CN111361252A - 一种高透气性抗皱多层面料及其制备方法 - Google Patents

一种高透气性抗皱多层面料及其制备方法 Download PDF

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CN111361252A
CN111361252A CN202010232766.8A CN202010232766A CN111361252A CN 111361252 A CN111361252 A CN 111361252A CN 202010232766 A CN202010232766 A CN 202010232766A CN 111361252 A CN111361252 A CN 111361252A
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fabric
titanium dioxide
nano titanium
fibrilia
hydrophilic nano
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周璀琼
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Shenzhen Song Of Song Garments Co ltd
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Shenzhen Song Of Song Garments Co ltd
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
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    • B32—LAYERED PRODUCTS
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    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

本发明公开了一种高透气性抗皱多层面料及其制备方法，包括外层面料、里层面料和不少于两层的中间层面料，所述外层面料、里层面料和中间层面料之间通过胶接技术粘贴在一起，所述中间层面料为具有抗皱除臭功能的新性材料制成，本发明通过对麻纤维进行疏水改性，使纤维表面具有拒水性，达到迅速吸湿和快速放湿的效果，也能保持麻纤维本身良好的透气性及除菌除臭性能，本发明使亲水性纳米钛白粉、多元羧酸和麻纤维之间发生交联，形成交错的网状结构，增强并提高亲水性纳米钛白粉与织物的结合力与负载量，提高麻纤维的抗皱性，同时通过亲水性纳米钛白粉的光催化作用分解臭气，提高麻纤维的自净功能，避免臭味对人体健康产生影响。

Description

一种高透气性抗皱多层面料及其制备方法
技术领域
本发明涉及纺织技术领域，具体是一种高透气性抗皱多层面料及其制备方法。
背景技术
麻布是以亚麻、苎麻、黄麻、剑麻、蕉麻等各种麻类植物纤维制成的一种布料，麻布制成的产品具有透气清爽，柔软舒适耐洗、耐晒，防腐、抑菌的的特点，一般用来制作休闲装、工作装，也可用来制作环保包装，时尚手袋，工艺礼品，工艺书画，建筑装修，店铺装饰，园林用品，工艺鞋帽，精美吊牌等等，它的优点是强度极高、吸湿、导热、透气性甚佳，它的缺点则是容易在穿着过程中产生褶皱。
在人们的日常生活中还存在令人不愉快恶汗味、体臭、烟臭味、新房装修中产生的挥发性有机物异味，这些味道严重污染了清新的空气，影响了人们的生活环境和身心健康，特别是伴随老龄化社会的到来，卧床的老龄者增多，对防止恶臭措施的要求也随之增高，这些都促进了消臭整理的迅速发展，另外，纺织品在穿着、使用过程中，会不小心沾污渍，这些污物不仅影响人们的使用，也是微生物繁殖的良好环境。
针对上述问题，现在设计一种改进的高透气性抗皱多层面料及其制备方法。
发明内容
本发明的目的在于提供一种高透气性抗皱多层面料及其制备方法，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：
一种高透气性抗皱多层面料，包括外层面料、里层面料和不少于两层的中间层面料，所述外层面料、里层面料和中间层面料之间通过胶接技术粘贴在一起，所述外层面料由的高分子防水透气材料PTFE膜与布料复合而成，所述里层面料由柔性无害亲肤无纺布制成，所述中间层面料为具有抗皱除臭功能的新型材料制成。
一种高透气性抗皱多层面料的制备方法：所述中间层面料的制作方法包括配制亲水性纳米钛白粉分散液、改性麻纤维制备、脱水、基布准备、酸碱中和、柔软拉幅，具体步骤为：
(1)配制亲水性纳米钛白粉分散液：
称取亲水性纳米钛白粉，亲水性纳米钛白粉用量为3g/L，并加入去离子水，通过搅拌使亲水性纳米钛白粉充分溶解到去离子水中，搅拌一定时间，再加分散剂，分散剂用量为0.3g/L，搅拌23分钟，得到稳定的亲水性纳米钛白粉分散液；
(2)改性麻纤维制备：
将麻纤维用浓度为30g/L的特氟隆溶液浸渍，特氟隆溶液中加入亲水性纳米钛白粉分散液，亲水性纳米钛白粉分散液用量为14g/L、多元羧酸用量28g/L、催化剂13g/L、多氨基封端聚合物8g/L、适量的水；
(5)脱水：
在90℃条件下烘干15分钟，然后110-135℃烘焙2分钟；
(6)基布准备：
将纤维上机织造，由经线和纬线采用一上一下平纹组织交织得到基布，经线选用棉纤维；
(5)酸碱中和：在水洗中和机上进行，水洗温度：45℃，车速：35米/分钟，布面PH值为7.1；
(6)柔软拉幅：在拉幅机上进行，所用助剂的组分及重量配比为柔软剂EPS：20g/L，醋酸：0.9g/L，其余为水。
作为本发明再进一步的方案：分散剂的组分为SDS、六偏磷酸钠、多聚磷酸钠或乙二醇。
作为本发明再进一步的方案：通过搅拌使亲水性纳米钛白粉充分溶解到去离子水中，搅拌时间为23分钟。
作为本发明再进一步的方案：改性麻纤维制备过程中，亲水性纳米钛白粉分散液用量小于或等于多元羧酸用量的二分之一。
作为本发明再进一步的方案：脱水过程中，在96℃条件下烘干18分钟，然后130℃烘焙3分钟。
作为本发明再进一步的方案：基布准备步骤中纬线选用改性麻纤维。
与现有技术相比，本发明的有益效果是：
1、本发明通过对麻纤维进行疏水改性，在保留麻纤维本身良好的吸湿性的同时，使纤维表面具有拒水性，达到迅速吸湿和快速放湿的效果，且对纤维的吸湿平衡回潮率无太大影响，也能保持麻纤维本身良好的透气性及除菌除臭性能。
2、本发明使亲水性纳米钛白粉、多元羧酸和麻纤维之间发生交联，形成交错的网状结构，来改变麻纤维的属性，增强并提高亲水性纳米钛白粉与织物的结合力与负载量，提高麻纤维的抗皱性，同时通过亲水性纳米钛白粉的光催化作用分解臭气，提高麻纤维的自净功能，吸收人体和环境中的臭味，避免臭味对人体健康产生影响。
附图说明
图1为一种高透气性抗皱多层面料的结构示意图。
其中：外层面料100、里层面料200、中间层面料300。
具体实施方式
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
请参阅图1，本发明实施例中，一种高透气性抗皱多层面料，包括外层面料100、里层面料200和不少于两层的中间层面料300，所述外层面料100、里层面料200和中间层面料300之间通过胶接技术粘贴在一起，所述外层面料100由的高分子防水透气材料PTFE膜与布料复合而成，所述里层面料200由柔性无害亲肤无纺布制成，所述中间层面料300为具有抗皱除臭功能的新型材料制成。
所述中间层面料300的制作方法包括配制亲水性纳米钛白粉分散液、改性麻纤维制备、脱水、基布准备、酸碱中和、柔软拉幅，具体步骤为：
(1)配制亲水性纳米钛白粉分散液：
称取亲水性纳米钛白粉，亲水性纳米钛白粉用量为3g/L，并加入去离子水，通过搅拌使亲水性纳米钛白粉充分溶解到去离子水中，搅拌时间为23分钟，再加分散剂，分散剂用量为0.3g/L，搅拌23分钟，得到稳定的亲水性纳米钛白粉分散液，分散剂的组分为SDS、六偏磷酸钠、多聚磷酸钠或乙二醇；
(2)改性麻纤维制备：
将麻纤维用浓度为30g/L的特氟隆溶液浸渍，特氟隆溶液中加入亲水性纳米钛白粉分散液，亲水性纳米钛白粉分散液用量为14g/L、多元羧酸用量28g/L、催化剂13g/L、多氨基封端聚合物8g/L、适量的水；
由于亲水性纳米钛白粉中Ti-O键的极性较大，表面吸附的水因极化发生解离，容易形成-OH，本发明使用多元羧酸对织物进行活化改性处理，使得多元羧酸中部分COOH与纤维上-OH发生交联改性，多元羧酸改性织物上的剩余自由羧基再与亲水性纳米钛白粉的-OH发生酯化反应，三者之间以共价键相连，形成交错的网状结构，增强并提高亲水性纳米钛白粉与织物的结合力与负载量，通过亲水性纳米钛白粉的光催化作用分解臭气；
亲水性纳米钛白粉具有亲水性的亲水基团，能够破坏麻纤维中细胞壁，改变麻纤维的渗透压，促进特氟隆溶液进入纤维内部，对纤维进行改性，且无毒副作用，不刺激皮肤，对环境无污染，该步骤对麻纤维进行疏水改性，在保留麻纤维本身良好的吸湿性的同时，使纤维表面具有拒水性，达到迅速吸湿和快速放湿的效果，且对纤维的吸湿平衡回潮率无太大影响，也能保持麻纤维本身良好的透气性及除菌除臭性能；
(7)脱水：
在90℃条件下烘干15分钟，然后110℃烘焙2分钟；
(8)基布准备：
将纤维上机织造，由经线和纬线采用一上一下平纹组织交织得到基布，经线选用棉纤维，纬线选用改性麻纤维；
(5)酸碱中和：在水洗中和机上进行，水洗温度：45℃，车速：35米/分钟，布面PH值7.1；
(6)柔软拉幅：在拉幅机上进行，所用助剂的组分及重量配比为柔软剂EPS：20g/L，醋酸：0.9g/L，其余为水。
实施例2
一种高透气性抗皱多层面料，包括外层面料100、里层面料200和不少于两层的中间层面料300，所述外层面料100、里层面料200和中间层面料300之间通过胶接技术粘贴在一起，所述外层面料100由的高分子防水透气材料PTFE膜与布料复合而成，所述里层面料200由柔性无害亲肤无纺布制成，所述中间层面料300为具有抗皱除臭功能的新型材料制成。
所述中间层面料300的制作方法包括配制亲水性纳米钛白粉分散液、改性麻纤维制备、脱水、基布准备、酸碱中和、柔软拉幅，具体步骤为：
(1)配制亲水性纳米钛白粉分散液：
称取亲水性纳米钛白粉，亲水性纳米钛白粉用量为3g/L，并加入去离子水，通过搅拌使亲水性纳米钛白粉充分溶解到去离子水中，搅拌时间为23分钟，再加分散剂，分散剂用量为0.3g/L，搅拌23分钟，得到稳定的亲水性纳米钛白粉分散液，分散剂的组分为SDS、六偏磷酸钠、多聚磷酸钠或乙二醇；
(2)改性麻纤维制备：
将麻纤维用浓度为30g/L的特氟隆溶液浸渍，特氟隆溶液中加入亲水性纳米钛白粉分散液，亲水性纳米钛白粉分散液用量为14g/L、多元羧酸用量28g/L、催化剂13g/L、多氨基封端聚合物8g/L、适量的水；
由于亲水性纳米钛白粉中Ti-O键的极性较大，表面吸附的水因极化发生解离，容易形成-OH，本发明使用多元羧酸对织物进行活化改性处理，使得多元羧酸中部分COOH与纤维上-OH发生交联改性，多元羧酸改性织物上的剩余自由羧基再与亲水性纳米钛白粉的-OH发生酯化反应，三者之间以共价键相连，形成交错的网状结构，增强并提高亲水性纳米钛白粉与织物的结合力与负载量，通过亲水性纳米钛白粉的光催化作用分解臭气；
亲水性纳米钛白粉具有亲水性的亲水基团，能够破坏麻纤维中细胞壁，改变麻纤维的渗透压，促进特氟隆溶液进入纤维内部，对纤维进行改性，且无毒副作用，不刺激皮肤，对环境无污染，该步骤对麻纤维进行疏水改性，在保留麻纤维本身良好的吸湿性的同时，使纤维表面具有拒水性，达到迅速吸湿和快速放湿的效果，且对纤维的吸湿平衡回潮率无太大影响，也能保持麻纤维本身良好的透气性及除菌除臭性能；
(9)脱水：
在90℃条件下烘干15分钟，然后120℃烘焙2分钟；
(10)基布准备：
将纤维上机织造，由经线和纬线采用一上一下平纹组织交织得到基布，经线选用棉纤维，纬线选用改性麻纤维；
(5)酸碱中和：在水洗中和机上进行，水洗温度：45℃，车速：35米/分钟，布面PH值7.1；
(6)柔软拉幅：在拉幅机上进行，所用助剂的组分及重量配比为柔软剂EPS：20g/L，醋酸：0.9g/L，其余为水。
实施例3
一种高透气性抗皱多层面料，包括外层面料100、里层面料200和不少于两层的中间层面料300，所述外层面料100、里层面料200和中间层面料300之间通过胶接技术粘贴在一起，所述外层面料100由的高分子防水透气材料PTFE膜与布料复合而成，所述里层面料200由柔性无害亲肤无纺布制成，所述中间层面料300为具有抗皱除臭功能的新型材料制成。
所述中间层面料300的制作方法包括配制亲水性纳米钛白粉分散液、改性麻纤维制备、脱水、基布准备、酸碱中和、柔软拉幅，具体步骤为：
(1)配制亲水性纳米钛白粉分散液：
称取亲水性纳米钛白粉，亲水性纳米钛白粉用量为3g/L，并加入去离子水，通过搅拌使亲水性纳米钛白粉充分溶解到去离子水中，搅拌时间为23分钟，再加分散剂，分散剂用量为0.3g/L，搅拌23分钟，得到稳定的亲水性纳米钛白粉分散液，分散剂的组分为SDS、六偏磷酸钠、多聚磷酸钠或乙二醇；
(2)改性麻纤维制备：
将麻纤维用浓度为30g/L的特氟隆溶液浸渍，特氟隆溶液中加入亲水性纳米钛白粉分散液，亲水性纳米钛白粉分散液用量为14g/L、多元羧酸用量28g/L、催化剂13g/L、多氨基封端聚合物8g/L、适量的水；
由于亲水性纳米钛白粉中Ti-O键的极性较大，表面吸附的水因极化发生解离，容易形成-OH，本发明使用多元羧酸对织物进行活化改性处理，使得多元羧酸中部分COOH与纤维上-OH发生交联改性，多元羧酸改性织物上的剩余自由羧基再与亲水性纳米钛白粉的-OH发生酯化反应，三者之间以共价键相连，形成交错的网状结构，增强并提高亲水性纳米钛白粉与织物的结合力与负载量，通过亲水性纳米钛白粉的光催化作用分解臭气；
亲水性纳米钛白粉具有亲水性的亲水基团，能够破坏麻纤维中细胞壁，改变麻纤维的渗透压，促进特氟隆溶液进入纤维内部，对纤维进行改性，且无毒副作用，不刺激皮肤，对环境无污染，该步骤对麻纤维进行疏水改性，在保留麻纤维本身良好的吸湿性的同时，使纤维表面具有拒水性，达到迅速吸湿和快速放湿的效果，且对纤维的吸湿平衡回潮率无太大影响，也能保持麻纤维本身良好的透气性及除菌除臭性能；
(11)脱水：
在90℃条件下烘干15分钟，然后135℃烘焙2分钟；
(12)基布准备：
将纤维上机织造，由经线和纬线采用一上一下平纹组织交织得到基布，经线选用棉纤维，纬线选用改性麻纤维；
(5)酸碱中和：在水洗中和机上进行，水洗温度：45℃，车速：35米/分钟，布面PH值7.1；
(6)柔软拉幅：在拉幅机上进行，所用助剂的组分及重量配比为柔软剂EPS：20g/L，醋酸：0.9g/L，其余为水。
对于本领域技术人员而言，显然本发明不限于上述示范性实施例的细节，而且在不背离本发明的精神或基本特征的情况下，能够以其他的具体形式实现本发明。因此，无论从哪一点来看，均应将实施例看作是示范性的，而且是非限制性的，本发明的范围由所附权利要求而不是上述说明限定，因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。不应将权利要求中的任何附图标记视为限制所涉及的权利要求。
此外，应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施例中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。

Claims (7)

1.一种高透气性抗皱多层面料，包括外层面料(100)、里层面料(200)和不少于两层的中间层面料(300)，其特征在于，所述外层面料(100)、里层面料(200)和中间层面料(300)之间通过胶接技术粘贴在一起，所述外层面料(100)由的高分子防水透气材料PTFE膜与布料复合而成，所述里层面料(200)由柔性无害亲肤无纺布制成，所述中间层面料(300)为具有抗皱除臭功能的新型材料制成。
2.一种权利要求1高透气性抗皱多层面料的制备方法，其特征在于，所述中间层面料(300)的制作方法包括配制亲水性纳米钛白粉分散液、改性麻纤维制备、脱水、基布准备、酸碱中和、柔软拉幅，具体步骤为：
(1)配制亲水性纳米钛白粉分散液：
称取亲水性纳米钛白粉，亲水性纳米钛白粉用量为3g/L，并加入去离子水，通过搅拌使亲水性纳米钛白粉充分溶解到去离子水中，搅拌时间为一定时间，再加分散剂，分散剂用量为0.3g/L，搅拌23分钟，得到稳定的亲水性纳米钛白粉分散液；
(2)改性麻纤维制备：
将麻纤维用浓度为30g/L的特氟隆溶液浸渍，特氟隆溶液中加入亲水性纳米钛白粉分散液，亲水性纳米钛白粉分散液用量为14g/L、多元羧酸用量28g/L、催化剂13g/L、多氨基封端聚合物8g/L、适量的水；
(3)脱水：
在90-100℃条件下烘干15分钟，然后110-135℃烘焙2分钟；
(4)基布准备：
将纤维上机织造，由经线和纬线采用一上一下平纹组织交织得到基布，经线选用棉纤维；
(5)酸碱中和：在水洗中和机上进行，水洗温度：45℃，车速：35米/分钟，布面PH值为7.1；
(6)柔软拉幅：在拉幅机上进行，所用助剂的组分及重量配比为柔软剂EPS：20g/L，醋酸：0.9g/L，其余为水。
3.根据权利要求2所述的一种高透气性抗皱多层面料的制备方法，其特征在于，分散剂的组分为SDS、六偏磷酸钠、多聚磷酸钠或乙二醇。
4.根据权利要求2所述的一种高透气性抗皱多层面料的制备方法，其特征在于，改性麻纤维制备过程中，亲水性纳米钛白粉分散液用量小于或等于多元羧酸用量的二分之一。
5.根据权利要求2所述的一种高透气性抗皱多层面料的制备方法，其特征在于，通过搅拌使亲水性纳米钛白粉充分溶解到去离子水中，搅拌时间为23分钟。
6.根据权利要求2所述的一种高透气性抗皱多层面料的制备方法，其特征在于，脱水过程中，在95℃条件下烘干17分钟，然后120℃烘焙3分钟。
7.根据权利要求2所述的一种高透气性抗皱多层面料的制备方法，其特征在于，基布准备步骤中纬线选用改性麻纤维。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113276491A (zh) * 2021-05-24 2021-08-20 保定月上服饰制造有限公司 一种具有高防水耐污性能的夹克及其制作方法
CN115354490A (zh) * 2022-09-15 2022-11-18 深圳市歌中歌服饰有限公司 一种纤维混纺吸湿抑菌面料的制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113276491A (zh) * 2021-05-24 2021-08-20 保定月上服饰制造有限公司 一种具有高防水耐污性能的夹克及其制作方法
CN115354490A (zh) * 2022-09-15 2022-11-18 深圳市歌中歌服饰有限公司 一种纤维混纺吸湿抑菌面料的制备方法
CN115354490B (zh) * 2022-09-15 2024-02-13 深圳市歌中歌服饰有限公司 一种纤维混纺吸湿抑菌面料的制备方法

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