CN111360024A - Method for deeply removing soluble components in industrial waste residue - Google Patents
Method for deeply removing soluble components in industrial waste residue Download PDFInfo
- Publication number
- CN111360024A CN111360024A CN202010170012.4A CN202010170012A CN111360024A CN 111360024 A CN111360024 A CN 111360024A CN 202010170012 A CN202010170012 A CN 202010170012A CN 111360024 A CN111360024 A CN 111360024A
- Authority
- CN
- China
- Prior art keywords
- waste residue
- industrial waste
- soluble components
- industrial
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002440 industrial waste Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 32
- 239000002699 waste material Substances 0.000 claims abstract description 45
- 239000000725 suspension Substances 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000003756 stirring Methods 0.000 claims abstract description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000243 solution Substances 0.000 claims abstract description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 12
- 239000010703 silicon Substances 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 9
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 239000002956 ash Substances 0.000 claims abstract description 8
- 238000009713 electroplating Methods 0.000 claims abstract description 8
- 239000010881 fly ash Substances 0.000 claims abstract description 8
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 239000010802 sludge Substances 0.000 claims abstract description 8
- 239000003814 drug Substances 0.000 claims abstract description 7
- 239000010813 municipal solid waste Substances 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002910 solid waste Substances 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 5
- 239000011259 mixed solution Substances 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 4
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000010276 construction Methods 0.000 abstract description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000010791 domestic waste Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000413 hydrolysate Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 239000002210 silicon-based material Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000004056 waste incineration Methods 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B2101/00—Type of solid waste
- B09B2101/30—Incineration ashes
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to a method for deeply removing soluble components in industrial waste residue, which is characterized by comprising the following steps: adding a silicon-containing medicament into water, stirring at a high speed for 10-30 min at a temperature of 20-40 ℃, and controlling the pH value of the solution to be 10-12; step two, adding the solution obtained in the step one into a mixed solution of industrial waste residue and water to form a suspension; adding aluminum powder or hydrogen peroxide into the suspension, and stirring at a low speed of 40-80 ℃ for 30-75 min; and step four, filtering and drying the suspension liquid in the step three to obtain the industrial waste residue after the soluble components are removed. The method has wide application range, and can be suitable for the pretreatment of industrial solid wastes such as sulfur-containing waste residues, household garbage incineration fly ash, aluminum ash, salt-containing waste residues, electroplating sludge or nitrogen-containing waste residues. The obtained residue can be used as auxiliary materials for civil engineering and construction and other resource utilization ways, and is beneficial to the comprehensive utilization of waste residues.
Description
Technical Field
The invention belongs to the technical field of environmental protection, and particularly relates to a method for deeply removing soluble components in industrial waste residues.
Background
Wet treatment of waste residues is a common means of promoting the reaction of solid phase components and further separating them from the waste residues. In the wet treatment process, the components such as Al, Fe, Ca and the like contained in the industrial waste residue form hydroxide in water to wrap the surface of the waste residue, so that the waste residue is agglomerated, water is prevented from entering the inside of the waste residue, pre-separation components cannot be completely removed, and the waste residue is not beneficial to subsequent utilization or treatment. The existing common methods are heating, rapid stirring, multi-stage water washing, ultrasonic stirring and the like. The treatment steps are complicated, and the reaction time is long; heating is needed, and energy consumption is large; the industrial scale application is poor, and the influence of impurities is large; the cost is high, the agglomeration treatment of the product is incomplete, the steps are multiple, and the industrialization cannot be realized; the problem of incomplete reaction cannot be solved completely.
Aiming at the problems in the prior art, the method for removing the soluble components in the waste residue is simple and quick, high in treatment efficiency and wide in adaptability.
Disclosure of Invention
The invention aims to solve the problem that the soluble component of the industrial waste residue can not be fully dissolved and thoroughly separated in the water washing process, and further provides a method for deeply removing the soluble component of the industrial waste residue.
The invention relates to a method for deeply removing soluble components in industrial waste residue, which is characterized by comprising the following steps:
adding a silicon-containing medicament into water, stirring at a high speed for 10-30 min at a temperature of 20-40 ℃, and controlling the pH value of the solution to be 10-12;
step two, adding the solution obtained in the step one into a mixed solution of industrial waste residue and water to form a suspension;
adding aluminum powder or hydrogen peroxide into the suspension, and stirring at a low speed of 40-80 ℃ for 30-75 min;
and step four, filtering and drying the suspension liquid in the step three to obtain the industrial waste residue after the soluble components are removed.
Further, in the first step, the silicon-containing agent is one of sodium silicate, silicon dioxide or methyl silicate.
Further, in the second step, the industrial waste residue is industrial solid waste, including industrial solid waste such as sulfur-containing waste residue, household garbage incineration fly ash, aluminum ash, salt-containing waste residue, electroplating sludge or nitrogen-containing waste residue.
Further, in the first step, the high-speed stirring speed is 300-400 r/min.
Further, in the second step, the mass ratio of the silicon-containing medicament to the industrial waste residue is 1: (3-5), wherein the mass ratio of the waste residue to the water is 1: (3-5).
Further, in the third step, the mass ratio of the aluminum powder or hydrogen peroxide to the industrial waste residue is 1: (50-120);
further, in the third step, the low-speed stirring speed is 50-150 r/min.
The method is suitable for separating components in sulfur-containing waste residues, household garbage incineration fly ash, aluminum ash, salt-containing waste residues, electroplating sludge or nitrogen-containing waste residues. When waste residues are washed by water, a silicon-containing agent is added, and silicate hydrosol is controllably formed under a certain pH condition, so that silica gel particles are connected with each other to form a three-dimensional network structure taking silica tetrahedron as a basic structure and are coated on the surface of waste residue particles, so that the waste residues are uniformly distributed in turbid liquid, waste residue components are completely dispersed, the contact of the waste residues and water is promoted, and the hydrolysis or dissolution of pre-separation components is guaranteed. Compared with the conventional wet treatment process, the method can realize the complete separation of soluble components in the waste residue in a short time, and has simple operation and short treatment time. The temperature required in the process of forming silicate hydrosol by the silicon-containing agent and the process of adding the silicate hydrosol into the waste residue solution for stirring is lower, so that the method is more economical and is suitable for industrial application. Through the mechanism, the material components after reaction can be separated from the unreacted components, the removal efficiency is improved, the low energy consumption, the simple process and the high removal efficiency are realized, and the method can be used for the waste residue pretreatment of large-scale treatment.
The method has wide application range, and can treat not only alkaline waste residues but also acidic waste residues. The acidic or alkaline solution can promote the formation of silicate hydrosol, the hydrosol can uniformly disperse the waste residue components under the common working condition, and the treatment energy consumption is low; the silicate hydrosol is applied to the pretreatment of waste residues, has good treatment effect and simple operation, and can be applied to the industry. The obtained residue can be used as auxiliary materials for civil engineering and construction and other resource utilization ways, and is beneficial to the comprehensive utilization of waste residues.
Drawings
FIG. 1 is a scanning electron micrograph of a hydrolysate of a silicon-containing compound according to the present invention.
FIG. 2 is another scanning electron micrograph of a hydrolysate of a silicon-containing compound according to the present invention.
Detailed Description
The invention relates to a method for deeply removing soluble components in industrial waste residue, which comprises the following steps:
step one, adding a silicon-containing medicament into water, and stirring at a high speed of 300-400 r/min for 10-30 min at a temperature of 20-40 ℃. Controlling the pH value of the solution to be 10-12. Preferably, the silicon containing agent is one of sodium silicate, silica or methyl silicate.
Step two, adding the solution obtained in the step one into a mixed solution of industrial waste residue and water to form a suspension; the mass ratio of the silicon-containing medicament to the industrial waste residue is 1: (3-5), wherein the mass ratio of the waste residue to the water is 1: (3-5). The industrial waste residue is industrial solid waste, including sulfur-containing waste residue, domestic waste incineration fly ash, aluminum ash, salt-containing waste residue, electroplating sludge or nitrogen-containing waste residue and the like. Adding aluminum powder or hydrogen peroxide (30%) into the suspension, wherein the mass ratio of the suspension to the industrial waste residue is 1: (50-120); stirring at low speed for 30-75 min at 40-80 ℃; the low-speed stirring speed is 50-150 r/min.
And step four, filtering and drying the suspension liquid in the step three to obtain the industrial waste residue after the soluble components are removed.
Example 1
The embodiment relates to a deep removal treatment method for soluble components in fly ash generated by burning household garbage, which comprises the following steps:
step one, adding 50 kilograms of sodium silicate into water, stirring at a high speed of 300r/min for 10 minutes at 20 ℃, and controlling the pH value of the solution to be 10;
step two, adding 150 kg of domestic waste incineration fly ash and 450 kg of water into the solution obtained in the step one, and mixing to form suspension;
adding 3 kg of aluminum powder into the suspension, and stirring at a low speed of 50r/min for 30min at 80 ℃;
and step four, filtering and drying the suspension liquid obtained in the step three to obtain the household garbage incineration fly ash from which the soluble components are removed.
Example 2
The embodiment relates to a deep removal treatment method of soluble components in aluminum ash, which comprises the following steps:
step one, adding 30 kilograms of silicon dioxide into water, stirring at a high speed of 400r/min for 30min at 40 ℃, and controlling the pH value of the solution to be 11;
step two, adding 150 kg of aluminum ash and 750 kg of water into the solution obtained in the step one, and mixing to form a suspension;
step three, adding 1.25 kg of hydrogen peroxide into the suspension, and stirring at a low speed of 150r/min for 65min at 70 ℃;
and step four, filtering and drying the suspension liquid in the step three to obtain the aluminum ash after the soluble components are removed.
Example 3
The embodiment relates to a deep removal treatment method for soluble components in salt-containing waste residue, which comprises the following steps:
step one, adding 30 kg of methyl silicate into water, stirring at a high speed of 350r/min for 20min at a temperature of 30 ℃, and controlling the pH value of the solution to be 12;
step two, adding 140 kilograms of salt-containing waste residues and 560 kilograms of water into the solution obtained in the step one, and mixing to form suspension;
step three, adding 1.25 kg of hydrogen peroxide into the suspension, and stirring at low speed for 60min at 60 ℃, wherein the low-speed stirring speed is 100 r/min;
and step four, filtering and drying the suspension liquid obtained in the step three to obtain the salt-containing waste residue after the soluble components are removed.
Example 4
The embodiment relates to a deep removal treatment method for soluble components in electroplating sludge, which comprises the following steps:
step one, adding 60 kilograms of silicon dioxide into water, stirring at a high speed of 380r/min for 15min at a temperature of 25 ℃, and controlling the pH value of the solution to be 10;
step two, adding 300 kg of electroplating sludge and 1550 kg of water into the solution obtained in the step one, and mixing to form a suspension;
adding 2.5 kilograms of hydrogen peroxide into the suspension, and stirring at low speed of 150r/min for 75min at 50 ℃;
and step four, filtering and drying the suspension liquid in the step three to obtain the electroplating sludge from which the soluble components are removed.
Example 5
The embodiment relates to a deep removal treatment method of soluble components in nitrogenous waste residues, which comprises the following steps:
step one, adding 30 kilograms of silicon dioxide into water, stirring at a high speed of 320r/min for 20min at a temperature of 30 ℃, and controlling the pH value of the solution to be 12;
step two, adding 150 kg of nitrogenous waste residues and 750 kg of water into the solution obtained in the step one, and mixing to form suspension;
step three, adding 1.25 kg of hydrogen peroxide into the suspension, and stirring at low speed of 80r/min for 70min at 42 ℃;
and step four, filtering and drying the suspension liquid obtained in the step three to obtain the nitrogenous waste residue after the soluble components are removed.
The above-mentioned embodiments are only preferred embodiments of the present invention, and are not intended to limit the embodiments of the present invention, and those skilled in the art can easily make various changes and modifications according to the main concept and spirit of the present invention, so the protection scope of the present invention shall be subject to the protection scope of the claims.
Claims (7)
1. The method for deeply removing the soluble components in the industrial waste residue is characterized by comprising the following steps of:
adding a silicon-containing medicament into water, stirring at a high speed for 10-30 min at a temperature of 20-40 ℃, and controlling the pH value of the solution to be 10-12;
step two, adding the solution obtained in the step one into a mixed solution of industrial waste residue and water to form a suspension;
adding aluminum powder or hydrogen peroxide into the suspension, and stirring at a low speed of 40-80 ℃ for 30-75 min;
and step four, filtering and drying the suspension liquid in the step three to obtain the industrial waste residue after the soluble components are removed.
2. The method for deeply removing soluble components in industrial waste residue according to claim 1, wherein in the first step, the silicon-containing agent is one of sodium silicate, silicon dioxide or methyl silicate.
3. The method for deeply removing the soluble component in the industrial waste residue according to claim 1, wherein in the second step, the industrial waste residue is industrial solid waste, and comprises sulfur-containing waste residue, household garbage incineration fly ash, aluminum ash, salt-containing waste residue, electroplating sludge or nitrogen-containing waste residue.
4. The method for deeply removing the soluble component in the industrial waste residue according to claim 1, wherein in the first step, the high-speed stirring speed is 300-400 r/min.
5. The method for deeply removing the soluble component in the industrial waste residue as claimed in claim 1, wherein in the second step, the mass ratio of the silicon-containing medicament to the industrial waste residue is 1: (3-5), wherein the mass ratio of the waste residue to the water is 1: (3-5).
6. The method for deeply removing the soluble components in the industrial waste residue according to claim 1, wherein in the third step, the mass ratio of the aluminum powder or hydrogen peroxide to the industrial waste residue is 1: (50-120).
7. The method for deeply removing the soluble component in the industrial waste residue according to claim 1, wherein in the third step, the low-speed stirring speed is 50-150 r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010170012.4A CN111360024B (en) | 2020-03-12 | 2020-03-12 | Method for deeply removing soluble components in industrial waste residue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010170012.4A CN111360024B (en) | 2020-03-12 | 2020-03-12 | Method for deeply removing soluble components in industrial waste residue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111360024A true CN111360024A (en) | 2020-07-03 |
| CN111360024B CN111360024B (en) | 2021-12-24 |
Family
ID=71201939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010170012.4A Active CN111360024B (en) | 2020-03-12 | 2020-03-12 | Method for deeply removing soluble components in industrial waste residue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111360024B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006290713A (en) * | 2005-04-05 | 2006-10-26 | Natoo Kenkyusho:Kk | Method of reforming slag particle group as artificial sand, and artificial sand |
| CN101328035A (en) * | 2007-06-20 | 2008-12-24 | 中国矿业大学(北京) | Fly ash hollow microsphere surface modified whitening method |
| CN104984979A (en) * | 2015-06-23 | 2015-10-21 | 上海环境卫生工程设计院 | Method for stabilizing incineration fly ash by means of chemical coating |
| CN105290077A (en) * | 2014-06-16 | 2016-02-03 | 北京精诚博桑科技有限公司 | Method for coprocessing fly ash and landfill leachate |
| CN108721824A (en) * | 2018-05-22 | 2018-11-02 | 重庆大学 | The method of incineration of refuse flyash synchronism stability heavy metal and degrading polycyclic aromatic hydrocarbons |
| CN109940029A (en) * | 2019-04-18 | 2019-06-28 | 重庆大学 | The method for being catalyzed polycyclic aromatic hydrocarbon in subcritical water oxidation degradation incineration of refuse flyash |
-
2020
- 2020-03-12 CN CN202010170012.4A patent/CN111360024B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006290713A (en) * | 2005-04-05 | 2006-10-26 | Natoo Kenkyusho:Kk | Method of reforming slag particle group as artificial sand, and artificial sand |
| CN101328035A (en) * | 2007-06-20 | 2008-12-24 | 中国矿业大学(北京) | Fly ash hollow microsphere surface modified whitening method |
| CN105290077A (en) * | 2014-06-16 | 2016-02-03 | 北京精诚博桑科技有限公司 | Method for coprocessing fly ash and landfill leachate |
| CN104984979A (en) * | 2015-06-23 | 2015-10-21 | 上海环境卫生工程设计院 | Method for stabilizing incineration fly ash by means of chemical coating |
| CN108721824A (en) * | 2018-05-22 | 2018-11-02 | 重庆大学 | The method of incineration of refuse flyash synchronism stability heavy metal and degrading polycyclic aromatic hydrocarbons |
| CN109940029A (en) * | 2019-04-18 | 2019-06-28 | 重庆大学 | The method for being catalyzed polycyclic aromatic hydrocarbon in subcritical water oxidation degradation incineration of refuse flyash |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111360024B (en) | 2021-12-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111333354A (en) | Method for preparing non-sintered cement by using municipal domestic waste and product | |
| CN113072314A (en) | Treatment method of household garbage incineration fly ash | |
| CN103991940B (en) | A kind of coal ash for manufacturing is for hybrid flocculant technique | |
| CN112934912A (en) | Pretreatment method of waste incineration fly ash | |
| CN110639935A (en) | Waste incineration fly ash treatment method | |
| CN113477670A (en) | Carbon neutralization-based household garbage incineration fly ash resource utilization process | |
| CN105293454A (en) | Method for preparing dilute nitric acid, sponge tin and polymeric aluminum through spent tin-fading liquid | |
| CN113024064A (en) | Simple, convenient and efficient harmless treatment process for phosphorus-poor combustible sludge | |
| CN111360024B (en) | Method for deeply removing soluble components in industrial waste residue | |
| CN105238488A (en) | Coal dealkalization method | |
| CN105461815A (en) | Method for grafting anhydride onto cellulosic material in ionic liquid to prepare carboxyl cellulose | |
| CN113121156A (en) | Treatment method of hazardous waste incineration fly ash | |
| CN111359581B (en) | Method for preparing heavy metal adsorbent by using waste polyvinyl chloride plastic | |
| CN110526364B (en) | Method for preparing poly-aluminum ferric silicate flocculant by utilizing waste incineration fly ash | |
| CN108373248A (en) | A method of quickly preparing porous magnetic activated coke based on dewatered sludge | |
| CN113800542A (en) | High-efficiency resource utilization technology for coking desulfurization ash | |
| CN114933471B (en) | Method for preparing ceramic material by utilizing blast furnace slag and dechlorinated waste incineration fly ash | |
| CN207347180U (en) | A kind of system comprehensively utilized to Aluminum sludge | |
| CN105439504B (en) | A kind of recoverying and utilizing method of organosilicon slag slurry | |
| CN109081353A (en) | A kind of tobermorite and application using humic acid activation incinerator bottom ash preparation | |
| CN1541969A (en) | Method for producing cement using burning fly ash as blending stock | |
| CN110304800A (en) | A kind of processing method of chemical industry excess sludge | |
| CN112591758B (en) | Method for efficiently recycling zirconium and silicon in zirconium slag | |
| CN113578257B (en) | Iron tailing composite material and preparation method and application thereof | |
| CN102701222A (en) | Method for producing white carbon black with coal gangue |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A method for deep removal of soluble components from industrial waste residue Effective date of registration: 20221206 Granted publication date: 20211224 Pledgee: Dongyang Branch of China Construction Bank Co.,Ltd. Pledgor: Zhejiang Meishen New Material Technology Co.,Ltd. Registration number: Y2022980025349 |