction part and can drive the first extraction part and the second extraction part to rotate relatively.
Furthermore, the passivation mechanism comprises an A L D reaction chamber at least capable of accommodating the cut end of the battery piece, at least one feeding pipe, at least one air inlet pipe and at least one air inlet pipe, wherein one end of the feeding pipe is communicated with the A L D reaction chamber, the other end of the feeding pipe is communicated with an external feeding device, and one end of the air inlet pipe is communicated with the A L D reaction chamber, and the other end of the air inlet pipe is communicated with an external air supply device.
The application also provides a battery piece, which is prepared by the battery piece preparation device.
The application provides a battery piece preparation process, which at least carries out passivation treatment on a battery piece opening end to form an insulating layer on the battery piece opening end; through the formation of the insulating layer, the positions of the openings of the battery segments are passivated, so that a suspension key is removed, the surface state is reduced, the power loss in the battery assembly is reduced, and the reliability of the battery assembly is improved.
The application also provides a battery piece preparation device, which can realize the battery piece preparation process; the cell preparation device comprises a scribing mechanism, a breaking mechanism and a passivation mechanism; the scribing mechanism is matched with the sheet breaking mechanism to break the whole battery sheet into a plurality of battery sheets meeting the specification; and then, the passivation mechanism carries out passivation treatment on the broken battery piece, so that an insulating layer is formed at the opening end of the battery piece.
The application also provides a battery piece, which is prepared by the battery piece preparation device; the fracture end of the battery piece is provided with the insulating layer, so that the battery piece is high in reliability and high in conductive power.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present application, the drawings needed to be used in the description of the embodiments are briefly introduced below, it is obvious that the drawings in the following description are only some embodiments of the present application, and other drawings can be obtained by those skilled in the art without inventive efforts, wherein:
FIG. 1 is a singulation process;
fig. 2 is a schematic diagram of an insulating layer formed at the mouth end of a battery piece after the passivation treatment is performed on the battery piece after the battery piece is divided;
FIG. 3 is a schematic structural diagram of an embodiment of a device for preparing a battery plate provided by the present application;
fig. 4 is a sheet separation process in which the entire cell sheet is divided into two.
Detailed Description
The technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
Referring first to fig. 1, fig. 1 illustrates a singulation process. The whole battery piece 1 is divided into a plurality of independent battery pieces 1 '/1' ″ … …; wherein, the separated side of two adjacent battery pieces is the fracture end of the battery piece. Therefore, the fracture end is a fracture position formed after the whole battery piece 1 is divided; since the position is cut, the inside of the entire cell piece 1 is exposed; although the exposed part of the cut end is also oxidized naturally, the formed oxide layer has insufficient passivation degree and high molecular activity, and the photoelectric conversion efficiency of the cell is reduced.
Therefore, the application discloses a battery piece preparation process, at least passivating the opening end of a battery piece to form an insulating layer at the opening end of the battery piece; through the formation of the insulating layer, the position of the opening of the battery piece is passivated, so that a dangling key is removed, the surface state is reduced, the power loss of the battery piece is reduced, and the reliability of the battery piece is improved.
Specifically, referring to fig. 2, the preparation process of the battery piece comprises the following steps: scribing the surface of the whole cell 1 by laser; breaking the whole cell slice 1 along the scribing line, so that the whole cell slice is divided into a plurality of cell slices 1 '/1'; the battery piece 1 '/1' is passivated, so that the insulating layer 2 is formed at the segment mouth end of the battery.
It is easy to understand that when the whole battery piece 1 is directly divided, the fracture ends are easily uneven, and the dividing quality cannot be guaranteed. Before splitting the whole cell piece 1, scribing the surface of the whole cell piece 1 by laser to form a dividing line 3; dividing the whole battery slice 1 into a plurality of battery slices 1 '/1' meeting the specification through a dividing line 3; the whole cell sheet 1 is divided along the dividing line 3 to obtain the desired cell sheet 1'/1 ".
Further, as for the passivation treatment, two ways can be generally adopted; one is an electroless plating film, for example, deposited by thermal oxidation, laughing gas oxidation, ozonization or nitric acid solution chemical method, thereby forming a SiO2 film layer at the fracture; for example, the film layer may be formed by PECVD (Plasma Enhanced Chemical Vapor Deposition), CVD (Chemical Vapor Deposition) or PVD (Physical Vapor Deposition) method to form Al2O3 film layer or containing Al2O3Or alternatively, deposited by the method of A L D.
It should be explained that, when a PECVD or CVD deposition process is used, the cell is sintered, the process temperature is high, and the silver paste on the surface of the cell is damaged by high temperature.
To this end, in one embodiment, the passivation process employs an a L D deposition technique.
Specifically, Atomic layer Deposition (A L D) is a surface chemical vapor Deposition-based nano-film Deposition technique that can deposit a material as a monoatomic film on a substrate surface by separately introducing two or more chemical sources into a reaction chamber while purging a vapor reaction product and an unreacted gas after a surface saturation reaction, thereby precisely controlling the thickness and uniformity of the deposited film within an Atomic layer thickness range, and SiO is manufactured by Atomic layer Deposition (A L D) and plasma Atomic layer Deposition (PEA L D)2、Al2O3And nano laminated layers and composite materials of SiNx and the like, thereby passivating the cut-off end, prolonging the minority carrier lifetime and improving the photoelectric conversion efficiency of the cell.
More specifically, using the a L D deposition technique, the cell 1'/1 "was placed in the a L D reaction chamber and the chemical source material was carried out by inert gas to react chemically at the cell segment open end to form the insulating layer 2.
The chemical source material is used for providing a silicon source, an aluminum source and/or an oxygen source, the relevant chemical source material is pulsed in an A L D reaction chamber according to the temperature and the vacuum degree required by the process, then inert gas is used for cleaning, and finally a composite film with the required thickness is formed at the opening end of the cell fragment through multiple times of pulsing and cleaning, namely the insulating layer 2 is formed.
It should be added that the passivation treatment can be performed on the battery segment opening end, for example, only the battery segment opening end is placed in the a L D reaction chamber for passivation treatment, or the whole battery piece is processed, for example, the battery piece is directly placed in the a L D reaction chamber for passivation operation, and the insulating layer 2 can be formed on the battery segment opening end.
Furthermore, the whole cell piece 1 is split to form a small cell piece with a fracture end, the fracture end is not flat, and based on the characteristic of A L D growth, the formed composite insulating layer 2 can be better coated on the surface of a complex structure, so that the connection position of the fracture end and the surrounding interface is further ensured to be coated, a good insulating layer 2 is formed, and the passivation effect is ensured.
For the passivation treatment, another embodiment is to directly coat the insulating layer 2 at the open end of the battery segment. For example, the insulating material is directly sprayed to the opening end of the battery segment to constitute the insulating layer 2.
Specifically, after the whole battery piece 1 is divided into a plurality of small battery pieces, an insulating material (e.g., an insulating varnish, or an insulating plastic, or an insulating film) may be sprayed or applied to the battery piece opening end, thereby forming the insulating layer 2 at the battery piece opening end.
The application also discloses a battery piece preparation device, which can realize the battery piece preparation process; the battery piece preparation facilities includes: the scribing mechanism 10 is used for scribing the surface of the whole battery piece 1; the sheet breaking mechanism 20 is arranged at the downstream of the scribing mechanism 10 and can break the whole cell sheet 1 along the scribing line; and a passivation mechanism 30 provided downstream of the sheet severing mechanism 20 and capable of passivating the severed cells 1'/1 ″.
With particular reference to fig. 3, the scribing mechanism 10 comprises: the bearing table 11 is used for bearing the whole battery piece 1; the laser device 12 has a working end facing the carrier 11 and can emit laser to scribe the entire cell 1 on the carrier 11. The whole battery piece 1 is placed on a bearing platform 11 and is delivered to the position below the laser device 12 by the bearing platform 11; the laser device 12 emits laser light to scribe the dividing lines 3 on the entire battery piece 1 by a predetermined stroke, thereby dividing the entire battery piece 1 into a plurality of small pieces.
The laser device 12 comprises a laser emitter and a laser driving component, wherein the laser driving component is connected with the laser emitter and can drive the laser emitter to move along the vertical and/or horizontal direction, so that the laser emitter can be controlled to mark a required dividing line 3 on the whole cell piece 1 along a preset track. Specifically, the laser driving assembly can be provided with a plurality of groups of linear driving mechanisms (for example, driving members such as an electric cylinder or a linear module are adopted) according to the requirement of a preset track, so that the laser transmitter can be driven to move as required.
In addition, in order to ensure the stability of laser scribing, the bearing table 11 can be provided with air holes and air extraction equipment communicated with the outside; therefore, after the whole battery piece 1 is arranged on the bearing platform 11, the air extraction equipment can vacuumize the inside of the bearing platform 11 to form negative pressure inside the bearing platform 11, so as to further absorb the whole battery piece 1 and prevent the whole battery piece 1 from displacing.
Further, the scribing mechanism 10 further includes a detecting component, which can detect the position and state of the whole battery piece 1 on the bearing table 11, and further transmit information to the control system, so that the control system controls the laser device 12 to accurately scribe the whole battery piece 1. Wherein, the detecting member can adopt a CCD (Charge-coupled Device) camera.
In one embodiment, referring to fig. 3 and 4, the whole cell 1 is divided into two parts; at this time, the scribing mechanism 10 can scribe a straight line on the surface of the whole cell piece 1 to divide the whole cell piece 1 into the first part 1' and the second part 1 "; the sheet severing mechanism 20 includes: a first extraction member 21 for extracting the first portion 1'; a second extraction element 22 for extracting a second portion 1 "; and a rotation driving member 23 connected to the first extraction member 21 and/or the second extraction member 22 and capable of driving the first extraction member 21 and the second extraction member 22 to rotate relatively.
Specifically, the first extraction part 21 and the second extraction part 22 are arranged side by side and are rotatably connected through a rotating shaft 24; the rotating shaft 24 is arranged along the extending direction of the dividing line 3; when the first extraction part 21 and the second extraction part 22 extract the first part 1 'and the second part 1', the rotating shaft 24 is opposite to the dividing line 3; the rotary driving member 23 drives the first extraction member 21 and the second extraction member 22 to rotate around the rotating shaft 14, so that the whole battery piece 1 can be broken along the dividing line 3.
The rotary driving member 23 may adopt a linear driving member such as an air cylinder, an electric cylinder, etc.; the output end of the rotary driving piece 23 is rotatably connected with one of the first extraction piece 21 and the second extraction piece 22 through a Y joint, and the other one of the first extraction piece 21 and the second extraction piece 22 is relatively fixedly arranged; when the rotating driving member 23 rotates, one of the first extraction member 21 and the second extraction member 22 rotates towards the other, so that the whole battery piece 1 can be broken. Alternatively, the rotary driving member 23 may adopt two sets of linear driving members, which are respectively connected with the first extracting member 21 and the second extracting member 22 in a rotary manner through Y joints; in this way, during rotation, the rotation driving member 23 can drive the first extraction member 21 and the second extraction member 22 to rotate towards each other, so as to break the whole battery piece 1.
Wherein, the first and second extractors 21 and 22 may adopt suction cups.
When the passivation treatment adopts the A L D deposition technology, the passivation mechanism 30 comprises an A L D reaction chamber 31 which can at least accommodate the cut end of the battery piece, at least one feeding pipe 32, at least one air inlet pipe 33 and at least one air inlet pipe 33, wherein one end of the feeding pipe 32 is communicated with the A L D reaction chamber 31, the other end of the feeding pipe is communicated with an external feeding device, and one end of the air inlet pipe 33 is communicated with the A L D reaction chamber 31, and the other end of the air inlet pipe is communicated with an external.
The feeding devices are used for providing the chemical source materials (namely, the silicon source, the aluminum source and/or the oxygen source), specifically, the required feeding devices are respectively arranged according to the process requirements and are respectively communicated with the A L D reaction chamber 31 through the feeding pipe 32, the feeding pipe 32 is provided with a control valve, the corresponding gaseous chemical source can be fed into the A L D reaction chamber 31 according to the process, similarly, the gas supply device is used for providing the inert gas, the gas inlet pipe 33 is also provided with a control valve, the inert gas can be fed into the A L D reaction chamber 31 according to the process, all the chemical source materials are connected with the inert gas, and the inert gas is used as a carrier gas and a purge gas for the A L D reaction.
Furthermore, the A L D reaction chamber 31 is also provided with a heating device and a cooling device, which can regulate and control the temperature in the A L D reaction chamber 31 to meet the reaction requirement, in addition, the A L D reaction chamber 31 is also provided with a vacuum device which can adjust the vacuum degree in the A L D reaction chamber 31 to meet the reaction requirement, and the specific parameters of the temperature and the vacuum degree are related to the actual reaction, and are not detailed here.
The cell is placed in the a L D reaction chamber 31, and the gas chemically reacts on the substrate by the a L D reaction to form a composite film, i.e., to constitute the insulating layer 2.
In addition, when the passivation treatment is performed by spraying an insulating material, the passivation treatment includes a spraying device or a coating device (not shown), and the inside of the device is filled with a gaseous or liquid insulating material; after the battery piece enters the device, the fracture end can be sprayed or smeared.
It should be added that the passivation treatment can be performed on the battery segment open end, for example, only the battery segment open end is placed in the a L D reaction chamber 31, or the spraying device, or the smearing device for passivation treatment, or the whole battery segment is processed, for example, the battery segment is directly placed in the a L D reaction chamber 31, or the spraying device, or the smearing device for passivation operation, and the formation of the insulating layer 2 on the battery segment open end can be achieved.
The application also discloses a battery piece which is prepared by the battery piece preparation device. The fracture end of the battery piece is provided with the insulating layer 2, so that the battery piece has good reliability and photoelectric conversion efficiency.
Furthermore, the terms "include" and "have," as well as any variations thereof, are intended to cover non-exclusive inclusions. Such that a process, method, system, article, or apparatus that comprises a list of steps or elements is not limited to only those steps or elements but may alternatively include other steps or elements not expressly listed or inherent to such process, method, article, or apparatus.
The above description is only an example of the present application and is not intended to limit the scope of the present application, and all modifications of equivalent structures and equivalent processes, which are made by the contents of the specification and the drawings, or which are directly or indirectly applied to other related technical fields, are intended to be included within the scope of the present application.

Claims (10)

1. The preparation process of the battery piece is characterized in that at least the segment opening end of the battery is passivated, so that an insulating layer is formed at the segment opening end of the battery.
2. The process for preparing a battery plate according to claim 1, which comprises the following steps:
scribing the surface of the whole cell (1) by laser;
breaking the whole battery piece (1) along the scribing line, so that the whole battery piece is divided into a plurality of battery pieces (1 '/1');
the battery piece (1 '/1') is passivated, so that an insulating layer (2) is formed at the opening end of the battery piece.
3. The battery piece preparation process as claimed in claim 1 or 2, wherein the passivation treatment adopts an A L D deposition technology.
4. The process for preparing a battery plate according to claim 3, wherein the A L D deposition technique is adopted, and the battery plate (1'/1 ") is placed into the A L D reaction chamber, and chemical source materials are carried out by inert gas to perform chemical reaction at the open end of the battery plate to form the insulating layer (2).
5. The battery piece preparation process according to claim 1 or 2, wherein the passivation treatment is to spray an insulating material on the battery piece opening end to form the insulating layer (2).
6. A battery piece manufacturing apparatus capable of implementing the battery piece manufacturing process according to any one of claims 1 to 5; the battery piece preparation device comprises:
the scribing mechanism (10) is used for scribing the surface of the whole battery piece (1);
the sheet breaking mechanism (20) is arranged at the downstream of the scribing mechanism (10) and can break the whole battery sheet (1) along a scribing line;
and a passivation mechanism (30) which is arranged at the downstream of the sheet breaking mechanism (20) and can passivate the broken battery sheets (1 '/1').
7. The device for preparing battery pieces according to claim 6, wherein the dicing mechanism (10) comprises:
the bearing table (11) is used for bearing the whole battery piece (1);
and the working end of the laser equipment (12) is right opposite to the bearing table (11), and can emit laser to scribe the whole battery piece (1) on the bearing table (11).
8. The battery piece preparation apparatus according to claim 6, wherein the whole battery piece (1) is divided into two; the scribing mechanism (10) can scribe a straight line on the surface of the whole battery piece (1) to divide the whole battery piece (1) into a first part (1 ') and a second part (1'); the sheet severing mechanism (20) includes:
-a first extraction member (21) for extracting said first portion (1');
-a second extraction member (22) for extracting said second portion (1 ");
and a rotary driving part (23) which is connected with the first extraction part (21) and/or the second extraction part (22) and can drive the first extraction part (21) and the second extraction part (22) to rotate relatively.
9. The device for preparing a battery plate as claimed in claim 6, wherein the passivation mechanism (30) comprises:
a L D reaction chamber (31), at least capable of accommodating the cut end of the battery piece;
at least one feeding pipe (32), wherein one end of the feeding pipe (32) is communicated with the A L D reaction chamber (31), and the other end of the feeding pipe is communicated with an external feeding device;
at least one intake pipe (33), intake pipe (33) one end intercommunication A L D reacting chamber (31), the other end intercommunication outside air feeder.
10. A battery sheet produced by the battery sheet production apparatus according to any one of claims 6 to 9.
CN202010232076.2A 2020-03-27 2020-03-27 Battery piece preparation process, battery piece preparation device and battery piece Active CN111403555B (en)

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CN111403555B CN111403555B (en) 2023-12-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112349811A (en) * 2020-10-27 2021-02-09 浙江晶科能源有限公司 Passivation method of battery piece

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103618033A (en) * 2013-12-05 2014-03-05 欧贝黎新能源科技股份有限公司 Silk-screen printing production manufacturing method of passivated-back solar cell
CN110071178A (en) * 2019-04-12 2019-07-30 泰州隆基乐叶光伏科技有限公司 A kind of preparation method being sliced battery and slice battery and photovoltaic module

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103618033A (en) * 2013-12-05 2014-03-05 欧贝黎新能源科技股份有限公司 Silk-screen printing production manufacturing method of passivated-back solar cell
CN110071178A (en) * 2019-04-12 2019-07-30 泰州隆基乐叶光伏科技有限公司 A kind of preparation method being sliced battery and slice battery and photovoltaic module

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112349811A (en) * 2020-10-27 2021-02-09 浙江晶科能源有限公司 Passivation method of battery piece

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